Process Integral Development Eng&Tech - Equilabo.com

PROCESS INTEGRAL DEVELOPMENT ENG&TECH
MICROACTIVITY–REFERENCE CATALYTIC REACTOR
Company Profile
Microactivity Reference data sheet MA
Microactivity Reference Catalytic Reactor
Microactivity Reference Worldwide Users
Scientific Publications
Microactivity Reference Configuration & Options
Our Primary Products And Services
Gasification Pilot Plant data sheet GS
Four Runs Microactivity Test MAT-ASTM D3907 data sheet MT
Continuous Polymerization Microplant data sheet PL
Supercritical Extraction Pilot Plant data sheet SF
Customized Pilot Plants data a sheet PP
Congress Participation
R&D Activities & Patents
Accreditations/Certifications
Our Customers Opinions

PID Eng&Tech was born in 2003 as a spin-off company of Spanish
Council for Scientific Research (CSIC) with 20 years of previous
accumulated experience. The Process Control Group of the Institute
of Catalysis and Petrochemistry (ICP) of the CSIC have devoted its
activity since 1989 to the development of technologies dedicated to
improving design, construction and operation mode of laboratoryscale
reactors and micro-scale pilot plants, and their data acquisition,
supervisory and control systems. PID Eng&Tech was awarded with
the prize of the "Contest of Ideas for Spin-off companies of
Researchers”, granted by the Universities and Research General Management.
His Royal Highness, the Prince of Spain,
Don Felipe de Borbón, at the inauguration
PID Eng&Tech staff is formed by experts with
multidisciplinary backgrounds in chemical engineering,
electronics, automated and software engineering.
Launched in 2003, with a head office in the Scientific
Park of Madrid, Process Integral Development
Eng&Tech was able to put into practice all the
experience, technological development and
innovations achieved over many years of working in
engineering field. From 2005, PID Eng&Tech's office
and laboratories are situated in Colmenar Viejo
(Madrid), near the Regional Park of Hoyo de
Manzanares.
PID Eng&Tech primary target market are universities and research centres, both private and public
sectors, which fulfil their research activities within the fields of basic chemistry, petrochemistry,
environment, catalysis, agrochemistry and food technology, supercritical fluid extraction and new
energies.
In addition, the company has a worldwide net of distributors that cover the following countries and
areas: The United States of America, Canada and Mexico, Germany, Switzerland and Austria,
Belgium, Italy, the Netherlands, Egypt, India, Saudi Arabia and the Middle East.
Process Integral Development Eng&Tech
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pid@pidengtech.com
PH: +34 918 459 930
FAX: +34 918 486 454
C/ Plomo 15 – Pol. Ind. Sur
E-28770 Colmenar Viejo
Madrid – Spain
www.pidengtech.com

The MICROACTIVITY-Reference is an automatic and computerized laboratory reactor for reactions of catalytic microactivity with
reactor bypass, preheater evaporator, pressure control valve and other process layouts in hot box, which avoids the possible
condensation of volatile products, at the time that preheats the reactants efficiently.
The MICROACTIVITY-Reference consists of an ATMOSPHERIC PRESSURE BASIC UNIT and some series of EXTRA PACKAGES
that improve or modify its efficiency. It is a single structure that contains the electronic unit, control and MFC’s system and includes the
hot box where the reactor and process valves are located. The system has local control and on-line remote control, based on TCP/IP
Ethernet communications with distributed control structure. A complete and elaborated security system is integrated in
microprocessor, independent of the computer.
For reactions at high pressure that involve separation of gases and liquids, a new system of level control of the condensed liquid is
introduced with almost no dead volume (0.3 ml), so that the sample of the liquid outlet is the condensed product mixture formed at the
very last minutes of reaction. A wide variety of reactions has been carried out in our reactors: Hydrocracking, Hydrotreating,
Isomerization, Hydrogenation, Hydrodesulphurization (HDS), Oxidation, Hydrodenitrogenation (HDN), Polymerization, Reforming
(aromatization), steam reforming, etc. Strategic alliances with our customers have induced to some of the most important technological
solutions at present for a variety of catalytic processes.
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MICROACTIVITY-Reference data sheet
BAS I C UNI T FEAT URES :
TFT touch screen process set-up.
Hotbox in SS 316 with conv ector of hot air. Max. recommended
temperature 180ºC ± 1ºC.
Reactor ov en in inox 304. Max. temperature 950ºC, ± 2ºC. Low
thermal inertia.
Tubular reactor AE in inox 316, max. recommended temperature
700ºC.i.d.=9,2 mm, L=300 mm, f ittings AE SF 562 CX. Porous
plate in Hastelloy C-276, 20 microns,
Thermocouple Ø=1,5 mm, incoloy, directly in cataly st bed,
without thermowell.
Valv e VICI 6 ports, 2 positions, 280ºC, 100 bar, f or reactor
by pass.
3 MFC’s Hi-Tec Bronkhorst f or a Basic Unit, precision 1% F.S.,
elastomers compatible with the process.
3 shut-off valv es, 3 check-v alv es and a gas-mixer in a Basic Unit,
6 MFC’s max.
Thermoelectric unit f or liquids condenser / separator.
Check-v alv e f or f eeding of liquids, cracking pressure 10 psig.
Spiral lay out f or liquid ev aporator or preheater and gases preheater.
Pressure transducer in the atmospheric or high-pressure unit.
250ºC heated line to chromatograph connection.
The CG unit is not included in this off er. HP or Varian is
recommended with sof tware f or Windows.
Furnace & ov en powered through 3 SSR proportional control 4/20
mA by phase angle control.
Security sy stem based on integrated microprocessor RS 485
(detector of flow f ail, pressure, temperature, lev el in separator).
Max. work pressure 100 bar. Work pressure in a Basic Unit: 1
bar.
Lay out, f ittings and v alv es are in inox 316, with v ery low dead
v olume, Hoke-Gy rolok, Swagelok, Autoclav e Engineers,
VICI-Valco quality .
Friendly superv ision and distributed control sof tware in real time
Process@ digital communication, Ethernet remote control.
Includes Pentium IV. 17” TFT. Process@ sof tware f or Windows.
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EXT RA P ACKAGES :
MFC: 4th, 5th and/or 6th MFC’s with power supply and v alv es.
PRES: High Pressure Unit includes pressure control system, based
on micrometric serv o-controlled v alv e, 100 bar max, +/-0.2 bar,
210ºC. PID Eng&Tech patented design. PID loop controller.
PUMP: Gilson HPLC liquid pump, 0.01-5 ml/m, 400 bar. Digital
communications.
LEVEL: Liquid/gas separator with lev el control f or operation with
liquids and gases at high pressure in continuous mode, zero dead
v olume, based on micrometric valv e serv o-controlled and capacitiv e
sensor lev el with approx. 0.3cc dead v olume with precision +/-
0.1cc in lev el control. 100 bars. PID Eng&Tech patented design.
TWO LIQUID PHASES SEPAR ATOR: New upgraded application
f or use in Fisher-Tropsch (GTL) reactions. At real time separation at
high pressure is obtained Water + Hy drocarbons + gases.
SC ALE: Scale f or weighting liquid output in real time. Digital
communications module.
MFM: MF M in exit gases line (f or on-line and in real time
superv ising procedures).
VICI: 2 nd VICI v alv e, 6 ports, 2 positions. Only for special purposes.
REAC: Construction materials of the reactor: Hastelloy C or X,
Inconel, Titanium, and special dimensions (id= 5.2 or 13.1 mm).

ATMOSPHERIC PRESSURE
BASIC UNIT
- Tubular reactor Autoclav e Engineers 700º with
porous plate
- Thermocouple, directly in cataly st bed
- Hotbox 170ºC
- VICI v alv e 6 ports, f or reactor by pass.
- 3 MFC’s, Hi-Tech Bronkhorst
- Thermoelectric unit f or liquids condenser /
separator.
- Microprocessor f or security integrated system
- 2 Control loops f or temperature
- 6 Control dev ices f or MFC’s.
- Work pressure in atmospheric basic unit: 1 bar.
- Design pressure: 100bar
- Lay out, f ittings and v alv es in inox 316L, v ery
low dead v olume
Friendly superv ision and distributed control
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MICROACTIVITY-Reference data sheet
MICROACTIVITY CATALYTIC REACTOR
FOR LABORATORY TESTS
450 ºC 500 ºC 550 ºC 600 ºC 680 ºC 700 ºC 720 ºC
30 50 70 90 110 130 150 170 190 210 230
Time of reac tion (min)
HIGH PRESSURE UNIT
FOR GASES ONLY
Atmospheric Pressure Basic Unit &:
- Pressure control sy stem, based on serv ocontrolled
micrometric v alv e by 1 st
precision stepper motor
- PID Eng&Tech patented design
- 100 bar max. ± 0.2 bar
- Control loop and 100 bar pressure
transducer
- Digital communications
- HPLC Gilson pump, 400 bar, 0.01-5
ml/min
- Up to 4, 5 or 6 Mass Flow Controllers
- Scale in liquid outlet
- Mass Flow Meter in gas outlet
- Construction materials or reactor
dimensions
- 2nd VICI-Valco v alv e for special
proposals
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HIGH PRESSURE UNIT
WITH LIQUID-GAS SEPARATOR
High Pressure Basic Unit &:
- Liquid/gas separator with lev el control,
in continuous mode, based on serv ocontrolled
micrometric v alv e and
capacitiv e sensor lev el with approx.
0.3cc dead v olume
- PID Eng&Tech patented design
- Cooling by Peltier thermoelectric eff ect
- Control loop and capacitiv e sensor
- Digital communications
- Two models: L1 or L2 (two phases)
EXTRA PACKAGES

The reference in modular catalytic reactor…
The Microactivity-Reference reactor (WO-2006008328 / EP-1757930 / US-2008063565) is probably
the most advanced worldwide modular laboratory system for measurement of catalytic activity and
selectivity. PID Eng&Tech, is a worldwide leading company at sector of Microreactors for Catalytic
studies. This instrument has been developed as a standard unit that can be adapted to whatever
performance is needed for catalytic testing through different configurations and options.
The Microactivity-Reference is a
compact reactor that is completely
automated. It is equipped with cuttingedge
process control technology in the
market. This enables the user to
program a series of experiments from
the computer, even on the network, and
obtain real-time results with the highest
degree of reproducibility and accuracy.
This equipment has been designed to
save time and resources at both,
catalyst development stage and factory
report process during catalyst
screening.
Originally designed by and for
researchers at Instituto de Catálisis y
Petroleoquímica of CSIC, Spain,
incorporating 20 years of continuous feedback from the most prestigious Laboratory Researchers, the
Microactivity-Reference has become an international reference with more than 170 units worldwide
studying all types of catalytic reactions. It is backed by its reliability, versatility, operating simplicity and
minimal maintenance.
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The patented control systems have been
specifically developed for this equipment.
They account for operating at the microscale.
There are no systems with similar
characteristics in the market for working with
microflows.
Microactivity-Reference is a universal piece of
equipment that provides great versatility. It
operates with flows that range from tens of
ml/min to even liters/min, and pressures
ranging vacuum to 100 bar (with the same
pressure control valve). The reaction
temperature ranges from room temperature to
1000ºC (using special material reactors).
The equipments of PID Eng & Tech are certified according to European standards PED97/23/EC
(pressure equipment), EN61326 EMC (Electromagnetic Compatibility) and 73/23/EEC (LVD-
Electrical Safety).

the Basic unit…
The basic unit , the simplest one, designed for working at atmospheric pressure, includes a mixing
gases unit based on MFCs with three units for the standard equipment, a tubular reactor SS316 with a
9 mm inner diameter, on the inside of a radiating oven capable of reaching 1000ºC with very low
thermal inertia, a reactor bypass enables isolating it while the feed analysis is being performed, and a
liquid-gas separator (cooled via thermoelectric effect) at the outflow separates liquid products. The
gases are fed to the analysis system via a temperature transfer line of up to 300ºC.
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All components that comprise the equipment
are housed inside of a hot box. This makes it
possible to keep the incoming and outgoing
product feed lines at a temperature of up to
190ºC. This prevents volatile products
condensation, thus maintaining the entire
process’s path insulated, This gives stability to
the flows, and prevents the presence of cold
points.
The basic equipment includes the hot box, the
control systems and a sophisticated safety
system; which makes it a piece of equipment
with an extraordinary level or reliability. Furthermore, this system may be configured by the user via a
local touch-screen, independent of the computer according to a distributed control philosophy. It thus
gives maximum priority to the safety of the equipment itself and its users. Finally, communication via
Ethernet between the equipment and the controlling computer makes it possible to program
experimental formulas, acquire system data and remote control from any workstation.
configuring the unit…
(P) High pressure: This option adds a pressure control loop to the basic unit; it enables working up to
100 bar with an accuracy of 0.1bar. Pressure control is based on a servo motorized micrometric
regulation valve (WO-2006021603 / EP-1775504 / US-2007241296) that gives it maximum stability in
pressure control thus minimizing the piston flow pulse effect of the stream that flows across the
catalyst bed. This system, developed especially for the Microactivity-Reference, deliver excellent
reproducibility in experimental data.
(G) Liquid Feed: This option enables a liquid feed via an HPLC pump, for working in either the liquid
or steam phase, and operating at pressures of up to 100 bar. The pump is installed with the necessary
accessories to ensure a continuous flow that is precise and without pulse, even when the feed is to be
evaporated.
(L1) High pressure liquid-gas separator: A microvolume system
for liquid-gas separation at a reactor’s outflow that operates at high
pressure (WO-2006021604 / EP-1757911 / US-2007238753) is
perhaps the Microactivity-Reference main contribution to quick
evolution and development in experimentation in the field of catalysis.
With a dead volume less than 0.5 ml, this system enables real time
separation of condensables, thus making it possible to learn the
composition of the liquid products obtained during the first reaction
minutes. This makes it possible to study reaction kinetics and catalyst
deactivation since the condensate during reaction is representative of
the last few minutes.
(L2) High pressure liquid-liquid-gas separator: This is the latest
evolution with which PID Eng&Tech contributes the advance in
catalytic reaction control. This configuration option (patent pending:
P200930603) is an evolution of the aforementioned liquid-gas
separating system. It enables separation of two non-miscible liquid
fractions, e.g. for use in Fisher-Tropsch reactions (GTL). The highpressure
separator has no appreciable dead volume and produces three differentiated phases in real
time: the condensable hydrocarbon, water and the gaseous fraction with lighter hydrocarbons.

and the options…
Starting with a basic unit, and through the configuration options, the Microactivity-Reference unit can
be customized for working at high pressure with the possibility of feeding liquids, or with two highpressure
liquid-gas separating models. The different options adapt the Microactivity-Reference reactor
to match any project requirement. The know-how acquired during the execution of more than 170
installations enables us to configure a unit tailored to each user and process’s specific needs. Some
representative options are listed below:
Optional reactors of 5, 13 and 17 mm in inner diameter, in Hastelloy C276, Hastelloy X,
Inconel 600, Inconel 625, SS310 materials and others. Allowing adapting the unit to the
specific characteristics of reaction type, temperature, pressure and reacton feed.
The system can incorporate up to 6 MFCs without changing the original configuration. The
outstream can be measured by a mass flow meter (MFM) installed at the gas exhaust or
weight scales (both for the feed vessel and for the liquid outflow); thus, it is possible to monitor
the system evolution and mass balance.
In systems with high-viscosity liquids, e.g. an HVGO, the HPLC pump, feed vessel and the hot
box’s external path is heated at 80ºC.
A second and even a third six-port valve switches between up/down flow through the catalyst
bed or, for instance, be used for bypassing the L/G separator, in the event the unit is used for
reactions where there is no liquid present.
Other options enable additional evaporators, separator temperature control, ovens with special
dimensions, pressures above 100 bar, more than one liquid feed pump, fluidized beds, two or
more serial units to be installed with different operating pressures, among others. It is also
possible to prepare complete laboratories with 8 or 16 Microactivity-Reference units with
adaptable configuration.
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(more information on web site)
CUSTOMER COMPAN Y / CENTER COUNTRY UNITS
Dr. A. Aguay o /Dr. J. M. Arandes Univ ersidad del País Vasco 6
Dr. A. Jiménez / Dr. Blanco Univ ersidad de Malaga 2
Dr. A. Pintar National Institute of Chemistry Slov enia 1
Dra. L. Daza Instituto de Catálisis y Petroleoquímica / CIEMAT 7
Dr. A. Selv anathan / Dr. Debashis SABIC Research &Technology Badadora India 2
Dr. C. Jiménez Univ ersidad de Córdoba 1
Dr. Costas N. Costa Univ ersity of Cy prus Cy prus 2
Dr. E. Gaigneaux / P. Ruíz Catholic Univ ersity of Louv ain Belgium 2
Dra. Gomez /Dr. Gilarranz /Dr. Casas Univ ersidad Autónoma de Madrid 4
Dr. Israel E. Wachs Lehigh Univ ersity USA 1
Dr. J. A. Odriozola / Dr. Ollero / Dr. Munuera Univ ersidad de Sev illa 5
Dr. J. Cambra Univ ersidad del País Vasco 5
Dr. K. Sapag Univ ersidad Nacional de San Luis Argentina 1
Dr. J. L Gª. Fierro Instituto de Catálisis y Petroleoquímica 5
Dr. T. Leonnides ICE/HT FORTH Greece 1
Dr. J. M. Pintado / Dr. Mtnez de la Osa Univ ersidad de Cádiz 2
Dr. J. Pis Instituto Nacional de Carbón 2
Dr. Khalid. S. Karim SABIC R&D Center Riy adh, Saudi Arabia Saudi Arabia 2
Dr. Khalid El Yahy aoui SABIC R&D Center Riy adh, Saudi Arabia Saudi Arabia 1
Dr. Tony Joseph SABIC R&D Center Riy adh, Saudi Arabia Saudi Arabia 2
Dr. L. Gandía / Dr. A. Gil Univ ersidad de Nav arra 4
Dr. L. Gora Institute of Polish Academy Science Poland 1
Dr. M. Montes Univ ersidad del Pais Vasco 3
Dr. J.M. Campelo / Dr. M. Rubio Univ ersidad de Códoba 3
Dr. Yahia Alhamed King Abdulaziz Univ ersity. Saudi Arabia 1
Mrs. Olga Goliv kina – NEOLAB JSC Moscow Oil Ref inery Russia 1
Dr. Miguel A. González Univ ersidad de Tarragona 1
Dr. Miguel Ángel Bañares Instituto de Catálisis y Petroleoquímica 1
Dr Hoang Anh Tuan Saigon Instrumentation Join Stock Company Vietnam 1
Dr. Narcis Homs Univ ersidad de Barcelona 2
Dr Lachezar Angelov Petrov King Abdulaziz Univ ersity Saudi Arabia 1
Dr. Van Grieken / Dra. Carrero / Dr. Serrano Univ ersidad Rey Juan Carlos 4
Dr. S. Al-Zahrani King Saud Univ ersity Saudi Arabia 1
Dr. T. Cordero / Dr. L. Alemany Univ ersidad de Málaga 2
Dr. V. Augugliaro Univ ersidad de Palermo Italy 1
Dr. V. Cortés / Dr. J. Prieto Instituto de Catálisis y Petroleoquímica 2
Dr Sippola Vaino NESTE OIL Finland 3
Dr. V. V. Fadeev YUKOS R&D Centre Russia 1
Dr. A. Fernández Petresa (Cepsa) 1
Mr. Brook March Altamira Instruments USA 1
Dr. Dav id Coker RTI USA 1
Dr. E. Caló / Mrs. G. Monteleone Enea-Cassacia Italy 1
Dr. Gerd Rabenstein Univ ersity of Graz Austria 1
Dra. Viv iane Schwartz Oak Ridge National Laboratory USA 1
Dr. G. Ov ejero Univ ersidad Complutense de Madrid 1
Dr. Victor Texeira da Silv a Fundaçâo COPPETEC Brazil 1
Dr Gregg Deluga General Electric USA 4
Dra. Ana Gay ubo Univ ersidad del País Vasco 2
Dr. De Chen Norwegian Univ ersity of Sciencie & Technology Norway 1
Dr. Kuman Noisk Russia 1
Dr. Jean Thiv olle Centre Nacional de la Recherche Scientif ique France 1
Dr. J.I Gutierrez Ortiz Univ ersidad Pais Vasco 3
Dr. Matthias Friedrich Max Planck Institute Germany 1
Dr. Sv en Jaras KTH Univ ersity Division of Chemical Technology Sweden 2
Dr. Ademir Donizete Elekeiroz Brazil 1
Dr. J. Mª Arauzo Univ ersidad de Zaragoza 1
Dr. Valer Almasán ITIM – CLUJ NOPOCA Rumania 1
Dr. Mark Tsodikov Russian Academy of Sciences Russia 1
Dr. Maged / Prof. Fathy El Ghonemy Group. Egy pt 2
Dr. J. A. Menendez Diaz Instituto del Carbón 1
Dr. Philipe Barthe Corning European Technology Center France 1
Dra. Mónica Antunes. Univ ersidad Rio de Janeiro Brazil 1
Dr. Bjorn NYNAS Sweden 1
Mr. Raúl Alonso Sanz DIGEMA 1
Dr. Jorge Rodríguez INIVAP Brazil 1
Dr. Andrzej Machocki 110 Univ ersity of Maria Curie Poland 1
Dra. Amay a Arteche INASMET 1
Dr. Alkinany King Abdul Aziz City for Science and Technology Saudi Arabia 4
9

Catal ysts for Chlorinated VOCs Abatement:
Multiple Effects of Water on the Acti vity of V
Based Catal ysts for the Combustion of
Chlorobenzene.
F. Bertinc hamps, A. Atti anes e, M. M. Mestdagh,
Eric M. Gaigneaux
Catal ysis Today, 112 (2006) 165-168
Surfac e modific ations of -Al2O3, SiO2 and SnO2
supports by titania grafting and their influenc e in
the c atal ytic c ombustion of methane.
C. Mateos , S.R.G. Carraz an, P. R uiz
Catal ysis Today, 104, Iss ue 1-4 (2006) 107-111
Influence of the solid state properties of
Pd/Mox(M=Ti, Al) catal ysts in c atal ytic
combustion of methane.
S.R. G. C arrazan, R. Mateos , V. Rives, P. Ruiz
Catal ysis Today, 104, Iss ue 1-4 (2006) 161-164
Origin of transient s peci es pres ent on the s urface
of a PdO/ -Al2O3 catal yst during the methane
combustion reaction.
O. Demoulin, M. Navez, P. Ruiz
Catal ysis Today, 104, Iss ue 1-4 (2006) 153-156
Positi ve effect of NOx on the performanc es of
VOx/TiO2 bas ed c atalys ts in the total oxi dation
abatement of chl orobenz ene.
F. Bertinc hamps, M. Treinen, N. Blangenois, E.
Mariage, E. M. Gaigneaux
Journal of C atal ysis, 230 (2005) 493-498.
Modulati on of s electi ve sites by intr oduc tion of
N2O, CO2 and H2 as gas promoters in the feed
during oxidation reac tions.
O. Demoulin, I. Seuni er, F. Dur y, M. N avez, R.
Rachwalik, B. Suli kows ki, S.R. Gonz alez
Carrazan, E.M. Gaigneaux, P. Ruiz
Catal ysis Today 99 (2005) 217-226
Investigation of parameters influenci ng the acti vation
of a Pd/γ-alumina catalys t during methane
combustion
O. Demoulin, G. Rupprechter, I. Seuni er, B. Le Clef,
M. Navez, P.Ruíz
Journal Physic al Chemistr y B,109,2005 20454-
20462
High throughput experimentati on applied to the
combustion of methane and a comparison with
conventional microreac tor meas urements.
O. Demoulin, M. Navez, F. Gracia,E. Wolf, P. R uiz
Catal ysis Today, 91-92 (2004) 85-89
Modification of Acti ve Catal ytic Sites with N2O and
CO2 as Gas Promoters during Oxidation
Reactions.
O. Demoulin, F. Dur y, M. Navez E. Gaigneaux,
P. Ruiz
Catal ysis Today 91-92 (2004) 27-31
Understandi ng the Acti vation Mechanism Induc ed
by NOx on the Performances of VOx/Ti Catal ysts
in the Total Oxidation of Chlorinated VOCs.
F. Bertinc hamps, M. Treinen, P. Eloy, A.-M. Dos
Santos, M. M estdagh, Eric M. Gaigneaux
Accepted for publication in Applied Catal ysis B
Sys tematic Inves tigation of Supported Transition
Metal Oxide Based For mulati ons for Catal ytic
Oxidati ve Elimination of (Chloro-) Aromatics. Part
I: Identific ation of the Optimal Main Acti ve Phases
and Supports.
Part II: Influence of the Nature and Addition
Protoc ol of Sec ondar y Phas es to VOx/TiO2
F. Bertinc hamps, C. Grégoire, E. M. Gaigneaux.
Accepted for publication in Applied Catal ysis B
The oxi dizing role of CO2 at mild temperature on
ceria bas ed catal ysts.
O. Demoulin, B. M. Navez, J. L. Mugabo, P. R uíz
Applied Catal ysis B: Environmental, in press.
Total Combustion of Methane on Pd/γ-Al2O3Bas ed
Catal ysts Deposited On F eCrAlloy Fibers by Dip-
Coating: Effect Of Pt Additi on. A. Mai one, F.
André, P. Ruíz
International Symposium on the Scientific Bases
for the Preparation of H eterogeneous C atal ysts ,
Louvain-la-Neuve, Belgium, September, 2006
The ac tivation of a Pd/g-alumina catal yst during
methane c ombus tion.
O. Demoulin, B. M. Navez, P. Ruíz
5th World C ongress on Oxi dation Catal ysis (5thWCOC)
25-30 September 2005, Sappor o, Japan
Comparison of Pt and Pd alumina-supported c atal ysts
towards the pres enc e of H2 in the feed in the catal ytic
combustion of methane
O. Demoulin,I. Seunier, M. Navez, P. R uíz
5th World C ongress on Oxi dation Catal ysis (5thWCOC)
25-30 September 2005, Sappor o, Japan
H2-assisted catal ytic c ombusti on of methane on a Pd/γ-
Al2O3
O. Demoulin, B. M. Navez, P. Ruíz
6th Int. Works hop on Catal ytic Combustion (IWCC6), 11- 14
September 2005, Ischi a, Ital y
The ac tivation of a Pd/γ-Al2O3 c atal yst during methane
combustion
O. Demoulin, B. M. Navez, P. Ruíz
6th Int. Works hop on Catal ytic Combustion (IWCC6), 11- 14
September 2005, Ischi a, Ital y
The oxi dizing role of CO2 at mild temperature on c eriabased
catal ysts
O. Demoulin, B. M. Navez, J. L. Mugabo P. Ruíz
4th Internati onal Conference on Environmental Catalysis
4th ICEC, 5-8 June 2005, Heidel berg, Ger many
Influence of the solid state properties of Pd/MOx
(M= Ti, Al) catalysts in c atal ytic c ombus tion of
methane
S. R. G. Carrazán, R. Mateos , V. Ri ves, P. Ruiz
First Conference of the Coordi nati on Action “Coordinati
on of N anos tructur ed Catal ytic Oxi des
Research and Development i n Europe
(CONCORDE)” funded by European Commission,
entitled "Understanding the dynamic and transient
behavior of oxi de c atal ysts in wor king conditions
and the relati ons hips with their catal ytic
perfor manc es” Louvain-la-Neuve (Belgium), J anuar y
26-28, 2005
Surfac e modific ations of MOx oxides s upports by
titania grafting and their infl uenc e in the catal ytic
combustion of methane performances .
C. Mateos-Pedrer o, P. Ruiz.
Understandi ng the dynamic and tr ansient behaviour
of oxi de c atal ysts in wor king conditions and the
relations hips with their catalytic performances .
First Conference of the Eur opean Union
Coordination Action “CO-ordination of
Nanostruc tured Catal ytic Oxides Res earch and
Development i n Europe”: CONCORDE. Louvain-la-
Neuve (Belgium), J anuar y 26-28, 2005
The diss ociati ve adsorpti on of CO2 at low
temperature: a new opportunity to implement the
use of CO2.
E.M. Gaigneaux, F. Dur y, C. Mateos, M. Navez, O.
Demoulin & P. R uiz
5th European Meeting on Environmental C hemistr y.
Bari, Italy, 15-18 December 2004
Modification of ac tive sites by the introducti on of gas
promoters in the feed during oxidation reacti ons.
O. Demoulin, I. Seuni er, F. Dur y, M. N avez, R.
Rachwalik , B. Sulikows kii, S.R.Gonz alez-Carrazan,
E.M. Gaigneaux and P. Ruiz
3 th Int. C ongress on Catal ysis, Jul y 2004, Paris quitar
A Sel ecti ve Combinatorial Approach: Application to
the c ombus tion of methane at low temperature.
O. Demoulin*, M. Nave, F. Gracia, L. Boll man, E.E.
Wolf and P. Ruiz
Europacat VI, 7 th European Works hop Meeting on
Selecti ve Oxidation “Innovative Selecti ve Oxidations:
Nanosc ale and Dynamics As pects" (ISO 2003),
August 31-Sept 04, 2003, Inns bruc k, Austria
Modulati on of the acti ve sites with CO2 or N2O as gas
promoter during oxidation reactions .
O. Demoulin, F. Dur y, M. Navez , E.M. Gaigneaux and
P. Ruiz
Europacat VI, 7 th European Works hop Meeting on
Selecti ve Oxidation “Innovative Selecti ve Oxidations:
Nanosc ale and Dynamics As pects" (ISO 2003),
August 31-Sept 04, 2003, Inns bruc k, Austria
The Role of Oxygen and H ydroxyl Support Species
on the M echanism of H2 Produc tion i n the Steam
Reforming of Phenol and Toluene over Metal Oxide-
Supported Rh and F e Catalys ts.
K. Polyc hronopoulou, C. N. Costa, A. M. Efstathiou
Catal ysis. Today, 112 (2006) 89- 93
Hydrogen Produc tion by Ethylene D ecomposition
over Ni Supported on Novel Carbon Nanotubes and
Nanofi bers.
P. G. Savva, G. G. Ol ympiou, C. N. Cos ta, V. A.
Ryzhkov and A. M. Efstathi ou
Catalal ysis Today, 102/103, (2005) 78-84
Novel Fe-Mn-Zn-Ti-O mi xed-metal oxides for the l owtemperature
removal of H2S from gas streams in the
presenc e of H2, CO2, and H2O.
K. Polyc hronopoulou, F. Cabello Galisteo, M. López
Granados, J. L. G. Fierro, T. Bakas, A. M. Efs tathiou
Journal. Catalysis, 236 (2), ( 2005). 205-220
Novel Zn-Ti-based mi xed metal oxides for l owtemperature
ads orption of H2S from industrial gas.
K. Polyc hronopoulou, J . L. G. Fierro and A. M.
Efstathiou
Applied Catal ysis B: Environmental, 57 (2), (2005)
125-137
Hydrogen Produc tion by Steam R efor ming of Phenol
over Novel Supported-Rh and Fe Catalys ts.
K. Polyc hronopoulou, Z. Theodorou, C. N. Cos ta, A.
M. Efstathiou
Chemic al Engineering Transac tions , 4, (2004).118
The phenol s team reformi ng reaction over MgObased
supported Rh c atal ysts .
K. Polyc hronopoulou, J .L.G. Fierro and A.M.
Efstathiou
Journal C atal ysis, 228 (2), (2004) 417-432
Effects of Support Surface Compositi on on the
Activity and Selecti vity of Pd/C C atal ysts i n Aqueous-
Phas e H ydrodec hlorinati on R eactions.
L. Cal vo, M. A. Gilarranz, A. F . Mohedano, J. A.
Casas, J. J. Rodríguez
Industrial & Engineering Chemistry A, Vol. 44 (17)
(2005) 6661 - 6667
Treatment of chlorophenols-bearing wastewaters
through hydrodec hlorati on using Pd/acti vated carbon.
catal ysts.
L. Cal vo, A. F. Mohedano, J. A. C asas, M. A.
Gilarranz, J. J . Rodríguez
Carbón A, Vol. 42 ( 7) (2004) 1377 - 1381
Compl ete oxidation of ac etone over manganese
oxi de c atal ysts supported on alumina- and zirconiapillared
clays.
L. M. Gandia, M.A. Vic ente, A. Gil
Applied Catal ysis B, Vol. 38 (2002) 295-307
Platinum c atal ysts supported on Al-pillared cl ays.
Applicati on to the catal ytic combustion of ac etone
and methyl-ethyl-ketone.
A. Gil, M.A. Vicente, J.-F. Lambert, L. M. Gandi a
Catal ysis Today, Vol. 68 (2001) 41-51
Effects of al kali-acid additi ves on the acti vity of a
manganes e oxide i n catal ytic combustion of ketones.
L. M. Gandia, A. Gil, S.A. Korili
Applied Catal ysis B, Vol. 33 (2001) 1-8
Influence of the surface ads orption-des orption
processes on the ignition cur ves of volatile organic
compounds (VOCs) complete oxidation over
supported catal ysts.
M. Paulis, L. M. Gandia, A. Gil, J. Sambeth, J.A.
Odriozola, M. Montes
Applied Catal ysis B, Vol. 26 (2000) 37-46
Preparation, Characterizati on and Catal ytic Acti vity i n
the D eep Oxidation of Acetone of Cr, Al-Pillared
Saponites.
A. Gil, M.A. Vicente, R. Tor anzo, M. A. Bañar es, L.
M. Candia
Journal of C hemical Tec hnology and Bi otec hnology,
Vol. 72 (1998) 131-136
Influence of the Incorporation of Palladium on
Ru/Mcm H ydrotreati ng Catal ysts.
D. Eliche-Quesada, J. Mérida-Robles, E. R odríguez-
Castellón and A. Jiménez-López
Applied Catálisis B, Vol.:65 (2006) 118-126

Cobalt, Copper and Iron-Contai ning Monolithic
Aluminosilicate-Supported Preparations for
Selecti ve Reduction of No with Ammoni a at Low
Temperatures.
M. Brandhorst, J. Z ajac, D.J. Jones, J . Rozière, A.
Jiménez-López , E. Rodriguez-Castellón
Applied Catal ysis B, Vol.: 55 (2005) 267- 76
Syntesis and Characterisation of Acid
Mesopor ous Phosphate Heterostructure (Pph)
Materials
J. Jiménez-Jiménez, M. R ubio Alons o, D. Eliche-
Ques ada, E. Rodríguez-Castellón, A. Jiménez-
López
Journal of Materials Chemistr y, Vol.: 15 (2005)
3466-3472
Influence of the Metallic Precursor in the
Hydrogenati on of T etralin over Pd-Pt Supported
Zirconium D oped Mes oporous Silica.
M. C. Carrión, B. R. Manzano, F . A. Jalón, D. E.
Eliche-Quesada, P. Maireles-Torres, E.
Rodríguez-Castellón, A. Ji ménez-López
Green C hemistry, Vol.: 7 (2005) 73-799
Copper and Sil ver C ontaining Monolithic Silica-
Supported Pr eparation for Selec tive Propene-
Propane Ads orption from Gas Phas e.
M. Kargol, J. Zaj ac, D. J . Jones, J. Rozi ère, Th.
Steriotis, A. Ji ménez-López and E. Rodríguez-
Castellón
Chemistr y of Materials, Vol.: 17 ( 2005) 6117-6127
Selecti ve Catalytic Reduction of Nitric Oxi de Over
Cu- Exc hanged C uban Natural Z eolites.
R. Moreno-Tos t, J. Santamaría-González , E.
Rodríguez-Castellón, A. Ji ménez-López . M. A.
Autié, E. González , M. C. Gl acial, C. de l as Pozas
Applai d Catal ysis B, Vol.: 50 (2004) 279- 288
Nickel Supported on Porous Silica as Catal ysts for
the Gas-Phase Hydrogenation of Ac etonitrile.
A. Infantes M olina, J. Merida Robl es, P. Braos
García, P. Maireles Torres, E. Rodríguez-
Castellón, A. Jiménez López
Journal of C atal ysis, Vol.:225 (2004) 479-488
No Reduction with Ammonia Employing Co/Pt
Supported on a Mes opor ous Silica Containing
Zirconium as a Low Tempeature Selecti ve
Reducti on Catal yst.
R. Moreno Tost, J. Santamaría González , E.
Rodríguez-Castellón, A. Ji ménez López
Applied Catal ysis B, Vol. 52 (2004) 241-249
Cetane Improvement of Diesel with a N ovel
Bimetallic Catal yst.
M. Jacquin, D.J. Jones, J . Rozière, M. Jacqui n, A.
Jiménez-López , E. Rodriguez-Castellón, J .M.
Trejo-Menayo, M. Lenarda, L. Storaro, A. Vaccari
And S. Albertazzi
Journal of C atal ysis, Vol: 228 (2004) 447-459
Hydrogenati on and H ydrogenol ysis/Ring-Opening
of Naphtalene on Pd/Pt Supported Zirconi um
Doped Mesoporous Silica C atal yst.
S. Albertazzi, E. Rodríguez-Castellón, M. Li vi, A.
Jiménez-López , A. Vacc ari
Journal of C atal ysis, Vol.: 228 (2004) 218-224
Hydrogenati on and Ring-Opening of T etralin on
Nickel Supported Zirconi um Doped Mes oporous
Silica Catal ysts. Influence of the Nickel Prec ursor.
D Eliche-Quesada, J . Merida-Robles, P. Maireles-
Torres, E. R odríguez-Castellón, A. Jiménez-
López
Langmuir, Vol: 19 (2003) 4985-4991
Effects of Preparati on Method and Sulfur
Poisoni ng on the H ydrogenation and Ring-
Opening of T etralin on Ni w/Zirconium D oped
Mesopor ous Silica Catalys ts.
D. E.-Quesada, J . M.-Robles , P. M.-Torres, E. R.-
Castellón, G. Busc a, E. Finocchio, A. J .-López
Journal Of Catálisis, (2003) 457-467
Cobalt Supported on Zirconium Doped
Mesopor ous Silica: A Selec tive Catal yst for
Reducti on of No with Ammonia at Low
Temperature.
R. M.-Tost, J. S.-González , P. M.-Torres, E. R.-
Castellón, A. Jiménez- López
Applied Catal ysis.B, ( 2002) 51-60
Nickel Oxide Supported on Zirconium-Doped
Mesopor ous Silica for Selecti ve Reduction of NO with
NH3.
R. Moreno Tost, J. Santamaría-Gonz ález, P. M.-
Torres, E. R.-Castellón, A. J.-López
Journal M aterial Chemistry, Vol. 12 (2002) 3331-333
Selecti ve catal ytic reduction of no by propane on
copper contining al umi na pillared α-zirconi um
phos phates .
R. Hernández-Huesca, J. Santamaría González , P.
Braos-García, P. Maireles T orres, E. Rodríguez
Castellón, A. Jiménez López
Applied Catal ysis B, Vol.: 29 (2001) 1-11
Dehydrogenati on and Ring-Openi ng of T etralin on Ni
and Nimo Supported on Alumina-Pillared Zirconi um
Phos phate C atal ysts . A T hiotoleranc e Study.
R. Hernández-Huesca, J. Mérida-Robles P. Maireles-
Torres, E. R odríguez-Castellón, A. Jiménez-López
Journal of C atal ysis (2001) 122-132
Copper Supported on Mixed Alumina/Gallium Oxide
Pillared Zirconium Phos phate for De-Nox
Applicati ons.
P. Braos-García, J. Santamaría-Gonz ález, P.
Maireles-Torres, E. R odríguez-Castellón, A. J .-López
Green C hemistry (2001) 289- 295
Insertion of porous chromia in γzirconi um phoshate
and its catal ytic perfor manc e in the oxi dati ve
dehydrogenation of propane.
A.Jiménez López , E. Rodríguez Castellón, J.
Santamaría González , P. Braos García, E. Felici, F.
Marmotti ni.
Langmuir A, Vol.: 16 (2000) 3317-3321
Determination of kinetic parameters of the
oxi dehidrogenation of ethane with CO2 on nanosized
calcium-doped c eria under fast deacti vation
processes .
M. Guio, J . Prieto, V. Cortés
Catal ysis Today 112 (2006) 148- 152.
On the origin of the high performanc e of MWNTsupported
PtPd c atalys ts for the hydrogenation of
aromatics
B. Pawelec, V. La Par ola, R. M. Navarro, S. Murcia-
Mascarós, J. L. G. Fierro
Carbon, 44(1) (2006) 84
Produc tion of H ydrogen from Methanol over Cu/ZnO
Catal ysts Pr omoted by ZrO2 and Al2O3.
J. Agrell, H. Birgersson, M. Boutonnet, I. Melian-
Cabrera, R. M. Navarro, J. L. G Fi erro
Journal of C atal ysis. 219(2) (2003) 389-403
Produc tion of H ydrogen by Oxidati ve Refor ming of
Ethanol over Pt catal ysts s upported on Al2O3 Doped
with C e and La.
R. M. Navarro, M. C. Al varez-Galván, M. Cruz
Sánc hez-Sánc hez, J . L. G Fierro
Applied Catálisis B: Environmental. 55 (2005) 229
Removal of crcinogen PAH c ompounds by Pd
catal ysts
B. Pawelec, J . M. Campos-Martín, E. C ano-Serrano,
R. M. Navarro, J. L. G Fierro
Environmental. Science. Technolog y, 39 ( 2005) 3374
Produc tion of H ydrogen by Partial Oxidation of
Methanol over Carbon-Supported Copper Catal ysts .
R. M. Navarro, M. A. Peña, J . L. G. Fierro
Topics in Catal ysis, 30/31 ( 2004) 481
Silica-alumina-supported transition metal sulphide
catal ysts for deep hydrodesulfurization.
B. Pawelec, R. M. Navarro, J. M. C ampos-Martín, A.
López-Agudo, P. T. Vasudevan, J. L. G. Fierro
Catal ysis Today 86 (1- 4) (2003) 73-85
Produc tion of H ydrogen by Partial Oxidation of
Methanol over a Cu/ZnO/Al2O3 C atal yst: Influence of
the Initial State of the C atal yst on the Start-Up
Behaviour of the Refor mer.
R. M. Navarro, M. A. Peña, J . L. G. Fierro
Journal of C atal ysis, 212 (1), (2002) 112-118
Oxidati ve methanol reforming reac tions on CuZnAl
Catal ysts derived from hydrotalcite-like prec ursors
S. Murcia-Mascarós, R. M. Navarro, L. Gómez-
Sainer o, U. Cos tantino, M. Nocc hetti, J. L. G. Fierro.
Journal of C atal ysis, 198, (2001) 338-347
11
Aromatics H ydrogenation over sul phur resistent Pt-
Pd alloys
R. M. Navarro, B. Pawelec , J. M. Trej o, R. Mariscal y
J .L.G. Fierro.
Journal of C atal ysis. 189 (2000) 184-194
Dibenzothiophene hydrodesulfurization on HY-zeolite
supported metal sulfide catal ysts
R. Navarro, B. Pawelec, P.T. Vas udevan, J. F .
Cambra y P. L. Arias.
Fuel Proc essing Technol ogy. 61 (1999) 73-88
Hydrodes ulfurizati on over PdMo/HY z eolite catal ysts
B. Pawelec, R. Navarro, J. L. G. Fierro, J. F . Cambra,
J. F. Zugazaga, P. L. Arias
Fuel, 76 (1) (1997) 61- 71
Reacti vati on of sintered Pt/Al2O3 Oxi dati on Catal ysts.
F. Cabello Galisteo, R. Mariscal, M. López Granados ,
J. L. G. Fierro, R. A. D aley J. A. Anderson
Applied. Catal ysis B, 59 (2005) 227- 233
Reacti vati on of Commercial Dies el Oxidation
Catal ysts by Acid Washing.
F. Cabello Galisteo, R. Mariscal, M. López.
Granados, J. L. G. Fierro, P. Bretes, O. Salas
Environmental Engineering, Science and Tec hnology
39 (2005) 3844-3848
Chemic al structures of coprecipitated Fe-Ce mi xed
oxi des.
F. J. Pérez-Alons o, M. López Granados, M. Oj eda, P.
Terreros, S. R ojas, T. Herranz, J. L. G. Fierro, M.
Gracia, J. R. Gancedo
Chemistr y of Materials 17 (2005) 2329-2339
TWC deacti vati on by lead: study of Rh/C eO2 s ystem.
C. Lares e, M. López Granados , F. Cabello Galisteo,
R. Mariscal, J. L. G. Fi erro
Applied Catal ysis B, 62 (2005) 132-143
Effect of mileage on the deacti vati on of vehicle-aged
Three-Way Catalys ts.
C. Lares e, F. C. Galisteo, M. Granados, R. M ariscal,
J. L. G. Fierro, R. F.-Ruíz, R. Sanguino, M. Luna
Catal ysis Today, 107-108 (2005) 77-85
Metal-Support Interactions and Reac tivity of C o/CeO2
Catal ysts in the Fischer-Tropsch Synthesis Reaction.
L. Spadaro, F. Arena, M. L. Granados, M. Ojeda, J . L.
G. Fierro, F. Frus teri
Journal of C atal ysis, 234 (2005) 451-462
Effects of Calcination T emperature on the Stability of
CePO4 Detected in Vehicle Aged Commercial Three-
Way Catal ysts.
C. Lares e, F. C abello Galisteo, M. López Granados,
R. Mariscal, J. L. G. Fi erro, P. S. Lambr ou, A. M.
Efstathiou
Applied Catal ysis B, 48 (2004) 113-123
Deacti vati on on vehicle-aged di esel oxidati on
catal ysts.
F. Cabello Galisteo, C. Larese, R. Mariscal, M. López
Granados, J. L. G. Fierro, R. F.-Ruiz, M. Furió.
Topics in Catal ysis 30-31 (2004) 451
Inhibiti on of the oxygenated c ompounds for mati on
during CO hydrogenation over Rh/ -Al2O3 c atal ysts
calcined at high temperature.
M. Ojeda, S. Rojas, F. J. G.-García, M. Granados, P.
Terreros, J. L. G. Fierro
Catal ysis Communications , 5 ( 2004) 703-707
Deacti vati on of real TWC c atal ysts by CePO4
formation.
C. Lares e, F. C abello Galisteo, M. López Granados,
R. Mariscal, J. L. G. Fi erro, M. Furió, R. Fernández
Ruiz
Applied Catal ysis. B: Environmental,40 2003,305-317
Interfacial properti es of Ir/TiO2 s ystems and their
relevanc e in cr otonaldehyde hydrogenati on.
P. Reyes , M. C. Aguirre, I. Melián-Cabrera, M. López
Granados, J. L. G. Fierro
Journal of. Catalysis. 208 (2002) 229-237
Reverse topotac tic trans formation of a C uO-ZnO-
Al2O3 catalys ts during Pd i mpregnation: relevanc e for
the performance of methanol s ynthesis from CO2 /H2
mixtures.
I. Melián-Cabrera, M. López Granados, J. L. G. Fierro
Journal of C atal ysis, 210, (2002) 273-284

Pd-modifie d Cu-Zn c at alys t for me th anol
syn th esis fro m CO2/H 2 mixtures: cat al ytic
structures an d p erfor manc e.
I. Melián-Ca brera, M. Ló pez Gran ad os, J. L. G.
Fierro
Journal of C atal ysis, 21 0 (20 02) 28 5-29 4
CO h ydrog e nati on with Co c atal yst s up port ed on
porous media .
K. S apag , S. Roj as, M. Ló pez Gr ana dos , J. L. G .
Fierro, S. Mendior oz
Journal of Mol ecular C atal ysis A : Che mical, 16 7
(2001) 81-8 9
CO2 h ydrog e natio n o ver P d-modifie d met ha nol
syn th esis cat alys ts.
I. Melián-Ca brera, M. Ló pez Gran ad os, P .
Terreros, L. G. Fierro
Catal ysis. To da y 45 (19 98) 2 51-2 56
Role of th e su pp ort in s yng as g as co n versio n o ver
Pd/Cu-K L ze olite c atal ysts .
J. An derso n, M. Ló pez Gran ad os, M. F.-G arcía
Journal of C atal ysis, 17 6 (19 98) 23 5-24 5
Spectroscopic evidences of Cu-Al interaction in Cu-
Zn-Al catalysts used in CO hydrog enation to
methan ol.
R. Ta vares Fig ueire do, A. M artín ez Arias, M.
Lóp ez Gra na dos, L. G. Fierro
Journal of. Cat alysis, 17 8 (1 99 8) 14 6-15 2
Bio-eth an ol ste a m ref orming : I nsig hts o n t he
mec hanis m f or h ydrog en prod uctio n
M. Benit o, J. L. Sa nz, R. Isa bel, R. Pa dilla, R.
Arjona, L. D aza
Journal of Po wer So urces, 151 (20 05) 1 1-1 7
Liq uid ph ase olig omerization of 1-h e xen e o ver
differe nt mes op orous alu minosilicat es (Al-MTS,
Al-MCM-41 and Al-SBA-1 5) an d
micrometer/ na no met er HZSM-5 ze olites.
R. Van Grie ke n, J. M. Esc ola, R. R odríg uez
Applie d Cat al ysis, acc ept ed .
Olig omerización d e 1-h e xe no en fas e líq uida
sobre c ataliza dores meso estruct urad os áci dos
R. van Grieken . J. M. Escola , R. Ro dríg uez
SECAT, J une 2 00 5, Madrid, S pain
Liq uid ph ase olig omerization of 1-h e xen e o ver
mes opor ous alu minosilicat es a nd na nocr yst alline
n-HZSM-5.
R. van Grieken . J. M. Escola , R. Ro dríg uez
3rd In tern atio nal FEZ A, A ug ust 200 5, C onf erenc e,
Prag ue
Canada
www.pide ngtech.com
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www.latonline. com
www.psr-sotelem.nl
www.techniksconsulta nts.com
Techniks Consul tants
www.elghonemy-group.com
USA
Mexico
Liq uid ph ase olig omerization of 1-h e xen e o ver
mes opor ous Al-SBA-1 5 a nd F e-SBA- 15 c atal ysts .
R. Van Grie ke n, J. M. Esc ola y R. R odríg uez
10t h Medit erran ean Cong ress of Ch emic al
Eng ineering , No ve mber 20 05, Barcel on a, S pai n
Hydrog e n pro duc tion b y eth an ol ste am ref orming
over Ni-Cu sup port ed c atal ysts .
A. J. Vizcaín o, J .A. C alles, A . Carrero
Procee ding s of th e 2 nd Euro pe an H ydrog en En erg y
Confere nce , No vember 2 00 5, Z arag oza, Sp ain, Pag .
362-3 65
Basic pro mo ters effec t o ver nic kel/ alu mina cat alys ts
on h ydrog e n pro ducti on vi a met han e c atal ytic partial
oxi dati on.
J. Req uies, M. A. Ca brero, V. L. Barrio, J. F . Ca mbra,
M. B. G üe mez, P. L. Arias, V . L a P arola, M. A. Pe ña,
J. L. G. Fierro
Catal ysis Tod a y
Hydrog e n pro duc tion fro m g lycer ol o ver nic kel
catal ysts s up port ed on Al2O 3 modifi ed b y Mg, Zr, Ce
or La.
A. Irion do, V. L. Barrio, J. F. Ca mbra , P. L. Arias, M.
B. Gü e mez, R. M. Na varro, M. C. S ánc hez-S ánc hez,
J. L. G. Fierro
Topics in Ca tal ysis, Acep ta do
Modificatio n o f t he Pd/ SiO2-Al2O 3 c atal ysts
thioresista nce b y the a dditio n o f a s eco nd metal (P t,
Ru an d Ni).
V.L. Barrio, P.L. Arias, J .F. Ca mbra , M.B. Gü emez,
B. P awelec; J .L. G. Fierro.
Catal ysis Co mmunica tions , 5 ( 200 4) 1 73-1 78
Hydro des ulfurizati on an d h ydrog en ation of mod el
compou nds o n silica-alu mina s up port ed bimetallic
syst ems .
V. L. Barrio, P. L. Arias, J. F. Ca mbra, M. B. Gü emez,
B. P awelec, J . L . G. Fierro.
FUEL, 8 2 (2 00 3) 50 1-50 9
Hydro treati ng on M-P d/AS A ca tal ysts to f ulfill se ver e
en viron me ntal r eg ulatio ns in diesel fu els.
V. L. Barrio, P. L. Arias, J. F. Ca mbra, M. B. Gü emez,
B. P awelec, J . L . G. Fierro.
PREPRINTS S ymp osia, 4 7 ( ) 7 9-83
Meth yl-na pht hale ne h ydr og ena tion on Pt/H Y-Al2O3
catal ysts. An a ppro ach t o h ydrog en atio n of
pol yaro ma tic h ydrocarb on mi xtur es.
P. L. Arias, J . F. Ca mbra, B . G üe mez, V. L. Barrio, R.
Navarro, B. Pa welec, J . L . G. Fi erro.
Fuel Proc essing Tech nol og y, 64 (20 00) 1 17-1 33
Bra zil
Argentina
12
Ireland
Poland
Ho lland Germany Russia
Belgium Austria
Spa in Slove nia
It aly Gre ece
Cyprus Middle East
Egypt
MnPd on alu mina cat alytic s yste ms f or met han e
combustio n.
V. L. Barrio, P. L. Arias, J. F. Ca mbra, M. B. Gü emez,
V. d e la Pe ña, M. C. Ál var ez-Gal vá n, J. L. G. Fierro.
Catal ytic Co mb ustio n, 1 (20 05) 160- 164
Meth yl-na pht hale ne h ydr og ena tion on Pt/H Y-Al2O3
catal ysts. An a ppro ach t o h ydrog en atio n of
pol yaro ma tic dies el fu els.
V. L. Barrio, J . F. C ambra, M. B. G ue mez , P. L. Arias,
B. P awelec, J . L . G. Fierro.
2nd W orld Cong ress on En viron ment al Cat alysis. 1
(1998) 25 7-25 9
Kinetic Beh a vio ur of th e SA PO-1 8 Cat alys t in th e
Transformatio n o f Met ha nol in to Ol efins.
A. G. Ga yubo , R. Vivanc o, A . Alo nso , B. Valle , A. T.
Ag ua yo
Ind ustrial & Eng ine ering Che mistry R ese arch, V ol.
44, 17 ( 200 5) 6 60 5-66 14
Initiatio n S te p a nd R eacti ve In termedia tes i n t he
Transformatio n o f Met ha nol in to Ol efins o ver S APO-
18 Ca tal yst.
A. G. Ga yubo , R. Vivanc o, A . Alo nso , J. Bilbao , A . T.
Ag ua yo
Ind ustrial & Eng ine ering Che mistry R ese arch, V ol.
44, 19 ( 200 5) 7 27 9-72 86
Effect of Nickel incorp oratio n on t he acidit y an d
stabilit y o f HZSM-5 ze olite in th e MTO Proc ess.
B. V alle, A . Alo nso , A. At ut xa, A. G. G a yu bo, J.
Bilbao
Catal ysis Tod a y, Vol. 10 6 (2 005) 11 8-12 2
Reactio n Sc he me an d Ki netic Modelling for t he MTO
Process o ver a SA PO-18 Cat alys t.
A. G. Ga yu vo, A. T. Ag ua yo, A. Al onso , A. At ut xa , J.
Bilbao
Catal ysis Tod a y, Vol. 10 6 (2 005) 11 2-11 7
Stud y of Reacti on C on ditions an d Ki netic Modelling of
met ha nol S ynt hesis b y CO2 Hidrog en atio n.
J. Ereñ a, A. T. Ag ua yo, J. M. Aran des , I. Sierra, M.
Olazar, J. Bilba o
19t h In tern atio nal S ymposiu m on Ch e mical Re action
Eng ineering , 3-6 S ept e mber 20 06, Berlin - G erman y
Develop me nt of ne w lo w te mp eratur e met han ol
syn th esis Catal ys ts.
J. Ereñ a, A. T. Ag ua yo, J. M. Aran des , I. Sierra, J.
Bilbao
17t h In tern atio nal c ong ress. o f Ch emical an d Pr ocess
Eng ineering . 27-3 1 A ug ust 2 00 6, Prag ue - Czec h
Repu blic
Saudi Arabia
Techniks Consultants
Vietnam
Ind ia
Yemen
Malasya

CATALYTIC REACTORS
The MICROACTIVITY-Reference MA is a
modular automatic and computerized
laboratory reactor for catalytic microactivity
reactions with reactor bypass, preheaters,
evaporator, pressure control valve and other
process layouts inside a hot box, which avoids
possible condensation of volatile products, at
the time that preheats the reactants efficiently.
The equipment consists of a BASIC UNIT and
some series of EXTRA PACKAGES that
improve its efficiency. This is the reference
worldwide unit at catalytic studies.
MICRO PILOT PLANTS
POLYMERIZATION PL
FOUR RUNS MICROACTIVITY-Test Unit MAT ASTM D3907 MT
This unit is a fully automatic and computerized laboratory reactor (described in
ES2011993 patent) for the analysis of Fluid Cracking Catalysts (FCC). This MAT
reactor is design to perform up to four independent and consecutive FCC test,
following the norms described by the standard method ASTM D3907, in automatic
mode without the presence of an operator.
The operator will be able to adjust for each independent
experiment stream time, catalyst/oil relationship, reaction
temperature, the regeneration times and temperature, gas
flow, and other parameters.
With an excellent reaction temperature control and making use
of a precise HPLC pump for gasoil dosification, even for very
short reaction time (10 seg), this unit carry out reaction and
regeneration in-situ and consecutives stages, with coke and
gases analysis. The four liquid products obtained are collected
in a cooled receiver until the end of the experiments.
PID Eng&Tech has worked for several years in
collaboration with industrial research centers to develop
and implement projects for polymerization pilot plants in
both discontinuous and continuous mode. This has led
PID Eng&Tech to a high level of knowledge on the
restrictions and demands on these processes and on the
technologies related to them.
PID Eng&Tech has its own solutions for operations such
as continuous feed regulation of catalysts or transferring
slurries, solutions that have been implemented and
validated on different scales (patent pending). PID
Eng&Tech, a leader in microscale, technology, has
manufactured the first microscale factory in the world for
obtaining bimodal polymers. It operates continuously with
a production of 200 g/h.
16

SUPERCRITICAL EXTRACTION SF
PID Eng&Tech has 4 plant models for SCF with volume
extractors between 350cc and 2L in capacity. They operate at
a maximum pressure of 380 bar, CO2 flowsup to 5 l/h, and
using two separators with independent control temperature
and pressure contrl. More than 15 units are currently in
operation.
GASIFICATION GS
In the past few years, PID Eng&Tech has built several different
laboratory units. They range from the 2” and 1.5 m high ones
to the 8” and 4 m ones. They produce synthesis gas through
the gasification of biomass, carbon or plastic waste.
Accompanying manufactured solids dispenser (patent
pending) makes it possible to feed the material to be gasified
with high accuracy and even operating with pressurized
gasifiers. PID Eng&Tech has also worked in the subsequent
phases of reforming, gas-shift, COprox.
TAYLOR MADE PILOT PLANTS PP
17
Improving competitiveness in the industry is
sharply marked by developing new products
with high quality features and a high added
value. Continuous and automatic pilot
plants that can simulate industrial
processes at the laboratory level with
reasonable scalability are essential for
seeking new products, improving the quality
of existing ones and developing new
processes. These systems’ high degree of
complexity, their high number of operating
variables and the interrelationship among
them requires an exhaustive study of the
instrumentation and control in order to
attain results provided by these systems
that are representative and reproducible.
An initial commitment toward development, the experience accumulated during 20 years carrying out
projects, and strong involvement with customers during the implementation and operation stages
accredit PID Eng&Tech as specialists in designing and building pilot plants and laboratory reactors.
THE SOFTWARE
PID Eng&Tech is a leading supplier of Supervisory Control
and Data Acquisition (SCADA) solutions for laboratory
reactors and pilot plants. Our systems include the
Process@ software making use of the Ethernet remote
control. The operator is able to set all the devices
configuration parameters: set points, alarm values,
calibration parameters settings, etc. Process@® can also
save sessions that are used in order to automate the
processes. The main innovation of Process@® application
is its ability to manage different manufacturer protocols.

Due to the renewed interest on innov ativ e way s to conv ert the existing f uel reserv es with improv ed technologies like gasif ication, PID
Eng&Tech has worked in collaboration with important researches in the f ield of gasif ication in order to dev elop the most versatile pilot
plant existing in the market nowaday s. Its v ersatility and complete automatization, allows the user to determine optimal experimental
conditions and detecting possible operational problem in industrial gasif iers.
The most outstanding f eature of the plant is its feeding system (pending patent), which has been dev eloped by PID Eng&Tech and can
f eed up to 1.5 kg/h of diff erent solids and mixtures in an homogenous, constant and reproducible way. The design of the sy stem
prev ents hot gases f rom entering in the feeding hopper, which would ruin the experiment.
FEATURES:
Fluidized Reactor
The reactor is div ided in reactor zone and f reeboard zone.
The operating homogeneous temperature is up to 900ºC.
• Reactor zone is Ø = 3” and length = 750 mm.
Freeboard zone is Ø = 5” and length = 630 mm.
• The pressure is measured drop inside reactor, f or
f luidization speed determination.
• Particle remov al sy stem is installed to collect char and
ashes f rom bed in continuous during the experiments.
• The radiant ty pe f urnace reaches 1000ºC and has t wo
zones to improv e the unif orm temperature.
Gasifying agent inlets
• Gases streams f or f luidize the bed and gasify are
preheated up to 600ºC.
• Water is f ed by means of an alternativ e positiv e
displacement pump and v aporized up to 600ºC.
Feeding system
Continuous and non-f luctuation solid f eeding sy stem
consists of 10 litres hopper and two screw f eeders. The
solid f low is constant f rom 0.2 to 1.5 Kg/h.
• A nitrogen f low will continuously flush the dosing screw,
promoting the motion of the solids.
Cyclones
Automated and computerized laboratory-pilot plant for the study of gasification process.
• Two cy clones connected in series and heated up to
400ºC, allow remov ing solid particles f rom gas stream.
Products treatment
• A SS316 Shell and multitube heat exchanger is used
to cool the hot gases and condense tar and steam. A
f ilter allows cleaning product gas.
18
Scrubbers and gas meter
• As optional, a wet gas scrubber is used
to remov e contaminants, and a wet gas
meter is used to outlet stream
measurement.
Control system
• The process v ariables are controlled by
independent PID controllers.
• A Programmable Logic Controller
controls the alarms of the plant,
launching the corresponding actions in
case of failure.
• The sof tware is responsible of process
monitorization, data acquisition and
registration and experiment automation.

EXPERIMENTAL CONDITIONS
This system is a v ery
versatile pilot plant which
allows researching v ery
diff erent feeding and
experimental conditions, such
as temperature, gas f low in
bed, air f low, residence time,
pressure, particle size…
PROCESS@ SOFTWARE
GASIFICATION PILOT PLANT PI DIAGRAM
The plant is f ully
instrumented and each
v ariable is automatically
controlled.
Saf ety system is superv ising
the operation of the pilot
plant.
19
The pilot plant includes process sy stem and
electronic control system. All these sy stems are
consisting on a distributed control based on PC
that has the Process@ software, based on
digital RS-485 communications between
controllers and management control system f or
superv isory control and data acquisition.
All sy stem is operated automatically and
manually and all display s are f itted on a control
panel board.
SOLID DOSAGE

The FOUR RUNS MICROACTIVITY Test Unit MAT ASTM D3907 is a fully automatic and computerized laboratory reactor for the
analysis of fluid cracking catalysts (FCC). This MAT reactor is design to perform up to four FCC test in automatic mode. The system
has been prepared to carry out FCC test following the norms described by the standard method ASTM D3907.
The MAT unit has been design to perform continuous control up to four independent and consecutives FCC tests. The operator
will be able to adjust for each independent experiment stream time, catalyst/oil relationship, reaction temperature, the regeneration
times and temperature, gas flow, and other parameters. Otherwise the operator can decided to run the experiments in fixed and
normalized conditions as described in ASTM D3907 norm. The instrumentation and process control installation, is based on a
distributed control by means of programmable logic controllers for the automatic management of the system and experimental data.
The system has local control and on-line remote control, based on TCP/IP Ethernet communications with distributed control structure.
B ASI C U N I T F E AT U R E S:
Gas f eedstock system
- MFC (100 ml/min) f or stripping with N2 and cataly st regeneration with O2
- 3 way v alve f or gas selection plus check v alv e.
Liquid f eedstock system
- 100 cc 316 stainless steel heated v essel.
- HPLC liquid pump, all tubing heated.
- Back pressure f or repetitiv e pump work and pulse elimination.
Reactor f eed system
- Pneumatically actuated stainless steel heated v alv e by VICI VALCO, with zero dead v olume. This v alv e leads f luid into the reactor or
outside through the purge.
- Stainless steel reactor head with inputs f or two thermocouples, a pressure sensor and the f eedstock.
- Pneumatically actuated stainless steel heated v alv e by VICI VALCO, with zero dead v olume. This v alv e leads f luid into the reactor or
outside through the purge.
- Stainless steel reactor head with inputs f or two thermocouples, a pressure sensor and the f eedstock.
Reaction system
- Quartz tubular reactor similar to described in Standard Method f or Testing Fluid Cracking Catalysts by MAT ASTM D3907.
- 316 Stainless steel solid rod with a drilling of 1 mm, inside the reactor, f or oil
preheater.
- Radiant heater placed on the top of the reactor f or preheating. Radiant heater placed on the bottom of the reactor to control the
reaction temperature. Both hav e v ery low thermal gradient and v ery high response.
- Pressure sensor.
- Two K-ty pe thermocouples; one f or the preheater temperature and the other placed inside the catalyst bed in order to measure the
reaction temperature.
- Porous plate supported in the reactor bottom part.
Liquid sampling system
- Pneumatically actuated stainless steel v alv e by VICI VALCO, with zero dead v olume. This v alv e has 6 ports connected to: f our liquid
sample tubes, CO2 and water
measurement line (f or the regeneration process), and v ent.
- Stainless steel distribution system with easy sample tubes f ix.
- One check v alv e placed af ter the distribution system to connect it with the burette.
- Four glass tubes f or sampling.
- Ref rigeration sy stem based on a stainless steel tank and a Peltier cell. It has a
pneumatic sy stem in order to place the cooling system ov er the tubes, for condensing the liquid f raction.
Gas sampling sy stem
- Liquid centrif ugal pump to f ill the burette.
- Burette f or the gas collection.
- Three lev el sensors (L1, L2 and L3) to measure the volume of the burette and
with automation purposes.
- Two electro-v alv es f or leading the gases towards chromatographer or v ent burette.
- Automatic injection of two gas samples in GC, with sy nchronism signal f or GC.
- Pneumatic actuator f or homogenization of gas sample in burette bef ore injection.
Regeneration and CO2 - H2O quantif ication system
- Regeneration in situ (quartz reactor) at high temperature.
- Copper cataly tic reactor f or CO oxidation to CO2 at 600ºC in CO2 and water line.
- CO2 inf rared analy zer f or coke quantif ication.
Control System
- TFT touch screen process set-up. Siemens.
- PLC (Programmable Logic Controller). Siemens.
- Digital controllers.
- PC remote control by Ethernet.
20

Quartz tubular reactor described in “Standard
Method for Testing Fluid Cracking
Catalysts by Microactivity Test
ASTM D3907”
21
μ

The Poly merization Micro-Pilot Plant, dev eloped by PID Eng&Tech, is designed f or continuous poly olef ins production at microscale.
PID Eng&Tech in co-operation with important Research and Technology Centres (ICP-CSIC and URJC) by means of diff erent Collaboration
Projects has dev eloped this pilot plant that comprises two liters continuous stirred-tank reactors that operate in series.
This Micro-Pilot Plant is f ully automatized and all of the process parameters, as the solv ent, comonomer, operating pressure and
temperature, residence time per reactor, etc., can be selected by user, or modif ied in a wide range.
The plant includes a pre-treating raw material area and
two reactor v essels followed, each one, of a f lash unit.
PID Eng&Tech's computerized process control sy stems
allow a direct control of temperature, lev el, pressure and
gas composition in the reactors.
The dev ices f or poly mer slurry driv ing between the
diff erent reaction steps and f or solid addition hav e been
studied in depth. These dev eloped mechanisms hav e
been designed f or perf orming the process in microscale
and is patent pending.
The cataly st is continuously added into the f irst reactor.
PID Eng&Tech has dev eloped in collaboration with ICP
(Catalyst and Petrochemical Institute of CSIC, Spain), a
sy stem, based in loops and actuated v alv es, patent
pending that allows to load it continuously .
FEATURES:
Automated and computerized laboratory-pilot plant for the study of polymers production
Feed and conditioning of gas and liquid f eed stocks
• Fiv e gas lines: two independent ethy lene f eed
streams (0-4 l/min), one f or each reactor; one
hy drogen stream (0-500 ml/min); one 1-butene
stream (0-50 ml/min); and one nitrogen line f or
inertization purposes.
• Two solv ent (heptane) lines; a common stream is
div ided in two, f eeding at real time with a H.P.
Dosapro Milon-Roy pump (5-10 ml/min), one f or
each reactor.
• A cataly st line; catalyst is added like a slurry in
heptane into f irst reactor;
• A cocataly st line; cocataly st (e.g. TIBA)
homogeneous solution in heptane is added to f irst
reactor using a HPLC pump.
Reactors and f lashes
• The plant comprises three SS316 stirred tanks (1 or
2 l) with high pressure closure sy stem. The 1 st
reactor works at 8 bar @ 80ºC, 1 st f lash, at P atm @
40 ºC and 2 nd reactor, at 2.5 bar @ 80ºC.
• Each one is prov ided with a magnetically coupled
stirred head, a heating jacket, cooling coil, v alv es
and accessories. Stirrer speed is controlled by
Inv erter.
• In addition to temperature and pressure control, the
ethy lene/hy drogen, or the ethy lene/butane,
composition relations are measure continuously ,
near-real time.
• In this way , the integrated control pressure/relation
loop allows the user to work holding simultaneously
a stable desired pressure and a stable desired
hy drogen/ethy lene (at the f irst reactor) and
butene/ethy lene (at the second reactor) relations
during the reaction time.
Distributed control system
All the process v ariables are controlled by distributed PID controllers. The
control system modules are linked with PC by means of a Process@ sof tware
f or remote control by digital communications. The sy stem can be controlled
manually or automatically , locally or remotely.
All the process and control v ariables and parameters are registered in only one
sof tware application. In addition, software allows the operator to design
automatic procedures f or design and automate the run.
Security system
Plant has sev eral independent saf ety lev els: automatic switch off in case of any
problem, pressure, lev el and temperature security systems; all of that based on
a Programmable logic controller (PLC) dev ice independent of PC. PLC
manages the alarm signals f rom controllers. In addition, actuated v alv es are
conf igured according to good saf ety practices.
22

POLYMERIZATION MICROPLANT PI DIAGRAM
PROCESS@ SOFTWARE
23

Automated and computerized laboratory-pilot plant for extraction of solid samples by means of
supercritical CO2.
The system is a modular-type built for easy return to factory for service. Each module (feed section, Extractor module
and two Separator modules) includes process system and electronic control system. All these systems are supervised
for distributed control system PC based. The security systems are integrated in each one of these modules.
Feed system
● Dosapro Milton Roy CO2 pump, 4.7 l/h, 380 bar, SS-316 hydraulic membrane, refrigerated head. Inverter for
computerized control. Check-valves, filters and other components.
● Refrigerator unit (-10ºC) for cooling CO2 line feed and CO2 pump head.
● Dosapro Milton Roy Co-solvent pump 0.3 l/h, 100 bar, SS-316 piston head. Inverter for computerized control.
● Back pressure system and bypass for flow measures at high pressure in Co-solvent pump.
Distributed control system
• All module control systems are linked w ith PC
computer by means of Process@ software for
remote control w ith digital communications. The
system can be controlled manually or automatically.
• Process@ software allows the operator to design
automatic procedures for the process run.
• Plant has several independent safety levels:
automatic sw itch-off in case of any problem,
pressure and temperature security systems, all that
based on electronic or mechanical devices and
independent of PC.
Test
• The system will be tested during 24 hours at 360 bar
closing (except MFM and rupture discs).
• The system w ill be tested during 4 hours at 340 bar
in Extractor, 220 bar in Separator 1 and 120 bar in
Separator 2, in operation mode, w ith 3 l/h CO2 and 20
cc/h ethanol as co-solvent.
24
Column System
• Furnace for CO2 preheater. Tw o control actions: heating by electrical
pow er and cooling by furnace opening and closing.
• 350 cc Head Line vessel, 400 bar, easy closure system, for solid
sample. Porous plate 20 microns. Quick connectors for agreeable
work.
• Furnace for control temperature of extraction operation, internal
thermocouple. Tw o control actions: heating by electrical power and
cooling by furnace opening and closing.
• Bypass system (two-three way valves) for cleaning procedures.
• Pneumatic security valve put into operation by pressure control
system.
• Pressure control system based on micrometric regulation
servocontrolled valve. High precision in pressure control and fast
response. Maximum pressure 340 bar.
• Rupture discs, check valves, filters and other components.
Three Separators
• 40 cc Head Line vessel, 400 bar, easy closure system, for extracts
collection. Valve for sample.
• Furnace for control temperature of separation operation, internal
thermocouple. Tw o control actions: heating by electrical power and
cooling by furnace opening and closing.
• Pressure control system based on micrometric regulation
servocontrolled valve. High precision in pressure control and fast
response. Max pressure 220 bar in Separator 1, 120 bar in
Separator 2.
• Separator 3 at atmospheric pressure and MFM for CO2 flow
measurement.

PID Eng&Tech was born as a spin-off company with more than 16 y ears of accumulated experience and has dev oted its activ ity to
the technologies dev elopment dedicated to the construction and operation mode of laboratory -scale reactors and micro-scale pilot
plants, and their data acquisition, superv isory and control sy stems. The main areas of PID are: petrochemistry, chemistry,
agrochemistry, cataly sis and new energies.
The staff that worked f or the Process Control Group, f ormed by experts with multidisciplinary backgrounds in chemical engineering,
electronics, automated and software engineering, set up in 2003, in the Scientif ic Park of Madrid, the company Process Integral
Dev elopment Eng&Tech, where the experience, technological dev elopment and innov ations achiev ed by the group ov er many
y ears of work in the field of engineering had been put into practice.
LAB-SCALE PILOT PLANTS
The incorporation to the market of new instrumentation (smart instrumentation,
f ield communications, automation of chromatographic techniques, low cost
time-sharing computers, new materials ...) has made possible to think of a
computerized process control sy stem designed to control discrete operations
common to many processes that are studied at pilot plant lev el, in such a way ,
that single designs can be used f or many diff erent processes.
Our automated control sy stems f or laboratory reactors and pilot plants hav e
many adv antages when compared to other sy stems. Some of them include size
and easy scale-up. One of the adv antages of our units is that y ou can start
"small" and later scale-up the sy stem as y our requirements grow. Putting
together a sy stem in this way keeps y our initial cost low, y et prov ides y ou with
the ability to add instruments and equipments at any time in the f uture. Lastly,
as y ou build and expand y our system, the initial cost of the unit decreases.
With a 19" industrial rack, howev er, y ou can place the sy stem in almost any
location. Other enclosures are also av ailable to prov ide the sy stem with
additional protection.
Our automated control systems include the Process@® software f or
superv isory control and data acquisition. Process@® software is based on
digital RS-485 communications bet ween controllers and management control
sy stem. The communication with the computer is managed by means of the
Ethernet, TCP/IP protocol.
The objectiv e of the PID Eng&Tech Company is, theref ore, to design and
prepare standard equipment to carry out common operation steps of pilot plant
reactors used to study different chemical processes and, thus, to build such
pilot plant reactors using modular components with the aim of diminishing at
least one f actor of 2 existing: construction time and cost. The design will
include the latest adv ances in process control technology .
PID Eng&Tech also off ers the possibility of installing improv ed automated
control sy stems f or pilot plants already in operation.
Sixteen y ears of experience and know-how back the company in the design,
dev elopment and construction of sev eral ty pes of pilot plants. Especially we
hav e a huge experience using MFC's, high pressure systems (400-600 bars),
special alloy s (Hastelloy®, Inconel®, Monel®, etc.), pressure control systems,
separation sy stems of pressurized liquid-gas mixtures, superv isory control and
data acquisition by PC, etc. The whole lot of equipments, reactors and plants
are deliv ered "turn-key ", checked and commissioned. We always prov ide a
user's handbook and practical training.
25

PID Eng&Tech has attended the following events:
As International marketing activities, PID Eng&Tech
has participated in several congresses around the
World.
From 2003 the Company opened new markets and
starts its Internationalization in Europe, Middle East,
Asia, EEUU and South America. The most important
business activity of PID during these 6 years was
based on Customer confidence activities and
Congress assistance. Nowadays we are looking for
covering through Distributors the most strategic
markets for our products.
ICC 2008. 14th International Congress on Catalysis 13-18 July 2008. COEX, Seoul,
Korea.
WPC 2008. 19th World Petroleum Congress 29 June-3 July 2008. IFEMA, Madrid, Spain
ISFL 2008. 6th International Symposium on Fuels and Lubricants 9-12 March 2008. New
Delhi, India.
PITTCON 2008.Pittsburgh
Conference on Analytical Chemistry
and Applied Spectroscopy 2-6 March
2008. New Orleans, USA.
EUROPACAT VIII. 26-31 August 2007.
Turku, Findland.
PITTCON 2007. Pittsburgh
Conference on Analytical Chemistry
and Applied Spectroscopy. February
25 - March 2 2007. Chicago, Illinois,
USA.
OPERANDO II. Second International
Congress on Operando Spectroscopy.
23-27 April 2006. Toledo, Spain.
EXPOQUIMIA 2005. 14-18 November 2005. Fira de Barcelona, Spain.
EUROPACAT VII. Catalysis: A Key To A Richer & Cleaner Society. 28 August - 1
September 2005. Sofia – Bulgaria
VII SEMINARIO ITALIANO DE CATALISI. 19-24 June 2005. Verbania-Pallanza, Italy.
NORTH AMERICAN MEETING ON CATALYSIS 2005. 20-25 May 2005. Philadelphia,
Pennsylvania, USA.
XXXVIII JAHRESTREFFEN DEUTSCHER KATALYTIKER. 16-18 March 2005. Weimar,
Germany.
13th INTERNATIONAL CONGRESS ON CATALYSIS. 11-16 July 2004. Palais des Congrès,
Paris, France.
BIOTECHNICA 2003. October 2003. Hannover, Germany.
PID Eng&Tech will attend these Congresses during the next four years:
2009 7-12 June National America Society of Catalyst San Francisco (USA)
2009 1-4 Sept. EuropaCat IX Salamanca (Spain)
2009 13-17 Sept . South America Congress on Catalysis Río de Janeiro (Brazil)
2009 21-23 Oct. COST Chemestry Workshop Benahabís (Spain)
2010 SICAT (Iberoamericano)
2011 EuropaCat X Czech Republic
2012 15 th International Catalyst Congress Munich
26

PID Eng&Tech experiences continuous growth and strives to expand its product line through various research
projects and research investments. PID Eng&Tech in collaboration with Catalysis and Petroleochemestry
Institute (CSIC, Spain) has been working in new investigation lines and in the development and improvements of
the products. This investment has the follow ing objectives:
LEADERSHIP: development of devices and instruments that solve the problems inherent in microscale
(components of limited dimensions, small volumes or quantities of matter, etc.). PID is a World leader in
microscale systems.
INNOVATION: Control systems development capable of manage the variables related to the micro-process,
allow ing the stability and safety of the process in addition to automating the operation of the plant. Moreover,
PID takes part in numerous technological programs and projects.
QUALITY and SECURITY: Analysis of risks that make necessary the incorporation of devices that guarantees
the safety in all the phases of the process. PID has certification ISO 9001 and ISO 14000 that is the result of
fulfilment of all the instructions that are applicable to its products. In addition, w ith all equipment PID supplies
the Declaration of Conformity that is demanded by the European Institutions.
Some of the R&D governmental projects subsidized by CDTI, IMADE, MITYC and MEC are:
NEOTEC PROJECT
"Instrument and equipments for specific processes of chemical research", 2004-2005. CDTI.
PIE PROJECT
"Investigation and development of a monitorized system and advance control for bioreactors".
"Research and development of an automated and computerized microreactors system for
combinatorial chemistry, with an "in situ" analysis", 2005.
"Research and development of an automated lab-scale reactor for catalytic microactivity studies
of chemical reactions", 2004.
PROFIT PROJECT
"Technical viability study for monitorization and advance control system, automatic, integrated and universal
for bioreactors to laboratory scale, pilot and semi-industrial with sterilization " In situ" ", 2006.
"Research and development of a new catalytic Microactivity reactor", 2004.
"Research and development of an automated pilot plant for extraction at supercritical conditions", 2005
TORRES QUEVEDO PROGRAM
PATENTS
"Viability study for development an automated unit for the study and evaluation of catalysts in the process
FCC (Fluid Catalytic Cracking)", 2005.
"Critical and technical viability studies for investigation and posterior development of microreactors system
for combinatory chemistry with "in situ" analysis", 2005.
"Critical and technical viability studies for investigation and posterior development of SCADA system for
bioreactors", 2004.
CSIC (Spanich Council for Scientific Research), proprietor of the patents listed below, granted PID Eng&Tech,
under the Patent License Agreement, to make, have made, use, sell, offer to sell and export products.
Automated reactor for catalytic microactivity studies: ES-2245238 / PTC-ES2005/070079 / WO-2006008328
/ EP-1757930 / US-2008063565
Servopositioner for microregulation valve: ES-2245239 / PCT-ES2005/070080 / WO-2006021603 / EP-
1775504 / US-2007241296
Capacitive level sensor for reduced volume systems: ES-2249139 / PCT-ES2005/070081 / WO-
2006021604 / EP-1757911 / US-2007283753
Modular integrated elements for processes control: ES-2032182
Computerized Unit for FCC catalysts studies and evaluation: ES-2011993
Method of immobilizing hydrocarbons inside submerged containers or of transporting said hydrocarbon to
the surface, using the properties of supercritical fluids at a great depth: WO-2004065526 / EP-1595786 /
NO-20053945 / CA-2514171 / US-2006016828
Immobilising or removing hydrocarbons inside sunken tanker ships, by delivering fluid into tank and then
degassing the resulting supercriticalfluid: ES-2213476 / ES-2214974
27

European Directives
PED - Directive 97/23/EC
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ISO 9001:2000 ISO 14001:2004
Our equipments meet the Directive 97/23/EC of the European Parliament and of the Council of 29 May
1997 on the approximation of the laws of the Member States concerning pressure equipment.
Conformity asessment applied procedures, according to the equipment category:
Equipment Category Asessment Module CONFORMITY ASESSMENT PROCEDURES
I A Internal production control
II A1
Internal manufacturing checks with monitoring of the final
asessment
III B+C1 EC Type-examination + Conformity to type
IV B+F EC Type-examination + Product verification
Unit G EC Unit verification
EMC - Directive 2004/108/EC (and former Directive 89/336/EEC modified by the Directives
91/263/CEE, 92/31/CEE, 93/68/CEE and 93/97/CEE)
Our equipments meet the European Directive 2004/108/EC on the approximation of the laws of the
Member States relating to Electromagnetic Compatibility. Its conformity has been checked with the
Harmonized Standard EN 61326:1997 (and its amendments EN 61326/A1:1998 and EN
61326/A2:2001) for "Electrical equipment for measurement, control and laboratory use – EMC
requirements" approved by the European Standardisation Organisation CENELEC.
Tests of EMC immunity according to the standard EN 61326:
- EN 61000-4-2: Electrostatic discharge immunity test.
- EN 61000-4-3: Radiated, radio-frequency, electromagnetic field immunity test.
- EN 61000-4-4: Electrical fast transient/burst immunity test.
- EN 61000-4-5: Surge immunity test.
- EN 61000-4-6: Immunity to conducted disturbances, induced by radio-frequency fields.
- EN 61000-4-11: Voltage Dips, Short Interruptions and Voltage Variations Immunity Tests.

Tests of EMC emission according to the standard EN 61326:
- EN 61000-3-2: Limits for harmonic current
emissions (equipment input current up to and
including 16 A per phase).
- EN 61000-3-3: Limitation of voltage changes,
voltage fluctuations and flicker in public low-voltage
supply systems, for equipment with rated current

"Design of Laboratory and Bench scale process plants is not really an easy task..., unless you work w ith PID
Eng&Tech. R&D in Chemical Processes relies strongly on having excellent instrumentation and control systems,
like those provided by them"
Dr. David Serrano, Director, Energy Institute
"We at NUCAT are very satisfied with the Microactivity reactor from PID Eng&Tech. Since the first contact everyone
was very helpful and cordial and, above all, very fast in their responses and eager to provide us w ith the best
solution for the problem w e had.
When the unit arrived it performed up to expectations and according to what was asked. Some people in the lab
were concerned about technical assistance because at that time there was no representative in Brazil. When the
first technical problem occurred the solution was provided by a simple exchange of e-mails, showing how
committed the company is in order to have a satisfied costumer.
At this time, I am really forward to buy two more units from this very professional and fantastic company"
Dr. Victor Teixeira da Silva, NUCAT /COPPE, Universidade Federal do Rio de Janeiro
“PID Eng&Tech is a fascinating company. It is like a dream come true for the applied researcher, enabling him to
overcome many of the challenges related to the development of sophisticated experimental equipment in the area
of Chemical Engineering. Since the creation of PID Eng&Tech w e have commissioned a number of original
experimental devices designed for solid fuel gasification, CO2 capture by solid sorbents and others reactors or pilot
plants. We are confident that our fruitful collaboration w ill continue in the future”.
Dr. José J. Pis, Carbon National Institute, CSIC
It is a real pleasure to give you some good and very positive feedbacks concerning the use of the PID Eng&Tech
Microactivity reactor. During the experiments and catalytic reactions we carried out w ith the Microactivity-Reference
reactor, we could observe a totally satisfactory functioning and could appreciate the high friendliness of its use; we
could therefore obtain nice and reliable results in our various studies. We are very satisfied.
Dr. Jean Thivolle-Cazat, National Center of Scientific Research, SOMC, France
“It is a great pleasure for me to be given this opportunity to say a few things about PID Eng&Tech. I have been
closely cooperating with PID Eng&Tech and in particular w ith its director Dr. Jose Prieto, for the last eight years. I
have to stress out from the beginning that it has been eight years of a fruitful and flaw less cooperation.
I have purchased from PID five different units so far and I am completely satisfied by their quality, durability and
their overall performance. Based on my experience, I can assure that PID Eng&Tech is able to offer a multi-level
support which starts with specialized equipment design and reaches out to maintenance and after-sale support.
During these years of cooperation I have experienced only purely professional treatment by the company at the
follow ing levels:
- Equipment Design: The experts of PID have helped me and my group w ith the designing of sophisticated and
complex equipment, w hich is used for advanced scientific experiments, by providing valuable information and
practical solutions to all the problems that came in our way.
- Training: The training programs given by PID consist an adequate way of understanding the operation and
maintenance of their products. It is worthwhile to notice that all training programs are carried out on same unit to be
purchased, something w hich is very helpful for the end users of the unit.
- Installation: All the units that I have purchased so far have arrived at my laboratory in a perfect state and almost
ready for use. Installation requires only the necessary connections to the gasses and/or liquid supplies….. and the
unit is ready for use.
- Maintenance: After attending the training program at PID, maintenance becomes very easy by all means.
- After-sale Support: The after-sale support at PID Eng&Tech is probably the best, most professional kind of support
that I have experienced so far in my career. The people at PID Eng&Tech have helped me and my group numerous
times w ith any modifications, adjustments and changes that we need to make in our equipments. They alw ays
answer promptly and they always deliver within reasonable time. They are fast and effective.
Finally, I w ould like to thank the director and all the personnel of PID for their valuable cooperation so far and
assure that our cooperation will continue to exist for many years”.
Prof. Costas N. Costa, Deputy Coordinator, Cyprus University of Technology
"The best of PID Eng&Tech is that they listen to your technical requirements and offer a personalized solution
quickly by adapting their standard processes. They are able to discern between your scientific and technical
problems, they can offer you solutions!"
Dr. Mario Montes, Euskal Herriko Unibertsitatea
“We are getting excellent performance with Microactivity reactors and pilot plants from PID Eng&Tech”.
Prof. Fierro, Catalysis and Petroleochemestry Institute
“I highly recommend PID Eng&Tech. Their Microactivity reactor is quite impressive, and we are planning to buy
other units from the same company”.
Prof. Saeed M. Al-Zahrani, Chemical Engineer Department King Saudi University
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