ANGEWANDTE CHEMIE 2000

ANGEWANDTE 

CHEMIE 

2000

Volume 39, Issue 17, 2000 

2963 Cover Picture 

Philip Kraft, Jerzy A. Bajgrowicz, Caroline Denis, Georg Fráter 

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Review 

Odds and Trends: Recent Developments in the Chemistry of 

Odorants 

Philip Kraft, Jerzy A. Bajgrowicz, Caroline Denis, Georg Fráter 

Olefin Metathesis and Beyond 

Alois Fürstner 

Essay 

Kekulé Escapes, Popper Notwithstanding 

Jerome A. Berson 

Highlight 

New Strategies for the Development of an Asymmetric Version of 

the Baylis-Hillman Reaction 

Peter Langer 

Nanoporous Structures by Design 

Michael J. Zaworotko 

Communication 

Supramolecular Nanocircles Consisting of Streptavidin and DNA 

Christof M. Niemeyer, Michael Adler, Song Gao, Lifeng Chi 

Dynamic Observations of the Hydrolysis of a DPPC Monolayer at 

the Air/Water Interface Catalyzed by Phospholipase A2 

Junbai Li, Zhijian Chen, Xiaoli Wang, Gerald Brezesinski, Helmuth Möhwald 

Uranium Hexakisamido Complexes 

Karsten Meyer, Daniel J. Mindiola, Thomas A. Baker, William M. Davis, 

Christopher C. Cummins 

Base-Induced Disproportionation of Elemental Gold 

Anja-Verena Mudring, Martin Jansen 

3067- 

3070 Unusual C-H Se=C Interactions in Aldols of Chiral N-Acyl 

Selones Detected by Gradient-Selected H- Se HMQC NMR

3070- 

3072 

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3074 

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3077 

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3079 

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3084 

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3090 

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3093 

3094- 

3096 

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3099 

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3101 

3101- 

Selones Detected by Gradient-Selected 1 H- 77 Se HMQC NMR 

Spectroscopy and X-ray Crystallography 

Ryszard Michalczyk, Jürgen G. Schmidt, Eddie Moody, Zizhong Li, Ruilian 

Wu, R. Bruce Dunlap, Jerome D. Odom, Louis A. Pete Silks III 

A Highly Active Catalyst System for Intermolecular Hydroacylation 

Chul-Ho Jun, Dae-Yon Lee, Hyuk Lee, Jun-Bae Hong 

Asymmetric Synthesis of a Chiral Secondary Grignard Reagent 

Reinhard W. Hoffmann, Bettina Hölzer, Oliver Knopff, Klaus Harms 

Unusually Stable Vinyl Cations 

Thomas Müller, Rita Meyer, Dirk Lennartz, Hans-Ullrich Siehl 

[(Cp*RuCl)2( -Cl)2]: Bond-Stretch or Spin-State Isomerism? 

John E. McGrady 

Silylated Cyclohexadienes: New Alternatives to Tributyltin Hydride 

in Free Radical Chemistry 

Armido Studer, Stephan Amrein 

[{Au[ -N(SiMe3)2]}4]: The First Base-Free Gold Amide 

Scott D. Bunge, Oliver Just, William S. Rees, Jr. 

Umpolung of P-H Bonds 

Dietrich Gudat, Asadollah Haghverdi, Martin Nieger 

Stereoselective Synthesis and Palladium-Catalyzed 

Transformations of 2-Alkylidene- 5-vinyltetrahydrofurans 

Peter Langer, Edith Holtz 

An Unusual Open-Framework Cobalt(ii) Phosphate with a Channel 

Structure That Exhibits Structural and Magnetic Transitions 

Amitava Choudhury, S. Neeraj, Srinivasan Natarajan, C. N. R. Rao 

Formation of Extended Tapes of Cyclic Water Hexamers in an 

Organic Molecular Crystal Host 

Radu Custelcean, Cerasela Afloroaei, Mircea Vlassa, Mihai Polverejan 

The First Solid-Phase Synthesis of a Peptide-Tethered Platinum(ii) 

Complex 

Marc S. Robillard, A. Rob P. M. Valentijn, Nico J. Meeuwenoord, Gijs A. van 

der Marel, Jacques H. van Boom, Jan Reedijk 

The First Structurally Characterized Aluminum Compounds with 

Terminal Acetylide Groups 

Wenjun Zheng, Nadia C. Mösch-Zanetti, Herbert W. Roesky, Manuel Hewitt, 

Fanica Cimpoesu, Thomas R. Schneider, Andreas Stasch, Jörg Prust 

Ruthenium-Catalyzed Enyne Metathesis of Acetylenic Boronates: A

3104 Concise Route for the Construction of Cyclic 1,3-Dienylboronic 

Esters 

Johanne Renaud, Claus-Dieter Graf, Lukas Oberer I 

3104- 

3107 

3107- 

3110 

3110- 

3114 

3114- 

3117 

3117- 

3119 

3120- 

3122 

3122- 

3124 

3124- 

3127 

3127- 

3130 

3130- 

3132 

A Light-Modulated Sequence-Specific DNA-Binding Peptide 

Ana M. Caamaño, M. Eugenio Vázquez, José Martínez-Costas, Luis Castedo, 

José L. Mascareñas 

TEM Studies of Platinum Nanowires Fabricated in Mesoporous 

Silica MCM-41 

Zheng Liu, Yasuhiro Sakamoto, Tetsu Ohsuna, Kenji Hiraga, Osamu Terasaki, 

Chang Hyun Ko, Hyun June Shin, Ryong Ryoo 

Network Polysilanes: Synthesis, Electrical Conductivity, Charge- 

Transfer Interaction, and Photoconductivity 

Takanobu Kobayashi, Hirokazu Shimura, Shin Mitani, Saeko Mashimo, Aiko 

Amano, Toshihisa Takano, Minoru Abe, Hamao Watanabe, Masashi Kijima, 

Hideki Shirakawa, Hiroyuki Yamaguchi 

Synthesis, Structure, and Magnetism of a Novel Alkoxide Bridged 

Nonacopper(ii) (Cu9O12) [3×3] Square Grid Generated by a Strict 

Self-Assembly Process 

Liang Zhao, Zhiqiang Xu, Laurence K. Thompson, Sarah L. Heath, David O. 

Miller, Masaaki Ohba 

Highly Efficient Degradation of Thiophosphate Pesticides 

Catalyzed by Platinum and Palladium Aryl Oxime Metallacycles 

Gregory M. Kazankov, Victoria S. Sergeeva, Elena N. Efremenko, Larissa 

Alexandrova, Sergey D. Varfolomeev, Alexander D. Ryabov 

[{( 5 -C5Me5)Fe}2( -H)4]: A Novel Dinuclear Iron Tetrahydrido 

Complex 

Yasuhiro Ohki, Hiroharu Suzuki 

Asymmetric Alkylation of Nitroalkanes 

Barry M. Trost, Jean-Philippe Surivet 

Enantiomeric Self-Recognition: Cation-Templated Formation of 

Homochiral Isoguanosine Pentamers 

Xiaodong Shi, James C. Fettinger, Mangmang Cai, Jeffery T. Davis 

Synthesis and Characterization of Iron Silasesquioxane 

Phosphane Complexes 

Fuchen Liu, Kevin D. John, Brian L. Scott, R. Tom Baker, Kevin C. Ott, 

William Tumas 

A Graphite-Like Complex with Large Cavities Constructed with the 

Complex Ligand [Ni II (bpca)2] 

Asako Kamiyama, Tomoko Noguchi, Takashi Kajiwara, Tasuku Ito

3133- 

3137 

3137- 

3140 

3140- 

3142 

I 

A Parallel Library of all Seven A2+B2+C2 Th Regioisomeric 

Hexakisadducts of Fullerene C60: Inspiration from Werner's 

Octahedral Stereoisomerism 

Wenyuan Qian, Yves Rubin 

A Chip-Based Biosensor for the Functional Analysis of Single Ion 

Channels 

Christian Schmidt, Michael Mayer, Horst Vogel 

A Room-Temperature Discotic Nematic Liquid Crystal 

Sandeep Kumar, Sanjay Kumar Varshney



Ivan S. Neretin, Konstantin A. Lyssenko, Mikhail Yu. Antipin, Yuri L. 

Slovokhotov, Olga V. Boltalina, Pavel A. Troshin, Andrei Yu. Lukonin, Lev. 

N. Sidorov, Roger Taylor 

3168- 

3210 

3212- 

3237 

3239- 

3241 

3241- 

3244 

3245- 

3249 

3249- 

3252 

3252- 

3255 

3255- 

3258 

3258- 

3261 

Review 

Multicomponent Reactions with Isocyanides 

Alexander Dömling, Ivar Ugi 

Force Spectroscopy of Molecular Systems - Single Molecule 

Spectroscopy of Polymers and Biomolecules 

Andreas Janshoff, Marcus Neitzert, York Oberdörfer, Harald Fuchs 

Highlight 

+ 

Does CH5 Have (a) Structure? A Tough Test for Experiment and 

Theory 

Peter R. Schreiner 

Organometallic Transformations Demonstrate That Fluorocarbons 

Are Reactive Molecules 

Thomas G. Richmond 

Communication 

Calcium-Dependent Carbohydrate-Carbohydrate Recognition 

between Lewis X Blood Group Antigens 

Armin Geyer, Christian Gege, Richard R. Schmidt 

Solid-Phase Synthesis of Doubly Labeled Peptide Nucleic Acids as 

Probes for the Real-Time Detection of Hybridization 

Oliver Seitz 

Redox Switches with Chiroptical Signal Expression Based on 

Binaphthyl Boron Dipyrromethene Conjugates 

Gerhard Beer, Christoph Niederalt, Stefan Grimme, Jörg Daub 

Allosteric Regulation of Artificial Phosphoesterase Activity by 

Metal Ions 

Igor O. Fritsky, Reina Ott, Roland Krämer 

Hexacyclinic acid, a Polyketide from Streptomyces with a Novel 

Carbon Skeleton 

Published Online: 13 Sep 2000

3261- 

3263 

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3276- 

3279 

3279- 

3281 

3281- 

3283 

3284- 

3287 

3287- 

3290 

3290- 

3292 

3293- 

3296 

The Dimerization of Chiral Allenes: Pairs of Enantiomers and Pairs 

of Homomers Furnish Different Diastereomers 

Manfred Christl, Stefan Groetsch, Kurt Günther 

Five-Coordinate Carbides in Ti-Al-C Complexes 

James E. Kickham, Frédéric Guérin, Jeffrey C. Stewart, Douglas W. Stephan 

The First Example of an Equilibrium between a Carbene and an 

Isomeric Carbyne Transition Metal Complex 

Pablo González-Herrero, Birgit Weberndörfer, Kerstin Ilg, Justin Wolf, Helmut 

Werner 

Model Studies of Phytochrome Photochromism: Protein-Mediated 

Photoisomerization of a Linear Tetrapyrrole in the Absence of 

Covalent Bonding 

Ingo Lindner, Silvia E. Braslavsky, Kurt Schaffner, Wolfgang Gärtner 

C60F18, a Flattened Fullerene: Alias a Hexa-Substituted Benzene 

Ivan S. Neretin, Konstantin A. Lyssenko, Mikhail Yu. Antipin, Yuri L. 

Slovokhotov, Olga V. Boltalina, Pavel A. Troshin, Andrei Yu. Lukonin, Lev. 

N. Sidorov, Roger Taylor 

The First Microporous Framework Cerium Silicate 

João Rocha, Paula Ferreira, Luís D. Carlos, Artur Ferreira 

Is Hydrogen Tunneling Involved in AcylCoA Desaturase 

9 

Reactions? The Case of a Desaturase That Transforms (E)-11- 

Tetradecenoic Acid into (Z,E)-9,11-Tetradecadienoic Acid 

José Luís Abad, Francisco Camps, Gemma Fabriàs 

Molecular Recognition with Introverted Functionality 

Adam R. Renslo, Julius Rebek, Jr. 

Towards Synthetic Molecular Muscles: Contraction and Stretching 

of a Linear Rotaxane Dimer 

M. Consuelo Jiménez, Christiane Dietrich-Buchecker, Jean-Pierre Sauvage 

Conformation Control of Oligosilanes Based on Configurationally 

Constrained Bicyclic Disilane Units 

Kohei Tamao, Hayato Tsuji, Masayoshi Terada, Masahiro Asahara, Shigehiro 

Yamaguchi, Akio Toshimitsu 

Asymmetric Synthesis of Baylis-Hillman-Type Allyl Alcohols via a 

Chiral Acetylenic Ester Titanium Alkoxide Complex 

Daisuke Suzuki, Hirokazu Urabe, Fumie Sato 

Analysis of Solid-Phase Reactions: Product Identification and 

Quantification by Use of UV-Chromophore-Containing Dual-Linker 

Analytical Constructs 

Geoff M. Williams, Robin A. E. Carr, Miles S. Congreve, Corinne Kay,

3296- 

3299 

3299- 

3302 

3302- 

3304 

3304- 

3307 

3307- 

3310 

3310- 

3312 

3312- 

3315 

3315- 

3319 

3319- 

3321 

3321- 

3324 

Stephen C. McKeown, Peter J. Murray, Jan J. Scicinski, Stephen P. Watson 

Redox-Switched Control of Binding Strength in Hydrogen-Bonded 

Metallocene Complexes 

Jonathan D. Carr, Simon J. Coles, Michael B. Hursthouse, Mark E. Light, 

James H. R. Tucker, Joanna Westwood 

Toward Crystalline Covalent Solids: Crystal-to-Crystal Dihydrogen 

to Covalent Bonding Transformation in NaBH4 THEC 

Radu Custelcean, Mircea Vlassa, James E. Jackson 

NMR and Theoretical Study of Acid Sites Formed by Adsorption of 

SO3 onto Oxide Surfaces 

Jinhua Zhang, John B. Nicholas, James F. Haw 

Syntheses, Structures, and Magnetic Properties of Two 

Gadolinium(iii)-Copper(ii) Coordination Polymers by a Hydrothermal 

Reaction 

Yucang Liang, Rong Cao, Weiping Su, Maochun Hong, Wenjian Zhang 

Experimental Observation of Pentaatomic Tetracoordinate Planar 

- 

Si- and Ge-Containing Molecules: MAl4 and MAl4 

Alexander I. Boldyrev, Xi Li, Lai-Sheng Wang 

Control of Architecture in Block-Copolymer Vesicles 

Hongwei Shen, Adi Eisenberg 

Hydrogen-Bonded Hexamolybdenum Clusters: Formation of 

Inorganic-Organic Networks 

Nicholas Prokopuk, Charles S. Weinert, David P. Siska, Charlotte L. Stern, 

Duward F. Shriver 

A Combinatorial Approach to Polyketide-Type Libraries by Iterative 

Asymmetric Aldol Reactions Performed on Solid Support 

Ian Paterson, Monica Donghi, Kai Gerlach 

Synthesis, Structure, and Reactivity of a 1 4 ,3 2 -Diphosphaallene 

Tsuyoshi Kato, Heinz Gornitzka, Antoine Baceiredo, Guy Bertrand 

4,5-Bis(diphenylphosphinoyl)-1,2,3-triazole: A Powerful New Ligand 

That Uses Two Different Modes of Chelation 

Arnold L. Rheingold, Louise M. Liable-Sands, Swiatoslaw Trofimenko



Jens Krömer, Idoia Rios-Carreras, Gerda Fuhrmann, Christiane Musch, Markus 

Wunderlin, Tony Debaerdemaeker, Elena Mena-Osteritz, Peter Bäuerle 

3348- 

3391 

3392- 

3406 

3407- 

3409 

3409- 

3411 

3413- 

3417 

3417- 

3419 

3419- 

3422 

3422- 

3425 

3425- 

Review 

Artificial Molecular Machines 

Vincenzo Balzani, Alberto Credi, Françisco M. Raymo, J. Fraser Stoddart 

The Chemistry of Form 

Stephen Mann 

Highlight 

Condensative Chain Polymerization - A Way Towards Living 

Polycondensation? 

Brigitte Voit 

Isopenicillin N Synthase: An Enzyme at Work 

Wolfdieter A. Schenk 

Communication 

A New Type of Supramolecular Compound: Molybdenum-Oxide- 

Based Composites Consisting of Magnetic Nanocapsules with 

Encapsulated Keggin-Ion Electron Reservoirs Cross-Linked to a 

Two-Dimensional Network 

Achim Müller, Samar K. Das, Paul Kögerler, Hartmut Bögge, Marc 

Schmidtmann, Alfred X. Trautwein, Volker Schünemann, Erich Krickemeyer, 

Wilhelm Preetz 

Linear Coupling of Three CO Ligands of Chromium Hexacarbonyl 

Leading to Functionalized Butenolides via Fischer Carbene 

Complexes 

Henri Rudler, Andrée Parlier, Victor Certal, Jacqueline Vaissermann 

Spectroscopy of the Formation of Microporous Transition Metal Ion 

Containing Aluminophosphates under Hydrothermal Conditions 

Bert M. Weckhuysen, David Baetens, Robert A. Schoonheydt 

First Catalytic Aldol-Transfer Reaction via Aluminum Enolates: A 

New Way To Generate Aldol Adducts of Aldehydes from Aldol 

Adducts of Ketones 

Ilkka Simpura, Vesa Nevalainen 

Applications of a Nonlinear Organic Reaction of Carbamates To

3428 Proliferate Aliphatic Amines 

Koji Arimitsu, Mana Miyamoto, Kunihiro Ichimura 

3428- 

3430 

3430- 

3432 

3432- 

3434 

3435- 

3437 

3438- 

3440 

3440- 

3442 

3442- 

3445 

3445- 

3447 

3447- 

3450 

3451- 

3453 

3453- 

3456 

3456- 

3460 

Probing the Conformation of Flexible Catalysts in Solution 

Jaume Balsells, Juan M. Betancort, Patrick J. Walsh 

A Three-Step Synthesis of Halomon 

Takayuki Sotokawa, Takeshi Noda, Sun Pi, Masahiro Hirama 

Synthesis of a Triazatriangulenium Salt 

Bo W. Laursen, Frederik C. Krebs 

Octahedral Grignard Reagents Can Be Chiral at Magnesium 

Marcus Vestergren, Björn Gustafsson, Öjvind Davidsson, Mikael Håkansson 

Design and Synthesis of Intramolecular Resonance-Energy 

Transfer Probes for Use in Ratiometric Measurements in Aqueous 

Solution 

Yasutomo Kawanishi, Kazuya Kikuchi, Hideo Takakusa, Shin Mizukami, 

Yasuteru Urano, Tsunehiko Higuchi, Tetsuo Nagano 

The Catalytic Alkylation of Aromatic Imines by Wilkinson's 

Complex: The Domino Reaction of Hydroacylation and ortho- 

Alkylation 

Chul-Ho Jun, Jun-Bae Hong, Yeon-Hee Kim, Kwan-Yong Chung 

Microreactors for Dynamic, High Throughput Screening of 

Fluid/Liquid Molecular Catalysis 

Claude de Bellefon, Nathalie Tanchoux, Sylvain Caravieilhes, Pierre 

Grenouillet, Volker Hessel 

Macromolecular-Multisite Catalysts Obtained by Grafting 

Diaminoaryl Palladium(ii) Complexes onto a Hyperbranched- 

Polytriallylsilane Support 

Christian Schlenk, Arjan W. Kleij, Holger Frey, Gerard van Koten 

Effective Gelation of Water Using a Series of Bis-urea Dicarboxylic 

Acids 

Lara A. Estroff, Andrew D. Hamilton 

Ruthenium-Based Four-Coordinate Olefin Metathesis Catalysts 

Melanie S. Sanford, Lawrence M. Henling, Michael W. Day, Robert H. Grubbs 

Calix[6]arene as a Wheel for Rotaxane Synthesis 

Arturo Arduini, Riccardo Ferdani, Andrea Pochini, Andrea Secchi, Franco 

Ugozzoli 

Insulated Molecular Wires: Synthesis of Conjugated Polyrotaxanes 

by Suzuki Coupling in Water 

Peter N. Taylor, Michael J. O'Connell, Luke A. McNeill, Michael J. Hall, Robin

3460- 

3463 

3463- 

3465 

3465- 

3467 

3467- 

3470 

3470- 

3473 

3473- 

3478 

3478- 

3480 

3481- 

3486 

3486- 

3489 

3490- 

3491 

3492- 

3494 

T. Aplin, Harry L. Anderson 

[{Ti( 5 -C5Me5)( -NH)}3( 3-N)]: An Efficient Entry to Single and 

Double Cube-Type Nitrido Complexes 

Angel Abarca, Avelino Martín, Miguel Mena, Carlos Yélamos 

Novel Mode of C-C Bond Cleavage of Norbornadiene on a Dinuclear 

Ruthenium Complex 

Yasuhiro Ohki, Hiroharu Suzuki 

Asymmetric, Catalytic Phenyl Transfer to Aldehydes: 

Enantioselective Synthesis of Diarylmethanols 

Carsten Bolm, Nina Hermanns, Jens P. Hildebrand, Kilian Muñiz 

A Synthetic Azinomycin Analogue with Demonstrated DNA Cross- 

Linking Activity: Insights into the Mechanism of Action of this 

Class of Antitumor Agent 

John A. Hartley, Ali Hazrati, Lloyd R. Kelland, Ruzwana Khanim, Michael 

Shipman, Franck Suzenet, Louise F. Walker 

Fascinating Alkali Halide Structures of Different Dimensionalities 

Incorporated in Host Lattices 

R. Vaidhyanathan, S. Neeraj, P.A. Prasad, Srinivasan Natarajan, C.N.R. Rao 

Model Studies towards Diazonamide A: Synthesis of the 

Heterocyclic Core 

K. C. Nicolaou, Scott A. Snyder, Klaus B. Simonsen, Alexandros E. Koumbis 

Triplet Di(9-anthryl)carbene Undergoes Trimerization 

Yasutake Takahashi, Masaaki Tomura, Ken-ichi Yoshida, Shigeru Murata, 

Hideo Tomioka 

Synthesis of the First Fully -Conjugated Macrocyclic 

Oligothiophenes: Cyclo[n]thiophenes with Tunable Cavities in the 

Nanometer Regime 

Jens Krömer, Idoia Rios-Carreras, Gerda Fuhrmann, Christiane Musch, Markus 

Wunderlin, Tony Debaerdemaeker, Elena Mena-Osteritz, Peter Bäuerle 

Investigating the Surface Morphology of Triacontyl Phases with 

Spin-Diffusion Solid-State NMR Spectroscopy 

Martin Raitza, Jürgen Wegmann, Stefan Bachmann, Klaus Albert 

The Influence of Mismatches on Long-Distance Charge Transport 

through DNA 

Bernd Giese, Stefan Wessely 

A Rectangular Zinc Cluster and a Rectangular Nickel Cluster That 

Exhibits Ferromagnetic Coupling 

Rolf W. Saalfrank, Stefan Trummer, Uwe Reimann, Mubarik M. Chowdhry, 

Frank Hampel, Oliver Waldmann

3494- 

3497 

3497- 

3500 

3500- 

3503 

3503- 

3506 

Diastereoselective and Enantioselective Palladium-Catalyzed 

Allylic Substitution with Nonstabilized Ketone Enolates 

Manfred Braun, Frank Laicher, Thorsten Meier 

Hydrogen-Bonded Analogues of Cavitands 

Alexander Shivanyuk, Thomas P. Spaniol, Kari Rissanen, Erkki Kolehmainen, 

Volker Böhmer 

Synthesis of the Square-Planar Gallium Species K2[Ga4(C6H3-2,6- 

Trip2)2] (Trip=C6H2-2,4,6-iPr3): The Role of Aryl-Alkali Metal Ion 

Interactions in the Structure of Gallium Clusters 

Brendan Twamley, Philip P. Power 

Light-Driven Microfabrication: Assembly of Multicomponent, Three- 

Dimensional Structures by Using Optical Tweezers 

R. Erik Holmlin, Michele Schiavoni, Clifford Y. Chen, Stephen P. Smith, Mara 

G. Prentiss, George M. Whitesides



Matthias Driess, Christian Monsé, Klaus Merz, Christoph van Wüllen 

3532- 

3556 

3558- 

3588 

3589- 

3590 

3590- 

3593 

3595- 

3598 

3598- 

3601 

3601- 

3604 

3604- 

3607 

3607- 

3610 

Review 

Asymmetric Activation 

Koichi Mikami, Masahiro Terada, Toshinobu Korenaga, Yousuke Matsumoto, 

Makoto Ueki, Rémy Angelaud 

Catalytic Asymmetric Hetero-Diels-Alder Reactions of Carbonyl 

Compounds and Imines 

Karl Anker Jørgensen 

Highlight 

Hot Stones or Cold Soup? New Investigations on the Endogenous 

Origin of Organic Compounds on Earth 

Kay Severin 

New and Selective Transition Metal Catalyzed Reactions of Allenes 

A. Stephen K. Hashmi L 

Communication 

Fast, Convenient, and Efficient Molybdenum-Catalyzed Asymmetric 

Allylic Alkylation under Noninert Conditions: An Example of 

Microwave-Promoted Fast Chemistry 

Nils-Fredrik K. Kaiser, Ulf Bremberg, Mats Larhed, Christina Moberg, Anders 

Hallberg 

A Novel Borosilicate Cage Compound with an Incomplete B4Si4 

Cube Structure: [(tBuSi)4(CH2=CHC6H4B)4O10] 

Lorraine A. Neville, Trevor R. Spalding, George Ferguson 

Hydrogen Bonding Interactions in Amorphous Salicyl Salicylate 

Bryan Greener, Stephen J. Archibald, Michael Hodkinson 

Cooperative Asymmetric Catalysis with Dendrimeric [Co(salen)] 

Complexes 

Rolf Breinbauer, Eric N. Jacobsen 

Structural Characterization of a Cyclohexameric meta- 

Phenyleneethynylene Made by Alkyne Metathesis with In Situ 

Catalysts 

Ping-Hua Ge, Wei Fu, Wolfgang A. Herrmann, Eberhardt Herdtweck, Charles 

Campana, Richard D. Adams, Uwe H. F. Bunz

3610- 

3612 

3613- 

3616 

3616- 

3619 

3620- 

3622 

3622- 

3626 

3626- 

3629 

3630- 

3632 

3633- 

3635 

3635- 

3638 

3638- 

3641 

3641- 

3643 

3644- 

Diisobutylaluminum-Promoted Regioselective De-O-benzylation of 

Perbenzylated Cyclodextrins: A Powerful New Strategy for the 

Preparation of Selectively Modified Cyclodextrins 

Alan J. Pearce, Pierre Sinaÿ 

Experimental Charge Densities of Semiconducting Cage Structures 

Containing Alkaline Earth Guest Atoms 

Anders Bentien, Anders E. C. Palmqvist, J. Daniel Bryan, Susan Latturner, 

Galen D. Stucky, Lars Furenlid, Bo B. Iversen 

Self-Assembly of Pentameric Porphyrin Light-Harvesting Antennae 

Complexes 

Richard A. Haycock, Arkady Yartsev, Ulrike Michelsen, Villy Sundström, 

Christopher A. Hunter 

A Refined Model for [Fe3S4] 0 Clusters in Proteins 

Detlef Bentrop, Ivano Bertini, Marco Borsari, Grazia Cosenza, Claudio 

Luchinat, Yohei Niikura 

The Total Synthesis of the Annonaceous Acetogenin, 

Muricatetrocin C 

Darren J. Dixon, Steven V. Ley, Dominic J. Reynolds 

Development of a Diversity-Based Approach for the Discovery of 

Stereoselective Polymerization Catalysts: Identification of a 

Catalyst for the Synthesis of Syndiotactic Polypropylene 

Jun Tian, Geoffrey W. Coates 

Pentaatomic Tetracoordinate Planar Carbon, [CAl4] 2- : A New 

Structural Unit and Its Salt Complexes 

Xi Li, Hai-Feng Zhang, Lai-Sheng Wang, Grant D. Geske, Alexander I. 

Boldyrev 

Ferromagnetic Ordering in a Two-Dimensional Copper Complex 

with Dual End-to-End and End-On Azide Bridges 

Zhen Shen, Jing-Lin Zuo, Song Gao, You Song, Chi-Ming Che, Hoong-Kun 

Fun, Xiao-Zeng You 

Asymmetric Conjugate Addition of Azide to , -Unsaturated 

Carbonyl Compounds Catalyzed by Simple Peptides 

Thomas E. Horstmann, David J. Guerin, Scott J. Miller 

The First Dendrimer-Based Enantioselective Fluorescent Sensor for 

the Recognition of Chiral Amino Alcohols 

Vincent J. Pugh, Qiao-Sheng Hu, Lin Pu 

Catalyst for DNA Ligation: Towards a Two-Stage Replication Cycle 

Jingdong Ye, Yahaloma Gat, David G. Lynn 

From Cubane to Supercubane: The Design, Synthesis, and

3646 Structure of a Three-Dimensional Open Framework Based on a 

Ln4O4 Cluster 

Bao-Qing Ma, Da-Shun Zhang, Song Gao, Tian-Zhu Jin, Chun-Hua Yan, 

Guang-Xian Xu 

3646- 

3649 

3649- 

3652 

3652- 

3656 

3656- 

3658 

3658- 

3660 

3660- 

3663 

3664- 

3667 

3667- 

3669 

3669- 

3671 

3671- 

3674 

Remarkable Anionic Axial Ligand Effects of Iron(iii) Porphyrin 

Complexes on the Catalytic Oxygenations of Hydrocarbons by H2O2 

and the Formation of Oxoiron(iv) Porphyrin Intermediates by m- 

Chloroperoxybenzoic Acid 

Wonwoo Nam, Mi H. Lim, So-Young Oh, Jung H. Lee, Ha J. Lee, Seung K. 

Woo, Cheal Kim, Woonsup Shin 

Dynamics of Hole Trapping by G, GG, and GGG in DNA 

William B. Davis, Izabela Naydenova, Reinhard Haselsberger, Alexander 

Ogrodnik, Bernd Giese, Maria E. Michel-Beyerle 

From Glycals to Glycopeptides: A Convergent and Stereoselective 

Total Synthesis of a High Mannose N-Linked Glycopeptide 

Zhi-Guang Wang, XuFang Zhang, David Live, Samuel J. Danishefsky 

Chemical Synthesis and DNA Photocleavage of the Intercalator- 

Carbohydrate Hybrid Moiety of the Neocarzinostatin Chromophore 

Kazunobu Toshima, Shigeki Takai, Yutaka Maeda, Ryusuke Takano, Shuichi 

Matsumura 

Alkane Carbonylation with Carbon Monoxide on Sulfated Zirconia: 

NMR Observation of Ketone and Carboxylic Acid Formation from 

Isobutane and CO 

Alexander G. Stepanov, Mikhail V. Luzgin, Alexey V. Krasnoslobodtsev, Vera 

P. Shmachkova, Nina S. Kotsarenko 

Nucleoglycoconjugates: Design and Synthesis of a New Class of 

DNA-Carbohydrate Conjugates 

Terry L. Sheppard, Chi-Huey Wong, Gerald F. Joyce 

Aligned Coaxial Nanowires of Carbon Nanotubes Sheathed with 

Conducting Polymers 

Mei Gao, Shaoming Huang, Liming Dai, Gordon Wallace, Ruiping Gao, 

Zhonglin Wang 

Living Coordination Polymerization of Allene Derivatives Bearing 

Hydroxy Groups by -Allylnickel Catalyst 

Masanori Taguchi, Ikuyoshi Tomita, Takeshi Endo 

Novel Group-Transfer Three-Component Coupling of Silyltellurides, 

Carbonyl Compounds, and Isocyanides 

Hiroshi Miyazoe, Shigeru Yamago, Jun-ichi Yoshida 

Structural Characterization of Novel Olefinic Cation Radicals: X-ray 

Crystallographic Evidence of - Hyperconjugation

3674- 

3676 

3676- 

3680 

3681- 

3683 

3684- 

3686 

3686- 

3688 

3688- 

3691 

3691- 

3694 

3695- 

3697 

3697- 

3699 

3699- 

3700 

3701- 

3703 

3703- 

Jay K. Kochi, Rajendra Rathore, Chengjian Zhu, and, Sergey V. Lindeman 

The First Templated Borogermanate (C2N2H10)2[(BO2.5)2(GeO2)3]: 

Linkage of Tetrahedra of Significantly Different Sizes 

Mike S. Dadachov, Kai Sun, Tony Conradsson, Xiaodong Zou 

Dodecacarbonyltetracobalt Catalysis in the Thermal Pauson-Khand 

Reaction 

Marie E. Krafft, Llorente V. R. Boñaga 

The First Stable Diazonium Ion on Solid Support - Investigations on 

Stability and Usage as Linker and Scavenger in Solid-Phase 

Organic Synthesis 

Stefan Dahmen, Stefan Bräse 

Perstannylated Ammonium and Phosphonium Ions: Organometallic 

Onium Ions That Are also Base-Stabilized Stannylium Ions 

Matthias Driess, Christian Monsé, Klaus Merz, Christoph van Wüllen 

New and Facile Entry to Nitrilium Phosphane Ylide Complex 

Chemistry by Using 7-Phosphanorbornadiene Complexes 

Rainer Streubel, Udo Schiemann, Peter G. Jones, Ngoc Hoa Tran Huy, François 

Mathey 

Spin Frustration in a Dimeric Mn II Complex with a Metallocene- 

Substituted -Nitronyl Nitroxide Radical 

Daniel Ruiz-Molina, Christian Sporer, Klaus Wurst, Peter Jaitner, Jaume 

Veciana 

Al5Br7 5 THF - The First Saltlike Aluminum Subhalide 

Christoph Klemp, Gregor Stößer, Ingo Krossing, Hansgeorg Schnöckel 

Efficient Enantioselective Extraction of Tris(diimine)ruthenium(ii) 

Complexes by Chiral, Lipophilic TRISPHAT Anions 

Jérôme Lacour, Catherine Goujon-Ginglinger, Sonya Torche-Haldimann, 

Jonathan J. Jodry 

2- 

Pb2 as Ligand in [Ph4P]2[{W(CO)5}4Pb2] 

Peter Rutsch, Gottfried Huttner 

Strong Field Iron(ii) Complex Converted by Light into a Long-Lived 

High-Spin State 

Franz Renz, Hiroki Oshio, Vadim Ksenofontov, Markus Waldeck, Hartmut 

Spiering, Philipp Gütlich 

In situ Transfer of Parahydrogen-Induced Nuclear Spin Polarization 

- Structural Characterization of Hydrogenation Intermediates 

Patrick Hübler, Joachim Bargon 

Hexaaryltetragermabuta-1,3-diene: A Molecule with Conjugated Ge-

3705 Ge Double Bonds 

Helmut Schäfer, Wolfgang Saak, Manfred Weidenbruch 

3705- 

3706 

3707- 

3710 

Functionalized Tellurium(ii) Thiolates: Tellurium Bis(2hydroxyethanethiolate) 

Hydrate, the First H2O-Te II Complex 

Holger Fleischer, Dieter Schollmeyer 

Asymmetric Activation/Deactivation of Racemic Ru Catalysts for 

Highly Enantioselective Hydrogenation of Ketonic Substrates 

Koichi Mikami, Toshinobu Korenaga, Takeshi Ohkuma, Ryoji Noyori



Anja Schwögler, Lars T. Burgdorf, Thomas Carell 

3740- 

3749 

3750- 

3771 

3772- 

3789 

3791- 

3794 

3794- 

3796 

3797- 

3800 

3801- 

3804 

3804- 

3808 

3808- 

3810 

3810- 

3813 

Review 

Organoselenium Chemistry in Stereoselective Reactions 

Thomas Wirth 

Wherefore Art Thou Copper? Structures and Reaction Mechanisms 

of Organocuprate Clusters in Organic Chemistry 

Eiichi Nakamura, Seiji Mori 

Ionic Liquids - New Solutions for Transition Metal Catalysis 

Peter Wasserscheid, Wilhelm Keim 

Correspondence 

On Closed-Shell Interactions, Polar Covalences, d Shell Holes, and 

Direct Images of Orbitals: The Case of Cuprite 

J. M. Zuo, M. O'Keeffe, M. Kim, J. C. H. Spence 

Final Comment on the Discussions of The Case of Cuprite 

Shu Guang Wang, W. H. Eugen Schwarz 

Highlight 

Stable Systems with a Triple Bond to Silicon or Its Homologues: 

Another Challenge 

Peter Jutzi 

Communication 

Monosaccharide-Alkyl Glycoside Glass Phases: Plasticization with 

Hydrophilic and Hydrophobic Molecules 

Iqbal Gill, Rao Valivety 

Enzymatic Glycosylation in Plasticized Glass Phases: A Novel and 

Efficient Route to O-Glycosides 

Iqbal Gill, Rao Valivety 

(CN3H6)4[Zn3(SeO3)5]: The First Organically Templated Selenite 

William T. A. Harrison, Mark L. F. Phillips, Jesse Stanchfield, Tina M. Nenoff 

Correlation of the Topology of the Electron Density of Pyrite-Type 

Transition Metal Sulfides with Their Catalytic Activity in 

Hydrodesulfurization

3813- 

3816 

3816- 

3819 

3819- 

3822 

3823- 

3828 

3829- 

3831 

3831- 

3835 

3835- 

3839 

3839- 

3842 

3843- 

3845 

3845- 

3848 

Yosslen Aray, Jesus Rodriguez, David Vega, Eloy Nouel Rodriguez-Arias 

Higher Adducts of C60 by Tether-Directed Remote Functionalization: 

X-Ray Crystal Structure and Reactivity of a Chiral Hexakis- 

Cyclopropanated Fullerene with all Addends Located along an 

Equatorial Belt 

Craig R. Woods, Jean-Pascal Bourgeois, Paul Seiler, François Diederich 

High-Throughput Structure Verification of a Substituted 4- 

Phenylbenzopyran Library by Using 2D NMR Techniques 

Harald Schröder, Peter Neidig, Gérard Rossé 

Molecular Topology: Easy Self-Assembly of an Organometallic 

Doubly Braided [2]Catenane 

Christopher P. McArdle, Jagadese J. Vittal, Richard J. Puddephatt 

Target-Accelerated Combinatorial Synthesis and Discovery of 

Highly Potent Antibiotics Effective Against Vancomycin-Resistant 

Bacteria 

K. C. Nicolaou, Robert Hughes, Suk Young Cho, Nicolas Winssinger, Christian 

Smethurst, Harald Labischinski, Rainer Endermann 

Photoinduced Electron Transfer from a Porphyrin to an Electron 

Acceptor in an Antibody-Combining Site 

Hiroyasu Yamaguchi, Mikiharu Kamachi, Akira Harada 

Hexagonal Layered Materials Composed of [M2(O2CCF3)4] (M=Ru and 

Rh) Donors and TCNQ Acceptors 

Hitoshi Miyasaka, Cristian S. Campos-Fernández, Rodolphe Clérac, Kim R. 

Dunbar 

Supramolecular Chemistry of Anionic Cobalt(iii) Bis(dicarbollide) 

and Cyclotriveratrylene in the Solid State and the Gas Phase 

Michaele J. Hardie, Colin L. Raston 

Novel Oligosaccharide Binding to the Cerium(iv) Bis(porphyrinate) 

Double Decker: Effective Amplification of a Binding Signal through 

Positive Homotropic Allosterism 

Atsushi Sugasaki, Masato Ikeda, Masayuki Takeuchi, Seiji Shinkai 

Open Square-Grid Coordination Polymers of the Dimensions 20×20 

Å: Remarkably Stable and Crystalline Solids Even after Guest 

Removal 

Kumar Biradha, Yoshito Hongo, Makoto Fujita 

The Electrical Properties of Gold Nanoparticle Assemblies Linked 

by DNA 

So-Jung Park, Anne A. Lazarides, Chad A. Mirkin, Paul W. Brazis, Carl R. 

Kannewurf, Robert L. Letsinger

3849- Rapid, Reversible Oxygen Atom Transfer between an 

3851 Oxomanganese(v) Porphyrin and Bromide: A Haloperoxidase Mimic 

with Enzymatic Rates 

Ning Jin, James L. Bourassa, Steven C. Tizio, John T. Groves 

3851- 

3855 

3855- 

3859 

3859- 

3862 

3862- 

3865 

3866- 

3868 

3868- 

3872 

3872- 

3873 

3874- 

3876 

3876- 

3879 

3879- 

3881 

The High-Valent Compound of Cytochrome P450: The Nature of the 

Fe-S Bond and the Role of the Thiolate Ligand as an Internal 

Electron Donor 

François Ogliaro, Shimrit Cohen, Michael Filatov, Nathan Harris, Sason Shaik 

Formation of Novel Ordered Mesoporous Silicas with Square 

Channels and Their Direct Observation by Transmission Electron 

Microscopy 

Tatsuo Kimura, Takayuki Kamata, Minekazu Fuziwara, Yuri Takano, Mizue 

Kaneda, Yasuhiro Sakamoto, Osamu Terasaki, Yoshiyuki Sugahara, Kazuyuki 

Kuroda 

Second-Order Nonlinear Optical Properties of Functionalized 

Ionophores: Cation-Steered Modulation of the First 

Hyperpolarizability 

Stephan Houbrechts, Yuji Kubo, Tomokazu Tozawa, Sumio Tokita, Tatsuo 

Wada, Hiroyuki Sasabe 

Self-Assembled Organometallic Block Copolymer Nanotubes 

Jose Raez, Raluca Barjovanu, Jason A. Massey, Mitchell A. Winnik, Ian 

Manners 

A Three-Step Entry to the Aspirochlorine Family of Antifungal 

Agents 

Zhicai Wu, Lawrence J. Williams, Samuel J. Danishefsky 

Ion-Specific Aggregation in Conjugated Polymers: Highly Sensitive 

and Selective Fluorescent Ion Chemosensors 

Jinsang Kim, D. Tyler McQuade, Sean K. McHugh, Timothy M. Swager 

[{Ir( 5 -C5Me5)(CO)}6Hg8][CF3CO2]6, a Mixed-Metal Cluster with an 

Ir6Hg6 Twelve-Membered Ring and Additional Hg Centers and Metal- 

Metal Bonds 

Giuseppina Chiaradonna, Giovanni Ingrosso, Fabio Marchetti 

Synthesis of Thymine Glycol Containing Oligonucleotides from a 

Building Block with the Oxidized Base 

Shigenori Iwai 

A Concise Stereoselective Route to the Pentacyclic Frameworks of 

Arisugacin A and Territrem B 

Luke R. Zehnder, Richard P. Hsung, Jiashi Wang, Geoffrey M. Golding 

Formation of the Unprecedented Trilithio-Capped 

Heteroadamantanyl Iminoalane Anion [(HAl)4(NPh)6{Li(OEt2)}3] - : An

3881- 

3884 

3884- 

3886 

3886- 

3888 

3889- 

3890 

3891- 

3893 

3894- 

3896 

3896- 

3898 

3898- 

3901 

3901- 

3905 

3905- 

3909 

3909- 

3911 

Open Cage Derived from a Rhombododecahedron 

Kenneth W. Henderson, Alan R. Kennedy, Arlene E. McKeown, Robert E. 

Mulvey 

New Fused Bicyclic Cyclotrigermanes from Cycloaddition Reactions 

of Cyclotrigermene 

Norihisa Fukaya, Masaaki Ichinohe, Akira Sekiguchi 

Direct Bromination of Keggin Fragments To Give [PW9O28Br6] 3- : A 

Polyoxotungstate with a Hexabrominated Face 

R. John Errington, Richard L. Wingad, William Clegg, Mark R. J. Elsegood 

Control of Xanthine Oxidase Activity by Light 

Lin Ai Tai, Kuo Chu Hwang 

Highly Enantioselective Rh-Catalyzed Hydrogenation Reactions 

Based on Chiral Monophosphite Ligands 

Manfred T. Reetz, Gerlinde Mehler 

Super-High-Throughput Screening of Enantioselective Catalysts by 

Using Capillary Array Electrophoresis 

Manfred T. Reetz, Klaus M. Kühling, Alfred Deege, Heike Hinrichs, Detlev 

Belder 

Novel Nickel(ii) Complexes for the Catalytic Copolymerization of 

Ethylene and Carbon Monoxide: Polyketone Synthesis in 

Supercritical Carbon Dioxide 

Wolfgang Kläui, Jochen Bongards, Guido J. Reiß 

A Soluble Polymer-Bound Ruthenium Carbene Complex: A Robust 

and Reusable Catalyst for Ring-Closing Olefin Metathesis 

Qingwei Yao 

Synthesis and Application of a Permanently Immobilized Olefin- 

Metathesis Catalyst 

Stephan C. Schürer, Simon Gessler, Nicole Buschmann, Siegfried Blechert 

Speciation in Solution: Silicate Oligomers in Aqueous Solutions 

Detected by Mass Spectrometry 

Patrick Bussian, Frank Sobott, Bernhard Brutschy, Wolfgang Schrader, Ferdi 

Schüth 

Stepwise Assembled Photoactive Films Containing Donor-Linked 

Fullerenes 

Chuping Luo, Dirk M. Guldi, Michele Maggini, Enzo Menna, Simonetta 

Mondini, Nicholas A. Kotov, Maurizio Prato 

Breaking the Rule: Synthesis and Molecular Structure of Dinuclear 

Rhodium Complexes with Bridging and Semibridging 

Trialkylphosphane Ligands

3912- 

3915 

3915- 

3917 

3918- 

3920 

3921- 

3922 

3923- 

3925 

3925- 

3929 

3929- 

3933 

3933- 

3935 

Thomas Pechmann, Carsten D. Brandt, Helmut Werner 

Cisplatin Changes the Mechanics of Single DNA Molecules 

Rupert Krautbauer, Hauke Clausen-Schaumann, Hermann E. Gaub 

Spherical Aromaticity in Ih Symmetrical Fullerenes: The 2(N+1) 2 Rule 

Andreas Hirsch, Zhongfang Chen, Haijun Jiao 

Self-Repairing DNA Based on a Reductive Electron Transfer through 

the Base Stack 

Anja Schwögler, Lars T. Burgdorf, Thomas Carell 

Room Temperature Oxidation of Carbon Monoxide Catalyzed by 

Hydrous Ruthenium Dioxide 

Ling Zang, Horst Kisch 

+ 

The Cl4 Ion 

Stefan Seidel, Konrad Seppelt 

[{Ag(tBuNH2)2}4][{Ag(tBuNH2)(tBuN=CHCH3)}2][Ag12(CF3CO2)14]: A 

8+ 

Compound with an Ag12 Cluster Core 

Peter Reiß, Florian Weigend, Reinhart Ahlrichs, Dieter Fenske 

Synthesis, Crystal Structure, and Binding Properties of the Mixed 

Valence Clusters [Cu32As30(dppm)8] and [Cu26Te12(PEt2Ph)12] 

Reinhart Ahlrichs, Jörn Besinger, Andreas Eichhöfer, Dieter Fenske, Axel 

Gbureck 

A Blue Luminescent Starburst Molecule and Its Orange 

Luminescent Trinuclear Pd II Complex: 1,3,5-tris(7-azaindol-1yl)benzene 

(tabH) and [Pd II 

3(tab)2Cl4] 

Qingguo Wu, Andrea Hook, Suning Wang



Nguyet T. Tran, Douglas R. Powell, Lawrence F. Dahl 

3964- 

4002 

4004- 

4032 

4033- 

4036 

4036- 

4038 

4039- 

4040 

4041- 

4045 

4045- 

4047 

4048- 

4051 

4051- 

4053 

Review 

Fischer Carbene Complexes as Chemical Multitalents: The 

Incredible Range of Products from Carbenepentacarbonylmetal , - 

Unsaturated Complexes 

Armin de Meijere, Heiko Schirmer, Michael Duetsch 

Piezoelectric Mass-Sensing Devices as Biosensors - An Alternative 

to Optical Biosensors? 

Andreas Janshoff, Hans-Joachim Galla, Claudia Steinem 

Highlight 

New Developments in the Origins of the Homochirality of 

Biologically Relevant Molecules 

Helmut Buschmann, Richard Thede, Detlef Heller 

The Wanzlick Equilibrium 

Volker P. W. Böhm, Wolfgang A. Herrmann 


Comments on the Terminology for Applications of Temporarily 

Attached Solubility-Modifying Moieties in Combinatorial Chemistry 

Andreas Link 

Communication 

Inorganic Layered Double Hydroxides as Nonviral Vectors 

Jin-Ho Choy, Seo-Young Kwak, Yong-Joo Jeong, Jong-Sang Park 

Epoxidation Catalysis by a Manganese Corrole and Isolation of an 

Oxomanganese(v) Corrole 

Zeev Gross, Galina Golubkov, Liliya Simkhovich 

Structural, Electrochemical, and Photophysical Properties of 

Gallium(iii) 5,10,15-Tris(pentafluorophenyl)corrole 

Jesper Bendix, Ivan J. Dmochowski, Harry B. Gray, Atif Mahammed, Liliya 

Simkhovich, Zeev Gross 

Evidence for the Formation of a Ru III -Ru III Bond in a Ruthenium 

Corrole Homodimer 

François Jérôme, Béatrice Billier, Jean-Michel Barbe, Enrique Espinosa,

4053- 

4055 

4055- 

4058 

4058- 

4061 

4061- 

4063 

4063- 

4067 

4067- 

4070 

4070- 

4073 

4073- 

4075 

4076- 

4079 

4079- 

4082 

4082- 

4084 

Slimane Dahaoui, Claude Lecomte, Roger Guilard 

A Triangular Triplatinum Complex with Electron-Releasing SiPh2 

and PMe3 Ligands: [{Pt( -SiPh2)(PMe3)}3] 

Kohtaro Osakada, Makoto Tanabe, Tomoaki Tanase 

Synthesis of a Versatile Tridentate Anthracene Ligand and its 

Application for the Synthesis of Hypervalent Pentacoordinate 

Boron Compounds (10-B-5) 

Makoto Yamashita, Yohsuke Yamamoto, Kin-ya Akiba, Shigeru Nagase 

Diels-Alder Type Addition of 1,3-Dienes to a Disulfide Bridging 

Ligand in Diruthenium Complexes 

Hiroyasu Sugiyama, Yong-Shou Lin, Kazuko Matsumoto 

Regiospecific Hydride Transfer from cis-[Ru(bpy)2(CO)(CHO)] + to 

NAD + Model Compounds: A Model for Enzymatic Reactions by 

Aldehyde Dehydrogenases 

Hideo Konno, Kazuhiko Sakamoto, Osamu Ishitani 

A New Self-Assembling System for Targeted Gene Delivery 

Michael A. W. Eaton, Terence S. Baker, Catherine F. Catterall, Kenneth Crook, 

Graham S. Macaulay, Barbara Mason, Timothy J. Norman, David Parker, Justin 

J. B. Perry, Richard J. Taylor, Alison Turner, A. Neil Weir 

A Versatile Periodate-Coupled Fluorogenic Assay for Hydrolytic 

Enzymes 

Fabrizio Badalassi, Denis Wahler, Gérard Klein, Paolo Crotti, Jean-Louis 

Reymond 

Formation of a Giant Supramolecular Porphyrin Array by Self- 

Coordination 

Kazuya Ogawa, Yoshiaki Kobuke 

Enantioselective Total Synthesis of (+)-Gelsemine: Determination 

of Its Absolute Configuration 

Satoshi Yokoshima, Hidetoshi Tokuyama, Tohru Fukuyama 

(-)-Rhizochalin is a Dimeric Enantiomorphic (2R)-Sphingolipid: 

Absolute Configuration of Pseudo-C2v-Symmetric Bis-2-amino-3alkanols 

by CD 

Tadeusz F. Molinski, Tatyana N. Makarieva, Valentin A. Stonik 

Amphoteric Character of 2-Vinyloxiranes: Synthetic Equivalents of 

, -Unsaturated Aldehydes and a Vinylogous Enolate 

Mark Lautens, Stéphane G. Ouellet, Stéphane Raeppel 

Total Synthesis of (+)-Eurylene and (+)-14-Deacetyleurylene 

Yoshiki Morimoto, Koji Muragaki, Toshiyuki Iwai, Yukio Morishita, Takamasa 

Kinoshita

4084- 

4088 

4088- 

4090 

4090- 

4092 

4093- 

4095 

4096- 

4098 

4098- 

4101 

4101- 

4104 

4104- 

4106 

4106- 

4108 

4108- 

4110 

Cuprophilicity: Spectroscopic and Structural Evidence for Cu-Cu 

Bonding Interactions in Luminescent Dinuclear Copper(i) 

Complexes with Bridging Diphosphane Ligands 

Chi-Ming Che, Zhong Mao, Vincent M. Miskowski, Man-Chung Tse, Chi- 

Keung Chan, Kung-Kai Cheung, David Lee Phillips, King-Hung Leung 

Low-Temperature Activation of Dioxygen and Hydrocarbon 

Oxidation Catalyzed by a Phosphovanadomolybdate: Evidence for 

a Mars-van Krevelen Type Mechanism in a Homogeneous Liquid 

Phase 

Alexander M. Khenkin, Ronny Neumann 

Oxidosqualene Cyclase Residues that Promote Formation of 

Cycloartenol, Lanosterol, and Parkeol 

Michelle M. Meyer, Michael J. R. Segura, William K. Wilson, Seiichi P. T. 

Matsuda 

A New Efficient Synthesis of (R,R)-2,2 -Bipyrrolidine: An Interesting 

Chiral 1,2-Diamine with C2 Symmetry 

Alexandre Alexakis, Axel Tomassini, Cyril Chouillet, Sylvain Roland, Pierre 

Mangeney, Gerald Bernardinelli 

Isolation of a Pyridinium Alkoxy Ion Bridged Dimeric Zinc Complex 

for the Coupling Reactions of CO2 and Epoxides 

Hoon Sik Kim, Jai Jun Kim, Byung Gwon Lee, Ok Sang Jung, Ho Gyeom Jang, 

Sang Ook Kang 

Rational Construction of Chiral Octanuclear Metallacycles 

Consisting of Octahedral Co III , Square-Planar Pd II , and Linear Au I or 

Ag I Ions 

Takumi Konno, Yu Chikamoto, Ken-ichi Okamoto, Tadashi Yamaguchi, 

Tasuku Ito, Masakazu Hirotsu 

Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic 

Isotope Effect of 31.1 

My-Hang V. Huynh, Peter S. White, Thomas J. Meyer 

The First Highly Enantioselective Rh-Catalyzed Enyne 

Cycloisomerization 

Ping Cao, Xumu Zhang 

Rhodium-Mediated Asymmetric Hydroformylation with a Novel 

Bis(diazaphospholidine) Ligand 

Simon Breeden, David J. Cole-Hamilton, Douglas F. Foster, Gary J. Schwarz, 

Martin Wills 

arachno-[Sn8] 6- or closo-[Li2Sn8] 4- ? Synthesis and Characterization 

of A4Li2Sn8 (A=Rb, K) 

Svilen Bobev, Slavi C. Sevov

4111- 

4114 

4114- 

4116 

4117- 

4118 

4119- 

4121 

4121- 

4125 

4127- 

4130 

4130- 

4133 

4133- 

4136 

4136- 

4139 

4139- 

4142 

4142- 

4145 

4145- 

Reductive Samariation of Anomeric 2-Pyridyl Sulfones with 

Catalytic Nickel: An Unexpected Improvement in the Synthesis of 

1,2-trans-Diequatorial C-Glycosyl Compounds 

Nicolas Miquel, Gilles Doisneau, Jean-Marie Beau 

Formation of Optically Active Aromatic -Amino Acids by Catalytic 

Enantioselective Addition of Imines to Aromatic Compounds 

Steen Saaby, Xiangming Fang, Nicholas Gathergood, Karl Anker Jørgensen 

Hydrogen/Deuterium Exchange Catalyzed by an Unusually Stable 

Mercury-Toluene Complex 

Alexander S. Borovik, Simon G. Bott, Andrew R. Barron 

Stabilization of a Reactive Cationic Species by Supramolecular 

Encapsulation 

Marco Ziegler, Julia L. Brumaghim, Kenneth N. Raymond 

Nanosized Pd145(CO)x(PEt3)30 Containing a Capped Three-Shell 145- 

Atom Metal-Core Geometry of Pseudo Icosahedral Symmetry 

Nguyet T. Tran, Douglas R. Powell, Lawrence F. Dahl 

A Novel CSiP Ring from the Reaction of a Complexed 

Phosphinidene and a Silene 

Mark J. M. Vlaar, Andreas W. Ehlers, Frans J. J. de Kanter, Marius Schakel, 

Anthony L. Spek, Martin Lutz, Nadejda Sigal, Yitzhak Apeloig, Koop 

Lammertsma 

Virtual Screening for Bioactive Molecules by Evolutionary De Novo 

Design 

Gisbert Schneider, Odile Clément-Chomienne, Laurence Hilfiger, Petra 

Schneider, Stefan Kirsch, Hans-Joachim Böhm, Werner Neidhart 

Chirally Modified n-Butyllithium: Tuning the Composition, 

Structure, and Enantioselectivity with Modular Fencholates 

Bernd Goldfuss, Melanie Steigelmann, Frank Rominger 

C-H Activation by Direct Borane-Hydrocarbon Dehydrogenation: 

Kinetic and Thermodynamic Aspects 

Bernd Goldfuss, Paul Knochel, Lars O. Bromm, Kolja Knapp, 

Multilevel Molecular Electronic Species: Electrochemical Reduction 

of a [2×2] Co II 4 Grid-Type Complex by 11 Electrons in 10 Reversible 

Steps 

Mario Ruben, Esther Breuning, Jean-Paul Gisselbrecht, Jean-Marie Lehn 

Repetitive Application of Perfluoro-Tagged Pd Complexes for Stille 

Couplings in a Fluorous Biphasic System 

Siegfried Schneider, Willi Bannwarth 

A Li10 Cage Containing the [C6H11P -C(Ph) -N] 2- Ion: Umpolung in

4148 the Oligomerization of a Nitrile 

Neil Feeder, Yvonne G. Lawson, Paul R. Raithby, Jeremy M. Rawson, 

Alexander Steiner, Jody A. Wood, Anthony D. Woods, Dominic S. Wright 

4148- 

4150 

4150- 

4153 

4153- 

4155 

4156- 

4158 

4158- 

4160 

4160- 

4162 

4162- 

4163 

Stabilization of a Pentastibacyclopentadienyl Ligand in the Triple- 

Decker Sandwich Complexes [{( 5 5 

-1,2,4-tBu3C5H2)Mo}2( , -Sb5)] 

and [( 5 5 

-1,2,4-tBu3C5H2)Mo( , -Sb5)Mo( 5 -1,4-tBu2-2-MeC5H2)] 

Hans Joachim Breunig, Neil Burford, Roland Rösler 

Alla Zamyatina, Sabine Gronow, Clemens Oertelt, Michael Puchberger, Helmut 

Brade, Paul Kosma 

A New Highly Efficient Catalyst System for the Coupling of 

Nonactivated and Deactivated Aryl Chlorides with Arylboronic 

Acids 

Alexander Zapf, Andreas Ehrentraut, Matthias Beller 

A Palladium-Catalyzed Synthesis of Amidines from Aryl Halides 

C. Gustaf Saluste, Richard J. Whitby, Mark Furber 

Cobalt on Charcoal: A Convenient and Inexpensive Heterogeneous 

Pauson-Khand Catalyst 

Seung Uk Son, Sang Ick Lee, Young Keun Chung 

(CuI)2P8Se3: An Adduct of D3-Symmetrical P8Se3 Cage Molecules 

with Cu2I2 Rhomboids 

Arno Pfitzner, Sara Reiser, Tom Nilges 

The Structure of the Fe IV O4 

4- Ion 

Mark T. Weller, Andrew L. Hector



Alfred Wittinghofer, Herbert Waldmann 

4192- 

4214 

4216- 

4235 

4237- 

4239 

4240- 

4242 

4242- 

4244 

4245- 

4247 

4249- 

4254 

4254- 

4257 

4257- 

4260 

Review 

Ras - A Molecular Switch Involved in Tumor Formation 

Alfred Wittinghofer, Herbert Waldmann 

Nematic Liquid Crystals for Active Matrix Displays: Molecular 

Design and Synthesis 

Peer Kirsch, Matthias Bremer 

Highlight 

An Eldorado for Homogeneous Catalysis? 

Gerald Dyker 

Molecular Gold - Multinuclear Gold(i) Complexes 

Vivian W.-W. Yam, Eddie C.-C. Cheng 

Single Fullerene Molecules and the Wave-Particle Dualism 

K. O. Greulich 


Reexamination of the Evidence for Solvent-Induced Intramolecular 

Electrophilic Catalysis by a cis Vicinal Hydroxyl Group in 

Ribonucleoside Phosphorylation Reactions 

Paul M. Cullis, Martin J. P. Harger, Michael Lee 

Communication 

New Mesotextured Hybrid Materials Made from Assemblies of 

Dendrimers and Titanium(iv)-Oxo-Organo Clusters 

Galo J. de A. A. Soler-Illia, Laurence Rozes, Mary Kate Boggiano, Clément 

Sanchez, Cédric-Olivier Turrin, Anne-Marie Caminade, Jean-Pierre Majoral 

Functionalized Fullerene as an Artificial Vector for Transfection 

Eiichi Nakamura, Hiroyuki Isobe, Naoki Tomita, Masaya Sawamura, Shigeki 

Jinno, Hiroto Okayama 

Ternary Complexes Between DNA, Polyamine, and Cucurbituril: A 

Modular Approach to DNA-Binding Molecules 

Hiroyuki Isobe, Naoki Tomita, Jae Wook Lee, Hee-Joon Kim, Kimoon Kim,

4260- 

4262 

4262- 

4265 

4266- 

4268 

4268- 

4271 

4271- 

4273 

4274- 

4276 

4276- 

4279 

4279- 

4281 

4282- 

4284 

4284- 

4287 

4287- 

Eiichi Nakamura 

Complexation of Antimony(iii) by Trypanothione 

Siucheong Yan, Keyang Ding, Li Zhang, Hongzhe Sun 

Supramolecular Modification of the Periphery of Dendrimers 

Resulting in Rigidity and Functionality 

Maurice W. P. L. Baars, Annika J. Karlsson, Victor Sorokin, Bas F. W. de 

Waal, E. W. Meijer 

Charge-Transfer Diamondoid Lattices: An Unprecedentedly Huge 

and Highly Catenating Diamondoid Network Arising from a 

Tetraphenol as a Tetrahedral Node and Benzoquinone as a Linear 

Spacer 

D. Shekhar Reddy, Takehisa Dewa, Ken Endo, Yasuhiro Aoyama 

Catalyst Screening Using an Array of Thermistors 

Ashley R. Connolly, John D. Sutherland 

[Cu(2-pyrazinecarboxylato)2HgI2] HgI2: An Open 

Noninterpenetrating Cu II -Hg II Mixed-Metal Cuboidal Framework 

Encapsulating Nearly Linear HgI2 Guest Molecules 

Yu-Bin Dong, Mark D. Smith, Hans-Conrad zur Loye 

Synthesis and Structure of a Monomeric Aluminum(i) Compound 

[{HC(CMeNAr)2}Al] (Ar=2,6-iPr2C6H3): A Stable Aluminum Analogue 

of a Carbene 

Chunming Cui, Herbert W. Roesky, Hans-Georg Schmidt, Mathias Noltemeyer, 

Haijun Hao, Fanica Cimpoesu 

Alumoxane Hydride and Aluminum Chalcogenide Hydride 

Compounds with Pyrazolato Ligands 

Wenjun Zheng, Nadia C. Mösch-Zanetti, Herbert W. Roesky, Mathias 

Noltemeyer, Manuel Hewitt, Hans-Georg Schmidt, Thomas R. Schneider 

Stereochemical Assignment of the C21-C38 Portion of the 

Desertomycin/Oasomycin Class of Natural Products by Using 

Universal NMR Databases: Prediction 

Yoshihisa Kobayashi, Choon-Hong Tan, Yoshito Kish 

Stereochemical Assignment of the C21-C38 Portion of the 

Desertomycin/Oasomycin Class of Natural Products by Using 

Universal NMR Databases: Proof 

Choon-Hong Tan, Yoshihisa Kobayashi, Yoshito Kishi 

Tuning the Regiospecificity of Cleavage in Fe III Catecholate 

Complexes: Tridentate Facial versus Meridional Ligands 

Du-Hwan Jo, Lawrence Que, Jr. 

An Unusually Shallow Distance-Dependence for Triplet-Energy

4290 Transfer 

Anthony Harriman, Abderrahim Khatyr, Raymond Ziessel, Andrew C. 

Benniston 

4290- 

4292 

4292- 

4295 

4295- 

4299 

4299- 

4301 

4301- 

4305 

4306- 

4308 

4308- 

4310 

4310- 

4313 

4314- 

4316 

4316- 

4319 

4319- 

4321 

The Distinct Effect of the o-Carboranyl Fragment: Its Influence on 

the I-I Distance in R3PI2 Complexes 

Francesc Teixidor, Rosario Núñez, Clara Viñas, Reijo Sillanpää, Raikko 

Kivekäs 

Remote Enantioselection Transmitted by an Achiral Peptide 

Nucleic Acid Backbone 

Igor A. Kozlov, Leslie E. Orgel, Peter E. Nielsen 

ZnBr2-Catalyzed Insertions of Carbonyl Compounds into 

Silacyclopropanes: Regiochemical Reversal Dependent on Metal 

Salt 

Annaliese K. Franz, K. A. Woerpel 

A Linker Scaffold to Present Dimers of Pharmacophores Prepared 

by Solid-Phase Syntheses 

Mookda Pattarawarapan, Kevin Burgess 

First Generation Light-Harvesting Dendrimers with a [Ru(bpy)3] 2+ 

Core and Aryl Ether Ligands Functionalized with Coumarin 450 

Xiaoli Zhou, Daniel S. Tyson, Felix N. Castellano 

Highly Regio- and Enantioselective Reduction of 3,5- 

Dioxocarboxylates 

Michael Wolberg, Werner Hummel, Christian Wandrey, Michael Müller 

Revision of the Absolute Configuration of Salicylihalamide A 

through Asymmetric Total Synthesis 

Yusheng Wu, Lothar Esser, Jef K. De Brabander 

Clean and Efficient Catalytic Reduction of Perchlorate 

Mahdi M. Abu-Omar, Lee D. McPherson, Joachin Arias, Virginie M. Béreau 

The First Entry to Complex Bakkanes: A Highly Effective 

Retroaldol-Aldol-Based Approach to (-)-Bakkenolides III, B, C, and 

H 

Olivier Hamelin, Yanyun Wang, Jean-Pierre Deprés, Andrew E. Greene 

A Tandem Sulfur Transfer/Reduction/Michael Addition Mediated by 

Benzyltriethylammonium Tetrathiomolybdate 

Kandikere Ramaiah Prabhu, Pennadam S. Sivanand, Srinivasan Chandrasekaran 

Transition Metal Complexes as Photosensitizers for Near-Infrared 

Lanthanide Luminescence 

Stephen I. Klink, Henk Keizer, Frank C. J. M. van Veggel

4321- 

4323 

4324- 

4326 

4327- 

4329 

4331- 

4333 

4333- 

4336 

4337- 

4339 

4339- 

4341 

4341- 

4343 

4343- 

4346 

4346- 

4348 

4348- 

4352 

4352- 

4354 

A Novel Iron-Based Catalyst for the Biphasic Oxidation of Benzene 

to Phenol with Hydrogen Peroxide 

Daniele Bianchi, Rossella Bortolo, Roberto Tassinari, Marco Ricci, Rodolfo 

Vignola 

Cyclodextrin Bilayer Vesicles 

Bart Jan Ravoo, Raphael Darcy 

Selective Enhancement of the One-Electron Oxidation of Guanine 

by Base Pairing with Cytosine 

Kiyohiko Kawai, Yasuharu Wata, Nobuyuki Ichinose, Tetsuro Majima 

First Synthesis of the Dendralene Family of Fundamental 

Hydrocarbons 

Simon Fielder, Daryl D. Rowan, Michael S. Sherburn 

The Hexaazidogermanate(iv) Ion: Syntheses, Structures, and 

Reactions 

Alexander C. Filippou, Peter Portius, Dirk U. Neumann, Klaus-Dieter 

Wehrstedt 

Selective Trimerization of -Olefins with Triazacyclohexane 

Complexes of Chromium as Catalysts 

Randolf D. Köhn, Matthias Haufe, Gabriele Kociok-Köhn, Siegfried Grimm, 

Peter Wasserscheid, Wilhelm Keim 

Identification of a New Sex Pheromone from the Silk Dragline of the 

Tropical Wandering Spider Cupiennius salei 

Mirjam Papke, Stefan Schulz, Harald Tichy, Ewald Gingl, Rudolf Ehn 

Analysis of the Silkworm Moth Pheromone Binding Protein- 

Pheromone Complex by Electrospray-Ionization Mass 

Spectrometry 

Neil J. Oldham, Jürgen Krieger, Heinz Breer, Annette Fischedick, Michal 

Hoskovec, Ale Svato 

Chemo-, Regio-, and Stereoselective Cyclization of 1,3- 

Bis(trimethylsilyloxy)-1,3-butadienes with Functionalized Epoxides 

Peter Langer, Tobias Eckardt 

Eight-Membered Carbocycles from a Dötz-Like Reaction 

José Barluenga, Fernando Aznar, M. Angel Palomero 

Combinatorial Solid-Phase Synthesis of Multivalent Cyclic 

Neoglycopeptides 

Valentin Wittmann, Sonja Seeberger 

Wound-Activated Chemical Defense in Unicellular Planktonic Algae 

Georg Pohnert

4355- 

4356 

4357- 

4359 

4359- 

4362 

4362- 

4364 

4364- 

4366 

4367- 

4369 

4369- 

4373 

4373- 

4375 

4376- 

4379 

4379- 

4382 

Remote Stereocontrol in Organocopper Chemistry: Highly 

Enantioselective Synthesis of Vinylallenes by 1,5-Substitution of 

Enyne Acetates 

Norbert Krause, Martin Purpura 

A New Class of Easily Obtained Carbonate-Related 3-Ligands and 

a Protein-Sized Doughnut-Shaped Coordination Oligomer 

Iris M. Müller, Richard Robson 

Catalytic Enantioselective Fluorination of -Ketoesters 

Lukas Hintermann, Antonio Togni 

6- 4- 

Octahedral SeO6 and Square-Pyramidal SeO5 , Two New 

Oxoselenate Anions 

Helmut Haas, Martin Jansen 

Total Synthesis of (+)-Ratjadone 

Mathias Christmann, Ulhas Bhatt, Monika Quitschalle, Eckhard Claus, Markus 

Kalesse 

Combinatorial Testing of Supported Catalysts for the 

Heterogeneous Polymerization of Olefins 

Martin Stork, Andreas Herrmann, Tanja Nemnich, Markus Klapper, Klaus 

Müllen 

An Allosteric Ribozyme Regulated by Doxycyline 

Nicolas Piganeau, Andreas Jenne, Vincent Thuillier, Michael Famulok 

Homoleptic Phosphoraneiminato Complexes of Rare Earth 

Elements as Initiators for Ring-Opening Polymerization of Lactones 

Thorsten Gröb, Gert Seybert, Werner Massa, Frank Weller, Ravi Palaniswami, 

Andreas Greiner, Kurt Dehnicke 

Tailored Alkene Oligomerization with H-ZSM-57 Zeolite 

Johan A. Martens, Raman Ravishankar, Igor E. Mishin, Pierre A. Jacobs 

Tribochemical Activation of Iron Oxide for the Reduction of NO with 

CO: How Lattice Defects Can Influence the Catalytic Activity 

Thomas Rühle, Olaf Timpe, Norbert Pfänder, Robert Schlögl



Burckhard Seelig, Sonja Keiper, Friedrich Stuhlmann, Andres Jäschke 

4414- 

4435 

4436- 

4461 

4463- 

4468 

4469- 

4470 

4471- 

4475 

4475- 

4476 

4477- 

4480 

4481- 

4483 

Review 

New Applications of Polyfunctional Organometallic Compounds in 

Organic Synthesis 

Andreas Boudier, Lars O. Bromm, Matthias Lotz, Paul Knochel 

Electron Spin Polarization and Time-Resolved Electron 

Paramagnetic Resonance: Applications to the Paradigms of 

Molecular and Supramolecular Photochemistry 

Nicholas J. Turro, Mark H. Kleinman, Erdem Karatekin 

Essay 

How Capillary Electrophoresis Sequenced the Human Genome 

Norman J. Dovichi, Jianzhong Zhang 

Highlight 

The Pharmaceutical Potential of Manganese-Based Superoxide 

Dismutase Mimics 

Roland Krämer 


How Can Metallic Ferromagnetism Be Explained? Itinerant 

Ferromagnetism of the Transition Metals: Our Present 

Understanding 

Gernot Stollhoff 

Reply 

Gregory A. Landrum, Richard Dronskowski 

Communication 

Complete Structural Characterization by Ab Initio X-Ray Powder 

Diffraction of [{Re( -H)(CO)4}n] and [{Re( -H)(CO)4}6], Inorganic 

Analogues of Polyethylene and Cyclohexane 

Norberto Masciocchi, Giuseppe D'Alfonso, Luca Garavaglia, Angelo Sironi 

Annelated Heptathiophene: A Fragment of a Carbon-Sulfur Helix 

Andrzej Rajca, Hua Wang, Maren Pink, Suchada Rajca

4483- 

4485 

4485- 

4488 

4488- 

4491 

4492- 

4494 

4494- 

4496 

4496- 

4500 

4500- 

4502 

4502- 

4505 

4505- 

4508 

4509- 

4511 

4512- 

4513 

Towards the DRED of Resin-Supported Combinatorial Libraries: A 

Non-Invasive Methodology Based on Bead Self-Encoding and 

Multispectral Imaging 

Hicham Fenniri, Hartmut G. Hedderich, Kenneth S. Haber, Jihane Achkar, 

Brian Taylor, Dor Ben-Amotz 

Polymorphism in p-Hydroxybenzoic Acid: The Effect of 

Intermolecular Hydrogen Bonding in Controlling Proton Order 

versus Disorder in the Carboxylic Acid Dimer Motif 

Benson M. Kariuki, Clare L. Bauer, Kenneth D. M. Harris, Simon J. Teat 

Structure Determination of an Oligopeptide Directly from Powder 

Diffraction Data 

Emilio Tedesco, Giles W. Turner, Kenneth D. M. Harris, Roy L. Johnston, 

Benson M. Kariuki 

Aromatic Aminations by Heterogeneous Ni 0 /C Catalysis 

Bruce H. Lipshutz, Hiroshi Ueda 

Application of a Spin-Labeled Spin-Trap to the Detection of Nitric 

Oxide (NO) 

Lucien Marx, André Rassat 

Novel NO Biosensor Based on the Surface Derivatization of GaAs 

by Hinged Iron porphyrins 

Deng Guo Wu, Gonen Ashkenasy, Dmitry Shvarts, Rachel V. Ussyshkin, Ron 

Naaman, Abraham Shanzer, David Cahen 

Stereoselective Synthesis of Highly Functionalized C-Glycosides 

based on Acetal [1,2] and [1,4] Wittig Rearrangements 

Katsuhiko Tomooka, Hiroshi Yamamoto, Takeshi Nakai 

Stereoselective Total Synthesis of Zaragozic Acid A based on an 

Acetal [1,2] Wittig Rearrangement 

Katsuhiko Tomooka, Makoto Kikuchi, Kazunobu Igawa, Masaki Suzuki, Ping- 

Huai Keong, Takeshi Nakai 

Subtle Variations in the Long-Range Transmission of 

Stereochemical Information: Matched and Mismatched Aldol 

Reactions 

Zhicai Wu, Fei Zhang, Samuel J. Danishefsky 

The Synthesis of CP-263,114 and CP-225,917: Striking Long-Range 

Stereocontrol in the Fashioning of C7 

Qiang Tan, Samuel J. Danishefsky 

Synthesis and Reactions of Palladium and Platinum Complexes 

Bearing Diphosphinidenecyclobutene Ligands: A Thermally Stable 

Catalyst for Ethylene Polymerization 

Shintaro Ikeda, Fumie Ohhata, Masaki Miyoshi, Rika Tanaka, Tatsuya Minami,

4513- 

4515 

4516- 

4518 

4518- 

4521 

4521- 

4524 

4524- 

4528 

4528- 

4531 

4531- 

4533 

4533- 

4537 

4537- 

4539 

4539- 

4542 

4542- 

4544 

Fumiyuki Ozawa, Masaaki Yoshifuji 

Highly Selective Ring-Opening/Cross-Metathesis Reactions of 

Norbornene Derivatives Using Selenocarbene Complexes as 

Catalysts 

Hiroyuki Katayama, Hideto Urushima, Tsuneo Nishioka, Chikaya Wada, 

Masato Nagao, Fumiyuki Ozawa 

Crystal Structure of [(Ph(Me)C:N:C(H)Ph)K (tBuOK)2 (thf)2] : A 

Unimetallic Mixed Anion Model for a Superbase ? 

Philip C. Andrews, Gary D. Fallon, Melissa Maguire, Anna C. Peatt 

Catalytic Asymmetric Aziridination with Arylborate Catalysts 

Derived from VAPOL and VANOL Ligands 

Jon C. Antilla, William D. Wulff 

Stereoselective Synthesis of RP- and SP-Dithymidine 

Phosphorothioates via Chiral Indolooxazaphosphorine 

Intermediates Derived from Tryptophan 

Yixin Lu, George Just 

Early Transition Metal -Diazoalkane Complexes 

Victorio Cadierno, Maria Zablocka, Bruno Donnadieu, Alain Igau, Jean-Pierre 

Majoral 

Hybrid Coordination Polymers - Metal Oxide Compounds with 

Chiral Structures 

Li-Min Zheng, Tabatha Whitfield, Xiqu Wang, Allan J. Jacobson 

[HC{(CMe)(NAr)}2]Al[(NSiMe3)2N2] (Ar=2,6-iPr2C6H3): The First Five- 

Membered AlN4 Ring System 

Chunming Cui, Herbert W. Roesky, Hans-Georg Schmidt, Mathias Noltemeyer 

Synthesis of Stable Organo(bis-silanetriols): X-Ray Powder 

Structure of 1,4-Bis(trihydroxysilyl)benzene 

Geneviève Cerveau, Robert J. P. Corriu, Bertrand Dabiens, Jean Le Bideau 

The Essential Role of a Zn II Ion in the Disproportionation of 

Semiquinone Radical Anion by an Imidazolate-Bridged Cu II -Zn II 

Model of Superoxide Dismutase 

Hideki Ohtsu, Shunichi Fukuzumi 

New Family of Cyclopropanating Reagents: Synthesis, Reactivity, 

and Stability Studies of Iodomethylzinc Phenoxides 

André B. Charette, Sébastien Francoeur, Jonathan Martel, Nicole Wilb 

A Near-Infrared Luminescent Label Based on Yb III Ions and Its 

Application in a Fluoroimmunoassay 

Martinus H. V. Werts, Richard H. Woudenberg, Peter G. Emmerink, Rob van 

Gassel, Johannes W. Hofstraat, Jan W. Verhoeven

4545- 

4547 

4547- 

4551 

4552- 

4555 

4555- 

4557 

4558- 

4562 

4562- 

4564 

4565- 

4567 

4567- 

4570 

4570- 

4571 

4573- 

4576 

4576- 

4579 

Removal of Benzyl Protecting Groups from Solid-Supported 

Compounds by Hydrogenolysis Using Palladium Nanoparticles 

Osamu Kanie, Gijsbert Grotenbreg, Chi-Huey Wong 

Tuning the Semiconducting Properties of Sexithiophene by , - 

Substitution - , -Diperfluorohexylsexithiophene: The First n-Type 

Sexithiophene for Thin-Film Transistors 

Antonio Facchetti, Yvonne Deng, Anchuan Wang, Yoshihiro Koide, Henning 

Sirringhaus, Tobin J. Marks, Richard H. Friend 

Crystallization of a Large-Pore Three-Dimensional Gallium 

Fluorophosphate under Mild Conditions 

Richard I. Walton, Franck Millange, Thierry Loiseau, Dermot O'Hare, Gérard 

Férey 

A One-Dimensional Metallocyclophane with Columnar Aromatic 

2 

Stacking: The Silver(i) -Coordination Complex of 1,2- 

Benztriphenylene 

Megumu Munakata, Gui Ling Ning, Yusaku Suenaga, Takayoshi Kuroda- 

Sowa, Masahiko Maekawa, Tetsuhiro Ohta 

Supramolecular Assembly of Hexagonal Mesostructured 

Germanium Sulfide and Selenide Nanocomposites Incorporating 

the Biologically Relevant Fe4S4 Cluster 

Pantelis N. Trikalitis, Thomas Bakas, Vasilios Papaefthymiou, Mercouri G. 

Kanatzidis 

Benzene-Centered Tri- and Tetrametallacarborane Sandwich 

Complexes 

Martin Bluhm, Hans Pritzkow, Walter Siebert, Russell N. Grimes 

Ground-State Reversal by Matrix Interaction: Electronic States and 

Vibrational Frequencies of CUO in Solid Argon and Neon 

Lester Andrews, Binyong Liang, Jun Li, Bruce E. Bursten 

Visualization of Single Multivalent Receptor-Ligand Complexes by 

Transmission Electron Microscopy 

Jason E. Gestwicki, Laura E. Strong, Laura L. Kiessling 

A Remarkable, Stable Radical-Molecule Complex: HO2 CF3C(O)OH 

Joseph S. Francisco 

Stochastic Resonance in a Bistable Chemical System: The 

Oxidation of Ascorbic Acid by Oxygen Catalyzed by Copper(ii) Ions 

Peter E. Strizhak, Igor Demjanchyk, Frank Fecher, Friedemann W. Schneider, 

Arno F. Münster 

Enantioselective Ribozyme Catalysis of a Bimolecular 

Cycloaddition Reaction

4580- 

4582 

4582- 

4586 

4586- 

4588 

4588- 

4591 

4591- 

4593 

4593- 

4596 

4596- 

4599 

4599- 

4602 

4602- 

4604 

4605- 

4607 

4607- 

4609 

4610- 

4612 

Burckhard Seelig, Sonja Keiper, Friedrich Stuhlmann, Andres Jäschke 

.- 

(Ph4P)S6 - A Compound Containing the Cyclic Radical Anion S6 

Bernhard Neumüller, Fritjof Schmock, Reinhard Kirmse, Andreas Voigt, Axel 

Diefenbach, F. Matthias Bickelhaupt, Kurt Dehnicke 

Conical Intersections in Charge-Transfer Induced Quenching 

Adalgisa Sinicropi, Uwe Pischel, Riccardo Basosi, Werner M. Nau, Massimo 

Olivucci 

From a Racemate to a Pure Enantiomer by Laser Pulses: Quantum 

Model Simulations for H2POSH 

Yuichi Fujimura, Leticia González, Kunihito Hoki, Dominik Kröner, Jörn 

Manz, Yukiyoshi Ohtsuki 

Bis(pentafluorophenyl)xenon, Xe(C6F5)2: A Homoleptic 

Diorganoxenon Derivative 

Nicola Maggiarosa, Dieter Naumann, Wieland Tyrra 

C6F5XeF, A Key Substrate in Xenon-Carbon Chemistry: Synthesis of 

Symmetric and Asymmetric Pentafluorophenylxenon(ii) Derivatives 

Hermann-Josef Frohn, Michael Theißen 

An Enantiospecific Synthesis of the Potent Immunosuppressant 

FR901483 

Goetz Scheffler, Hirofumi Seike, Erik J. Sorensen 

Total Synthesis of (-)-Spirotryprostatin B and Three Stereoisomers 

Larry E. Overman, Mark D. Rosen 

Reconstitution of Channel Proteins in (Polymerized) ABA Triblock 

Copolymer Membranes 

Wolfgang Meier, Corinne Nardin, Mathias Winterhalter 

Direct Observation of the Lower Critical Solution Temperature of 

Surface-Attached Thermo-Responsive Hydrogels by Surface 

Plasmon Resonance 

Erik Wischerhoff, Thomas Zacher, André Laschewsky, El Djouhar Rekaï 

Asymmetric Synthesis of -Substituted -Nitrophosphonic Acids 

by Phospha-Analogous Michael Addition to Aromatic Nitroalkenes 

Dieter Enders, Livio Tedeschi, Jan Willem Bats 

Breakdown of Bond Length-Bond Strength Correlation: A Case 

Study 

Martin Kaupp, Bernhard Metz, Hermann Stoll L 

Transition Metal Catalyzed Preparation of Grignard Compounds 

Borislav Bogdanovi , Manfred Schwickardi

4612- 

4615 

4615- 

4617 

Total Synthesis of Lankacyclinol 

David R. Williams, Guillermo S. Cortez, Stéphane L. Bogen, Christian M. 

Rojas 

Phenylaziridine as a Masked 1,3 Dipole in Reactions with 

Nonactivated Alkenes 

Ioana Ungureanu, Philippe Klotz, André Mann

ANGEWANDTE 

CHEMIE 

2001

Volume 40, Issue 1, 2001 


Dieter Seebach, Albert K. Beck, Alexander Heckel 

40- 

73 

74- 

91 

92- 

138 

139- 

143 

145- 

147 

147- 

149 

151- 

154 

154- 

157 

157- 

160 

Review 

Asymmetric Catalysis by Architectural and Functional Molecular 

Engineering: Practical Chemo- and Stereoselective Hydrogenation of 

Ketones 

Ryoji Noyori, Takeshi Ohkuma 

Dendritic Encapsulation of Function: Applying Nature's Site Isolation 

Principle from Biomimetics to Materials Science 

Stefan Hecht, Jean M. J. Fréchet 

TADDOLs, Their Derivatives, and TADDOL Analogues: Versatile 

Chiral Auxiliaries 

Dieter Seebach, Albert K. Beck, Alexander Heckel 

Essay 

Angewandte Chemie in Light of the Science Citation Index 

Werner Marx 

Highlight 

Metal-Assisted Cleavage of a C-C Double Bond: Simple and 

Reversible 

Helmut Werner, Elke Bleuel 

NMR Quantum Computing 

Steffen J. Glaser 

Communication 

Synthesis, Structure, and Preliminary Magnetic Studies of a Ni24 

Wheel 

Angela L. Dearden, Simon Parsons, Richard E. P. Winpenny 

Off-the-Shelf Colorimetric Anion Sensors 

Hidekazu Miyaji, Jonathan L. Sessler 

Resolution and Kinetic Stability of a Chiral Supramolecular 

Assembly Made of Labile Components 

Andreas J. Terpin, Marco Ziegler, Darren W. Johnson, Kenneth N. Raymond 

160- Catalytic Asymmetric Friedel-Crafts Alkylation of , -Unsaturated -

163 Ketoesters: Enantioselective Addition of Aromatic C-H Bonds to 

Alkenes 

Kim B. Jensen, Jacob Thorhauge, Rita G. Hazell, Karl Anker Jørgensen 

165- 

169 

169- 

171 

172- 

174 

174- 

177 

177- 

179 

180- 

183 

183- 

186 

186- 

188 

189- 

190 

191- 

195 

Nonpeptidic v 3 Integrin Antagonist Libraries: On-Bead Screening 

and Mass Spectrometric Identification without Tagging 

Christoph Gibson, Gábor A. G. Sulyok, Diane Hahn, Simon L. Goodman, Günter 

Hölzemann, Horst Kessler 

The First Synthetic Application of a Monooxygenase Employing 

Indirect Electrochemical NADH Regeneration 

Frank Hollmann, Andreas Schmid, Eberhard Steckhan 

Patterning Solid-Supported Lipid Bilayer Membranes by 

Lithographic Polymerization of a Diacetylene Lipid 

Kenichi Morigaki, Tobias Baumgart, Andreas Offenhäusser, Wolfgang Knoll 

Synthesis of 1,4-Diazidobuta-1,3-dienes by Electrocyclic Ring 

Opening: Precursors for Bi-2H-azirin-2-yls and Their Valence 

Isomerization to Diazabenzenes 

Klaus Banert, Frank Köhler 

Highly Enantioselective Isomerization of 4,7-Dihydro-1,3-dioxepins 

Catalyzed by Me-DuPHOS-Modified Dihalogenonickel Complexes 

and Determination of the Absolute Configuration of the 

Isomerization Products 

Herbert Frauenrath, Dirk Brethauer, Stefan Reim, Martin Maurer, Gerhard Raabe 

Tetracyclopropylmethane: A Unique Hydrocarbon with S4 Symmetry 

Sergei I. Kozhushkov, Rafael R. Kostikov, Alexander P. Molchanov, Roland 

Boese, Jordi Benet-Buchholz, Peter R. Schreiner, Christopher Rinderspacher, Ion 

Ghiviriga, Armin de Meijere 

Cyclopentadienyl-Free Calcium Alkyls with Heteroelement- 

Substituted Anionic Phosphane Ligands: Synthesis and Structure of 

a Trialkyl Calcate(ii) and of an Organocalcium Heterocubane 

Volker Knapp, Gerhard Müller 

The Unusual Photochemistry of Dendrimers with an Anthracene 

Core 

Derong Cao, Herbert Meier 

A Silyl Substituent Can Dictate a Concerted Electrocyclic Pathway: 

Inward Torquoselectivity in the Ring Opening of 3-Silyl-1cyclobutene 

Masahiro Murakami, Yasufumi Miyamoto, Yoshihiko Ito 

The Spongistatins: Architecturally Complex Natural Products - Part 

One: A Formal Synthesis of (+)-Spongistatin 1 by Construction of an 

Advanced ABCD Fragment

196- 

199 

199- 

202 

202- 

206 

207- 

210 

210- 

213 

213- 

216 

216- 

219 

220- 

222 

222- 

224 

224- 

227 

Amos B. Smith III, Victoria A. Doughty, Qiyan Lin, Linghang Zhuang, Mark D. 

McBriar, Armen M. Boldi, William H. Moser, Noriaki Murase, Kiyoshi 

Nakayama, Masao Sobukawa 

The Spongistatins: Architecturally Complex Natural Products - Part 

Two: Synthesis of the C(29-51) Subunit, Fragment Assembly, and 

Final Elaboration to (+)-Spongistatin 2 

Amos B. Smith III, Qiyan Lin, Victoria A. Doughty, Linghang Zhuang, Mark D. 

McBriar, Jeffrey K. Kerns, Christopher S. Brook, Noriaki Murase, Kiyoshi 

Nakayama 

A Chemical Model of Homeostasis 

Helmut H. Zepik, Eveline Blöchliger, Pier Luigi Luisi 

Mechanistic Studies of Periodinane-Mediated Reactions of Anilides 

and Related Systems 

K. C. Nicolaou, Phil S. Baran, Remo Kranich, Yong-Li Zhong, Kazuyuki Sugita, 

Ning Zou 

New Synthetic Technology for the Construction of N-Containing 

Quinones and Derivatives Thereof: Total Synthesis of 

Epoxyquinomycin B 

K. C. Nicolaou, Kazuyuki Sugita, Phil S. Baran, Yong-Li Zhong 

Structure and Base Catalysis of Supercritical Water in the 

Noncatalytic Benzaldehyde Disproportionation Using Water at High 

Temperatures and Pressures 

Yutaka Ikushima, Kiyotaka Hatakeda, Osamu Sato, Toshirou Yokoyama, 

Masahiko Arai 

Isolation of Dinuclear ( -Silylene)(silyl)nickel Complexes and Si-Si 

Bond Formation on a Dinuclear Nickel Framework 

Shigeru Shimada, Maddali L. N. Rao, Teruyuki Hayashi, Masato Tanaka 

A Mass Spectrometric Labeling Strategy for High-Throughput 

Reaction Evaluation and Optimization: Exploring C-H Activation 

Jason W. Szewczyk, Rebecca L. Zuckerman, Robert G. Bergman, Jonathan A. 

Ellman 

Reversible S-S Bond Breaking and Bond Formation in Disulfide- 

Containing Dinuclear Complexes of Mn I 

Javier Ruiz, Mario Ceroni, Oscar V. Quinzani, Víctor Riera, Oscar E. Piro 

Efficient Catalytic Alkane Nitration with NO2 under Air Assisted by N- 

Hydroxyphthalimide 

Satoshi Sakaguchi, Yoshiki Nishiwaki, Takaaki Kitamura, Yasutaka Ishii 

Immobilization of Redox-Active Ligands on an Electrode: The 

Dendrimer Route 

Franck Le Derf, Eric Levillain, Gaëlle Trippé, Alain Gorgues, Marc Sallé, Rosa-

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María Sebastían, Anne-Marie Caminade, Jean-Pierre Majoral 

A Rare Phosphane Coordination Mode: A Symmetrically 2-Bridging 

Phosphole in a Dinuclear Palladium(i) Complex 

Mathieu Sauthier, Boris Le Guennic, Valérie Deborde, Loïc Toupet, Jean- 

François Halet, Régis Réau 

Asymmetric Total Synthesis of Rhizoxin D 

Gary E. Keck, Carrie A. Wager, Travis T. Wager, Kenneth A. Savin, Jonathan A. 

Covel, Mark D. McLaws, Dhileep Krishnamurthy, Victor J. Cee 

Kinetic Resolution of Amines by a Nonenzymatic Acylation Catalyst 

Shigeru Arai, Stéphane Bellemin-Laponnaz, Gregory C. Fu 

High-Nuclearity Chromium-Nickel-Cyanide Clusters: An Open 

Cr8Ni5(CN)24 Cage and a C3-Symmetric Cr10Ni9(CN)42 Cluster 

Incorporating Three Forms of Cyanonickelate 

Jennifer J. Sokol, Matthew P. Shores, Jeffrey R. Long 

Chelate Formation around a Hexarhenium Cluster Core by the 

Diphosphane Ligand Ph2P(CH2)6PPh2 

Zhong-Ning Chen, Takashi Yoshimura, Masaaki Abe, Yoichi Sasaki, Shoji 

Ishizaka, Haeng-Boo Kim, Noboru Kitamura 

Coordinatively Unsaturated Metal Centers as Building Blocks for 

High Coordination Number Metallomesogens 

Koen Binnemans, Katleen Lodewyckx 

Singly and Doubly Oxidized Phthalocyanine (pc) Rings: 

[Cu(pc)(ReO4)] and [Cu(pc)(ReO4)2] 

Anna S. Gardberg, Peter E. Doan, Brian M. Hoffman, James A. Ibers 

Highly Active Metathesis Catalysts Generated In Situ from 

Inexpensive and Air-Stable Precursors 

Janis Louie, Robert H. Grubbs 

Highly Enantioselective Palladium-Catalyzed Ene-Type Cyclization of 

a 1,6-Enyne 

Manabu Hatano, Masahiro Terada, Koichi Mikami

Volume 40, Issue 2, 2001 


Chun-Ru Wang, Tsutomu Kai, Testuo Tomiyama, Takuya Yoshida, Yuji 

Kobayashi, Eiji Nishibori, Masaki Takata, Makoto Sakata, Hisanori Shinohara 

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Review 

Combinatorial and Evolution-Based Methods in the Creation of 

Enantioselective Catalysts 

Manfred T. Reetz 

Combinatorial Heterogeneous Catalysis - A New Path in an Old Field 

Selim Senkan 

Essay 

Wilhelm Schlenk: The Man Behind the Flask 

Thomas T. Tidwell 

Highlight 

Diversity-Based Organic Synthesis in the Era of Genomics and 

Proteomics 

Prabhat Arya, Doug T. H. Chou, Myung-Gi Baek 

Chemically Modified Amino Acids in Copper Proteins That Bind or 

Activate Dioxygen 

Malcolm A. Halcrow 

Communication 

The Key to Solving the Protein-Folding Problem Lies in an Accurate 

Description of the Denatured State 

Wilfred F. van Gunsteren, Roland Bürgi, Christine Peter, Xavier Daura 

Electronic Insight into an Antithrombotic Agent by High-Resolution 

X-Ray Crystallography 

Ralf Flaig, Tibor Koritsánszky, Rainer Soyka, Ludger Häming, Peter Luger 

Polyol-Mediated Preparation of Nanoscale Oxide Particles 

Claus Feldmann, Hans-Otto Jungk 

Counter-Rotating Ring Currents in Coronene and Corannulene 

Erich Steiner, Patrick W. Fowler, Leonardus W. Jenneskens 

Towards the Development of Antitumor Vaccines: A Synthetic 

Conjugate of a Tumor-Associated MUC1 Glycopeptide Antigen and a

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Tetanus Toxin Epitope 

Stefanie Keil, Christine Claus, Wolfgang Dippold, Horst Kunz 

Synthesis and Membrane-Binding Properties of a Characteristic 

Lipopeptide from the Membrane-Anchoring Domain of Influenza 

Virus A Hemagglutinin 

Frank Eisele, Jürgen Kuhlmann, Herbert Waldmann 

First Use of a Mineral Liquid Crystal for Measurement of Residual 

Dipolar Couplings of a Nonlabeled Biomolecule 

Hervé Desvaux, Jean-Christophe P. Gabriel, Patrick Berthault, Franck Camerel 

Novel Approach to Mixed Group 15/16 Element Ligands - Formation 

of Unusual Trichalcogenophosphonato Ligands in Mixed Fe/Cr 

Clusters 

Manfred Scheer, Shubhangi B. Umbarkar, Saurav Chatterjee, Rajiv Trivedi, 

Pradeep Mathur 

About the Chemistry of Phosphorus Suboxides 

Bernd Engels, Anna R. Soares Valentim, Sigrid D. Peyerimhoff 

Alkylating Polymers: Resin-Released Carbenium Ions as Versatile 

Reactive Intermediates in Polymer-Assisted Solution-Phase 

Synthesis 

Jörg Rademann, Joachim Smerdka, Günther Jung, Philipp Grosche, Dietmar 

Schmid 

Molecular Switching in the Near Infrared (NIR) with a Functionalized 

Boron-Dipyrromethene Dye 

Knut Rurack, Matthias Kollmannsberger, Jörg Daub 

An Efficient Cobalt(i) Catalyst System for the Selective 1,4- 

Hydrovinylation of 1,3-Dienes 

Gerhard Hilt, François-Xavier du Mesnil, Steffen Lüers 

Subnanomolar Inhibitors from Computer Screening: A Model Study 

Using Human Carbonic Anhydrase II 

Sven Grüneberg, Bernd Wendt, Gerhard Klebe 

Thioformaldehyde S-sulfide (Thiosulfine) 

Grzegorz Mlosto , Jaroslaw Roma ski, Hans Peter Reisenauer, Günther Maier 

A Scandium Carbide Endohedral Metallofullerene: (Sc2C2)@C84 

Chun-Ru Wang, Tsutomu Kai, Testuo Tomiyama, Takuya Yoshida, Yuji 

Kobayashi, Eiji Nishibori, Masaki Takata, Makoto Sakata, Hisanori Shinohara 

A Two-Dimensional Polyrotaxane with Large Cavities and Channels: 

A Novel Approach to Metal-Organic Open-Frameworks by Using 

Supramolecular Building Blocks 

Eunsung Lee, Jaheon Kim, Jungseok Heo, Dongmok Whang, Kimoon Kim

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Design of a Molecular Beacon DNA Probe with Two Fluorophores 

Peng Zhang, Terry Beck, Weihong Tan 

An Exceptionally Stable Ti Superoxide Radical Ion: A Novel 

Heterogeneous Catalyst for the Direct Conversion of Aromatic 

Primary Amines to Nitro Compounds 

Gajanan K. Dewkar, Milind D. Nikalje, Iliyas Sayyed Ali, Abhimanyu S. 

Paraskar, H. S. Jagtap, A. Sudalai 

Parallel Synthesis of ZSM-5 Zeolite Films from Clear Organic-Free 

Solutions 

Re Lai, Beom Seok Kang, George R. Gavalas 

Bowl-Shaped Tris(2,6-diphenylbenzyl)tin Hydride: A Unique 

Reducing Agent for Radical and Ionic Chemistry 

Kouji Sasaki, Yuichiro Kondo, Keiji Maruoka 

Chemoselective Iterative Dehydrative Glycosylation 

Hien M. Nguyen, Jennifer L. Poole, David Y. Gin 

-Mannosynthase: Synthesis of -Mannosides with a Mutant - 

Mannosidase 

Oyekanmi Nashiru, David L. Zechel, Dominik Stoll, Taraneh Mohammadzadeh, 

R. Antony J. Warren, Stephen G. Withers 

6-Aminofulvene-1-aldimine: A Model Molecule for the Study of 

Intramolecular Hydrogen Bonds 

Rosa María Claramunt, Dionísia Sanz, Sergio Hugo Alarcón, Marta Pérez 

Torralba, José Elguero, Concepción Foces-Foces, Mariusz Pietrzak, Uwe Langer, 

Hans-Heinrich Limbach 

Identification and Isolation of a Receptor for N-Methyl 

Alkylammonium Salts: Molecular Amplification in a Pseudo-peptide 

Dynamic Combinatorial Library 

Graham R. L. Cousins, Ricardo L. E. Furlan, Yiu-Fai Ng, James E. Redman, 

Jeremy K. M. Sanders 

Synthesis of a Conjugated Macromolecular Initiator for Nitroxide- 

Mediated Free Radical Polymerization 

Ulf Stalmach, Bert de Boer, Alice D. Post, Paul F. van Hutten, Georges 

Hadziioannou 

X-Ray Photoelectron Spectroscopy of Porphycenes: Charge 

Asymmetry Across Low-Barrier Hydrogen Bonds 

Abhik Ghosh, John Moulder, Martin Bröring, Emanuel Vogel 

Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two- 

Dimensional Topological Architecture and Unusual Magnetic 

Behavior

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Bao-Qing Ma, Song Gao, Gang Su, Guang-Xian Xu 

Immobilization of Homogeneous Palladium(ii) Complex Catalysts on 

Novel Polysiloxanes with Controllable Solubility: Important 

Implications for the Study of Heterogeneous Catalysis on Silica 

Surfaces 

Yaw-Shyan Fu, Shuchun J. Yu 

Catalytic Enantioselective Protonation of Lithium Ester Enolates 

Generated by Conjugate Addition of Arylthiolate to Enoates 

Katsumi Nishimura, Masashi Ono, Yasuo Nagaoka, Kiyoshi Tomioka 

Synthesis of Nanophase Iron Oxide in Lumazine Synthase Capsids 

Wayne Shenton, Stephen Mann, Helmut Cölfen, Adelbert Bacher, Markus 

Fischer 

-Cyclodextrin-Assisted Intervalence Charge Transfer in Mixed- 

Valent [2]Rotaxane Complexes Having Metal Centers Linked by an 

Interrupted -Electron System 

Atindra D. Shukla, H. C. Bajaj, Amitava Das 

Synthesis and Self-Assembly of Monodisperse Indium Nanoparticles 

Prepared from the Organometallic Precursor [In( 5 -C5H5)] 

Katerina Soulantica, André Maisonnat, Marie-Claire Fromen, Marie-José 

Casanove, Pierre Lecante, Bruno Chaudret 

Induction of a Preferred Twist in a Biphenyl Core by Stereogenic 

Centers: A Novel Approach to the Absolute Configuration of 1,2- and 

1,3-Diols 

Stefano Superchi, Daniele Casarini, Alessandro Laurita, Alfonso Bavoso, Carlo 

Rosini 

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Fullerene Anions: Unusual Charge Distribution in C70 

Tamar Sternfeld, Roy E. Hoffman, Ivan Aprahamian, Mordecai Rabinovitz 

An Artificial Ion Channel Formed by a Macrocyclic Resorcin[4]arene 

with Amphiphilic Cholic Acid Ether Groups 

Naomi Yoshino, Akiharu Satake, Yoshiaki Kobuke

ANGEWANDTE CHEMIE 2000

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