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MANUCOL HV 1. IDENTIFICATION OF THE SUBSTANCE ...

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Revision Date: 10/25/2002<br />

Issued: 09/01/2008<br />

Safety Data Sheet (91/155/EEC)<br />

32175I<br />

<strong>MANUCOL</strong> <strong>HV</strong><br />

<strong>1.</strong> <strong>IDENTIFICATION</strong> <strong>OF</strong> <strong>THE</strong> <strong>SUBSTANCE</strong>/PREPARATION AND <strong>THE</strong><br />

COMPANY/UNDERTAKING<br />

Identification of the substance/preparation<br />

Product Id: 32175I<br />

Product Name: <strong>MANUCOL</strong> <strong>HV</strong><br />

CAS Registry Number: 9005-38-3<br />

CAS Name: Alginic acid, sodium salt<br />

EEC Name: SODIUM ALGINATE E401<br />

Responsible Party: FMC Europe NV<br />

Avenue Mounier 83<br />

1200 Brussels, Belgium<br />

Tel:353 21 435 4133 (General Information - Cork, Ireland)<br />

Emergency Telephone Number: +47/32 30 3500 (FMC Plant- Drammen, Norway)<br />

Prepared By: Product Stewardship<br />

Product Use: (UK) FOR MANUFACTURE <strong>OF</strong> FOODSTUFFS AND NOT FOR RETAIL SALE.<br />

2. COMPOSITION/INFORMATION ON INGREDIENTS<br />

Components: EU Classification: UK OES/MEL: German MAK:<br />

Sodium alginate<br />

9005-38-3<br />

NA Not determined Not determined<br />

Hazard Overview<br />

Target Organs: None.<br />

Primary Entry Routes: Not applicable.<br />

3. HAZARDS <strong>IDENTIFICATION</strong><br />

Acute Health Hazards: The presence of water and this product together on any surface will result in that<br />

surface becoming extremely slippery. In common with most organic substances, this<br />

product should be treated as a combustible dust when in the finely-divided and airsuspended<br />

state. Local nuisance dust OES applies.<br />

Chronic Health Hazards: None expected based on available data- see Toxicological Data Section 1<strong>1.</strong><br />

Signs and Symptoms of Overexposure<br />

32175I<br />

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Eye Contact: May cause mild eye irritation.<br />

Skin Contact: Prolonged contact with the dry powder may cause drying or chapping of the skin.<br />

Ingestion: Not a hazard under normal use conditions.<br />

Inhalation: Excessive inhalation of dust can mechanically impede respiration. Due to the<br />

hygroscopic properties of the gums, they can form a paste or gel in the airway.<br />

4. FIRST AID MEASURES<br />

Eye Contact: Flush with copious amounts of water.<br />

Skin Contact: Wash with soap and water.<br />

Ingestion: Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek<br />

medical attention. Never give anything by mouth to an unconscious person.<br />

Inhalation: If inhaled, remove to fresh air. If not breathing or if breathing is difficult, give artificial<br />

respiration or oxygen by trained personnel. Seek medical attention.<br />

5. FIRE-FIGHTING MEASURES<br />

Flash Point (°F): N.Ap.<br />

Extinguishing Media: Alcohol foam/ Dry chemical/ Carbon dioxide / Water<br />

Unusual Fire/Explosion Hazards: Powdered material may form explosive dust-air mixtures.<br />

Special Protective Equipment: Fire fighters should wear full protective clothing, including self-contained breathing<br />

equipment.<br />

Personal Precautionary<br />

Measures:<br />

Procedure for<br />

Cleaning/Absorption:<br />

6. ACCIDENTAL RELEASE MEASURES<br />

Use appropriate protective equipment.<br />

Scoop up and remove. Minimize dust generation and accumulation. Water<br />

washdown not recommended.<br />

7. HANDLING AND STORAGE<br />

Handling: Minimize dust generation and accumulation. Wash thoroughly with soap and water<br />

after handling.<br />

Storage: Store in a cool, dry place, out of direct sunlight. Hygroscopic Material. Keep<br />

containers closed tightly when not in use.<br />

8. EXPOSURE CONTROLS / PERSONAL PROTECTION<br />

Engineering Controls: Use in a well ventilated area.<br />

Respiratory Protection: Local nuisance dust OES applies. Use in a well ventilated area. An approved<br />

respirator (i.e. NIOSH, etc.) should be worn when exposures are expected to exceed<br />

the applicable limits.<br />

Hand Protection: Use gloves as a standard industrial handling procedure.<br />

Eye Protection: Safety glasses.<br />

32175I<br />

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9. PHYSICAL AND CHEMICAL PROPERTIES<br />

Physical State: Powder<br />

Color: White / Yellowish brown<br />

Odor: Slight<br />

pH: ~Neutral (1% solution)<br />

Boiling Point (°F): Not determined<br />

Melting Point/Freezing Point(°F): Not determined<br />

Vapor Pressure: Not determined<br />

Solubility: Soluble in water<br />

10. STABILITY AND REACTIVITY<br />

Chemical Stability: Stable under normal conditions of handling, use and transportation.<br />

Hazardous Polymerization: Will not occur<br />

Conditions to Avoid: Minimize dust generation and accumulation.<br />

Materials to Avoid: Strong oxidizers.<br />

Hazardous Decomposition<br />

Products:<br />

Toxicity Test:<br />

Acute Oral LD50 (mg/kg): >5,000 (rat)<br />

Acute Inhalation LC50 (mg/l): >4.7 (1hr.) (rat)<br />

Carbon dioxide. Carbon monoxide.<br />

1<strong>1.</strong> TOXICOLOGICAL INFORMATION<br />

Skin Irritation: Non-irritating to rabbit skin.<br />

Eye Irritation: Non-irritating to rabbit eye.<br />

Other Information: Chronic Oral, Rat: No adverse effects at dosage levels up to 5% of the diet.<br />

Chronic Oral, Dog: No adverse effects at dosage levels up to 15% of the diet.<br />

12. ECOLOGICAL INFORMATION<br />

Biodegradability: Sodium alginate is biodegradable: BOD5: ~300 mg O2/g; COD: ~660 mg O2/g<br />

Aquatic Toxicity: No data is available on the adverse effects of this material on the environment.<br />

13. DISPOSAL CONSIDERATIONS<br />

Disposal of Waste Method: Follow all applicable community, national or regional regulations regarding waste<br />

management methods.<br />

14. TRANSPORT INFORMATION<br />

Hazard Classification: This product is non-hazardous, and no special precautions require to be taken in<br />

connection with transportation.<br />

Classification:<br />

15. REGULATORY INFORMATION<br />

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This product is not classified as hazardous under the terms of the EEC directive 67/548/EEC, UN regulations or the<br />

European ADR/RID agreements.<br />

TSCA Inventory List: This product and/or its components is listed on TSCA.<br />

California Proposition 65<br />

Carcinogens & Reproductive<br />

Toxicity (CRT) List:<br />

None of the components of this product is listed on CALPROP.<br />

Canada DSL Inventory List: This product and/or its components is listed on DSL.<br />

Canada NDSL Inventory List: This product and/or its components is not listed on NDSL.<br />

EU EINECS List: This product and/or its components is not listed on or is exempt from EINECS.<br />

ELINCS: This product and/or its components is not listed on ELINCS.<br />

Germany VCI Assigned This product and/or its components is not listed on WGK.<br />

Classification into Water<br />

Endangering Classes (WGK) List:<br />

Japan Inventory of Existing &<br />

New Chemical Substances<br />

(ENCS):<br />

Australia Inventory of Chemical<br />

Substances (AICS) List:<br />

This product and/or its components is listed on ENCS.<br />

This product and/or its components is listed on AICS.<br />

Food Approvals: Food Grade Sodium alginate is affirmed as a "Generally Recognized as Safe" GRAS<br />

under the US FDA (21 CFR 184.1724).<br />

16. O<strong>THE</strong>R INFORMATION<br />

Prepared By: Product Stewardship<br />

Legend: N.Av.= Not Available; N.Ap.= Not Applicable<br />

Important Note: The information contained in this document (as well as any advice or assistance)<br />

is provided by FMC only as a courtesy and is intended to be general in nature.<br />

Any uses suggested by FMC are presented only to assist our customers in exploring<br />

possible applications. FMC makes no warranty, express or implied, as to its<br />

accuracy or completeness, or the results to be obtained from such information,<br />

advice or assistance. Each customer is solely responsible for determining whether<br />

the FMC products are suitable for such customer’s intended use, and for obtaining any<br />

necessary governmental registrations and approvals for such customer’s production,<br />

marketing, sale, use and/or transportation of finished goods using or incorporating the<br />

FMC products.<br />

***END <strong>OF</strong> MSDS***<br />

32175I<br />

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