05.04.2013 Views

2012 Summer Symposium Program - Middlebury College

2012 Summer Symposium Program - Middlebury College

2012 Summer Symposium Program - Middlebury College

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

Page 12<br />

13<br />

Malcolm Littlefield ‘13<br />

Major: ENVS, CHEM<br />

National Science Foundation<br />

(Costanza-Robinson)<br />

Annie Mejaes ‘13<br />

Major: ENVS, CHEM<br />

National Science Foundation<br />

(Costanza-Robinson)<br />

Molly Costanza-Robinson<br />

Associate Professor of<br />

Chemistry and Environmental<br />

Studies<br />

14<br />

Adrienne Matunas ‘13<br />

Major: RELI, PHIL<br />

Undergraduate Collaborative<br />

Research Fund<br />

Yonna McShane<br />

Director of Learning Resources<br />

for CTLR<br />

<strong>Middlebury</strong> <strong>Summer</strong> Research <strong>Symposium</strong> <strong>2012</strong><br />

substantive section into thirds, we found that accurate, inaccurate, intrusive facts<br />

occur in differing patterns by time, as does the proportion of accurate facts for each<br />

interview. These findings have important implications for health professionals who<br />

interview children.<br />

Surfactant Modification of Montmorillonite for<br />

Environmental Contaminant Remediation<br />

Malcolm Littlefield, Annie Mejaes, and Molly Costanza-Robinson<br />

Department of Chemistry & Biochemistry, <strong>Middlebury</strong> <strong>College</strong>, <strong>Middlebury</strong> VT 05753<br />

Surfactant-modified clay minerals (organoclays) are increasingly being examined<br />

as a cost-effective, sorbent for environmental contaminants (e.g., for groundwater<br />

remediation). However, few studies have examined the relationship between the<br />

microstructure and chemistry of the organoclay and its capacity to adsorb various<br />

contaminants. Our work this summer involved preparing and characterizing<br />

a Na-montmorillonite that we modified with the cationic surfactant myristyl<br />

trimethylammonium bromide. The organomontmorillonite was prepared at various<br />

surfactant surface coverages (% of cation exchange capacity, CEC). X-ray diffraction<br />

revealed the basal spacing of 100 % CEC montmorillonite to be 17.8 Å, significantly<br />

larger than that for unmodified montmorillonite (12.5 Å). An expanded basal spacing<br />

may increase the clay’s adsorption capacity for larger contaminants. No uptake of<br />

aniline, a model contaminant, was observed for unmodified montorillonite, whereas<br />

1.2 mg/g of aniline was adsorbed by the 100% CEC modified montorillonite. We<br />

attribute these findings to the increased hydrophobicity of the modified clay surface,<br />

as well as the increased basal spacing. These preliminary findings, along with<br />

additional data, will greatly increase our ability to optimize clays for contaminant<br />

uptake.<br />

Utilization of Academic Support Services at the Center for Teaching,<br />

Learning, and Research<br />

Adrienne Matunas and Yonna McShane<br />

Center for Teaching, Learning, and Research, <strong>Middlebury</strong> <strong>College</strong>, <strong>Middlebury</strong> VT 05753<br />

The Center for Teaching, Learning, and Research offers an array of academic<br />

support services to <strong>Middlebury</strong> students, including peer and professional tutoring<br />

in writing, quantitative disciplines, languages, oral presentation skills, study skills,<br />

and time management. Literature reviews about postsecondary academic support<br />

reveal the widespread belief that learning centers at 4-year institutions serve a<br />

small segment of the student body, predominantly first-year students and students<br />

experiencing academic crises. At institutions like <strong>Middlebury</strong> where student<br />

achievement is very high, it is often assumed that few students seek tutoring, or that

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!