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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

FIRE PROTECTION OF CONCRETE STRUCTURES EXPOSED TO<br />

FAST FIRES<br />

Pierre Pimienta *, Octavian An<strong>to</strong>n **, Jean-Chris<strong>to</strong>phe Mindeguia *, Romuald Avenel *<br />

Heidi Cuypers **, Eric Cesmat *<br />

* CSTB – Scientific and Technical Center for Construction, University <strong>of</strong> Paris-Est - 84 Avenue Jean<br />

Jaurès, 77447 Marne la Vallée Cedex, France (contact: pierre.pimienta@cstb.fr)<br />

** PRTC N.V. - Bormstraat, 24 B-2830 Tisselt, Belgium (contact: h.cuypers@prtc.be)<br />

KEYWORDS: Concrete spalling, <strong>fire</strong> protective panels, calcium alumina silicates engineered matrix<br />

for high performing <strong>fire</strong> <strong>protection</strong> <strong>of</strong> <strong>concrete</strong>s.<br />

ABSTRACT<br />

The aim <strong>of</strong> this research is <strong>to</strong> assess, through a scientific experimental program, the behaviour under<br />

the increased hydrocarbon temperature/time curve, <strong>of</strong> <strong>concrete</strong> <strong>structures</strong> protected by calcium<br />

alumina silicates panels developed and produced by a special mineral and matrix engineering<br />

technology for a resistance <strong>to</strong> these conditions <strong>of</strong> temperature.<br />

The principal investigations on this research are focussed on: the influence <strong>of</strong> the thickness <strong>of</strong> the<br />

<strong>protection</strong> on the temperature gradient and behaviour <strong>of</strong> the <strong>concrete</strong>; the nature <strong>of</strong> the <strong>concrete</strong> and in<br />

particular the nature <strong>of</strong> the aggregates which impacts on the thermal diffusivity <strong>of</strong> the <strong>concrete</strong> and the<br />

sensitivity with respect <strong>to</strong> spalling, the implementation or not <strong>of</strong> a compressive stress on bot<strong>to</strong>m fibre<br />

<strong>of</strong> the slab <strong>exposed</strong> <strong>to</strong> <strong>fire</strong>.<br />

1. Introduction<br />

The construction pr<strong>of</strong>essionals pay a particular interest <strong>to</strong> the behaviour <strong>of</strong> <strong>concrete</strong> <strong>structures</strong> in <strong>fast</strong><br />

<strong>fire</strong>s conditions and particularly in tunnels. This interest was jumping at a higher degree <strong>of</strong> concern<br />

following dramatic events encountered in road and railways tunnels in the recent decade and largely<br />

informed by different media [1]. Numbers <strong>of</strong> research studies concerning the behaviour <strong>of</strong> different<br />

<strong>concrete</strong> <strong>structures</strong> were performed, experimentally from small <strong>to</strong> big scale full systems testing in real<br />

exposure conditions [2], [3] or by mathematical modelling [4], [5]. Meanwhile, the exact mechanisms<br />

controlling the behaviour <strong>of</strong> <strong>concrete</strong> in <strong>fast</strong> <strong>fire</strong> conditions are still not well known; and this is due <strong>to</strong><br />

the complexity <strong>of</strong> parameters playing a role in these scenarios. Still <strong>to</strong>day, experimentation is then the<br />

only reliable way <strong>of</strong> assessing the <strong>fire</strong> resistance <strong>of</strong> a <strong>concrete</strong> structure.<br />

The most apprehended phenomenon is the spalling <strong>of</strong> the <strong>concrete</strong> when <strong>exposed</strong> <strong>to</strong> a <strong>fast</strong> firing and<br />

particularly in tunnels where temperatures grow very <strong>fast</strong>, reaching in few minutes high values as<br />

1300°C and even more [6]. Spalling can take several aspects but always leading <strong>to</strong> the loss <strong>of</strong> a part <strong>of</strong><br />

the structure and the loss <strong>of</strong> the mechanical resistance for the remaining <strong>concrete</strong> [7]. Between the<br />

hypotheses on the process leading <strong>to</strong> spalling, two hypotheses are largely considered <strong>to</strong>day: the<br />

thermo-mechanical one that is essentially based on the differential dimensional constraints developed<br />

during exposure <strong>to</strong> high temperature [8], [9], and the thermo-hydric one that considers the pores water<br />

vapour pressures developed when the structure is <strong>exposed</strong> <strong>to</strong> a <strong>fast</strong> firing as responsible for the<br />

physical destruction <strong>of</strong> the <strong>concrete</strong> [10], [11].<br />

In this study we chose <strong>to</strong> focus the spalling study on the analysis <strong>of</strong> the thermal gradients in<strong>to</strong> the first<br />

centimetres <strong>of</strong> the <strong>concrete</strong> slabs. One <strong>of</strong> the main objectives <strong>of</strong> this study was <strong>to</strong> define the critical<br />

thermal gradient for the type <strong>of</strong> <strong>concrete</strong> investigated and test configuration (with or without<br />

constraint).<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

2. The <strong>fire</strong> <strong>protection</strong> <strong>of</strong> <strong>concrete</strong>: the PROMATECT®<br />

In view <strong>to</strong> better understand the transfer <strong>of</strong> temperature through the <strong>concrete</strong> structure and the relation<br />

<strong>to</strong> the appearance and development <strong>of</strong> spalling, non protected and protected <strong>concrete</strong> constructions<br />

were investigated. The type and thickness <strong>of</strong> the <strong>protection</strong> was between the key <strong>to</strong>ols for a scientific<br />

investigation and definition <strong>of</strong> effective <strong>protection</strong>. This study investigated on the behaviour <strong>of</strong><br />

<strong>concrete</strong> protected mainly by a calcium alumina silicate board, PROMATECT®T, developed and<br />

industrially produced following a special approach – the Mineral and Matrix Engineering – for the<br />

best <strong>fire</strong> <strong>protection</strong> performances for flat as well as curved <strong>concrete</strong> surfaces. Known also as<br />

PROMAXON® Technology (see Figure 1), the manufacturing process <strong>of</strong> the product starts from the<br />

a<strong>to</strong>m level <strong>of</strong> selected raw materials playing with their chemical affinities in view <strong>to</strong> build synthetic<br />

mineral crystal <strong>structures</strong> and aggregate <strong>of</strong> crystals best fitted <strong>to</strong> build the full matrix <strong>of</strong> the product<br />

with the desired texture and structure for the best performances. In this program different thicknesses<br />

were voluntary applied in order <strong>to</strong> involve development <strong>of</strong> different thermal gradients in<strong>to</strong> the<br />

<strong>concrete</strong> slab during the <strong>fire</strong>.<br />

_ 3 µm<br />

Figure 1. Controlled crystal growth and aggregation for specially designed porosity – PROMAXON®<br />

Technology.<br />

In the construction <strong>of</strong> the matrix by this technology, special endothermic phases are integrated in the<br />

crystallization process <strong>to</strong> bring at the desired moment in a <strong>fire</strong> the most effective cooling <strong>of</strong> the<br />

interface with the <strong>concrete</strong> <strong>to</strong> protect. Two type <strong>of</strong> <strong>protection</strong> boards were used in this study -<br />

PROMATECT® H for some particular constructions and PROMATECT® T.<br />

PROMATECT® -H is an au<strong>to</strong>claved calcium silicate board with nominal dimensions <strong>of</strong> 2.5 x 1.25 m,<br />

thickness from 6 <strong>to</strong> 27 mm and a nominal density <strong>of</strong> 870 kg/m³. The matrix <strong>of</strong> H type was developed<br />

<strong>to</strong> satisfy different <strong>fire</strong> <strong>protection</strong> construction requirements.<br />

PROMATECT® -T is a product specially designed for <strong>fire</strong> <strong>protection</strong> applications <strong>of</strong> <strong>concrete</strong><br />

<strong>structures</strong> in tunnels, board with nominal dimensions <strong>of</strong> 2.5 x 1.2 m, thickness from 15 <strong>to</strong> 40 mm and<br />

a nominal density <strong>of</strong> 900 kg/m³. The matrix is based on calcium alumina silicates developed under<br />

controlled crystal growth technology. Mineral and Matrix Engineering concept was used <strong>to</strong> design a<br />

matrix with an optimized cooling action at the right moment during the <strong>fire</strong>.<br />

Between the physical characteristics <strong>of</strong> interest for tunnel applications, PROMATECT® H has<br />

thermal conductivity <strong>of</strong> 0.175 W/mK, 0.212 W/mK for PROMATECT® T. The densities being<br />

similar, the differences are on the textural detail <strong>of</strong> the matrix: H type has a laminar texture when T<br />

type has a monolithic one. Another important characteristic is the specific energy (Cp) that is also a<br />

parameter largely used particularly by those using mathematical modelling approach for the definition<br />

<strong>of</strong> the necessary <strong>protection</strong>(type and thickness) for safe constructions. The value given by<br />

scientific/technical literature is around 1.00 J/gK for calcium silicates or calcium alumina silicates.<br />

Important <strong>to</strong> note is that the value is measured after heating the product up <strong>to</strong> 500 °C and cooled<br />

down. But by such method <strong>of</strong> measuring, all eventual advantages that a specific product can bring for<br />

an efficient and cost advantageous <strong>fire</strong> <strong>protection</strong> can not be seen and exploited (Figure 2, left second<br />

run). This study paid a particular attention <strong>to</strong> this and proposed, by a rigorous parallel experimental<br />

and mathematical modelling, a better procedure for assessing reliable Cp values (Figure 2, right).<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

specific energy [J/gK]<br />

12<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

0 100 200 300 400 500 600<br />

CP on sample after<br />

Temperature<br />

stabilisation (second<br />

[°C]<br />

run)<br />

Cp on sample as received (first run)<br />

Specific energy [kJ/kgK]<br />

FEM specific enery PT-T<br />

50000<br />

45000<br />

40000<br />

1st endotherm<br />

35000<br />

30000<br />

25000<br />

2nd endotherm<br />

20000<br />

15000<br />

10000<br />

5000<br />

0<br />

0 100 200 300 400 500 600<br />

Temperature [°C]<br />

Figure 2. On the left, specific energy (Cp) measured after a first heating <strong>to</strong> 500 °C (generally used by modelling<br />

people) and for virgin sample (first run, i.e. with no pre heating). On the right, the endotherms that are<br />

considered in this study for the finite element modelling.<br />

3. Experimental settings<br />

3.1 Testing program<br />

The experimental program <strong>of</strong> this study was jointly carried out at the PRTC labora<strong>to</strong>ry (Promat<br />

Research and Technology Center, Belgium) and at the CSTB labora<strong>to</strong>ry (France). The number <strong>of</strong><br />

tests, depending on the thermal <strong>protection</strong> thickness, type <strong>of</strong> <strong>concrete</strong> and type <strong>of</strong> loading are<br />

summarized in the Table 1. Tests in the two labora<strong>to</strong>ries were done on the same slabs <strong>concrete</strong> and<br />

<strong>protection</strong> systems. The main difference is that the tests that were made at PRTC consisted in<br />

unloaded slabs while tests in CSTB consisted in loaded slabs.<br />

Number <strong>of</strong> tests<br />

Unloaded slabs<br />

(Promat Research and Technology<br />

Center)<br />

Loaded slabs (CSTB)<br />

Protection<br />

thickness [mm]<br />

Calcareous<br />

<strong>concrete</strong><br />

Silico-calcareous<br />

<strong>concrete</strong><br />

Calcareous<br />

<strong>concrete</strong><br />

Silico-calcareous<br />

<strong>concrete</strong><br />

/ = no test<br />

0 1 1 1 1<br />

8 1 1 1 1<br />

12.5 1 1 1 /<br />

15 1 1 1 /<br />

20 / / 1 /<br />

25 / / 1 /<br />

3.2 Concrete mixes<br />

Table 1. Summary <strong>of</strong> the experimental program<br />

For this study, two types <strong>of</strong> <strong>concrete</strong> have been tested. Both <strong>of</strong> them are ordinary <strong>concrete</strong>s<br />

(compressive strength lower than 60 MPa). The only difference between the two formulas comes from<br />

the nature <strong>of</strong> the aggregates. The first <strong>concrete</strong>, that we called B40, is fabricated with calcareous<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

aggregates. These aggregates are crushed rocks with a content <strong>of</strong> almost 99 % <strong>of</strong> CaO. The second<br />

<strong>concrete</strong>, that we called B40SC, is fabricated with a mix <strong>of</strong> calcareous and siliceous aggregates. These<br />

silico-calcareous aggregates are composed by alluvial semi-crushed sand and limes<strong>to</strong>ne gravels.<br />

Testing two types <strong>of</strong> aggregates allows analysing the <strong>fire</strong> behaviour <strong>of</strong> the most common <strong>concrete</strong>s<br />

that one may use in France. Moreover, previous studies have shown that the behaviour <strong>of</strong> <strong>concrete</strong> at<br />

high temperature is strongly dependant on the nature <strong>of</strong> the aggregates [13].<br />

The composition <strong>of</strong> the two types <strong>of</strong> <strong>concrete</strong>s used for the study is given in Table 2. It is in<br />

conformity with standard NF EN 206.<br />

kg Calcareous <strong>concrete</strong> Silico-calcareous <strong>concrete</strong><br />

CEM II 42.5 R cement 350 350<br />

8/12.5 calcareous gravel 330<br />

12.5/20 calcareous gravel 720<br />

4/8 silico-calcareous gravel 150<br />

8/20 silico-calcareous gravel 890<br />

0/2 sand 845 845<br />

Water 188 188<br />

Superplasticizer 4.31 5.25<br />

W / C ratio 0.54 0.54<br />

28 days Rc [MPa] 39 40<br />

Table 2. Composition <strong>of</strong> the two <strong>concrete</strong>s <strong>of</strong> the study<br />

3.3 Unloaded tests<br />

During the same <strong>fire</strong> test, both <strong>concrete</strong> types (calcareous and silico-calcareous) were tested (see<br />

Figure 3). In parallel with the thermal data collection, a video camera placed inside <strong>of</strong> the furnace was<br />

capturing all moments and brought very useful information <strong>of</strong> the moment and the way <strong>concrete</strong><br />

spalling occurred.<br />

Figure 3. The testing furnace in Promat labora<strong>to</strong>ry (left) and the design <strong>of</strong> the construction for testing (right).<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

3.4 Loaded tests<br />

Generally, most <strong>of</strong> the <strong>fire</strong>s tests carried out on <strong>concrete</strong> slabs consist in applying a mechanical load<br />

that results in the bending <strong>of</strong> the slabs (involving an initial tensile stress in the slab bed that is <strong>exposed</strong><br />

<strong>to</strong> <strong>fire</strong>). However, previous studies shown that <strong>concrete</strong> spalling can be more severe for compressed<br />

elements. In this study, the influence <strong>of</strong> an initial compressive stress in the slab bed <strong>exposed</strong> <strong>to</strong> <strong>fire</strong><br />

has then been analysed.<br />

For that, an innovative testing procedure has been developed at the CSTB. This facility consists in<br />

bending the slab in such a way that a compressive stress <strong>of</strong> 10 MPa is initially applied <strong>to</strong> the slab bed<br />

that is <strong>exposed</strong> <strong>to</strong> <strong>fire</strong>. Firstly, the <strong>concrete</strong> slab is horizontally placed upon a gas burners furnace. The<br />

geometry <strong>of</strong> the slab is shown in Figure 4. The <strong>exposed</strong> surface <strong>of</strong> the slab is 4490 x 1000 mm² and its<br />

thickness in the "<strong>fire</strong> zone" is 200 mm. Then stiff metal beams (length = 4000 mm) are fixed on each<br />

end <strong>of</strong> the slab. The ends <strong>of</strong> the slab have a greater thickness than in heated zone (350 mm) and are<br />

rigidified by a dense reinforcement. A dead load <strong>of</strong> 1 <strong>to</strong>n is suspended at the end <strong>of</strong> the metal beams.<br />

This system involves the bending <strong>of</strong> the slab in a direction at the opposite <strong>of</strong> the <strong>fire</strong>. This induces<br />

then an initial compressive stress <strong>of</strong> 10 MPa in the inferior bed <strong>of</strong> the slab.<br />

Figure 4. Geometry and principle <strong>of</strong> the "compressive" <strong>fire</strong> test.<br />

3.5 Fire curve<br />

All the tests <strong>of</strong> the study (loaded and unloaded tests) are carried out under the so-called temperature/<br />

time curve "HCM" (for Modified HydroCarbon <strong>fire</strong>, in French), defined by the Technical Instruction<br />

annexed in the circular n° 2000-63 <strong>of</strong> August 25th, 2000.<br />

The thermal program is described by the following relation:<br />

T = 1280. (1-0,325e (-0,167t) -0,675 e (-2,5t) )+ 20<br />

Where T is the furnace inner temperature in [°C] and t the time in [min]. The evolution <strong>of</strong> the<br />

temperature, according <strong>to</strong> the HCM curve is shown in Figure 4 for a duration <strong>of</strong> 3 hours. 1200 °C are<br />

reached in only 10 minutes and 1300 °C are reached after 30 minutes.<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

1400<br />

Modified HydroCarbon (HCM) <strong>fire</strong> curve<br />

1400<br />

Temperature (°C)<br />

1200<br />

1000<br />

800<br />

600<br />

400<br />

200<br />

0<br />

0 20 40 60 80 100 120 140 160 180 200<br />

Time (min)<br />

Temperature (°C)<br />

1200<br />

1000<br />

800<br />

600<br />

400<br />

200<br />

0<br />

0 2 4 6 8 10 12 14 16 18 20<br />

Time (min)<br />

Figure 5. Evolution <strong>of</strong> the inner furnace temperature under a HCM <strong>fire</strong> curve (on the right, focus on the 20 first<br />

minutes <strong>of</strong> <strong>fire</strong>).<br />

4. Results<br />

In this paragraph, the main results <strong>of</strong> the study are presented. Firstly, we present the analysis <strong>of</strong> the<br />

<strong>concrete</strong> spalling risk depending on different parameters (thermal <strong>protection</strong> thickness, type <strong>of</strong><br />

aggregates, mechanical loading). Then we present an experimental and numerical study attending <strong>to</strong><br />

establish the link between <strong>concrete</strong> spalling and the thermal gradients that is induced in the first<br />

centimetres <strong>of</strong> the <strong>fire</strong>d slab. At last, we present the results <strong>of</strong> the assessment <strong>of</strong> the residual<br />

compressive strength <strong>of</strong> <strong>concrete</strong> in the <strong>fire</strong>d slabs, from drilled cores.<br />

4.1 Concrete spalling<br />

The Table 3 summarizes the results <strong>of</strong> the maximal <strong>concrete</strong> spalling depths that were measured<br />

depending on different parameters such as the thickness <strong>of</strong> the thermal <strong>protection</strong>, the type <strong>of</strong><br />

aggregates and the type <strong>of</strong> mechanical loading. The main observations are as following.<br />

When <strong>concrete</strong> slabs are not thermally protected, <strong>concrete</strong> spalling occurs for any type <strong>of</strong> our tested<br />

<strong>concrete</strong>s (i.e. for both types <strong>of</strong> aggregates) and for any type <strong>of</strong> mechanical loading (i.e. with no<br />

loading or for compressive loading). In that case, <strong>concrete</strong> spalling involves the disappearance <strong>of</strong><br />

<strong>concrete</strong> cover and then the direct exposure <strong>to</strong> <strong>fire</strong> <strong>of</strong> the reinforcement.<br />

For the under sized thermal <strong>protection</strong> boards ( from 8 <strong>to</strong> 15 mm), <strong>concrete</strong> spalling can also occur.<br />

This has been particularly observed during loaded tests. It is very important <strong>to</strong> note that when <strong>concrete</strong><br />

spalling occurred for protected slabs, <strong>concrete</strong> spalling was deeper than for slabs with no <strong>protection</strong><br />

(see Figure 6). This unexpected result clearly indicates that an under sizing <strong>of</strong> the thermal <strong>protection</strong><br />

can involve an important damage <strong>of</strong> the <strong>concrete</strong> structure (with in particular an important exposure <strong>of</strong><br />

the reinforcement <strong>to</strong> <strong>fire</strong>).<br />

For thick enough thermal <strong>protection</strong> (20 and 25 mm in our study), <strong>concrete</strong> spalling is avoided in the<br />

case <strong>of</strong> loaded slabs. This results in a continuous <strong>protection</strong> <strong>of</strong> the reinforcement during the <strong>fire</strong> and<br />

good residual mechanical performances (see § 4.3).<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

Maximal spalling<br />

depth<br />

Protection<br />

thickness [mm]<br />

Calcareous<br />

<strong>concrete</strong><br />

Unloaded slabs<br />

Silico-calcareous<br />

<strong>concrete</strong><br />

Calcareous<br />

<strong>concrete</strong><br />

Loaded slabs<br />

Silico-calcareous<br />

<strong>concrete</strong><br />

0 55 30 49 85<br />

8 50 0 63 77<br />

12.5 0 0 137 /<br />

15 0 0 130 / 45 /<br />

20 / / 0 /<br />

25 / / 0 /<br />

/ = no test; 0 = no spalling<br />

Table 3. Summary <strong>of</strong> the measurement <strong>of</strong> the maximal spalling depth.<br />

In our study, the influence <strong>of</strong> the type <strong>of</strong> aggregates on <strong>concrete</strong> spalling is not clear. Indeed, for tests<br />

with no mechanical loading, <strong>concrete</strong> spalling is deeper for calcareous <strong>concrete</strong>. Moreover, we<br />

observed for slabs protected with 8 mm boards that <strong>concrete</strong> spalling only occurs for calcareous<br />

<strong>concrete</strong>. On the contrary, for tests with mechanical loading, <strong>concrete</strong> spalling is deeper for silicocalcareous<br />

<strong>concrete</strong>. One important aspect <strong>of</strong> <strong>fire</strong> <strong>concrete</strong> behaviour is the spalling that can occur<br />

during the cooling down <strong>of</strong> the structure and even for a long period after the <strong>fire</strong> (actually, it can be<br />

better seen as a <strong>concrete</strong> departure or a <strong>concrete</strong> fall than a real spalling). In the § 4.3, we will see that<br />

the type <strong>of</strong> aggregates can influence this particular type <strong>of</strong> <strong>concrete</strong> departure.<br />

Observing the results in Table 3, we can say that the initial presence <strong>of</strong> a compressive stress at the<br />

inferior bed <strong>of</strong> the slab is unfavourable regarding <strong>to</strong> <strong>concrete</strong> spalling.<br />

However, for slabs with no <strong>protection</strong>, the influence <strong>of</strong> loading is not that clear: the presence <strong>of</strong> load<br />

only involves deeper spalling for silico-calcareous <strong>concrete</strong>. In the case <strong>of</strong> the calcareous <strong>concrete</strong>,<br />

spalling depth does not seem <strong>to</strong> be influenced by the loading.<br />

In the case <strong>of</strong> under sized thermal <strong>protection</strong> boards (from 8 <strong>to</strong> 15 mm), the presence <strong>of</strong> the loading<br />

leads <strong>to</strong> deeper spalling. In particular, for thermal <strong>protection</strong> <strong>of</strong> 12.5 and 15 mm, <strong>concrete</strong> spalling<br />

only occurs in the case <strong>of</strong> loaded slabs. However, we want <strong>to</strong> emphasize that making a direct link<br />

between <strong>concrete</strong> spalling risk and the presence <strong>of</strong> a compressive loading is not that easy. Indeed,<br />

observations during the <strong>fire</strong> tests led us <strong>to</strong> distinguish two modes <strong>of</strong> rupture resulting on <strong>concrete</strong><br />

spalling:<br />

- 1- <strong>concrete</strong> spalling firstly occurs leading <strong>to</strong> the fall <strong>of</strong> the <strong>protection</strong> board. In such a case,<br />

we could directly link <strong>concrete</strong> spalling <strong>to</strong> the presence <strong>of</strong> a mechanical load,<br />

- 2- thermal <strong>protection</strong> board first falls resulting in a sudden exposure <strong>of</strong> "virgin" <strong>concrete</strong><br />

zones <strong>to</strong> <strong>fire</strong>. This mechanism also leads <strong>to</strong> <strong>concrete</strong> spalling but the influence <strong>of</strong> the<br />

mechanical loading seems <strong>to</strong> be more linked with the mechanical resistance <strong>of</strong> the thermal<br />

<strong>protection</strong> system (board and anchorages) itself. This behaviour has been also observed by<br />

[13].<br />

One main difficulty <strong>of</strong> the study is that these both types <strong>of</strong> rupture mode can occur during the same<br />

<strong>fire</strong> test. Further studies have <strong>to</strong> be performed in order <strong>to</strong> better analyse the influence <strong>of</strong> the<br />

mechanical loading on <strong>concrete</strong> spalling (e.g. by using a high velocity camera during <strong>fire</strong> tests).<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

0 mm<br />

(49 mm)<br />

8 mm<br />

(63 mm)<br />

12.5 mm<br />

(137 mm)<br />

Figure 6. Mapping and pictures <strong>of</strong> the <strong>exposed</strong> surface after HCM <strong>fire</strong> tests <strong>of</strong> loaded slabs (calcareous<br />

<strong>concrete</strong>) with thermal <strong>protection</strong> <strong>of</strong> 0 (unprotected), 8 and 12.5 mm. Between brackets is the maximal spalling<br />

depth.<br />

4.2 Thermal gradient analysis<br />

The thermal gradients developed in the <strong>concrete</strong> slabs <strong>of</strong> different constructions were determined<br />

experimentally by measuring temperature via thermocouples inserted from the surface in<strong>to</strong> the<br />

<strong>concrete</strong> at every 20 mm up <strong>to</strong> the cold side, and also calculated by finite elements modelling method.<br />

In a first step <strong>of</strong> the study, these values were analysed and compared for each construction tested by<br />

the two labora<strong>to</strong>ries. The thermal properties – thermal conductivity, specific heat and density<br />

evolution with temperature – <strong>of</strong> the <strong>concrete</strong>, were determined following the Eurocode 2 documents<br />

[14]; those <strong>of</strong> the <strong>protection</strong> boards were established by Promat labora<strong>to</strong>ries. The thermal gradient<br />

developed near the <strong>concrete</strong> surface is considered being the most critical one; the values were<br />

expressed as:<br />

Gradient = (T 20mm – T 0mm ) / 20 mm [°C/cm]<br />

Experimental thermal gradient: first <strong>of</strong> all, the values <strong>of</strong> temperatures measured in the two<br />

labora<strong>to</strong>ries were used <strong>to</strong> verify the similarities between the two furnaces as temperature<br />

developments and distribution during each trial (and these in comparison with the common calibration<br />

values <strong>of</strong> furnaces from the two labora<strong>to</strong>ries). Then, the values from the interface (or surface for the<br />

non protected constructions) through the <strong>concrete</strong> were used <strong>to</strong> search the correlation between the<br />

thermal gradients and the presence or absence <strong>of</strong> spalling. It was observed that the temperature values<br />

measured in the <strong>concrete</strong> in both labora<strong>to</strong>ries were in good agreement; on the contrary, the values<br />

measured at the interface by the thermocouples scales (depth zero) were slightly different. The<br />

interface temperatures measured at PROMAT are in better accordance with simulated values (see next<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

paragraph). Then, they were used for the establishment <strong>of</strong> the thermal gradients for the different tests.<br />

The gradients experimentally determined by this way are presented in Figure 7.<br />

Numerical thermal gradient: calculated thermal values were compared with the measured ones.<br />

Best fitting between the calculated and the measured experimental values was found when the FEM<br />

<strong>to</strong>ok in<strong>to</strong> consideration the dynamic change in thermal properties <strong>of</strong> materials with temperature<br />

increase and particularly the endothermic events (see § 2). The numerical simulations were done<br />

separately for both labora<strong>to</strong>ries and are related with the testing observations (spalling or no spalling<br />

and time <strong>of</strong> spalling). The Figure 7 presents the appearance <strong>of</strong> spalling (or absence <strong>of</strong> spalling) in a<br />

graph giving the relation between the thermal gradients and the thickness <strong>of</strong> the thermal <strong>protection</strong><br />

(including the tests without <strong>protection</strong>). Three distinct cases/zones were defined (Figure 8): zone 1<br />

including the case <strong>of</strong> non protected <strong>concrete</strong> or <strong>concrete</strong> protected with 8 mm PROMATECT® H<br />

developed spalling in both labora<strong>to</strong>ries; a zone 3 includes the cases <strong>of</strong> <strong>concrete</strong> protected with 20 and<br />

25 mm PROMATECT® T boards where no spalling was observed; and in between, a zone 2 that<br />

concerns slabs protected by 12.5 and 15 mm thick PROMATECT® T boards. In this zone, unloaded<br />

experiments demonstrated no spalling while loaded experiments have shown spalling. This is<br />

particularly in this zone that the two different modes <strong>of</strong> failure described at the § 4.1 were observed.<br />

Gradient [°C/cm]<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

spalling after 2/1.5 min<br />

at CSTB/PRTC<br />

spalling after 20/21 min<br />

at CSTB/PRTC<br />

no spalling at PRTC<br />

damage at CSTB<br />

(32min)<br />

Exp. Gradient at failure time determined by CSTB<br />

FEM gradient at failure time determined by CSTB<br />

Exp. Gradient at failure time determined by PRTC<br />

FEM gradient at failure time determined by PRTC<br />

no spalling at PRTC<br />

no spalling at CSTB<br />

0<br />

damage at CSTB (19min)<br />

no <strong>protection</strong><br />

8mm PT-H<br />

12.5mm PT-T<br />

15mm PT-T<br />

20mm PT-T<br />

25mm PT-T<br />

Type <strong>of</strong> thermal <strong>protection</strong><br />

Figure 7. Relation between thermal gradient, thickness <strong>of</strong> the <strong>protection</strong> and development <strong>of</strong> <strong>concrete</strong> spalling.<br />

Gradient [°C/cm]<br />

300<br />

250<br />

200<br />

150<br />

100<br />

50<br />

Zone 1<br />

0<br />

no <strong>protection</strong><br />

8mm PT-H<br />

12.5mm PT-T<br />

15mm PT-T<br />

20mm PT-T<br />

25mm PT-T<br />

Exp. Gradient at failure time determined by CSTB<br />

FEM gradient at failure time determined by CSTB<br />

Exp. Gradient at failure time determined by PRTC<br />

FEM gradient at failure time determined by PRTC<br />

Zone 2<br />

Zone 3<br />

Type <strong>of</strong> thermal <strong>protection</strong><br />

Figure 8. Definition <strong>of</strong> risk and safety zones; the intermediate zone 2 defines a questioning situation.<br />

4.3 Residual compressive strength <strong>of</strong> <strong>concrete</strong><br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

The assessment <strong>of</strong> the residual mechanical performance <strong>of</strong> <strong>concrete</strong> slabs has been carried out on<br />

drilled cores. The cores were drilled at different locations <strong>of</strong> the slabs several months after the <strong>fire</strong> test<br />

(see Figure 9). The first operation consisted in measuring the height <strong>of</strong> the core, allowing us <strong>to</strong><br />

determine the <strong>concrete</strong> spalling depth (operation in Figure 9). Small disks were then cut from the<br />

cores; the distance "x" from the interface between <strong>concrete</strong> and thermal <strong>protection</strong> board <strong>to</strong> the upper<br />

side <strong>of</strong> the cut disk was noted (operation in Figure 9). At last, a compression test was carried out in<br />

a direction parallel <strong>to</strong> the main heat flow in the slab (operation in Figure 9). The obtained<br />

compressive strength was assumed <strong>to</strong> be representative <strong>of</strong> the residual mechanical performance <strong>of</strong> the<br />

<strong>concrete</strong> at a distance "x" from the interface.<br />

Figure 9. Schematic representation <strong>of</strong> the testing procedure for the assessment <strong>of</strong> the residual compressive<br />

strength on drilled cores from <strong>fire</strong> tested slabs (blue zones correspond <strong>to</strong> ejected <strong>concrete</strong>).<br />

The different spalling depths that were measured on drilled cores (for a same slab, we present the<br />

minimal, maximal and mean measured spalling depths) are presented in Figure 10. The results are<br />

presented for different thermal <strong>protection</strong> board thicknesses. The main observations are as following:<br />

- by comparing the measurements <strong>of</strong> <strong>concrete</strong> spalling that were done just after the <strong>fire</strong> tests<br />

(red curves in Figure 10) and the measurements <strong>of</strong> <strong>concrete</strong> spalling that were done on drilled<br />

cores (i.e. several month after <strong>fire</strong> test), we can observe that the departure <strong>of</strong> cover <strong>concrete</strong><br />

can continue even after a long period following a <strong>fire</strong>. This phenomenon is particularly true in<br />

the case <strong>of</strong> the silico-calcareous <strong>concrete</strong>. This "post-<strong>fire</strong>" <strong>concrete</strong> departure can be explained<br />

by different mechanisms (inverse thermal gradient during cooling down that induces tensile<br />

stresses in the cover <strong>concrete</strong> zones, "re-hydration" or "re-humidification" <strong>of</strong> the <strong>concrete</strong> that<br />

can result in swelling and falling <strong>of</strong> the material…) and appears as a main fac<strong>to</strong>r <strong>to</strong> take in<strong>to</strong><br />

account for the post-<strong>fire</strong> assessing <strong>of</strong> a <strong>concrete</strong> structure. Indeed, this cover <strong>concrete</strong><br />

departure can play a role for the residual mechanical performance <strong>of</strong> the structure (decrease <strong>of</strong><br />

the resistive cross-section) as well for its durability (decrease <strong>of</strong> reinforcement <strong>protection</strong><br />

regarding <strong>to</strong> aggressive fac<strong>to</strong>rs),<br />

- the measurements confirm the tendencies observed just after the <strong>fire</strong> test (see § 4.1): the<br />

absence, or the under sizing <strong>of</strong> the thermal <strong>protection</strong> (from 8 <strong>to</strong> 15 mm in our study),<br />

involves and important spalling <strong>of</strong> cover <strong>concrete</strong>. Moreover, the measurements confirm the<br />

fact that in the case <strong>of</strong> an under sized thermal <strong>protection</strong>, <strong>concrete</strong> spalling can be deeper than<br />

for a slab without <strong>protection</strong>,<br />

- a thermal <strong>protection</strong> that is correctly designed (20 and 25 mm in our study) allows avoiding<br />

<strong>concrete</strong> spalling, even after a long period after the <strong>fire</strong>.<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

Spalling depth [mm]<br />

120<br />

100<br />

80<br />

60<br />

40<br />

t0 spalling - calcareous<br />

t0 spalling - siliceous<br />

tmini spalling - calcareous<br />

tmini spalling - siliceous<br />

tmean spalling -calcareous<br />

tmean spalling -siliceous<br />

tmaxi spalling - calcareous<br />

tmaxi spalling - siliceous<br />

20<br />

0<br />

0 5 10 15 20 25 30<br />

Thermal <strong>protection</strong> boards thickness [mm]<br />

Figure 10. Measurements <strong>of</strong> the spalling depth <strong>of</strong> <strong>concrete</strong> on drilled cores from <strong>fire</strong>s tested slabs according <strong>to</strong><br />

the thermal <strong>protection</strong> board thickness and the type <strong>of</strong> <strong>concrete</strong> (blue curves). The red curves (t0 spalling)<br />

correspond <strong>to</strong> the measurements on <strong>concrete</strong> slabs just after the <strong>fire</strong> test.<br />

The measurements <strong>of</strong> the residual compressive strength <strong>of</strong> <strong>concrete</strong> at different depths <strong>of</strong> the <strong>fire</strong>d<br />

slabs are presented in<br />

Figure 11. The main observations are as following:<br />

- in the case <strong>of</strong> slabs without thermal <strong>protection</strong> and in the case <strong>of</strong> slabs with under sized<br />

thermal <strong>protection</strong> (from 8 <strong>to</strong> 15 mm in our study), the residual mechanical performance<br />

decreases when approaching the interface between the <strong>concrete</strong> and the <strong>protection</strong> board.<br />

Indeed, residual compressive strengths are twice or three times lower close <strong>to</strong> the interface<br />

than in a zone where we can consider that <strong>concrete</strong> is still "healthy" (at more than 100 mm<br />

from the interface),<br />

- for well designed thermal <strong>protection</strong> (20 and 25 mm in our study), the residual compressive<br />

strength does not vary along the depth <strong>of</strong> the slab. Indeed, the strengths that are measured<br />

close at the interface (these measurements are only possible in that case <strong>of</strong> thermal <strong>protection</strong><br />

since <strong>concrete</strong> spalling does not occur) are quite similar with the ones that are measured in the<br />

"healthy" zone.<br />

60<br />

Residual compressive strength vs <strong>concrete</strong> depth<br />

Compressive stregth [Mpa]<br />

50<br />

40<br />

calcareous_no <strong>protection</strong><br />

30<br />

siliceous_no <strong>protection</strong><br />

calcareous_8 mm<br />

20<br />

siliceous_8 mm<br />

calcareous_15 mm<br />

10<br />

calcareous_20 mm<br />

calcareous_25 mm<br />

0<br />

0 20 40 60 80 100 120 140 160 180 200<br />

interface <strong>concrete</strong> slab /<br />

thermal <strong>protection</strong> board<br />

Concrete depth [mm]<br />

Figure 11. Residual compressive strength <strong>of</strong> <strong>concrete</strong> measured on cut drilled cores at different depth <strong>of</strong> the<br />

<strong>concrete</strong> slab. Results for both types <strong>of</strong> <strong>concrete</strong>s and different thicknesses <strong>of</strong> thermal <strong>protection</strong>.<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

5. Conclusions<br />

This study was carried out thanks <strong>to</strong> the joint action <strong>of</strong> two labora<strong>to</strong>ries: PRTC in Belgium and CSTB<br />

in France. Its main goal was the optimization <strong>of</strong> the calcium alumina silicates thermal <strong>protection</strong><br />

PROMATECT® for <strong>concrete</strong> <strong>structures</strong> that are <strong>exposed</strong> <strong>to</strong> <strong>fast</strong> <strong>fire</strong>s (HCM <strong>fire</strong> in this study).<br />

Fire tests were then carried out in both labora<strong>to</strong>ries in order <strong>to</strong> analyse the influence <strong>of</strong> several<br />

parameters on <strong>concrete</strong> spalling: thickness <strong>of</strong> the thermal <strong>protection</strong> boards, type <strong>of</strong> <strong>concrete</strong> (2 types<br />

<strong>of</strong> aggregate) and type <strong>of</strong> mechanical loading (no loading and compressive loading). The main<br />

conclusions are as following:<br />

- Under the HCM <strong>fire</strong> curve, all the slabs that were not protected showed important spalling.<br />

One consequence <strong>of</strong> this spalling is the direct exposition <strong>to</strong> <strong>fire</strong> <strong>of</strong> the reinforcement, which<br />

can imply failure <strong>of</strong> the structure. In the same way, if the thermal <strong>protection</strong> is under sized<br />

(from 8 <strong>to</strong> 15 mm in our study), <strong>concrete</strong> spalling can also occur. An important result is that<br />

<strong>concrete</strong> spalling for under sized thermal <strong>protection</strong>s can be more severe than unprotected<br />

slabs.<br />

- A correct design <strong>of</strong> the thermal <strong>protection</strong> (20 and 25 mm in our study) allows avoiding the<br />

<strong>concrete</strong> spalling.<br />

- No clear influence <strong>of</strong> the type <strong>of</strong> aggregate has been observed. Calcareous <strong>concrete</strong> showed<br />

more pronounced spalling than silico-calcareous <strong>concrete</strong> for <strong>fire</strong> tests without loading. The<br />

inverse tendency was observed for loaded <strong>fire</strong> tests.<br />

- The influence <strong>of</strong> the type <strong>of</strong> loading on <strong>concrete</strong> spalling was not easily interpreted. Indeed,<br />

two types <strong>of</strong> failure have been observed during the <strong>fire</strong> tests and both <strong>of</strong> them can occur<br />

during the same test: either <strong>concrete</strong> first spalls involving the fall <strong>of</strong> the thermal <strong>protection</strong>, or<br />

the thermal <strong>protection</strong> system (board + anchorages) falls involving a sudden exposure <strong>to</strong> <strong>fire</strong><br />

<strong>of</strong> virgin <strong>concrete</strong> (and then spalling). Further observations are needed <strong>to</strong> better analyse the<br />

influence <strong>of</strong> the type <strong>of</strong> loading.<br />

In this study, we made a link between <strong>concrete</strong> spalling and the induced thermal gradient in the first<br />

centimetres <strong>of</strong> the slab. This approach is assumed <strong>to</strong> be reliable if one regards the severity <strong>of</strong> such a<br />

<strong>fast</strong> <strong>fire</strong> (HCM curve). Thermal gradient was first assessed in an experimental way, by taking in<strong>to</strong><br />

account the temperature measurements <strong>of</strong> both labora<strong>to</strong>ries at the interface between the <strong>concrete</strong> slab<br />

and the <strong>protection</strong> board and the measurement <strong>of</strong> the temperature at 20 mm in<strong>to</strong> the <strong>concrete</strong> slab.<br />

Temperatures that were measured inside <strong>concrete</strong> appeared very similar between both labora<strong>to</strong>ries<br />

while the interface temperature showed slight differences. The use <strong>of</strong> numerical simulations, by mean<br />

<strong>of</strong> finite elements s<strong>of</strong>tware, allowed us <strong>to</strong> better evaluate the interface temperature and then <strong>to</strong> assess<br />

the thermal gradient in <strong>concrete</strong> at the moment just before <strong>concrete</strong> spalling. By this way, three zones<br />

have been identified:<br />

- Zone 1: in this zone, <strong>concrete</strong> spalling risk is high. In our study, this zone concerns the slabs<br />

without <strong>protection</strong> and the slabs protected with an 8 mm thick board.<br />

- Zone 2: this zone appears <strong>to</strong> be a "grey" zone i.e. no clear conclusion can be made concerning<br />

<strong>concrete</strong> spalling risk. More observations are needed. In our study, this zone concerns the<br />

slabs protected with a 12.5 and 15 mm thick board.<br />

- Zone 3: this zone can be considered as a "safe" zone. No <strong>concrete</strong> spalling is observed during<br />

the <strong>fire</strong>. In our study, this zone concerns the slabs a 20 and 25 mm thick board.<br />

A major aspect <strong>of</strong> the study <strong>of</strong> the behaviour <strong>of</strong> <strong>fire</strong>d <strong>concrete</strong> structure is the assessment <strong>of</strong> the<br />

residual mechanical properties (i.e. just after cooling and after a long period following the <strong>fire</strong>). In this<br />

study, the residual compressive strength <strong>of</strong> <strong>concrete</strong> has been measured on drilled cores that were<br />

taken out from the slabs several months after the <strong>fire</strong> test (only for loaded slabs). An original<br />

experimental method allowed us evaluating the residual mechanical performance <strong>of</strong> the slabs<br />

depending on the thermal <strong>protection</strong> thickness and on the type <strong>of</strong> <strong>concrete</strong> (nature <strong>of</strong> the aggregates).<br />

The main observations are as following:<br />

- An under sizing (from 8 <strong>to</strong> 15 mm in our study), or an absence, <strong>of</strong> the thermal <strong>protection</strong><br />

involves an important decrease <strong>of</strong> the residual mechanical performance <strong>of</strong> the <strong>concrete</strong>. This<br />

is particularly true for cover <strong>concrete</strong>. This loss <strong>of</strong> compressive strength, that we assume <strong>to</strong> be<br />

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Fourth International Symposium on Tunnel Safety and Security, Frankfurt am Main, Germany, March 17-19, 2010<br />

representative <strong>of</strong> the damage state <strong>of</strong> the structure, implied a decrease <strong>of</strong> the whole structure<br />

resistance and a decrease <strong>of</strong> its durability.<br />

- A correct design <strong>of</strong> the thermal <strong>protection</strong> (20 and 25 mm in our study) allows minimizing the<br />

mechanical damage <strong>of</strong> the whole <strong>concrete</strong> slab during <strong>fire</strong> (even for the cover <strong>concrete</strong>). Then<br />

the advantage <strong>of</strong> these <strong>protection</strong>s not only comes from the suppression <strong>of</strong> <strong>concrete</strong> spalling<br />

risk but also from the preservation <strong>of</strong> the mechanical performances <strong>of</strong> a <strong>fire</strong>d <strong>concrete</strong><br />

structure. This is particularly an advantage in the case <strong>of</strong> <strong>fire</strong>d tunnels, in terms <strong>of</strong> financial<br />

and time needs for the structure repairing.<br />

To conclude, the importance <strong>of</strong> the <strong>fire</strong> <strong>protection</strong> relies on its quality and its thickness. These aspects<br />

are strictly dependent on the product design. In particular, the results that are presented in this paper<br />

can not be directly extended <strong>to</strong> other similar thermal <strong>protection</strong> products, other types <strong>of</strong> <strong>concrete</strong> or<br />

other <strong>fire</strong> curves.<br />

6. Acknowledgments<br />

The authors acknowledge the staff <strong>of</strong> both labora<strong>to</strong>ries for their participation <strong>to</strong> this experimental<br />

research.<br />

7. References<br />

[1] Haack, A. Catastrophic Tunnel Fires - What have we learnt? International symposium on catastrophic tunnel<br />

<strong>fire</strong>s (CTF). Boras, Sweden, 2003.<br />

[2] Jansson R. and Bostrom L. Experimental study on the influence <strong>of</strong> polypropylene fibres on material<br />

properties and <strong>fire</strong> spalling <strong>of</strong> <strong>concrete</strong>. fib task group 4.3 workshop "Fire design o <strong>concrete</strong> <strong>structures</strong> -<br />

from materials modelling <strong>to</strong> structural performance". Coimbra, Portugal, 2007.<br />

[3] Kalifa, P., G. Chéné, and Gallé C. "High-temperature behaviour <strong>of</strong> HPC with polypropylene fibres: From<br />

spalling <strong>to</strong> microstructure." Cement and Concrete Research 31(10): 1487-1499, 2001.<br />

[4] Schrefler, B. A., G. A. Khoury, Gawin D. and Majorana C.E. "Thermo-hydro-mechanical modelling <strong>of</strong> high<br />

performance <strong>concrete</strong> at high temperatures." Engineering Computations 19(7-8): 787-819, 2002.<br />

[5] Ulm, F.-J., P. Acker, and Levy M. "The ``Chunnel'' Fire. II: Analysis <strong>of</strong> Concrete Damage." Journal <strong>of</strong><br />

Engineering Mechanics 125(3): 283-289, 1999.<br />

[6] Mindeguia J.C., "Contribution expérimentale à la compréhension du risqué d'instabilité thermique des<br />

bé<strong>to</strong>ns", PhD thesis, University <strong>of</strong> Pau, France, 2009.<br />

[7] Khoury G.A. and Anderberg Y. Concrete spalling - Review, Fire Safety Design, 2000.<br />

[8] Bazant, Z. P., G. Cusatis, and Cedolin L. "Temperature Effect on Concrete Creep Modelled by<br />

Microprestress-Solidification Theory." Journal <strong>of</strong> Engineering Mechanics 130(6): 691-699, 2004.<br />

[9] Sercombe, J., C. Galle, Durand S.F., and Bouniol P. On the importance <strong>of</strong> thermal gradients in the spalling<br />

<strong>of</strong> high-strength <strong>concrete</strong> 14th Engineering Mechanics Conference Austin, USA, 2000.<br />

[10] Harmathy, T. Z. Effect <strong>of</strong> moisture on the <strong>fire</strong> endurance <strong>of</strong> building elements. Research paper 270. Ottawa,<br />

Division <strong>of</strong> Building Research, 1965.<br />

[11] Phan L.T. High-Strength Concrete at High Temperature: An Overview. Utilization <strong>of</strong> High Strength/High<br />

Performance Concrete, 6th International Symposium. Leipzig, Germany, 2002.<br />

[12] Mindeguia J.C., Pimienta P., Carré H. and La Borderie C., "On the influence <strong>of</strong> aggregate nature on<br />

<strong>concrete</strong> behaviour at high temperature", paper submitted <strong>to</strong> the European Journal <strong>of</strong> Environmental and<br />

Civil Engineering, January 2010.<br />

[13] Bostrom L., Larsen C. K., "Concrete for tunnel linings <strong>exposed</strong> <strong>to</strong> severe <strong>fire</strong> exposure", Fire Technology,<br />

42, 351-362, 2006.<br />

[14] CEN (2004). Eurocode 2: calcul des <strong>structures</strong> en bé<strong>to</strong>n - Partie 1-2: Règles générales - Calcul du<br />

comportement au feu.<br />

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