MATERIAL SAFETY DATA SHEET - Star brite
MATERIAL SAFETY DATA SHEET - Star brite
MATERIAL SAFETY DATA SHEET - Star brite
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<strong>MATERIAL</strong> <strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
1. Product and Company Identification<br />
Material name<br />
Version # 01<br />
Issue date 05-08-2012<br />
Revision date -<br />
Supersedes date -<br />
Product code<br />
Product use<br />
Manufacturer/Supplier<br />
General Information:<br />
<strong>Star</strong><strong>brite</strong> Rust Stain Remover<br />
892XX<br />
Cleaner.<br />
<strong>Star</strong> <strong>brite</strong> Distributing, Inc.<br />
4041 SW 47th Avenue<br />
Fort Lauderdale, FL 33314 US<br />
Contact Person: Vincent Waclawek<br />
(954) 587-6280<br />
Emergency 24-Hour Emergency: CHEMTREC: (703) 527-3887<br />
or (800) 424-9300<br />
2. Hazards Identification<br />
Physical state<br />
Appearance<br />
Emergency overview<br />
Liquid.<br />
Clear, pale yellow liquid.<br />
DANGER!<br />
Causes eye burns. Harmful if absorbed through skin or swallowed. Combustible liquid and vapor.<br />
OSHA regulatory status This product is hazardous according to OSHA 29 CFR 1910.1200.<br />
Potential health effects<br />
Routes of exposure<br />
Eyes<br />
Skin<br />
Inhalation<br />
Ingestion<br />
Signs and symptoms<br />
Potential environmental effects<br />
Inhalation. Eye contact. Skin contact. Ingestion.<br />
Causes eye burns.<br />
Harmful if absorbed through skin.<br />
May cause respiratory tract irritation.<br />
Harmful if swallowed.<br />
3. Composition / Information on Ingredients<br />
Contact can cause corrosive burns, corneal damage, and blindness. Symptoms of overexposure<br />
may be headache, dizziness, tiredness, nausea and vomiting.<br />
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic<br />
organisms.<br />
Components CAS # Percent<br />
Oxalic acid<br />
Ethylene glycol N-butyl ether<br />
Dodecylebenzene sulfonic acid<br />
Composition comments<br />
144-62-7
Skin contact<br />
Inhalation<br />
Ingestion<br />
Notes to physician<br />
5. Fire Fighting Measures<br />
Flammable properties<br />
Extinguishing media<br />
Suitable extinguishing<br />
media<br />
Unsuitable extinguishing<br />
media<br />
Fire fighting<br />
equipment/instructions<br />
Specific methods<br />
Hazardous combustion<br />
products<br />
6. Accidental Release Measures<br />
Personal precautions<br />
Environmental precautions<br />
Methods for containment<br />
Methods for cleaning up<br />
Other information<br />
7. Handling and Storage<br />
Handling<br />
Storage<br />
Immediately flush with plenty of water for at least 15 minutes while removing contaminated<br />
clothing and shoes. Get medical attention immediately. Wash contaminated clothing before reuse.<br />
Destroy or thoroughly clean contaminated shoes.<br />
If symptomatic, move to fresh air. Get medical attention if symptoms persist.<br />
Call a physician or poison control center immediately. DO NOT induce vomiting. If victim is fully<br />
conscious, give a cupful of water. Never give anything by mouth to an unconscious person. If<br />
vomiting occurs, keep head lower than the hips to help prevent aspiration.<br />
Treat symptomatically.<br />
Combustible liquid and vapor. Containers may explode when heated.<br />
Carbon dioxide (CO2). Foam. Dry chemical. Water fog.<br />
None known.<br />
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.<br />
Cool containers exposed to heat with water spray and remove container, if no risk is involved.<br />
Carbon oxides. Sulfur oxides.<br />
8. Exposure Controls / Personal Protection<br />
Occupational exposure limits<br />
US. ACGIH Threshold Limit Values<br />
Components<br />
Ethylene glycol N-butyl<br />
ether (111-76-2)<br />
Oxalic acid (144-62-7)<br />
Ensure adequate ventilation. Wear suitable protective clothing. See Section 8 of the MSDS for<br />
Personal Protective Equipment.<br />
Collect and dispose of spillage as indicated in Section 13 of the MSDS.<br />
Eliminate all ignition sources. Dike the spilled material, where this is possible. Prevent entry into<br />
waterways, sewer, basements or confined areas.<br />
Large Spills: Dike far ahead of liquid spill for later recovery and disposal. Use a non-combustible<br />
material like vermiculite, sand or earth to soak up the product and place into a container for later<br />
disposal.<br />
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece).<br />
Never return spills to original containers for re-use. Following product recovery, flush area with<br />
water. Clean surface thoroughly to remove residual contamination.<br />
Clean up in accordance with all applicable regulations.<br />
Do not get in eyes and avoid contact with skin and clothing. Avoid breathing mist or vapor. Use<br />
only with adequate ventilation. Wash thoroughly after handling. Observe good industrial hygiene<br />
practices.<br />
Keep container tightly closed and in a well-ventilated place. Store in closed original container at<br />
room temperature. Store away from incompatible materials.<br />
Type<br />
TWA<br />
STEL<br />
TWA<br />
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)<br />
Components<br />
Type<br />
Ethylene glycol N-butyl<br />
ether (111-76-2)<br />
Oxalic acid (144-62-7)<br />
PEL<br />
PEL<br />
Value<br />
20 ppm<br />
2 mg/m3<br />
1 mg/m3<br />
Value<br />
240 mg/m3<br />
50 ppm<br />
1 mg/m3<br />
<strong>Star</strong><strong>brite</strong> Rust Stain Remover<br />
900495 Version #: 01 Revision date: - Issue date: 05-08-2012<br />
CPH CPH MSDS NA<br />
2 / 7
Canada. Alberta OELs (Occupational Health & Safety Code, Schedule 1, Table 2)<br />
Components<br />
Type<br />
Value<br />
Ethylene glycol N-butyl<br />
ether (111-76-2)<br />
TWA<br />
97 mg/m3<br />
20 ppm<br />
Oxalic acid (144-62-7)<br />
STEL<br />
2 mg/m3<br />
TWA<br />
1 mg/m3<br />
Canada. British Columbia OELs. (Occupational Exposure Limits for Chemical Substances, Occupational Health and<br />
Safety Regulation 296/97, as amended)<br />
Components<br />
Type<br />
Value<br />
Ethylene glycol N-butyl<br />
TWA<br />
20 ppm<br />
ether (111-76-2)<br />
Oxalic acid (144-62-7)<br />
STEL<br />
2 mg/m3<br />
TWA<br />
1 mg/m3<br />
Canada. Ontario OELs. (Control of Exposure to Biological or Chemical Agents)<br />
Components<br />
Type<br />
Value<br />
Ethylene glycol N-butyl<br />
TWA<br />
20 ppm<br />
ether (111-76-2)<br />
Oxalic acid (144-62-7)<br />
STEL<br />
2 mg/m3<br />
TWA<br />
1 mg/m3<br />
Canada. Quebec OELS. (Ministry of Labor - Regulation Respecting the Quality of the Work Environment)<br />
Components<br />
Type<br />
Value<br />
Ethylene glycol N-butyl<br />
ether (111-76-2)<br />
TWA<br />
97 mg/m3<br />
20 ppm<br />
Oxalic acid (144-62-7)<br />
STEL<br />
2 mg/m3<br />
TWA<br />
1 mg/m3<br />
Mexico. Occupational Exposure Limit Values<br />
Components<br />
Type<br />
Ethylene glycol N-butyl<br />
ether (111-76-2)<br />
Oxalic acid (144-62-7)<br />
Engineering controls<br />
Personal protective equipment<br />
Eye / face protection<br />
Skin protection<br />
Respiratory protection<br />
General hygiene<br />
considerations<br />
9. Physical & Chemical Properties<br />
Appearance<br />
Physical state<br />
Form<br />
Color<br />
Odor<br />
Odor threshold<br />
pH 1.8<br />
Vapor pressure<br />
Vapor density<br />
Boiling point<br />
Melting point/Freezing point<br />
STEL<br />
TWA<br />
STEL<br />
TWA<br />
Value<br />
360 mg/m3<br />
75 ppm<br />
120 mg/m3<br />
26 ppm<br />
2 mg/m3<br />
1 mg/m3<br />
Provide adequate ventilation. Observe Occupational Exposure Limits and minimize the risk of<br />
inhalation of vapors.<br />
Use approved safety goggles or face shield.<br />
Wear appropriate chemical resistant clothing to prevent any possibility of skin contact.<br />
In case of inadequate ventilation, use respiratory protection.<br />
Always observe good personal hygiene measures, such as washing after handling the material<br />
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective<br />
equipment to remove contaminants.<br />
Clear, pale yellow liquid.<br />
Liquid.<br />
Liquid.<br />
Clear, pale yellow.<br />
Characteristic.<br />
Not available.<br />
Not available.<br />
Not available.<br />
212 °F (100 °C) Approximate.<br />
32 °F (0 °C) Approximate.<br />
<strong>Star</strong><strong>brite</strong> Rust Stain Remover<br />
900495 Version #: 01 Revision date: - Issue date: 05-08-2012<br />
CPH CPH MSDS NA<br />
3 / 7
Solubility (water)<br />
Specific gravity<br />
Flash point<br />
Flammability limits in air,<br />
upper, % by volume<br />
Flammability limits in air,<br />
lower, % by volume<br />
Auto-ignition temperature<br />
Complete.<br />
1 (20°C)<br />
152.6 °F (67 °C) Pensky-Martens Closed Cup Approximate.<br />
Not available.<br />
Not available.<br />
Not available.<br />
Evaporation rate < 1 (n-Butyl acetate = 1)<br />
10. Chemical Stability & Reactivity Information<br />
Chemical stability<br />
Conditions to avoid<br />
Incompatible materials<br />
Hazardous decomposition<br />
products<br />
Possibility of hazardous<br />
reactions<br />
11. Toxicological Information<br />
Toxicological data<br />
Components<br />
Material is stable under normal conditions.<br />
Contact with incompatible materials.<br />
Strong oxidizing agents. Bases.<br />
No hazardous decomposition products are known.<br />
Will not occur.<br />
Species<br />
Dodecylebenzene sulfonic acid (27176-87-0)<br />
Acute<br />
Oral<br />
LD50<br />
Oxalic acid (144-62-7)<br />
Acute<br />
Oral<br />
LC50<br />
Sensitization<br />
Acute effects<br />
Carcinogenicity<br />
ACGIH Carcinogens<br />
Rat<br />
Rat<br />
None known.<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
IARC Monographs. Overall Evaluation of Carcinogenicity<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
12. Ecological Information<br />
Ecotoxicological data<br />
Components<br />
Dodecylebenzene sulfonic acid (27176-87-0)<br />
Aquatic<br />
Crustacea<br />
Fish<br />
Test Results<br />
890 mg/kg<br />
375 mg/kg<br />
Risk of serious damage to eyes. Harmful in contact with skin and if swallowed.<br />
EC50<br />
LC50<br />
Species<br />
Daphnia magna<br />
Fish<br />
A3 Confirmed animal carcinogen with unknown relevance to<br />
humans.<br />
3 Not classifiable as to carcinogenicity to humans.<br />
Test Results<br />
5.88 mg/l, 48 hours<br />
1 mg/l, 96 hours<br />
Ecotoxicity<br />
Persistence and degradability<br />
Bioaccumulation /<br />
Accumulation<br />
Mobility in environmental<br />
media<br />
The product may affect the acidity (pH-factor) in water with risk of harmful effects to aquatic<br />
organisms.<br />
No data available.<br />
No data available.<br />
No data available.<br />
<strong>Star</strong><strong>brite</strong> Rust Stain Remover<br />
900495 Version #: 01 Revision date: - Issue date: 05-08-2012<br />
CPH CPH MSDS NA<br />
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13. Disposal Considerations<br />
Waste codes<br />
Disposal instructions<br />
Waste from residues / unused<br />
products<br />
Contaminated packaging<br />
14. Transport Information<br />
D002: Waste Corrosive material [pH 12.5, or corrosive to steel]<br />
Must be incinerated in a suitable incineration plant holding a permit delivered by the competent<br />
authorities. Do not allow this material to drain into sewers/water supplies. Do not contaminate<br />
ponds, waterways or ditches with chemical or used container. When this product as supplied is to<br />
be discarded as waste, it may meet the definition of a RCRA waste under 40 CFR 261.<br />
Dispose of waste and residues in accordance with local authority requirements.<br />
Since emptied containers retain product residue, follow label warnings even after container is<br />
emptied.<br />
DOT<br />
Basic shipping requirements:<br />
UN number<br />
NA1993<br />
Proper shipping name Combustible liquids, n.o.s. (Ethylene glycol N-butyl ether)<br />
Hazard class<br />
Combustible Liquid<br />
Packing group<br />
III<br />
Additional information:<br />
Special provisions<br />
B1, B52, IB3, T4, TP1, TP29<br />
Packaging exceptions 150<br />
Packaging non bulk 203<br />
Packaging bulk<br />
242<br />
IATA<br />
Not regulated as dangerous goods.<br />
IMDG<br />
Not regulated as dangerous goods.<br />
TDG<br />
Proper shipping name<br />
Hazard class<br />
UN number<br />
Packing group<br />
Special provisions<br />
General<br />
15. Regulatory Information<br />
COMBUSTIBLE LIQUID, N.O.S. (ETHYLENE GLYCOL N-BUTYL ETHER)<br />
Combustible Liquid<br />
UN1993<br />
III<br />
16<br />
This product meets the limited quantities exception as follows:<br />
DOT: Not regulated as dangerous goods except when shipped in bulk.<br />
Otherwise, the above descriptions apply.<br />
US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200.<br />
All components are on the U.S. EPA TSCA Inventory List.<br />
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)<br />
Oxalic acid (CAS 144-62-7)<br />
1.0 % One-Time Export Notification only.<br />
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
1.0 % N230<br />
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
CERCLA (Superfund) reportable quantity (lbs) (40 CFR 302.4)<br />
Dodecylebenzene sulfonic acid: 1000<br />
Superfund Amendments and Reauthorization Act of 1986 (SARA)<br />
Hazard categories<br />
Section 302 extremely<br />
hazardous substance (40<br />
CRF 355, Appendix A)<br />
<strong>Star</strong><strong>brite</strong> Rust Stain Remover<br />
Immediate Hazard - Yes<br />
Delayed Hazard - No<br />
Fire Hazard - Yes<br />
Pressure Hazard - No<br />
Reactivity Hazard - No<br />
900495 Version #: 01 Revision date: - Issue date: 05-08-2012<br />
No<br />
N230 Listed.<br />
CPH CPH MSDS NA<br />
5 / 7
Section 311/312 (40 CFR<br />
370)<br />
Drug Enforcement<br />
Administration (DEA) (21 CFR<br />
1308.11-15)<br />
Canadian regulations<br />
WHMIS status<br />
WHMIS classification<br />
WHMIS labeling<br />
No<br />
Not controlled<br />
This product has been classified in accordance with the hazard criteria of the CPR and the MSDS<br />
contains all the information required by the CPR.<br />
Controlled<br />
B3 - Combustible Liquids<br />
D1A - Immediate/Serious-VERY TOXIC<br />
D2B - Other Toxic Effects-TOXIC<br />
Inventory status<br />
Country(s) or region Inventory name On inventory (yes/no)*<br />
Australia<br />
Australian Inventory of Chemical Substances (AICS)<br />
Yes<br />
Canada<br />
Canada<br />
China<br />
Europe<br />
Europe<br />
Japan<br />
Korea<br />
New Zealand<br />
Philippines<br />
United States & Puerto Rico<br />
Domestic Substances List (DSL)<br />
Non-Domestic Substances List (NDSL)<br />
Inventory of Existing Chemical Substances in China (IECSC)<br />
European Inventory of Existing Commercial Chemical<br />
Substances (EINECS)<br />
European List of Notified Chemical Substances (ELINCS)<br />
Inventory of Existing and New Chemical Substances (ENCS)<br />
Existing Chemicals List (ECL)<br />
New Zealand Inventory<br />
Philippine Inventory of Chemicals and Chemical Substances<br />
(PICCS)<br />
Toxic Substances Control Act (TSCA) Inventory<br />
*A "Yes" indicates this product complies with the inventory requirements administered by the governing country(s)<br />
State regulations<br />
This product does not contain a chemical known to the State of California to cause cancer, birth<br />
defects or other reproductive harm.<br />
US - California Hazardous Substances (Director's): Listed substance<br />
Dodecylebenzene sulfonic acid (CAS 27176-87-0) Listed.<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
Listed.<br />
Oxalic acid (CAS 144-62-7)<br />
Listed.<br />
US - California Proposition 65 - Carcinogens & Reproductive Toxicity (CRT): Listed substance<br />
Not listed.<br />
US - New Jersey RTK - Substances: Listed substance<br />
Dodecylebenzene sulfonic acid (CAS 27176-87-0)<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
Oxalic acid (CAS 144-62-7)<br />
US. Massachusetts RTK - Substance List<br />
Listed.<br />
Listed.<br />
Listed.<br />
Dodecylebenzene sulfonic acid (CAS 27176-87-0) Listed.<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
Listed.<br />
Oxalic acid (CAS 144-62-7)<br />
Listed.<br />
US. New Jersey Worker and Community Right-to-Know Act<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
US. Pennsylvania RTK - Hazardous Substances<br />
Dodecylebenzene sulfonic acid (CAS 27176-87-0)<br />
Ethylene glycol N-butyl ether (CAS 111-76-2)<br />
Oxalic acid (CAS 144-62-7)<br />
500 LBS<br />
Listed.<br />
Listed.<br />
Listed.<br />
Yes<br />
No<br />
Yes<br />
Yes<br />
No<br />
Yes<br />
Yes<br />
Yes<br />
Yes<br />
Yes<br />
<strong>Star</strong><strong>brite</strong> Rust Stain Remover<br />
900495 Version #: 01 Revision date: - Issue date: 05-08-2012<br />
CPH CPH MSDS NA<br />
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16. Other Information<br />
HMIS® ratings Health: 3<br />
Flammability: 2<br />
Physical hazard: 0<br />
NFPA ratings Health: 2<br />
Flammability: 2<br />
Instability: 0<br />
Disclaimer<br />
The information contained herein is based on data considered accurate. However, no warranty is<br />
expressed or implied regarding the accuracy of these data or the results to be obtained from the<br />
use thereof. <strong>Star</strong> <strong>brite</strong> assumes no responsibility for injury to the vendee or third persons<br />
proximately caused by the material if reasonable safety procedures are not adhered to as<br />
stipulated in the data sheet. Additionally, <strong>Star</strong> <strong>brite</strong> assumes no responsibility for injury to vendee<br />
or third persons proximately caused by abnormal use of the material even if reasonable safety<br />
procedures are followed. Furthermore, vendee assumes the risk in his use of the material.<br />
<strong>Star</strong><strong>brite</strong> Rust Stain Remover<br />
900495 Version #: 01 Revision date: - Issue date: 05-08-2012<br />
CPH CPH MSDS NA<br />
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