Atom Transfer Radical Polymerization (ATRP): Current Status and ...

May 22, 2012 

Volume 45, Issue 10 

Pages 4015-4428 

PERSPECTIVE 

Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives 

Krzysztof Matyjaszewski 

pp 4015–4039 

Publication Date (Web): April 11, 2012 (Perspective) 

DOI: 10.1021/ma3001719 

Section: 

Chemistry of Synthetic High Polymers 

ARTICLES 

Acrylamide Homopolymers and Acrylamide–N-Isopropylacrylamide Block Copolymers by 

Atomic Transfer Radical Polymerization in Water 

D. A. Z. Wever, P. Raffa, F. Picchioni, and A. A. Broekhuis 

pp 4040–4045 

Publication Date (Web): May 10, 2012 (Article) 

DOI: 10.1021/ma3006125 

Section: 

Chemistry of Synthetic High Polymers

Structure/Properties Relationship for Bis(phenoxyamine)Zr(IV)-Based Olefin Polymerization 

Catalysts: A Simple DFT Model To Predict Catalytic Activity 

Gianluca Ciancaleoni, Natascia Fraldi, Roberta Cipullo, Vincenzo Busico, Alceo Macchioni, and Peter H. M. 

Budzelaar 

pp 4046–4053 


DOI: 10.1021/ma300343c 

Section: 


Binuclear Heteroligated Titanium Catalyst Based on Phenoxyimine Ligands: Synthesis, 

Characterization, and Ethylene (Co)polymerization 

Shuliang Han, Erdong Yao, Wei Qin, Shaofei Zhang, and Yuguo Ma 

pp 4054–4059 


DOI: 10.1021/ma300384w 

Section: 


New Degradable Alternating Copolymers from Naturally Occurring Aldehydes: Well- 

Controlled Cationic Copolymerization and Complete Degradation 

Yasushi Ishido, Arihiro Kanazawa, Shokyoku Kanaoka, and Sadahito Aoshima 

pp 4060–4068 


DOI: 10.1021/ma3004828 

Section: 


Functionalized Isothianaphthene Monomers That Promote Quinoidal Character in Donor– 

Acceptor Copolymers for Organic Photovoltaics 

Jessica D. Douglas, Gianmarco Griffini, Thomas W. Holcombe, Eric P. Young, Olivia P. Lee, Mark S. Chen, and Jean 

M. J. Fréchet 

pp 4069–4074 


DOI: 10.1021/ma300589k 

Section: 


Toward a Better Understanding of the Parameters that Lead to the Formation of Nonspherical 

Polystyrene Particles via RAFT-Mediated One-Pot Aqueous Emulsion Polymerization 

Wenjing Zhang, Franck D’Agosto, Olivier Boyron, Jutta Rieger, and Bernadette Charleux 

pp 4075–4084 


DOI: 10.1021/ma300596f 

Section: 


Synthesis and Properties of Highly Cross-Linked Thermosetting Resins of 

Benzocyclobutene-Functionalized Benzoxazine 

Yuanrong Cheng, Jun Yang, Yunxia Jin, Dunying Deng, and Fei Xiao 

pp 4085–4091 


DOI: 10.1021/ma3004218 

Section: 

Plastics Manufacture and Processing

Radical Polymerization in the Presence of Chain Transfer Monomer: An Approach to 

Branched Vinyl Polymers 

Li Jiang, Wenyan Huang, Xiaoqiang Xue, Hongjun Yang, Bibiao Jiang, Dongliang Zhang, Jianbo Fang, Jianhai Chen, 

Yang Yang, Guangqun Zhai, Lizhi Kong, and Shifeng Wang 

pp 4092–4100 


DOI: 10.1021/ma300443g 

Section: 


Fullerene-Functionalized Donor–Acceptor Block Copolymers through Etherification as 

Stabilizers for Bulk Heterojunction Solar Cells 

Maria Heuken, Hartmut Komber, Tim Erdmann, Volodymyr Senkovskyy, Anton Kiriy, and Brigitte Voit 

pp 4101–4114 

Publication Date (Web): April 30, 2012 (Article) 

DOI: 10.1021/ma300473w 

Section: 


Conjugated Polymers of Rylene Diimide and Phenothiazine for n-Channel Organic Field- 

Effect Transistors 

Weiyi Zhou, Yugeng Wen, Lanchao Ma, Yunqi Liu, and Xiaowei Zhan 

pp 4115–4121 


DOI: 10.1021/ma3005058 

Section: 


Fluorescence Turn-On Sensing of Anions Based on Disassembly Process of Urea- 

Functionalized Poly(phenylenebutadiynylene) Aggregates 

Ryosuke Sakai, Atsushi Nagai, Yasuyuki Tago, Shin-ichiro Sato, Yoshinobu Nishimura, Tatsuo Arai, Toshifumi Satoh, 

and Toyoji Kakuchi 

pp 4122–4127 


DOI: 10.1021/ma300481j 

Section: 

Inorganic Analytical Chemistry

Synthesis of π-Conjugated Polymers Containing Fluorinated Arylene Units via Direct 

Arylation: Efficient Synthetic Method of Materials for OLEDs 

Wei Lu, Junpei Kuwabara, Takayuki Iijima, Hideyuki Higashimura, Hideki Hayashi, and Takaki Kanbara 

pp 4128–4133 


DOI: 10.1021/ma3004899 

Section: 


Photopolymerization of N-Vinylcarbazole Using Visible-Light Harvesting Iridium Complexes 

as Photoinitiators 

Jacques Lalevée, Frédéric Dumur, Cédric R. Mayer, Didier Gigmes, Gihane Nasr, Mohamad-Ali Tehfe, Sofia Telitel, 

Fabrice Morlet-Savary, Bernadette Graff, and Jean Pierre Fouassier 

pp 4134–4141 


DOI: 10.1021/ma3005229 

Section: 


Synthesis, Purification, and Characterization of Well-Defined All-Conjugated Diblock 

Copolymers PF8TBT-b-P3HT 

Michael Sommer, Hartmut Komber, Sven Huettner, Rhiannon Mulherin, Peter Kohn, Neil C. Greenham, and Wilhelm 

T. S. Huck 

pp 4142–4151 


DOI: 10.1021/ma300533k 

Section: 


Termination and Transfer Kinetics of Sodium Acrylate Polymerization in Aqueous Solution 

Johannes Barth and Michael Buback 

pp 4152–4157 


DOI: 10.1021/ma202457x 

Section: 


One-Step Synthesis of Amphiphilic, Double Thermoresponsive Diblock Copolymers 

Jan Weiss and André Laschewsky 

pp 4158–4165 


DOI: 10.1021/ma300285y 

Section: 


Renewable Biobased Polymeric Materials: Facile Synthesis of Itaconic Anhydride-Based 

Copolymers with Poly(L-lactic acid) Grafts 

Tomoya Okuda, Kiyoaki Ishimoto, Hitomi Ohara, and Shiro Kobayashi 

pp 4166–4174 


DOI: 10.1021/ma300387j 

Section: 


Synthesis of Aliphatic Polyamide Dendrimers Based on Facile Convergent Method 

Yumiko Ito, Tomoya Higashihara, and Mitsuru Ueda 

pp 4175–4183 


DOI: 10.1021/ma300735w 

Section: 


Ring-Opening Polymerizations of 1,3-Dehydroadamantanes: Synthesis of Novel Thermally 

Stable Poly(1,3-adamantane)s 

Sotaro Inomata, Shin-ichi Matsuoka, Shiko Sakai, Hiroyuki Tajima, and Takashi Ishizone 

pp 4184–4195 


DOI: 10.1021/ma300395s 

Section: 


Macromolecular Ligands for Gadolinium MRI Contrast Agents 

Yang Li, Mariana Beija, Sophie Laurent, Luce vander Elst, Robert N. Muller, Hien T. T. Duong, Andrew B. Lowe, 

Thomas P. Davis, and Cyrille Boyer 

pp 4196–4204 


DOI: 10.1021/ma300521c 

Section: 


Chain Transfer Kinetics of Acid/Base Switchable N-Aryl-N-Pyridyl Dithiocarbamate RAFT 

Agents in Methyl Acrylate, N-Vinylcarbazole and Vinyl Acetate Polymerization 

Daniel J. Keddie, Carlos Guerrero-Sanchez, Graeme Moad, Roger J. Mulder, Ezio Rizzardo, and San H. Thang 

pp 4205–4215 


DOI: 10.1021/ma300616g 

Section: 


Pressure Quench of Flow-Induced Crystallization Precursors 

Zhe Ma, Luigi Balzano, and Gerrit W. M. Peters 

pp 4216–4224 


DOI: 10.1021/ma2027325 

Section: 

Physical Properties of Synthetic High Polymers

Polymer Dynamics in PEG-Silica Nanocomposites: Effects of Polymer Molecular Weight, 

Temperature and Solvent Dilution 

So Youn Kim, Henriette W. Meyer, Kay Saalwächter, and Charles F. Zukoski 

pp 4225–4237 


DOI: 10.1021/ma300439k 

Section: 

Physical Properties of Synthetic High Polymers 

Electrical Conductivity of Electrospun Polyaniline and Polyaniline-Blend Fibers and Mats 

Yuxi Zhang and Gregory C. Rutledge 

pp 4238–4246 


DOI: 10.1021/ma3005982 

Section: 

Textiles and Fibers

Extremely High Thermal Resistive Poly(p-phenylene benzobisoxazole) with Desired Shape 

and Form from a Newly Synthesized Soluble Precursor 

Takahiro Fukumaru, Tsuyohiko Fujigaya, and Naotoshi Nakashima 

pp 4247–4253 


DOI: 10.1021/ma3006526 

Section: 


Multilength Scale Studies of the Confined Crystallization in Poly(L-lactide)-block- 

Poly(ethylene glycol) Copolymer 

Jingjing Yang, Yongri Liang, Jun Luo, Chuanzhuang Zhao, and Charles C. Han 

pp 4254–4261 


DOI: 10.1021/ma202505f 

Section: 


Morphological Phase Behavior of Poly(RTIL)-Containing Diblock Copolymer Melts 

Vincent F. Scalfani, Erin F. Wiesenauer, John R. Ekblad, Julian P. Edwards, Douglas L. Gin, and Travis S. Bailey 

pp 4262–4276 


DOI: 10.1021/ma300328u 

Section: 


On the Measurements of Rigidity Modulus of Soft Materials in Nanoindentation Experiments 

at Small Depth 

Maxim E. Dokukin and Igor Sokolov 

pp 4277–4288 


DOI: 10.1021/ma202600b 

Section: 

Surface Chemistry and Colloids

Theory of Lamellar Superstructure from a Mixture of Two Cylindrical PS–PMMA Block 

Copolymers 

John G. Spiro, Nicolas Illy, Mitchell A. Winnik, Jeffrey D. Vavasour, and Mark D. Whitmore 

pp 4289–4294 


DOI: 10.1021/ma202717p 

Section: 


Surface Organization of a Perfluorocarbon-Functionalized Polystyrene Homopolymer 

Michael D. Dimitriou, Elisa Martinelli, Daniel A. Fischer, Giancarlo Galli, and Edward J. Kramer 

pp 4295–4302 


DOI: 10.1021/ma300069e 

Section: 


Combinatorial Block Copolymer Ordering on Tunable Rough Substrates 

Manish M. Kulkarni, Kevin G. Yager, Ashutosh Sharma, and Alamgir Karim 

pp 4303–4314 


DOI: 10.1021/ma300169a 

Section: 


Morphological Evolution within Spin-Cast Ultrathin Polymer Blend Films Clarified by a 

Freestanding Method 

Hong Zhang and Shinji Takeoka 

pp 4315–4321 


DOI: 10.1021/ma3005394 

Section: 


Glucose-Functionalized, Serum-Stable Polymeric Micelles from the Combination of Anionic 

and RAFT Polymerizations 

Ligeng Yin, Molly C. Dalsin, Antons Sizovs, Theresa M. Reineke, and Marc A. Hillmyer 

pp 4322–4332 


DOI: 10.1021/ma300218n 

Section: 

Pharmaceuticals 

Bridged DNA Circles: A New Model System To Study DNA Topology 

Alexander Vologodskii 

pp 4333–4336 


DOI: 10.1021/ma300520x 

Section: 

General Biochemistry 

Thermoresponsive Poly(2-oxazoline) Block Copolymers Exhibiting Two Cloud Points: 

Complex Multistep Assembly Behavior 

Loan T. T. Trinh, Hanneke M. L. Lambermont-Thijs, Ulrich S. Schubert, Richard Hoogenboom, and Anna-Lena 

Kjøniksen 

pp 4337–4345 


DOI: 10.1021/ma300570j 

Section: 


How Does DNA Complex with Polyethylenimine with Different Chain Lengths and Topologies 

in Their Aqueous Solution Mixtures? 

Zhuojun Dai and Chi Wu 

pp 4346–4353 


DOI: 10.1021/ma2027963 

Section: 

Pharmaceuticals 

Dynamic Patterning in PEO-Based Single Ion Conductors for Li Ion Batteries 

Kokonad Sinha, Wenqin Wang, Karen I. Winey, and Janna K. Maranas 

pp 4354–4362 


DOI: 10.1021/ma300051y 

Section: 


Quantitative Viscoelastic Mapping of Polyolefin Blends with Contact Resonance Atomic 

Force Microscopy 

Dalia G. Yablon, Anil Gannepalli, Roger Proksch, Jason Killgore, Donna C. Hurley, Jean Grabowski, and Andy H. 

Tsou 

pp 4363–4370 


DOI: 10.1021/ma2028038 

Section: 


Polymer Detachment Kinetics from Adsorbing Surface: Theory, Simulation and Similarity to 

Infiltration into Porous Medium 

Jaroslaw Paturej, Andrey Milchev, Vakhtang G. Rostiashvili, and Thomas A. Vilgis 

pp 4371–4380 


DOI: 10.1021/ma202671n 

Section: 


Computer Simulation Studies of Chain Dynamics in Polymer Brushes 

Daniel Reith, Andrey Milchev, Peter Virnau, and Kurt Binder 

pp 4381–4393 


DOI: 10.1021/ma202745b 

Section: 


Quasielastic Neutron Scattering Study on the Dynamics of Poly(alkylene oxide)s 

C. Gerstl, G. J. Schneider, A. Fuxman, M. Zamponi, B. Frick, T. Seydel, M. Koza, A.-C. Genix, J. Allgaier, D. 

Richter, J. Colmenero, and A. Arbe 

pp 4394–4405 


DOI: 10.1021/ma3003399 

Section: 


Sphere-to-Cylinder Transitions in Thin Films of Diblock Copolymers under Shear: The Role of 

Wetting Layers 

Alexandros Chremos, Paul M. Chaikin, Richard A. Register, and Athanassios Z. Panagiotopoulos 

pp 4406–4415 


DOI: 10.1021/ma300382v 

Section: 


How Deformation Enhances Mobility in a Polymer Glass 

Yongchul G. Chung and Daniel J. Lacks 

pp 4416–4421 


DOI: 10.1021/ma300431x 

Section: 


NOTES

Why RNA and Protein Chains Are Linear and Not Colliding inside Nuclear Pores 

Chi Wu 

pp 4422–4424 

Publication Date (Web): May 8, 2012 (Note) 

DOI: 10.1021/ma300456d 

Section: 

General Biochemistry 

Synthesis and Intramolecular Charge-Transfer Interactions of a Donor–Acceptor Type 

Polymer Containing Ferrocene and TCNAQ Moieties 

Wenyi Huang and Chang Dae Han 

pp 4425–4428 

Publication Date (Web): May 10, 2012 (Note) 

DOI: 10.1021/ma300226m 

Section:

Atom Transfer Radical Polymerization (ATRP): Current Status and ...

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