Safety Data Sheet - Kiehl-Group

Safety Data Sheet 

J O H A N N E S K I E H L 

K G 

according to Regulation (EC) No 1907/2006 

Blutoxol 

Print date: 13.05.2013 Product code: j5503_sd 

Page 1 of 8 

SECTION 1: Identification of the substance/mixture and of the company/undertaking 

1.1. Product identifier 

Blutoxol 

1.2. Relevant identified uses of the substance or mixture and uses advised against 

Use of the substance/mixture 

Liquid disinfectant cleaner concentrate for the food area 

1.3. Details of the supplier of the safety data sheet 

Company name: 

Street: 

Place: 

Post-office box: 


Robert-Bosch-Str. 9 

D-85235 Odelzhausen 

15 

D-85233 Odelzhausen 

Telephone: +49 8134 9305.0 Telefax:+49 8134 6466 

e-mail: 

K G 

joachim.dr-gross@kiehl-group.com 

Contact person: Dr. Joachim Gross 

Telephone: +49 8134 9305-36 

Responsible Department: 

1.4. Emergency telephone 

number: 

Notrufnummer für deutsch- und englischsprachige Länder: +49/89/19240 

Nationale Notrufnummer für die Schweiz (Tox-Zentrum Zürich): 145 

Numéro d'urgence France: INRS: +33 (0) 1 45 42 59 59 

Numero d' emergenza Italia: Centro Antiveleni - 20162 Milano: 02/66101029 

ETTSZ /Egészségügyi Toxikológiai Tájékoztató Szolgálat/, 1096 Budapest, 

Nagyvárad tér 2. Ügyeleti telefonszám: 476-64-00, 476-64-64 

Eesti: Häirekeskuse number: 112 / Mürgistusteabekeskuse number: 16662 

Romania: Institutul National de Sanatate Publica: Tel. de urgenta: 021/3183606 

Emergency telephone number for all other countries: +49/8134/9305-36 

+49/89/19240 (germanophone and anglophone) 

KIEHL Austria GmbH Perfektastr. 57 / Top 3; A-1230 Wien Tel. +43 (0) 1 / 604 99 93 

KIEHL FRANCE S.A.R.L. 1, Rue de l´industrie - B.P. 54; F-67172 Brumath Cedex Tél. +33 (0) 3.88.59.52.25 

KIEHL Italia s.r.l. Via Michelangelo 29; I-16036 Avegno (GE) Tel. +39 / 0185 730 008 

KIEHL Schweiz AG St. Dionys-Str. 33; CH-8645 Jona Tel. +41 (0) 55 / 254 74 74 

Johannes Kiehl KG Ganz Ábrahám ucta 4/12, H-2142 Nagytarcsa Tel. +36 (0) 1 / 348-08 41 

KIEHL Middle East L.L.C. P.O. Box 11 40 19 Abu Dhabi, U.A.E. Tel. +971 2 550 33 96 

SECTION 2: Hazards identification 

2.1. Classification of the substance or mixture 

2.2. Label elements 

Indications of danger: Xi - Irritant, N - Dangerous for the environment 

R phrases: 

Irritating to skin. 

Risk of serious damage to eyes. 

Very toxic to aquatic organisms. 

Danger symbols: 

Xi - Irritant; N - Dangerous for the environment 

Xi - Irritant 

N - Dangerous for the 

environment 

Revision No: 1,07 GB - EN 

Revision date: 18.02.2011



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Blutoxol 


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R phrases 

38 Irritating to skin. 

41 Risk of serious damage to eyes. 

50 Very toxic to aquatic organisms. 

S phrases 

26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 

61 Avoid release to the environment. Refer to special instructions / Safety data sheets. 

24/25 Avoid contact with skin and eyes. 

37/39 Wear suitable gloves and eye/face protection. 

SECTION 3: Composition/information on ingredients 

(according to 648/2004/CE) 

3.2. Mixtures 

Chemical characterization 

nonionic surfactants



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After ingestion 

Drink plenty of water. Do NOT induce vomiting. If symptoms persist, call a physician. 

4.3. Indication of any immediate medical attention and special treatment needed 

If you feel unwell, seek medical advice (show the label where possible). 

Show this safety data sheet to the doctor in attendance. 

SECTION 5: Firefighting measures 

5.1. Extinguishing media 

Suitable extinguishing media 

Any extinguishing means and measures are acceptable. 

5.2. Special hazards arising from the substance or mixture 

This information is not available. 

5.3. Advice for firefighters 

Use extinguishing measures that are appropriate to local circumstances and the surrounding 

environment. The product itself does not burn. 

SECTION 6: Accidental release measures 

6.1. Personal precautions, protective equipment and emergency procedures 

Avoid contact with skin and eyes. 

6.2. Environmental precautions 

Do not flush into surface water. 

6.3. Methods and material for containment and cleaning up 

Wipe up with absorbent material (e.g. cloth, fleece). After cleaning, flush away traces with water. 

Never return spills in original containers for re-use. 

6.4. Reference to other sections 

Refer to protective measures listed in sections 7 and 8. 

SECTION 7: Handling and storage 

7.1. Precautions for safe handling 

Advice on safe handling 

Avoid contact with skin and eyes. 

Smoking, eating and drinking should be prohibited in the application area. 

Wash hands after handling. 

Advice on protection against fire and explosion 

Not required 

7.2. Conditions for safe storage, including any incompatibilities 

Requirements for storage rooms and vessels 

Store at room temperature in the original container. Store in a place accessible by authorized persons 

only. 

Advice on storage compatibility 

Keep away from food, drink and animal feedingstuffs. 

Do not store near acids. 

Further information on storage conditions 

Keep container tightly closed. 

Never return unused material to storage receptacle. 

7.3. Specific end use(s) 






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SECTION 8: Exposure controls/personal protection 

8.1. Control parameters 

8.2. Exposure controls 

Occupational exposure controls 

Not required 

Protective and hygiene measures 

Handle in accordance with good industrial hygiene and safety practice. 

Use protective skin cream before handling the product. 

Hand protection 

Protective gloves 

Recommendation: Nature latex gloves with parts of polychloropren latex and a coating thickness of 0.6 

mm which protect at least 8 hours (corresponds to the permeability level 6 of the European norm 

DIN/EN 374) and provide a resistance to swelling of < 15%. 

Eye protection 

Safety glasses with side-shields. 

SECTION 9: Physical and chemical properties 

9.1. Information on basic physical and chemical properties 

Physical state: 

Colour: 

Odour: 

liquid 

light red 

characteristic 

Test method 

pH-Value (at 20 °C): 13 K-QP1012C 

Changes in the physical state 

Melting point: 

Boiling point: 

Sublimation point: 

Softening point: 

Flash point: 

Flammability 

Solid: 

Gas: 

98 °C 

not applicable 


>100 °C 



Lower explosion limits: 

Upper explosion limits: 

Ignition temperature: 

Auto-ignition temperature 

Solid: 

Gas: 

Vapour pressure: 



>300 °C 



not determined 

Density (at 20 °C): 1,03 g/cm³ K-QP1012E 

Water solubility: 

completely miscible 

(at 20 °C) 

Solubility in other solvents 


Partition coefficient: 






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Viscosity / dynamic: 

Viscosity / kinematic: 

Vapour density: 

Evaporation rate: 





9.2. Other information 

Solid content: 


SECTION 10: Stability and reactivity 

10.1. Reactivity 


10.2. Chemical stability 


10.3. Possibility of hazardous reactions 


10.4. Conditions to avoid 

Do not expose to temperatures above 35 °C. 

10.5. Incompatible materials 


10.6. Hazardous decomposition products 

No decomposition if stored and applied as directed. 

Further information 

Do not mix with other detergents or chemicals. 

SECTION 11: Toxicological information 

11.1. Information on toxicological effects 

Acute toxicity 

Acute oral toxicity (LD50): 14760 mg/kg (rat) 

Acute dermal toxicity (LD50): 133680 mg/kg (rabbit) 

CAS No 

Chemical name 

Exposure routes 

Method 

Dose 

Species 

Source 

69011-36-5 i-C13-Fatty alcohol polyglycol ethers 5-12 EO 

oral 

ATE 

500 mg/kg 

7173-51-5 didecyldimethylammonium chloride 

oral 

LD50 

658 mg/kg 

rat 

dermal 

68391-01-5 C12-C16-Dimethylbenzyl ammonium chloride 

LD50 >2000 

mg/kg 

rat 

oral 

dermal 

ATE 

ATE 

500 mg/kg 

1100 mg/kg 

Additional information on tests 

Classification according to European directive on classification of hazardous preparations 1999/45/EC. 


Irritating to eyes and skin. 

Health injuries are not known or expected under normal use. 





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SECTION 12: Ecological information 

12.1. Toxicity 

CAS No 

7173-51-5 

Toxicity to fish (LC50): 38,6 mg/l (Oncorhynchus mykiss (rainbow trout)) 

Toxicity to fish (NOEC): 1,28 mg/l (Brachydanio rerio (zebra fish)) 

LC50/96h/bluegill sunfish = 20,6 mg/l 

EC50/48h/daphnia = 2,00 mg/l 

Toxicity to daphnia (NOEC): 0,284 mg/l (Daphnia magna (Water flea)) 

EC50/96h/green algae = 1,50 mg/l 

Toxicity to bacteria (EC50): 375 mg/l 

EC10/18h/bacteria = 5,20 mg/l 

Toxicity to soil dwelling organisms.: 161400 mg/kg (Eisenia fetida (earthworms)) 

Chemical name 

Aquatic toxicity Method Dose h Species 

Source 

didecyldimethylammonium chloride 

Acute fish toxicity LC50 0,97 mg/l 96 Brachydanio rerio (zebra 

fish) 

Acute algae toxicity ErC50 0,12 mg/l 96 Scenedesmus 

capricornutum (fresh water 

algae) 

Acute crustacea toxicity EC50 0,06 mg/l 48 Daphnia 

12.2. Persistence and degradability 

Contains no substances known to be hazardous to the environment or not degradable in waste water 

treatment plants. The surfactants in the product meet all requirements of the detergents regulation 

648/2004/EC. 

12.3. Bioaccumulative potential 


12.4. Mobility in soil 


12.5. Results of PBT and vPvB assessment 


12.6. Other adverse effects 



Chemical Oxygen Demand (COD) 340 mg O2/g. 

Cationic compounds are biodegradable only in high dilution. They are adequate diluted in sewage and 

become inactive through contact with other waste-water substances. Therefore solutions could be 

disposed of in the sewerage system. 

SECTION 13: Disposal considerations 

13.1. Waste treatment methods 

Advice on disposal 

Container should be emptied thoroughly. Do not pour remains of product in large quantities into the 

sewage. 

Waste disposal number of waste from residues/unused products 

070699 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats, grease, soaps, 

detergents, disinfectants and cosmetics; wastes not otherwise specified 

Waste disposal number of used product 





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070699 

WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats, grease, soaps, 

detergents, disinfectants and cosmetics; wastes not otherwise specified 

Contaminated packaging 

Clean container with water. Cans or containers must be cleaned and returned to the manufacturers for 

recycling. 

SECTION 14: Transport information 

Land transport (ADR/RID) 

14.1. UN number: 

14.2. UN proper shipping name: 

14.3. Transport hazard class(es): 

14.4. Packing group: 

Hazard label: 

3082 

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 

(Quaternary ammonium compounds) 

9 

III 

9 

Classification code: 

M6 

Special Provisions: 274, 335, 601 

Limited quantity: 

LQ7 

Transport category: 3 

Hazard No: 

Tunnel restriction code: 

90 

E 

Other applicable information (land transport) 

E1 

Marine transport (IMDG) 

14.1. UN number: 

14.2. UN proper shipping name: 

14.3. Transport hazard class(es): 

14.4. Packing group: 

Hazard label: 

3082 

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. 

(quaternary ammonium compounds) 

9 

III 

9 

Special Provisions: 

Limited quantity: 

EmS: 

Other applicable information (marine transport) 

E1 

14.5. Environmental hazards 

Dangerous for the environment: 

179, 274, 335, 909 

5 L 

F-A, S-F 

yes 

14.6. Special precautions for user 

Not required 





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14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code 

Not relevant 

Other applicable information 

The product, filled in cartons of 2 x 5 litre containers is not subject to transport regulations and 

therefore has not to be considered a hazardous material. 

SECTION 15: Regulatory information 

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 

National regulatory information 

Water contaminating class (D): 

15.2. Chemical safety assessment 

2 - water contaminating 

Chemical safety assessments for substances in this mixture were not carried out. 

SECTION 16: Other information 

Full text of R phrases referred to under Sections 2 and 3 

21/22 Harmful in contact with skin and if swallowed. 

22 Harmful if swallowed. 

34 Causes burns. 

38 Irritating to skin. 

41 Risk of serious damage to eyes. 

50 Very toxic to aquatic organisms. 

Full text of H statements referred to under Sections 2 and 3 

H302 

Harmful if swallowed. 

H312 

Harmful in contact with skin. 

H314 

Causes severe skin burns and eye damage. 

H318 

Causes serious eye damage. 

H400 

Very toxic to aquatic life. 

Further Information 

This data sheet contains changes from the previous version in section(s): 4 / 7 / 8 

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety 

data sheet.)

Safety Data Sheet - Kiehl-Group

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