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Lisa Molofsky

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Lines-of-Evidence Approach to the<br />

Evaluation of Stray Gas Incidents<br />

<strong>Lisa</strong> <strong>Molofsky</strong>, Ann Smith,<br />

John Connor, Shahla Farhat<br />

GSI Environmental Inc.<br />

Tom Wagner, Albert Wylie<br />

Cabot Oil and Gas Corporation<br />

GSI ENVIRONMENTAL INC.<br />

Houston and Austin, TX<br />

(713) 522-6300<br />

CABOT OIL & GAS<br />

Pittsburgh, PA


Methane in Groundwater:<br />

Anthropogenic or Natural?<br />

GAS WELL MIGRATION<br />

NATURAL GAS SEEP<br />

House Explosion, Western PA<br />

KEY<br />

POINT:<br />

Eternal Flame Falls, NY<br />

Multiple sources of methane in shallow<br />

groundwater. Source identification challenging.


Practical Guidelines for Evaluation of<br />

Methane Impacts on Groundwater<br />

• Case Study: Marcellus, NE PA<br />

• Problem: Asserted that<br />

Marcellus shale gas<br />

extraction was causing stray<br />

gas impacts on water wells<br />

• Lessons Learned: Lines of<br />

Evidence for Stray Gas<br />

Studies<br />

Susquehanna<br />

County<br />

PENNSYLVANIA


Methane Impacts on GW in Northeastern Pennsylvania:<br />

Regional Survey of “Pre-Drill” Methane in Water Wells<br />

“Pre-Drill” Methane in >1700 Water Wells, 2008 - 2011<br />

FINDINGS<br />

■ 78% of water wells contain methane<br />

■ Higher concentrations in valleys vs. uplands


Mechanism for Methane Accumulation in Valleys?<br />

Methane from Shallow Subsurface<br />

Valley Faults and Fractures<br />

http://science.kennesaw.edu/


Underlying Geology of Northeastern PA:<br />

Non-Producing Gas-Bearing Units<br />

Key Strata<br />

Geologic Cross Section: Susquehanna County<br />

■ Glacial Till: Contains<br />

Microbial Gas<br />

■ Catskill &<br />

Lockhaven<br />

Formations:<br />

Thermogenic gascharged<br />

sandstone<br />

deposits (with<br />

extensive fracture<br />

networks)<br />

■ Marcellus shale: Gas<br />

at ~6000 ft below<br />

surface.


Underlying Geology of Northeastern PA<br />

Key Point<br />

Organic<br />

seams in<br />

Catskill<br />

formation<br />

are potential<br />

source of<br />

thermogenic<br />

gas


Fault and Fracture Networks<br />

Seismic Line: Susquehanna County, NE PA<br />

Large-Scale<br />

Faults<br />

Tully<br />

Limestone<br />

Question:<br />

Barriers to gas migration from deeper<br />

units or structural connections?


Historic Locations of Gas Shows: 200 years<br />

Key Point<br />

Shrewsbury Gas Field, 1969<br />

Lovelton Gas<br />

Field, 1965<br />

Salt Springs, pre-1800<br />

Shallow gas<br />

shows<br />

observed<br />

in water and<br />

gas wells<br />

for over<br />

200 years<br />

Harveys Lake Gas Field, 1956


Salt Springs State Park, PA:<br />

Historic Bubbling Spring<br />

Susquehanna<br />

County, PA<br />

Inscription on rock<br />

wall behind spring:<br />

“JMK 1862”


Water Well Construction and Aquifer<br />

Dynamics in NE Pennsylvania<br />

WATER WELLS:<br />

• Most wells penetrate the<br />

Catskill Sandstone<br />

• Open hole completions,<br />

draw water from fractures<br />

GAS WELLS:<br />

• All pass through Catskill<br />

and Lockhaven<br />

• Surface casing<br />

• Open annular spaces<br />

• Casing integrity<br />

Source: PA DCNR, 2012


Isotope Analyses: Source Gases<br />

Identified by Pennsylvania DEP and Cabot<br />

Upper and Middle<br />

Devonian Gases<br />

Above Marcellus<br />

Marcellus<br />

Shale Gas<br />

Source Gases<br />

Marcellus<br />

Production Gas<br />

(PA DEP & Cabot)<br />

CO 2<br />

Reduction<br />

Microbial Gas<br />

Thermogenic<br />

Gas<br />

Fermentation<br />

Upper / Middle<br />

Devonian Gas<br />

Above Marcellus<br />

(PA DEP)<br />

Dissolved Gas<br />

Identified as<br />

Upper/Middle<br />

Devonian (PA DEP)<br />

KEY<br />

POINT:<br />

Local Marcellus shale gas may be distinguished from<br />

shallower overlying Upper and Middle Devonian gases.


Isotope Analyses: Water Well Gases<br />

Sampled by PA DEP, Cabot Oil, and Duke Univ.<br />

Upper and Middle<br />

Devonian Gases<br />

Above Marcellus<br />

Marcellus<br />

Shale Gas<br />

Water Samples<br />

Water Wells:<br />

Dissolved Gas<br />

(PA DEP & Cabot)<br />

CO 2<br />

Reduction<br />

Microbial Gas<br />

Thermogenic<br />

Gas<br />

Fermentation<br />

Osborn et al. Study:<br />

Dissolved Gas<br />

In Water Wells<br />

Spring:<br />

Salt Springs<br />

State Park<br />

(Cabot)<br />

KEY<br />

POINT:<br />

Dissolved gases from local water wells are most consistent<br />

with microbial or shallow thermogenic sources.


Lessons Learned:<br />

Lines of Evidence for Stray Gas Investigations<br />

Geology/<br />

Hydrogeology<br />

Presence of gas-bearing strata, fault and<br />

fracture systems, aquifer dynamics<br />

History<br />

Regional<br />

Patterns<br />

Well<br />

Construction<br />

Prior oil and gas activity, stray gas<br />

incidents and evidence of naturallyoccurring<br />

gas seeps.<br />

Regional patterns of methane occurrence<br />

and composition.<br />

Construction and completion details for<br />

affected water wells and nearby gas wells.<br />

Geochemical<br />

Fingerprinting<br />

Analyses of composition and isotopic<br />

signatures of gas sources.


OBJECTIVE:<br />

Effective approach for<br />

evaluation of potential<br />

impacts of shale gas<br />

development on GW<br />

resources.<br />

Credit: Bennett V/Flickr

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