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Suggested Stage 2 Chemistry 2008 SACE Board of SA Exam ...

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© <strong>SA</strong>STA 2009 <strong>2008</strong> <strong>Exam</strong> Solutions 211<br />

Question 8 Comments<br />

(a)<br />

(b) (i)<br />

(ii) (1) [Any two <strong>of</strong>:]<br />

• Enzyme chain gains energy.<br />

• Hydrogen bonds/ion-dipole and dispersion forces are<br />

overcome.<br />

• The 3-D shape <strong>of</strong> the enzyme will change.<br />

Must mention:<br />

• If the structure <strong>of</strong> the enzyme changes then it is unable to<br />

carry out its biological function.<br />

(ii) (2)(A) CO2 + H2O → H2CO3<br />

(B)<br />

CO2 + H2O H2CO3<br />

Acidic or<br />

low pH<br />

(c) (ii) (1) 0.21 – 0.23<br />

(ii)<br />

(2) ppb = µg/L<br />

no. µg Cd = 3.5 x 0.010<br />

(3) ppb = µg/kg<br />

= 0.035 µg<br />

= = 0.035/0.00045 = 77.7777<br />

= 78 ppb (2 sf)<br />

[Any two <strong>of</strong>:]<br />

• Cd lamp is used<br />

• wavelength used is absorbed only by Cd<br />

• Na absorbs a different wavelength/does not absorb this<br />

wavelength<br />

Note:<br />

Take care when drawing<br />

or copying structures.<br />

Be careful with the<br />

positioning <strong>of</strong> the bonds.<br />

Note:<br />

Section <strong>of</strong> molecule<br />

therefore open at least<br />

one end or both.<br />

Note:<br />

Must have three distinct<br />

clear points for full<br />

marks.<br />

Note:<br />

1 mark for correct<br />

species<br />

1 mark for balancing<br />

Note:<br />

Should show full<br />

working for calculations.<br />

Note:<br />

Should show full<br />

working for calculations.<br />

Note:<br />

Must have two distinct<br />

clear points for full<br />

marks.<br />

(iii) Has non zero absorbance for zero concentration <strong>of</strong> cadmium. Note:<br />

Not does not start at zero

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