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4. First case study – the subdivision of the light - HM Treasury

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F05 Ch4 Subdivision <strong>of</strong> <strong>the</strong> <strong>light</strong>.doc<br />

05/04/2006 19:34:00<br />

Technological roulette <strong>–</strong> a multi-disciplinary <strong>study</strong> <strong>of</strong> <strong>the</strong> dynamics <strong>of</strong> innovation in electrical, electronic<br />

and communications engineering.<br />

<strong>4.</strong> <strong>First</strong> <strong>case</strong> <strong>study</strong> <strong>–</strong> <strong>the</strong> <strong>subdivision</strong> <strong>of</strong> <strong>the</strong> <strong>light</strong><br />

when one <strong>of</strong> <strong>the</strong> limbs was touched with a scalpel. Galvani later observed a similar<br />

reaction in legs which were hung by copper skewers from an iron rail. It fell to<br />

Allessandro Volta to give <strong>the</strong> correct<br />

explanation for this phenomenon, viz.<br />

that <strong>the</strong> contact between dissimilar<br />

metals gave rise to an electrical<br />

potential which acted as a stimulus for<br />

<strong>the</strong> muscular action.<br />

Volta went on to devise a<br />

practical means <strong>of</strong> utilising this effect <strong>–</strong><br />

his couronne des tasses, a battery<br />

consisting <strong>of</strong> a number <strong>of</strong> cups<br />

containing a saline solution into which<br />

were dipped plates <strong>of</strong> zinc and silver.<br />

The silver plate <strong>of</strong> one cup was<br />

connected to <strong>the</strong> zinc plate <strong>of</strong> <strong>the</strong> next<br />

cup, <strong>the</strong> terminal zinc and silver plates<br />

<strong>of</strong> <strong>the</strong> battery serving as a source from<br />

which a continuous electrical current<br />

could be drawn. He subsequently<br />

constructed his pile consisting <strong>of</strong><br />

alternating plates <strong>of</strong> dissimilar metals separated by discs <strong>of</strong> moistened material.<br />

The results <strong>of</strong> Volta’s research were communicated in a letter to Sir Joseph Banks,<br />

President <strong>of</strong> <strong>the</strong> Royal Society <strong>of</strong> London and read by him to <strong>the</strong> Society on 26th June<br />

1800, Houston 1894,p107 stimulating a host <strong>of</strong> inventions and discoveries in <strong>the</strong> field <strong>of</strong><br />

electrochemistry.<br />

In 1801, Humphry Davy was appointed as <strong>the</strong> director <strong>of</strong> <strong>the</strong> laboratory <strong>of</strong> <strong>the</strong> Royal<br />

Institution which had been founded by Count Rumford two years earlier. He used a<br />

Voltaic pile to perform electrolysis on a wide variety <strong>of</strong> chemical compounds.<br />

Davy’s bro<strong>the</strong>r noted Davy 1836, p446 that among <strong>the</strong>se early experiments were several<br />

investigations <strong>of</strong> luminous properties <strong>of</strong> <strong>the</strong> electric current. These were recorded in a<br />

65<br />

Fig. <strong>4.</strong>5 Volta’sCouronne des tasses<br />

Fig. <strong>4.</strong>6 Volta’s pile<br />

from Phil Trans Roy Soc (1800)<br />

Fleming1921<br />

Jarvis 1955a

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