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ficha de informações de segurança de produtos químicos ... - Acrilex

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Product name: Oil Colors Classic<br />

1 – Product/Company I<strong>de</strong>ntification<br />

Material Safety Data Sheet<br />

MSDS no.<br />

141<br />

Page<br />

1 / 6<br />

Last review date<br />

10/11/2008<br />

Product name: Oil Colors Classic<br />

Product internal co<strong>de</strong>: Ref: 14123 / 14137 / 14120 / 141160<br />

Company: <strong>Acrilex</strong> Tintas Especiais S/A<br />

Address: Estrada Galvão Bueno, 5.000 Bairro Batistini – S.B.C. – S.P.<br />

CEP (Postal Co<strong>de</strong>): 09842-900<br />

Phone: (0XX11) 4397-9255<br />

Fax: (0XX11) 4397-9009<br />

e-mail: tintas@acrilex.com.br<br />

Emergency phone numbers:<br />

Product Information: (0XX11) 4397-9265<br />

Medical Emergency: (0XX11) 4397-9245<br />

Transport emergency: (0XX11) 4397-9258<br />

2 – Composition and information on the ingredients<br />

Product type: Prepared<br />

Chemical nature (origin): Artistic Paint<br />

Ingredients or chemical impurities that may lead to hazard<br />

Chemical Name CAS No. Concentration range (%)<br />

Linseed Oil 8001-26-1 30 - 40<br />

Organic Pigments Not available 02 - 30<br />

Mineral Filler Not available 50 - 70<br />

Additives Not available 01 - 03<br />

3 – Hazards I<strong>de</strong>ntification<br />

Serious hazards: Product classified as harmful and inflammable.<br />

Product’s effects<br />

Adverse effects to human health: Harmful. The steam emitted for this product can irritate eyes,<br />

mucous membranes and skin. In strong concentrations, it can lead to<br />

narcosis. Ingestion can cause intense abdominal pain and gastric<br />

irritation.<br />

Main symptoms: It can cause nauseas and diarrhea.<br />

Physical and chemical hazards: Inflammable liquid.<br />

Specific hazards: Inflammable and harmful product.


Product name: Oil Colors Classic<br />

MSDS.: 141<br />

Page: 2 / 6<br />

Last review date 10/11/2008<br />

4 - First aid measures<br />

Inhalation: Bad effects to heath are not expected<br />

Contact with skin: wash with plenty of water and soap<br />

Contact with eyes: Wash with plenty of water until the irritation felling is gone. If the irritation is<br />

persisting, search for medical assistance.<br />

Ingestion: Search for medical assistance<br />

Notes to the physician: There is no specific antidote.<br />

5 - Fire fighting measures<br />

Proper extinguishing means<br />

Proper extinguishing means: Foam, dry chemical pow<strong>de</strong>r, CO2 (carbon dioxi<strong>de</strong>) extinguishers, water<br />

nebulization.<br />

Specific hazards: Avoid contact with flame or heat sources.<br />

Special methods: Cool the receptacles exposed to fire with water fog. Remove them from the fire<br />

area, if there is a possibility of doing this without any risk.<br />

Protection for the firefighters: During the fire fighting, use mask and complete protection against fire.<br />

6 – Acci<strong>de</strong>ntal release measures<br />

Personal precautions: Wear personal protective equipments (PPE). Provi<strong>de</strong> security for the people.<br />

Avoid contact with eyes and skin. Avoid the inhalation of fog and vapors. Avoid<br />

the direct contact with liquids. Reduce the vapor emission using a water spray.<br />

Removal of ignition sources: Eliminate all the ignition sources, avoid sparks, flames and smoking at risky area.<br />

Isolate the leakage from all the ignition sources.<br />

Dust control: Not applicable, because it is a liquid product.<br />

Prevention Prevenção da of inhalation inalação, Impermeable boots, gloves and clothes, hermetic security glasses for chemical<br />

and contact with skin,<br />

mucous mucosas and e olhos: eyes:<br />

products and appropriate respiratory protection.<br />

Precautions concerning to the<br />

environment: Stop the flow if possible, do not gui<strong>de</strong> the spread material for any public drain<br />

services. Avoid the possibility of contamination of superficial Waters and water<br />

sources. Restrict the leakage to the smallest area as much as possible. The later<br />

treatment of water should be taken into account before removing the product with<br />

water. Avoid using this kind of removal.


Product name: Oil Colors Classic<br />

MSDS.: 141<br />

Page: 3 / 6<br />

Last review date 10/11/2008 continuation…<br />

Cleaning measures:<br />

Recovering: Collect the product in an emergency receptacle properly labeled and well closed.<br />

Keep it recovered for subsequent elimination.<br />

Neutralization: Absorb with soil another absorbing material.<br />

Discard: Do not discard it together with the common waste. Do not discard it in the sewage<br />

system or in water courses. Keep it isolated if possible for later recovering or discard.<br />

The final discard of it should be supervised by a specialist, according to the valid<br />

environmental legislation.<br />

7 – Handling and storage<br />

Handling<br />

Technical measures: Provi<strong>de</strong> local ventilation where it is required by the processes. All the conduction<br />

elements of the system in contact with the product should be connected to an<br />

electrical ground system. Use anti-spark tools.<br />

Prevention of the worker<br />

exposition: Use personal protective equipments (PPE) in or<strong>de</strong>r to avoid contact with the<br />

product.<br />

Precautions for a Use the personal protective equipment indicated.<br />

secure handling:<br />

Gui<strong>de</strong>lines for a Handle according with the general rules of industrial security and hygiene.<br />

secure handling:<br />

Storage<br />

Appropriate technical measures: The storage place should have impermeable floor, free from combustible<br />

material. Besi<strong>de</strong>s that, it should be equipped with a contention dyke in or<strong>de</strong>r to<br />

retain the product in case of leakage.<br />

Storage conditions<br />

Appropriate: Store the product in tanks properly <strong>de</strong>signed and approved or metallic receptacles,<br />

like casks and well closed cans, well aired places and on the room temperature,<br />

un<strong>de</strong>r the atmospheric pressure, away from heat, oxidizing agents and ignition<br />

sources.<br />

To be avoi<strong>de</strong>d: Humid, uncovered and airless places.<br />

Non-compliant products/<br />

materials: Strong oxidizing products (liquid chlorine and concentrated oxygen).<br />

Secure material for the packages<br />

Recommen<strong>de</strong>d: Casks ma<strong>de</strong> of carbon steel and/or plastic packages.


Product name: Oil Colors Classic<br />

MSDS.: 141<br />

Page: 4 / 6<br />

Last review date 10/11/2008<br />

8 – Exposition control and personal protection<br />

Appropriate personal protective equipments<br />

Respiratory protection: In low concentrations, use respirator with chemical filter for organic vapors. In<br />

high concentrations, use respiratory equipment or an air sent assembly.<br />

Hands protection: PVC gloves or other gloves resistant to organic solvents.<br />

Eyes protection: In the operations in which there is the possibility of throwing or sprinkle of the<br />

product, it is recommen<strong>de</strong>d to use security glasses or facial protector.<br />

Protection for skin and body: In activities that result in direct contact with the liquid, use PVA aprons and boots.<br />

Special precautions: Keep emergency showers and eye washer available in the places in which the<br />

product is handled.<br />

Hygiene measures: Clean up clothes and shoes after use. General control methods commonly used in<br />

industrial hygiene should minimize the exposure to the product. Do not eat, drink<br />

or smoke while handling chemical products. Separate the working clothes from<br />

the common ones.<br />

9 – Physical and Chemical properties<br />

Physical state: Pasty<br />

Color: Several (According to the Catalogue)<br />

Odor: Characteristic<br />

pH: Not applicable<br />

Specific temperatures:<br />

Distillation range: Not available<br />

Flash point: 122 ° C (closed cup)<br />

Explosivity limits:<br />

Upper: (LES) 9,0 %<br />

Lower: (LEI) 0,9 %<br />

Density: Between 1,037 e 1,750 (Variable according to the color)<br />

Solubility: Insoluble in water.<br />

10 – Stability and reactivity<br />

Specific conditions<br />

Instability: Stable in normal handling and in normal storage conditions.<br />

Hazardous reactions: None, when the product is stored, used and processed correctly.<br />

Conditions to be avoi<strong>de</strong>d: Exposition to ignition sources and high temperatures for long periods.<br />

Hazardous products resulting<br />

from <strong>de</strong>composition: An incomplete combustion will result in the emission of irritable, corrosive and<br />

toxic gases.


Product name: Oil Colors Classic<br />

MSDS.: 141<br />

Page: 5 / 6<br />

Last review date 10/11/2008<br />

11 – Toxicological information<br />

Information according to the different exposition means<br />

Utmost toxicity: Harmful product.<br />

Local effects: It can provoke headache, nausea, vertigo, mental confusion, irritation in the upper<br />

airways. Mo<strong>de</strong>rately irritating for skin. Irritating for eyes.<br />

12 – Ecological information<br />

Environmental effects, behavior and impacts caused by the product<br />

Mobility Mo<strong>de</strong>rately volatile.<br />

Environmental impact: It can contaminate ground waters.<br />

Ecotoxicity: Like the most of the hydrocarbons, its presence in water can result in the<br />

transmission of unwanted quality to the water, making it impossible to be<br />

consumed.<br />

13 – Disposal consi<strong>de</strong>rations<br />

Disposal methods<br />

Product: The treatment and the discard of the product should be technically evaluated in<br />

each case.<br />

Product waste: Discard in an authorized installation.<br />

Used package: Discard in an authorized installation. Do not reuse the package.<br />

14 – Transport information<br />

National and international regulations Resolution No. 420/2004, ANTT (Agência Nacional <strong>de</strong> Transportes<br />

Terrestres - National Agency of Terrestrial Transport).<br />

Edict No. 96.044/88 (Regulamento <strong>de</strong> Transporte Rodoviário <strong>de</strong><br />

Produtos Perigosos – Regulation of Dangerous Goods Highway<br />

Transport) – Edict No. 98.973/90 (Regulamento <strong>de</strong> Transporte<br />

Ferroviário <strong>de</strong> Produtos Perigosos – Regulation of Dangerous<br />

Goods Railway Transport) - IATA handbook (International Air<br />

Transportation Association) - IMDG Co<strong>de</strong> handbook (International<br />

Maritime Dangerous Goods Co<strong>de</strong>) from IMO (International<br />

Maritime Organization).<br />

Product classified as dangerous and inflammable<br />

ONU Number: 1263<br />

Risk class 3<br />

Risk number 30<br />

Package group: III


Product name: Oil Colors Classic<br />

MSDS.: 141<br />

Page: 6 / 6<br />

Last review date 10/11/2008<br />

15 – Regulatory information<br />

Standards: ABNT / NBR 14725<br />

Directive 67/548/EEC<br />

Classification and symbols: Inflammable (F)<br />

Harmful (Xn)<br />

Information on risks and security, according to the product label:<br />

16 – Other information<br />

R10 - Inflammable product.<br />

R20 / R21 Harmful if inhaled or in contact with skin.<br />

S7 - Cover after use.<br />

S2 / S13- Keep out of reach of children and animals.<br />

S46 - In case of ingestion, do not provoke vomiting and seek medical assistance<br />

immediately, taking the product label or package.<br />

S51 - Used only in well aired places.<br />

This product is consi<strong>de</strong>red harmful and inflammable.

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