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Spin, Isospin and Strong Interaction Dynamics - Progress in Physics

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Volume 4 PROGRESS IN PHYSICS October, 2011<br />

A motionless free electron is the simplest case <strong>and</strong> the<br />

sp<strong>in</strong>-up electron state is [4, see p. 10]<br />

ψ(x µ ) = Ce −imt ⎛⎜⎝<br />

1<br />

0<br />

0<br />

0<br />

⎞<br />

, (1)<br />

⎟⎠<br />

where m denotes the electron’s mass.<br />

A second example is the state of an electron bound to a<br />

hypothetical po<strong>in</strong>tlike very massive positive charge. Here the<br />

electron is bound to a spherically symmetric charge Ze. The<br />

general form of a j π hydrogen atom wave function is [5, see<br />

pp. 926–927]<br />

( ) FY<br />

ψ(rθϕ) = jlm<br />

, (2)<br />

GY jl ′ m<br />

where Y jlm denotes the ord<strong>in</strong>ary Y lm coupled with a sp<strong>in</strong>-1/2<br />

to j, j = l ± 1/2, l ′ = l ± 1, F, G are radial functions <strong>and</strong> the<br />

parity is (−1) l .<br />

By the general laws of electrodynamics, the state must be<br />

an eigenfunction of angular momentum <strong>and</strong> parity. Furthermore,<br />

here we have a problem of one electron (the source at<br />

the orig<strong>in</strong> is treated as an <strong>in</strong>ert object) <strong>and</strong> <strong>in</strong>deed, its wave<br />

function (2) is an eigenfunction of both angular momentum<br />

<strong>and</strong> parity [5, see p. 927].<br />

The next problem is a set of n-electrons bound to an attractive<br />

positive charge at the orig<strong>in</strong>. (This is a k<strong>in</strong>d of an<br />

ideal atom where the source’s volume <strong>and</strong> sp<strong>in</strong> are ignored.)<br />

Obviously, the general laws of electrodynamics hold <strong>and</strong> the<br />

system is represented by an eigenfunction of the total angular<br />

momentum <strong>and</strong> parity J π . Here a s<strong>in</strong>gle electron is affected by<br />

a spherically symmetric attractive field <strong>and</strong> by the repulsive<br />

fields of the other electrons. Hence, a s<strong>in</strong>gle electron does not<br />

move <strong>in</strong> a spherically symmetric field <strong>and</strong> it cannot be represented<br />

by a well def<strong>in</strong>ed s<strong>in</strong>gle particle angular momentum<br />

<strong>and</strong> parity.<br />

The general procedure used for solv<strong>in</strong>g this problem is to<br />

exp<strong>and</strong> the overall state as a sum of configurations. In every<br />

configuration, the electrons’ s<strong>in</strong>gle particle angular momentum<br />

<strong>and</strong> parity are well def<strong>in</strong>ed. These angular momenta are<br />

coupled to the overall angular momentum J <strong>and</strong> the product<br />

of the s<strong>in</strong>gle particle parity is the parity of the entire system.<br />

The role of configurations has already been recognized <strong>in</strong> the<br />

early decades of quantum physics [6]. An application of the<br />

first generation of electronic computers has provided a numerical<br />

proof of the vital role of f<strong>in</strong>d<strong>in</strong>g the correct configuration<br />

<strong>in</strong>teraction required for a description of even the simplest<br />

case of the ground state of the two electron He atom [7].<br />

The result has proved that several configurations are required<br />

for a good description of this state <strong>and</strong> no configuration dom<strong>in</strong>ates<br />

the others. This issue plays a very important role <strong>in</strong> the<br />

<strong>in</strong>terpretation of the state of the proton <strong>and</strong> of the ∆ ++ .<br />

For example, let us write down the 0 + ground state He g of<br />

the Helium atom as a sum of configurations:<br />

ψ(He g ) = f 0 (r 1 ) f 0 (r 2 ) 1 + 1 +<br />

2 2<br />

+ f 1 (r 1 ) f 1 (r 2 ) 1 − 1 −<br />

2 2<br />

+<br />

f 2 (r 1 ) f 2 (r 2 ) 3 − 3 −<br />

2 2<br />

+ f 3 (r 1 ) f 3 (r 2 ) 3 + 3 +<br />

2 2<br />

+<br />

f 4 (r 1 ) f 4 (r 2 ) 5 + 5 +<br />

2 2<br />

+ . . .<br />

Here <strong>and</strong> below, the radial functions f i (r), g i (r) <strong>and</strong> h i (r)<br />

denote the two-component Dirac radial wave function (multiplied<br />

be the correspond<strong>in</strong>g coefficients). In order to couple<br />

to J = 0 the two s<strong>in</strong>gle particle j states must be equal<br />

<strong>and</strong> <strong>in</strong> order to make an even total parity both must have the<br />

same parity. These requirements make a severe restriction on<br />

acceptable configurations needed for a description of the 0 +<br />

ground state of the He atom.<br />

Higher two-electron total angular momentum allows the<br />

usage of a larger number of acceptable configurations. For<br />

example, the J π = 1 − state of the He atom can be written as<br />

follows:<br />

ψ(He 1 −) = g 0 (r 1 )h 0 (r 2 ) 1 + 1 −<br />

2 2<br />

+ g 1 (r 1 )h 1 (r 2 ) 1 + 3<br />

2 2<br />

g 2 (r 1 )h 2 (r 2 ) 1 − 3 +<br />

2 2<br />

+ g 3 (r 1 )h 3 (r 2 ) 3 − 3<br />

2 2<br />

g 4 (r 1 )h 4 (r 2 ) 3 − 5 +<br />

2 2<br />

+ g 5 (r 1 )h 5 (r 2 ) 3 + 5<br />

2 2<br />

g 6 (r 1 )h 6 (r 2 ) 5 + 5 −<br />

2 2<br />

. . .<br />

−<br />

+<br />

+<br />

+<br />

−<br />

+<br />

Us<strong>in</strong>g the same rules one can apply simple comb<strong>in</strong>atorial<br />

calculations <strong>and</strong> f<strong>in</strong>d a larger number of acceptable configurations<br />

for a three or more electron atom. The ma<strong>in</strong> conclusion<br />

of this section is that, unlike a quite common belief, there are<br />

only three restrictions on configurations required for a good<br />

description of a J π state of more than one Dirac particles:<br />

(3)<br />

(4)<br />

1. Each configuration must have the total angular momentum<br />

J.<br />

2. Each configuration must have the total parity π.<br />

3. Follow<strong>in</strong>g the Pauli exclusion pr<strong>in</strong>ciple, each configuration<br />

should not conta<strong>in</strong> two or more identical s<strong>in</strong>gle<br />

particle quantum states of the same Dirac particle.<br />

These restrictions <strong>in</strong>dicate that a state can be written as a sum<br />

of many configurations, each of which has a well def<strong>in</strong>ed s<strong>in</strong>gle<br />

particles angular momentum <strong>and</strong> parity of its Dirac particles.<br />

The mathematical basis of this procedure is as follows.<br />

Take the Hilbert sub-space made of configurations that satisfy<br />

the three requirements mentioned above <strong>and</strong> calculate<br />

the Hamiltonian matrix. A diagonalization of this Hamiltonian<br />

yields eigenvalues <strong>and</strong> eigenstates. These eigenvalues<br />

<strong>and</strong> eigenstates are related to a set of physical states that have<br />

the given J π . As po<strong>in</strong>ted out above, calculations show that<br />

for a quite good approximation to a quantum state one needs<br />

a not very small number of configurations <strong>and</strong> that no configuration<br />

has a dom<strong>in</strong>ant weight. These conclusions will be<br />

used later <strong>in</strong> this work.<br />

56 Eliahu Comay. <strong>Sp<strong>in</strong></strong>, <strong>Isosp<strong>in</strong></strong> <strong>and</strong> <strong>Strong</strong> <strong>Interaction</strong> <strong>Dynamics</strong>

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