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A study of monoelectronic reduction of Artemisinin pp 1296–1299<br />
Maria Luisa Navacchia, Massimo L. Capobianco, Mila D’Angelantonio, Giancarlo Marconi*<br />
O O<br />
O<br />
H<br />
O<br />
O<br />
ART<br />
H<br />
e<br />
H2O/EtOH<br />
- solv<br />
O<br />
O<br />
OH<br />
O ACID<br />
A novel reaction mechanism for the formation of deoxyanthocyanidins pp 1300–1303<br />
André Sousa, Nuno Mateus, Victor de Freitas*<br />
Cinnamic aldehydes:<br />
R= H. coniferaldehyde<br />
R= OCH3. sinapaldehyde<br />
HO<br />
H3CO<br />
R<br />
3'<br />
2'<br />
4'<br />
OH<br />
HO<br />
7<br />
8<br />
A<br />
8a<br />
O<br />
C<br />
1'<br />
2<br />
B<br />
6'<br />
5'<br />
OCH3 6<br />
5<br />
4a<br />
4<br />
3<br />
H<br />
OH H<br />
Deoxyanthocyanidins:<br />
R= H. 3-deoxypeonidin<br />
R= OCH3. 3-deoxymalvidin<br />
*Corresponding author<br />
Supplementary data available via SciVerse ScienceDirect<br />
Contents / Tetrahedron Letters 53 (2012) 1193–1199 1199<br />
R<br />
O<br />
CH CH C<br />
H<br />
(Intermediary compounds)<br />
0.04<br />
0.03<br />
A<br />
0.02<br />
0.01<br />
+H +<br />
HO<br />
487nm<br />
H3CO<br />
0<br />
350 400 450 500 550 600<br />
Wavelength (nm)<br />
3-deoxypeonidin<br />
R<br />
OH<br />
CH CH C<br />
HO OH<br />
H<br />
OH<br />
phloroglucinol<br />
Abstracted/indexed in: AGRICOLA, Beilstein, BIOSIS Previews, CAB Abstracts, Chemical Abstracts, Chemical Engineering and<br />
Biotechnology Abstracts, Current Biotechnology Abstracts, Current Contents: Life Sciences, Current Contents: Physical,<br />
Chemical and Earth Sciences, Current Contents Search, Derwent Drug File, Ei Compendex, EMBASE/Excerpta Medica, Medline,<br />
PASCAL, Research Alert, Science Citation Index, SciSearch. Also covered in the abstract and citation database SciVerse Scopus â .<br />
Full text available on SciVerse ScienceDirect â<br />
Available online at www.sciencedirect.com<br />
ISSN 0040-4039