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L lies anywhere on the surface of a cone that makes an angle θ with the z axis such<br />
that<br />
The fourth quantum number is the spin magnetic quantum number ms. There are<br />
only two directions to exist for the electron spin. Either the spin is up or down<br />
relative to the z-axis. The values of the spin magnetic quantum number are<br />
ms = - ½, + ½ .<br />
___________________________________________________________________<br />
Solution to Question 2 (18 points)<br />
a) The Fermi energy for copper is 7.0 eV. (i) Find the probability of an energy level<br />
at 7.15 eV is being occupied by an electron at 300K if the electrons in copper follow<br />
the Femi-Dirac distribution function. (ii) Find the Fermi level at 0K if the density of<br />
electrons 8.75x10 22 cm -3 .<br />
Solution<br />
(i) The probability f(E) = ( E EF ) / kT<br />
1<br />
e<br />
For E = 7.15 eV, EF = 7 eV, kT = 0.026 eV<br />
f(E = 7.15 eV) = ( 7.<br />
15 7)<br />
/ 0.<br />
026<br />
1<br />
e<br />
<br />
(ii) The electron density n = g ( E)<br />
f ( E)<br />
dE<br />
0<br />
The density of states g(E) =<br />
1 <br />
8<br />
2m<br />
3<br />
h<br />
3/<br />
2<br />
1 <br />
E<br />
1/<br />
2<br />
The probability at T = 0K: f(E) = 1 for E < EF<br />
= 0 for E > EF<br />
8<br />
Then n =<br />
3/<br />
2 EF<br />
2m<br />
1/<br />
2 2 8<br />
E dE <br />
3<br />
h<br />
3<br />
3/<br />
2<br />
2m<br />
3/<br />
2<br />
E 3 F<br />
h<br />
0<br />
2 / 3<br />
= 3.11x10 -3 = 0.311 %<br />
2<br />
h 3n<br />
<br />
The Fermi level EF(0) = <br />
2m<br />
8<br />
<br />
34<br />
2<br />
22 6<br />
2<br />
( 6.<br />
63x10<br />
) 3(<br />
8.<br />
75x10<br />
x10<br />
) <br />
<br />
31<br />
2(<br />
9.<br />
1 10 )<br />
<br />
<br />
8 <br />
<br />
<br />
x <br />
1.<br />
154 x10 -18 = 7.213 eV<br />
J<br />
2 / 3