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Stability of Allyl Radicals

Stability of Allyl Radicals

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• When a single hydrogen atom on a carbon has been replaced by a<br />

halogen atom, monohalogenation has taken place.<br />

• When excess halogen is used, it is possible to replace more than one<br />

hydrogen atom on a single carbon with halogen atoms.<br />

• Monohalogenation can be achieved experimentally by adding halogen X 2<br />

to an excess <strong>of</strong> alkane.<br />

Figure 15.2<br />

Complete halogenation <strong>of</strong><br />

CH 4 using excess Cl 2<br />

Radical Halogenation <strong>of</strong> Alkanes<br />

10

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