FEATURE REVERSE OSMOSIS PRESSURE VESSEL Courtesy <strong>of</strong> Dr. Gary Graham, Ohio State University Extension, Wooster, Ohio. 26 NATIONAL BOARD BULLETIN / FALL 2008 nationalboard.org
CAROL DAVIDSON COOKING PANCAKES at The <strong>National</strong> <strong>Maple</strong> <strong>Syrup</strong> <strong>Festival</strong>. Osmosis is <strong>the</strong> natural diffusion, without pressure, <strong>of</strong> a solvent through a semipermeable membrane from a solution with low solute concentration <strong>to</strong> a solution with high solute concentration. On <strong>the</strong> o<strong>the</strong>r hand, reverse osmosis uses high pressure <strong>to</strong> force a solvent from an area <strong>of</strong> high solute concentration through a membrane <strong>to</strong> an area <strong>of</strong> low solute concentration. It was achieved in 1959 when a UCLA pr<strong>of</strong>essor, Samuel Yuster, and two <strong>of</strong> his students, Sidney Loeb and Srinivasa Sourirajan, trying <strong>to</strong> find a way <strong>to</strong> extract pure water from salt water, produced a syn<strong>the</strong>tic membrane from cellulose acetate polymer. The membrane rejected <strong>the</strong> salt, but let <strong>the</strong> water pass. The operating pressures <strong>of</strong> <strong>the</strong> membrane ranged from 800 <strong>to</strong> 1,000 lb/in! for sea water and 200 <strong>to</strong> 400 lb/in! for brackish water. Today reverse osmosis is <strong>the</strong> most efficient way <strong>of</strong> ridding both salt and fresh water <strong>of</strong> impurities. And, as maple syrup producers have found out, an efficient way <strong>of</strong> capturing <strong>the</strong>m. Straight from <strong>the</strong> tree, sap has a sugar content <strong>of</strong> 2 percent; <strong>to</strong> increase <strong>the</strong> content <strong>to</strong> 67 percent (or, <strong>to</strong> turn sap “in<strong>to</strong> thick, sweet syrup that piques <strong>the</strong> palate”), producers must reduce <strong>the</strong> water. “Reverse osmosis,” Bur<strong>to</strong>n says, “is a process we do with <strong>the</strong> sap before it even gets <strong>to</strong> <strong>the</strong> evapora<strong>to</strong>r. What we do is discard <strong>the</strong> water and capture <strong>the</strong> impurities – we want <strong>the</strong> impurities, <strong>the</strong> sugar. What happens when you filter <strong>the</strong> sap is you go from 2 percent sugar content <strong>to</strong> 4 percent; <strong>the</strong>n if you filter it again, you go from 4 percent <strong>to</strong> 8 percent. Some producers are even going from 8 percent <strong>to</strong> 16 percent before it goes <strong>to</strong> <strong>the</strong> evapora<strong>to</strong>r.” nationalboard.org DRAWING OFF A BUCKET OF 100% PURE MAPLE SYRUP. According <strong>to</strong> Dr. Timothy Perkins, direc<strong>to</strong>r <strong>of</strong> <strong>the</strong> Proc<strong>to</strong>r <strong>Maple</strong> Research Center at <strong>the</strong> University <strong>of</strong> Vermont, reverse osmosis uses pump-generated pressure <strong>to</strong> push water through a membrane in a high-pressure chamber. “The sugar in sap can’t pass through <strong>the</strong> pores in <strong>the</strong> membrane, so it’s retained and concentrated; however, <strong>the</strong> water does pass through <strong>the</strong> membrane and is discarded or used for washing or rinsing cycles.” Perkins says reverse osmosis pressure vessels generally work under a maximum pressure <strong>of</strong> 200 <strong>to</strong> 300 psi, though that can vary greatly depending on <strong>the</strong> vessel and membrane. Reverse osmosis as a viable method for <strong>the</strong> concentration <strong>of</strong> sugar in sap was first tested in 1966 at <strong>the</strong> USDA <strong>Maple</strong> Research Labora<strong>to</strong>ry. The first reverse osmosis system was installed in 1971; by <strong>the</strong> early eighties, a <strong>to</strong>tal <strong>of</strong> about 100 machines were operating in Canada and <strong>the</strong> US. Something producers need <strong>to</strong> be wary <strong>of</strong> when using reverse osmosis is <strong>the</strong> contamination <strong>of</strong> <strong>the</strong> membrane by microorganisms in <strong>the</strong> sap. Because sap NATIONAL BOARD BULLETIN / FALL 2008 t27 FEATURE