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A study of monoelectronic reduction of Artemisinin pp 1296–1299<br />

Maria Luisa Navacchia, Massimo L. Capobianco, Mila D’Angelantonio, Giancarlo Marconi*<br />

O O<br />

O<br />

H<br />

O<br />

O<br />

ART<br />

H<br />

e<br />

H2O/EtOH<br />

- solv<br />

O<br />

O<br />

OH<br />

O ACID<br />

A novel reaction mechanism for the formation of deoxyanthocyanidins pp 1300–1303<br />

André Sousa, Nuno Mateus, Victor de Freitas*<br />

Cinnamic aldehydes:<br />

R= H. coniferaldehyde<br />

R= OCH3. sinapaldehyde<br />

HO<br />

H3CO<br />

R<br />

3'<br />

2'<br />

4'<br />

OH<br />

HO<br />

7<br />

8<br />

A<br />

8a<br />

O<br />

C<br />

1'<br />

2<br />

B<br />

6'<br />

5'<br />

OCH3 6<br />

5<br />

4a<br />

4<br />

3<br />

H<br />

OH H<br />

Deoxyanthocyanidins:<br />

R= H. 3-deoxypeonidin<br />

R= OCH3. 3-deoxymalvidin<br />

*Corresponding author<br />

Supplementary data available via SciVerse ScienceDirect<br />

Contents / Tetrahedron Letters 53 (2012) 1193–1199 1199<br />

R<br />

O<br />

CH CH C<br />

H<br />

(Intermediary compounds)<br />

0.04<br />

0.03<br />

A<br />

0.02<br />

0.01<br />

+H +<br />

HO<br />

487nm<br />

H3CO<br />

0<br />

350 400 450 500 550 600<br />

Wavelength (nm)<br />

3-deoxypeonidin<br />

R<br />

OH<br />

CH CH C<br />

HO OH<br />

H<br />

OH<br />

phloroglucinol<br />

Abstracted/indexed in: AGRICOLA, Beilstein, BIOSIS Previews, CAB Abstracts, Chemical Abstracts, Chemical Engineering and<br />

Biotechnology Abstracts, Current Biotechnology Abstracts, Current Contents: Life Sciences, Current Contents: Physical,<br />

Chemical and Earth Sciences, Current Contents Search, Derwent Drug File, Ei Compendex, EMBASE/Excerpta Medica, Medline,<br />

PASCAL, Research Alert, Science Citation Index, SciSearch. Also covered in the abstract and citation database SciVerse Scopus â .<br />

Full text available on SciVerse ScienceDirect â<br />

Available online at www.sciencedirect.com<br />

ISSN 0040-4039

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