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i THERMAL PROCESSING EFFECTS ON TOTAL ... - McGill University

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lentils do not contain any traces of isoflavone content. Therefore, simple phenols and<br />

flavonoids are mostly low molecular weight compounds which can be solubilized in<br />

alkaline conditions or be retained in the fiber matrix, based on their ester linkages (Bravo,<br />

1998).<br />

Figure 2.4 Basic structure and numbering system of flavonoids (Adapted from<br />

Bravo, 1998)<br />

Another group of basic phenolics, tannins, contain at least two phenol rings.<br />

Tannins are highly hydroxylated compounds of high molecular weight, which form<br />

insoluble complexes with proteins and carbohydrates. They are divided into two groups:<br />

condensed and hydrolysable (Bravo, 1998; Kim et al., 2003). Tannic acid, one of the best<br />

known hydrolysable tannins (Fig 2.5) consists of a pentagalloyl glucose molecule that<br />

can be further esterified into five Gallic acid subunits (Bravo, 1998). Additionally,<br />

phenolic compounds act as radical scavengers and chelators of metals ions (Lopes et al.,<br />

1999, Bravo, 1998).<br />

Figure 2.5: Basic Structure of tannic acid (Adapted from Bravo, 1998)<br />

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