Surface-Enhanced Raman Scattering (SERS) - iaria
Surface-Enhanced Raman Scattering (SERS) - iaria
Surface-Enhanced Raman Scattering (SERS) - iaria
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<strong>SERS</strong> fluctuation sources<br />
• Photo-induced and site dependent – variation of the<br />
local field enhancement<br />
• Submonolayer coverage of hot spots<br />
• Photo-induced and spontaneous dynamics –<br />
chemistry change for long scans<br />
• Photo-bleaching of dyes, photo-desorption, photoinduced<br />
surface diusion,<br />
• Substrate heating, and possibly substrate<br />
morphology changes (through photo-oxidation for<br />
example)<br />
• <strong>Surface</strong> diusion of a single molecule in-and-out of<br />
a hot-spot (for SMD)<br />
August 19, 2012 ICQNM 2012 Rome, Italy 61