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Safety Data Sheet according to Regulation (EC) No. 1907 ... - Ballistol

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<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />

<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />

Revision 30.11.2011 (GB) Version 1.0<br />

Airsoft<br />

1. Identification of the substance/mixture and of the company/undertaking<br />

Product identifier<br />

Name of product Airsoft<br />

Manufacturer/distribu<strong>to</strong>r F.W. KLEVER GmbH<br />

Hauptstr. 20, D-84168 Aham<br />

Phone 08744/9699-0, Fax 08744/9699-96<br />

E-Mail info@ballis<strong>to</strong>l.de<br />

Internet www.ballis<strong>to</strong>l.de<br />

Advice Büro / Labor<br />

Phone 08744/9699-0<br />

Emergency advice 08744/9699-0<br />

This number is only available at office times.<br />

Recommended intended purpose(s)<br />

Propellant für airsoft weapons<br />

2. Hazards identification<br />

Classification <strong>according</strong> <strong>to</strong> 67/548/E<strong>EC</strong> or 1999/45/<strong>EC</strong><br />

F+; R12<br />

R-phrases<br />

12 Extremely flammable.<br />

Labelling <strong>according</strong> <strong>to</strong> 67/548/E<strong>EC</strong> or 1999/45/<strong>EC</strong><br />

F+ Extremely flammable<br />

R-phrases<br />

12 Extremely flammable.<br />

3. Composition/information on ingredients<br />

Hazardous ingredients<br />

CAS <strong>No</strong> <strong>EC</strong> <strong>No</strong> Name [%<br />

weight]<br />

74-98-6 200-827-9 propane F+ R12<br />

75-28-5 200-857-2 isobutane < 15 F+ R12<br />

106-97-8 203-448-7 butane < 15 F+ R12<br />

Classification <strong>according</strong> <strong>to</strong> 67/548/E<strong>EC</strong><br />

Page 1/6


4. First aid measures<br />

General information<br />

Remove contaminated soaked clothing immediately.<br />

Take away from danger area and lay down affected person.<br />

In case of inhalation<br />

Ensure of fresh air.<br />

In case of skin contact<br />

In case of contact with skin wash off with warm water.<br />

<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />

<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />

Revision 30.11.2011 (GB) Version 1.0<br />

Airsoft<br />

In case of eye contact<br />

In case of contact with eyes rinse with plenty of water carefully. In the event of persistent symp<strong>to</strong>ms seek<br />

medical treatment.<br />

In case of ingestion<br />

Do not induce vomiting.<br />

Give water <strong>to</strong> drink in small sips.<br />

Rinse out mouth thoroughly with water.<br />

5. Firefighting measures<br />

Suitable extinguishing media<br />

Foam<br />

Carbon dioxide<br />

Water spray jet<br />

Extinguishing media which must not be used for safety reasons<br />

Keine<br />

Special hazards arising from the substance or mixture<br />

Nitrogen oxides (NOx)<br />

Carbon monoxide (CO)<br />

Carbon dioxide (CO2)<br />

Vapours may form explosive mixtures with air<br />

Special protective equipment for fire-fighters<br />

Use breathing apparatus with independent air supply ( isolated ).<br />

Additional information<br />

Cool endangered containers with water spray jet.<br />

Heating causes rise in pressure with risk of bursting<br />

6. Accidental release measures<br />

Personal precautions<br />

Ensure adequate ventilation.<br />

Keep people away and stay on the upwind side.<br />

Use personal protective clothing.<br />

Keep away sources of ignition.<br />

Do not breath vapour or spray.<br />

Environmental precautions<br />

Do not discharge in<strong>to</strong> the drains/surface waters/groundwater.<br />

Methods for cleaning up<br />

Suck off by room ventilation.<br />

Do not distribute with water.<br />

Page 2/6


7. Handling and s<strong>to</strong>rage<br />

<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />

<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />

Revision 30.11.2011 (GB) Version 1.0<br />

Airsoft<br />

Advice on safe handling<br />

Care for thoroughly room ventilation, if necessary use in well ventilated area with local exhaust ventilation<br />

at workplace.<br />

Take measures against electrostatically charging.<br />

Use only in well-ventilated areas.<br />

Do not spray in<strong>to</strong> flames or ignition sources<br />

Advice on protection against fire and explosion<br />

Keep away from sources of ignition - <strong>No</strong> smoking<br />

Container under pressure<br />

Protect aerosols from temperatures exceeding 50°C<br />

Do not open with force or incinerate, even when empty<br />

Requirements for s<strong>to</strong>rage rooms and vessels<br />

Keep in closed original container.<br />

Advice on s<strong>to</strong>rage compatibility<br />

Do not s<strong>to</strong>re <strong>to</strong>gether with food.<br />

Further information on s<strong>to</strong>rage conditions<br />

Protect from extreme heat and cold.<br />

Keep cool.<br />

S<strong>to</strong>rage group 2B<br />

8. Exposure controls/personal protection<br />

Respira<strong>to</strong>ry protection<br />

Breathing apparatus in the event of aerosol or mist formation.<br />

Respira<strong>to</strong>ry protection must be worn whenever the WEL levels have been exceeded<br />

The following applies <strong>to</strong> propane in general: If the concentration is exceeded, closed-circuit breathing<br />

apparatures must be used<br />

Use filter apparatus type AX, identification colour brown <strong>according</strong> <strong>to</strong> EN 371<br />

Hand protection<br />

Leather gloves<br />

Eye protection<br />

tightly fitting goggles<br />

Skin protection<br />

protective clothing<br />

General protective measures<br />

Avoid contact with eyes and skin<br />

Do not inhale aerosols<br />

Hygiene measures<br />

At work do not eat, drink, smoke or take drugs.<br />

S<strong>to</strong>ring of food in workroom forbidden.<br />

Wash hands before breaks and after work.<br />

Use barrier skin cream.<br />

Limitation and surveillance of the environment<br />

---<br />

Page 3/6


9. Physical and chemical properties<br />

Form<br />

aerosol<br />

Colour<br />

colourless, clear<br />

Important health, safety and environmental information<br />

boiling range<br />

<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />

<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />

Revision 30.11.2011 (GB) Version 1.0<br />

Airsoft<br />

Odour<br />

odourless<br />

Value Temperature at Method Remark<br />

ca. -40 °C<br />

Flash point ca. -82 °C DIN/ISO 2592<br />

Ignition temperature<br />

Lower explosion limit<br />

Upper explosion limit<br />

ca. 370 °C<br />

ca. 1,5 Vol-%<br />

ca. 10,9 Vol-%<br />

Vapour pressure ca. 7700 hPa 20 °C<br />

Density ca. 0,5 g/cm3 20 °C<br />

Solubility in water<br />

10. Stability and reactivity<br />

< 0,1 g/l<br />

Conditions <strong>to</strong> avoid<br />

Formation of explosive gas/air mixtures.<br />

Extremely flammable. Container under pressure. Protect from direct exposure <strong>to</strong> sunlight and<br />

temperatures exceeding 50°C.<br />

Materials <strong>to</strong> avoid<br />

Reactions with strong oxidising agents.<br />

Hazardous decomposition products<br />

Carbon monoxide<br />

Carbon dioxide<br />

Additional information<br />

Product is stable under normal s<strong>to</strong>rage conditions<br />

11. Toxicological information<br />

Acute <strong>to</strong>xicity/Irritability/Sensitization<br />

Irritability skin<br />

Irritability eye<br />

Value/Validation Species Method Remark<br />

non-irritant<br />

non-irritant<br />

Skin sensitization non-sensitizing<br />

Experiences made from practice<br />

May cause frostbite.<br />

Page 4/6


<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />

<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />

Revision 30.11.2011 (GB) Version 1.0<br />

Airsoft<br />

Additional information<br />

The product has not been tested. The information is derived from the properties of the individual<br />

components.<br />

12. Ecological information<br />

General regulation<br />

If appropriate application no interferences in sewage treatment plants.<br />

Do not allow uncontrolled leakage of product in<strong>to</strong> the environment.<br />

The breakdown properties of the product have not been tested. The information on these is given on the<br />

basis of details in the literature.<br />

13. Disposal considerations<br />

Waste code <strong>No</strong>. Name of waste<br />

16 05 04* gases in pressure containers (including halons) containing dangerous<br />

substances<br />

Wastes marked with an asterisk are considered <strong>to</strong> be hazardous waste pursuant <strong>to</strong> Directive 91/689/E<strong>EC</strong> on<br />

hazardous waste.<br />

Recommendations for the product<br />

Product rests: send for disposal, e.g. special waste incineration.<br />

There are no harmonised regulations on the disposal of chemicals in the member states of the EU. In<br />

Germany, the Recycling and Waste Management Act 8 KrW-/AbfG) stipulates recycling as a requirement.<br />

Recommendations for packaging<br />

Totally emptied packaging may be taken for recycling.<br />

14. Transport information<br />

Land and inland navigation transport ADR/RID<br />

UN-Nummer: 1950<br />

Including 1.000 ml LQ2 (max. 30 kg/package)<br />

ADR/RID: Klasse 2, Code: 5F<br />

Marine transport IMDG<br />

ADR: UN-Number: 1950, Aerosols (maximum 1 l)<br />

Including 1.000 ml LQ2 (max. 30 kg/package)<br />

ADR/RID: Klasse 2, Code: 5F<br />

EmS: F-D, S-U<br />

Air transport ICAO/IATA-DGR<br />

UN/ID-Number: 1950, Aerosols, flammable<br />

ICAO/IATA: Class 2.1<br />

Passanger/Cargo: 203<br />

15. Regula<strong>to</strong>ry information<br />

Other regulations (EU)<br />

Observe regulation 98/24/<strong>EC</strong> for employee health protection against the threat of chemical substances in<br />

the workplace.<br />

Aerosol directive (75/324/E<strong>EC</strong>).<br />

Page 5/6


VOC standard<br />

VOC content ca.99,5 %<br />

National regulations<br />

Restriction of occupation<br />

Observe employment restrictions for young people.<br />

Water hazard class 1 value from literature<br />

Decree for case of<br />

interference/remarks<br />

Nr.: 7 b<br />

<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />

<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />

Revision 30.11.2011 (GB) Version 1.0<br />

Airsoft<br />

Chemical <strong>Safety</strong> Assessment<br />

Chemical safety assessments for substances in this mixture were not carried out.<br />

16. Other information<br />

Recommended uses and restrictions<br />

National and local regulations concerning chemicals shall be observed.<br />

The information in this data sheet has been established <strong>to</strong> our best knowledge and was up-<strong>to</strong>-date at time<br />

of revision. It does not represent a guarantee for the properties of the product described in terms of the<br />

legal warranty regulations.<br />

Further information<br />

The information contained herein is based on the state of our knowledge. It characterizes the product with<br />

regard <strong>to</strong> the appropriate safety precautions. It does not represent a guarantee of the properties of the<br />

product.<br />

R12 = Extremely flammable<br />

Wording of the R/H-phrases specified in chapter 3 (not the classification of the mixture!)<br />

R 12 Extremely flammable.<br />

Page 6/6

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