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Phytoremediation of Volatile Organic Compounds in ... - CLU-IN

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Appendix 1: Field work <strong>in</strong>volv<strong>in</strong>g the phytoremediation <strong>of</strong> VOC-contam<strong>in</strong>ated groundwater<br />

Site (alphabetically by state) Po<strong>in</strong>t <strong>of</strong> Contact* Tree Species Primary Contam<strong>in</strong>ant Year Implemented Objectives Performance to Date Depth <strong>of</strong> Impact Other Comments<br />

Trees have grown consistently<br />

(up to 8 ft/year for the poplar).<br />

Comparison <strong>of</strong> groundwater<br />

concentrations from pre<strong>in</strong>stallation<br />

<strong>of</strong> the<br />

TreeMediation system and 2<br />

Hydraulic control and reduction<br />

grow<strong>in</strong>g seasons later <strong>in</strong>dicate<br />

<strong>of</strong> TCE contam<strong>in</strong>ant levels <strong>in</strong><br />

10-15 ft below ground surface N/A<br />

significant reduction <strong>of</strong> the TCE<br />

the aquifer<br />

concentrations <strong>in</strong> the aquifer<br />

both at the source area and on<br />

the property boundary.<br />

Hydraulic effects on the<br />

groundwater flow have also<br />

been demonstrated.<br />

TCE (up to 25 mg/L) 2000<br />

About 200 hybrid poplars (P.<br />

maximowiczii x trichocarpa ) on<br />

concentrated plot with about 50<br />

willows (Salix pentandra ) on<br />

boundary<br />

Unspecified manufactur<strong>in</strong>g facility - Ed Gattliff, Applied Natural<br />

Aurora, Ill<strong>in</strong>ois<br />

Sciences, Inc.<br />

10-15 ft below ground surface N/A<br />

Monitor<strong>in</strong>g <strong>of</strong> water levels and<br />

groundwater concentrations<br />

Hydraulic control and<br />

groundwater remediation<br />

through rhizodegradation,<br />

phytodegradation and<br />

evapotranspiration<br />

BTEX 2001-2002<br />

Full-scale project us<strong>in</strong>g seed and<br />

poles <strong>of</strong> poplar varieties, deeprooted<br />

prairie grasses and flowers<br />

David Tsao, Group<br />

Environmental Management<br />

Company, a BP affiliated<br />

company<br />

Rochelle Term<strong>in</strong>al, Ill<strong>in</strong>ois<br />

N/A<br />

Groundwater is 2-4 ft below<br />

ground surface<br />

Survival rate is greater than<br />

90%. Trees have grown 3-8 ft<br />

<strong>in</strong> 1.5 grow<strong>in</strong>g seasons. Have<br />

had substantial deer damage.<br />

To <strong>in</strong>tercept shallow<br />

groundwater downgradient<br />

from active landfill, reduce<br />

mass <strong>of</strong> contam<strong>in</strong>ant mov<strong>in</strong>g<br />

<strong>of</strong>f-site, hydraulic conta<strong>in</strong>ment<br />

2001-2002<br />

Full-scale project <strong>of</strong> 900 hybrid Low concentrations <strong>of</strong> organics<br />

poplars (DN-34), laurel leaf willows, (primarily BTEX with Benzene<br />

and understory grasses on one at 4 ug/L, TCE at 2-5 ug/L,<br />

acre site<br />

DCE at 1-70 ug/L)<br />

Eric Aitchison, Ecolotree, Inc.<br />

Leachate <strong>in</strong>terception buffer,<br />

northern Ill<strong>in</strong>ois<br />

<strong>IN</strong>DIANA<br />

1-10 ft below ground surface A Horizon soil on top <strong>of</strong> slag<br />

Monitor<strong>in</strong>g <strong>of</strong> water levels and<br />

sap flow<br />

Hydraulic control through<br />

evapotranspiration<br />

Pilot-scale project us<strong>in</strong>g potted<br />

black alder, cottonwood, willow, Phenols, alkal<strong>in</strong>ity 1998<br />

Norway spruce, Austrian p<strong>in</strong>e stock<br />

David Tsao, Group<br />

Environmental Management<br />

Company, a BP affiliated<br />

company<br />

Whit<strong>in</strong>g Ref<strong>in</strong>ery - J&L West,<br />

Indiana<br />

N/A<br />

Groundwater is 3-6 ft below<br />

ground surface<br />

Hydraulic cap to hold residual<br />

contam<strong>in</strong>ation <strong>in</strong> place, to<br />

degrade residual contam<strong>in</strong>ation<br />

<strong>in</strong> soil, to cleanup<br />

Greater than 95% survival<br />

contam<strong>in</strong>ated groundwater, to<br />

reduce groundwater flow rates<br />

from the site<br />

BTEX (less than 2 mg/L) November 2001<br />

Full-scale project <strong>of</strong> 350 hybrid<br />

poplars (DN-34) and understory<br />

grasses on 0.5 acres<br />

Louis Licht, Ecolotree, Inc.<br />

Unspecified leak<strong>in</strong>g underground<br />

storage tank site, Indiana<br />

IOWA<br />

Trees planted by trench<strong>in</strong>g 10<br />

ft below ground and plant<strong>in</strong>g 15<br />

ft trees to bottom <strong>of</strong> trench<br />

Groundwater is 9-11 ft below<br />

ground surface<br />

Greater than 95% survival<br />

To <strong>in</strong>tercept PCE/TCE/DCEcontam<strong>in</strong>ated<br />

groundwater<br />

water and promote their<br />

degradation, reduce mass flow<br />

<strong>of</strong> contam<strong>in</strong>ants <strong>of</strong>f-site<br />

April 2002<br />

PCE (up to 15 mg/L), TCE (up<br />

to 50 ug/L)<br />

Full-scale project with 700 hybrid<br />

poplar trees (DN-34) on one acre<br />

site<br />

Louis Licht, Ecolotree, Inc.<br />

Unspecified chlor<strong>in</strong>ated solvent<br />

spill site, northern Iowa<br />

KANSAS<br />

Trees planted <strong>in</strong> 10 ft deep<br />

auger holes to access<br />

groundwater<br />

Groundwater is 9-11 ft below<br />

ground surface<br />

Some tree loss, likely due to<br />

soil or free product<br />

phytotoxicity. 75% survival<br />

after two grow<strong>in</strong>g seasons.<br />

To <strong>in</strong>tercept groundwater,<br />

create a hydraulic cap, and<br />

clean up contam<strong>in</strong>ated soil<br />

January 2001<br />

Gasol<strong>in</strong>e and diesel-range<br />

organics (up to 3,000 mg/kg <strong>in</strong><br />

soil). Total volatile petroleum<br />

hydrocarbons range between 2<br />

and 36 mg/L <strong>in</strong> groudwater)<br />

Full-scale project us<strong>in</strong>g 204 hybrid<br />

poplar trees (DN-34) and<br />

understory grasses on a 0.3 acre<br />

site<br />

Eric Aitchison, Ecolotree, Inc.<br />

Unspecified hydrocarbon spill site,<br />

southern Kansas<br />

0-2 ft below ground surface N/A<br />

Monitor<strong>in</strong>g <strong>of</strong> water levels, sap<br />

flow, and groundwater<br />

concentrations<br />

Rhizodegradation,<br />

phytodegradation, and<br />

evapotranspiration <strong>in</strong> the<br />

riparian zone<br />

BTEX, MTBE 2001<br />

Full-scale project us<strong>in</strong>g whips <strong>of</strong><br />

poplar varieties<br />

David Tsao, Group<br />

Environmental Management<br />

Company, a BP affiliated<br />

company<br />

Sugar Creek Ref<strong>in</strong>ery - T156,<br />

Kansas<br />

KENTUCKY<br />

10-15 ft below ground surface N/A<br />

Monitor<strong>in</strong>g <strong>of</strong> water levels and<br />

groundwater concentrations<br />

Hydraulic control and<br />

groundwater remediation<br />

through rhizodegradation,<br />

phytodegradation, and<br />

evapotranspiration<br />

BTEX 2000<br />

Full-scale project with potted stock<br />

<strong>of</strong> poplar varieties<br />

David Tsao, Group<br />

Environmental Management<br />

Company, a BP affiliated<br />

company<br />

Louisville Term<strong>in</strong>al, Kentucky<br />

LOUSIANA<br />

5 ft below ground surface N/A<br />

Poplar did not thrive <strong>in</strong> wet,<br />

heavy soil conditions<br />

Remediation <strong>of</strong> TCE and its<br />

derivatives <strong>in</strong> a shallow aquifer<br />

TCE (up to 353 ug/L) 1995<br />

100 hybrid poplars (P.<br />

maximowiczii x trichocarpa ) and<br />

willow on 0.5 acre plot<br />

Ed Gattliff, Applied Natural<br />

Sciences, Inc.<br />

Unspecified oil transfer depot-<br />

Lafayette, Louisiana<br />

5-10 ft below ground surface N/A<br />

Monitor<strong>in</strong>g <strong>of</strong> water levels and<br />

groundwater concentrations<br />

Hydraulic control and<br />

groundwater remediation<br />

through rhizodegradation,<br />

phytodegradation, and<br />

evapotranspiration<br />

2000, with rema<strong>in</strong>der <strong>of</strong><br />

site scheduled for 2002<br />

Full-scale project us<strong>in</strong>g eucalyptus,<br />

Ethane Dichloride,<br />

poplar, and native willow potted<br />

Toluene Diam<strong>in</strong>e<br />

stock<br />

David Tsao, Group<br />

Environmental Management<br />

Company, a BP affiliated<br />

company<br />

Combustion Superfund, Louisiana<br />

Page 35

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