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Surface Plasmon Polaritons (SPPs) - Introduction and basic properties

Surface Plasmon Polaritons (SPPs) - Introduction and basic properties

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2<br />

1,6<br />

1,2<br />

0,8<br />

0,4<br />

0<br />

-0,4<br />

-0,8<br />

eps'<br />

Weak <strong>and</strong> strong molecular vibrations<br />

weak oscillator: ε‘ > 1<br />

wavenumber / cm -1<br />

eps''<br />

860 880 900 920 940<br />

caused by: molecular vibrations<br />

examples: PMMA, PS, proteins<br />

1<br />

0,8<br />

0,6<br />

0,4<br />

0,2<br />

0<br />

-0,2<br />

-0,4<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

-5<br />

-10<br />

strong oscillator: ε‘ < 0<br />

eps' eps''<br />

860 880 900 920 940<br />

wavenumber / cm -1<br />

crystal lattice vibrations<br />

SiC, Xonotlit, Calcite, Si 3 N 4<br />

25<br />

20<br />

15<br />

10<br />

5<br />

0<br />

-5<br />

-10

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