2012 Summer Symposium Program - Middlebury College
2012 Summer Symposium Program - Middlebury College
2012 Summer Symposium Program - Middlebury College
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13<br />
Malcolm Littlefield ‘13<br />
Major: ENVS, CHEM<br />
National Science Foundation<br />
(Costanza-Robinson)<br />
Annie Mejaes ‘13<br />
Major: ENVS, CHEM<br />
National Science Foundation<br />
(Costanza-Robinson)<br />
Molly Costanza-Robinson<br />
Associate Professor of<br />
Chemistry and Environmental<br />
Studies<br />
14<br />
Adrienne Matunas ‘13<br />
Major: RELI, PHIL<br />
Undergraduate Collaborative<br />
Research Fund<br />
Yonna McShane<br />
Director of Learning Resources<br />
for CTLR<br />
<strong>Middlebury</strong> <strong>Summer</strong> Research <strong>Symposium</strong> <strong>2012</strong><br />
substantive section into thirds, we found that accurate, inaccurate, intrusive facts<br />
occur in differing patterns by time, as does the proportion of accurate facts for each<br />
interview. These findings have important implications for health professionals who<br />
interview children.<br />
Surfactant Modification of Montmorillonite for<br />
Environmental Contaminant Remediation<br />
Malcolm Littlefield, Annie Mejaes, and Molly Costanza-Robinson<br />
Department of Chemistry & Biochemistry, <strong>Middlebury</strong> <strong>College</strong>, <strong>Middlebury</strong> VT 05753<br />
Surfactant-modified clay minerals (organoclays) are increasingly being examined<br />
as a cost-effective, sorbent for environmental contaminants (e.g., for groundwater<br />
remediation). However, few studies have examined the relationship between the<br />
microstructure and chemistry of the organoclay and its capacity to adsorb various<br />
contaminants. Our work this summer involved preparing and characterizing<br />
a Na-montmorillonite that we modified with the cationic surfactant myristyl<br />
trimethylammonium bromide. The organomontmorillonite was prepared at various<br />
surfactant surface coverages (% of cation exchange capacity, CEC). X-ray diffraction<br />
revealed the basal spacing of 100 % CEC montmorillonite to be 17.8 Å, significantly<br />
larger than that for unmodified montmorillonite (12.5 Å). An expanded basal spacing<br />
may increase the clay’s adsorption capacity for larger contaminants. No uptake of<br />
aniline, a model contaminant, was observed for unmodified montorillonite, whereas<br />
1.2 mg/g of aniline was adsorbed by the 100% CEC modified montorillonite. We<br />
attribute these findings to the increased hydrophobicity of the modified clay surface,<br />
as well as the increased basal spacing. These preliminary findings, along with<br />
additional data, will greatly increase our ability to optimize clays for contaminant<br />
uptake.<br />
Utilization of Academic Support Services at the Center for Teaching,<br />
Learning, and Research<br />
Adrienne Matunas and Yonna McShane<br />
Center for Teaching, Learning, and Research, <strong>Middlebury</strong> <strong>College</strong>, <strong>Middlebury</strong> VT 05753<br />
The Center for Teaching, Learning, and Research offers an array of academic<br />
support services to <strong>Middlebury</strong> students, including peer and professional tutoring<br />
in writing, quantitative disciplines, languages, oral presentation skills, study skills,<br />
and time management. Literature reviews about postsecondary academic support<br />
reveal the widespread belief that learning centers at 4-year institutions serve a<br />
small segment of the student body, predominantly first-year students and students<br />
experiencing academic crises. At institutions like <strong>Middlebury</strong> where student<br />
achievement is very high, it is often assumed that few students seek tutoring, or that