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<strong>Wiki</strong> <strong>Book</strong> <strong>Mounir</strong> <strong>Gmati</strong>
<strong>Wiki</strong> <strong>Book</strong> <strong>Mounir</strong> <strong>Gmati</strong><br />
Lévitation Quantique:<br />
Les ingrédients et la recette<br />
PDF generated using the open source mwlib toolkit. See http://code.pediapress.com/ for more information.<br />
PDF generated at: Mon, 14 Nov 2011 01:54:04 UTC
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Contents<br />
Articles<br />
Superconductivity 1<br />
Superconductivity 1<br />
Type-I superconductor 14<br />
Yttrium barium copper oxide 15<br />
Liquid nitrogen 20<br />
Magnetism 23<br />
Magnetism 23<br />
Magnetic field 33<br />
Flux pinning 54<br />
Magnetic levitation 55<br />
References<br />
Article Sources and Contributors 63<br />
Image Sources, Licenses and Contributors 65<br />
Article Licenses<br />
License 66
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Superconductivity<br />
Superconductivity<br />
Superconductivity is a phenomenon of exactly zero electrical<br />
resistance occurring in certain materials below a characteristic<br />
temperature. It was discovered by Heike Kamerlingh Onnes on April 8,<br />
1911 in Leiden. Like ferromagnetism and atomic spectral lines,<br />
superconductivity is a quantum mechanical phenomenon. It is<br />
characterized by the Meissner effect, the complete ejection of magnetic<br />
field lines from the interior of the superconductor as it transitions into<br />
the superconducting state. The occurrence of the Meissner effect<br />
indicates that superconductivity cannot be understood simply as the<br />
idealization of perfect conductivity in classical physics.<br />
The electrical resistivity of a metallic conductor decreases gradually as<br />
temperature is lowered. In ordinary conductors, such as copper or<br />
silver, this decrease is limited by impurities and other defects. Even<br />
near absolute zero, a real sample of a normal conductor shows some<br />
resistance. In a superconductor, the resistance drops abruptly to zero<br />
when the material is cooled below its critical temperature. An electric<br />
current flowing in a loop of superconducting wire can persist<br />
indefinitely with no power source. [1]<br />
In 1986, it was discovered that some cuprate-perovskite ceramic<br />
materials have a critical temperature above 90 K (−183 °C). Such a<br />
high transition temperature is theoretically impossible for a<br />
conventional superconductor, leading the materials to be termed<br />
high-temperature superconductors. Liquid nitrogen boils at 77 K,<br />
facilitating many experiments and applications that are less practical at<br />
lower temperatures. In conventional superconductors, electrons are<br />
A magnet levitating above a high-temperature<br />
superconductor, cooled with liquid nitrogen.<br />
Persistent electric current flows on the surface of<br />
the superconductor, acting to exclude the<br />
magnetic field of the magnet (Faraday's law of<br />
induction). This current effectively forms an<br />
electromagnet that repels the magnet.<br />
A high-temperature superconductor levitating<br />
above a magnet<br />
held together in pairs by an attraction mediated by lattice phonons. The best available model of high-temperature<br />
superconductivity is still somewhat crude. There is a hypothesis that electron pairing in high-temperature<br />
superconductors is mediated by short-range spin waves known as paramagnons.<br />
Classification<br />
There is not just one criterion to classify superconductors. The most common are<br />
• By their physical properties: they can be Type I (if their phase transition is of first order) or Type II (if their<br />
phase transition is of second order).<br />
• By the theory to explain them: they can be conventional (if they are explained by the BCS theory or its<br />
derivatives) or unconventional (if not).<br />
• By their critical temperature: they can be high temperature (generally considered if they reach the<br />
superconducting state just cooling them with liquid nitrogen, that is, if T c > 77 K), or low temperature (generally<br />
if they need other techniques to be cooled under their critical temperature).<br />
1
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Superconductivity 2<br />
• By material: they can be chemical elements (as mercury or lead), alloys (as niobium-titanium or<br />
germanium-niobium or niobium nitride), ceramics (as YBCO or the magnesium diboride), or organic<br />
superconductors (as fullerenes or carbon nanotubes, though these examples technically might be included among<br />
the chemical elements as they are composed entirely of carbon).<br />
Elementary properties of superconductors<br />
Most of the physical properties of superconductors vary from material to material, such as the heat capacity and the<br />
critical temperature, critical field, and critical current density at which superconductivity is destroyed.<br />
On the other hand, there is a class of properties that are independent of the underlying material. For instance, all<br />
superconductors have exactly zero resistivity to low applied currents when there is no magnetic field present or if the<br />
applied field does not exceed a critical value. The existence of these "universal" properties implies that<br />
superconductivity is a thermodynamic phase, and thus possesses certain distinguishing properties which are largely<br />
independent of microscopic details.<br />
Zero electrical DC resistance<br />
The simplest method to measure the electrical resistance of a sample of<br />
some material is to place it in an electrical circuit in series with a<br />
current source I and measure the resulting voltage V across the sample.<br />
The resistance of the sample is given by Ohm's law as R = V/I. If the<br />
voltage is zero, this means that the resistance is zero.<br />
Superconductors are also able to maintain a current with no applied<br />
voltage whatsoever, a property exploited in superconducting<br />
electromagnets such as those found in MRI machines. Experiments<br />
have demonstrated that currents in superconducting coils can persist<br />
for years without any measurable degradation. Experimental evidence<br />
points to a current lifetime of at least 100,000 years. Theoretical<br />
estimates for the lifetime of a persistent current can exceed the<br />
estimated lifetime of the universe, depending on the wire geometry and the temperature. [1]<br />
Electric cables for accelerators at CERN: top,<br />
regular cables for LEP; bottom, superconducting<br />
cables for the LHC<br />
In a normal conductor, an electric current may be visualized as a fluid of electrons moving across a heavy ionic<br />
lattice. The electrons are constantly colliding with the ions in the lattice, and during each collision some of the<br />
energy carried by the current is absorbed by the lattice and converted into heat, which is essentially the vibrational<br />
kinetic energy of the lattice ions. As a result, the energy carried by the current is constantly being dissipated. This is<br />
the phenomenon of electrical resistance.<br />
The situation is different in a superconductor. In a conventional superconductor, the electronic fluid cannot be<br />
resolved into individual electrons. Instead, it consists of bound pairs of electrons known as Cooper pairs. This<br />
pairing is caused by an attractive force between electrons from the exchange of phonons. Due to quantum mechanics,<br />
the energy spectrum of this Cooper pair fluid possesses an energy gap, meaning there is a minimum amount of<br />
energy ΔE that must be supplied in order to excite the fluid. Therefore, if ΔE is larger than the thermal energy of the<br />
lattice, given by kT, where k is Boltzmann's constant and T is the temperature, the fluid will not be scattered by the<br />
lattice. The Cooper pair fluid is thus a superfluid, meaning it can flow without energy dissipation.<br />
In a class of superconductors known as type II superconductors, including all known high-temperature<br />
superconductors, an extremely small amount of resistivity appears at temperatures not too far below the nominal<br />
superconducting transition when an electric current is applied in conjunction with a strong magnetic field, which<br />
may be caused by the electric current. This is due to the motion of vortices in the electronic superfluid, which<br />
dissipates some of the energy carried by the current. If the current is sufficiently small, the vortices are stationary,
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Superconductivity 3<br />
and the resistivity vanishes. The resistance due to this effect is tiny compared with that of non-superconducting<br />
materials, but must be taken into account in sensitive experiments. However, as the temperature decreases far enough<br />
below the nominal superconducting transition, these vortices can become frozen into a disordered but stationary<br />
phase known as a "vortex glass". Below this vortex glass transition temperature, the resistance of the material<br />
becomes truly zero.<br />
Superconducting phase transition<br />
In superconducting materials, the<br />
characteristics of superconductivity<br />
appear when the temperature T is<br />
lowered below a critical temperature<br />
T c . The value of this critical<br />
temperature varies from material to<br />
material. Conventional<br />
superconductors usually have critical<br />
temperatures ranging from around<br />
20 K to less than 1 K. Solid mercury,<br />
for example, has a critical temperature<br />
of 4.2 K. As of 2009, the highest<br />
critical temperature found for a<br />
conventional superconductor is 39 K<br />
[2] [3]<br />
for magnesium diboride (MgB ),<br />
2<br />
although this material displays enough<br />
exotic properties that there is some<br />
Behavior of heat capacity (c v , blue) and resistivity (ρ, green) at the superconducting phase<br />
transition<br />
doubt about classifying it as a "conventional" superconductor. [4] Cuprate superconductors can have much higher<br />
critical temperatures: YBa 2 Cu 3 O 7 , one of the first cuprate superconductors to be discovered, has a critical<br />
temperature of 92 K, and mercury-based cuprates have been found with critical temperatures in excess of 130 K. The<br />
explanation for these high critical temperatures remains unknown. Electron pairing due to phonon exchanges<br />
explains superconductivity in conventional superconductors, but it does not explain superconductivity in the newer<br />
superconductors that have a very high critical temperature.<br />
Similarly, at a fixed temperature below the critical temperature, superconducting materials cease to superconduct<br />
when an external magnetic field is applied which is greater than the critical magnetic field. This is because the Gibbs<br />
free energy of the superconducting phase increases quadratically with the magnetic field while the free energy of the<br />
normal phase is roughly independent of the magnetic field. If the material superconducts in the absence of a field,<br />
then the superconducting phase free energy is lower than that of the normal phase and so for some finite value of the<br />
magnetic field (proportional to the square root of the difference of the free energies at zero magnetic field) the two<br />
free energies will be equal and a phase transition to the normal phase will occur. More generally, a higher<br />
temperature and a stronger magnetic field lead to a smaller fraction of the electrons in the superconducting band and<br />
consequently a longer London penetration depth of external magnetic fields and currents. The penetration depth<br />
becomes infinite at the phase transition.<br />
The onset of superconductivity is accompanied by abrupt changes in various physical properties, which is the<br />
hallmark of a phase transition. For example, the electronic heat capacity is proportional to the temperature in the<br />
normal (non-superconducting) regime. At the superconducting transition, it suffers a discontinuous jump and<br />
thereafter ceases to be linear. At low temperatures, it varies instead as e −α /T for some constant, α. This exponential<br />
behavior is one of the pieces of evidence for the existence of the energy gap.
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Superconductivity 4<br />
The order of the superconducting phase transition was long a matter of debate. Experiments indicate that the<br />
transition is second-order, meaning there is no latent heat. However in the presence of an external magnetic field<br />
there is latent heat, as a result of the fact that the superconducting phase has a lower entropy below the critical<br />
temperature than the normal phase. It has been experimentally demonstrated [5] that, as a consequence, when the<br />
magnetic field is increased beyond the critical field, the resulting phase transition leads to a decrease in the<br />
temperature of the superconducting material.<br />
Calculations in the 1970s suggested that it may actually be weakly first-order due to the effect of long-range<br />
fluctuations in the electromagnetic field. In the 1980s it was shown theoretically with the help of a disorder field<br />
theory, in which the vortex lines of the superconductor play a major role, that the transition is of second order within<br />
the type II regime and of first order (i.e., latent heat) within the type I regime, and that the two regions are separated<br />
by a tricritical point. [6] The results were confirmed by Monte Carlo computer simulations. [7]<br />
Meissner effect<br />
When a superconductor is placed in a weak external magnetic field H, and cooled below its transition temperature,<br />
the magnetic field is ejected. The Meissner effect does not cause the field to be completely ejected but instead the<br />
field penetrates the superconductor but only to a very small distance, characterized by a parameter λ, called the<br />
London penetration depth, decaying exponentially to zero within the bulk of the material. The Meissner effect is a<br />
defining characteristic of superconductivity. For most superconductors, the London penetration depth is on the order<br />
of 100 nm.<br />
The Meissner effect is sometimes confused with the kind of diamagnetism one would expect in a perfect electrical<br />
conductor: according to Lenz's law, when a changing magnetic field is applied to a conductor, it will induce an<br />
electric current in the conductor that creates an opposing magnetic field. In a perfect conductor, an arbitrarily large<br />
current can be induced, and the resulting magnetic field exactly cancels the applied field.<br />
The Meissner effect is distinct from this—it is the spontaneous expulsion which occurs during transition to<br />
superconductivity. Suppose we have a material in its normal state, containing a constant internal magnetic field.<br />
When the material is cooled below the critical temperature, we would observe the abrupt expulsion of the internal<br />
magnetic field, which we would not expect based on Lenz's law.<br />
The Meissner effect was given a phenomenological explanation by the brothers Fritz and Heinz London, who<br />
showed that the electromagnetic free energy in a superconductor is minimized provided<br />
where H is the magnetic field and λ is the London penetration depth.<br />
This equation, which is known as the London equation, predicts that the magnetic field in a superconductor decays<br />
exponentially from whatever value it possesses at the surface.<br />
A superconductor with little or no magnetic field within it is said to be in the Meissner state. The Meissner state<br />
breaks down when the applied magnetic field is too large. Superconductors can be divided into two classes according<br />
to how this breakdown occurs. In Type I superconductors, superconductivity is abruptly destroyed when the strength<br />
of the applied field rises above a critical value H c . Depending on the geometry of the sample, one may obtain an<br />
intermediate state [8] consisting of a baroque pattern [9] of regions of normal material carrying a magnetic field mixed<br />
with regions of superconducting material containing no field. In Type II superconductors, raising the applied field<br />
past a critical value H c1 leads to a mixed state (also known as the vortex state) in which an increasing amount of<br />
magnetic flux penetrates the material, but there remains no resistance to the flow of electric current as long as the<br />
current is not too large. At a second critical field strength H c2 , superconductivity is destroyed. The mixed state is<br />
actually caused by vortices in the electronic superfluid, sometimes called fluxons because the flux carried by these<br />
vortices is quantized. Most pure elemental superconductors, except niobium, technetium, vanadium and carbon<br />
nanotubes, are Type I, while almost all impure and compound superconductors are Type II.
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Superconductivity 5<br />
London moment<br />
Conversely, a spinning superconductor generates a magnetic field, precisely aligned with the spin axis. The effect,<br />
the London moment, was put to good use in Gravity Probe B. This experiment measured the magnetic fields of four<br />
superconducting gyroscopes to determine their spin axes. This was critical to the experiment since it is one of the<br />
few ways to accurately determine the spin axis of an otherwise featureless sphere.<br />
Theories of superconductivity<br />
Since the discovery of superconductivity, great efforts have been devoted to finding out how and why it works.<br />
During the 1950s, theoretical condensed matter physicists arrived at a solid understanding of "conventional"<br />
superconductivity, through a pair of remarkable and important theories: the phenomenological Ginzburg-Landau<br />
theory (1950) and the microscopic BCS theory (1957). [10] [11] Generalizations of these theories form the basis for<br />
understanding the closely related phenomenon of superfluidity, because they fall into the Lambda transition<br />
universality class, but the extent to which similar generalizations can be applied to unconventional superconductors<br />
as well is still controversial. The four-dimensional extension of the Ginzburg-Landau theory, the Coleman-Weinberg<br />
model, is important in quantum field theory and cosmology.<br />
London theory<br />
The first phenomenological theory of superconductivity was London theory. It was put forward by the brothers Fritz<br />
and Heinz London in 1935, shortly after the discovery that magnetic fields are expelled from superconductors. A<br />
major triumph of the equations of this theory is their ability to explain the Meissner effect [12] , wherein a material<br />
exponentially expels all internal magnetic fields as it crosses the superconducting threshold. By using the London<br />
equation, one can obtain the dependence of the magnetic field inside the superconductor on the distance to the<br />
surface [13] .<br />
There are two London equations:<br />
The first equation follows from the Newton's second law for superconducting electrons.<br />
History of superconductivity<br />
Superconductivity was discovered on April 8, 1911 by Heike Kamerlingh Onnes, who was studying the resistance of<br />
solid mercury at cryogenic temperatures using the recently-produced liquid helium as a refrigerant. At the<br />
temperature of 4.2 K, he observed that the resistance abruptly disappeared. [14] In the same experiment, he also<br />
observed the superfluid transition of helium at 2.2 K, without recognizing its significance. (The precise date and<br />
circumstances of the discovery were only reconstructed a century later, when Onnes's notebook was found.) [15] In<br />
subsequent decades, superconductivity was observed in several other materials. In 1913, lead was found to<br />
superconduct at 7 K, and in 1941 niobium nitride was found to superconduct at 16 K.<br />
The next important step in understanding superconductivity occurred in 1933, when Meissner and Ochsenfeld<br />
discovered that superconductors expelled applied magnetic fields, a phenomenon which has come to be known as the<br />
Meissner effect. [16] In 1935, F. and H. London showed that the Meissner effect was a consequence of the<br />
minimization of the electromagnetic free energy carried by superconducting current. [17]<br />
In 1950, the phenomenological Ginzburg-Landau theory of superconductivity was devised by Landau and<br />
Ginzburg. [18] This theory, which combined Landau's theory of second-order phase transitions with a<br />
Schrödinger-like wave equation, had great success in explaining the macroscopic properties of superconductors. In<br />
particular, Abrikosov showed that Ginzburg-Landau theory predicts the division of superconductors into the two<br />
categories now referred to as Type I and Type II. Abrikosov and Ginzburg were awarded the 2003 Nobel Prize for
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Superconductivity 6<br />
their work (Landau had received the 1962 Nobel Prize for other work, and died in 1968).<br />
Also in 1950, Maxwell and Reynolds et al. found that the critical temperature of a superconductor depends on the<br />
isotopic mass of the constituent element. [19] [20] This important discovery pointed to the electron-phonon interaction<br />
as the microscopic mechanism responsible for superconductivity.<br />
The complete microscopic theory of superconductivity was finally proposed in 1957 by Bardeen, Cooper and<br />
Schrieffer. [11] Independently, the superconductivity phenomenon was explained by Nikolay Bogolyubov. This BCS<br />
theory explained the superconducting current as a superfluid of Cooper pairs, pairs of electrons interacting through<br />
the exchange of phonons. For this work, the authors were awarded the Nobel Prize in 1972.<br />
The BCS theory was set on a firmer footing in 1958, when Bogolyubov showed that the BCS wavefunction, which<br />
had originally been derived from a variational argument, could be obtained using a canonical transformation of the<br />
electronic Hamiltonian. [21] In 1959, Lev Gor'kov showed that the BCS theory reduced to the Ginzburg-Landau<br />
theory close to the critical temperature. [22]<br />
In 1962, the first commercial superconducting wire, a niobium-titanium alloy, was developed by researchers at<br />
Westinghouse, allowing the construction of the first practical superconducting magnets. In the same year, Josephson<br />
made the important theoretical prediction that a supercurrent can flow between two pieces of superconductor<br />
separated by a thin layer of insulator. [23] This phenomenon, now called the Josephson effect, is exploited by<br />
superconducting devices such as SQUIDs. It is used in the most accurate available measurements of the magnetic<br />
flux quantum , and thus (coupled with the quantum Hall resistivity) for Planck's constant h. Josephson<br />
was awarded the Nobel Prize for this work in 1973.<br />
In 2008, it was discovered that the same mechanism that produces superconductivity could produce a superinsulator<br />
state in some materials, with almost infinite electrical resistance. [24]<br />
High-temperature superconductivity<br />
Until 1986, physicists had believed that BCS theory forbade superconductivity at temperatures above about 30 K. In<br />
that year, Bednorz and Müller discovered superconductivity in a lanthanum-based cuprate perovskite material, which<br />
had a transition temperature of 35 K (Nobel Prize in Physics, 1987). [25] It was soon found that replacing the<br />
lanthanum with yttrium (i.e., making YBCO) raised the critical temperature to 92 K, which was important because<br />
liquid nitrogen could then be used as a refrigerant (the boiling point of nitrogen is 77 K at atmospheric pressure). [26]<br />
This is important commercially because liquid nitrogen can be produced cheaply on-site from air, and is not prone to<br />
some of the problems (for instance solid air plugs) of helium in piping. Many other cuprate superconductors have<br />
since been discovered, and the theory of superconductivity in these materials is one of the major outstanding<br />
challenges of theoretical condensed matter physics. [27]<br />
From about 1993, the highest temperature superconductor was a ceramic material consisting of thallium, mercury,<br />
copper, barium, calcium and oxygen (HgBa 2 Ca 2 Cu 3 O 8+δ ) with T c = 138 K. [28]<br />
In February 2008, an iron-based family of high-temperature superconductors was discovered. [29] [30] Hideo Hosono,<br />
of the Tokyo Institute of Technology, and colleagues found lanthanum oxygen fluorine iron arsenide<br />
(LaO 1-x F x FeAs), an oxypnictide that superconducts below 26 K. Replacing the lanthanum in LaO 1−x F x FeAs with<br />
samarium leads to superconductors that work at 55 K. [31]
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Superconductivity 7<br />
Crystal structure of high-temperature ceramic superconductors<br />
The structure of a high-T c superconductor is closely related to perovskite structure, and the structure of these<br />
compounds has been described as a distorted, oxygen deficient multi-layered perovskite structure. One of the<br />
properties of the crystal structure of oxide superconductors is an alternating multi-layer of CuO 2 planes with<br />
superconductivity taking place between these layers. The more layers of CuO 2 the higher T c . This structure causes a<br />
large anisotropy in normal conducting and superconducting properties, since electrical currents are carried by holes<br />
induced in the oxygen sites of the CuO 2 sheets. The electrical conduction is highly anisotropic, with a much higher<br />
conductivity parallel to the CuO 2 plane than in the perpendicular direction. Generally, Critical temperatures depend<br />
on the chemical compositions, cations substitutions and oxygen content. They can be classified as superstripes; i.e.,<br />
particular realizations of superlattices at atomic limit made of superconducting atomic layers, wires, dots separated<br />
by spacer layers, that gives multiband and multigap superconductivity.<br />
YBaCuO superconductors<br />
The first superconductor found with T c > 77 K (liquid nitrogen boiling<br />
point) is yttrium barium copper oxide (YBa 2 Cu 3 O 7-x ), the proportions<br />
of the 3 different metals in the YBa 2 Cu 3 O 7 superconductor are in the<br />
mole ratio of 1 to 2 to 3 for yttrium to barium to copper respectively.<br />
Thus, this particular superconductor is often referred to as the 123<br />
superconductor.<br />
The unit cell of YBa 2 Cu 3 O 7 consists of three pseudocubic elementary<br />
perovskite unit cells. Each perovskite unit cell contains a Y or Ba atom<br />
at the center: Ba in the bottom unit cell, Y in the middle one, and Ba in<br />
the top unit cell. Thus, Y and Ba are stacked in the sequence<br />
[Ba–Y–Ba] along the c-axis. All corner sites of the unit cell are<br />
occupied by Cu, which has two different coordinations, Cu(1) and<br />
Cu(2), with respect to oxygen. There are four possible crystallographic<br />
sites for oxygen: O(1), O(2), O(3) and O(4). [32] The coordination<br />
polyhedra of Y and Ba with respect to oxygen are different. The<br />
tripling of the perovskite unit cell leads to nine oxygen atoms, whereas<br />
YBa 2 Cu 3 O 7 has seven oxygen atoms and, therefore, is referred to as an<br />
oxygen-deficient perovskite structure. The structure has a stacking of<br />
YBCO unit cell<br />
different layers: (CuO)(BaO)(CuO 2 )(Y)(CuO 2 )(BaO)(CuO). One of the key feature of the unit cell of YBa 2 Cu 3 O 7-x<br />
(YBCO) is the presence of two layers of CuO 2 . The role of the Y plane is to serve as a spacer between two CuO 2<br />
planes. In YBCO, the Cu–O chains are known to play an important role for superconductivity. T c is maximal near 92<br />
K when x ≈ 0.15 and the structure is orthorhombic. Superconductivity disappears at x ≈ 0.6, where the structural<br />
transformation of YBCO occurs from orthorhombic to tetragonal. [33]
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Superconductivity 8<br />
Bi-, Tl- and Hg-based high-T c superconductors<br />
The crystal structure of Bi-, Tl- and Hg-based high-T c superconductors are very similar. Like YBCO, the<br />
perovskite-type feature and the presence of CuO 2 layers also exist in these superconductors. However, unlike YBCO,<br />
Cu–O chains are not present in these superconductors. The YBCO superconductor has an orthorhombic structure,<br />
whereas the other high-T c superconductors have a tetragonal structure.<br />
The Bi–Sr–Ca–Cu–O system has three superconducting phases forming a homologous series as<br />
Bi 2 Sr 2 Ca n−1 Cu n O 4+2n+x (n = 1, 2 and 3). These three phases are Bi-2201, Bi-2212 and Bi-2223, having transition<br />
temperatures of 20, 85 and 110 K, respectively, where the numbering system represent number of atoms for Bi, Sr,<br />
Ca and Cu respectively. [34] The two phases have a tetragonal structure which consists of two sheared<br />
crystallographic unit cells. The unit cell of these phases has double Bi–O planes which are stacked in a way that the<br />
Bi atom of one plane sits below the oxygen atom of the next consecutive plane. The Ca atom forms a layer within the<br />
interior of the CuO 2 layers in both Bi-2212 and Bi-2223; there is no Ca layer in the Bi-2201 phase. The three phases<br />
differ with each other in the number of CuO 2 planes; Bi-2201, Bi-2212 and Bi-2223 phases have one, two and three<br />
CuO 2 planes, respectively. The c axis of these phases increases with the number of CuO 2 planes (see table below).<br />
The coordination of the Cu atom is different in the three phases. The Cu atom forms an octahedral coordination with<br />
respect to oxygen atoms in the 2201 phase, whereas in 2212, the Cu atom is surrounded by five oxygen atoms in a<br />
pyramidal arrangement. In the 2223 structure, Cu has two coordinations with respect to oxygen: one Cu atom is<br />
bonded with four oxygen atoms in square planar configuration and another Cu atom is coordinated with five oxygen<br />
atoms in a pyramidal arrangement. [35]<br />
Tl–Ba–Ca–Cu–O superconductor: The first series of the Tl-based superconductor containing one Tl–O layer has<br />
the general formula TlBa 2 Ca n-1 Cu n O 2n+3 , [36] whereas the second series containing two Tl–O layers has a formula of<br />
Tl 2 Ba 2 Ca n-1 Cu n O 2n+4 with n = 1, 2 and 3. In the structure of Tl 2 Ba 2 CuO 6 (Tl-2201), there is one CuO 2 layer with<br />
the stacking sequence (Tl–O) (Tl–O) (Ba–O) (Cu–O) (Ba–O) (Tl–O) (Tl–O). In Tl 2 Ba 2 CaCu 2 O 8 (Tl-2212), there<br />
are two Cu–O layers with a Ca layer in between. Similar to the Tl 2 Ba 2 CuO 6 structure, Tl–O layers are present<br />
outside the Ba–O layers. In Tl 2 Ba 2 Ca 2 Cu 3 O 10 (Tl-2223), there are three CuO2 layers enclosing Ca layers between<br />
each of these. In Tl-based superconductors, T c is found to increase with the increase in CuO 2 layers. However, the<br />
value of T c decreases after four CuO 2 layers in TlBa 2 Ca n-1 Cu n O 2n+3 , and in the Tl 2 Ba 2 Ca n-1 Cu n O 2n+4 compound, it<br />
decreases after three CuO 2 layers. [37]<br />
Hg–Ba–Ca–Cu–O superconductor: The crystal structure of HgBa 2 CuO 4 (Hg-1201), [38] HgBa 2 CaCu 2 O 6<br />
(Hg-1212) and HgBa 2 Ca 2 Cu 3 O 8 (Hg-1223) is similar to that of Tl-1201, Tl-1212 and Tl-1223, with Hg in place<br />
of Tl. It is noteworthy that the T c of the Hg compound (Hg-1201) containing one CuO 2 layer is much larger as<br />
compared to the one-CuO 2 -layer compound of thallium (Tl-1201). In the Hg-based superconductor, T c is also found<br />
to increase as the CuO 2 layer increases. For Hg-1201, Hg-1212 and Hg-1223, the values of T c are 94, 128 and 134 K<br />
respectively, as shown in table below. The observation that the T c of Hg-1223 increases to 153 K under high pressure<br />
indicates that the T c of this compound is very sensitive to the structure of the compound. [39]
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Superconductivity 9<br />
Critical temperature (T c ), crystal structure and lattice constants of some high-T c<br />
superconductors<br />
Formula Notation T c (K) No. of Cu-O<br />
YBa 2 Cu 3 O 7<br />
Bi 2 Sr 2 CuO 6<br />
Bi 2 Sr 2 CaCu 2 O 8<br />
Bi 2 Sr 2 Ca 2 Cu 3 O 6<br />
Tl 2 Ba 2 CuO 6<br />
Tl 2 Ba 2 CaCu 2 O 8<br />
Tl 2 Ba 2 Ca 2 Cu 3 O 10<br />
TlBa 2 Ca 3 Cu 4 O 11<br />
HgBa 2 CuO 4<br />
HgBa 2 CaCu 2 O 6<br />
Preparation of high-T c superconductors<br />
planes<br />
in unit cell<br />
Crystal structure<br />
123 92 2 Orthorhombic<br />
Bi-2201 20 1 Tetragonal<br />
Bi-2212 85 2 Tetragonal<br />
Bi-2223 110 3 Tetragonal<br />
Tl-2201 80 1 Tetragonal<br />
Tl-2212 108 2 Tetragonal<br />
Tl-2223 125 3 Tetragonal<br />
Tl-1234 122 4 Tetragonal<br />
Hg-1201 94 1 Tetragonal<br />
Hg-1212 128 2 Tetragonal<br />
HgBa 2 Ca 2 Cu 3 O 8 Hg-1223 134 3 Tetragonal<br />
The simplest method for preparing high-T c superconductors is a<br />
solid-state thermochemical reaction involving mixing, calcination and<br />
sintering. The appropriate amounts of precursor powders, usually<br />
oxides and carbonates, are mixed thoroughly using a ball mill. Solution<br />
chemistry processes such as coprecipitation, freeze-drying and sol-gel<br />
methods are alternative ways for preparing a homogenous mixture.<br />
These powders are calcined in the temperature range from 800 °C to<br />
950 °C for several hours. The powders are cooled, reground and<br />
calcined again. This process is repeated several times to get<br />
homogenous material. The powders are subsequently compacted to<br />
Superconductor timeline<br />
pellets and sintered. The sintering environment such as temperature, annealing time, atmosphere and cooling rate<br />
play a very important role in getting good high-T c superconducting materials. The YBa 2 Cu 3 O 7-x compound is<br />
prepared by calcination and sintering of a homogenous mixture of Y 2 O 3 , BaCO 3 and CuO in the appropriate atomic<br />
ratio. Calcination is done at 900–950 °C, whereas sintering is done at 950 °C in an oxygen atmosphere. The oxygen<br />
stoichiometry in this material is very crucial for obtaining a superconducting YBa 2 Cu 3 O 7−x compound. At the time<br />
of sintering, the semiconducting tetragonal YBa 2 Cu 3 O 6 compound is formed, which, on slow cooling in oxygen<br />
atmosphere, turns into superconducting YBa 2 Cu 3 O 7−x . The uptake and loss of oxygen are reversible in<br />
YBa 2 Cu 3 O 7−x . A fully oxidized orthorhombic YBa 2 Cu 3 O 7−x sample can be transformed into tetragonal YBa 2 Cu 3 O 6<br />
by heating in a vacuum at temperature above 700 °C. [33]<br />
The preparation of Bi-, Tl- and Hg-based high-T c superconductors is difficult compared to YBCO. Problems in these<br />
superconductors arise because of the existence of three or more phases having a similar layered structure. Thus,<br />
syntactic intergrowth and defects such as stacking faults occur during synthesis and it becomes difficult to isolate a<br />
single superconducting phase. For Bi–Sr–Ca–Cu–O, it is relatively simple to prepare the Bi-2212 (T c ≈ 85 K) phase,<br />
whereas it is very difficult to prepare a single phase of Bi-2223 (T c ≈ 110 K). The Bi-2212 phase appears only after<br />
few hours of sintering at 860–870 °C, but the larger fraction of the Bi-2223 phase is formed after a long reaction
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Superconductivity 10<br />
time of more than a week at 870 °C. [35] Although the substitution of Pb in the Bi–Sr–Ca–Cu–O compound has been<br />
found to promote the growth of the high-T c phase, [40] a long sintering time is still required.<br />
Possible superconductivity of the vacuum<br />
Maxim Chernodub of the French National Centre for Scientific Research has postulated that the vacuum can become<br />
a superconductor in magnetic fields of 10 16 Tesla or more, [41] at temperatures of at least a billion, [42] perhaps billions<br />
of degrees. [43]<br />
Applications<br />
Superconducting magnets are some of the most powerful electromagnets known. They are used in MRI/NMR<br />
machines, mass spectrometers, and the beam-steering magnets used in particle accelerators. They can also be used<br />
for magnetic separation, where weakly magnetic particles are extracted from a background of less or non-magnetic<br />
particles, as in the pigment industries.<br />
In the 1950s and 1960s, superconductors were used to build experimental digital computers using cryotron switches.<br />
More recently, superconductors have been used to make digital circuits based on rapid single flux quantum<br />
technology and RF and microwave filters for mobile phone base stations.<br />
Superconductors are used to build Josephson junctions which are the building blocks of SQUIDs (superconducting<br />
quantum interference devices), the most sensitive magnetometers known. SQUIDs are used in scanning SQUID<br />
microscopes and magnetoencephalography. Series of Josephson devices are used to realize the SI volt. Depending on<br />
the particular mode of operation, a superconductor-insulator-superconductor Josephson junction can be used as a<br />
photon detector or as a mixer. The large resistance change at the transition from the normal- to the superconducting<br />
state is used to build thermometers in cryogenic micro-calorimeter photon detectors. The same effect is used in<br />
ultrasensitive bolometers made from superconducting materials.<br />
Other early markets are arising where the relative efficiency, size and weight advantages of devices based on<br />
high-temperature superconductivity outweigh the additional costs involved.<br />
Promising future applications include high-performance smart grid, electric power transmission, transformers, power<br />
storage devices, electric motors (e.g. for vehicle propulsion, as in vactrains or maglev trains), magnetic levitation<br />
devices, fault current limiters, nanoscopic materials such as buckyballs, nanotubes, composite materials and<br />
superconducting magnetic refrigeration. However, superconductivity is sensitive to moving magnetic fields so<br />
applications that use alternating current (e.g. transformers) will be more difficult to develop than those that rely upon<br />
direct current.<br />
Nobel Prize for Superconductivity<br />
1913 Heike Kamerlingh Onnes on Matter at low temperature<br />
1972 John Bardeen, Leon N. Cooper, J. Robert Schrieffer on Theory of superconductivity<br />
1973 Leo Esaki, Ivar Giaever, Brian D. Josephson on Tunneling in superconductors<br />
1987 Georg Bednorz, Alex K. Müller on High-temperature superconductivity<br />
2003 Alexei A. Abrikosov, Vitaly L. Ginzburg, Anthony J. Leggett on Pioneering contributions to the theory of<br />
superconductors and superfluids. [44]
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Superconductivity 11<br />
References<br />
[1] John C. Gallop (1990). SQUIDS, the Josephson Effects and Superconducting Electronics (http:/ / books. google. com/ ?id=ad8_JsfCdKQC&<br />
printsec=frontcover). CRC Press. pp. 3, 20. ISBN 0750300515. .<br />
[2] Jun Nagamatsu, Norimasa Nakagawa, Takahiro Muranaka, Yuji Zenitani and Jun Akimitsu (2001). "Superconductivity at 39 K in magnesium<br />
diboride". Nature 410 (6824): 63. Bibcode 2001Natur.410...63N. doi:10.1038/35065039. PMID 11242039.<br />
[3] Paul Preuss (14 August 2002). "A most unusual superconductor and how it works: first-principles calculation explains the strange behavior of<br />
magnesium diboride" (http:/ / www. lbl. gov/ Science-Articles/ Archive/ MSD-superconductor-Cohen-Louie. html). Research News<br />
(Lawrence Berkeley National Laboratory). . Retrieved 2009-10-28.<br />
[4] Hamish Johnston (17 February 2009). "Type-1.5 superconductor shows its stripes" (http:/ / physicsworld. com/ cws/ article/ news/ 37806).<br />
Physics World (Institute of Physics). . Retrieved 2009-10-28.<br />
[5] R. L. Dolecek (1954). "Adiabatic Magnetization of a Superconducting Sphere". Physical Review 96 (1): 25–28.<br />
Bibcode 1954PhRv...96...25D. doi:10.1103/PhysRev.96.25.<br />
[6] H. Kleinert (1982). "Disorder Version of the Abelian Higgs Model and the Order of the Superconductive Phase Transition" (http:/ / www.<br />
physik. fu-berlin. de/ ~kleinert/ 97/ 97. pdf). Lettere al Nuovo Cimento 35 (13): 405–412. doi:10.1007/BF02754760. .<br />
[7] J. Hove, S. Mo, A. Sudbo (2002). "Vortex interactions and thermally induced crossover from type-I to type-II superconductivity" (http:/ /<br />
www. physik. fu-berlin. de/ ~kleinert/ papers/ sudbotre064524. pdf). Physical Review B 66 (6): 064524. arXiv:cond-mat/0202215.<br />
Bibcode 2002PhRvB..66f4524H. doi:10.1103/PhysRevB.66.064524. .<br />
[8] Lev D. Landau, Evgeny M. Lifschitz (1984). Electrodynamics of Continuous Media. Course of Theoretical Physics. 8. Oxford:<br />
Butterworth-Heinemann. ISBN 0-7506-2634-8.<br />
[9] David J. E. Callaway (1990). "On the remarkable structure of the superconducting intermediate state". Nuclear Physics B 344 (3): 627–645.<br />
Bibcode 1990NuPhB.344..627C. doi:10.1016/0550-3213(90)90672-Z.<br />
[10] J. Bardeen, L. N. Cooper and J. R. Schrieffer (1957). "Microscopic Theory of Superconductivity". Physical Review 106 (1): 162–164.<br />
Bibcode 1957PhRv..106..162B. doi:10.1103/PhysRev.106.162.<br />
[11] J. Bardeen, L. N. Cooper and J. R. Schrieffer (1957). "Theory of Superconductivity". Physical Review 108 (5): 1175–1205.<br />
Bibcode 1957PhRv..108.1175B. doi:10.1103/PhysRev.108.1175.<br />
[12] Meissner, W.; R. Ochsenfeld (1933). "Ein neuer Effekt bei Eintritt der Supraleitfähigkeit". Naturwissenschaften 21 (44): 787.<br />
Bibcode 1933NW.....21..787M. doi:10.1007/BF01504252.<br />
[13] "The London equations" (http:/ / openlearn. open. ac. uk/ mod/ oucontent/ view. php?id=398540& section=3. 3). The Open University. .<br />
Retrieved 2011-10-16.<br />
[14] H. K. Onnes (1911). "The resistance of pure mercury at helium temperatures". Commun. Phys. Lab. Univ. Leiden 12: 120.<br />
[15] The Discovery of Superconductivity (http:/ / ilorentz. org/ history/ cold/ DelftKes_HKO_PT. pdf)<br />
[16] W. Meissner and R. Ochsenfeld (1933). "Ein neuer Effekt bei Eintritt der Supraleitfähigkeit". Naturwissenschaften 21 (44): 787–788.<br />
Bibcode 1933NW.....21..787M. doi:10.1007/BF01504252.<br />
[17] F. London and H. London (1935). "The Electromagnetic Equations of the Supraconductor". Proceedings of the Royal Society of London A<br />
149 (866): 71–88. Bibcode 1935RSPSA.149...71L. doi:10.1098/rspa.1935.0048. JSTOR 96265.<br />
[18] V. L. Ginzburg and L.D. Landau (1950). "On the theory of superconductivity". Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki 20: 1064.<br />
[19] E. Maxwell (1950). "Isotope Effect in the Superconductivity of Mercury". Physical Review 78 (4): 477. Bibcode 1950PhRv...78..477M.<br />
doi:10.1103/PhysRev.78.477.<br />
[20] C. A. Reynolds, B. Serin, W. H. Wright and L. B. Nesbitt (1950). "Superconductivity of Isotopes of Mercury". Physical Review 78 (4): 487.<br />
Bibcode 1950PhRv...78..487R. doi:10.1103/PhysRev.78.487.<br />
[21] N. N. Bogoliubov (1958). "A new method in the theory of superconductivity". Zhurnal Eksperimental'noi i Teoreticheskoi Fiziki 34: 58.<br />
[22] L. P. Gor'kov (1959). "Microscopic derivation of the Ginzburg--Landau equations in the theory of superconductivity". Zhurnal<br />
Eksperimental'noi i Teoreticheskoi Fiziki 36: 1364.<br />
[23] B. D. Josephson (1962). "Possible new effects in superconductive tunnelling". Physics Letters 1 (7): 251–253. Bibcode 1962PhL.....1..251J.<br />
doi:10.1016/0031-9163(62)91369-0.<br />
[24] "Newly discovered fundamental state of matter, a superinsulator, has been created." (http:/ / www. sciencedaily. com/ releases/ 2008/ 04/<br />
080408160614. htm). Science Daily. April 9, 2008. . Retrieved 2008-10-23.<br />
[25] J. G. Bednorz and K. A. Mueller (1986). "Possible high T C superconductivity in the Ba-La-Cu-O system". Zeitschrift für Physik B 64 (2):<br />
189–193. Bibcode 1986ZPhyB..64..189B. doi:10.1007/BF01303701.<br />
[26] M. K. Wu et al. (1987). "Superconductivity at 93 K in a New Mixed-Phase Y-Ba-Cu-O Compound System at Ambient Pressure". Physical<br />
Review Letters 58 (9): 908–910. Bibcode 1987PhRvL..58..908W. doi:10.1103/PhysRevLett.58.908. PMID 10035069.<br />
[27] Alexei A. Abrikosov (8 December 2003). "type II Superconductors and the Vortex Lattice" (http:/ / nobelprize. org/ nobel_prizes/ physics/<br />
laureates/ 2003/ abrikosov-lecture. html). Nobel Lecture. .<br />
[28] P. Dai, B. C. Chakoumakos, G. F. Sun, K. W. Wong, Y. Xin and D. F. Lu (1995). "Synthesis and neutron powder diffraction study of the<br />
superconductor HgBa 2 Ca 2 Cu 3 O 8+δ by Tl substitution". Physica C 243 (3–4): 201–206. Bibcode 1995PhyC..243..201D.<br />
doi:10.1016/0921-4534(94)02461-8.<br />
[29] Hiroki Takahashi, Kazumi Igawa, Kazunobu Arii, Yoichi Kamihara, Masahiro Hirano, Hideo Hosono (2008). "Superconductivity at 43 K in<br />
an iron-based layered compound LaO 1−x F x FeAs". Nature 453 (7193): 376–378. Bibcode 2008Natur.453..376T. doi:10.1038/nature06972.
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PMID 18432191.<br />
[30] Adrian Cho. "Second Family of High-Temperature Superconductors Discovered" (http:/ / sciencenow. sciencemag. org/ cgi/ content/ full/<br />
2008/ 417/ 1). ScienceNOW Daily News. .<br />
[31] Zhi-An Ren et al. (2008). "Superconductivity and phase diagram in iron-based arsenic-oxides ReFeAsO1-d (Re = rare-earth metal) without<br />
fluorine doping". EPL 83: 17002. Bibcode 2008EL.....8317002R. doi:10.1209/0295-5075/83/17002.<br />
[32] R. Hazen et al. (1987). "Crystallographic description of phases in the Y-Ba-Cu-O superconductor". Physical Review B 35 (13): 7238.<br />
Bibcode 1987PhRvB..35.7238H. doi:10.1103/PhysRevB.35.7238.<br />
[33] Neeraj Khare (2003-05-01). Handbook of High-Temperature Superconductor Electronics (http:/ / books. google. com/<br />
books?id=is-L_R2H3IAC). ISBN 0-8247-0823-7. .<br />
[34] R. Hazen et al. (1988). "Superconductivity in the high-T c Bi-Ca-Sr-Cu-O system: Phase identification". Physical Review Letters 60 (12):<br />
1174. Bibcode 1988PhRvL..60.1174H. doi:10.1103/PhysRevLett.60.1174.<br />
[35] J. Tarascon et al. (1988). "Preparation, structure, and properties of the superconducting compound series Bi 2 Sr 2 Ca n−1 Cu n O y with n = 1, 2,<br />
and 3". Physical Review B 38 (13): 8885. Bibcode 1988PhRvB..38.8885T. doi:10.1103/PhysRevB.38.8885.<br />
[36] Z. Sheng et al. (1988). "Superconductivity at 90 K in the Tl-Ba-Cu-O system". Physical Review Letters 60 (10): 937–940.<br />
Bibcode 1988PhRvL..60..937S. doi:10.1103/PhysRevLett.60.937. PMID 10037895.<br />
[37] Z.Z. Sheng, A. M. Hermann, Z. Z.; Hermann, A. M. (1988). "Superconductivity in the rare-earth-free Tl-Ba-Cu-O system above<br />
liquid-nitrogen temperature". Nature 332 (6159): 55. Bibcode 1988Natur.332...55S. doi:10.1038/332055a0.<br />
[38] S. N. Putilin et al. (1993). "Superconductivity at 94 K in HgBa2Cu04+δ". Nature 362 (6417): 226. Bibcode 1993Natur.362..226P.<br />
doi:10.1038/362226a0.<br />
[39] C. W. Chu et al. (1993). "Superconductivity above 150 K in HgBa2Ca2Cu3O8+δ at high pressures". Nature 365 (6444): 323.<br />
Bibcode 1993Natur.365..323C. doi:10.1038/365323a0.<br />
[40] D. Shi et al. (1989). "Origin of enhanced growth of the 110 K superconducting phase by Pb doping in the Bi-Sr-Ca-Cu-O system". Applied<br />
Physics Letters 55 (7): 699. Bibcode 1989ApPhL..55..699S. doi:10.1063/1.101573.<br />
[41] Maggie McKee: How to turn the vacuum into a superconductor (http:/ / webcache. googleusercontent. com/<br />
search?q=cache:yuuQSPuvjdAJ:www. newscientist. com/ article/ mg21028073. 800-how-to-turn-the-vacuum-into-a-superconductor. html+<br />
"maxim+ chernodub"+ "new+ scientist"& cd=4& hl=en& ct=clnk& gl=uk& source=www. google. co. uk). New Scientist, April 8, 2011,<br />
retrieved May 13, 2011<br />
[42] Alasdair Wilkins: Ultra-hot superconductors could spontaneously form in the vacuum of space (http:/ / io9. com/ 5787141/ ultra+<br />
hot-superconductors-could-spontaneously-form-in-the-vacuum-of-space). io9, March 30, 2011, retrieved May 13, 2011<br />
[43] Jon Cartwright: Superconductivity from nowhere (http:/ / physicsworld. com/ cws/ article/ news/ 45558). Physicworld.com, March 29, 2011,<br />
retrieved May 13, 2011<br />
[44] The Nobel Prize for Physics, 1901–2008 [=http:/ / math. ucr. edu/ home/ baez/ physics/ Administrivia/ nobel. html "The Nobel Prize for<br />
Physics,1901-2008"]. =.<br />
Further reading<br />
• Hagen Kleinert (1989). "Superflow and Vortex Lines" (http:/ / www. physik. fu-berlin. de/ ~kleinert/<br />
kleiner_reb1/ contents1. html). Gauge Fields in Condensed Matter. 1. World Scientific. ISBN 9971-5-0210-0.<br />
• Anatoly Larkin; Andrei Varlamov (2005). Theory of Fluctuations in Superconductors. Oxford University Press.<br />
ISBN 0198528159.<br />
• A. G. Lebed (2008). The Physics of Organic Superconductors and Conductors. 110 (1rst ed.). Springer.<br />
ISBN 978-3-540-76667-4.<br />
• Jean Matricon, Georges Waysand, Charles Glashausser (2003). The Cold Wars: A History of Superconductivity.<br />
Rutgers University Press. ISBN 0813532957.<br />
• "Physicist Discovers Exotic Superconductivity" (http:/ / www. sciencedaily. com/ releases/ 2006/ 08/<br />
060817101658. htm). ScienceDaily. 17 August 2006.<br />
• Michael Tinkham (2004). Introduction to Superconductivity (2nd ed.). Dover <strong>Book</strong>s. ISBN 0-486-43503-2.<br />
• Terry Orlando, Kevin Delin (1991). Foundations of Applied Superconductivity. Prentice Hall.<br />
ISBN 978-0-2011-8323-8.<br />
• Paul Tipler, Ralph Llewellyn (2002). Modern Physics (4th ed.). W. H. <strong>Free</strong>man. ISBN 0-7167-4345-0.
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Superconductivity 13<br />
External links<br />
• Everything about superconductivity: properties, research, applications with videos, animations, games (http:/ /<br />
www. superconductivity. eu)<br />
• Video about Type I Superconductors: R=0/transition temperatures/ B is a state variable/ Meissner effect/ Energy<br />
gap(Giaever)/ BCS model (http:/ / alfredleitner. com)<br />
• Superconductivity: Current in a Cape and Thermal Tights. An introduction to the topic for non-scientists (http:/ /<br />
www. magnet. fsu. edu/ education/ tutorials/ magnetacademy/ superconductivity101/ ) National High Magnetic<br />
Field Laboratory<br />
• Introduction to superconductivity (http:/ / www. ornl. gov/ reports/ m/ ornlm3063r1/ pt1. html)<br />
• Lectures on Superconductivity (series of videos, including interviews with leading experts) (http:/ / www. msm.<br />
cam. ac. uk/ ascg/ lectures/ )<br />
• Superconducting Niobium Cavities (http:/ / www. sns. gov/ partnerlabs/ jlab. shtml)<br />
• Superconductivity in everyday life : Interactive exhibition (http:/ / www. superlife. info)<br />
• Videos for various types of superconducting levitations including trains and hoolahoops – also videos of Ohm's<br />
law in a superconductor (http:/ / h0. web. u-psud. fr/ supraconductivite/ vulgaFilms. html)<br />
• Video of the Meissner effect from the NJIT Mathclub (http:/ / web. njit. edu/ ~mathclub/ superconductor/ index.<br />
html)<br />
• Superconductivity News Update (http:/ / www. superconductivitynewsupdate. com)<br />
• Superconductor Week Newsletter – industry news, links, et cetera (http:/ / www. superconductorweek. com)<br />
• Superconducting Magnetic Levitation (http:/ / www. maniacworld. com/ Superconducting-Magnetic-Levitation.<br />
html)<br />
• National Superconducting Cyclotron Laboratory at Michigan State University (http:/ / www. nscl. msu. edu)<br />
• High Temperature Superconducting and Cryogenics in RF applications (http:/ / www. suptech. com/<br />
hts_crfe_tech. htm)<br />
• CERN Superconductors Database (http:/ / sdb-server. cern. ch/ mediawiki/ index. php/ Main_Page)<br />
• Magnetisation of High Temperature superconductors by the flux pumping method (http:/ / www. fluxpump. co.<br />
uk/ default. aspx)<br />
• YouTube Video Levitating magnet (http:/ / youtube. com/ watch?v=indyz6O-Xyw& feature=user)<br />
• Isotope effect in superconductivity (http:/ / www. physics. csulb. edu/ ~abill/ isotope. html)<br />
• International Workshop on superconductivity in Diamond and Related Materials (free download papers) (http:/ /<br />
www. iop. org/ EJ/ toc/ 1468-6996/ 9/ 4)<br />
• New Diamond and Frontier Carbon Technology Volume 17, No.1 Special Issue on Superconductivity in CVD<br />
Diamond (http:/ / www. nims. go. jp/ NFM/ NDFCT17/ NDFCT17. html)<br />
• DoITPoMS Teaching and Learning Package – "Superconductivity" (http:/ / www. doitpoms. ac. uk/ tlplib/<br />
superconductivity/ index. php)<br />
• The Nobel Prize for Physics, 1901–2008 (http:/ / math. ucr. edu/ home/ baez/ physics/ Administrivia/ nobel. html)
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Type-I superconductor 14<br />
Type-I superconductor<br />
Superconductors cannot be penetrated by magnetic flux lines (Meissner–Ochsenfeld effect). This Meissner state<br />
breaks down when the applied magnetic field is too large. Superconductors can be divided into two classes according<br />
to how this breakdown occurs. In Type-I superconductors, superconductivity is abruptly destroyed via a first order<br />
phase transition when the strength of the applied field rises above a critical value H c . As such, they have only a<br />
single critical magnetic field at which the material ceases to superconduct, becoming resistive. Depending on the<br />
geometry of the sample, one may obtain an intermediate state described first by Lev Landau [1] consisting of a<br />
baroque pattern [2] of macroscopically large regions of normal material carrying a magnetic field mixed with regions<br />
of superconducting material containing no field. Elementary superconductors, such as aluminium and lead are<br />
typical Type-I superconductors. The origin of their superconductivity is explained by BCS theory. This type of<br />
superconductivity is normally exhibited by pure metals, e.g. aluminium, lead or mercury.<br />
References<br />
[1] L.D. Landau (1984). Electrodynamics of Continuous Media. Course of Theoretical Physics. Vol. 8. Butterworth-Heinemann.<br />
ISBN 0-7506-2634-8.<br />
[2] D.J.E. Callaway (1990). "On the remarkable structure of the superconducting intermediate state". Nuclear Physics B 344: 627–645.<br />
Bibcode 1990NuPhB.344..627C. doi:10.1016/0550-3213(90)90672-Z.
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Yttrium barium copper oxide 15<br />
Yttrium barium copper oxide<br />
CAS number<br />
Yttrium barium copper oxide<br />
Identifiers<br />
Properties<br />
107539-20-8 [1]<br />
Molecular formula YBa 2 Cu 3 O 7<br />
Molar mass 666.19<br />
Appearance Black solid<br />
Density<br />
3[2] [3]<br />
6.3 g/cm<br />
Melting point >1000 °C<br />
Solubility in water Insoluble<br />
Structure<br />
Crystal structure Based on the perovskite structure.<br />
Coordination<br />
geometry<br />
Hazards<br />
Orthorhombic<br />
EU classification Irritant (Xi)<br />
Related high-T c<br />
superconductors<br />
Related compounds<br />
BaLaO 3-x<br />
Related compounds Yttrium(III) oxide<br />
Barium oxide<br />
Copper(II) oxide<br />
(verify) [4] (what is: / ?)<br />
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)<br />
Infobox references<br />
Yttrium barium copper oxide, often abbreviated YBCO, is a crystalline chemical compound with the formula<br />
YBa 2 Cu 3 O 7 . This material, a famous "high-temperature superconductor", achieved prominence because it was the<br />
first material to achieve superconductivity above the boiling point (77 K) of liquid nitrogen.<br />
History<br />
In April 1986 (seventy-five years after the discovery of superconductivity in 1911), Georg Bednorz and Karl Müller,<br />
working at IBM in Zurich, discovered that certain semiconducting oxides became superconducting at 35 K, then<br />
considered a relatively high temperature. In particular, the lanthanum barium copper oxides, an oxygen deficient<br />
perovskite-related material, proved promising. In 1987, Bednorz and Müller were jointly awarded the Nobel Prize in<br />
Physics for this work.
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Yttrium barium copper oxide 16<br />
Building on that, Maw-Kuen Wu and his graduate students, Ashburn and Torng [5] at the University of Alabama in<br />
Huntsville in 1987, and Paul Chu and his students at the University of Houston in 1987 (see superconductor page for<br />
info), discovered YBCO has a T c of 93 K. (The first samples were Y 1.2 Ba 0.8 CuO 4 .) Their work led to a rapid<br />
succession of new high temperature superconducting materials, ushering in a new era in material science and<br />
chemistry.<br />
YBCO was the first material to become superconducting above 77 K, the boiling point of liquid nitrogen. All<br />
materials developed before 1986 became superconducting only at temperatures near the boiling points of liquid<br />
helium (T b = 4.2 K) or liquid hydrogen (T b = 20.28 K) — the highest being Nb 3 Ge at 23 K. The significance of the<br />
discovery of YBCO is the much lower cost of the refrigerant used to cool the material to below the critical<br />
temperature.<br />
Synthesis<br />
Relatively pure YBCO was first synthesized by heating a mixture of the metal carbonates at temperatures between<br />
[6] [7]<br />
1000 to 1300 K.<br />
4 BaCO 3 + Y 2 (CO 3 ) 3 + 6 CuCO 3 + (1/2−x) O 2 → 2 YBa 2 Cu 3 O 7−x + 13 CO 2<br />
Modern syntheses of YBCO use the corresponding oxides and nitrates. [7]<br />
The superconducting properties of YBa 2 Cu 3 O 7−x are sensitive to the value of x, its oxygen content. Only those<br />
materials with 0 ≤ x ≤ 0.65 are superconducting below T c , and when x ~ 0.07 the material superconducts at the<br />
highest temperature of 95 K, [7] or in highest magnetic fields: 120 T for B perpendicular and 250 T for B parallel to<br />
the CuO 2 planes. [8]<br />
In addition to being sensitive to the stoichiometry of oxygen, the properties of YBCO are influenced by the<br />
crystallization methods used. Care must be taken to sinter YBCO. YBCO is a crystalline material, and the best<br />
superconductive properties are obtained when crystal grain boundaries are aligned by careful control of annealing<br />
and quenching temperature rates.<br />
Numerous other methods to synthesize YBCO have developed since its discovery by Wu and his coworkers, such as<br />
chemical vapor deposition (CVD), [6] [7] sol-gel, [9] and aerosol [10] methods. These alternative methods, however, still<br />
require careful sintering to produce a quality product.<br />
However, new possibilities have been opened since the discovery that trifluoroacetic acid (TFA), a source of<br />
fluorine, prevents the formation of the undesired barium carbonate (BaCO 3 ). Routes such as CSD (chemical solution<br />
deposition) have opened a wide range of possibilities, particularly in the preparation of long length YBCO tapes. [11]<br />
This route lowers the temperature necessary to get the correct phase to around 700 °C. This, and the lack of<br />
dependence on vacuum, makes this method a very promising way to get scalable YBCO tapes.
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Yttrium barium copper oxide 17<br />
Structure<br />
YBCO crystallises in a defect perovskite structure<br />
consisting of layers. The boundary of each layer is<br />
defined by planes of square planar CuO 4 units<br />
sharing 4 vertices. The planes can some times be<br />
slightly puckered. [6] Perpendicular to these CuO 2<br />
planes are CuO 4 ribbons sharing 2 vertices. The<br />
yttrium atoms are found between the CuO 2 planes,<br />
while the barium atoms are found between the CuO 4<br />
ribbons and the CuO 2 planes. This structural feature<br />
is illustrated in the figure to the right.<br />
More details<br />
Although YBa 2 Cu 3 O 7 is a well-defined chemical<br />
compound with a specific structure and<br />
stoichiometry, materials with less than seven oxygen<br />
atoms per formula unit are non-stoichiometric<br />
compounds. The structure of these materials depends<br />
on the oxygen content. This non-stoichiometry is<br />
denoted by the YBa Cu O in the chemical<br />
2 3 7-x<br />
formula. When x = 1, the O(1) sites in the Cu(1) layer<br />
are vacant and the structure is tetragonal. The<br />
tetragonal form of YBCO is insulating and does not<br />
superconduct. Increasing the oxygen content slightly<br />
causes more of the O(1) sites to become occupied. For x < 0.65, Cu-O chains along the b axis of the crystal are<br />
formed. Elongation of the b axis changes the structure to orthorhombic, with lattice parameters of a = 3.82, b = 3.89,<br />
and c = 11.68 Å. Optimum superconducting properties occur when x ~ 0.07, i.e., almost all of the O(1) sites are<br />
occupied, with few vacancies.<br />
In experiments where other elements are substituted at the Cu and Ba sites evidence has shown that conduction<br />
occurs in the Cu(2)O planes while the Cu(1)O(1) chains act as charge reservoirs, which provide carriers to the CuO<br />
planes. However, this model fails to address superconductivity in the homologue Pr123 (praseodymium instead of<br />
yttrium). [12] This (conduction in the copper planes) confines conductivity to the a-b planes and a large anisotropy in<br />
transport properties is observed. Along the c axis, normal conductivity is 10 times smaller than in the a-b plane. For<br />
other cuprates in the same general class, the anisotropy is even greater and inter-plane transport is highly restricted.<br />
Furthermore, the superconducting length scales show similar anisotropy, in both penetration depth (λ ab ≈ 150 nm, λ c<br />
≈ 800 nm) and coherence length, (ξ ab ≈ 2 nm, ξ c ≈ 0.4 nm). Although the coherence length in the a-b plane is 5<br />
times greater than that along the c axis it is quite small compared to classic superconductors such as niobium (where<br />
ξ ≈ 40 nm). This modest coherence length means that the superconducting state is more susceptible to local<br />
disruptions from interfaces or defects on the order of a single unit cell, such as the boundary between twinned crystal<br />
domains. This sensitivity to small defects complicates fabricating devices with YBCO, and the material is also<br />
sensitive to degradation from humidity.
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Yttrium barium copper oxide 18<br />
Superconductive properties<br />
It is a Type-II superconductor.<br />
Penetration depth : 120 nm in the ab plane, 800 nm along the c axis.<br />
Coherence length : 2 nm in the ab plane, 0.4 nm along the c axis.<br />
Properties of single crystals<br />
The upper critical field is 120 T for B perpendicular and 250 T for B parallel to the CuO 2 planes.<br />
Bulk properties<br />
Bulk properties depend greatly on the manner of synthesis and treatment because of the effect on crystal size,<br />
alignment, and density and type of lattice defects.<br />
Applications in technology<br />
"The implementation of thin-film YBCO receiver coils has improved the signal-to-noise ratio of nuclear magnetic<br />
resonance (NMR) spectrometers by a factor of 3 compared to that achievable with conventional coils." [13]<br />
Several commercial applications of high temperature superconducting materials have been realized. For example,<br />
superconducting materials are finding use as magnets in magnetic resonance imaging, magnetic levitation, and<br />
Josephson junctions. (The most used material for power cables and magnets is BSCCO.)<br />
YBCO has yet to be used in many applications involving superconductors for two primary reasons:<br />
• First, while single crystals of YBCO have a very high critical current density, polycrystals have a very low critical<br />
current density: only a small current can be passed while maintaining superconductivity. This problem is due to<br />
crystal grain boundaries in the material. When the grain boundary angle is greater than about 5°, the supercurrent<br />
cannot cross the boundary. The grain boundary problem can be controlled to some extent by preparing thin films<br />
via CVD or by texturing the material to align the grain boundaries.<br />
• A second problem limiting the use of this material in technological applications is associated with processing of<br />
the material. Oxide materials such as this are brittle, and forming them into wires by any conventional process<br />
does not produce a useful superconductor. (Unlike BSCCO, the powder-in-tube process does not give good<br />
results with YBCO.)<br />
It should be noted that cooling materials to liquid nitrogen temperature (77 K) is often not practical on a large scale,<br />
although many commercial magnets are routinely cooled to liquid helium temperatures (4.2 K).<br />
The most promising method developed to utilize this material involves deposition of YBCO on flexible metal tapes<br />
coated with buffering metal oxides. This is known as coated conductor. Texture (crystal plane alignment) can be<br />
introduced into the metal tape itself (the RABiTS process) or a textured ceramic buffer layer can be deposited, with<br />
the aid of an ion beam, on an untextured alloy substrate (the IBAD process). Subsequent oxide layers prevent<br />
diffusion of the metal from the tape into the superconductor while transferring the template for texturing the<br />
superconducting layer. Novel variants on CVD, PVD, and solution deposition techniques are used to produce long<br />
lengths of the final YBCO layer at high rates. Companies pursuing these processes include American<br />
Superconductor, Superpower (a division of Intermagnetics General Corp), Sumitomo, Fujikura, Nexans<br />
Superconductors, and European Advanced Superconductors. A much larger number of research institutes have also<br />
produced YBCO tape by these methods.
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Yttrium barium copper oxide 19<br />
Surface modification of YBCO<br />
Surface modification of materials has often led to new and improved properties. Corrosion inhibition, polymer<br />
adhesion and nucleation, preparation of organic superconductor/insulator/high-T c superconductor trilayer structures,<br />
and the fabrication of metal/insulator/superconductor tunnel junctions have been developed using surface-modified<br />
YBCO. [14]<br />
These molecular layered materials are synthesized using cyclic voltammetry. Thus far, YBCO layered with<br />
alkylamines, arylamines, and thiols have been produced with varying stability of the molecular layer. It has been<br />
proposed that amines act as Lewis bases and bind to Lewis acidic Cu surface sites in YBa 2 Cu 3 O 7 to form stable<br />
coordination bonds.<br />
References<br />
[1] http:/ / www. commonchemistry. org/ ChemicalDetail. aspx?ref=107539-20-8<br />
[2] Knizhnik, A (2003). "Interrelation of preparation conditions, morphology, chemical reactivity and homogeneity of ceramic YBCO". Physica<br />
C: Superconductivity 400: 25. Bibcode 2003PhyC..400...25K. doi:10.1016/S0921-4534(03)01311-X.<br />
[3] Grekhov, I (1999). "Growth mode study of ultrathin HTSC YBCO films on YBaCuNbO buffer". Physica C: Superconductivity 324: 39.<br />
Bibcode 1999PhyC..324...39G. doi:10.1016/S0921-4534(99)00423-2.<br />
[4] http:/ / en. wikipedia. org/ wiki/ %3Ayttrium_barium_copper_oxide?diff=cur& oldid=432929974<br />
[5] M. K. Wu, J. R. Ashburn, C. J. Torng, P. H. Hor, R. L. Meng, L. Gao, Z. J. Huang, Y. Q. Wang, and C. W. Chu (1987). "Superconductivity at<br />
93 K in a New Mixed-Phase Y-Ba-Cu-O Compound System at Ambient Pressure". Physical Review Letters 58 (9): 908–910.<br />
Bibcode 1987PhRvL..58..908W. doi:10.1103/PhysRevLett.58.908. PMID 10035069.<br />
[6] Housecroft, C. E.; Sharpe, A. G. (2004). Inorganic Chemistry (2nd ed.). Prentice Hall. ISBN 978-0130399137.<br />
[7] Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Oxford: Butterworth-Heinemann. ISBN 0080379419.<br />
[8] T. Sekitania, N. Miura, S. Ikedaa, Y. H. Matsudaa, Y. Shioharab (2004). "Upper critical field for optimally-doped YBa2Cu3O7−δ" (http:/ /<br />
www. sciencedirect. com/ science?_ob=ArticleURL& _udi=B6TVH-4BWYV0D-H& _user=10& _rdoc=1& _fmt=& _orig=search&<br />
_sort=d& view=c& _acct=C000050221& _version=1& _urlVersion=0& _userid=10& md5=28aeb1ca959e86bc4a201f483224ec06). Elsevier<br />
Science B.V.. .<br />
[9] Yang-Kook Sun, In-Hwan Oh (1996). "Preparation of Ultrafine YBa2Cu3O7-x Superconductor Powders by the Poly(vinyl alcohol)-Assisted<br />
Sol−Gel Method". Ind. Eng. Chem. Res. 35 (11): 4296. doi:10.1021/ie950527y.<br />
[10] Zhou, Derong (1991) (Ph.D. Thesis). Yttrium Barium Copper Oxide Superconducting Powder Generation by An Aerosol Process. University<br />
of Cincinnati. pp. 28. Bibcode 1991PhDT........28Z.<br />
[11] O. Castano, A. Cavallaro, A. Palau, J. C. Gonzalez, M. Rossell, T. Puig, F. Sandiumenge, N. Mestres, S. Pinol, A. Pomar, and X. Obradors<br />
(2003). "High quality YBa 2 Cu 3 O {7–x} thin films grown by trifluoroacetates metal-organic deposition". Supercond. Sci. Technol. 16: 45–53.<br />
Bibcode 2003SuScT..16...45C. doi:10.1088/0953-2048/16/1/309.<br />
[12] Oka, K (1998). "Crystal growth of superconductive PrBa2Cu3O7−y". Physica C 300 (3–4): 200. doi:10.1016/S0921-4534(98)00130-0.<br />
[13] Superconducting devices (http:/ / encyclopedia2. thefreedictionary. com/ Superconducting+ devices)<br />
[14] F. Xu et al. (1998). "Surface Coordination Chemistry of YBa2Cu3O7-δ". Langmuir 14 (22): 6505. doi:10.1021/la980143n.<br />
External links<br />
• Diagram of YBCO structure (http:/ / www. ch. ic. ac. uk/ otway/ YBCO. html)<br />
• New World Record For Superconducting Magnet 26.8T April 2007 (http:/ / www. physorg. com/<br />
news105718161. html)<br />
• External MSDS Data Sheet (safety classifications) for YBCO (http:/ / www. futurescience. com/ manual/<br />
ybcomsds. html).<br />
• Superconductivity in everyday life : Interactive exhibition – little if any specific to YBCO (http:/ / www.<br />
superlife. info).
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Liquid nitrogen 20<br />
Liquid nitrogen<br />
Liquid nitrogen is nitrogen in a liquid state at a very low temperature.<br />
It is produced industrially by fractional distillation of liquid air. Liquid<br />
nitrogen is a colourless clear liquid with density of 0.807 g/mL at its<br />
boiling point and a dielectric constant of 1.4. [1] Liquid nitrogen is often<br />
referred to by the abbreviation, LN 2 or "LIN" or "LN" and has the UN<br />
number 1977.<br />
At atmospheric pressure, liquid nitrogen boils at 77K (-196°C; -321°F)<br />
and is a cryogenic fluid which can cause rapid freezing on contact with<br />
living tissue, which may lead to frostbite. When appropriately insulated<br />
from ambient heat, liquid nitrogen can be stored and transported, for<br />
example in vacuum flasks. Here, the very low temperature is held<br />
constant at 77 K by slow boiling of the liquid, resulting in the<br />
evolution of nitrogen gas. Depending on the size and design, the<br />
holding time of vacuum flasks ranges from a few hours to a few weeks.<br />
Liquid nitrogen can easily be converted to the solid by placing it in a<br />
vacuum chamber pumped by a rotary vacuum pump. [2] Liquid nitrogen<br />
freezes at 63 K (−210 °C; −346 °F). Despite its reputation, liquid<br />
nitrogen's efficiency as a coolant is limited by the fact that it boils<br />
immediately on contact with a warmer object, enveloping the object in<br />
insulating nitrogen gas. This effect, known as the Leidenfrost effect,<br />
applies to any liquid in contact with an object significantly hotter than<br />
its boiling point. More rapid cooling may be obtained by plunging an<br />
object into a slush of liquid and solid nitrogen than into liquid nitrogen<br />
alone.<br />
Nitrogen was first liquefied at the Jagiellonian University on 15 April<br />
1883 by Polish physicists, Zygmunt Wróblewski and Karol Olszewski. [3]<br />
Uses<br />
Liquid nitrogen<br />
MIT students preparing homemade ice cream<br />
with liquid nitrogen.<br />
Liquid nitrogen is a compact and readily transported source of nitrogen gas without pressurization. Further, its ability<br />
to maintain temperatures far below the freezing point of water makes it extremely useful in a wide range of<br />
applications, primarily as an open-cycle refrigerant, including:<br />
• in cryotherapy for removing unsightly or potentially malignant skin lesions such as warts and actinic keratosis<br />
• as a coolant for CCD cameras in astronomy<br />
• to store cells at low temperature for laboratory work<br />
• in cryogenics<br />
• as a source of very dry nitrogen gas<br />
• for the immersion freezing and transportation of food products<br />
• for the cryopreservation of blood, reproductive cells (sperm and egg), and other biological samples and materials<br />
• as a method of freezing water pipes in order to work on them in situations where a valve is not available to block<br />
water flow to the work area<br />
• in the process of promession, a way to dispose of the dead<br />
• for cooling a high-temperature superconductor to a temperature sufficient to achieve superconductivity
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Liquid nitrogen 21<br />
• for the cryonic preservation in the hope of future reanimation.<br />
• to preserve tissue samples from surgical excisions for future studies<br />
• to shrink-weld machinery parts together<br />
• as a coolant for vacuum pump traps and in controlled-evaporation processes in chemistry.<br />
• as a coolant to increase the sensitivity of infrared homing seeker heads of missiles such as the Strela 3<br />
• as a coolant to temporarily shrink mechanical components during machine assembly and allow improved<br />
interference fits<br />
• as a coolant for computers [4]<br />
• in food preparation, such as for making ultra-smooth ice cream. [5]<br />
Safety<br />
Since the liquid to gas expansion ratio of nitrogen is 1:694 at 20C, a<br />
tremendous amount of force can be generated if liquid nitrogen is<br />
rapidly vaporized. In an incident in 2006 at Texas A&M University,<br />
the pressure-relief devices of a tank of liquid nitrogen were<br />
malfunctioning and later sealed. As a result of the subsequent pressure<br />
buildup, the tank failed catastrophically and exploded. The force of the<br />
explosion was sufficient to propel the tank through the ceiling<br />
immediately above it. [6]<br />
Because of its extremely low temperature, careless handling of liquid<br />
nitrogen may result in cold burns.<br />
As liquid nitrogen evaporates it will reduce the oxygen concentration<br />
in the air and might act as an asphyxiant, especially in confined spaces.<br />
Nitrogen is odorless, colorless and tasteless, and may produce asphyxia<br />
without any sensation or prior warning. [7] A laboratory assistant died in<br />
Scotland in 1999, apparently from asphyxiation, possibly caused by<br />
liquid nitrogen spilled in a basement storage room. [8]<br />
Vessels containing liquid nitrogen can condense oxygen from air. The<br />
liquid in such a vessel becomes increasingly enriched in oxygen<br />
Filling a liquid nitrogen Dewar from a storage<br />
(boiling point = 90 K) as the nitrogen evaporates, and can cause violent oxidation of organic material.<br />
References<br />
[1] "Dielectric Constants" (http:/ / www. apgsensors. com/ ltr2/ access. php?file=pdf/ dielectric-constants. pdf). .<br />
[2] Umrath, W. (1974) Cooling bath for rapid freezing in electron microscopy. Journal of Microscopy 101, 103–105.<br />
[3] William Augustus Tilden (2009). A Short History of the Progress of Scientific Chemistry in Our Own Times (http:/ / books. google. com/<br />
books?id=8SKrWdFLEd4C& pg=PA249). BiblioBazaar, LLC. p. 249. ISBN 1103358421. .<br />
[4] Wainner, Scott; Robert Richmond (2003). The <strong>Book</strong> of Overclocking: Tweak Your PC to Unleash Its Power. No Starch Press. pp. 44.<br />
ISBN 188641176X.<br />
[5] Liquid Nitrogen Ice Cream Recipe (http:/ / www. 101cookbooks. com/ archives/ 001366. html), March 7, 2006<br />
[6] Brent S. Mattox. "Investigative Report on Chemistry 301A Cylinder Explosion" (http:/ / ucih. ucdavis. edu/ docs/ chemistry_301a. pdf)<br />
(reprint). Texas A&M University. .<br />
[7] British Compressed Gases Association (2000) BCGA Code of Practice CP30. The Safe Use of Liquid nitrogen Dewars up to 50 litres. (http:/ /<br />
www. bcga. co. uk/ preview/ products. php?g1=3ff921& n=2) ISSN 0260-4809.<br />
[8] Inquiry after man dies in chemical leak (http:/ / news. bbc. co. uk/ 2/ hi/ uk_news/ scotland/ 484813. stm), BBC News, .<br />
tank
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Liquid nitrogen 22<br />
External links<br />
• Behind the scenes video (http:/ / www. younghotelier. com/ interviews/<br />
video-cooking-with-liquid-nitrogen-in-the-real-world-tang-restaurant-dubai/ ) – How liquid nitrogen is used in<br />
restaurants for cooking and cocktails
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Magnetism<br />
Magnetism<br />
Magnetism is a property of materials that respond at an atomic or subatomic level to an applied magnetic field.<br />
Ferromagnetism is the strongest and most familiar type of magnetism. It is responsible for the behavior of permanent<br />
magnets, which produce their own persistent magnetic fields, as well as the materials that are attracted to them.<br />
However, all materials are influenced to a greater or lesser degree by the presence of a magnetic field. Some are<br />
attracted to a magnetic field (paramagnetism); others are repulsed by a magnetic field (diamagnetism); others have a<br />
much more complex relationship with an applied magnetic field (spin glass behavior and antiferromagnetism).<br />
Substances that are negligibly affected by magnetic fields are known as non-magnetic substances. They include<br />
copper, aluminium, gases, and plastic.<br />
The magnetic state (or phase) of a material depends on temperature (and other variables such as pressure and applied<br />
magnetic field) so that a material may exhibit more than one form of magnetism depending on its temperature, etc.<br />
History<br />
Aristotle attributed the first of what could be called a scientific discussion on magnetism to Thales, who lived from<br />
about 625 BCE to about 545 BCE. [1] Around the same time, in ancient India, the Indian surgeon, Sushruta, was the<br />
first to make use of the magnet for surgical purposes. [2]<br />
In ancient China, the earliest literary reference to magnetism lies in a 4th century BCE book called <strong>Book</strong> of the Devil<br />
Valley Master (鬼谷子): "The lodestone makes iron come or it attracts it." [3] The earliest mention of the attraction of<br />
a needle appears in a work composed between AD 20 and 100 (Louen-heng): "A lodestone attracts a needle." [4] The<br />
ancient Chinese scientist Shen Kuo (1031–1095) was the first person to write of the magnetic needle compass and<br />
that it improved the accuracy of navigation by employing the astronomical concept of true north (Dream Pool<br />
Essays, AD 1088), and by the 12th century the Chinese were known to use the lodestone compass for navigation.<br />
They sculpted a directional spoon from lodestone in such a way that the handle of the spoon always pointed south.<br />
Alexander Neckham, by 1187, was the first in Europe to describe the compass and its use for navigation. In 1269,<br />
Peter Peregrinus de Maricourt wrote the Epistola de magnete, the first extant treatise describing the properties of<br />
magnets. In 1282, the properties of magnets and the dry compass were discussed by Al-Ashraf, a Yemeni physicist,<br />
astronomer, and geographer. [5]<br />
In 1600, William Gilbert published his De Magnete, Magneticisque Corporibus, et de Magno Magnete Tellure (On<br />
the Magnet and Magnetic Bodies, and on the Great Magnet the Earth). In this work he describes many of his<br />
experiments with his model earth called the terrella. From his experiments, he concluded that the Earth was itself<br />
magnetic and that this was the reason compasses pointed north (previously, some believed that it was the pole star<br />
(Polaris) or a large magnetic island on the north pole that attracted the compass).<br />
An understanding of the relationship between electricity and magnetism began in 1819 with work by Hans Christian<br />
Oersted, a professor at the University of Copenhagen, who discovered more or less by accident that an electric<br />
current could influence a compass needle. This landmark experiment is known as Oersted's Experiment. Several<br />
other experiments followed, with André-Marie Ampère, who in 1820 discovered that the magnetic field circulating<br />
in a closed-path was related to the current flowing through the perimeter of the path; Carl Friedrich Gauss;<br />
Jean-Baptiste Biot and Félix Savart, both of which in 1820 came up with the Biot-Savart Law giving an equation for<br />
the magnetic field from a current-carrying wire; Michael Faraday, who in 1831 found that a time-varying magnetic<br />
flux through a loop of wire induced a voltage, and others finding further links between magnetism and electricity.<br />
23
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Magnetism 24<br />
James Clerk Maxwell synthesized and expanded these insights into Maxwell's equations, unifying electricity,<br />
magnetism, and optics into the field of electromagnetism. In 1905, Einstein used these laws in motivating his theory<br />
of special relativity, [6] requiring that the laws held true in all inertial reference frames.<br />
Electromagnetism has continued to develop into the 21st century, being incorporated into the more fundamental<br />
theories of gauge theory, quantum electrodynamics, electroweak theory, and finally the standard model.<br />
Sources of magnetism<br />
Magnetism, at its root, arises from two sources:<br />
1. Electric currents or more generally, moving electric charges create magnetic fields (see Maxwell's Equations).<br />
2. Many particles have nonzero "intrinsic" (or "spin") magnetic moments. Just as each particle, by its nature, has a<br />
certain mass and charge, each has a certain magnetic moment, possibly zero.<br />
In magnetic materials, sources of magnetization are the electrons' orbital angular motion around the nucleus, and the<br />
electrons' intrinsic magnetic moment (see electron magnetic dipole moment). The other sources of magnetism are the<br />
nuclear magnetic moments of the nuclei in the material which are typically thousands of times smaller than the<br />
electrons' magnetic moments, so they are negligible in the context of the magnetization of materials. Nuclear<br />
magnetic moments are important in other contexts, particularly in nuclear magnetic resonance (NMR) and magnetic<br />
resonance imaging (MRI).<br />
Ordinarily, the enormous number of electrons in a material are arranged such that their magnetic moments (both<br />
orbital and intrinsic) cancel out. This is due, to some extent, to electrons combining into pairs with opposite intrinsic<br />
magnetic moments as a result of the Pauli exclusion principle (see electron configuration), or combining into filled<br />
subshells with zero net orbital motion. In both cases, the electron arrangement is so as to exactly cancel the magnetic<br />
moments from each electron. Moreover, even when the electron configuration is such that there are unpaired<br />
electrons and/or non-filled subshells, it is often the case that the various electrons in the solid will contribute<br />
magnetic moments that point in different, random directions, so that the material will not be magnetic.<br />
However, sometimes — either spontaneously, or owing to an applied external magnetic field — each of the electron<br />
magnetic moments will be, on average, lined up. Then the material can produce a net total magnetic field, which can<br />
potentially be quite strong.<br />
The magnetic behavior of a material depends on its structure, particularly its electron configuration, for the reasons<br />
mentioned above, and also on the temperature. At high temperatures, random thermal motion makes it more difficult<br />
for the electrons to maintain alignment.<br />
Topics
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Magnetism 25<br />
Diamagnetism<br />
Diamagnetism appears in all materials,<br />
and is the tendency of a material to<br />
oppose an applied magnetic field, and<br />
therefore, to be repelled by a magnetic<br />
field. However, in a material with<br />
paramagnetic properties (that is, with a<br />
tendency to enhance an external<br />
magnetic field), the paramagnetic<br />
behavior dominates. [8] Thus, despite its<br />
universal occurrence, diamagnetic<br />
behavior is observed only in a purely<br />
Hierarchy of types of magnetism. [7]<br />
diamagnetic material. In a diamagnetic material, there are no unpaired electrons, so the intrinsic electron magnetic<br />
moments cannot produce any bulk effect. In these cases, the magnetization arises from the electrons' orbital motions,<br />
which can be understood classically as follows:<br />
When a material is put in a magnetic field, the electrons circling the nucleus will experience, in addition to<br />
their Coulomb attraction to the nucleus, a Lorentz force from the magnetic field. Depending on which<br />
direction the electron is orbiting, this force may increase the centripetal force on the electrons, pulling them in<br />
towards the nucleus, or it may decrease the force, pulling them away from the nucleus. This effect<br />
systematically increases the orbital magnetic moments that were aligned opposite the field, and decreases the<br />
ones aligned parallel to the field (in accordance with Lenz's law). This results in a small bulk magnetic<br />
moment, with an opposite direction to the applied field.<br />
Note that this description is meant only as an heuristic; a proper understanding requires a quantum-mechanical<br />
description.<br />
Note that all materials undergo this orbital response. However, in paramagnetic and ferromagnetic substances, the<br />
diamagnetic effect is overwhelmed by the much stronger effects caused by the unpaired electrons.<br />
Paramagnetism<br />
In a paramagnetic material there are unpaired electrons, i.e. atomic or molecular orbitals with exactly one electron in<br />
them. While paired electrons are required by the Pauli exclusion principle to have their intrinsic ('spin') magnetic<br />
moments pointing in opposite directions, causing their magnetic fields to cancel out, an unpaired electron is free to<br />
align its magnetic moment in any direction. When an external magnetic field is applied, these magnetic moments<br />
will tend to align themselves in the same direction as the applied field, thus reinforcing it.<br />
Ferromagnetism<br />
A ferromagnet, like a paramagnetic substance, has unpaired electrons. However, in addition to the electrons' intrinsic<br />
magnetic moment's tendency to be parallel to an applied field, there is also in these materials a tendency for these<br />
magnetic moments to orient parallel to each other to maintain a lowered-energy state. Thus, even when the applied<br />
field is removed, the electrons in the material maintain a parallel orientation.<br />
Every ferromagnetic substance has its own individual temperature, called the Curie temperature, or Curie point,<br />
above which it loses its ferromagnetic properties. This is because the thermal tendency to disorder overwhelms the<br />
energy-lowering due to ferromagnetic order.<br />
Some well-known ferromagnetic materials that exhibit easily detectable magnetic properties (to form magnets) are<br />
nickel, iron, cobalt, gadolinium and their alloys.
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Magnetism 26<br />
Magnetic domains<br />
The magnetic moment of atoms in a ferromagnetic material cause them to<br />
behave something like tiny permanent magnets. They stick together and align<br />
themselves into small regions of more or less uniform alignment called<br />
magnetic domains or Weiss domains. Magnetic domains can be observed<br />
with a magnetic force microscope to reveal magnetic domain boundaries that<br />
resemble white lines in the sketch. There are many scientific experiments that<br />
can physically show magnetic fields.<br />
Effect of a magnet on the domains.<br />
Magnetic domains in ferromagnetic<br />
material.<br />
When a domain contains too many molecules, it becomes unstable<br />
and divides into two domains aligned in opposite directions so that<br />
they stick together more stably as shown at the right.<br />
When exposed to a magnetic field, the domain boundaries move so<br />
that the domains aligned with the magnetic field grow and<br />
dominate the structure as shown at the left. When the magnetizing<br />
field is removed, the domains may not return to an unmagnetized<br />
state. This results in the ferromagnetic material's being<br />
magnetized, forming a permanent magnet.<br />
When magnetized strongly enough that the prevailing domain<br />
overruns all others to result in only one single domain, the material<br />
is magnetically saturated. When a magnetized ferromagnetic<br />
material is heated to the Curie point temperature, the molecules are<br />
agitated to the point that the magnetic domains lose the<br />
organization and the magnetic properties they cause cease. When<br />
the material is cooled, this domain alignment structure spontaneously returns, in a manner roughly analogous to how<br />
a liquid can freeze into a crystalline solid.<br />
Antiferromagnetism<br />
In an antiferromagnet, unlike a ferromagnet, there is a tendency for the<br />
intrinsic magnetic moments of neighboring valence electrons to point<br />
in opposite directions. When all atoms are arranged in a substance so<br />
that each neighbor is 'anti-aligned', the substance is<br />
antiferromagnetic. Antiferromagnets have a zero net magnetic<br />
moment, meaning no field is produced by them. Antiferromagnets are<br />
less common compared to the other types of behaviors, and are mostly<br />
observed at low temperatures. In varying temperatures,<br />
antiferromagnets can be seen to exhibit diamagnetic and ferrimagnetic properties.<br />
Antiferromagnetic ordering<br />
In some materials, neighboring electrons want to point in opposite directions, but there is no geometrical<br />
arrangement in which each pair of neighbors is anti-aligned. This is called a spin glass, and is an example of<br />
geometrical frustration.
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Magnetism 27<br />
Ferrimagnetism<br />
Like ferromagnetism, ferrimagnets retain their magnetization in the<br />
absence of a field. However, like antiferromagnets, neighboring pairs<br />
of electron spins like to point in opposite directions. These two<br />
properties are not contradictory, because in the optimal geometrical<br />
arrangement, there is more magnetic moment from the sublattice of<br />
electrons that point in one direction, than from the sublattice that points<br />
in the opposite direction.<br />
The first discovered magnetic substance, magnetite, was originally<br />
Ferrimagnetic ordering<br />
believed to be a ferromagnet; Louis Néel disproved this, however, with the discovery of ferrimagnetism.<br />
Superparamagnetism<br />
When a ferromagnet or ferrimagnet is sufficiently small, it acts like a single magnetic spin that is subject to<br />
Brownian motion. Its response to a magnetic field is qualitatively similar to the response of a paramagnet, but much<br />
larger.<br />
Electromagnet<br />
An electromagnet is a type of magnet whose magnetism is produced by the flow of electric current. The magnetic<br />
field disappears when the current ceases.<br />
Electromagnets attracts paper clips when current<br />
is applied creating a magnetic field. The<br />
electromagnet loses them when current and<br />
magnetic field are removed.<br />
Other types of magnetism<br />
• Molecular magnet<br />
• Metamagnetism<br />
• Molecule-based magnet<br />
• Spin glass<br />
Magnetism, electricity, and special relativity<br />
As a consequence of Einstein's theory of special relativity, electricity<br />
and magnetism are fundamentally interlinked. Both magnetism lacking<br />
electricity, and electricity without magnetism, are inconsistent with<br />
special relativity, due to such effects as length contraction, time<br />
dilation, and the fact that the magnetic force is velocity-dependent.<br />
However, when both electricity and magnetism are taken into account, the resulting theory (electromagnetism) is<br />
fully consistent with special relativity. [6] [9] In particular, a phenomenon that appears purely electric to one observer<br />
may be purely magnetic to another, or more generally the relative contributions of electricity and magnetism are<br />
dependent on the frame of reference. Thus, special relativity "mixes" electricity and magnetism into a single,<br />
inseparable phenomenon called electromagnetism, analogous to how relativity "mixes" space and time into<br />
spacetime.
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Magnetism 28<br />
Magnetic fields in a material<br />
In a vacuum,<br />
where μ 0 is the vacuum permeability.<br />
In a material,<br />
The quantity μ 0 M is called magnetic polarization.<br />
If the field H is small, the response of the magnetization M in a diamagnet or paramagnet is approximately linear:<br />
the constant of proportionality being called the magnetic susceptibility. If so,<br />
In a hard magnet such as a ferromagnet, M is not proportional to the field and is generally nonzero even when H is<br />
zero (see Remanence).<br />
Force due to magnetic field - The magnetic force<br />
The phenomenon of magnetism is "mediated" by the magnetic field.<br />
An electric current or magnetic dipole creates a magnetic field, and<br />
that field, in turn, imparts magnetic forces on other particles that are in<br />
the fields.<br />
Maxwell's equations, which simplify to the Biot-Savart law in the case<br />
of steady currents, describe the origin and behavior of the fields that<br />
govern these forces. Therefore magnetism is seen whenever electrically<br />
charged particles are in motion---for example, from movement of<br />
electrons in an electric current, or in certain cases from the orbital<br />
motion of electrons around an atom's nucleus. They also arise from<br />
"intrinsic" magnetic dipoles arising from quantum-mechanical spin.<br />
Magnetic lines of force of a bar magnet shown by<br />
iron filings on paper<br />
The same situations that create magnetic fields — charge moving in a current or in an atom, and intrinsic magnetic<br />
dipoles — are also the situations in which a magnetic field has an effect, creating a force. Following is the formula<br />
for moving charge; for the forces on an intrinsic dipole, see magnetic dipole.<br />
When a charged particle moves through a magnetic field B, it feels a Lorentz force F given by the cross product: [10]<br />
where<br />
is the electric charge of the particle, and<br />
v is the velocity vector of the particle<br />
Because this is a cross product, the force is perpendicular to both the motion of the particle and the magnetic field. It<br />
follows that the magnetic force does no work on the particle; it may change the direction of the particle's movement,<br />
but it cannot cause it to speed up or slow down. The magnitude of the force is<br />
where is the angle between v and B.<br />
One tool for determining the direction of the velocity vector of a moving charge, the magnetic field, and the force<br />
exerted is labeling the index finger "V", the middle finger "B", and the thumb "F" with your right hand. When<br />
making a gun-like configuration, with the middle finger crossing under the index finger, the fingers represent the
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Magnetism 29<br />
velocity vector, magnetic field vector, and force vector, respectively. See also right hand rule.<br />
Magnetic dipoles<br />
A very common source of magnetic field shown in nature is a dipole, with a "South pole" and a "North pole", terms<br />
dating back to the use of magnets as compasses, interacting with the Earth's magnetic field to indicate North and<br />
South on the globe. Since opposite ends of magnets are attracted, the north pole of a magnet is attracted to the south<br />
pole of another magnet. The Earth's North Magnetic Pole (currently in the Arctic Ocean, north of Canada) is<br />
physically a south pole, as it attracts the north pole of a compass.<br />
A magnetic field contains energy, and physical systems move toward configurations with lower energy. When<br />
diamagnetic material is placed in a magnetic field, a magnetic dipole tends to align itself in opposed polarity to that<br />
field, thereby lowering the net field strength. When ferromagnetic material is placed within a magnetic field, the<br />
magnetic dipoles align to the applied field, thus expanding the domain walls of the magnetic domains.<br />
Magnetic monopoles<br />
Since a bar magnet gets its ferromagnetism from electrons distributed evenly throughout the bar, when a bar magnet<br />
is cut in half, each of the resulting pieces is a smaller bar magnet. Even though a magnet is said to have a north pole<br />
and a south pole, these two poles cannot be separated from each other. A monopole — if such a thing exists —<br />
would be a new and fundamentally different kind of magnetic object. It would act as an isolated north pole, not<br />
attached to a south pole, or vice versa. Monopoles would carry "magnetic charge" analogous to electric charge.<br />
Despite systematic searches since 1931, as of 2010, they have never been observed, and could very well not exist. [11]<br />
Nevertheless, some theoretical physics models predict the existence of these magnetic monopoles. Paul Dirac<br />
observed in 1931 that, because electricity and magnetism show a certain symmetry, just as quantum theory predicts<br />
that individual positive or negative electric charges can be observed without the opposing charge, isolated South or<br />
North magnetic poles should be observable. Using quantum theory Dirac showed that if magnetic monopoles exist,<br />
then one could explain the quantization of electric charge---that is, why the observed elementary particles carry<br />
charges that are multiples of the charge of the electron.<br />
Certain grand unified theories predict the existence of monopoles which, unlike elementary particles, are solitons<br />
(localized energy packets). The initial results of using these models to estimate the number of monopoles created in<br />
the big bang contradicted cosmological observations — the monopoles would have been so plentiful and massive<br />
that they would have long since halted the expansion of the universe. However, the idea of inflation (for which this<br />
problem served as a partial motivation) was successful in solving this problem, creating models in which monopoles<br />
existed but were rare enough to be consistent with current observations. [12]<br />
Quantum-mechanical origin of magnetism<br />
In principle all kinds of magnetism originate (similar to Superconductivity) from specific quantum-mechanical<br />
phenomena which are not easily explained (e.g. Mathematical formulation of quantum mechanics, in particular the<br />
chapters on spin and on the Pauli principle). A successful model was developed already in 1927, by Walter Heitler<br />
and Fritz London, who derived quantum-mechanically, how hydrogen molecules are formed from hydrogen atoms,<br />
i.e. from the atomic hydrogen orbitals and centered at the nuclei A and B, see below. That this leads to<br />
magnetism, is not at all obvious, but will be explained in the following.<br />
According the Heitler-London theory, so-called two-body molecular -orbitals are formed, namely the resulting<br />
orbital is:
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Magnetism 30<br />
Here the last product means that a first electron, r 1 , is in an atomic hydrogen-orbital centered at the second nucleus,<br />
whereas the second electron runs around the first nucleus. This "exchange" phenomenon is an expression for the<br />
quantum-mechanical property that particles with identical properties cannot be distinguished. It is specific not only<br />
for the formation of chemical bonds, but as we will see, also for magnetism, i.e. in this connection the term exchange<br />
interaction arises, a term which is essential for the origin of magnetism, and which is stronger, roughly by factors<br />
100 and even by 1000, than the energies arising from the electrodynamic dipole-dipole interaction.<br />
As for the spin function , which is responsible for the magnetism, we have the already mentioned Pauli's<br />
principle, namely that a symmetric orbital (i.e. with the + sign as above) must be multiplied with an antisymmetric<br />
spin function (i.e. with a - sign), and vice versa. Thus:<br />
I.e., not only and must be substituted by α and β, respectively (the first entity means "spin up", the second<br />
one "spin down"), but also the sign + by the − sign, and finally r i by the discrete values s i (= ±½); thereby we have<br />
,<br />
and . The "singlet state", i.e. the - sign, means: the<br />
spins are antiparallel, i.e. for the solid we have antiferromagnetism, and for two-atomic molecules one has<br />
diamagnetism. The tendency to form a (homoeopolar) chemical bond (this means: the formation of a symmetric<br />
molecular orbital , i.e. with the + sign) results through the Pauli principle automatically in an antisymmetric spin<br />
state (i.e. with the - sign). In contrast, the Coulomb repulsion of the electrons, i.e. the tendency that they try to avoid<br />
each other by this repulsion, would lead to an antisymmetric orbital function (i.e. with the - sign) of these two<br />
particles, and complementary to a symmetric spin function (i.e. with the + sign, one of the so-called "triplet<br />
functions"). Thus, now the spins would be parallel (ferromagnetism in a solid, paramagnetism in two-atomic gases).<br />
The last-mentioned tendency dominates in the metals iron, cobalt and nickel, and in some rare earths, which are<br />
ferromagnetic. Most of the other metals, where the first-mentioned tendency dominates, are nonmagnetic (e.g.<br />
sodium, aluminium, and magnesium) or antiferromagnetic (e.g. manganese). Diatomic gases are also almost<br />
exclusively diamagnetic, and not paramagnetic. However, the oxygen molecule, because of the involvement of<br />
π-orbitals, is an exception important for the life-sciences.<br />
The Heitler-London considerations can be generalized to the Heisenberg model of magnetism (Heisenberg 1928).<br />
The explanation of the phenomena is thus essentially based on all subtleties of quantum mechanics, whereas the<br />
electrodynamics covers mainly the phenomenology.<br />
Units of electromagnetism<br />
SI units related to magnetism<br />
SI electromagnetism units<br />
Symbol [13] Name of Quantity Derived Units Conversion of International to SI base units<br />
Electric current ampere (SI base unit)<br />
Electric charge coulomb<br />
Potential difference; Electromotive force volt<br />
Electric resistance; Impedance; Reactance ohm<br />
Resistivity ohm metre<br />
Electric power watt<br />
Capacitance farad<br />
Electric field strength volt per metre
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Magnetism 31<br />
Other units<br />
Electric displacement field Coulomb per square metre<br />
Permittivity farad per metre<br />
Electric susceptibility Dimensionless<br />
Conductance; Admittance; Susceptance siemens<br />
Conductivity siemens per metre<br />
Magnetic flux density, Magnetic induction tesla<br />
Magnetic flux weber<br />
Magnetic field strength ampere per metre<br />
Inductance henry<br />
Permeability henry per metre<br />
Magnetic susceptibility Dimensionless<br />
• gauss – The gauss, abbreviated as G, is the CGS unit of magnetic field (B).<br />
• oersted – The oersted is the CGS unit of magnetizing field (H).<br />
• Maxwell – is the CGS unit for the magnetic flux.<br />
• gamma – is a unit of magnetic flux density that was commonly used before the tesla became popular (1 gamma =<br />
1 nT)<br />
• μ 0 – common symbol for the permeability of free space (4π×10 −7 N/(ampere-turn) 2 ).<br />
Living things<br />
Some organisms can detect magnetic fields, a phenomenon known as magnetoception. Magnetobiology studies<br />
magnetic fields as a medical treatment; fields naturally produced by an organism are known as biomagnetism.<br />
References<br />
[1] Fowler, Michael (1997). "Historical Beginnings of Theories of Electricity and Magnetism" (http:/ / galileoandeinstein. physics. virginia. edu/<br />
more_stuff/ E& M_Hist. html). . Retrieved 2008-04-02.<br />
[2] Vowles, Hugh P. (1932). "Early Evolution of Power Engineering". Isis (University of Chicago Press) 17 (2): 412–420 [419–20].<br />
doi:10.1086/346662.<br />
[3] Li Shu-hua, “Origine de la Boussole 11. Aimant et Boussole,” Isis, Vol. 45, No. 2. (Jul., 1954), p.175<br />
[4] Li Shu-hua, “Origine de la Boussole 11. Aimant et Boussole,” Isis, Vol. 45, No. 2. (Jul., 1954), p.176<br />
[5] Schmidl, Petra G. (1996–1997). "Two Early Arabic Sources On The Magnetic Compass". Journal of Arabic and Islamic Studies 1: 81–132.<br />
[6] A. Einstein: "On the Electrodynamics of Moving Bodies" (http:/ / www. fourmilab. ch/ etexts/ einstein/ specrel/ www/ ), June 30, 1905.<br />
[7] HP Meyers (1997). Introductory solid state physics (http:/ / books. google. com/ ?id=Uc1pCo5TrYUC& pg=PA322) (2 ed.). CRC Press.<br />
p. 362; Figure 11.1. ISBN 0748406603. .<br />
[8] Catherine Westbrook, Carolyn Kaut, Carolyn Kaut-Roth (1998). MRI (Magnetic Resonance Imaging) in practice (http:/ / books. google. com/<br />
?id=Qq1SHDtS2G8C& pg=PA217) (2 ed.). Wiley-Blackwell. p. 217. ISBN 0632042052. .<br />
[9] Griffiths 1998, chapter 12<br />
[10] Jackson, John David (1999). Classical electrodynamics (3rd ed.). New York, [NY.]: Wiley. ISBN 0-471-30932-X<br />
[11] Milton mentions some inconclusive events (p.60) and still concludes that "no evidence at all of magnetic monopoles has survived" (p.3).<br />
Milton, Kimball A. (June 2006). "Theoretical and experimental status of magnetic monopoles". Reports on Progress in Physics 69 (6):<br />
1637–1711. arXiv:hep-ex/0602040. Bibcode 2006RPPh...69.1637M. doi:10.1088/0034-4885/69/6/R02..<br />
[12] Guth, Alan (1997). The Inflationary Universe: The Quest for a New Theory of Cosmic Origins. Perseus. ISBN 0-201-32840-2.<br />
OCLC 38941224..<br />
[13] International Union of Pure and Applied Chemistry (1993). Quantities, Units and Symbols in Physical Chemistry, 2nd edition, Oxford:<br />
Blackwell Science. ISBN 0-632-03583-8. pp. 14–15. Electronic version. (http:/ / www. iupac. org/ publications/ books/ gbook/<br />
green_book_2ed. pdf)
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Magnetism 32<br />
Further reading<br />
• Furlani, Edward P. (2001). Permanent Magnet and Electromechanical Devices: Materials, Analysis and<br />
Applications. Academic Press. ISBN 0-12-269951-3. OCLC 162129430.<br />
• Griffiths, David J. (1998). Introduction to Electrodynamics (3rd ed.). Prentice Hall. ISBN 0-13-805326-X.<br />
OCLC 40251748.<br />
• Kronmüller, Helmut. (2007). Handbook of Magnetism and Advanced Magnetic Materials, 5 Volume Set. John<br />
Wiley & Sons. ISBN 978-0-470-02217-7. OCLC 124165851.<br />
• Tipler, Paul (2004). Physics for Scientists and Engineers: Electricity, Magnetism, Light, and Elementary Modern<br />
Physics (5th ed.). W. H. <strong>Free</strong>man. ISBN 0-7167-0810-8. OCLC 51095685.<br />
• David K. Cheng (1992). Field and Wave Electromagnetics. Addison-Wesley Publishing Company, Inc..<br />
ISBN 0-201-12819-5.<br />
External links<br />
• Magnetism (http:/ / www. bbc. co. uk/ programmes/ p003k9dd) on In Our Time at the BBC. ( listen now (http:/ /<br />
www. bbc. co. uk/ iplayer/ console/ p003k9dd/ In_Our_Time_Magnetism))<br />
• Magnetism Experiments (http:/ / sciencecastle. com/ sc/ index. php/ scienceexperiments/ search?p=0& t=a&<br />
v=mr& c=0& cl=1)<br />
• Electromagnetism (http:/ / www. lightandmatter. com/ html_books/ 0sn/ ch11/ ch11. html) - a chapter from an<br />
online textbook<br />
• Video: The physicist Richard Feynman answers the question, Why do bar magnets attract or repel each other?<br />
(http:/ / www. youtube. com/ watch?v=wMFPe-DwULM)<br />
• On the Magnet, 1600 (http:/ / www. antiquebooks. net/ readpage. html#gilbert) First scientific book on magnetism<br />
by the father of electrical engineering. Full English text, full text search.
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Magnetic field 33<br />
Magnetic field<br />
A magnetic field is a mathematical description of the magnetic influence of electric currents and magnetic materials.<br />
The magnetic field at any given point is specified by both a direction and a magnitude (or strength); as such it is a<br />
vector field. [1] The magnetic field is most commonly defined in terms of the Lorentz force it exerts on moving<br />
electric charges. There are two separate but closely related fields to which the name 'magnetic field' can refer: a<br />
magnetic B field and a magnetic H field.<br />
Magnetic fields are produced by moving electric charges and the intrinsic magnetic moments of elementary particles<br />
associated with a fundamental quantum property, their spin. In special relativity, electric and magnetic fields are two<br />
interrelated aspects of a single object, called the electromagnetic field tensor; the aspect of the electromagnetic field<br />
that is seen as a magnetic field is dependent on the reference frame of the observer. In quantum physics, the<br />
electromagnetic field is quantized and electromagnetic interactions result from the exchange of photons.<br />
Magnetic fields have had many uses in ancient and modern society. The Earth produces its own magnetic field,<br />
which is important in navigation. Rotating magnetic fields are utilized in both electric motors and generators.<br />
Magnetic forces give information about the charge carriers in a material through the Hall effect. The interaction of<br />
magnetic fields in electric devices such as transformers is studied in the discipline of magnetic circuits.<br />
History<br />
Although magnets and magnetism were<br />
known much earlier, one of the first<br />
descriptions of the magnetic field was<br />
produced in 1269 by the French scholar<br />
Petrus Peregrinus [2] who mapped out the<br />
magnetic field on the surface of a spherical<br />
magnet using iron needles. Noting that the<br />
resulting field lines crossed at two points he<br />
named those points 'poles' in analogy to<br />
Earth's poles. Almost three centuries later,<br />
William Gilbert of Colchester replicated<br />
Petrus Peregrinus' work and was the first to<br />
state explicitly that Earth itself was a<br />
magnet. Gilbert's great work De Magnete<br />
was published in 1600 and helped to<br />
establish the study of magnetism as a<br />
science.<br />
One of the first successful models of the<br />
magnetic field was developed in 1824 by<br />
One of the first drawings of a magnetic field, by René Descartes, 1644. It<br />
illustrated his theory that magnetism was caused by the circulation of tiny helical<br />
particles, "threaded parts", through threaded pores in magnets.<br />
Siméon-Denis Poisson (1781–1840). Poisson assumed that magnetism was due to 'magnetic charges' such that like<br />
'magnetic charges' repulse while opposites attract. The model he created is exactly analogous to modern<br />
electrostatics with a magnetic H-field being produced by 'magnetic charges' in the same way that an electric field<br />
E-field is produced by electric charges. It predicts the correct H-field for permanent magnets. It predicts the forces<br />
between magnets. And, it predicts the correct energy stored in the magnetic fields. [3]<br />
Three remarkable discoveries though, would challenge Poisson's model. First, in 1819, Hans Christian Oersted<br />
discovered that an electric current generates a magnetic field encircling it. Then, André-Marie Ampère showed that<br />
parallel wires having currents in the same direction attract one another. Finally Jean-Baptiste Biot and Félix Savart
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discovered the Biot–Savart law which correctly predicts the magnetic field around any current-carrying wire.<br />
Together, these discoveries suggested a model in which the magnetic B field of a material is produced by<br />
microscopic current loops. In this model, these current loops (called magnetic dipoles) would replace the dipoles of<br />
charge of the Poisson's model. [4] No magnetic charges are needed which has the additional benefit of explaining why<br />
magnetic charge can not be isolated; cutting a magnet in half does not result in two separate poles but in two separate<br />
magnets, each of which has both poles.<br />
The next decade saw two developments that help lay the foundation for the full theory of electromagnetism. In 1825,<br />
Ampère published his Ampère's law which like the Biot–Savart law correctly described the magnetic field generated<br />
by a steady current but was more general. And, in 1831, Michael Faraday showed that a changing magnetic field<br />
generates an encircling electric field and thereby demonstrated that electricity and magnetism are even more tightly<br />
knitted.<br />
Between 1861 and 1865, James Clerk Maxwell developed and published a set of Maxwell's equations which<br />
explained and united all of classical electricity and magnetism. The first set of these equations was published in a<br />
paper entitled On Physical Lines of Force in 1861. The mechanism that Maxwell proposed to underlie these<br />
equations in this paper was fundamentally incorrect, which is not surprising since it predated the modern<br />
understanding even of the atom. Yet, the equations were valid although incomplete. He completed the set of<br />
Maxwell's equations in his later 1865 paper A Dynamical Theory of the Electromagnetic Field and demonstrated the<br />
fact that light is an electromagnetic wave. Thus, he theoretically unified not only electricity and magnetism but light<br />
as well. This fact was then later confirmed experimentally by Heinrich Hertz in 1887.<br />
Even though the classical theory of electrodynamics was essentially complete with Maxwell's equations, the<br />
twentieth century saw a number of improvements and extensions to the theory. Albert Einstein, in his great paper of<br />
1905 that established relativity, showed that both the electric and magnetic fields are part of the same phenomena<br />
viewed from different reference frames. (See moving magnet and conductor problem for details about the thought<br />
experiment that eventually helped Albert Einstein to develop special relativity.) Finally, the emergent field of<br />
quantum mechanics was merged with electrodynamics to form quantum electrodynamics or QED.<br />
Definitions, units, and measurement<br />
Alternative names for the field B [5]<br />
• Magnetic flux density<br />
• Magnetic induction<br />
• Magnetic field<br />
[5] [6]<br />
Alternative names for the field H<br />
• Magnetic field intensity<br />
• Magnetic field strength<br />
• Magnetic field<br />
• Magnetizing field<br />
The term magnetic field is historically used to describe a magnetic H-field whereas other terms were used to describe<br />
a related magnetic B-field. Informally, and formally for some recent textbooks mostly in physics, the term 'magnetic<br />
field' is used to describe the magnetic B-field as well as or in place of H. [7] There are many alternative names for<br />
both (see sidebar to right). To avoid confusion, this article uses B-field and H-field for these fields, and uses<br />
magnetic field where either or both fields apply.<br />
The magnetic field can be defined in many equivalent ways based on the effects it has on its environment. For<br />
instance, a particle having an electric charge, q, and moving in a B-field with a velocity, v, experiences a force, F,<br />
called the Lorentz force. See Force on a charged particle below. Alternatively, the magnetic field can be defined in
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terms of the torque it produces on a magnetic dipole. See Torque on a magnet due to a B-field below.<br />
The H-field is defined as a modification of B due to magnetic fields produced by material media. See H and B inside<br />
and outside of magnetic materials below for the relationship between B and H. Outside of a material (i.e., in<br />
vacuum) the B and H fields are indistinguishable. (They only differ by a multiplicative constant.) Inside a material,<br />
though, they may differ in relative magnitude and even direction. Often, though, they differ only by a material<br />
dependent multiplicative constant.<br />
The B-field is measured in teslas in SI units and in gauss in cgs units. (1 tesla = 10,000 gauss). The SI unit of tesla is<br />
equivalent to (newton·second)/(coulomb·metre). [8] The H-field is measured in ampere-turn per metre (A/m) in SI<br />
units, and in oersteds (Oe) in cgs units. [9]<br />
Devices used to measure the local magnetic field are called magnetometers. Important classes of magnetometers<br />
include using a rotating coil, Hall effect magnetometers, NMR magnetometers, SQUID magnetometers, and fluxgate<br />
magnetometers. The magnetic fields of distant astronomical objects are measured through their effects on local<br />
charged particles. For instance, electrons spiraling around a field line produce synchrotron radiation which is<br />
detectable in radio waves.<br />
The smallest precision level for a magnetic field measurement [10] is on the order of attoteslas (10 −18 tesla); the<br />
largest magnetic field produced in a laboratory is 2,800 T (VNIIEF in Sarov, Russia, 1998). [11] The magnetic field of<br />
some astronomical objects such as magnetars are much higher; magnetars range from 0.1 to 100 GT (10 8 to<br />
10 11 T). [12] See orders of magnitude (magnetic field).<br />
Magnetic field lines<br />
Compasses reveal the direction of<br />
the local magnetic field. As seen<br />
here, the magnetic field points<br />
towards a magnet's south pole and<br />
away from its north pole.<br />
Mapping the magnetic field of an object is simple in principle. First, measure the<br />
strength and direction of the magnetic field at a large number of locations. Then,<br />
mark each location with an arrow (called a vector) pointing in the direction of the<br />
local magnetic field with a length proportional to the strength of the magnetic field.<br />
A simpler way to visualize the magnetic field is to 'connect' the arrows to form<br />
"magnetic field lines". Magnetic field lines make it much easier to visualize and<br />
understand the complex mathematical relationships underlying magnetic field. If<br />
done carefully, a field line diagram contains the same information as the vector<br />
field it represents. The magnetic field can be estimated at any point on a magnetic<br />
field line diagram (whether on a field line or not) using the direction and density of<br />
nearby magnetic field lines. [13] A higher density of nearby field lines indicates a<br />
stronger magnetic field.
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Various phenomena have the effect of "displaying" magnetic field lines<br />
as though the field lines are physical phenomena. For example, iron<br />
filings placed in a magnetic field line up to form lines that correspond<br />
to 'field lines'. Magnetic fields "lines" are also visually displayed in<br />
polar auroras, in which plasma particle dipole interactions create<br />
visible streaks of light that line up with the local direction of Earth's<br />
magnetic field. However, field lines are a visual and conceptual aid<br />
only and are no more real than (for example) the contour lines<br />
(constant altitude) on a topographic map. They do not exist in the<br />
actual field; a different choice of mapping scale could show twice as<br />
many "lines" or half as many.<br />
Field lines can be used as a qualitative tool to visualize magnetic<br />
forces. In ferromagnetic substances like iron and in plasmas, magnetic<br />
forces can be understood by imagining that the field lines exert a<br />
tension, (like a rubber band) along their length, and a pressure<br />
perpendicular to their length on neighboring field lines. 'Unlike' poles<br />
The direction of magnetic field lines represented<br />
by the alignment of iron filings sprinkled on<br />
paper placed above a bar magnet. The mutual<br />
attraction of opposite poles of the iron filings<br />
results in the formation of elongated clusters of<br />
filings along "field lines". The field is not<br />
precisely the same as around the isolated magnet;<br />
the magnetization of the filings alters the field<br />
somewhat.<br />
of magnets attract because they are linked by many field lines; 'like' poles repel because their field lines do not meet,<br />
but run parallel, pushing on each other.<br />
Most physical phenomena that "display" magnetic field lines do not include which direction along the lines that the<br />
magnetic field is in. A compass, though, reveals that magnetic field lines outside of a magnet point from the north<br />
pole (compass points away from north pole) to the south (compass points toward the south pole). The magnetic field<br />
of a straight current-carrying wire encircles the wire with a direction that depends on the direction of the current and<br />
that can be measured with a compass as well.<br />
B-field lines never end<br />
Field lines are a useful way to represent any vector field and often reveal sophisticated properties of fields quite<br />
simply. One important property of the B-field revealed this way is that magnetic B field lines neither start nor end<br />
(mathematically, B is a solenoidal vector field); a field line either extends to infinity or wraps around to form a<br />
closed curve. [14] To date no exception to this rule has been found. (See magnetic monopole below.)<br />
Magnetic field lines exit a magnet near its north pole and enter near its south pole, but inside the magnet B-field lines<br />
continue through the magnet from the south pole back to the north. [15] If a B-field line enters a magnet somewhere it<br />
has to leave somewhere else; it is not allowed to have an end point. Magnetic poles, therefore, always come in N and<br />
S pairs. Cutting a magnet in half results in two separate magnets each with both a north and a south pole.<br />
More formally, since all the magnetic field lines that enter any given region must also leave that region, subtracting<br />
the 'number' [16] of field lines that enter the region from the number that exit gives identically zero. Mathematically<br />
this is equivalent to:<br />
,<br />
where the integral is a surface integral over the closed surface S (a closed surface is one that completely surrounds a<br />
region with no holes to let any field lines escape). Since dA points outward, the dot product in the integral is positive<br />
for B-field pointing out and negative for B-field pointing in.<br />
There is also a corresponding differential form of this equation covered in Maxwell's equations below.
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H-field lines begin and end near magnetic poles<br />
Unlike B-field lines, which never end, the H-field lines due to a magnetic material begin in a region(s) of the magnet<br />
called the north pole pass through the magnet and/or outside of the magnet and ends in a different region of the<br />
material called the south pole. Near the north pole, therefore, all H-field lines point away from the north pole<br />
(whether inside the magnet or out) while near the south pole (whether inside the magnet or out) all H-field lines<br />
point toward the south pole. (The B-field lines, for comparison, form a closed loop going from south to north inside<br />
the magnet and from north to south outside the magnet)<br />
The H-field, therefore, is analogous to the electric field E which starts at a positive charge and ends at a negative<br />
charge. It is tempting, therefore, to model magnets in terms of magnetic charges localized near the poles.<br />
Unfortunately, this model is incorrect; for instance, it often fails when determining the magnetic field inside of<br />
magnets. (See "Non-uniform magnetic field causes like poles to repel and opposites to attract" below.)<br />
Outside a material, though, the H-field is identical to the B-field (to a multiplicative constant) so that in many cases<br />
the distinction can be ignored. This is particularly true for magnetic fields, such as those due to electric currents, that<br />
are not generated by magnetic materials.<br />
Magnetic monopole (hypothetical)<br />
A magnetic monopole is a hypothetical particle (or class of particles) that has, as its name suggests, only one<br />
magnetic pole (either a north pole or a south pole). In other words, it would possess a "magnetic charge" analogous<br />
to an electric charge. Magnetic field lines would start or end on magnetic monopoles, so if they exist, they would<br />
give exceptions to the rule that magnetic field lines neither start nor end.<br />
Modern interest in this concept stems from particle theories, notably Grand Unified Theories and superstring<br />
theories, that predict either the existence, or the possibility, of magnetic monopoles. These theories and others have<br />
inspired extensive efforts to search for monopoles. Despite these efforts, no magnetic monopole has been observed<br />
to date. [17]<br />
In recent research, materials known as spin ices can simulate monopoles, but do not contain actual monopoles.<br />
The magnetic field and permanent magnets<br />
Permanent magnets are objects that produce their own persistent magnetic fields. They are made of ferromagnetic<br />
materials, such as iron and nickel, that have been magnetized, and they have both a north and a south pole.<br />
Magnetic field of permanent magnets<br />
The magnetic field of permanent magnets can be quite complicated, especially near the magnet. The B field of a<br />
small [18] straight magnet is proportional to the magnet's strength (called its magnetic dipole moment m). The<br />
equations are non-trivial and also depend on the distance from the magnet and the orientation of the magnet. For<br />
simple magnets, m points in the direction of a line drawn from the south to the north pole of the magnet. Flipping a<br />
bar magnet is equivalent to rotating its m by 180 degrees.<br />
It is sometimes useful to model the force and torques between two magnets as due to magnetic poles repelling or<br />
attracting each other in the same manner as the Coulomb force between electric charges. In this model, a magnetic<br />
H-field is produced by magnetic charges that are 'smeared' around each pole. A north pole therefore feels a force in<br />
the direction of the H-field while the force on the south pole is opposite to the H-field.<br />
Unfortunately, the concept of poles of 'magnetic charge' does not accurately reflect what happens inside a magnet<br />
(see ferromagnetism). Magnetic charges do not exist. Magnetic poles cannot exist apart from each other; all magnets<br />
have north/south pairs which cannot be separated without creating two magnets each having a north/south pair.<br />
Finally, magnetic charge fails to account for magnetism that is produced by electric currents nor the force that a<br />
magnetic field applies to moving electric charges.
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The more physically correct description of magnetism involves atomic sized loops of current distributed throughout<br />
the magnet. [19]<br />
Non-uniform magnetic field causes like poles to repel and opposites to attract<br />
The force between two small magnets is quite complicated and depends on the strength and orientation of both<br />
magnets and the distance and direction of the magnets relative to each other. The force is particularly sensitive to<br />
rotations of the magnets due to magnetic torque. The force on each magnet depends on its magnetic moment and the<br />
magnetic field B [20] of the other.<br />
To understand the force between magnets and to generalize it to other cases, it is useful to examine the magnetic<br />
charge model given above (with the caveats given above as well). In this model, the H-field of the first magnet<br />
pushes and pulls on the magnetic charges near both poles of the second magnet. If the H-field due to the first magnet<br />
is the same at both poles of the second magnet then there is no net force on that magnet since the force is opposite<br />
for opposite poles. The magnetic field is not the same, though; the magnetic field is significantly stronger near the<br />
poles of a magnet. In this nonuniform magnetic field, each pole sees a different field and is subject to a different<br />
force. This difference in the two forces moves the magnet in the direction of increasing magnetic field and may also<br />
cause a net torque.<br />
This is a specific example of a general rule that magnets are attracted (or repulsed depending on the orientation of<br />
the magnet) into regions of higher magnetic field. Any non-uniform magnetic field whether caused by permanent<br />
magnets or by electric currents will exert a force on a small magnet in this way.<br />
Mathematically, the force on a small magnet having a magnetic moment m due to a magnetic field B is: [21]<br />
where the gradient ∇ is the change of the quantity m · B per unit distance and the direction is that of maximum<br />
increase of m · B. To understand this equation, note that the dot product m · B = mBcos(θ), where m and B represent<br />
the magnitude of the m and B vectors and θ is the angle between them. If m is in the same direction as B then the dot<br />
product is positive and the gradient points 'uphill' pulling the magnet into regions of higher B-field (more strictly<br />
larger m · B). This equation is strictly only valid for magnets of zero size, but is often a good approximation for not<br />
too large magnets. The magnetic force on larger magnets is determined by dividing them into smaller regions having<br />
their own m then summing up the forces on each of these regions.<br />
Torque on a magnet due to a B-field<br />
Magnetic torque on a magnet due to an external magnetic field can be observed by placing two magnets near each<br />
other while allowing one to rotate. Magnetic torque is used to drive simple electric motors. In one simple motor<br />
design, a magnet is fixed to a freely rotating shaft and subjected to a magnetic field from an array of electromagnets.<br />
By continuously switching the electric current through each of the electromagnets, thereby flipping the polarity of<br />
their magnetic fields, like poles are kept next to the rotor; the resultant torque is transferred to the shaft. See Rotating<br />
magnetic fields below.<br />
Magnetic torque τ tends to align a magnet's poles with the B-field lines (since m is in the direction of the poles this is<br />
equivalent to saying that it tends to align m in the same direction as B). This is why the magnetic needle of a<br />
compass points toward earth's north pole. By definition, the direction of the Earth's local magnetic field is the<br />
direction in which the north pole of a compass (or of any magnet) tends to point.<br />
Mathematically, the torque τ on a small magnet is proportional both to the applied B-field and to the magnetic<br />
moment m of the magnet:<br />
where × represents the vector cross product. Note that this equation includes all of the qualitative information<br />
included above. There is no torque on a magnet if m is in the same direction as B. (The cross product is zero for two
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vectors that are in the same direction.) Further, all other orientations feel a torque that twists them toward the<br />
direction of B.<br />
The magnetic field and electric currents<br />
Currents of electric charges both generate a magnetic field and feel a force due to magnetic B-fields.<br />
Magnetic field due to moving charges and electric currents<br />
All moving charged particles produce magnetic fields. Moving point<br />
charges, such as electrons, produce complicated but well known<br />
magnetic fields that depend on the charge, velocity, and acceleration of<br />
the particles. [22]<br />
Magnetic field lines form in concentric circles around a cylindrical<br />
current-carrying conductor, such as a length of wire. The direction of<br />
such a magnetic field can be determined by using the "right hand grip<br />
rule" (see figure at right). The strength of the magnetic field decreases<br />
with distance from the wire. (For an infinite length wire the strength<br />
decreases inversely proportional to the distance.)<br />
Bending a current-carrying wire into a loop concentrates the magnetic<br />
field inside the loop while weakening it outside. Bending a wire into<br />
multiple closely spaced loops to form a coil or "solenoid" enhances this<br />
effect. A device so formed around an iron core may act as an<br />
electromagnet, generating a strong, well-controlled magnetic field. An<br />
infinitely long cylindrical electromagnet has a uniform magnetic field<br />
inside, and no magnetic field outside. A finite length electromagnet<br />
Right hand grip rule: current (I) flowing through<br />
a conductor in the direction indicated by the<br />
white arrow produces a magnetic field (B) around<br />
the conductor as shown by the red arrows.<br />
Solenoid<br />
produces a magnetic field that looks similar to that produced by a uniform permanent magnet, with its strength and<br />
polarity determined by the current flowing through the coil.<br />
The magnetic field generated by a steady current (a constant flow of electric charges in which charge is neither<br />
accumulating nor depleting at any point) [23] is described by the Biot–Savart law:<br />
where the integral sums over the wire length where vector dℓ is the direction of the current, μ 0 is the magnetic<br />
constant, r is the distance between the location of dℓ and the location at which the magnetic field is being calculated,<br />
and r̂ is a unit vector in the direction of r.<br />
A slightly more general [24] [25] way of relating the current to the B-field is through Ampère's law:<br />
where the line integral is over any arbitrary loop and is the current enclosed by that loop. Ampère's law is<br />
enc<br />
always valid for steady currents and can be used to calculate the B-field for certain highly symmetric situations such<br />
as an infinite wire or an infinite solenoid.<br />
In a modified form that accounts for time varying electric fields, Ampère's law is one of four Maxwell's equations<br />
that describe electricity and magnetism.
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Force on moving charges and current<br />
Force on a charged particle<br />
A charged particle moving in a B-field experiences a<br />
sideways force that is proportional to the strength of<br />
the magnetic field, the component of the velocity that<br />
is perpendicular to the magnetic field and the charge<br />
of the particle. This force is known as the Lorentz<br />
force, and is given by<br />
Charged particle drifts in a magnetic field with (A) no net force, (B)<br />
an electric field, E, (C) a charge independent force, F (e.g. gravity), and<br />
(D) an inhomogeneous magnetic field, grad H.
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Magnetic force on charged particles and currents, shown in 3d. The electric<br />
current shown here is conventional, the real current would be a charge of –q<br />
flowing in exactly the opposite direction. Only one charge carrier is shown to<br />
prevent cluttering the diagram. r 1 is the position of entry into the field B, r 2 is<br />
the exit. The vector l is the integral (sum) of all all infinitesimal vectors dr<br />
from r 1 to r 2 .<br />
where F is the force, q is the electric charge of the particle, v is the instantaneous velocity of the particle, and B is the<br />
magnetic field (in teslas).<br />
The Lorentz force is always perpendicular to both the velocity of the particle and the magnetic field that created it.<br />
When a charged particle moves in a static magnetic field it will trace out a helical path in which the helix axis is<br />
parallel to the magnetic field and in which the speed of the particle will remain constant. Because the magnetic force<br />
is always perpendicular to the motion, the magnetic field can do no work on an isolated charge. It can only do work<br />
indirectly, via the electric field generated by a changing magnetic field. It is often claimed that the magnetic force<br />
can do work to a non-elementary magnetic dipole, or to charged particles whose motion is constrained by other<br />
forces, but this is incorrect [26] because the work in those cases is performed by the electric forces of the charges<br />
deflected by the magnetic field.<br />
Force on current-carrying wire<br />
The force on a current carrying wire is similar to that of a moving charge as expected since a charge carrying wire is<br />
a collection of moving charges. A current carrying wire feels a sideways force in the presence of a magnetic field.<br />
The Lorentz force on a macroscopic current is often referred to as the Laplace force. Consider a conductor of length<br />
l and area of cross section A and has charge q which is due to electric current i .If a conductor is placed in a magnetic<br />
field of induction B which makes an angle θ (theta) with the velocity of charges in the conductor which has i current
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flowing in it. then force exerted due to small particle q is<br />
then for n number of charges it has<br />
then force exerted on the body is<br />
but<br />
that is<br />
The right-hand rule: Pointing the thumb of the right hand in the<br />
direction of the conventional current and the fingers in the direction<br />
of the B-field the force on the current points out of the palm. The<br />
force is reversed for a negative charge.<br />
Direction of force<br />
The direction of force on a charge or a current can be<br />
determined by a mnemonic known as the right-hand<br />
rule. See the figure on the left. Using the right hand<br />
and pointing the thumb in the direction of the moving<br />
positive charge or positive current and the fingers in the<br />
direction of the magnetic field the resulting force on the<br />
charge points outwards from the palm. The force on a<br />
negatively charged particle is in the opposite direction.<br />
If both the speed and the charge are reversed then the<br />
direction of the force remains the same. For that reason<br />
a magnetic field measurement (by itself) cannot<br />
distinguish whether there is a positive charge moving to<br />
the right or a negative charge moving to the left. (Both of these cases produce the same current.) On the other hand, a<br />
magnetic field combined with an electric field can distinguish between these, see Hall effect below.<br />
An alternative mnemonic to the right hand rule is Fleming's left hand rule.<br />
H and B inside and outside of magnetic materials<br />
The formulas derived for the magnetic field above are correct when dealing with the entire current. A magnetic<br />
material placed inside a magnetic field, though, generates its own bound current which can be a challenge to<br />
calculate. (This bound current is due to the sum of atomic sized current loops and the spin of the subatomic particles<br />
such as electrons that make up the material.) The H-field as defined above helps factor out this bound current; but in<br />
order to see how, it helps to introduce the concept of magnetization first.
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Magnetization<br />
The magnetization field M represents how strongly a region of material is magnetized. For a uniform magnet, the<br />
magnetization is equal to its magnetic moment, m, divided by its volume. More generally, the magnetization of a<br />
region is defined as net magnetic dipole moment per unit volume of that region. Since the SI unit of magnetic<br />
moment is ampere-turn meter 2 , the SI unit of magnetization M is ampere-turn per meter which is identical to that of<br />
the H-field.<br />
The magnetization M field of a region points in the direction of the average magnetic dipole moment in the region<br />
and is in the same direction as the local B-field it produces. Therefore, M field lines move from near the south pole<br />
of a magnet to near its north. Unlike B, magnetization only exists inside a magnetic material. Therefore,<br />
magnetization field lines begin and end near magnetic poles.<br />
The physically correct way to represent magnetization is to add all of the currents of the dipole moments that<br />
produce the magnetization. See Magnetic dipoles below and magnetic poles vs. atomic currents for more<br />
information. The resultant current is called bound current and is the source of the magnetic field due to the magnet.<br />
Given the definition of the magnetic dipole, the magnetization field follows a similar law to that of Ampere's law:<br />
[27]<br />
where the integral is a line integral over any closed loop and I b is the 'bound current' enclosed by that closed loop.<br />
It is also possible to model the magnetization in terms of magnetic charge in which magnetization begins at and ends<br />
at bound 'magnetic charges'. If a given region, therefore, has a net positive 'magnetic charge' then it will have more<br />
magnetic field lines entering it than leaving it. Mathematically this is equivalent to:<br />
,<br />
where the integral is a closed surface integral over the closed surface S and q M is the 'magnetic charge' (in units of<br />
magnetic flux) enclosed by S. (A closed surface completely surrounds a region with no holes to let any field lines<br />
escape.) The negative sign occurs because, like B inside a magnet, the magnetization field moves from south to<br />
north.<br />
H-field and magnetic materials<br />
The H-field is defined as:<br />
(definition of H in SI units)<br />
With this definition, Ampere's law becomes:<br />
where I f represents the 'free current' enclosed by the loop so that the line integral of H does not depend at all on the<br />
bound currents. [28] For the differential equivalent of this equation see Maxwell's equations. Ampere's law leads to the<br />
boundary condition<br />
where K f is the surface free current density. [29]<br />
Similarly, a surface integral of H over any closed surface is independent of the free currents and picks out the<br />
'magnetic charges' within that closed surface:
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which does not depend on the free currents.<br />
The H-field, therefore, can be separated into two [30] independent parts:<br />
where H 0 is the applied magnetic field due only to the free currents and H d is the demagnetizing field due only to the<br />
bound currents.<br />
The magnetic H-field, therefore, re-factors the bound current in terms of 'magnetic charges'. The H field lines loop<br />
only around 'free current' and, unlike the magnetic B field, begins and ends at near magnetic poles as well.<br />
Magnetism<br />
Most materials respond to an applied B-field by producing their own magnetization M and therefore their own<br />
B-field. Typically, the response is very weak and exists only when the magnetic field is applied. The term<br />
'magnetism' describes how materials respond on the microscopic level to an applied magnetic field and is used to<br />
categorize the magnetic phase of a material. Materials are divided into groups based upon their magnetic behavior:<br />
• Diamagnetic materials [31] produce a magnetization that opposes the magnetic field.<br />
• Paramagnetic materials [31] produce a magnetization in the same direction as the applied magnetic field.<br />
[32] [33]<br />
• Ferromagnetic materials and the closely related ferrimagnetic materials and antiferromagnetic materials<br />
can have a magnetization independent of an applied B-field with a complex relationship between the two fields.<br />
• Superconductors (and ferromagnetic superconductors) [34] [35] are materials that are characterized by perfect<br />
conductivity below a critical temperature and magnetic field. They also are highly magnetic and can be perfect<br />
diamagnets below a lower critical magnetic field. Superconductors often have a broad range of temperatures and<br />
magnetic fields (the so named mixed state) for which they exhibit a complex hysteretic dependence of M on B.<br />
In the case of paramagnetism and diamagnetism, the magnetization M is often proportional to the applied magnetic<br />
field such that:<br />
where μ is a material dependent parameter called the permeability. In some cases the permeability may be a second<br />
rank tensor so that H may not point in the same direction as B. These relations between B and H are examples of<br />
constitutive equations. However, superconductors and ferromagnets have a more complex B to H relation, see<br />
magnetic hysteresis.<br />
Energy stored in magnetic fields<br />
Energy is needed to generate a magnetic field both to work against the electric field that a changing magnetic field<br />
creates and to change the magnetization of any material within the magnetic field. For non-dispersive materials this<br />
same energy is released when the magnetic field is destroyed so that this energy can be modeled as being stored in<br />
the magnetic field.<br />
For linear, non-dispersive, materials (such that B = μH where μ is frequency-independent), the energy density is:<br />
If there are no magnetic materials around then μ can be replaced by μ 0 . The above equation cannot be used for<br />
nonlinear materials, though; a more general expression given below must be used.<br />
In general, the incremental amount of work per unit volume δW needed to cause a small change of magnetic field δB<br />
is:<br />
Once the relationship between H and B is known this equation is used to determine the work needed to reach a given<br />
magnetic state. For hysteretic materials such as ferromagnets and superconductors the work needed will also depend
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on how the magnetic field is created. For linear non-dispersive materials, though, the general equation leads directly<br />
to the simpler energy density equation given above.<br />
Electromagnetism: the relationship between magnetic and electric fields<br />
Faraday's Law: Electric force due to a changing B-field<br />
A changing magnetic field, such as a magnet moving through a conducting coil, generates an electric field (and<br />
therefore tends to drive a current in the coil). This is known as Faraday's law and forms the basis of many electrical<br />
generators and electric motors.<br />
Mathematically, Faraday's law is:<br />
where is the electromotive force (or EMF, the voltage generated around a closed loop) and Φ m is the magnetic<br />
flux—the product of the area times the magnetic field normal to that area. (This definition of magnetic flux is why B<br />
is often referred to as magnetic flux density.)<br />
The negative sign is necessary and represents the fact that any current generated by a changing magnetic field in a<br />
coil produces a magnetic field that opposes the change in the magnetic field that induced it. This phenomenon is<br />
known as Lenz's Law.<br />
This integral formulation of Faraday's law can be converted [36] into a differential form, which applies under slightly<br />
different conditions. This form is covered as one of Maxwell's equations below.<br />
Maxwell's correction to Ampère's Law: The magnetic field due to a changing electric field<br />
Similar to the way that a changing magnetic field generates an electric field, a changing electric field generates a<br />
magnetic field. This fact is known as 'Maxwell's correction to Ampère's law'. Maxwell's correction to Ampère's<br />
Law bootstrap together with Faraday's law of induction to form electromagnetic waves, such as light. Thus, a<br />
changing electric field generates a changing magnetic field which generates a changing electric field again.<br />
Maxwell's correction to Ampère law is applied as an additive term to Ampere's law given above. This additive term<br />
is proportional to the time rate of change of the electric flux and is similar to Faraday's law above but with a different<br />
and positive constant out front. (The electric flux through an area is proportional to the area times the perpendicular<br />
part of the electric field.)<br />
This full Ampère law including the correction term is known as the Maxwell–Ampère equation. It is not commonly<br />
given in integral form because the effect is so small that it can typically be ignored in most cases where the integral<br />
form is used. The Maxwell term is critically important in the creation and propagation of electromagnetic waves.<br />
These, though, are usually described using the differential form of this equation given below.
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Maxwell's equations<br />
Like all vector fields the B-field has two important mathematical properties that relates it to its sources. (For<br />
magnetic fields the sources are currents and changing electric fields.) These two properties, along with the two<br />
corresponding properties of the electric field, make up Maxwell's Equations. Maxwell's Equations together with the<br />
Lorentz force law form a complete description of classical electrodynamics including both electricity and<br />
magnetism.<br />
The first property is the divergence of a vector field A, ∇ · A which represents how A 'flows' outward from a given<br />
point. As discussed above, a B-field line never starts or ends at a point but instead forms a complete loop. This is<br />
mathematically equivalent to saying that the divergence of B is zero. (Such vector fields are called solenoidal vector<br />
fields.) This property is called Gauss's law for magnetism and is equivalent to the statement that there are no<br />
magnetic charges or magnetic monopoles. The electric field on the other hand begins and ends at electric charges so<br />
that its divergence is non-zero and proportional to the charge density (See Gauss's law).<br />
The second mathematical property is called the curl, such that ∇ × A represents how A curls or 'circulates' around a<br />
given point. The result of the curl is called a 'circulation source'. The equations for the curl of B and of E are called<br />
the Ampère–Maxwell equation and Faraday's law respectively. They represent the differential forms of the integral<br />
equations given above.<br />
The complete set of Maxwell's equations then are:<br />
where J = complete microscopic current density and ρ is the charge density.<br />
Magnetic field, like all pseudovectors, changes<br />
sign when reflected in a mirror: When a loop of<br />
wire (black), carrying a current is reflected in a<br />
mirror (dotted line), the magnetic field it<br />
generates (blue) is not simply reflected in the<br />
mirror; rather, it is reflected and reversed.<br />
Technically, B is a pseudovector (also called an axial vector) due to being defined by a vector cross product.<br />
Because of the right-hand rule, a current-carrying loop viewed in a mirror results in a B vector that is both<br />
mirror-imaged and flipped in orientation, whereas an ordinary vector (e.g., velocity) is mirror-imaged only. (See<br />
diagram to right.)<br />
As discussed above, materials respond to an applied electric E field and an applied magnetic B field by producing<br />
their own internal 'bound' charge and current distributions that contribute to E and B but are difficult to calculate. To<br />
circumvent this problem the auxiliary H and D fields are defined so that Maxwell's equations can be re-factored in<br />
terms of the free current density J f and free charge density ρ f :
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These equations are not any more general than the original equations (if the 'bound' charges and currents in the<br />
material are known'). They also need to be supplemented by the relationship between B and H as well as that<br />
between E and D. On the other hand, for simple relationships between these quantities this form of Maxwell's<br />
equations can circumvent the need to calculate the bound charges and currents.<br />
Electric and magnetic fields: different aspects of the same phenomenon<br />
According to the special theory of relativity, the partition of the electromagnetic force into separate electric and<br />
magnetic components is not fundamental, but varies with the observational frame of reference: An electric force<br />
perceived by one observer may be perceived by another (in a different frame of reference) as a magnetic force, or a<br />
mixture of electric and magnetic forces.<br />
Formally, special relativity combines the electric and magnetic fields into a rank-2 tensor, called the<br />
electromagnetic tensor. Changing reference frames mixes these components. This is analogous to the way that<br />
special relativity mixes space and time into spacetime, and mass, momentum and energy into four-momentum.<br />
Magnetic vector potential<br />
In advanced topics such as quantum mechanics and relativity it is often easier to work with a potential formulation of<br />
electrodynamics rather than in terms of the electric and magnetic fields. In this representation, the vector potential,<br />
A, and the scalar potential, φ, are defined such that:<br />
The vector potential A may be interpreted as a generalized potential momentum per unit charge [37] just as φ is<br />
interpreted as a generalized potential energy per unit charge.<br />
Maxwell's equations when expressed in terms of the potentials can be cast into a form that agrees with special<br />
relativity with little effort. [38] In relativity A together with φ forms the four-potential analogous to the<br />
four-momentum which combines the momentum and energy of a particle. Using the four potential instead of the<br />
electromagnetic tensor has the advantage of being much simpler; further it can be easily modified to work with<br />
quantum mechanics.
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Quantum electrodynamics<br />
In modern physics, the electromagnetic field is understood to be not a classical field, but rather a quantum field; it is<br />
represented not as a vector of three numbers at each point, but as a vector of three quantum operators at each point.<br />
The most accurate modern description of the electromagnetic interaction (and much else) is Quantum<br />
electrodynamics (QED), [39] which is incorporated into a more complete theory known as the "Standard Model of<br />
particle physics".<br />
In QED, the magnitude of the electromagnetic interactions between charged particles (and their antiparticles) is<br />
computed using perturbation theory; these rather complex formulas have a remarkable pictorial representation as<br />
Feynman diagrams in which virtual photons are exchanged.<br />
Predictions of QED agree with experiments to an extremely high degree of accuracy: currently about 10 −12 (and<br />
limited by experimental errors); for details see precision tests of QED. This makes QED one of the most accurate<br />
physical theories constructed thus far.<br />
All equations in this article are in the classical approximation, which is less accurate than the quantum description<br />
mentioned here. However, under most everyday circumstances, the difference between the two theories is negligible.<br />
Important uses and examples of magnetic field<br />
Earth's magnetic field<br />
The Earth's magnetic field is thought to be produced by convection currents in the outer liquid of Earth's core. The<br />
Dynamo theory proposes that these movements produce electric currents which, in turn, produce the magnetic<br />
field. [40]<br />
The presence of this field causes a compass, placed anywhere within it, to rotate so that the "north pole" of the<br />
magnet in the compass points roughly north, toward Earth's north magnetic pole. This is the traditional definition of<br />
the "north pole" of a magnet, although other equivalent definitions are also possible.<br />
One confusion that arises from this definition is that, if<br />
Earth itself is considered as a magnet, the south pole of<br />
that magnet would be the one nearer the north<br />
magnetic pole, and vice-versa [41] (opposite poles<br />
attract, so the north pole of the compass magnet is<br />
attracted to the south pole of Earth's interior magnet).<br />
The north magnetic pole is so-named not because of<br />
the polarity of the field there but because of its<br />
geographical location. The north and south poles of a<br />
permanent magnet are so-called because they are<br />
"north-seeking" and "south-seeking", respectively. [42]<br />
The figure to the right is a sketch of Earth's magnetic<br />
field represented by field lines. For most locations, the<br />
magnetic field has a significant up/down component in<br />
addition to the North/South component. (There is also<br />
an East/West component; Earth's magnetic poles do<br />
not coincide exactly with Earth's geological pole.) The<br />
magnetic field can be visualised as a bar magnet buried<br />
deep in Earth's interior.<br />
A sketch of Earth's magnetic field representing the source of the<br />
field as a magnet. The geographic north pole of Earth is near the top<br />
of the diagram, the south pole near the bottom. The south pole of that<br />
magnet is deep in Earth's interior below Earth's North Magnetic Pole.<br />
Earth's magnetic field is not constant — the strength of the field and the location of its poles vary. Moreover, the<br />
poles periodically reverse their orientation in a process called geomagnetic reversal. The most recent reversal
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occurred 780,000 years ago.<br />
Rotating magnetic fields<br />
The rotating magnetic field is a key principle in the operation of alternating-current motors. A permanent magnet in<br />
such a field rotates so as to maintain its alignment with the external field. This effect was conceptualized by Nikola<br />
Tesla, and later utilized in his, and others', early AC (alternating-current) electric motors.<br />
A rotating magnetic field can be constructed using two orthogonal coils with 90 degrees phase difference in their AC<br />
currents. However, in practice such a system would be supplied through a three-wire arrangement with unequal<br />
currents.<br />
This inequality would cause serious problems in standardization of the conductor size and so, in order to overcome<br />
it, three-phase systems are used where the three currents are equal in magnitude and have 120 degrees phase<br />
difference. Three similar coils having mutual geometrical angles of 120 degrees create the rotating magnetic field in<br />
this case. The ability of the three-phase system to create a rotating field, utilized in electric motors, is one of the main<br />
reasons why three-phase systems dominate the world's electrical power supply systems.<br />
Because magnets degrade with time, synchronous motors use DC voltage fed rotor windings which allows the<br />
excitation of the machine to be controlled and induction motors use short-circuited rotors (instead of a magnet)<br />
following the rotating magnetic field of a multicoiled stator. The short-circuited turns of the rotor develop eddy<br />
currents in the rotating field of the stator, and these currents in turn move the rotor by the Lorentz force.<br />
In 1882, Nikola Tesla identified the concept of the rotating magnetic field. In 1885, Galileo Ferraris independently<br />
researched the concept. In 1888, Tesla gained U.S. Patent 381968 [43] for his work. Also in 1888, Ferraris published<br />
his research in a paper to the Royal Academy of Sciences in Turin.<br />
Hall effect<br />
The charge carriers of a current carrying conductor placed in a transverse magnetic field experience a sideways<br />
Lorentz force; this results in a charge separation in a direction perpendicular to the current and to the magnetic field.<br />
The resultant voltage in that direction is proportional to the applied magnetic field. This is known as the 'Hall effect'.<br />
The Hall effect is often used to measure the magnitude of a magnetic field. It is used as well to find the sign of the<br />
dominant charge carriers in materials such as semiconductors (negative electrons or positive holes).<br />
Magnetic circuits<br />
An important use of H is in magnetic circuits where inside a linear material B = μ H. Here, μ is the magnetic<br />
permeability of the material. This result is similar in form to Ohm's law J = σ E, where J is the current density, σ is<br />
the conductance and E is the electric field. Extending this analogy, the counterpart to the macroscopic Ohm's law ( I<br />
= V ⁄ R ) is:<br />
where is the magnetic flux in the circuit, is the magnetomotive force applied to<br />
the circuit, and is the reluctance of the circuit. Here the reluctance is a quantity similar in nature to<br />
resistance for the flux.<br />
Using this analogy it is straight-forward to calculate the magnetic flux of complicated magnetic field geometries, by<br />
using all the available techniques of circuit theory.
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Magnetic field shape descriptions<br />
• An azimuthal magnetic field is one that runs east-west.<br />
• A meridional magnetic field is one that runs north-south. In the<br />
solar dynamo model of the Sun, differential rotation of the solar<br />
plasma causes the meridional magnetic field to stretch into an<br />
azimuthal magnetic field, a process called the omega-effect. The<br />
reverse process is called the alpha-effect. [44]<br />
• A dipole magnetic field is one seen around a bar magnet or around<br />
a charged elementary particle with nonzero spin.<br />
• A quadrupole magnetic field is one seen, for example, between the<br />
poles of four bar magnets. The field strength grows linearly with the<br />
radial distance from its longitudinal axis.<br />
• A solenoidal magnetic field is similar to a dipole magnetic field,<br />
except that a solid bar magnet is replaced by a hollow<br />
electromagnetic coil magnet.<br />
• A toroidal magnetic field occurs in a doughnut-shaped coil, the<br />
Schematic quadrupole magnet ("four-pole")<br />
magnetic field. There are four steel pole tips, two<br />
opposing magnetic north poles and two opposing<br />
magnetic south poles.<br />
electric current spiraling around the tube-like surface, and is found, for example, in a tokamak.<br />
• A poloidal magnetic field is generated by a current flowing in a ring, and is found, for example, in a tokamak.<br />
• A radial magnetic field is one in which the field lines are directed from the center outwards, similar to the spokes<br />
in a bicycle wheel. An example can be found in a loudspeaker transducers (driver). [45]<br />
• A helical magnetic field is corkscrew-shaped, and sometimes seen in space plasmas such as the Orion Molecular<br />
Cloud. [46]<br />
Magnetic dipoles<br />
The magnetic field of a magnetic dipole is depicted on the right. From<br />
outside, the ideal magnetic dipole is identical to that of an ideal electric<br />
dipole of the same strength. Unlike the electric dipole, a magnetic<br />
dipole is properly modeled as a current loop having a current I and an<br />
area a. Such a current loop has a magnetic moment of:<br />
where the direction of m is perpendicular to the area of the loop and<br />
depends on the direction of the current using the right-hand rule. An<br />
ideal magnetic dipole is modeled as a real magnetic dipole whose area<br />
a has been reduced to zero and its current I increased to infinity such<br />
that the product m = Ia is finite. In this model it is easy to see the<br />
connection between angular momentum and magnetic moment which<br />
is the basis of the Einstein-de Haas effect "rotation by magnetization"<br />
and its inverse, the Barnett effect or "magnetization by rotation". [47]<br />
Magnetic field lines around a ”magnetostatic<br />
dipole” pointing to the right.<br />
Rotating the loop faster (in the same direction) increases the current and therefore the magnetic moment, for<br />
example.<br />
It is sometimes useful to model the magnetic dipole similar to the electric dipole with two equal but opposite<br />
magnetic charges (one south the other north) separated by distance d. This model produces an H-field not a B-field.<br />
Such a model is deficient, though, both in that there are no magnetic charges and in that it obscures the link between<br />
electricity and magnetism. Further, as discussed above it fails to explain the inherent connection between angular<br />
momentum and magnetism.
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Notes<br />
[1] Technically, a magnetic field is a pseudo vector; pseudo-vectors, which also include torque and rotational velocity, are similar to vectors<br />
except that they remain unchanged when the coordinates are inverted.<br />
[2] His Epistola Petri Peregrini de Maricourt ad Sygerum de Foucaucourt Militem de Magnete, which is often shortened to Epistola de magnete,<br />
is dated 1269 C.E.<br />
[3] By the definition of magnetization, in this model, and in analogy to the physics of springs, the work done per unit volume, in stretching and<br />
twisting the bonds between magnetic charge to increment the magnetization by μ 0 δM is W = H · μ 0 δM. In this model, B = μ 0 (H + M ) is an<br />
effective magnetization which includes the H-field term to account for the energy of setting up the magnetic field in a vacuum. Therefore the<br />
total energy density increment needed to increment the magnetic field is W = H · δB.<br />
[4] It is a remarkable fact that from the 'outside' the field of a dipole of magnetic charge has the exact same form as that of an elementary current<br />
loop called a magnetic dipole. It is therefore only for the physics of magnetism 'inside' of magnetic material that the two models differ.<br />
[5] Electromagnetics, by Rothwell and Cloud, p23 (http:/ / books. google. com/ books?id=jCqv1UygjA4C& pg=PA23)<br />
[6] R.P. Feynman, R.B. Leighton, M. Sands (1963). The Feynman Lectures on Physics, volume 2.<br />
[7] Edward Purcell, in Electricity and Magnetism, McGraw-Hill, 1963, writes, Even some modern writers who treat B as the primary field feel<br />
obliged to call it the magnetic induction because the name magnetic field was historically preempted by H. This seems clumsy and pedantic. If<br />
you go into the laboratory and ask a physicist what causes the pion trajectories in his bubble chamber to curve, he'll probably answer<br />
"magnetic field", not "magnetic induction." You will seldom hear a geophysicist refer to the Earth's magnetic induction, or an astrophysicist<br />
talk about the magnetic induction of the galaxy. We propose to keep on calling B the magnetic field. As for H, although other names have<br />
been invented for it, we shall call it "the field H" or even "the magnetic field H." In a similar vein, M Gerloch (1983). Magnetism and<br />
Ligand-field Analysis (http:/ / books. google. com/ ?id=Ovo8AAAAIAAJ& pg=PA110). Cambridge University Press. p. 110.<br />
ISBN 0521249392. . says: "So we may think of both B and H as magnetic fields, but drop the word 'magnetic' from H so as to maintain the<br />
distinction ... As Purcell points out, 'it is only the names that give trouble, not the symbols'."<br />
[8] This can be seen from the magnetic part of the Lorentz force law F mag = (qvB).<br />
[9] Magnetic Field Strength Converter (http:/ / www. unitconversion. org/ unit_converter/ magnetic-field-strength. html), UnitConversion.org.<br />
[10] "Gravity Probe B Executive Summary" (http:/ / www. nasa. gov/ pdf/ 168808main_gp-b_pfar_cvr-pref-execsum. pdf). pp. 10,21. .<br />
[11] "With record magnetic fields to the 21st Century" (http:/ / ieeexplore. ieee. org/ xpl/ freeabs_all. jsp?arnumber=823621). IEEE Xplore. .<br />
[12] Kouveliotou, C.; Duncan, R. C.; Thompson, C. (February 2003). " Magnetars (http:/ / solomon. as. utexas. edu/ ~duncan/ sciam. pdf)".<br />
Scientific American; Page 36.<br />
[13] The use of iron filings to display a field presents something of an exception to this picture; the filings alter the magnetic field so that it is<br />
much larger along the "lines" of iron, due to the large permeability of iron relative to air.<br />
[14] Magnetic field lines may also wrap around and around without closing but also without ending. These more complicated non-closing<br />
non-ending magnetic field lines are moot, though, since the magnetic field of objects that produce them are calculated by adding the magnetic<br />
fields of 'elementary parts' having magnetic field lines that do form closed curves or extend to infinity.<br />
[15] To see that this must be true imagine placing a compass inside a magnet. There, the north pole of the compass points toward the north pole<br />
of the magnet since magnets stacked on each other point in the same direction.<br />
[16] As discussed above, magnetic field lines are primarily a conceptual tool used to represent the mathematics behind magnetic fields. The total<br />
'number' of field lines is dependent on how the field lines are drawn. In practice, integral equations such as the one that follows in the main<br />
text are used instead.<br />
[17] Two experiments produced candidate events that were initially interpreted as monopoles, but these are now regarded to be inconclusive. For<br />
details and references, see magnetic monopole.<br />
[18] Here 'small' means that the observer is sufficiently far away that it can be treated as being infinitesimally small. 'Larger' magnets need to<br />
include more complicated terms in the expression and depend on the entire geometry of the magnet not just m.<br />
[19] Griffiths, David J. (1999). Introduction to Electrodynamics (3rd ed.). Prentice Hall. pp. 255–8. ISBN 0-13-805326-X. OCLC 40251748.<br />
[20] Either B or H may be used for the magnetic field outside of the magnet.<br />
[21] See Eq. 11.42 in E. Richard Cohen, David R. Lide, George L. Trigg (2003). AIP physics desk reference (http:/ / books. google. com/<br />
?id=JStYf6WlXpgC& pg=PA381) (3 ed.). Birkhäuser. p. 381. ISBN 0387989730. .<br />
[22] Griffiths, David J. (1999). Introduction to Electrodynamics (3rd ed.). Prentice Hall. p. 438. ISBN 0-13-805326-X. OCLC 40251748.<br />
[23] In practice, the Biot–Savart law and other laws of magnetostatics are often used even when the currents are changing in time as long as it is<br />
not changing too quickly. It is often used, for instance, for standard household currents which oscillate sixty times per second.<br />
[24] Griffiths, David J. (1999). Introduction to Electrodynamics (3rd ed.). Prentice Hall. pp. 222–225. ISBN 0-13-805326-X. OCLC 40251748.<br />
[25] The Biot–Savart law contains the additional restriction (boundary condition) that the B-field must go to zero fast enough at infinity. It also<br />
depends on the divergence of B being zero, which is always valid. (There are no magnetic charges.)<br />
[26] Deissler, R.J. (2008). "Dipole in a magnetic field, work, and quantum spin" (http:/ / academic. csuohio. edu/ deissler/<br />
PhysRevE_77_036609. pdf). Physical Review E 77 (3, pt 2): 036609. Bibcode 2008PhRvE..77c6609D. doi:10.1103/PhysRevE.77.036609.<br />
PMID 18517545. .<br />
[27] Griffiths, David J. (1999). Introduction to Electrodynamics (3rd ed.). Prentice Hall. pp. 266–8. ISBN 0-13-805326-X. OCLC 40251748.<br />
[28] John Clarke Slater, Nathaniel Herman Frank (1969). Electromagnetism (http:/ / books. google. com/ ?id=GYsphnFwUuUC& pg=PA69)<br />
(first published in 1947 ed.). Courier Dover Publications. p. 69. ISBN 0486622630. .
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Magnetic field 52<br />
[29] David Griffiths. Introduction to Electrodynamics (3rd 1999 ed.). p. 332.<br />
[30] A third term is needed for changing electric fields and polarization currents; this displacement current term is covered in Maxwell's<br />
equations below.<br />
[31] RJD Tilley (2004). Understanding Solids (http:/ / books. google. com/ ?id=ZVgOLCXNoMoC& pg=PA368). Wiley. p. 368.<br />
ISBN 0470852755. .<br />
[32] Sōshin Chikazumi, Chad D. Graham (1997). Physics of ferromagnetism (http:/ / books. google. com/ ?id=AZVfuxXF2GsC&<br />
printsec=frontcover) (2 ed.). Oxford University Press. p. 118. ISBN 0198517769. .<br />
[33] Amikam Aharoni (2000). Introduction to the theory of ferromagnetism (http:/ / books. google. com/ ?id=9RvNuIDh0qMC& pg=PA27) (2<br />
ed.). Oxford University Press. p. 27. ISBN 0198508085. .<br />
[34] M Brian Maple et al. (2008). "Unconventional superconductivity in novel materials" (http:/ / books. google. com/ ?id=PguAgEQTiQwC&<br />
pg=PA640). In K. H. Bennemann, John B. Ketterson. Superconductivity. Springer. p. 640. ISBN 3540732527. .<br />
[35] Naoum Karchev (2003). "Itinerant ferromagnetism and superconductivity" (http:/ / books. google. com/ ?id=3AFo_yxBkD0C& pg=PA169).<br />
In Paul S. Lewis, D. Di (CON) Castro. Superconductivity research at the leading edge. Nova Publishers. p. 169. ISBN 1590338618. .<br />
[36] A complete expression for Faraday's law of induction in terms of the electric E and magnetic fields can be written as:<br />
where ∂Σ(t) is the moving closed path<br />
bounding the moving surface Σ(t), and dA is an element of surface area of Σ(t). The first integral calculates the work done moving a charge a<br />
distance dℓ based upon the Lorentz force law. In the case where the bounding surface is stationary, the Kelvin–Stokes theorem can be used to<br />
show this equation is equivalent to the Maxwell–Faraday equation.<br />
[37] E. J. Konopinski (1978). "What the electromagnetic vector potential describes". Am. J. Phys. 46 (5): 499–502.<br />
Bibcode 1978AmJPh..46..499K. doi:10.1119/1.11298.<br />
[38] Griffiths, David J. (1999). Introduction to Electrodynamics (3rd ed.). Prentice Hall. p. 422. ISBN 0-13-805326-X. OCLC 40251748.<br />
[39] For a good qualitative introduction see: Feynman, Richard (2006). QED: the strange theory of light and matter. Princeton University Press.<br />
ISBN 0-691-12575-9.<br />
[40] Herbert, Yahreas (June 1954). "What makes the earth Wobble" (http:/ / books. google. com/ ?id=NiEDAAAAMBAJ& pg=PA96&<br />
dq=What+ makes+ the+ earth+ wobble& q=What makes the earth wobble). Popular Science (New York: Godfrey Hammond): p.266. .<br />
[41] College Physics, Volume 10, by Serway, Vuille, and Faughn, page 628 weblink (http:/ / books. google. com/ books?id=CX0u0mIOZ44C&<br />
pg=PT660). "the geographic North Pole of Earth corresponds to a magnetic south pole, and the geographic South Pole of Earth corresponds to<br />
a magnetic north pole".<br />
[42] Kurtus, Ron (2004). "Magnets" (http:/ / www. school-for-champions. com/ science/ magnets. htm). School for champions: Physics topics. .<br />
Retrieved 17 July 2010.<br />
[43] http:/ / www. google. com/ patents?vid=381968<br />
[44] The Solar Dynamo (http:/ / www. cora. nwra. com/ ~werne/ eos/ text/ dynamo. html), retrieved Sep 15, 2007.<br />
[45] I. S. Falconer and M. I. Large (edited by I. M. Sefton), " Magnetism: Fields and Forces (http:/ / www. physics. usyd. edu. au/ super/<br />
life_sciences/ electricity. html)" Lecture E6, The University of Sydney, retrieved 3 Oct 2008<br />
[46] Robert Sanders, " Astronomers find magnetic Slinky in Orion (http:/ / berkeley. edu/ news/ media/ releases/ 2006/ 01/ 12_helical. shtml)",<br />
12 January 2006 at UC Berkeley. Retrieved 3 Oct 2008<br />
[47] (See magnetic moment for further information.)<br />
B. D. Cullity, C. D. Graham (2008). Introduction to Magnetic Materials (http:/ / books. google. com/<br />
?id=ixAe4qIGEmwC& pg=PA103) (2 ed.). Wiley-IEEE. p. 103. ISBN 0471477419. .<br />
References<br />
Further reading<br />
• Durney, Carl H. and Johnson, Curtis C. (1969). Introduction to modern electromagnetics. McGraw-Hill.<br />
ISBN 0-07-018388-0.<br />
• Furlani, Edward P. (2001). Permanent Magnet and Electromechanical Devices: Materials, Analysis and<br />
Applications. Academic Press Series in Electromagnetism. ISBN 0-12-269951-3. OCLC 162129430.<br />
• Jiles, David (1994). Introduction to Electronic Properties of Materials (1st ed ed.). Springer.<br />
ISBN 0-412-49580-5.<br />
• Kraftmakher, Yaakov (2001). "Two experiments with rotating magnetic field" (http:/ / www. iop. org/ EJ/<br />
abstract/ 0143-0807/ 22/ 5/ 302). Eur. J. Phys. 22: 477–482.<br />
• Melle, Sonia; Rubio, Miguel A.; Fuller, Gerald G. (2000). "Structure and dynamics of magnetorheological fluids<br />
in rotating magnetic fields" (http:/ / prola. aps. org/ abstract/ PRE/ v61/ i4/ p4111_1). Phys. Rev. E 61:
<strong>Wiki</strong> <strong>Book</strong> <strong>Mounir</strong> <strong>Gmati</strong><br />
Magnetic field 53<br />
4111–4117.<br />
• Rao, Nannapaneni N. (1994). Elements of engineering electromagnetics (4th ed.). Prentice Hall.<br />
ISBN 0-13-948746-8. OCLC 221993786.<br />
• Mielnik, Bogdan (1989). "An electron trapped in a rotating magnetic field" (http:/ / scitation. aip. org/ getabs/<br />
servlet/ <strong>Get</strong>absServlet?prog=normal& id=JMAPAQ000030000002000537000001& idtype=cvips& gifs=yes).<br />
Journal of Mathematical Physics 30 (2): 537–549.<br />
• Thalmann, Julia K. (2010). Evolution of Coronal Magnetic Fields. uni-edition. ISBN 978-3-942171-41-0.<br />
• Tipler, Paul (2004). Physics for Scientists and Engineers: Electricity, Magnetism, Light, and Elementary Modern<br />
Physics (5th ed.). W. H. <strong>Free</strong>man. ISBN 0-7167-0810-8. OCLC 51095685.<br />
External links<br />
Information<br />
• Crowell, B., " Electromagnetism (http:/ / www. lightandmatter. com/<br />
html_books/ 0sn/ ch11/ ch11. html)".<br />
• Nave, R., " Magnetic Field (http:/ / hyperphysics. phy-astr. gsu. edu/ hbase/<br />
magnetic/ magfie. html)". HyperPhysics.<br />
• "Magnetism", The Magnetic Field (http:/ / theory. uwinnipeg. ca/ physics/<br />
mag/ node2. html#SECTION00110000000000000000). theory.uwinnipeg.ca.<br />
• Hoadley, Rick, " What do magnetic fields look like (http:/ / my. execpc. com/<br />
~rhoadley/ magfield. htm)?" 17 July 2005.<br />
Field density<br />
• Oppelt, Arnulf (2006-11-02). "magnetic field strength" (http:/ / searchsmb.<br />
techtarget. com/ sDefinition/ 0,290660,sid44_gci763586,00. html). Retrieved<br />
2007-06-04.<br />
• "magnetic field strength converter" (http:/ / www. unitconversion. org/<br />
unit_converter/ magnetic-field-strength. html). Retrieved 2007-06-04.<br />
Rotating magnetic fields<br />
• " Rotating magnetic fields (http:/ / www. tpub. com/ neets/<br />
book5/ 18a. htm)". Integrated Publishing.<br />
• "Introduction to Generators and Motors", rotating magnetic<br />
field (http:/ / www. tpub. com/ content/ neets/ 14177/ css/<br />
14177_87. htm). Integrated Publishing.<br />
• " Induction Motor – Rotating Fields (http:/ / www. egr. msu.<br />
edu/ ~jurkovi4/ Experiment4. pdf)". (dead link)<br />
Diagrams<br />
• McCulloch, Malcolm,"A2: Electrical Power and Machines",<br />
Rotating magnetic field (http:/ / www. eng. ox. ac. uk/<br />
~epgmdm/ A2/ img89. htm). eng.ox.ac.uk.<br />
• "AC Motor Theory" Figure 2 Rotating Magnetic Field (http:/<br />
/ www. tpub. com/ content/ doe/ h1011v4/ css/ h1011v4_23.<br />
htm). Integrated Publishing.<br />
• "Magnetic Fields" Arc & Mitre Magnetic Field Diagrams<br />
(http:/ / www. first4magnets. com/ ekmps/ shops/ trainer27/<br />
resources/ Other/ magnetic-fields. pdf). Magnet Expert Ltd.
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Flux pinning 54<br />
Flux pinning<br />
Flux pinning is the phenomenon that magnetic flux lines do not move (become trapped, or "pinned") in spite of the<br />
Lorentz force acting on them inside a current-carrying Type II superconductor. The phenomenon cannot occur in<br />
Type I superconductors, since these cannot be penetrated by magnetic fields (Meissner–Ochsenfeld effect). Flux<br />
pinning is only possible when there are defects in the crystalline structure of the superconductor (usually resulting<br />
from grain boundaries or impurities).<br />
Importance of flux pinning<br />
Flux pinning is desirable in high-temperature ceramic superconductors to prevent "flux creep", which can create a<br />
pseudo-resistance and depress both critical current density and critical field.<br />
Degradation of a high-temperature superconductor's properties due to flux creep is a limiting factor in the use of<br />
these superconductors. SQUID magnetometers suffer reduced precision in a certain range of applied field due to flux<br />
creep in the superconducting magnet used to bias the sample, and the maximum field strength of high-temperature<br />
superconducting magnets is drastically reduced by the depression in critical field.<br />
References<br />
• Future Science [1] introduction to high-temperature superconductors.<br />
• American Magnetics [2] tutorial on magnetic field exclusion and flux pinning in superconductors.<br />
• Cern Lhc documentation [3] Stability of superconductors.<br />
Other sources<br />
• Flux-Pinning of Bi 2 Sr 2 CaCu 2 O (8 + Delta) High T c Superconducting Tapes Utilizing (Sr,Ca) 14 Cu 24 O (41 + Delta) and<br />
Sr 2 CaAl 2 O 6 Defects (T. Haugan; et al. AFB OH Propulsion Directorate. Air Force Research Lab<br />
Wright-Patterson. Oct 2003)<br />
References<br />
[1] http:/ / www. futurescience. com/ scintro. html<br />
[2] http:/ / www. americanmagnetics. com/ supercon. php<br />
[3] http:/ / quench-analysis. web. cern. ch/ quench-analysis/ phd-fs-html/ node41. html
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Magnetic levitation 55<br />
Magnetic levitation<br />
Magnetic levitation, maglev, or magnetic suspension is a<br />
method by which an object is suspended with no support other<br />
than magnetic fields. Magnetic pressure is used to counteract the<br />
effects of the gravitational and any other accelerations.<br />
Earnshaw's theorem proves that using only static ferromagnetism<br />
it is impossible to stably levitate against gravity, but<br />
servomechanisms, the use of diamagnetic materials,<br />
superconduction, or systems involving eddy currents permit this to<br />
occur.<br />
In some cases the lifting force is provided by magnetic levitation,<br />
but there is a mechanical support bearing little load that provides<br />
stability. This is termed pseudo-levitation.<br />
Magnetic levitation is used for maglev trains, magnetic bearings<br />
and for product display purposes.<br />
Lift<br />
Levitating pyrolytic carbon<br />
Magnetic materials and systems are able to attract or press each other apart or together with a force dependent on the<br />
magnetic field and the area of the magnets, and a magnetic pressure can then be defined.<br />
The magnetic pressure of a magnetic field on a superconductor can be calculated by:<br />
where is the force per unit area in pascals, is the magnetic field just above the superconductor in teslas,<br />
and = 4π×10 −7 N·A −2 is the permeability of the vacuum. [1]<br />
Stability<br />
Static stability means that any small displacement away from a stable equilibrium causes a net force to push it back<br />
to the equilibrium point.<br />
Earnshaw's theorem proved conclusively that it is not possible to levitate stably using only static, macroscopic,<br />
paramagnetic fields. The forces acting on any paramagnetic object in any combinations of gravitational, electrostatic,<br />
and magnetostatic fields will make the object's position, at best, unstable along at least one axis, and it can be<br />
unstable equilibrium along all axes. However, several possibilities exist to make levitation viable, for example, the<br />
use of electronic stabilization or diamagnetic materials (since relative magnetic permeability is less than one [2] ); it<br />
can be shown that diamagnetic materials are stable along at least one axis, and can be stable along all axes.<br />
Conductors can have a relative permeability to alternating magnetic fields of below one, so some configurations<br />
using simple AC driven electromagnets are self stable.<br />
Dynamic stability occurs when the levitation system is able to damp out any vibration-like motion that may occur.
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Magnetic levitation 56<br />
Methods<br />
For successful levitation and control of all 6 axes (3 spatial and 3 rotational) a combination of permanent magnets<br />
and electromagnets or diamagnets or superconductors as well as attractive and repulsive fields can be used. From<br />
Earnshaw's theorem at least one stable axis must be present for the system to levitate successfully, but the other axes<br />
can be stabilised using ferromagnetism.<br />
The primary ones used in maglev trains are servo-stabilized electromagnetic suspension (EMS), electrodynamic<br />
suspension (EDS), and experimentally, Inductrack.<br />
Mechanical constraint (pseudo-levitation)<br />
With a small amount of mechanical constraint for stability,<br />
pseudo-levitation is relatively straightforwardly achieved.<br />
If two magnets are mechanically constrained along a single vertical<br />
axis, for example, and arranged to repel each other strongly, this will<br />
act to levitate one of the magnets above the other.<br />
Another geometry is where the magnets are attracted, but constrained<br />
from touching by a tensile member, such as a string or cable.<br />
Another example is the Zippe-type centrifuge where a cylinder is<br />
suspended under an attractive magnet, and stabilized by a needle<br />
bearing from below.<br />
Diamagnetism<br />
Mechanical constraint (in this case the lateral<br />
restrictions created by a box) can permit<br />
pseudo-levitation of permanent magnets<br />
Diamagnetism is the property of an object which causes it to create a magnetic field in opposition to an externally<br />
applied magnetic field, thus causing a repulsive effect. Specifically, an external magnetic field alters the orbital<br />
velocity of electrons around their nuclei, thus changing the magnetic dipole moment. According to Lenz's law, this<br />
opposes the external field. Diamagnets are materials with a magnetic permeability less than μ0 (a relative<br />
permeability less than 1). Consequently, diamagnetism is a form of magnetism that is only exhibited by a substance<br />
in the presence of an externally applied magnetic field. It is generally quite a weak effect in most materials, although<br />
superconductors exhibit a strong effect. Diamagnetic materials cause lines of magnetic flux to curve away from the<br />
material, and superconductors can exclude them completely (except for a very thin layer at the surface).
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Magnetic levitation 57<br />
Direct diamagnetic levitation<br />
A substance that is diamagnetic repels a magnetic field. All<br />
materials have diamagnetic properties, but the effect is very weak,<br />
and is usually overcome by the object's paramagnetic or<br />
ferromagnetic properties, which act in the opposite manner. Any<br />
material in which the diamagnetic component is strongest will be<br />
repelled by a magnet.<br />
Earnshaw's theorem does not apply to diamagnets. These behave<br />
in the opposite manner to normal magnets owing to their relative<br />
permeability of μ r < 1 (i.e. negative magnetic susceptibility).<br />
Diamagnetic levitation can be used to levitate very light pieces of<br />
pyrolytic graphite or bismuth above a moderately strong<br />
permanent magnet. As water is predominantly diamagnetic, this<br />
technique has been used to levitate water droplets and even live<br />
animals, such as a grasshopper, frog and a mouse. However, the<br />
magnetic fields required for this are very high, typically in the<br />
range of 16 teslas, and therefore create significant problems if<br />
ferromagnetic materials are nearby.<br />
The minimum criterion for diamagnetic levitation is , where:<br />
• is the magnetic susceptibility<br />
• is the density of the material<br />
• is the local gravitational acceleration (−9.8 m/s 2 on Earth)<br />
• is the permeability of free space<br />
• is the magnetic field<br />
• is the rate of change of the magnetic field along the vertical axis.<br />
Assuming ideal conditions along the z-direction of solenoid magnet:<br />
• Water levitates at<br />
• Graphite levitates at<br />
A live frog levitates inside a 32 mm diameter vertical<br />
bore of a Bitter solenoid in a magnetic field of about 16<br />
teslas at the High Field Magnet Laboratory [3] of the<br />
Radboud University in Nijmegen the Netherlands.<br />
Direct link to video [4]
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Magnetic levitation 58<br />
Diamagnetically-stabilized levitation<br />
A permanent magnet can be stably suspended by various configurations of strong permanent magnets and strong<br />
diamagnets. When using superconducting magnets, the levitation of a permanent magnet can even be stabilized by<br />
the small diamagnetism of water in human fingers. [5]<br />
Superconductors<br />
Superconductors may be considered perfect diamagnets (μ r = 0), as<br />
well as the property they have of completely expelling magnetic fields<br />
due to the Meissner effect when the superconductivity initially forms.<br />
The levitation of the magnet is further stabilized due to flux pinning<br />
within the superconductor; this tends to stop the superconductor<br />
leaving the magnetic field, even if the levitated system is inverted.<br />
These principles are exploited by EDS (Electrodynamic Suspension),<br />
superconducting bearings, flywheels, etc.<br />
In trains, a very strong magnetic field is required to levitate a massive<br />
train, the JR–Maglev have superconducting magnetic coils.<br />
JR–Maglev levitation is not by Meissner effect.<br />
Rotational stabilization<br />
A magnet can be levitated against gravity when gyroscopically<br />
stabilized by spinning it in a toroidal field created by a base ring of<br />
magnet(s). However, it will only remain stable until the rate of<br />
A superconductor levitating a permanent magnet<br />
precession slows below a critical threshold—the region of stability is quite narrow both spatially and in the required<br />
rate of precession. The first discovery of this phenomenon was by Roy Harrigan, a Vermont inventor who patented a<br />
levitation device in 1983 based upon it. [6] Several devices using rotational stabilization (such as the popular Levitron<br />
toy) have been developed citing this patent. Non-commercial devices have been created for university research<br />
laboratories, generally using magnets too powerful for safe public interaction.<br />
Servomechanisms<br />
The attraction from a fixed strength magnet decreases with increased<br />
distance, and increases at closer distances. This is unstable. For a stable<br />
system, the opposite is needed, variations from a stable position should<br />
push it back to the target position.<br />
Stable magnetic levitation can be achieved by measuring the position<br />
and speed of the object being levitated, and using a feedback loop<br />
which continuously adjusts one or more electromagnets to correct the<br />
object's motion, thus forming a servomechanism.<br />
Many systems use magnetic attraction pulling upwards against gravity<br />
for these kinds of systems as this gives some inherent lateral stability,<br />
but some use a combination of magnetic attraction and magnetic<br />
repulsion to push upwards.<br />
The Transrapid system uses servomechanisms to<br />
pull the train up from underneath the track and<br />
maintains a constant gap while travelling at high<br />
Either system represents examples of ElectroMagnetic Suspension (EMS). For a very simple example, some tabletop<br />
levitation demonstrations use this principle, and the object cuts a beam of light to measure the position of the object.<br />
speed
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Magnetic levitation 59<br />
The electromagnet is above the object being levitated; the electromagnet is turned off whenever the object gets too<br />
close, and turned back on when it falls further away. Such a simple system is not very robust; far more effective<br />
control systems exist, but this illustrates the basic idea.<br />
EMS magnetic levitation trains are based on this kind of levitation: The train wraps around the track, and is pulled<br />
upwards from below. The servo controls keep it safely at a constant distance from the track.<br />
Induced currents<br />
These schemes work due to repulsion due to Lenz's law. When a conductor is presented with a time-varying<br />
magnetic field electrical currents in the conductor are set up which create a magnetic field that causes a repulsive<br />
effect.<br />
Relative motion between conductors and magnets<br />
If one moves a base made of a very good electrical conductor such as copper, aluminium or silver close to a magnet,<br />
an (eddy) current will be induced in the conductor that will oppose the changes in the field and create an opposite<br />
field that will repel the magnet (Lenz's law). At a sufficiently high rate of movement, a suspended magnet will<br />
levitate on the metal, or vice versa with suspended metal. Litz wire made of wire thinner than the skin depth for the<br />
frequencies seen by the metal works much more efficiently than solid conductors.<br />
An especially technologically-interesting case of this comes when one uses a Halbach array instead of a single pole<br />
permanent magnet, as this almost doubles the field strength, which in turn almost doubles the strength of the eddy<br />
currents. The net effect is to more than triple the lift force. Using two opposed Halbach arrays increases the field<br />
even further. [7]<br />
Halbach arrays are also well-suited to magnetic levitation and stabilisation of gyroscopes and electric motor and<br />
generator spindles.<br />
Oscillating electromagnetic fields<br />
A conductor can be levitated above an electromagnet (or vice versa) with an alternating current flowing through it.<br />
This causes any regular conductor to behave like a diamagnet, due to the eddy currents generated in the conductor. [8]<br />
[9] Since the eddy currents create their own fields which oppose the magnetic field, the conductive object is repelled<br />
from the electromagnet, and most of the field lines of the magnetic field will no longer penetrate the conductive<br />
object.<br />
This effect requires non-ferromagnetic but highly conductive materials like aluminium or copper, as the<br />
ferromagnetic ones are also strongly attracted to the electromagnet (although at high frequencies the field can still be<br />
expelled) and tend to have a higher resistivity giving lower eddy currents. Again, litz wire gives the best results.<br />
The effect can be used for stunts such as levitating a telephone book by concealing an aluminium plate within it.<br />
At high frequencies (a few tens of kilohertz or so) and kilowatt powers small quantities of metals can be levitated<br />
and melted using levitation melting without the risk of the metal being contaminated by the crucible. [10]<br />
One source of oscillating magnetic field that is used is the linear induction motor. This can be used to levitate as well<br />
as provide propulsion.
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Magnetic levitation 60<br />
Strong focusing<br />
Earnshaw's theory strictly only applies to static fields. Alternating magnetic fields, even purely alternating attractive<br />
fields, [11] can induce stability and confine a trajectory through a magnetic field to give a levitation effect.<br />
This is used in particle accelerators to confine and lift charged particles, and has been proposed for maglev trains<br />
also. [11]<br />
Dynamic stability<br />
Magnetic fields are conservative forces and therefore in principle have no built-in damping, and in practice many of<br />
the levitation schemes are under-damped and in some cases negatively damped. [12] This can permit vibration modes<br />
to exist that can cause the item to leave the stable region.<br />
Damping of motion is done in a number of ways:<br />
• external mechanical damping (in the support), such as dashpots, air drag etc.<br />
• eddy current damping (conductive metal influenced by field)<br />
• tuned mass dampers in the levitated object<br />
• electromagnets controlled by electronics<br />
Difficulties<br />
Most of the levitation techniques have various complexities.<br />
• The power requirements of electromagnets increase rapidly with load-bearing capacity, which also necessitates<br />
relative increases in conductor and cooling equipment mass and volume.<br />
• Superconductors require very low temperatures to operate, often helium cooling is employed.<br />
Uses<br />
Maglev transportation<br />
Maglev, or magnetic levitation, is a system of transportation that suspends, guides and propels vehicles,<br />
predominantly trains, using magnetic levitation from a very large number of magnets for lift and propulsion. This<br />
method has the potential to be faster, quieter and smoother than wheeled mass transit systems. The technology has<br />
the potential to exceed 6,400 km/h (4,000 mi/h) if deployed in an evacuated tunnel. [13] If not deployed in an<br />
evacuated tube the power needed for levitation is usually not a particularly large percentage and most of the power<br />
needed is used to overcome air drag, as with any other high speed train.<br />
The highest recorded speed of a maglev train is 581 kilometers per hour (361 mph), achieved in Japan in 2003, [14]<br />
6 km/h faster than the conventional TGV speed record. This is slower than many aircraft, since aircraft can fly at far<br />
higher altitudes where air drag is lower, thus high speeds are more readily attained.
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Magnetic levitation 61<br />
Magnetic bearings<br />
• Magnetic bearings<br />
• Flywheels<br />
• Centrifuges<br />
• Magnetic ring spinning<br />
Levitation melting<br />
Electromagnetic levitation (EML), patented by Muck in 1923 [15] , is one of the oldest levitation techniques used<br />
for containerless experiments. [16] The technique enables the levitation of an object using electromagnets. A typical<br />
EML coil has reversed winding of upper and lower sections energized by a radio frequency power supply.<br />
History<br />
This list is incomplete.<br />
• 1839 Earnshaw's theorem showed electrostatic levitation was impossible, later theorem was extended to<br />
magnetostatic levitation by others<br />
• 1912 Emile Bachelet awarded a patent in March 1912 for his “levitating transmitting apparatus” (patent no.<br />
1,020,942) for electromagnetic suspension system<br />
• 1933 Superdiamagnetism Walter Meissner and Robert Ochsenfeld (the Meissner effect)<br />
• 1934 Hermann Kemper “monorail vehicle with no wheels attached.” Reich Patent number 643316<br />
• 1939 Braunbeck’s extension showed that magnetic levitation is possible with diamagnetic materials<br />
• 1939 Bedford, Peer, and Tonks aluminum plate placed on two concentric cylindrical coils shows 6-axis stable<br />
levitation. [17]<br />
• 1961 James R. Powell and BNL colleague Gordon Danby electrodynamic levitation using superconducting<br />
magnets<br />
• 1970s Spin stabilized magnetic levitation Roy M. Harrigan<br />
• 1974 Magnetic river Eric Laithwaite and others<br />
• 1979 transrapid train carried passengers<br />
• 1984 Low speed maglev shuttle in Birmingham Eric Laithwaite and others<br />
• 1999 Inductrack permanent magnet electrodynamic levitation (General Atomics)<br />
• 2000 Diamagnetically levitated live frog Andre Geim<br />
References<br />
[1] Lecture 19 MIT 8.02 Electricity and Magnetism, Spring 2002<br />
[2] Braunbeck, W. <strong>Free</strong> suspension of bodies in electric and magnetic fields, Zeitschrift für Physik, 112, 11, pp753-763 (1939)<br />
[3] http:/ / RU. nl/ HFML<br />
[4] http:/ / web. Archive. org/ web/ 20070211113825/ http:/ / www. HFML. RU. nl/ pics/ Movies/ frog. mpg<br />
[5] Diamagnetically stabilized magnet levitation (http:/ / netti. nic. fi/ ~054028/ images/ LeviTheory. pdf)<br />
[6] US patent 4382245 (http:/ / worldwide. espacenet. com/ textdoc?DB=EPODOC& IDX=US4382245), Roy M. Harrigan, "Levitation device",<br />
issued 1983-05-03<br />
[7] (https:/ / www. llnl. gov/ str/ November03/ Post. html)<br />
[8] Eddy current magnetic levitation, models and experiments by Marc T. Thompson (http:/ / www. classictesla. com/ download/<br />
ieee_potentials_2000. pdf)<br />
[9] Levitated Ball-Levitating a 1 cm aluminum sphere (http:/ / sprott. physics. wisc. edu/ demobook/ chapter5. htm)<br />
[10] "Magnetic levitation of liquid metals", Journal of Fluid Mechanics 117, pages 27-43, by A. J. Mestel<br />
[11] Attractive levitation for high-speed ground transport with largeguideway clearance and alternating-gradient stabilization Hull, J.R.<br />
Magnetics, IEEE Transactions on Volume 25, Issue 5, Sep 1989 Page(s):3272 - 3274 Digital Object Identifier 10.1109/20.42275 (http:/ /<br />
ieeexplore. ieee. org/ Xplore/ login. jsp?url=/ iel1/ 20/ 1621/ 00042275. pdf?tp=& isnumber=1621& arnumber=42275& type=ref)<br />
[12] A Review of Dynamic Stability of Repulsive-Force Maglev Suspension Systems- Y. Cai and D.M.Rote<br />
[13] http:/ / www. popsci. com/ scitech/ article/ 2004-04/ trans-atlantic-maglev
<strong>Wiki</strong> <strong>Book</strong> <strong>Mounir</strong> <strong>Gmati</strong><br />
Magnetic levitation 62<br />
[14] "Japan's maglev train sets speed record" (http:/ / www. theglobeandmail. com/ servlet/ story/ RTGAM. 20031202. gtmaglevdec2/ BNStory/<br />
International/ ). CTVglobemedia Publishing Inc.. 2003-12-02. . Retrieved 2009-02-16.<br />
[15] O. Muck. German patent no. 42204 (Oct. 30, 1923)<br />
[16] Paul C. Nordine, J. K. Richard Weber, and Johan G. Abadie (2000), "Properties of high-temperature melts using levitation", Pure and<br />
Applied Chemistry 72: 2127–2136, doi:10.1351/pac200072112127<br />
[17] linear Electric Machines- A Personal View ERIC R. LAITHWAITE, FELLOW, IEEE, PROCEEDINGS OF THE IEEE, VOL. 63, NO. 2,<br />
FEBRUARY 1975<br />
External links<br />
• Maglev Trains (http:/ / www. magnet. fsu. edu/ education/ community/ slideshows/ maglev/ index. html) Audio<br />
slideshow from the National High Magnetic Field Laboratory discusses magnetic levitation, the Meissner Effect,<br />
magnetic flux trapping and superconductivity<br />
• Magnetic Levitation - Science is Fun (http:/ / www. levitationfun. com/ index. html)<br />
• Magnetic (superconducting) levitation experiment (YouTube) (http:/ / www. youtube. com/<br />
watch?v=nWTSzBWEsms& feature=related)<br />
• Maglev video gallery (http:/ / users. bigpond. net. au/ com/ maglevvideogallery/ )<br />
• How can you magnetically levitate objects? (http:/ / my. execpc. com/ ~rhoadley/ maglev. htm)<br />
• Levitated aluminum ball (oscillating field) (http:/ / sprott. physics. wisc. edu/ demobook/ chapter5. htm)<br />
• Instructions to build an optically triggered feedback maglev demonstration (http:/ / www. coilgun. info/ levitation/<br />
home. htm)<br />
• Videos of diamagnetically levitated objects, including frogs and grasshoppers (http:/ / www. hfml. sci. kun. nl/<br />
levitation-movies. html)<br />
• Larry Spring's Mendocino Brushless Magnetic Levitation Solar Motor (http:/ / www. larryspring. com/<br />
class_motors. html)<br />
• A Classroom Demonstration of Levitation... (http:/ / arxiv. org/ abs/ 0803. 3090)<br />
• 25kg MAGLEV suspension setup (http:/ / www. youtube. com/ watch?v=Y_WG4YStMxs& feature=related)<br />
• 25kg MAGLEV suspension control via Classical control strategy (http:/ / www. youtube. com/<br />
watch?v=kXodf7WKiFs)<br />
• 25kg MAGLEV suspension via State feedback control strategy (http:/ / www. youtube. com/<br />
watch?v=TsgoF13KvYk& feature=related)<br />
• Frogs levitate in a strong enough magnetic field (http:/ / www. physics. org/ facts/ frog-really. asp)
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Article Sources and Contributors 63<br />
Article Sources and Contributors<br />
Superconductivity Source: http://en.wikipedia.org/w/index.php?oldid=460476186 Contributors: 2over0, 52 6f 62, ASchwarz, AVand, Aeronautics, Agnel P.B., Ahoerstemeier, Ahpook,<br />
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Type-I superconductor Source: http://en.wikipedia.org/w/index.php?oldid=430200914 Contributors: 2over0, Anoop K Nayak, Athaler, Auriam, Dick Chu, DrTorstenHenning, Eynar, Graeme<br />
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Liquid nitrogen Source: http://en.wikipedia.org/w/index.php?oldid=458759995 Contributors: - ), 99of9, A8UDI, Aaronsharpe, Adys, Agent Smith (The Matrix), Aiyizo, Aldaron, Alex.tan,<br />
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Image Sources, Licenses and Contributors 65<br />
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