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2830 Contents / Carbohydrate Research 346 (2011) 2825–2830<br />
Investigation of a sulfate transfer during autohydrolysis of a fucoidan from the brown alga Fucus evanescens<br />
by tandem ESIMS<br />
Stanislav D. Anastyuk*, Natalia M. Shevchenko, Pavel S. Dmitrenok, Tatyana N. Zvyagintseva<br />
1<br />
H3C O<br />
4<br />
OR<br />
RO<br />
O<br />
Autohydrolysis<br />
- R=SO3 ,Ac<br />
H<br />
1<br />
3C O<br />
OR<br />
ESIMS analysis<br />
O 3<br />
OR<br />
H<br />
1<br />
3C O<br />
4<br />
OR<br />
RO<br />
O<br />
Autohydrolysis<br />
+D-Rib, D-Glc<br />
1<br />
H3C O<br />
ESIMS analysis<br />
OR<br />
O 3<br />
OR<br />
-<br />
[Fuc(SO3Na)-Na] 2-<br />
[Fuc2(SO3Na)2-2Na] 2-<br />
[FucGal(SO3Na)2-2Na] [Fuc4(SO3Na)3-3Na]<br />
4-<br />
[Fuc4(SO3Na)4-4Na] 3-<br />
[Fuc6(SO3Na)4-4Na] 4-<br />
[Fuc3(SO3Na)3-2Na] 2-<br />
[Fuc6(SO3Na)3-3Na] 3-<br />
[Fuc4(SO3Na)2-2Na] 2-<br />
-<br />
[Fuc2(SO3Na)-Na] [RibSO3Na-Na] -<br />
[GlcSO 3Na-Na] -<br />
pp 2975–2977<br />
Chemical structure of the O-polysaccharide isolated from Pectobacterium atrosepticum SCRI 1039 pp 2978–2981<br />
Małgorzata Czerwicka, Kinga Marszewska, Anna Bychowska, Halina Dziadziuszko, Krzysztof Brzozowski, Ewa Łojkowska,<br />
Piotr Stepnowski, Zbigniew Kaczyński*<br />
*Corresponding author<br />
Supplementary data available via ScienceDirect<br />
COVER<br />
Three dimensional structure of the molecular complex formed upon interaction of hevein, a plant lectin isolated from Hevea Brasiliensis tree,<br />
with the Manbeta1-4GlcNAcbeta14GlcNAcbetaAsn fragment of mammalian glycoproteins. The structure has been deduced by combination of<br />
NMR methods and molecular modelling protocols. The molecular recognition mode involves the typical interactions present in the recognition<br />
of neutral sugars by lectins, mainly CH-pi stacking interactions, hydrogen bonds and van der Waals forces. The figure has been designed by Dr.<br />
Ana Ardá and represents the first part of an ongoing collaboration with Prof. Carlo Unverzagt, at the University of Bayreuth, performed with the<br />
support of EUROCarbDB: http://www.eurocarbdb.org) and EU-NMR (http://www.eu-nmr.eu), and was presented at Tokyo during the XXV<br />
International Carbohydrate Symposium on the occasion of the Whistler Award to Jesús Jiménez-Barbero.<br />
Available online at www.sciencedirect.com<br />
Abstracted/Indexed in: Chem. Abstr.: Curr. Contents: Phys., Chem. & Earth Sci. Life Sci. Current Awareness in Bio. Sci. (CABS).<br />
Science Citation Index. Full texts are incorporated in CJELSEVIER, a file in the Chemical Journals Online database which<br />
is availabe on STN â International. Also covered in the abstract and citation database SciVerse Scopus â . Full text available on<br />
SciVerse ScienceDirect â<br />
ISSN 0008-6215
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