05.04.2013 Views

High capacity distillation revamps - DigitalRefining

High capacity distillation revamps - DigitalRefining

High capacity distillation revamps - DigitalRefining

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

<strong>High</strong> <strong>capacity</strong> <strong>distillation</strong> <strong>revamps</strong><br />

A review of fundamental tray design principles used to increase column <strong>capacity</strong>.<br />

Understanding how high-<strong>capacity</strong> trays work assists in selection and design<br />

Daryl Hanson and Edward Hartman Process Consulting Services Inc<br />

In the past 10 years the mass transfer industry<br />

has developed a number of tray designs to<br />

increase column <strong>capacity</strong> by 10–30 per cent<br />

over well-designed conventional trays. While<br />

some of these trays, such as UOP’s and Shell’s<br />

have been in service for more than 20 years,<br />

several have only been commercialised in the<br />

past five. <strong>High</strong> <strong>capacity</strong> tray designs employ<br />

several different mechanical features to increase<br />

<strong>capacity</strong>.<br />

Maximising tray hydraulic <strong>capacity</strong> always<br />

reduces tray efficiency and/or operating flexibility.<br />

Balancing <strong>capacity</strong>, efficiency, and operating<br />

flexibility is the challenge facing the engineer<br />

performing a revamp. Some designs have inherently<br />

more efficiency due to the longer distance<br />

the liquid travels across the tray. Others have<br />

extremely high <strong>capacity</strong>, lower efficiency and<br />

little turndown. Which high <strong>capacity</strong> tray is<br />

needed depends on the specific process<br />

objectives.<br />

<strong>High</strong> <strong>capacity</strong> trays increase column vapour<br />

and liquid <strong>capacity</strong> by increasing active area,<br />

increasing downcomer <strong>capacity</strong>, decreasing weir<br />

loading and reducing hydraulic gradient.<br />

Trays flood when the liquid and/or the vapour<br />

rate exceed the <strong>capacity</strong> of the particular design.<br />

In some cases an optimised conventional tray<br />

will debottleneck the column. In those instances<br />

where it is necessary to use high <strong>capacity</strong> trays,<br />

one or all of the four principles to increase<br />

vapour and liquid handling may be needed.<br />

Often, tray <strong>capacity</strong>, column efficiency, and operating<br />

flexibility will need to be balanced to meet<br />

revamp objectives. Two case studies, described<br />

later, highlight this balance.<br />

Tray <strong>capacity</strong><br />

Trays flood because the active area and/or the<br />

Figure 1 Conventional two-pass tray<br />

downcomers are not capable of handling the<br />

operating vapour and liquid rates. Figure 1 shows<br />

a conventional two-pass tray where liquid flows<br />

down the column through downcomers, while<br />

vapour flows up through the active area.<br />

Incipient flooding begins when liquid is entrained<br />

with the rising vapour and reaches the tray<br />

above. If the downcomers have the <strong>capacity</strong> to<br />

handle both the entrained liquid plus the normal<br />

liquid flow, then fractionation will suffer but the<br />

column will be operable.<br />

Once the downcomer <strong>capacity</strong> is exceeded, the<br />

tray vapour space begins to fill with liquid. At<br />

this point the tray will hydraulically flood,<br />

common symptoms being periodic loss of level<br />

below the flooded trays followed by “dumping”<br />

of the accumulated liquid causing high levels.<br />

www.digitalrefining.com/article/1000325 PTQ Q4 2001 1


Figure 2 Jet (vapour) flooding<br />

When trays flood the column pressure drop<br />

increases.<br />

Trays fractionate by mixing the liquid and<br />

vapour phases together on and above the active<br />

area. The mixed phases separate by Stoke’s Law<br />

with the liquid settling onto the tray deck or into<br />

the top of the downcomer, while liquid-free<br />

vapour rises up the column through the next<br />

tray.<br />

Jet flooding occurs when the localised velocity<br />

through the tray deck is high enough to entrain<br />

liquid to the tray above (Figure 2). Jet flooding<br />

is common in low and moderate pressure services<br />

such as atmospheric crude, FCC main<br />

fractionator, or naphtha splitters. These low to<br />

moderate pressure systems have high vapour<br />

rates and relatively low liquid rates in the fractionating<br />

sections.<br />

Tray downcomers must have the <strong>capacity</strong> to<br />

handle the liquid flowing from one tray to the<br />

next without backing liquid onto the tray deck. A<br />

downcomer can flood by two distinct mechanisms.<br />

Downcomer choke flood occurs when the<br />

rate of liquid entering the top of the downcomer<br />

is too high to allow entrained vapour to<br />

disengage.<br />

The downcomer chokes with liquid and vapour,<br />

and when it does the liquid level on the tray deck<br />

builds up and the column floods. On a simple<br />

basis, downcomer backup flood occurs when the<br />

liquid and froth level in the downcomer exceeds<br />

the tray spacing plus the weir height. Liquid fills<br />

the normal vapour space above the tray deck,<br />

causing flooding.<br />

Downcomer backup is impacted on by several<br />

tray design parameters with the pressure loss<br />

components shown below:<br />

• Dry tray pressure drop – vapour induced loss<br />

• Weir height – set by tray designer<br />

• Weir crest (height of liquid flowing over the<br />

weir) – gpm/inch of weir<br />

• Liquid gradient<br />

• Pressure loss under the downcomer or through<br />

dynamic seal – velocity<br />

Downcomer backup determines the maximum<br />

and minimum operable liquid rates through a<br />

high <strong>capacity</strong> tray, assuming choke is not occurring.<br />

There must be enough liquid height in the<br />

downcomer to overcome the pressure drop of the<br />

various components.<br />

Total liquid height in a downcomer results<br />

from the dry tray pressure-drop (vapour induced<br />

pressure drop through the sieve holes or valves),<br />

weir height, height of liquid flowing over the<br />

weir (gpm/inch of weir), liquid gradient and<br />

pressure loss caused by liquid flowing under the<br />

downcomer or through the dynamic seal.<br />

Liquid level on the tray deck is not uniform<br />

and this reduces tray <strong>capacity</strong>. The liquid gradient<br />

is the driving force needed to push the liquid<br />

across the tray from inlet to outlet. This gradient<br />

causes non-uniform vapour flow rate through the<br />

active area with the variability depending on the<br />

magnitude of the gradient. Liquid gradient<br />

causes high vapour velocity near the outlet weirs,<br />

which results in localised flooding of the tray<br />

active area.<br />

<strong>High</strong> <strong>capacity</strong> tray <strong>revamps</strong> need to balance<br />

hydraulic <strong>capacity</strong>, turndown, and column efficiency<br />

to meet fractionation objectives. Each<br />

factor impacting on tray <strong>capacity</strong> should be<br />

reviewed independently. In practice, the designer<br />

concurrently evaluates all the factors involved,<br />

otherwise an unwanted limit can be created.<br />

Increasing active area<br />

Tray active area is the part of the tray where the<br />

vapour flows through the valve or sieve holes.<br />

Increasing vapour rate requires more active area<br />

assuming the downcomer is not restricting<br />

<strong>capacity</strong>. For instance, increasing tray active area<br />

by 15 per cent will increase the vapour handling<br />

2 PTQ Q4 2001 www.digitalrefining.com/article/1000325


Figure 3 Downcomer flooding: choke and backup<br />

<strong>capacity</strong> by about 15 per cent, all other factors<br />

being equal. Conventional trays have a top downcomer,<br />

bottom downcomer and active areas.<br />

Reducing one or both of the downcomer areas<br />

can be used to increase active area.<br />

Increasing active area, assuming the top downcomer<br />

area cannot be changed, requires less<br />

bottom downcomer area. Conventional trays<br />

have a solid plate at the bottom of the downcomer<br />

(inlet panel). <strong>High</strong> <strong>capacity</strong> designs either<br />

heavily slope the downcomer from top to bottom<br />

or they truncate the downcomer above the tray<br />

deck. While both increase active area, the heavily<br />

sloped downcomers maintain the downcomer<br />

height. This maximises liquid handling<br />

flexibility.<br />

However, as the number of tray passes<br />

increases, the heavily sloped tray inlet panel will<br />

take up a significant amount of bottom downcomer<br />

area. Alternatively, the downcomer can be<br />

truncated above the tray deck. This eliminates<br />

the tray inlet panel (solid plate) and maximises<br />

active area for any given top downcomer area.<br />

Most high <strong>capacity</strong> trays will either heavily slope<br />

or truncate the downcomer to increase active<br />

area. One version of Koch-Glitsch’s Superfrac<br />

tray has very heavily sloped downcomers, while<br />

other high <strong>capacity</strong> trays use truncated downcomers<br />

to maximise <strong>capacity</strong>. Ultimate <strong>capacity</strong><br />

and operating flexibility will determine which<br />

design should be implemented.<br />

Increasing active area, while maximising<br />

downcomer height improves liquid handling<br />

flexibility. UOP’s MD tray was the first commercial<br />

application of a truncated downcomer. This<br />

concept totally eliminates the bottom downcomer<br />

area and maximises active area.<br />

Subsequently Shell developed the HiFi and<br />

Calming Section trays. Shell trays are designed<br />

and manufactured by Sulzer Chemtech.<br />

Other tray vendors, including Saint-Gobain<br />

NorPro and ACS, have applied truncated downcomers<br />

to maximise active area. Increasing active<br />

area lowers vapour velocity, which decreases the<br />

spray or froth height on the tray. This unloads<br />

the trays, allowing vapour rate to be increased.<br />

Increasing downcomer <strong>capacity</strong><br />

Maximum tray liquid rate is limited by downcomer<br />

choke or backup flood. Once either of<br />

these limits is reached, the tray begins to fill with<br />

liquid. Both potential downcomer flooding mechanisms<br />

must be assessed when revamping a<br />

tower (Figure 3).<br />

Downcomer choke occurs because the top<br />

downcomer area is not large enough to concurrently<br />

separate the vapour and allow liquid to<br />

flow into the downcomer. Vapour is always<br />

entrained with the liquid entering the downcomers,<br />

the quantity being a function of the<br />

difference between the vapour and liquid densities,<br />

weir loading, and the liquid surface tension.<br />

<strong>High</strong>-pressure <strong>distillation</strong>, such as depropanisers<br />

and deethanisers, requires large downcomers<br />

due to the system properties. The top area must<br />

be large enough for the entrained vapour to flow<br />

www.digitalrefining.com/article/1000325 PTQ Q4 2001 5


Shell HiFi tray Koch-Glitsch Superfrac tray<br />

out of the downcomer while liquid is flowing into<br />

the downcomer. Often, the various hydraulic<br />

calculation programs do not address downcomer<br />

choke flood.<br />

Downcomer flooding by backing up causes the<br />

liquid or froth height in the downcomer to overflow<br />

the tray weir. Backup flood can be caused<br />

by any of the components affecting liquid height<br />

in the downcomer, including dry tray pressure<br />

drop, weir height, height of liquid over the weir,<br />

gradient, and head loss under the downcomer or<br />

through the dynamic seal. Increasing the active<br />

area, increasing hole area on the tray, or using<br />

lower pressure drop valves or sieve decks reduces<br />

dry tray pressure drop and lowers downcomer<br />

backup.<br />

Maximum hole area as a percentage of active<br />

area for small movable valves and sieve holes is<br />

approximately 15 per cent and 13 per cent<br />

respectively, to maintain vapour rate flexibility.<br />

<strong>High</strong>er hole area will further reduce pressure<br />

drop and increase vapour <strong>capacity</strong>; however, it<br />

causes weeping and loss of efficiency when the<br />

vapour rate is reduced. Using open area above<br />

these guidelines has caused instability and low<br />

tray efficiency.<br />

Truncated downcomers use slots or holes in<br />

the bottom downcomer plates to seal the downcomers<br />

and prevent vapour flow up the<br />

downcomers. The downcomer slot area and<br />

downcomer height largely determine the liquid<br />

handling flexibility. Downcomer height is tray<br />

spacing minus the height of the truncated downcomer<br />

above the tray floor. Increasing the<br />

downcomer clearance on a heavily sloped tray or<br />

the slot area in the truncated downcomer will<br />

lower backup. These also reduce liquid turndown<br />

because the downcomer can unseal.<br />

Once a downcomer unseals, vapour flows up<br />

the downcomer and tray <strong>capacity</strong> and efficiency<br />

is reduced. Trays have been known to enter into<br />

an unstable dual-flow mode.<br />

Decreasing weir loading<br />

Weir loading is a measure of the amount of<br />

liquid flowing over a unit of weir length (gpm/<br />

inch of weir). Decreasing the weir loading<br />

increases vapour <strong>capacity</strong>, decreases the height<br />

of liquid over the weir (weir crest), increases the<br />

downcomer <strong>capacity</strong> (gpm/ft 2 liquid entering the<br />

top downcomer), and reduces liquid gradient<br />

across the tray.<br />

Maximum tray vapour <strong>capacity</strong> occurs at<br />

approximately 3–4gpm/in of weir, assuming all<br />

other parameters being equal. Tray <strong>capacity</strong> will<br />

increase by 10 per cent when weir loading is<br />

reduced from 8 to 3gpm/in of weir. Reducing<br />

weir loading requires more weir length.<br />

Conventional and many high <strong>capacity</strong> trays use<br />

one-, two-, four- – and very rarely six-pass –<br />

trays to increase weir length. The maximum<br />

number of passes is set by the column diameter,<br />

liquid rate and vapour rate.<br />

Minimum column diameter for a two-, four-,<br />

and six-pass tray is approximately 5, 11 and 14ft,<br />

respectively. Once column diameter is at or<br />

above the minimum, the number of passes can<br />

be selected based on the required weir length<br />

needed to control the weir loading. Increasing<br />

the weir length (more tray passes) decreases the<br />

flow path length (FPL). Once the FPL drops<br />

below about 16in it is not possible to inspect the<br />

trays by removing the tray panels. Decreasing<br />

the FPL also reduces tray efficiency and may<br />

4 PTQ Q4 2001 www.digitalrefining.com/article/1000325


equire higher vapour and liquid rates to meet<br />

the desired fractionation.<br />

Some high <strong>capacity</strong> tray designs, such as the<br />

Shell HiFi, allow the number of downcomers to<br />

be customised to the specific liquid rate so that<br />

optimum weir loading is achieved. This maximises<br />

tray <strong>capacity</strong>. At other times, the number of<br />

downcomers can be selected to maximise tray<br />

efficiency, while meeting the column <strong>capacity</strong><br />

objectives.<br />

Reducing weir loading has several other benefits.<br />

It reduces the liquid height flowing over the<br />

weir. This decreases the liquid level on the tray<br />

and decreases downcomer backup. Reducing<br />

weir loading also decreases the downcomer top<br />

area required to disengage vapour and liquid in<br />

the top of the downcomer. The liquid flowing<br />

over the weir travels less horizontal distance,<br />

which reduces the required downcomer top area<br />

and allows more active area.<br />

Reducing hydraulic gradient<br />

Liquid gradient provides the driving force to<br />

push liquid across the tray’s flow path length.<br />

Increasing flow path length will increase the<br />

liquid gradient. Conventional valves restrict<br />

liquid flow and increase hydraulic gradient when<br />

compared to a sieve tray. Reducing hydraulic<br />

gradient results in more uniform vapour flow<br />

rate through the active area and higher tray<br />

<strong>capacity</strong>. Minimising liquid gradient can increase<br />

tray <strong>capacity</strong> by 6–8 per cent.<br />

Liquid gradient influences vapour flow through<br />

the tray deck because the total pressure drop<br />

across any part of a tray must be constant. Total<br />

tray pressure drop includes dry tray (flow<br />

through the valves or sieve holes) and liquid<br />

pressure drop. Conventional and high <strong>capacity</strong><br />

cross-flow trays have the highest liquid level and<br />

liquid density where liquid enters the active area.<br />

Liquid head at the tray inlet is the highest, and<br />

is lowest at the outlet weir.<br />

Vapour flow is highest where liquid head is the<br />

lowest because more vapour- induced pressure<br />

drop is required to meet the constant total pressure<br />

loss criteria across each section of the tray.<br />

Special design features such as directional<br />

valves, slots, and bubble promoters can be used<br />

to minimise liquid gradient and aerate the liquid<br />

on the tray to a more uniform density. Using<br />

vapour to push the liquid across the tray reduces<br />

liquid gradient. The Koch-Glitsch Superfrac tray<br />

NorproTriton tray<br />

uses directional devices to minimise gradient<br />

and maximise <strong>capacity</strong>. In recent years, several<br />

tray vendors have designed their valves to push<br />

the liquid across the tray including Saint-Gobain<br />

Norpro’s Triton and ACS Max Flow.<br />

Efficiency and <strong>capacity</strong><br />

Column efficiency, <strong>capacity</strong>, and operating flexibility<br />

must be balanced when applying high<br />

<strong>capacity</strong> trays. Improving column efficiency can<br />

reduce the required vapour and liquid rate for a<br />

given separation requirement. The specific <strong>distillation</strong><br />

system will determine whether efficiency<br />

has a meaningful impact on vapour and liquid<br />

load.<br />

The number of trays and the efficiency of each<br />

tray set the column efficiency. Fractionation<br />

requirements and column efficiency determine<br />

the tray vapour and liquid loads. Revamps need<br />

to balance the number of trays, tray efficiency,<br />

tray <strong>capacity</strong> and liquid rate flexibility<br />

Vessel height and tray spacing determine the<br />

number of trays that will fit in an existing<br />

column. Process simulation with the appropriate<br />

VLE and transport property methods are<br />

required to determine the reflux ratio and<br />

column efficiency relationship, as well as the<br />

tray-by-tray liquid and vapour loads. Some<br />

columns have extreme vapour and liquid rate<br />

variability; therefore, tray spacing in the bottom<br />

of the column can be increased, while reducing<br />

tray spacing elsewhere. Lowering the tray spacing<br />

reduces tray <strong>capacity</strong> by the square root of<br />

the tray spacing ratio. For instance, a tray on<br />

12in spacing will have approximately 70 per cent<br />

of the <strong>capacity</strong> of a tray on 24in. Therefore, the<br />

www.digitalrefining.com/article/1000325 PTQ Q4 2001 5


optimum number of trays is a balance between<br />

column efficiency and tray <strong>capacity</strong>. Lower tray<br />

spacing also reduces liquid rate flexibility.<br />

Tray efficiency is a complex function of the<br />

<strong>distillation</strong> system properties (key components,<br />

relative volatility, viscosity, surface tension, etc)<br />

and the tray design. For a given <strong>distillation</strong><br />

system, tray efficiency decreases as flow path<br />

length is reduced. Heavily sloping or truncating<br />

the downcomer can maximise FPL and increase<br />

efficiency. Directional valve or bubble promoters<br />

allow longer flow path lengths while minimising<br />

liquid gradient.<br />

Liquid flow patterns can be improved through<br />

special design features such as the side-downcomer<br />

layout or directional valves on the<br />

Koch-Glitsch Superfrac tray. These help minimise<br />

stagnant zones and improve tray efficiency.<br />

Operability and flexibility<br />

Some of the high <strong>capacity</strong> tray design features,<br />

such as the truncated downcomer, influence<br />

operability and flexibility. The area under the<br />

truncated downcomer uses valves, directional<br />

valves, or bubble promoters to increase vapour<br />

<strong>capacity</strong> and reduce liquid gradient.<br />

Truncated downcomers must be sealed so that<br />

liquid flows through the downcomers, while<br />

vapour flows through the active area. If a significant<br />

amount of vapour flows up the downcomer,<br />

liquid is prevented from flowing down. Unsealed<br />

downcomers can cause poor operating stability,<br />

reduce tray <strong>capacity</strong>, and lower tray efficiency.<br />

Most conventional trays have an outlet weir<br />

height equal to or greater than the downcomer<br />

clearance. This creates a positive seal and<br />

prevents vapour flow up the downcomer. All<br />

high <strong>capacity</strong> and some conventional trays use a<br />

dynamic seal. The liquid rate flowing under the<br />

downcomers must be high enough to develop the<br />

seal. Truncated downcomers have a plate at the<br />

bottom with holes or slots. A minimum liquid<br />

rate is needed to create the seal and prevent<br />

vapour passage.<br />

Maximum liquid rate occurs once the downcomer<br />

fills with froth and backs liquid onto the<br />

tray above. Truncated or dynamically sealed<br />

downcomers can only operate between these two<br />

limits. This is important during the review of<br />

start-up procedures and when establishing the<br />

liquid rates required for stable operation.<br />

When the downcomer unseals, vapour flows<br />

up the downcomer. Once the vapour flow is high<br />

enough to prevent liquid flow into the downcomers<br />

or the pressure drop through the valve or<br />

sieve holes gets low enough, then liquid flows<br />

through the tray deck. Poor vapour-liquid mixing<br />

occurs and tray efficiency decreases. <strong>High</strong> <strong>capacity</strong><br />

trays can operate as dual-flow trays under<br />

some conditions. Vapour and liquid alternately<br />

flow through the same hole. Tray efficiency loss<br />

of 30–40 per cent has been observed in a xylene<br />

splitter when the downcomers unseal.<br />

Another potential problem area is the distance<br />

from the bottom of the truncated downcomer to<br />

the tray deck. It must be high enough to prevent<br />

the froth on the tray from reaching it, while<br />

providing sufficient cross-sectional area between<br />

the tray deck and edge of the truncated downcomer<br />

for vapour to escape. If the downcomer is<br />

too close to the tray deck, then the vapour flow<br />

area is choked. Thus, the active area under the<br />

downcomer is ineffective, which lowers overall<br />

tray <strong>capacity</strong>.<br />

If excess height is used, the column liquid<br />

<strong>capacity</strong> is reduced because the downcomer<br />

height is very short.<br />

<strong>High</strong> sieve or valve hole area in the active area<br />

also controls the tray operating stability. <strong>High</strong><br />

tray hole areas increase vapour <strong>capacity</strong>, but<br />

lower the vapour rate flexibility. As a rule, the<br />

higher the <strong>capacity</strong> through a given column<br />

diameter, the less flexibility is available. In fact,<br />

extreme tray designs have approached pointoperation<br />

and will only operate over a very<br />

limited range of vapour and liquid rates. They<br />

have no turn down capability.<br />

Case Study 1: Column efficiency<br />

Revamping a C 3 splitter with improved efficiency,<br />

high <strong>capacity</strong> trays increased column feed rate<br />

by 7 per cent, while maintaining fractionation.<br />

The column in this case study was operating at<br />

two distinct constraints: condenser and tray<br />

<strong>capacity</strong> limits. C 3 splitter reflux ratio and tray<br />

loading will decrease as column pressure is<br />

reduced because the propylene/propane relative<br />

volatility increases.<br />

Concurrently, low pressure reduces the propylene<br />

stream condensing temperature, which can<br />

lower the condenser <strong>capacity</strong> through reduced<br />

cooling water and propylene stream temperature<br />

differences.<br />

In this example, during low pressure operation<br />

6 PTQ Q4 2001 www.digitalrefining.com/article/1000325


the reflux ratio was lowest, but the<br />

condenser <strong>capacity</strong> limited unit feed<br />

rate. Increasing tower pressure alleviated<br />

the condensing limitation but<br />

increased the tray loads and flooded<br />

the column. Prior to the revamp, the<br />

column had high <strong>capacity</strong> trays,<br />

however, they had relatively low<br />

efficiency.<br />

C 3 splitter fractionation is more<br />

complex than many refinery services<br />

because of the impact of operating<br />

pressure and column efficiency on tray<br />

loading. Many times, when there is a<br />

bottleneck in column <strong>capacity</strong>, high<br />

<strong>capacity</strong> trays are specified without<br />

looking at the big picture and formulating<br />

the best revamp strategy.<br />

Quantifying the existing column and<br />

auxiliary (condenser) equipment limitations<br />

is critical before any revamp.<br />

Column efficiency evaluation showed<br />

current operation at the inflection point<br />

of the reflux (or reboil, reflux ratio)<br />

versus stage curve. Understanding fractionation<br />

efficiency sensitivity was<br />

essential to finding the best solution.<br />

Figure 4 is a curve for the separation,<br />

which analyses the reflux ratio versus<br />

stage curves. There are three distinct<br />

zones of operation shown on Figure 4<br />

and described in Table 1. They are<br />

represented by Zones A, B and C.<br />

For this splitter, the existing operation was on<br />

the borderline of Zones A and B. The most costeffective<br />

revamp strategy was to increase tray<br />

efficiency to stay within the condenser constraint.<br />

The existing splitter had 100 high <strong>capacity</strong> trays.<br />

The trays were set on 15in tray spacing<br />

throughout the column. The single phase feed<br />

entered the tower onto tray 45. The condenser<br />

used cooling tower water. The existing trays were<br />

a high <strong>capacity</strong> and low efficiency design.<br />

Column peripheral equipment and utility limitations<br />

prevented increasing feed rate with the<br />

low efficiency trays. The existing cooling water<br />

condensers were limited to 104 million Btu/hr<br />

due to cooling water availability.<br />

Increasing the cooling water supply would have<br />

required another cell to be added to the existing<br />

cooling tower. This required major capital investment<br />

and it could not be justified. Hence the<br />

Figure 4 Column efficiency vs reflux ratio curve<br />

Zone Sensitivity to efficiency Result<br />

A <strong>High</strong> Tower benefits from addition of stages or<br />

increased tray efficiency<br />

B Moderate Tower may not reap benefits of additional<br />

stages<br />

C Low Revamp to higher tray spacing is beneficial<br />

to gain <strong>capacity</strong>. Revamp with low<br />

efficiency trays is a good strategy<br />

Table 1<br />

Fractionation efficiency sensitivity<br />

condenser limit was a significant factor in the<br />

revamp. When operating in Zone A and B,<br />

increasing column <strong>capacity</strong> without increasing<br />

condenser <strong>capacity</strong> requires more column<br />

efficiency.<br />

Increasing column operating pressure raises<br />

the overhead vapour temperature and increases<br />

condensing <strong>capacity</strong> by raising propylene<br />

condensing temperature. However, this increase<br />

also raises tray vapour and liquid rates due to<br />

decreasing relative volatility as pressure<br />

increases. Both the condenser and tray capacities<br />

were limiting the unit feed rate. Column feed<br />

rate was a balance between the limitation<br />

imposed by the trays and the overhead condenser<br />

system.<br />

The revamp strategy was to increase the<br />

number of fractionation stages by using higher<br />

efficiency trays. The new tray design used a<br />

longer flow path length and design features to<br />

www.digitalrefining.com/article/1000325 PTQ Q4 2001 7


Figure 5 Increasing liquid handling flexibility<br />

minimise liquid gradient. Since the tower was<br />

operating in the Zone A part of the curve, additional<br />

efficiency reduced the required reflux<br />

ratio. Lower reflux ratio translated into greater<br />

throughput at existing condenser limitations.<br />

After the revamp the feed rate increased by 7 per<br />

cent.<br />

Post revamp operating tray efficiency increased<br />

and the reflux ratio decreased from 10.4:10.6 to<br />

9.2:9.4. Further analysis of product and intermediate<br />

tower samples indicates the tray efficiency<br />

is 88–92 per cent. This is an efficiency increase<br />

of 15 percentage points over the low efficiency<br />

tray. This revamp illustrates the strategy of<br />

revamping a tower for additional column efficiency<br />

when operating in Zone A or B of the<br />

stage versus reflux curve.<br />

Case Study 2: Improved flexibility<br />

In the previous case study, increasing column<br />

efficiency was the correct strategy given the<br />

constraints. In this case, an FCC depropaniser<br />

was limited by liquid handling flexibility. The<br />

column was operating in the middle of Zone C of<br />

Figure 4; therefore, reflux ratio is not sensitive<br />

to the number of trays and the tray efficiency.<br />

The column had 56 trays on 16in tray spacing.<br />

The design used short 12in deep truncated downcomers,<br />

which set the maximum and minimum<br />

liquid rate. Reboiler fouling limited available<br />

heat input as run-length progressed, therefore<br />

reflux ratio decreased. This reduced the liquid<br />

rates inside the column. Due to the short spacing<br />

of the internals, the liquid flexibility on the trays<br />

was small and the tray downcomers unsealed.<br />

This caused the trays to operate in a dual-flow<br />

manner with liquid and vapour flow through the<br />

downcomers and active area.<br />

A revamp strategy was formulated to increase<br />

operating flexibility. The 56 trays were analysed<br />

and it was confirmed that unsealing of the downcomers<br />

occurred as the reboiler fouled. A simple<br />

fix would be to retrofit the existing truncated<br />

downcomer dynamic seals with a lower slot area<br />

to increase liquid head loss and increase downcomer<br />

backup. This would eliminate the<br />

unsealing to meet the minimum rates, but then<br />

the design would not meet the maximum liquid<br />

rate.<br />

The problem was operating flexibility due to<br />

short tray spacing. Short tray spacing, in<br />

conjunction with truncated downcomers, yields<br />

low liquid rate flexibility.<br />

The revamp strategy focused on understanding<br />

the reflux versus column efficiency curve for this<br />

system. A key question was: “Does this tower<br />

need 56 trays for the required separation?”<br />

A revamp strategy was formulated based on<br />

future operating conditions of 115 per cent of<br />

current rates, while improving product separation<br />

due to higher reflux ratio. Operating range<br />

was specified as 105 per cent of design (115 per<br />

8 PTQ Q4 2001 www.digitalrefining.com/article/1000325


cent of current) with a turndown to 50 per cent<br />

of rates.<br />

The answer to this question comes directly<br />

from the reflux ratio versus stage (column efficiency)<br />

curve. The tower had 56 trays and was<br />

operating in the Zone C region of the curve; high<br />

tray count (more efficiency) was not a benefit.<br />

Therefore, a revamp strategy to decrease the<br />

number of trays was developed.<br />

The optimal revamp strategy was to reduce the<br />

number of trays from 56 to 44 new trays (Figure<br />

5). The tray spacing was increased to 20in. This<br />

yielded a tray vapour <strong>capacity</strong> increase of 12 per<br />

cent (square root of 20/16) with the additional<br />

benefits of improved liquid rate flexibility due to<br />

increased downcomer height. The downcomer<br />

height is a function of tray spacing and the<br />

distance of the truncated downcomer from the<br />

tray deck.<br />

As the truncated height was kept essentially<br />

constant, the downcomer plus weir height was<br />

increased by over 4in or approximately 25 per<br />

cent.<br />

By moving the operating point from Zone C to<br />

a Zone B operation, fewer trays are required<br />

without materially affecting the reboiler duty,<br />

condenser duty or reflux requirements. The key<br />

to using this curve is to understand the separation<br />

and the relative volatility of the specific<br />

system.<br />

Small errors in relative volatility in a low relative<br />

volatility system, such as a C 3 splitter, will<br />

result in large reflux ratio errors and major<br />

equipment design problems. With high relative<br />

volatility systems, like an FCC depropaniser,<br />

small relative volatility errors have much less<br />

impact. This revamp illustrates the strategy of<br />

revamping a tower for additional tray <strong>capacity</strong><br />

when operating in Zone C of the column efficiency<br />

curve. Column <strong>capacity</strong> and operating<br />

flexibility were driven by tray hydraulics, not<br />

column efficiency.<br />

Links<br />

More articles from: Process Consulting services<br />

More articles from the following categories:<br />

Mass Transfer & separation<br />

Revamps, shutdowns and Turnarounds<br />

www.digitalrefining.com/article/1000325 PTQ Q4 2001 9

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!