Rovral® AquaFlo - agriCentre UK - BASF

SAFETY PRECAUTIONS
Operator protection
Engineering control of operator exposure must be used where reasonably practicable in addition to the
following personal protective clothing:
WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) AND SUITABLE PROTECTIVE GLOVES when handling
the concentrate, contaminated surfaces or treated seed.
WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) when bagging treated seed.
However, engineering controls may replace personal protective equipment if a COSHH assessment shows
they provide an equal or higher standard of protection.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY with plenty of water and seek medical advice.
IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible).
WHEN USING DO NOT EAT, DRINK OR SMOKE.
WASH HANDS AND EXPOSED SKIN before meals and after work.
DO NOT HANDLE seed unnecessarily.
Environmental protection
Do not contaminate surface waters or ditches with chemical or used container.
Consumer protection
DO NOT USE TREATED SEED as food or feed.
DO NOT RE-USE SACKS OR CONTAINERS THAT HAVE BEEN USED FOR TREATED SEED for food or feed.
Storage and disposal
KEEP OUT OF REACH OF CHILDREN.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS.
KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.
DO NOT RE-USE CONTAINER for any purpose.
KEEP TREATED SEED SECURE from people, domestic stock/pets and wildlife at all times during storage and
use.
BURY OR REMOVE SPILLAGES.
This label is compliant with the CPA Voluntary Initiative Guidance
Rovral ® AquaFlo
MAPP 14206
A suspension concentrate containing 500 g/l iprodione.
A seed treatment for the control of seed-borne Alternaria of ornamental seed.
The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work.
5 litres ℮
UN 3082
Packing Group III
Environmentally
Hazardous Substance,
Liquid, N.O.S.
(contains iprodione 43%)
Supplied by:
BASF plc
Crop Protection
PO Box 4, Earl Road
Cheadle Hulme, CHEADLE
Cheshire SK8 6QG
Tel: 0161 485 6222
Emergency Information:
(24 hours freephone):
0049 180 2273112
Technical Enquiries:
0845 602 2553 (office hours)
® = registered trademark of BASF 81067697GB1052
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HARMFUL
DANGEROUS FOR
THE ENVIRONMENT
Rovral ® AquaFlo
A suspension concentrate containing 500 g/litre iprodione
LIMITED EVIDENCE OF A CARCINOGENIC EFFECT
VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE
LONG TERM ADVERSE EFFECTS IN THE AQUATIC
ENVIRONMENT
WEAR SUITABLE PROTECTIVE CLOTHING AND GLOVES
KEEP OUT OF THE REACH OF CHILDREN
KEEP AWAY FROM FOOD, DRINK AND ANIMAL
FEEDINGSTUFFS
WHEN USING DO NOT EAT, DRINK OR SMOKE
IF SWALLOWED, SEEK MEDICAL ADVICE IMMEDIATELY
AND SHOW THIS CONTAINER OR LABEL
THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE WAY
USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION
FOR USE ONLY AS AN AGRICULTURAL/HORTICULTURAL SEED TREATMENT, as directed below:
CROPS MAXIMUM INDIVIDUAL
DOSE
To avoid risks to man and the environment, comply with
the instructions for use
This product is approved under the Plant Protection Products Regulations 2005.
IMPORTANT INFORMATION
MAXIMUM NUMBER OF
TREATMENTS PER CROP
LATEST TIME OF
APPLICATION
Ornamental seeds 1ml in 1 litre water 1 Prior to drilling/planting
Rovral AquaFlo must be used in conjunction with a seed treatment that is coloured or a coloured seed
film coating.
READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS
INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF
PRACTICE FOR USING PLANT PROTECTION PRODUCTS.
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DIRECTIONS FOR USE
IMPORTANT: This information is approved as part of the Product Label. All instructions within
this section must be read carefully in order to obtain safe and successful use of this product.
A seed treatment for the control of seed-borne Alternaria of ornamental seed.
1. Restrictions/Warnings
CONSULT PROCESSORS BEFORE USING ON CROPS INTENDED FOR PROCESSING.
Seed treatment may affect the rate of flow of seed through seed drills. Seed drills should be
re-calibrated before sowing any treated seed.
2. Disease Control
Rovral AquaFlo controls Alternaria spp. of ornamentals.
2.1 Resistance
Strains of Alternaria spp. resistant to iprodione are known to occur. Where strains exist Rovral
AquaFlo may not give satisfactory control.
3. Crop Specific Information
3.1 Ornamental Seeds
Rovral AquaFlo can be applied as a dressing to flower seeds to provide control of Alternaria
spp.
For the seed treatment, the seed can be soaked for eight hours in a solution of 1 ml of Rovral
AquaFlo in 1 litre of water. After treatment, dry the seeds thoroughly before sowing or packing.
Seeds of the bedding plants, Lobelia, Nemesia, wallflower, Zinnia and Cineraria spp may be
safely treated.
PRECAUTIONS – TREATED SEED
Information to be included on treated seed labels
THIS SEED HAS BEEN TREATED WITH Rovral AquaFlo (contains iprodione).
DO NOT HANDLE treated seed unnecessarily.
DO NOT USE TREATED SEED as food or feed.
DO NOT RE-USE SACKS OR CONTAINERS THAT HAVE BEEN USED FOR TREATED SEED
for food or feed.
KEEP TREATED SEED SECURE from people, domestic stock/pets and wildlife at all times
during storage and use.
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WASH HANDS AND EXPOSED SKIN before meals and after work.
BURY OR REMOVE SPILLAGES.
HARMFUL TO GAME AND WILDLIFE. Treated seed should not be left on the soil surface. Bury
spillages.
The following does not form part of the product label under the Plant Protection
Products Regulations 2005
With many products there is a general risk of resistance developing to the active ingredients.
For this reason a change in activity cannot be ruled out. It is generally impossible to predict with
certainty how resistance may develop because there are so many crop and use connected
ways of influencing this. We therefore have to exclude liability for damage or loss attributable
to any such resistance that may develop. To help minimise any loss in activity the BASF
recommended rate should in all events be adhered to.
Numerous, particularly regional or regionally attributable, factors can influence the activity of
the product. Examples include weather and soil conditions, crop plant varieties, crop rotation,
treatment times, application amounts, admixture with other products, appearance of organisms
resistant to active ingredients and spraying techniques. Under particular conditions a change
in activity or damage to plants cannot be ruled out. The manufacturer or supplier is therefore
unable to accept any liability in such circumstances. All goods supplied by us are of high grade
and we believe them to be suitable, but as we cannot exercise control over their mixing or use
or the weather conditions during and after application, which may affect the performance of the
material, all conditions and warranties, statutory or otherwise, as to the quality or fitness for any
purpose of our goods are excluded and no responsibility will be accepted by us for any damage
or injury whatsoever arising from their storage, handling, application or use; but nothing should
be deemed to exclude or restrict any liability upon us which cannot be excluded or restricted
under the provisions of the Unfair Contract Terms Act 1977 or any similar applicable law.
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Section 6 of the Health and Safety at Work Act
Additional Product Safety Information
The product label provides information on a specific pesticidal use of the product; do not
use otherwise, unless you have assessed any potential hazard involved, the safety measures
required and that the particular use has “off-label” approval or is otherwise permitted under the
Plant Protection Products Regulations.
The information on this label is based on the best available information including data from test
results
Safety Data Sheet
1. Identification of the substance/mixture and of the company/undertaking
ROVRAL AQUAFLO
Use: crop protection product, fungicide
Company:
BASF SE
67056 Ludwigshafen
GERMANY
Contact address:
BASF plc
PO Box 4, Earl Road, Cheadle Hulme, Cheadle, Cheshire
SK8 6QG, UNITED KINGDOM
Telephone: +44 161 485-6222
Telefax number: +44 161 488-4274
E-mail address: product-safety-north@basf.com
Emergency information:
International emergency number:
Telephone: +49 180 2273-112
2. Hazards Identification
Possible Hazards (according to Directive 67/548/EWG or 1999/45/EC)
Limited evidence of a carcinogenic effect.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. Composition/Information on Ingredients
Chemical nature
crop protection product, product for seed treatment, fungicide, suspension concentrate (SC)
Hazardous ingredients
according to Directive 1999/45/EC
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iprodione Content (W/W): 43.1 %
CAS Number: 36734-19-7
EC-Number: 253-178-9
INDEX-Number: 616-054-00-9
Hazard symbol(s): Xn, N
R-phrase(s): 40, 50/53
The wording of the hazard symbols and R-phrases is specified in chapter 16 if dangerous ingredients
are mentioned.
4. First-Aid Measures
General advice:
Avoid contact with the skin, eyes and clothing. Remove contaminated clothing. If difficulties occur:
Obtain medical attention. Show container, label and/or safety data sheet to physician.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
After contact with skin, wash immediately with plenty of water and soap. If irritation develops, seek
medical attention.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce
vomiting unless told to by a poison control center or doctor. Never induce vomiting or give anything by
mouth if the victim is unconscious or having convulsions.
Note to physician:
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.
5. Fire-Fighting Measures
Suitable extinguishing media:
water spray, carbon dioxide, foam, dry powder
Specific hazards:
carbon monoxide, hydrogen chloride, nitrogen oxides, organochloric compounds
The substances/groups of substances mentioned can be released in case of fire.
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if
exposed to fire. Collect contaminated extinguishing water separately, do not allow to reach sewage
or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with
official regulations.
6. Accidental Release Measures
Personal precautions:
Use personal protective clothing. Avoid contact with the skin, eyes and clothing. Remove contaminated
clothes, undergarments and shoes immediately.
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Environmental precautions:
Do not allow contamination of public drains or surface or ground waters. Inform local water plc if
spillage enters drains and the Environment Agency (England & Wales), the Scottish Environmental
Protection Agency (Scotland), or the Environment and Heritage Service (Northern Ireland) if it enters
surface or ground waters. Keep people and animals away.
Methods for cleaning up or taking up:
For small amounts: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose
binder, kieselguhr).
For large amounts: Dike spillage. Pump off product.
Cleaning operations should be carried out only while wearing breathing apparatus. Dispose of
absorbed material in accordance with regulations. Collect waste in suitable containers, which can
be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents,
observing environmental regulations.
7. Handling and Storage
Handling
No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores
and work areas.
Protection against fire and explosion:
No special precautions necessary. The substance/product is non-combustible. Product is not
explosive.
Storage
Segregate from foods and animal feeds.
Further information on storage conditions: Keep away from heat. Protect from direct sunlight.
Protect from temperatures below: 0 °C
The product can crystallize below the limit temperature.
Protect from temperatures above: 40 °C
Changes in the properties of the product may occur if substance/product is stored above indicated
temperature for extended periods of time.
8. Exposure Controls/Personal Protection
Components with workplace control parameters
none
For normal use and handling refer to the product label/leaflet. In all other cases the following apply.
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Wear respiratory protection if ventilation is
inadequate. Particle filter with medium efficiency for solid and liquid particles (e.g. EN 143 or 149,
Type P2 or FFP2)
Hand protection:
Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended:
Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile
rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) and other
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
~xmam1338901597.indd 7 05.06.2012 15:06:42

oots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case
of dust).
General safety and hygiene measures:
The statements on personal protective equipment in the instructions for use apply when handling cropprotection
agents in final-consumer packing. Avoid contact with the skin, eyes and clothing. Wearing
of closed work clothing is recommended. Take off immediately all contaminated clothing. Store work
clothing separately. Keep away from food, drink and animal feeding stuffs. No eating, drinking, smoking
or tobacco use at the place of work. Hands and/or face should be washed before breaks and at the
end of the shift.
9. Physical and Chemical Properties
Form: liquid, suspension
Colour: white
Odour: faint odour, fruity
pH value: 4.2 (20 °C) (measured with the undiluted substance)
5 - 6.5 (10 g/l, 20 °C)
crystallization temperature: -8.8 °C
Boiling point: approx. 100 °C
Flash point: Non-flammable., No flash point -
Measurement made up to the boiling
point.
(Directive 92/69/EEC, A.9)
Flammability: not highly flammable
Ignition temperature: 500 °C (Directive 92/69/EEC, A.15)
Explosion hazard: not explosive (Directive 92/69/EEC, A.14)
Fire promoting properties: not fire-propagating (calculated)
Vapour pressure: approx. 23 hPa
Information applies to the solvent.
(20 °C)
Density: approx. 1.164 g/cm3 (20 °C) (OECD Guideline 109)
Relative density: 1.164 (20 °C) (OECD Guideline 109)
Bulk density: not applicable
Solubility in water:
Partitioning coefficient
dispersible
n-octanol/water (log Pow): not applicable
Information on: iprodione (ISO);
3-(3,5-dichlorophenyl)-2,4-dioxo-N-isopropylimidazolidine-1-carboxamide
Partitioning coefficient n-octanol/water (log Pow): 3.0 (pH value: 5)
----------------------------------
Surface tension: 37.1 mN/m (4 %(V)) (OECD-Guideline 115)
Viscosity, dynamic: 67.8 mPa.s (20 °C, 100 1/s) (OECD 114)
10. Stability and Reactivity
Thermal decomposition: No decomposition if stored and handled as
prescribed/indicated.
Hazardous reactions:
No hazardous reactions if stored and handled as prescribed/indicated.
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.
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11. Toxicological Information
Acute toxicity
Experimental/calculated data:
LD50 rat (oral): > 2,000 mg/kg
LC50 rat (by inhalation): > 2.08 mg/l 4 h
An aerosol was tested.
LD50 rat (dermal): > 2,000 mg/kg
Irritation
Experimental/calculated data:
Skin corrosion/irritation rabbit: non-irritant
Serious eye damage/irritation rabbit: non-irritant
Respiratory/Skin sensitization
Experimental/calculated data:
modified Buehler test guinea pig: Skin sensitizing effects were not observed in animal studies. Skin
sensitizing effects were not observed in animal studies.
Other relevant toxicity information
Misuse can be harmful to health.
12. Ecological Information
Ecotoxicity
Toxicity to fish:
LC50 (96 h) 17.2 mg/l, Lepomis macrochirus
The product has not been tested. The statement has been derived from products of a similar structure
or composition.
Aquatic invertebrates:
EC50 (48 h) 2.67 mg/l, Daphnia magna (OECD Guideline 202, part 1)
Aquatic plants:
EC50 (72 h) 7.4 mg/l (biomass), Scenedesmus subspicatus
The product has not been tested. The statement has been derived from products of a similar structure
or composition.
Persistence and degradability
Assessment biodegradation and elimination (H2O):
Not readily biodegradable (by OECD criteria).
The ecological data given are those of the active ingredient.
Bioaccumulation potential
Information on: iprodione (ISO);
3-(3,5-dichlorophenyl)-2,4-dioxo-N-isopropylimidazolidine-1-carboxamide
Bioaccumulation potential:
Bioconcentration factor: 46.8
Significant accumulation in organisms is not to be expected.
----------------------------------
Additional information
Other ecotoxicological advice:
Do not discharge product into the environment without control.
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13. Disposal Considerations
Must be disposed of or incinerated in accordance with local regulations.
The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted
(United Kingdom).
This product and any uncleaned containers must be disposed of as hazardous waste in accordance
with the 2005 Hazardous Waste Regulations and amendments (United Kingdom)
Contaminated packaging:
Contaminated packaging should be emptied as far as possible and disposed of in the same manner
as the substance/product.
14. Transport Information
Land transport
ADR
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Proper shipping name:
RID
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains IPRODIONE 43%)
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains IPRODIONE 43%)
Inland waterway transport
ADNR
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Proper shipping name:
Sea transport
IMDG
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains IPRODIONE 43%)
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Marine pollutant: YES
Proper shipping name:
Air transport
IATA/ICAO
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains IPRODIONE 43%)
Hazard class: 9
Packing group: III
ID number: UN 3082
Hazard label: 9, EHSM
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains IPRODIONE 43%)
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Further information
This product is subject to The Carriage of Dangerous Goods and Use of Transportable Pressure
Equipment Regulations 2007 and their amendments (United Kingdom).
15. Regulatory Information
Regulations of the European union (Labelling) / National legislation/Regulations
Classification/labelling in accordance with UK regulations.:
Hazard symbol(s)
Xn Harmful.
N Dangerous for the environment.
R-phrase(s)
R40 Limited evidence of a carcinogenic effect.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
S-phrase(s)
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feeding stuffs.
S36/37 Wear suitable protective clothing and gloves.
S20/21 When using do not eat, drink or smoke.
S35 This material and its container must be disposed of in a safe way.
S46 If swallowed, seek medical advice immediately and show this container or label.
S57 Use appropriate container to avoid environmental contamination.
Hazard determining component(s) for labelling: IPRODIONE
Other regulations
To avoid risks to man and the environment, comply with the instructions for use.
The data should be considered when making any assessment under the Control of Substances
Hazardous to Health Regulations (COSHH), and related guidance, for example, ‚COSHH Essentials‘
(United Kingdom).
This product is classified under the Chemicals (Hazard Information and Packaging) Regulations,
(CHIP) (United Kingdom).
This product may be subject to the Control of Major Accident Hazards Regulations (COMAH), and
amendments if specific threshold tonnages are exceeded (United Kingdom).
16. Other Information
For proper and safe use of this product, please refer to the approval conditions laid down on the
product label.
Full text of hazard symbols and R-phrases if mentioned as hazardous components in chapter 3:
Xn Harmful.
N Dangerous for the environment.
40 Limited evidence of a carcinogenic effect.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
If you have any queries relating to this MSDS, it‘s contents or any other product safety related
questions, please write to the following e-mail address: product-safety-north@basf.com
The data contained in this safety data sheet are based on our current knowledge and experience
and describe the product only with regard to safety requirements. The data do not describe the
product‘s properties (product specification). Neither should any agreed property nor the suitability of
the product for any specific purpose be deduced from the data contained in the safety data sheet. It is
the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and
legislation are observed.
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MAPP 14206
A suspension concentrate containing 500 g/l iprodione.
A seed treatment for the control of seed-borne Alternaria of ornamental seed.
The (COSHH) Control of Substances Hazardous to Health Regulations may apply to the use of this product at work.
5 litres ℮
SAFETY PRECAUTIONS
Operator protection
Engineering control of operator exposure must be used where reasonably practicable in addition to the
following personal protective clothing:
WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) AND SUITABLE PROTECTIVE GLOVES when handling
the concentrate, contaminated surfaces or treated seed.
WEAR SUITABLE PROTECTIVE CLOTHING (COVERALLS) when bagging treated seed.
However, engineering controls may replace personal protective equipment if a COSHH assessment shows
they provide an equal or higher standard of protection.
IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY with plenty of water and seek medical advice.
IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible).
WHEN USING DO NOT EAT, DRINK OR SMOKE.
WASH HANDS AND EXPOSED SKIN before meals and after work.
DO NOT HANDLE seed unnecessarily.
Environmental protection
Do not contaminate surface waters or ditches with chemical or used container.
Consumer protection
DO NOT USE TREATED SEED as food or feed.
DO NOT RE-USE SACKS OR CONTAINERS THAT HAVE BEEN USED FOR TREATED SEED for food or feed.
Storage and disposal
KEEP OUT OF REACH OF CHILDREN.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS.
KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.
DO NOT RE-USE CONTAINER for any purpose.
KEEP TREATED SEED SECURE from people, domestic stock/pets and wildlife at all times during storage and
use.
BURY OR REMOVE SPILLAGES.
This label is compliant with the CPA Voluntary Initiative Guidance
Rovral ® AquaFlo
UN 3082
Packing Group III
Environmentally
Hazardous Substance,
Liquid, N.O.S.
(contains iprodione 43%)
Supplied by:
BASF plc
Crop Protection
PO Box 4, Earl Road
Cheadle Hulme, CHEADLE
Cheshire SK8 6QG
Tel: 0161 485 6222
Emergency Information:
(24 hours freephone):
0049 180 2273112
Technical Enquiries:
0845 602 2553 (office hours)
® = registered trademark of BASF 81067697GB1052
~xmam1338901597.indd 12 05.06.2012 15:06:42