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Material Safety Data Sheet

Material Safety Data Sheet

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<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />

1. Chemical Product and Company Identification<br />

Common Name<br />

Synonym<br />

Catalogue number<br />

Supplier<br />

NEWS 610 Activator<br />

KAN 442195; PCD 5330; A-0019.501<br />

143 6401; 790 0018<br />

Area of Application : Industrial applications. Graphic Arts Imaging.<br />

Emergency telephone<br />

number<br />

For other EHS<br />

Information<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

NEWS 610 Activator<br />

Anitec Newspaper Company<br />

383 Dwight Street<br />

Holyoke, MA 01040<br />

USA<br />

Tel. (413) 538-9624<br />

In Case of Emergency (medical/roadside) (24hrs)<br />

Kodak Polychrome Graphics, Environmental Solutions Department;<br />

11465 Johns Creek Parkway, #260, Duluth, GA 30097; USA<br />

Phone: 1-877-574-7274 ext. 511, Additional phone: (770) 232-2133<br />

E-mail: PEP@kpgraphics.com, Fax: (770) 232-2150;<br />

2. Composition, Information on Ingredients<br />

1) Water 7732-18-5 85-90 Not available.<br />

2) Sodium sulfite 7757-83-7 5-10 Not available.<br />

3) Sodium thiosulfate 7772-98-7 1-5 Not available.<br />

4) 2-(Methylamino)ethanol 109-83-1 1-5 Not available.<br />

5) Glycerol 56-81-5 1-5 TWA: 10 (mg/m 3 )<br />

6) Hydroquinone 123-31-9


NEWS 610 Activator<br />

Medical Conditions<br />

Aggravated by<br />

Overexposure:<br />

Overexposure<br />

/Signs/Symptoms<br />

See Toxicological Information (section 11)<br />

4. First Aid Measures<br />

Eye Contact<br />

Skin Contact<br />

Inhalation<br />

Ingestion<br />

5. Fire Fighting Measures<br />

Flammability of the<br />

Product<br />

Auto-Ignition<br />

Temperature<br />

Hazardous thermal<br />

(de)composition<br />

products<br />

Fire Hazards in<br />

Presence of Various<br />

Substances<br />

Explosion Hazards in<br />

Presence of Various<br />

Substances<br />

Fire Fighting Media<br />

and Instructions<br />

Protective Clothing<br />

(Fire)<br />

Special Remarks on<br />

Fire Hazards<br />

Special Remarks on<br />

Explosion Hazards<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

Page: 2/6<br />

Repeated or prolonged exposure is not known to aggravate medical condition. Although responses have<br />

not been consistent across routes of exposure, species, or sex, some animal studies suggest that<br />

hydroquinone is weakly tumorigenic for rodents following the administration of high oral doses. In contrast,<br />

long-term epidemiological studies of employees engaged in the manufacturing and use of hydroquinone<br />

have shown no evidence of increased cancer risk from exposure to hydroquinone.<br />

-<br />

Check for and remove any contact lenses. In case of contact with eyes, rinse immediately with plenty of<br />

water. Seek medical attention.<br />

After contact with skin, wash immediately with plenty of water. If irritation persists, seek medical attention.<br />

Allow the victim to rest in a well-ventilated area. If irritation persists, seek medical attention.<br />

INDUCE VOMITING by sticking finger in throat. Have conscious person drink several glasses of water or<br />

milk. Seek medical attention.<br />

Non-flammable.<br />

Not applicable.<br />

sulfur oxides (SO2, SO3...) carbon oxides (CO, CO2)<br />

Not applicable.<br />

-<br />

Use DRY chemicals, CO2, water spray or foam.<br />

Be sure to use an approved/certified respirator or equivalent.<br />

-<br />

None.<br />

6. Accidental Release Measures<br />

Small Spill and Leak<br />

Large Spill and Leak :<br />

7. Handling and Storage<br />

Handling<br />

Storage<br />

Continued on Next Page<br />

:<br />

:<br />

:<br />

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste<br />

disposal container. If necessary: Neutralize the residue with a dilute solution of acetic acid. Finish<br />

cleaning by spreading water on the contaminated surface and dispose of according to local and regional<br />

authority requirements.<br />

Absorb with an inert material and put the spilled material in an appropriate waste disposal. Neutralize<br />

the residue with a dilute solution of acetic acid. Finish cleaning by spreading water on the contaminated<br />

surface and dispose of according to local and regional authority requirements.<br />

Avoid breathing vapors or spray mists. Avoid contact with skin and clothing. Do not get in eyes. Keep<br />

container closed. Use only with adequate ventilation. Wash thoroughly after handling.<br />

Store at room temperature 25°C (77°F) or lower. Prevent from freezing


NEWS 610 Activator<br />

8. Exposure Controls, Personal Protection<br />

Engineering Controls<br />

Personal Protection<br />

Eyes<br />

Body<br />

Respiratory<br />

Protective Clothing<br />

(Pictograms)<br />

Hands<br />

Feet<br />

Personal Protection in<br />

Case of a Large Spill<br />

1) Water<br />

2) Sodium sulfite<br />

3) Sodium thiosulfate<br />

4) 2-(Methylamino)ethanol<br />

5) Glycerol<br />

6) Hydroquinone<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

Page: 3/6<br />

Use good general ventilation(>10 air changes/hour) and engineering controls (local exhaust, filter's,<br />

process enclosures if necessary) to maintain airborne levels below ACGIH Threshold Limit Values (TLV)<br />

and OSHA Permissible Exposure Limits(PEL). Ensure that eyewash station and safety shower is proximal<br />

to the work-station location.<br />

Splash goggles.<br />

Lab coat.<br />

Wear appropriate respirator when ventilation is inadequate.<br />

Gloves (impervious).<br />

Not applicable.<br />

Splash goggles. Lab coat. Gloves (impervious). Ventilation is normally required when handling or using<br />

this product (typically 10 air changes per hour).<br />

Product Name Exposure Limits<br />

Consult local authorities for acceptable exposure limits.<br />

9. Physical and Chemical Properties<br />

Physical State and<br />

Appearance<br />

Molecular Weight<br />

Molecular Formula<br />

pH (1% Soln/Water)<br />

Boiling/Condensation<br />

Point<br />

Melting/Freezing Point<br />

Density<br />

Specific Gravity<br />

Vapor Pressure<br />

Vapor Density<br />

Volatility<br />

VOC by EPA Method<br />

24<br />

VOC Calculated<br />

Ionicity (in Water)<br />

Dispersion Properties<br />

Solubility<br />

Liquid.<br />

Not applicable.<br />

11 [Basic.]<br />

>100°C (212°F)<br />


NEWS 610 Activator<br />

10. Stability and Reactivity<br />

Stability and Reactivity<br />

Conditions of Instability<br />

Incompatibility with<br />

Various Substances<br />

Hazardous<br />

Decomposition Products<br />

Hazardous<br />

Polymerization<br />

The product is stable.<br />

-<br />

Incompatible with some strong acids.<br />

sulfur oxides (SO2, SO3...) carbon oxides (CO, CO2)<br />

Will not occur.<br />

11. Toxicological Information<br />

Toxicity to Animals<br />

Chronic Effects on<br />

Humans<br />

Other Toxic Effects on<br />

Humans<br />

12. Ecological Information<br />

Biodegradable/OECD<br />

BOD5 and COD<br />

Ecotoxicity<br />

Toxicity of the Products<br />

of Biodegradation<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

Water:<br />

ORAL (LD50): Acute: >90000 mg/kg [Rat].<br />

Sodium sulfite:<br />

ORAL (LD50): Acute: 6400 mg/kg [Rat].<br />

Sodium thiosulfate:<br />

ORAL (LD50): Acute: >5000 mg/kg [Rat].<br />

2-(Methylamino)ethanol:<br />

ORAL (LD50): Acute: 2340 mg/kg [Rat].<br />

Glycerol:<br />

ORAL (LD50): Acute: 12600 mg/kg [Rat].<br />

Hydroquinone:<br />

ORAL (LD50): Acute: 320 mg/kg [Rat].<br />

DERMAL (LD50): Acute: 900 mg/kg [Rat, Rabbit].<br />

Page: 4/6<br />

CARCINOGENIC EFFECTS: Classified None. by OSHA [Sodium sulfite]. Classified None. by OSHA<br />

[Sodium thiosulfate]. Classified None. by OSHA [2-(Methylamino)ethanol]. Classified A3 (Proven for<br />

animal.) by ACGIH [Hydroquinone]. Classified None. by OSHA [Hydroquinone]. Classified 3 (Not<br />

classifiable for human.) by IARC [Hydroquinone].<br />

Hazardous in case of skin contact (irritant), of eye contact (corrosive). Although responses have not been<br />

consistent across routes of exposure, species, or sex, some animal studies suggest that hydroquinone is<br />

weakly tumorigenic for rodents following the administration of high oral doses. In contrast, long-term<br />

epidemiological studies of employees engaged in the manufacturing and use of hydroquinone have<br />

shown no evidence of increased cancer risk from exposure to hydroquinone.<br />

Not available.<br />

13. Disposal Considerations<br />

Waste Information<br />

Consult your local or regional authorities.<br />

14. Transport Information<br />

DOT Classification :<br />

Continued on Next Page<br />

:<br />

:<br />

:<br />

:<br />

:<br />

-<br />

Ecotoxicity in water (LC50): 2600 mg/l 96 hours [Fish]. 69 mg/l 48 hours [Daphnia]. (Sodium sulfite). 100<br />

mg/l 96 hours [Fish]. (2-(Methylamino)ethanol).<br />

The product itself and its products of degradation are not toxic.<br />

Waste must be disposed of in accordance with federal, state and local environmental control regulations.<br />

Not a DOT controlled material (United States).<br />

Not applicable.<br />

Not applicable.


NEWS 610 Activator<br />

Marine Pollutant : -<br />

Hazardous Substances<br />

Reportable Quantity<br />

Special Provisions for<br />

Transport<br />

TDG Classification<br />

ADR/RID Classification<br />

IMO/IMDG<br />

Classification<br />

ICAO/IATA<br />

Classification<br />

HCS Classification<br />

U.S. Federal Regulations<br />

:<br />

:<br />

:<br />

:<br />

:<br />

:<br />

Not applicable.<br />

-<br />

Not applicable.<br />

Not controlled under TDG (Canada).<br />

Not controlled under ADR (Europe).<br />

Not controlled under IMDG.<br />

Not applicable.<br />

Not applicable.<br />

Not applicable.<br />

Not controlled under IATA.<br />

Not applicable.<br />

Not applicable.<br />

15. Regulatory Information<br />

International<br />

Regulations<br />

WHMIS<br />

(Canada)<br />

DSCL (EEC)<br />

International<br />

Lists<br />

State Regulations<br />

Continued on Next Page<br />

:<br />

:<br />

:<br />

:<br />

:<br />

CLASS: Irritating substance.<br />

Clean Water Act (CWA) 311: No products were found.<br />

Clean air act (CAA) 112 accidental release prevention: No products were found.<br />

Clean air act (CAA) 112 regulated flammable substances: No products were found.<br />

Clean air act (CAA) 112 regulated toxic substances: No products were found.<br />

CLASS D-2B: <strong>Material</strong> causing other toxic effects (TOXIC).<br />

No products were found.<br />

R36/38- Irritating to eyes and skin.<br />

-<br />

No products were found.<br />

California prop. 65: No products were found.<br />

Page: 5/6<br />

: TSCA 8(b) inventory: Water<br />

SARA 302/304/311/312 extremely hazardous substances: No products were found.<br />

SARA 302/304 emergency planning and notification: Hydroquinone<br />

SARA 302/304/311/312 hazardous chemicals: No products were found.<br />

SARA 311/312 MSDS distribution - chemical inventory - hazard identification: Sodium sulfite: immediate<br />

health hazard, delayed health hazard; 2-(Methylamino)ethanol: fire, immediate health hazard;<br />

Hydroquinone: immediate health hazard, delayed health hazard<br />

SARA 313 toxic chemical notification and release reporting: Hydroquinone 0.9%<br />

Clean Water Act (CWA) 307: No products were found.<br />

This product has been classified in accordance with hazard criteria of the Controlled Products Regulations<br />

and the MSDS contains all the information required by the Controlled Products Regulations.


NEWS 610 Activator<br />

16. Other Information<br />

Label Requirements<br />

Hazardous <strong>Material</strong><br />

Information System<br />

(U.S.A.)<br />

References<br />

Other Special<br />

Considerations<br />

:<br />

:<br />

:<br />

:<br />

Health<br />

Fire Hazard<br />

Reactivity<br />

Personal Protection<br />

Not available.<br />

Not available.<br />

* 2 National Fire<br />

0<br />

0<br />

Protection<br />

Association (U.S.A.) Health<br />

Validated by Kodak Polychrome Graphics on 2000-09-06. Verified by Kodak Polychrome Graphics.<br />

In Case of Emergency CALL 1-800-451-8346<br />

B<br />

Printed 2000-09-06.<br />

Page: 6/6<br />

CAUSES SEVERE SKIN IRRITATION. CAUSES EYE IRRITATION. MAY CAUSE ALLERGIC SKIN<br />

REACTION. MAY BE HARMFUL IF SWALLOWED. POSSIBLE CANCER HAZARD. CONTAINS<br />

MATERIAL WHICH MAY CAUSE CANCER BASED ON ANIMAL DATA.<br />

Notice to Reader<br />

To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its<br />

subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein.<br />

Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be<br />

used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.<br />

1<br />

0<br />

0<br />

Fire Hazard<br />

Reactivity<br />

Specific Hazard

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