Safety Data Sheet according to Regulation (EC) No. 1907 ... - Ballistol
Safety Data Sheet according to Regulation (EC) No. 1907 ... - Ballistol
Safety Data Sheet according to Regulation (EC) No. 1907 ... - Ballistol
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<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />
<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />
Revision 30.11.2011 (GB) Version 1.0<br />
Airsoft<br />
1. Identification of the substance/mixture and of the company/undertaking<br />
Product identifier<br />
Name of product Airsoft<br />
Manufacturer/distribu<strong>to</strong>r F.W. KLEVER GmbH<br />
Hauptstr. 20, D-84168 Aham<br />
Phone 08744/9699-0, Fax 08744/9699-96<br />
E-Mail info@ballis<strong>to</strong>l.de<br />
Internet www.ballis<strong>to</strong>l.de<br />
Advice Büro / Labor<br />
Phone 08744/9699-0<br />
Emergency advice 08744/9699-0<br />
This number is only available at office times.<br />
Recommended intended purpose(s)<br />
Propellant für airsoft weapons<br />
2. Hazards identification<br />
Classification <strong>according</strong> <strong>to</strong> 67/548/E<strong>EC</strong> or 1999/45/<strong>EC</strong><br />
F+; R12<br />
R-phrases<br />
12 Extremely flammable.<br />
Labelling <strong>according</strong> <strong>to</strong> 67/548/E<strong>EC</strong> or 1999/45/<strong>EC</strong><br />
F+ Extremely flammable<br />
R-phrases<br />
12 Extremely flammable.<br />
3. Composition/information on ingredients<br />
Hazardous ingredients<br />
CAS <strong>No</strong> <strong>EC</strong> <strong>No</strong> Name [%<br />
weight]<br />
74-98-6 200-827-9 propane F+ R12<br />
75-28-5 200-857-2 isobutane < 15 F+ R12<br />
106-97-8 203-448-7 butane < 15 F+ R12<br />
Classification <strong>according</strong> <strong>to</strong> 67/548/E<strong>EC</strong><br />
Page 1/6
4. First aid measures<br />
General information<br />
Remove contaminated soaked clothing immediately.<br />
Take away from danger area and lay down affected person.<br />
In case of inhalation<br />
Ensure of fresh air.<br />
In case of skin contact<br />
In case of contact with skin wash off with warm water.<br />
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />
<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />
Revision 30.11.2011 (GB) Version 1.0<br />
Airsoft<br />
In case of eye contact<br />
In case of contact with eyes rinse with plenty of water carefully. In the event of persistent symp<strong>to</strong>ms seek<br />
medical treatment.<br />
In case of ingestion<br />
Do not induce vomiting.<br />
Give water <strong>to</strong> drink in small sips.<br />
Rinse out mouth thoroughly with water.<br />
5. Firefighting measures<br />
Suitable extinguishing media<br />
Foam<br />
Carbon dioxide<br />
Water spray jet<br />
Extinguishing media which must not be used for safety reasons<br />
Keine<br />
Special hazards arising from the substance or mixture<br />
Nitrogen oxides (NOx)<br />
Carbon monoxide (CO)<br />
Carbon dioxide (CO2)<br />
Vapours may form explosive mixtures with air<br />
Special protective equipment for fire-fighters<br />
Use breathing apparatus with independent air supply ( isolated ).<br />
Additional information<br />
Cool endangered containers with water spray jet.<br />
Heating causes rise in pressure with risk of bursting<br />
6. Accidental release measures<br />
Personal precautions<br />
Ensure adequate ventilation.<br />
Keep people away and stay on the upwind side.<br />
Use personal protective clothing.<br />
Keep away sources of ignition.<br />
Do not breath vapour or spray.<br />
Environmental precautions<br />
Do not discharge in<strong>to</strong> the drains/surface waters/groundwater.<br />
Methods for cleaning up<br />
Suck off by room ventilation.<br />
Do not distribute with water.<br />
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7. Handling and s<strong>to</strong>rage<br />
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />
<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />
Revision 30.11.2011 (GB) Version 1.0<br />
Airsoft<br />
Advice on safe handling<br />
Care for thoroughly room ventilation, if necessary use in well ventilated area with local exhaust ventilation<br />
at workplace.<br />
Take measures against electrostatically charging.<br />
Use only in well-ventilated areas.<br />
Do not spray in<strong>to</strong> flames or ignition sources<br />
Advice on protection against fire and explosion<br />
Keep away from sources of ignition - <strong>No</strong> smoking<br />
Container under pressure<br />
Protect aerosols from temperatures exceeding 50°C<br />
Do not open with force or incinerate, even when empty<br />
Requirements for s<strong>to</strong>rage rooms and vessels<br />
Keep in closed original container.<br />
Advice on s<strong>to</strong>rage compatibility<br />
Do not s<strong>to</strong>re <strong>to</strong>gether with food.<br />
Further information on s<strong>to</strong>rage conditions<br />
Protect from extreme heat and cold.<br />
Keep cool.<br />
S<strong>to</strong>rage group 2B<br />
8. Exposure controls/personal protection<br />
Respira<strong>to</strong>ry protection<br />
Breathing apparatus in the event of aerosol or mist formation.<br />
Respira<strong>to</strong>ry protection must be worn whenever the WEL levels have been exceeded<br />
The following applies <strong>to</strong> propane in general: If the concentration is exceeded, closed-circuit breathing<br />
apparatures must be used<br />
Use filter apparatus type AX, identification colour brown <strong>according</strong> <strong>to</strong> EN 371<br />
Hand protection<br />
Leather gloves<br />
Eye protection<br />
tightly fitting goggles<br />
Skin protection<br />
protective clothing<br />
General protective measures<br />
Avoid contact with eyes and skin<br />
Do not inhale aerosols<br />
Hygiene measures<br />
At work do not eat, drink, smoke or take drugs.<br />
S<strong>to</strong>ring of food in workroom forbidden.<br />
Wash hands before breaks and after work.<br />
Use barrier skin cream.<br />
Limitation and surveillance of the environment<br />
---<br />
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9. Physical and chemical properties<br />
Form<br />
aerosol<br />
Colour<br />
colourless, clear<br />
Important health, safety and environmental information<br />
boiling range<br />
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />
<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />
Revision 30.11.2011 (GB) Version 1.0<br />
Airsoft<br />
Odour<br />
odourless<br />
Value Temperature at Method Remark<br />
ca. -40 °C<br />
Flash point ca. -82 °C DIN/ISO 2592<br />
Ignition temperature<br />
Lower explosion limit<br />
Upper explosion limit<br />
ca. 370 °C<br />
ca. 1,5 Vol-%<br />
ca. 10,9 Vol-%<br />
Vapour pressure ca. 7700 hPa 20 °C<br />
Density ca. 0,5 g/cm3 20 °C<br />
Solubility in water<br />
10. Stability and reactivity<br />
< 0,1 g/l<br />
Conditions <strong>to</strong> avoid<br />
Formation of explosive gas/air mixtures.<br />
Extremely flammable. Container under pressure. Protect from direct exposure <strong>to</strong> sunlight and<br />
temperatures exceeding 50°C.<br />
Materials <strong>to</strong> avoid<br />
Reactions with strong oxidising agents.<br />
Hazardous decomposition products<br />
Carbon monoxide<br />
Carbon dioxide<br />
Additional information<br />
Product is stable under normal s<strong>to</strong>rage conditions<br />
11. Toxicological information<br />
Acute <strong>to</strong>xicity/Irritability/Sensitization<br />
Irritability skin<br />
Irritability eye<br />
Value/Validation Species Method Remark<br />
non-irritant<br />
non-irritant<br />
Skin sensitization non-sensitizing<br />
Experiences made from practice<br />
May cause frostbite.<br />
Page 4/6
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />
<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />
Revision 30.11.2011 (GB) Version 1.0<br />
Airsoft<br />
Additional information<br />
The product has not been tested. The information is derived from the properties of the individual<br />
components.<br />
12. Ecological information<br />
General regulation<br />
If appropriate application no interferences in sewage treatment plants.<br />
Do not allow uncontrolled leakage of product in<strong>to</strong> the environment.<br />
The breakdown properties of the product have not been tested. The information on these is given on the<br />
basis of details in the literature.<br />
13. Disposal considerations<br />
Waste code <strong>No</strong>. Name of waste<br />
16 05 04* gases in pressure containers (including halons) containing dangerous<br />
substances<br />
Wastes marked with an asterisk are considered <strong>to</strong> be hazardous waste pursuant <strong>to</strong> Directive 91/689/E<strong>EC</strong> on<br />
hazardous waste.<br />
Recommendations for the product<br />
Product rests: send for disposal, e.g. special waste incineration.<br />
There are no harmonised regulations on the disposal of chemicals in the member states of the EU. In<br />
Germany, the Recycling and Waste Management Act 8 KrW-/AbfG) stipulates recycling as a requirement.<br />
Recommendations for packaging<br />
Totally emptied packaging may be taken for recycling.<br />
14. Transport information<br />
Land and inland navigation transport ADR/RID<br />
UN-Nummer: 1950<br />
Including 1.000 ml LQ2 (max. 30 kg/package)<br />
ADR/RID: Klasse 2, Code: 5F<br />
Marine transport IMDG<br />
ADR: UN-Number: 1950, Aerosols (maximum 1 l)<br />
Including 1.000 ml LQ2 (max. 30 kg/package)<br />
ADR/RID: Klasse 2, Code: 5F<br />
EmS: F-D, S-U<br />
Air transport ICAO/IATA-DGR<br />
UN/ID-Number: 1950, Aerosols, flammable<br />
ICAO/IATA: Class 2.1<br />
Passanger/Cargo: 203<br />
15. Regula<strong>to</strong>ry information<br />
Other regulations (EU)<br />
Observe regulation 98/24/<strong>EC</strong> for employee health protection against the threat of chemical substances in<br />
the workplace.<br />
Aerosol directive (75/324/E<strong>EC</strong>).<br />
Page 5/6
VOC standard<br />
VOC content ca.99,5 %<br />
National regulations<br />
Restriction of occupation<br />
Observe employment restrictions for young people.<br />
Water hazard class 1 value from literature<br />
Decree for case of<br />
interference/remarks<br />
Nr.: 7 b<br />
<strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong> <strong>according</strong> <strong>to</strong> <strong>Regulation</strong> (<strong>EC</strong>)<br />
<strong>No</strong>. <strong>1907</strong>/2006 (REACH)<br />
Revision 30.11.2011 (GB) Version 1.0<br />
Airsoft<br />
Chemical <strong>Safety</strong> Assessment<br />
Chemical safety assessments for substances in this mixture were not carried out.<br />
16. Other information<br />
Recommended uses and restrictions<br />
National and local regulations concerning chemicals shall be observed.<br />
The information in this data sheet has been established <strong>to</strong> our best knowledge and was up-<strong>to</strong>-date at time<br />
of revision. It does not represent a guarantee for the properties of the product described in terms of the<br />
legal warranty regulations.<br />
Further information<br />
The information contained herein is based on the state of our knowledge. It characterizes the product with<br />
regard <strong>to</strong> the appropriate safety precautions. It does not represent a guarantee of the properties of the<br />
product.<br />
R12 = Extremely flammable<br />
Wording of the R/H-phrases specified in chapter 3 (not the classification of the mixture!)<br />
R 12 Extremely flammable.<br />
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