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Revision Date 21/05/2012<br />

Revision 2<br />

Superse<strong>de</strong>s date 01/08/2011<br />

SDS No. 12565<br />

SAFETY DATA SHEET<br />

LEFRANC & BOURGEOIS ESSENCE D'ASPIC / OIL OF SPIKE LAVENDER<br />

According to Regulation (EC) No 1907/2006<br />

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING<br />

1.1. Product i<strong>de</strong>ntifier<br />

Product name<br />

Product No. 31151<br />

LEFRANC & BOURGEOIS ESSENCE D'ASPIC / OIL OF SPIKE LAVENDER<br />

1.2. Relevant i<strong>de</strong>ntified uses of the substance or mixture and uses advised against<br />

I<strong>de</strong>ntified uses<br />

Thinner for Oil Painting<br />

1.3. Details of the supplier of the <strong>safety</strong> <strong>data</strong> <strong>sheet</strong><br />

Supplier<br />

Contact Person<br />

1.4. Emergency telephone number<br />

33 (0)2 43 83 83 00 This number is only available during office hours.<br />

SECTION 2: HAZARDS IDENTIFICATION<br />

2.1. Classification of the substance or mixture<br />

Classification (1999/45/EEC) Xi;R38. R43. N;R51/53. R10.<br />

2.2. Label elements<br />

ColArt International SA<br />

5 Rue Rene Panhard<br />

Z.I .Nord<br />

72021 Le Mans Ce<strong>de</strong>x 2<br />

+33 2 43 83 83 00<br />

Lefranc-Bourgeois@colart.fr<br />

Jon Lloyd Group Regulatory Affairs Manager +44 (0)20842434224; j.lloyd@colart.co.uk<br />

Contains<br />

Labelling<br />

(R)-P-MENTHA-1,8-DIENE<br />

(S)-P-MENTHA-1,8-DIENE<br />

PINENES (ALPHA OR BETA)<br />

Risk Phrases<br />

Safety Phrases<br />

2.3. Other hazards<br />

Irritant<br />

R10<br />

R38<br />

R43<br />

Dangerous for the<br />

environment<br />

Flammable.<br />

Irritating to skin.<br />

May cause sensitisation by skin contact.<br />

R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the<br />

aquatic environment.<br />

S2<br />

S24<br />

Keep out of the reach of children.<br />

Avoid contact with skin.<br />

S29/56 Do not empty into drains, dispose of this material and its container at<br />

hazardous or special waste collection point.<br />

S37<br />

Wear suitable gloves.<br />

S46<br />

S51<br />

S61<br />

S64<br />

If swallowed, seek medical advice immediately and show this container or<br />

label.<br />

Use only in well-ventilated areas.<br />

Avoid release to the environment. Refer to special instructions/<strong>safety</strong> <strong>data</strong><br />

<strong>sheet</strong>s.<br />

If swallowed, rinse mouth with water (only if the person is conscious).<br />

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS<br />

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3.2. Mixtures<br />

LEFRANC & BOURGEOIS ESSENCE D'ASPIC / OIL OF SPIKE LAVENDER<br />

SDS No. 12565<br />

(R)-P-MENTHA-1,8-DIENE 5-10%<br />

CAS-No.: 5989-27-5 EC No.: 227-813-5<br />

Classification (EC 1272/2008)<br />

Flam. Liq. 3 - H226<br />

Skin Irrit. 2 - H315<br />

Skin Sens. 1 - H317<br />

Aquatic Acute 1 - H400<br />

Aquatic Chronic 1 - H410<br />

Classification (67/548/EEC)<br />

Xi;R38.<br />

N;R50/53.<br />

R10,R43.<br />

(S)-P-MENTHA-1,8-DIENE 1-5%<br />

CAS-No.: 5989-54-8 EC No.: 227-815-6<br />

Classification (EC 1272/2008)<br />

Flam. Liq. 3 - H226<br />

Skin Irrit. 2 - H315<br />

Skin Sens. 1 - H317<br />

Aquatic Acute 1 - H400<br />

Aquatic Chronic 1 - H410<br />

Classification (67/548/EEC)<br />

Xi;R38.<br />

N;R50/53.<br />

R10,R43.<br />

LINALOOL 30-60%<br />

CAS-No.: 78-70-6 EC No.: 201-134-4<br />

Classification (EC 1272/2008)<br />

Skin Irrit. 2 - H315<br />

Classification (67/548/EEC)<br />

Xi;R38.<br />

PINENES (ALPHA OR BETA) 5-10%<br />

CAS-No.:<br />

EC No.:<br />

Classification (EC 1272/2008)<br />

Flam. Liq. 3 - H226<br />

Skin Sens. 1 - H317<br />

Asp. Tox. 1 - H304<br />

Aquatic Acute 1 - H400<br />

Aquatic Chronic 1 - H410<br />

Classification (67/548/EEC)<br />

Xn;R65.<br />

N;R50/53.<br />

R10,R43.<br />

The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.<br />

SECTION 4: FIRST AID MEASURES<br />

4.1. Description of first aid measures<br />

General information<br />

Consult a physician for specific advice.<br />

Inhalation<br />

Move the exposed person to fresh air at once. Keep the affected person warm and at rest. Get prompt medical attention.<br />

Ingestion<br />

NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Immediately rinse mouth and provi<strong>de</strong> fresh air. DO NOT induce<br />

vomiting. Get medical attention immediately.<br />

Skin contact<br />

Remove affected person from source of contamination. Promptly wash contaminated skin with water. Promptly remove clothing if soaked<br />

through and wash the skin with water.<br />

Eye contact<br />

Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes and get medical attention.<br />

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LEFRANC & BOURGEOIS ESSENCE D'ASPIC / OIL OF SPIKE LAVENDER<br />

4.2. Most important symptoms and effects, both acute and <strong>de</strong>layed<br />

SDS No. 12565<br />

4.3. Indication of any immediate medical attention and special treatment nee<strong>de</strong>d<br />

SECTION 5: FIREFIGHTING MEASURES<br />

5.1. Extinguishing media<br />

Extinguishing media<br />

Extinguish with carbon dioxi<strong>de</strong> or dry pow<strong>de</strong>r. Do not use water as an extinguisher.<br />

Unsuitable extinguishing media<br />

DO NOT use water if avoidable.<br />

5.2. Special hazards arising from the substance or mixture<br />

Unusual Fire & Explosion Hazards<br />

No unusual fire or explosion hazards noted.<br />

5.3. Advice for firefighters<br />

Special Fire Fighting Procedures<br />

Avoid breathing fire vapours. Water spray should be used to cool containers.<br />

Protective equipment for fire-fighters<br />

Selection of respiratory protection for fire fighting: follow the general fire precautions indicated in the workplace.<br />

SECTION 6: ACCIDENTAL RELEASE MEASURES<br />

6.1. Personal precautions, protective equipment and emergency procedures<br />

Wear protective clothing as <strong>de</strong>scribed in Section 8 of this <strong>safety</strong> <strong>data</strong> <strong>sheet</strong>. Avoid inhalation of vapours and contact with skin and eyes.<br />

Provi<strong>de</strong> a<strong>de</strong>quate ventilation.<br />

6.2. Environmental precautions<br />

Contain spillages with sand, earth or any suitable adsorbent material. Do not allow to enter drains, sewers or watercourses. Collect and<br />

dispose of spillage as indicated in section 13.<br />

6.3. Methods and material for containment and cleaning up<br />

Ventilate well. Absorb small quantities with paper towels and evaporate in safe place (fume hood). Allow sufficient time for vapours to<br />

completely clear the hood ducts, then burn the paper in a location away from combustible materials. Absorb in vermiculite, dry sand or earth<br />

and place into containers.<br />

6.4. Reference to other sections<br />

SECTION 7: HANDLING AND STORAGE<br />

7.1. Precautions for safe handling<br />

Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Ventilate well, avoid breathing vapours. Use approved<br />

respirator if air contamination is above accepted level.<br />

7.2. Conditions for safe storage, including any incompatibilities<br />

Flammable/combustible - Keep away from oxidisers, heat and flames. Store in tightly closed original container in a dry, cool and well-ventilated<br />

place. Protect from light, including direct sunrays.<br />

Storage Class<br />

Chemical storage. Flammable liquid storage.<br />

7.3. Specific end use(s)<br />

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION<br />

8.1. Control parameters<br />

8.2. Exposure controls<br />

Protective equipment<br />

3 / 6


Process conditions<br />

LEFRANC & BOURGEOIS ESSENCE D'ASPIC / OIL OF SPIKE LAVENDER<br />

Provi<strong>de</strong> eyewash station. Use engineering controls to reduce air contamination to permissible exposure level.<br />

Engineering measures<br />

Provi<strong>de</strong> a<strong>de</strong>quate ventilation, including appropriate local extraction, to ensure that the <strong>de</strong>fined occupational exposure limit is not excee<strong>de</strong>d.<br />

Respiratory equipment<br />

If ventilation is insufficient, suitable respiratory protection must be provi<strong>de</strong>d.<br />

Hand protection<br />

For prolonged or repeated skin contact use suitable protective gloves. Nitrile gloves are recommen<strong>de</strong>d.<br />

Eye protection<br />

Use eye protection.<br />

Hygiene measures<br />

SDS No. 12565<br />

Use appropriate skin cream to prevent drying of skin. Promptly remove non-impervious clothing that becomes wet or contaminated. No specific<br />

hygiene procedures noted, but good personal hygiene practices are always advisable, especially when working with chemicals.<br />

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES<br />

9.1. Information on basic physical and chemical properties<br />

Appearance<br />

Liquid<br />

Colour<br />

Light (or pale).<br />

Odour<br />

Characteristic.<br />

Solubility<br />

Insoluble in water<br />

Relative <strong>de</strong>nsity 0, 880-0, 905<br />

Vapour pressure<br />

175-300 kPa<br />

Flash point<br />

51 CC (Closed cup).<br />

9.2. Other information<br />

SECTION 10: STABILITY AND REACTIVITY<br />

10.1. Reactivity<br />

10.2. Chemical stability<br />

10.3. Possibility of hazardous reactions<br />

10.4. Conditions to avoid<br />

10.5. Incompatible materials<br />

10.6. Hazardous <strong>de</strong>composition products<br />

During fire, toxic gases (CO, CO2, NOx) are formed.<br />

SECTION 11: TOXICOLOGICAL INFORMATION<br />

11.1. Information on toxicological effects<br />

Toxicological information<br />

No information available.<br />

General information<br />

Contains small amounts of organic solvents. Extensive use of the product in areas with ina<strong>de</strong>quate ventilation may result in hazardous vapour<br />

concentrations.<br />

Inhalation<br />

May cause irritation to the respiratory system. Vapours may cause headache, fatigue, dizziness and nausea.<br />

Skin contact<br />

Product has a <strong>de</strong>fatting effect on skin. Prolonged contact may cause redness, irritation and dry skin.<br />

Eye contact<br />

May cause temporary eye irritation.<br />

SECTION 12: ECOLOGICAL INFORMATION<br />

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Ecotoxicity<br />

LEFRANC & BOURGEOIS ESSENCE D'ASPIC / OIL OF SPIKE LAVENDER<br />

Dangerous for the environment: May cause long-term adverse effects in the aquatic environment.<br />

SDS No. 12565<br />

12.1. Toxicity<br />

12.2. Persistence and <strong>de</strong>gradability<br />

12.3. Bioaccumulative potential<br />

12.4. Mobility in soil<br />

12.5. Results of PBT and vPvB assessment<br />

12.6. Other adverse effects<br />

SECTION 13: DISPOSAL CONSIDERATIONS<br />

13.1. Waste treatment methods<br />

Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authority requirements.<br />

SECTION 14: TRANSPORT INFORMATION<br />

14.1. UN number<br />

UN No. (ADR/RID/ADN) 1169<br />

UN No. (IMDG) 1169<br />

UN No. (ICAO) 1169<br />

14.2. UN proper shipping name<br />

Proper Shipping Name<br />

Proper Shipping Name<br />

AROMATIC LIQUID EXTRACTS<br />

AROMATIC LIQUID EXTRACTS<br />

14.3. Transport hazard class(es)<br />

ADR/RID/ADN Class 3<br />

ADR/RID/ADN Class<br />

Class 3: Flammable liquids.<br />

IMDG Class 3<br />

ICAO Class/Division 3<br />

Transport Labels<br />

FLAMMABLE<br />

LIQUID<br />

3<br />

14.4. Packing group<br />

ADR/RID/ADN Packing group<br />

IMDG Packing group<br />

ICAO Packing group<br />

III<br />

III<br />

III<br />

14.5. Environmental hazards<br />

Environmentally Hazardous Substance/Marine Pollutant<br />

5 / 6


LEFRANC & BOURGEOIS ESSENCE D'ASPIC / OIL OF SPIKE LAVENDER<br />

SDS No. 12565<br />

14.6. Special precautions for user<br />

Hazard No. (ADR)<br />

Tunnel Restriction Co<strong>de</strong><br />

30 Flammable liquid (flash-point between 23°C and 60°C, inclusive) or flammable liquid or solid in the<br />

molten state with a flash-point above 60°C, heated to a temperature equal to or above its flash-point, or self<br />

heating liquid.<br />

(D/E)<br />

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Co<strong>de</strong><br />

SECTION 15: REGULATORY INFORMATION<br />

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture<br />

EU Legislation<br />

Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. System of specific information relating to<br />

Dangerous Preparations. 2001/58/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006<br />

concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency,<br />

amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as<br />

Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.<br />

Water hazard classification<br />

2<br />

15.2. Chemical Safety Assessment<br />

SECTION 16: OTHER INFORMATION<br />

Revision Date 21/05/2012<br />

Revision 2<br />

Superse<strong>de</strong>s date 01/08/2011<br />

Date 07/10/2009<br />

Risk Phrases In Full<br />

R10<br />

Flammable.<br />

R65<br />

Harmful: may cause lung damage if swallowed.<br />

R38<br />

Irritating to skin.<br />

R43<br />

May cause sensitisation by skin contact.<br />

R51/53<br />

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />

R50/53<br />

Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />

Hazard Statements In Full<br />

H315<br />

Causes skin irritation.<br />

H226<br />

Flammable liquid and vapour.<br />

H304<br />

May be fatal if swallowed and enters airways.<br />

H317<br />

May cause an allergic skin reaction.<br />

H410<br />

Very toxic to aquatic life with long lasting effects.<br />

H400<br />

Very toxic to aquatic life.<br />

Disclaimer<br />

This information relates only to the specific material <strong>de</strong>signated and may not be valid for such material used in combination with any other materials or in any<br />

process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty<br />

guarantee or representation is ma<strong>de</strong> to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such<br />

information for his own particular use.<br />

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