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Geological and environmental implications of the evaporite karst in Spain

Geological and environmental implications of the evaporite karst in Spain

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Environ Geol (2008) 53:951–965 957<br />

bedrock collapse s<strong>in</strong>khole 15 m deep <strong>and</strong> 75 m <strong>in</strong> diameter.<br />

Clear evidence <strong>of</strong> <strong>the</strong> active dissolution processes that<br />

affect Triassic <strong>evaporite</strong>s is <strong>the</strong> presence <strong>of</strong> sal<strong>in</strong>e lakes <strong>and</strong><br />

spr<strong>in</strong>gs associated with <strong>the</strong>se formations. The Gallocanta<br />

Lake, 13 km 2 <strong>in</strong> area, is located at <strong>the</strong> bottom <strong>of</strong> a limestone<br />

<strong>karst</strong> polje whose deepen<strong>in</strong>g by corrosion processes<br />

ceased when <strong>the</strong> underly<strong>in</strong>g shales <strong>and</strong> <strong>evaporite</strong>s were<br />

reached, propitiat<strong>in</strong>g <strong>the</strong> development <strong>of</strong> this sal<strong>in</strong>e lacustr<strong>in</strong>e<br />

system <strong>of</strong> paramount <strong>environmental</strong> <strong>in</strong>terest (Gracia<br />

et al. 2001) (Fig. 2d). The waters <strong>of</strong> La Sima spr<strong>in</strong>g <strong>in</strong><br />

Santa Cruz de Moya rise through a <strong>karst</strong>ic conduit developed<br />

at <strong>the</strong> foot <strong>of</strong> a slope flow<strong>in</strong>g <strong>in</strong>to <strong>the</strong> Turia River. In<br />

1984, <strong>the</strong> development <strong>of</strong> several s<strong>in</strong>kholes around <strong>the</strong><br />

spr<strong>in</strong>g triggered a l<strong>and</strong>slide <strong>of</strong> 100,000 tons (Durán <strong>and</strong><br />

Del Val 1984). Subsequent to this event, water <strong>of</strong> <strong>the</strong> Turia<br />

River, which supplies Valencia City, was not dr<strong>in</strong>kable for<br />

a few months, due to <strong>in</strong>creased sal<strong>in</strong>ity.<br />

Karstification <strong>of</strong> Tertiary evaporitic rocks<br />

General geological <strong>and</strong> <strong>environmental</strong> <strong>implications</strong><br />

The subsidence phenomena caused by <strong>karst</strong>ification <strong>of</strong><br />

<strong>evaporite</strong>s is <strong>the</strong> topic that has received a wider attention <strong>in</strong><br />

<strong>the</strong> Tertiary bas<strong>in</strong>s. These are particularly frequent <strong>in</strong> <strong>the</strong><br />

sectors where <strong>the</strong> evaporitic bedrock is overla<strong>in</strong> by<br />

Quaternary alluvial deposits which may behave as perched<br />

aquifers (terraces <strong>and</strong> mantled pediments) or as discharge<br />

areas fed by upward groundwater flows (floodpla<strong>in</strong>s). This<br />

alluvial <strong>karst</strong> occurs <strong>in</strong> reaches <strong>of</strong> <strong>the</strong> ma<strong>in</strong> Spanish<br />

fluvial systems where <strong>the</strong>y traverse evaporitic outcrops<br />

(Gutiérrez <strong>and</strong> Gutiérrez 1998; Benito et al. 2000; Gutiérrez<br />

et al. 2001; Guerrero et al. 2007) (Fig. 1). Commonly,<br />

<strong>in</strong> <strong>the</strong>se areas <strong>the</strong> alluvial deposits show sharp<br />

thicken<strong>in</strong>gs, locally reach<strong>in</strong>g more than 100 m. The<br />

thickened alluvial deposits fill complex dissolution<strong>in</strong>duced<br />

bas<strong>in</strong>s up to several tens <strong>of</strong> kilometers long generated<br />

by synsedimentary subsidence. These thicken<strong>in</strong>gs<br />

are generally larger <strong>in</strong> areas where <strong>the</strong> <strong>evaporite</strong>s conta<strong>in</strong><br />

halite <strong>and</strong> glauberite <strong>in</strong> <strong>the</strong> subsurface. Recently, a novel<br />

morpho-stratigraphical model <strong>of</strong> fluvial evolution controlled<br />

by different subsidence/aggradation ratios has been<br />

proposed for areas affected by this phenomenon (Guerrero<br />

et al. 2007). From an economic perspective, <strong>the</strong> thickened<br />

alluvial deposits constitute highly valuable aquifers <strong>and</strong> a<br />

substantial source <strong>of</strong> aggregates. On <strong>the</strong> o<strong>the</strong>r side, as a<br />

consequence <strong>of</strong> <strong>the</strong> synsedimentary subsidence, deposits <strong>of</strong><br />

different alluvial levels may be superimposed <strong>and</strong> bounded<br />

by angular unconformities (Fig. 3a). These peculiar<br />

arrangements have given rise to erroneous <strong>in</strong>terpretations.<br />

Some authors have attributed a tectonic orig<strong>in</strong> to <strong>the</strong><br />

unconformities <strong>and</strong> ascribed a Tertiary age to <strong>the</strong> deformed<br />

lower units.<br />

Ano<strong>the</strong>r characteristic <strong>of</strong> alluvial sediments underla<strong>in</strong> by<br />

Tertiary <strong>evaporite</strong>s is <strong>the</strong> presence <strong>of</strong> numerous gravitational<br />

deformations. Some <strong>of</strong> <strong>the</strong>se features were erroneously<br />

<strong>in</strong>terpreted as periglacial cryoturbations by several<br />

authors (Imperatori 1955; Johnson 1960; Brosche 1978)<br />

(Fig. 3b). These structures may affect solely <strong>the</strong> alluvial<br />

mantle, or both <strong>the</strong> cover <strong>and</strong> <strong>the</strong> bedrock, depend<strong>in</strong>g on<br />

whe<strong>the</strong>r <strong>the</strong>y result from a rockhead or <strong>in</strong>terstatal <strong>karst</strong>ification,<br />

respectively. Deep-seated <strong>in</strong>terstratal <strong>karst</strong> seems to<br />

be particularly common <strong>in</strong> areas where <strong>the</strong> evaporitic sequence<br />

bears halite <strong>and</strong> glauberite units <strong>in</strong> <strong>the</strong> subsurface<br />

(Guerrero et al. 2004a, 2007). These deformational structures,<br />

toge<strong>the</strong>r with dissolutional features found <strong>in</strong> paleo<strong>karst</strong><br />

exposures, are <strong>the</strong> best source <strong>of</strong> <strong>in</strong>formation to<br />

underst<strong>and</strong> <strong>the</strong> subsidence processes <strong>in</strong>volved <strong>in</strong> <strong>the</strong> generation<br />

<strong>of</strong> s<strong>in</strong>kholes: sagg<strong>in</strong>g, suffusion, <strong>and</strong> collapse (ei<strong>the</strong>r<br />

by brecciation or through <strong>the</strong> development <strong>of</strong> welldef<strong>in</strong>ed<br />

failure planes) (Gutiérrez 2004; Gutiérrez et al.<br />

2008a).<br />

The current activity <strong>of</strong> dissolution <strong>and</strong> subsidence processes<br />

is revealed by <strong>the</strong> formation <strong>and</strong> reactivation <strong>of</strong><br />

s<strong>in</strong>kholes that show a wide variety <strong>of</strong> sizes <strong>and</strong> geometries,<br />

largely depend<strong>in</strong>g on <strong>the</strong> dom<strong>in</strong>ant subsidence mechanism.<br />

S<strong>in</strong>kholes that <strong>in</strong>tercept <strong>the</strong> water table host lakes that may<br />

have a notable <strong>environmental</strong> <strong>in</strong>terest. Although, some <strong>of</strong><br />

<strong>the</strong>se wetl<strong>and</strong>s are protected zones, commonly <strong>the</strong>y are<br />

used for disposal <strong>of</strong> waste material or are filled to transform<br />

<strong>the</strong>m <strong>in</strong>to arable or urban l<strong>and</strong> (Gutiérrez et al. 2007). On<br />

<strong>the</strong> o<strong>the</strong>r h<strong>and</strong>, s<strong>in</strong>khole activity caused by <strong>the</strong> <strong>karst</strong>ification<br />

on Tertiary evaporties constitutes a geological hazard<br />

<strong>of</strong> great economic impact <strong>in</strong> some sectors <strong>of</strong> <strong>the</strong> Spanish<br />

territory, like <strong>in</strong> <strong>the</strong> outskirts <strong>of</strong> Zaragoza city, <strong>in</strong> Calatayud,<br />

<strong>in</strong> <strong>the</strong> sou<strong>the</strong>astern sector <strong>of</strong> Madrid metropolitan<br />

area, <strong>and</strong> <strong>in</strong> Oviedo. As an example, <strong>in</strong> Oviedo city, partially<br />

built <strong>of</strong> Tertiary <strong>evaporite</strong>s, <strong>the</strong> direct economic<br />

losses caused by a s<strong>in</strong>khole event triggered by water<br />

withdrawal <strong>in</strong> 1998 were estimated at 18 million euros<br />

(M. Gutiérrez-Claverol, personal communication).<br />

Generally, <strong>the</strong> s<strong>in</strong>kholes show a higher probability <strong>of</strong><br />

occurrence (hazard) <strong>in</strong> <strong>the</strong> lower alluvial levels, co<strong>in</strong>cid<strong>in</strong>g<br />

with areas where development <strong>and</strong> human activity tend to<br />

concentrate result<strong>in</strong>g <strong>in</strong> high-risk situations (Gutiérrez et al.<br />

2001, 2004a). Commonly, <strong>the</strong> most effective mitigation<br />

strategy is avoidance <strong>of</strong> exist<strong>in</strong>g s<strong>in</strong>kholes <strong>and</strong> high susceptibility<br />

areas. Unfortunately, <strong>the</strong> s<strong>in</strong>khole hazard analyses<br />

are rarely <strong>in</strong>corporated <strong>in</strong> <strong>the</strong> local plann<strong>in</strong>g process.<br />

Ano<strong>the</strong>r frequent characteristic <strong>of</strong> <strong>the</strong> fluvial valleys<br />

excavated <strong>in</strong> Tertiary <strong>evaporite</strong>s is <strong>the</strong> presence <strong>of</strong> unstable<br />

gypsum escarpments with hang<strong>in</strong>g valleys, triangular facets,<br />

<strong>and</strong> numerous mass movements (Gutiérrez et al. 1994,<br />

2001). Slope movements that have produced <strong>the</strong> highest<br />

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