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L lies anywhere on the surface of a cone that makes an angle θ with the z axis such<br />

that<br />

The fourth quantum number is the spin magnetic quantum number ms. There are<br />

only two directions to exist for the electron spin. Either the spin is up or down<br />

relative to the z-axis. The values of the spin magnetic quantum number are<br />

ms = - ½, + ½ .<br />

___________________________________________________________________<br />

Solution to Question 2 (18 points)<br />

a) The Fermi energy for copper is 7.0 eV. (i) Find the probability of an energy level<br />

at 7.15 eV is being occupied by an electron at 300K if the electrons in copper follow<br />

the Femi-Dirac distribution function. (ii) Find the Fermi level at 0K if the density of<br />

electrons 8.75x10 22 cm -3 .<br />

Solution<br />

(i) The probability f(E) = ( E EF ) / kT<br />

1<br />

e<br />

For E = 7.15 eV, EF = 7 eV, kT = 0.026 eV<br />

f(E = 7.15 eV) = ( 7.<br />

15 7)<br />

/ 0.<br />

026<br />

1<br />

e<br />

<br />

(ii) The electron density n = g ( E)<br />

f ( E)<br />

dE<br />

0<br />

The density of states g(E) =<br />

1 <br />

8<br />

2m<br />

3<br />

h<br />

3/<br />

2<br />

1 <br />

E<br />

1/<br />

2<br />

The probability at T = 0K: f(E) = 1 for E < EF<br />

= 0 for E > EF<br />

8<br />

Then n =<br />

3/<br />

2 EF<br />

2m<br />

1/<br />

2 2 8<br />

E dE <br />

3<br />

h<br />

3<br />

3/<br />

2<br />

2m<br />

3/<br />

2<br />

E 3 F<br />

h<br />

0<br />

2 / 3<br />

= 3.11x10 -3 = 0.311 %<br />

2<br />

h 3n<br />

<br />

The Fermi level EF(0) = <br />

2m<br />

8<br />

<br />

34<br />

2<br />

22 6<br />

2<br />

( 6.<br />

63x10<br />

) 3(<br />

8.<br />

75x10<br />

x10<br />

) <br />

<br />

31<br />

2(<br />

9.<br />

1 10 )<br />

<br />

<br />

8 <br />

<br />

<br />

x <br />

1.<br />

154 x10 -18 = 7.213 eV<br />

J<br />

2 / 3

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