Chemistry Manual 2012-2013 - Edison State College
Chemistry Manual 2012-2013 - Edison State College
Chemistry Manual 2012-2013 - Edison State College
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Blake Schmidt Page 1<br />
Modeling<br />
<strong>Chemistry</strong><br />
Honors<br />
Course <strong>Manual</strong>
Blake Schmidt - Introduction Page 2<br />
Welcome to Modeling <strong>Chemistry</strong> - Honors.<br />
You are about to embark on a<br />
learning experience unlike any<br />
other you have had in school.<br />
Modeling <strong>Chemistry</strong>-Honors is first and foremost a course in science. As such,<br />
your role in this class will be more often as a scientist than as a traditional student.<br />
Exactly what that means will soon become clear. For now, however, you need to<br />
know that this course will demand a lot from you. You will need to be active both<br />
inside and outside of the classroom: observing, experimenting, researching,<br />
reviewing, studying and practicing nearly every day.<br />
Our journey through chemistry is<br />
comparable to the construction of a<br />
building. Not only will you need to establish<br />
a strong foundation, but each subsequent<br />
level will need to be strong as well. If any<br />
level is incomplete, neglected, or just<br />
constructed poorly, the entire building is<br />
threatened. The same is true for this<br />
course. We will build continually on our<br />
knowledge of chemistry. If you fail to<br />
complete any one section in its entirety, you<br />
will impair your ability to build further. And<br />
yes, the final is cumulative.<br />
Acknowledgments<br />
The Modeling <strong>Chemistry</strong> Curriculum is a product of the Modeling Instruction Program. For information about<br />
Modeling Instruction, please visit http://modeling.asu.edu. This specific manual has been created by Blake<br />
Schmidt to supplement the Modeling <strong>Chemistry</strong> Curriculum. It follows the Modeling Instruction Curriculum<br />
very closely, but not exactly. The overwhelming majority of the labs and worksheets (i.e. Example Problems)<br />
are Modeling Instruction materials, but this exact manual is not a direct product of Modeling Instruction.<br />
Therefore, Blake Schmidt is fully responsible for any errors or deviations from the Modeling Curriculum.<br />
The author remains gratefully for the advice and assistance of Michael Mitchell, Frank Lock, and ACS -Hach<br />
Scientific for their aid in the formation of this manual. I also thank my past students for their helpful inputs.
Blake Schmidt - Introduction Page 3<br />
Course Syllabus<br />
This syllabus outlines the expectations<br />
students will need to meet in order to be<br />
successful in chemistry. This syllabus should be<br />
considered as a supplement to Charlotte<br />
County Public School's policies as described in<br />
the “Code of Student Conduct.” You are<br />
responsible for knowing and following these<br />
guidelines.<br />
Point Breakdown: Each quarter<br />
grade will be based on points<br />
earned in the following categories:<br />
Tests & Quizzes…………………….70%<br />
Participation……………...….…….20%<br />
Lab Reports…………………….……10%<br />
Semester grades will be based on<br />
35% for each quarter and 30% for<br />
the semester examination.<br />
Participation: Major concepts will be broken down into units (see Basic Plan of Attack). Each unit will consist<br />
mainly of laboratories and whiteboard classroom discussions. The fundamental concepts will be developed<br />
during these exercises. Each student is expected to participate in a positive manner toward the development<br />
of these concepts and to maintain a notebook. Students begin with a 75% (C) for participation. Each positive<br />
contribution adds to this score. Minimal participation will result in deduction, and negative participation (e.g.<br />
disruptive behavior) will result in major deduction (see Participation in Appendix).<br />
Tests and Quizzes: Students should expect to be quizzed for understanding as concepts are developed. Each<br />
unit may have one or two small quizzes and they may be unannounced. The overwhelming majority of points<br />
for this category, however, will be earned during tests. Each unit concludes with a test. Note that 70% of a<br />
quarter grade will be based on two or three tests. There will be an opportunity during office hours to earn<br />
back up to half of missed test points for most, but not all, tests. To repair a test, students will need to answer a<br />
new set of questions similar to those missed on the test. The total percentage of points earned back on the<br />
test will be determined by the percentage of questions answered correctly (100% correct = 50% back, 75%<br />
correct = 37.5% back, 50% correct = 25% back, 10% correct = 5% back, etc.). Students are encouraged to<br />
review their test with the instructor during office hours prior to attempting to answer the new questions. Test<br />
repair will be available during office hours for the entirety of the quarter in which the test was given.<br />
Lab Reports: Students are expected to write a complete PPOWR lab report for each lab. All lab reports are due<br />
the next school day following the completion of a lab. Each lab report will be assessed quickly for completion<br />
as a participation grade. Three lab reports will be formally assessed for content each quarter. Students will<br />
choose the three lab reports they submit for grading, but these must be submitted on the normal due date for<br />
that lab. Students can not submit lab reports for formal grading after that lab's due date.<br />
Academic Honesty: To make this class work its best, I encourage you to discuss and process information with<br />
friends, family, Google, and even Wikipedia (I especially recommend Wikipedia). At the same time, you cannot<br />
attempt to claim someone else’s work or thoughts as your own. You must give credit where credit is due:<br />
Always provide a reference. Make sure you are familiar with the difference between an acceptable<br />
paraphrase and plagiarism (see Appendix). I take cheating very seriously and will not tolerate plagiarism. Any<br />
plagiarized assignment will receive a failing grade and further action may be warranted depending on previous<br />
record (i.e. course failure). Consider yourself duly warned.
Blake Schmidt - Introduction Page 4<br />
Materials: Students are expected to bring these materials to class EVERYDAY:<br />
• Pens or pencils<br />
• Sturdy notebook - Whatever you like best.<br />
• Scientific Calculator with Log function (e.g. Texas Instruments TI-30Xa)<br />
Cell Phones Are NOT Calculators!<br />
• Dry Erase Markers (Expo markers are recommended)<br />
• Ability and eagerness to think<br />
Expectations: Students earning an A (>89.5%) will demonstrate a mastery<br />
of concepts and lab techniques that far exceeds expectations, as well as<br />
exceptional scientific writing and presentation skills. These students<br />
frequently lead and support their classmates and help others understand<br />
the material. B (89.4%-79.5%) students demonstrate great<br />
understanding of concepts and lab techniques, with work distinguished in<br />
most areas but not all. These students frequently demonstrate an ability<br />
to process information independently and share knowledge with others.<br />
C (79.4%-69.5%) students are defined as average, or meeting<br />
expectations. These students demonstrate a good understanding and<br />
ability to answer questions, but rarely expand or provide independent<br />
thought. D (69.4%-59.5%) students demonstrate a fair understanding and<br />
ability to answer questions, but are below the average level of their<br />
classmates. Students earning an F (
Blake Schmidt - Introduction Page 5<br />
Laboratory Safety Agreement<br />
If there is an emergency, inform the instructor immediately.<br />
Safety in the laboratory is very important. You must obey the following rules and behave in an<br />
appropriate manner at all times. Before you begin any experiment, you must be familiar with the<br />
procedure. Be sure you know where to put the waste. All damaged glass must be disposed in the<br />
sharps waste container. Make sure you know where the fire extinguisher, fire blanket, and eye-wash<br />
station are located.<br />
Appropriate attire is required for lab safety.<br />
• Eye protection must be worn over the eyes at all times.<br />
• We recommend that you do not wear contact lenses.<br />
• You must wear closed toe shoes.<br />
• Keep long hair pulled back.<br />
• Clothes that cover the body and legs are highly recommended.<br />
Responsible behavior is required for lab safety.<br />
• Eating and drinking are not allowed in the lab.<br />
• Wash hands frequently while in the lab and at the end of each lab period.<br />
• Gloves should be used when handling toxic or corrosive chemicals.<br />
• Never use an open flame in the vicinity of flammable substances.<br />
• Keep your face away from the opening of the vessel when mixing reagents, when applying heat,<br />
or when testing for an odor.<br />
Etiquette is necessary for lab safety.<br />
• At the end of each lab, make sure you clean your lab bench and put your chair away.<br />
• All materials should be cleaned and left to dry or put back in the appropriate place.<br />
Hazard Warning: CAUTION---the solids, liquids and gaseous substances, and combinations thereof,<br />
used in experiments are potentially hazardous in one or more of the following ways:<br />
• they may be irritants to, or have caustic action on, the skin, mucous membranes, lungs, and eyes.<br />
• they may be systemic poisons.<br />
• they may be flammable or explosive.
Blake Schmidt - Introduction Page 6<br />
○<br />
○<br />
○<br />
○<br />
Semester One<br />
Welcome to Modeling <strong>Chemistry</strong>-Honors<br />
• Introduction/Expectations PPT<br />
• Syllabus (Signatures)<br />
• <strong>Chemistry</strong> Concepts Inventory<br />
• Expectations Quiz<br />
Unit 1: What is Science?<br />
• Student Presentations (Science is…)<br />
• The Scientific Method PPT<br />
• McPherson Paper<br />
• Acting Scientifically PPT<br />
• Dimensional Analysis PPT<br />
• Test<br />
Unit 2: Identifying Matter<br />
• Lab/Whiteboard Expectations Lab<br />
• Mass and Change Labs<br />
• Conservation of Matter PPT<br />
• Volume Lab<br />
• Mass and Volume Lab<br />
• Density of a Gas Lab<br />
• Thickness of Al Foil Lab<br />
• Test<br />
Unit 3: Physical Properties of Matter<br />
• Release the Gas Lab<br />
• Hot vs. Cold Lab<br />
• Thermal Expansion Lab<br />
• Sea Level and Global Warming PPT<br />
• Crush Can Lab<br />
• Straw Presentations<br />
• Weather and Atmosphere PPT<br />
• Pressure, Number of Particles, Temperature, and<br />
Volume Labs<br />
• Test<br />
○<br />
○<br />
○<br />
○<br />
Basic Plan of Attack<br />
Semester Two<br />
Unit 6: Naming Compounds<br />
• Naming Molecular Compounds PPT<br />
• Naming Ionic Compounds PPT<br />
• Test<br />
Unit 7: Counting Particles<br />
• 5 Balloons Lab<br />
• 5 Balloons Hypothesis PPT<br />
• Relative Mass Lab<br />
• The Mole PPT<br />
• Empirical Formula Lab<br />
• MgxOy Lab<br />
• Magnesium sulfate ∙ ?-hydrate Lab<br />
• Test<br />
Unit 8: Chemical Reactions<br />
• Nail Lab<br />
• Galvanized Nail Lab<br />
• Electrochemistry PPT<br />
• Chemical Reactions Lab<br />
• Chemical Change Lab<br />
• Energy in Reactions PPT<br />
• Test<br />
Unit 9: Solution Stoichiometry<br />
• Molarity Lab<br />
• Lead iodide/Cobalt hydroxide Lab<br />
• BCA Tables PPT<br />
• Acids/Bases/pH PPT<br />
• Sodium Hydroxide/Hydrochloric Acid Lab<br />
• Test<br />
○<br />
○<br />
Unit 4: Thermodynamics<br />
• Heat vs. Temperature Lab<br />
• Icy Hot Lab<br />
• Energy and Change PPT<br />
• Lauric Acid/Candle Wax Labs<br />
• Heat is On PPT<br />
• Temperature of Bunsen Burner Flame Lab<br />
• Heat Capacity of Steel/Anti-Freeze Labs<br />
• Absolute Zero<br />
• Test<br />
Unit 5: Classifying Matter<br />
• Solubility of Sugar Lab<br />
• Solubility and Solutions PPT<br />
• Sand and Salt Lab<br />
• Electrolysis of Water Lab<br />
• Classifying Matter/Periodic Table PPT<br />
• Sticky Tape Lab<br />
• Atomic Theory PPT<br />
• Conductivity Lab<br />
• Melting Point Lab<br />
• Molecular Compounds PPT<br />
• Ionic Compounds PPT<br />
• Metallic/Covalent Networks PPT<br />
• Unknowns Lab<br />
• Test<br />
• Midterm Examination<br />
○<br />
○<br />
Unit 10: Gas and Energy Stoichiometry<br />
• 3 Containers Lab<br />
• Molar Volume of Gas Lab<br />
• Molar Gas Law PPT<br />
• Energy of Combustion Lab<br />
• Calorimetry PPT<br />
• Test<br />
Unit 11: Quantum Theory<br />
• Wave Interference Simulation<br />
• Properties of Waves<br />
•<br />
• Do the Wave PPT<br />
• Describing Light Lab<br />
• Emission Spectra/Flame Test Lab<br />
• Atom<br />
• The Quantum Atom Model PPT<br />
• Test<br />
• <strong>Chemistry</strong> Concepts Inventory<br />
• Final Examination (Cumulative)<br />
Blackbody Radiation/Photoelectric Effect<br />
Lab/Whiteboard<br />
PowerPoint Presentation<br />
Video
Blake Schmidt - Unit 1 Page 7<br />
Unit 1: What is Science?<br />
Student Presentations (Science is…)<br />
Prepare a 2-4 minute oral presentation that answers the question, "what is science?"<br />
Keep your opinion/thoughts as the focus. Do not provide a textbook definition.<br />
As you define science, please try to also answer the following questions:<br />
Is science good or bad?<br />
Of what use is science?<br />
Who does science?<br />
What, if anything, does science produce?<br />
After hearing the presentations, reflect on your answer. Has your opinion changed at all?<br />
It is highly recommended that you formalize your thoughts by putting them into your<br />
notebook. By writing such a reflection, you challenge your mind to think more deeply<br />
about the topic and you provide yourself with an invaluable resource for reviewing.<br />
The Scientific Method<br />
In order to view PowerPoint presentations from the course website, you may need to<br />
download Microsoft's PowerPoint Viewer, which is available from Microsoft's website:<br />
http://www.microsoft.com/downloads/details.aspx?FamilyID=<br />
048dc840-14e1-467d-8dca-19d2a8fd7485&DisplayLang=en<br />
McPherson G. 2001. Teaching & Learning the Scientific Method.<br />
The American Biology Teacher 63 (4): 242-245.<br />
Hypothesis Formation may be the most important part of the scientific method. Let's<br />
figure out how to form a good hypothesis.<br />
U1 EP1<br />
Acting Scientifically<br />
U1 EP2<br />
Dimensional Analysis (Conversions)<br />
U1 EP3
Blake Schmidt - Unit 1 Page 8<br />
U1 EP1<br />
Unit 1: Example Problems 1<br />
The Scientific Method<br />
1.<br />
True or False. All scientists use the same scientific method for all scientific endeavors. Why or why not?<br />
2.<br />
List the 7 steps of the basic scientific method presented in class.<br />
3.<br />
Hypothetically go through all the steps of the scientific method yourself. For example, you may have<br />
noticed that grass grows poorly next to sidewalks on campus. Why? Form a hypothesis, a prediction, a<br />
hypothetical experiment, etc. Do not use this example: come up with your own original example.<br />
4.<br />
How is a hypothesis different from a prediction?<br />
5.<br />
Why is it important to distinguish a hypothesis from a prediction?<br />
6.<br />
In January 2005, Bobby Henderson proposed the existence of an intelligent designer known as Flying<br />
Spaghetti Monster (FSM). By August 2005, BoingBoing.net offered $1 million to anyone that could prove<br />
that Jesus was NOT the son the of FSM. Why was BoingBoing.net confident enough to stake a million<br />
dollars against anyone finding such evidence?<br />
7.<br />
How does Pastafarianism (belief in FSM) demonstrate a difference between science and religion and the<br />
danger of teaching non-science in a science classroom?
Blake Schmidt - Unit 1 Page 9<br />
U1 EP2 Unit 1: Example Problems 2<br />
Accuracy/Precision/Significant Figures<br />
1.<br />
Explain how a series of measurements can be precise without being accurate.<br />
2.<br />
Why are significant figures important when reporting measurements?<br />
3.<br />
Suppose a graduated cylinder was not calibrated correctly. How would this effect the results of<br />
a measurement? How would it effect the results of a calculation using this measurement?<br />
4.<br />
5.<br />
6.<br />
How many significant figures are there in each of the following numbers?<br />
a. 0.4004 m<br />
b. 6000 g<br />
c. 1.00030 km<br />
d. 400 mL<br />
Write the following numbers in scientific notation.<br />
a. 0.0006730 g<br />
b. 7500 km<br />
c. 602.2 mm<br />
d. .0094 mg<br />
Calculate the sum of 6.078 g and 0.3329 g.<br />
7.<br />
Subtract 7.11 cm from 8.2 cm.<br />
8.<br />
What is the product of 0.8102 m and 3.44 m?<br />
9.<br />
Divide 94.20 g by 3.16722 mL.<br />
10.<br />
A large building is 1.02 x 10 2 m long, 31 m wide, and 4.25E2 m high. Calculate the volume.
Blake Schmidt - Unit 1 Page 10<br />
U1 EP3<br />
Unit 1: Example Problems 3<br />
Dimensional Analysis<br />
1.<br />
A quarterback throws for 350. yards in a game. How many feet? How many inches?<br />
2.<br />
A car traveling at 75 miles per hour will travel what distance in 90. minutes?<br />
3.<br />
A bullet is fired at 1500. feet per second. How many miles per hour?<br />
4.<br />
A car travels at 100. miles per hour. How many feet per second?<br />
5.<br />
A patient takes 2000. mg of Tylenol. How many grams? How many kg?<br />
6.<br />
What is the mass in kilograms of a 2.2E5 g container of fertilizer?<br />
7.<br />
A horse travels 244 furlongs in a fortnight. How many miles per hour was the horse traveling?<br />
A furlong is 1/8 mile and a fortnight is 2 weeks.<br />
8.<br />
The drug Surital can be used as a pre-anesthetic at a dosage of 1.0 mL per 5.0 lbs. How much<br />
Surital should be given to a dog that is 19 kg? 1 kg = 2.2 lbs.<br />
9.<br />
To reduce salivation when using Surital, atropine can be used at a dosage of 1.0 cc per 20. lbs.<br />
How much atropine should be used for a 4.5 kg cat? 1 cc = 1 mL.<br />
10.<br />
Ketomine can be used as an intramuscular anesthetic for cats. The dosage is 15.0 mg per lb.<br />
The ketomine is available in bottled form with a concentration of 100. mg per cc. How many cc<br />
are needed for a 7.21 kg cat?<br />
11.<br />
A man suffers a heart attack. The responding paramedic estimates the man to be 175 lbs.<br />
Epinephrine is injected into the trachea at 1.0 cc per 10. kg. How much epinephrine should be<br />
administered to this man?
Blake Schmidt - Unit 2 Page 11<br />
Unit 2: Identifying Matter<br />
Lab/Whiteboard Expectations Lab<br />
The purpose of this lab is to familiarize you with experimenting and whiteboarding in chemistry.<br />
The majority of labs will be very similar to this lab in terms of format. You will not be given a detailed<br />
list of steps to follow. You will, however, be given a basic overview of the lab and made aware of any<br />
special items. Because you will be tested on the concepts and techniques developed during labs, it is<br />
critical to keep thorough and organized notes. An example of notes for this lab has been included.<br />
You should follow a similar format for all other labs.<br />
Mass and Change Labs<br />
The following six labs will help us identify and understand matter:<br />
1. Clumped/Separate Steel Wool<br />
4. Solid/Dissolved Alka-Seltzer<br />
2. Ice/Liquid Water<br />
5. Burnt Steel Wool<br />
3. Solid/Dissolved Sugar<br />
6. Solid from Liquids<br />
After completing all the labs, form a hypothesis to explain all of your observations about mass.<br />
U2 EP1<br />
Conservation of Mass Presentation<br />
Volume Lab<br />
Now that you have a grasp of mass, you can learn about volume. In this lab, you will investigate the<br />
relationship between volume measured with a ruler and volume measured with a graduated cylinder.<br />
Mass and Volume Lab<br />
With mass and volume under your belt, investigate how these two quantities of matter are related.<br />
U2 EP2<br />
Density of a Gas Lab<br />
How does the density of a gas compare with a liquid or solid? What must be true about the particles<br />
that make up a gas? What about the particles in a liquid or solid?<br />
Thickness of Aluminum Foil Lab<br />
Combine your understanding of mass and volume with your mastery of math and determine the<br />
thickness of aluminum foil. If you have time, compare how heavy-duty foil measures up with regular?<br />
U2 EP3
Blake Schmidt - Unit 2 Page 12<br />
Example Notes<br />
Unit 2 Expectations Lab<br />
Purpose: become familiar with labs and whiteboards (W/B)<br />
Procedure: Fill 1000 ml beaker with water.<br />
3 test tubes with water (1 = 10% full; 2 = 50%; 3 = 100%).<br />
Seal with thumb and then flip test tube into water.<br />
Place a piece of calcium carbide into 1000 ml beaker.<br />
Trap gas coming off calcium carbide in test tube.<br />
Flame test for each.<br />
Observations: Water stays in upside-down test tube in beaker.<br />
Calcium carbide bubbles when placed in water, releasing gas.<br />
(10% filled with water) Exploded-flame shot out of test tube and made a<br />
loud whistle.Test tube was cool afterwards and did not have any residue.<br />
(50%) Ignited gas made a relatively small flame that traveled down the<br />
test tube rather quickly and then went out. The test tube turned black<br />
and warmed a little. Black ash came out of the tube and floated<br />
around the room.<br />
(100%) Ignited gas made a small flame that burned for about 15<br />
seconds just a little down into the tube (close to the top of tube). Flame<br />
then went out and top of test tube was hot. No ash or black residue.<br />
Whiteboard Particle Diagrams<br />
100 % 50% 10%<br />
AIR<br />
ASH<br />
FLAME<br />
GAS<br />
Reflection: I need to make sure I keep the room neat and clean, and wear<br />
goggles. I also need to really think about what I put on my whiteboard.<br />
For example, if there are two types of gases in my test tube, I should draw<br />
both. I also need to be specific with my drawings so that others know what<br />
I’ve drawn: like using different symbols or colors to represent different types<br />
of particles. I also need to pay attention to other presentations and make<br />
sure others thought of the same stuff I, or my group, did. One question that<br />
I should ask myself often is “how do I know?” This question will help me put<br />
my thoughts onto paper and into my presentations, and we need to<br />
demonstrate our thoughts. As far as the experiment goes, I think the way<br />
the gas burns depends mostly on how much air is mixed into it.
Blake Schmidt - Unit 2 Page 13<br />
U2 EP1<br />
Unit 2: Example Problems 1<br />
Mass and Change<br />
1.<br />
When you pulled the steel wool apart, you found that the mass was unchanged. When you heated the<br />
steel wool, you found that the mass changed. Explain.<br />
Draw diagrams (at the particle level) of the steel wool before and after the change.<br />
Clumped/Separated<br />
Before Heating/After Heating<br />
2.<br />
When ice melts, the volume of water is smaller than that of the ice. How does the mass of the water<br />
compare to the mass of the ice?<br />
Draw diagrams of the ice and water. Use small circles to represent the water particles.<br />
3.<br />
When the sugar dissolved in the water, you found that the mass remained unchanged. When the Alka-<br />
Seltzer dissolved in the water, the mass of the system changed. Explain.<br />
Draw diagrams of each of the materials before and after it was dissolved.<br />
Solid Sugar/Dissolved Sugar<br />
Solid Alka-Seltzer/Dissolved Alka-Seltzer<br />
4.<br />
Form a hypothesis to explain the observations from the Mass and Change labs.
Blake Schmidt - Unit 2 Page 14<br />
U2 EP2<br />
Unit 2: Example Problems 2<br />
Mass, Volume and Density<br />
1.<br />
Study the matter shown to the right. Assume the<br />
particles are uniformly distributed throughout each<br />
object and particles of the same size have the same<br />
mass. In the table below, show how the masses,<br />
volumes and densities of A and B compare by adding<br />
the symbol or = to the statement in the second<br />
column. Explain your reasoning for each answer.<br />
A<br />
B<br />
Property<br />
Mass<br />
Volume<br />
Density<br />
Relationship Reasoning<br />
A ____ B<br />
A ____ B<br />
A ____ B<br />
2.<br />
Study the matter shown to the right. Assume the<br />
particles are uniformly distributed throughout each<br />
object and particles of the same size have the same<br />
mass. In the table below show how the masses,<br />
volumes and densities compare by adding the symbol<br />
or = to the statement in the second column.<br />
Explain your reasoning for each answer.<br />
C<br />
E<br />
D<br />
Property<br />
Mass<br />
Volume<br />
Density<br />
Relationship Reasoning<br />
C ____ D<br />
C ____ E<br />
D ____ E<br />
C ____ D<br />
C ____ E<br />
D ____ E<br />
C ____ D<br />
C ____ E<br />
D ____ E<br />
3.<br />
Is object F or object G more dense? Assume the<br />
particles are uniformly distributed throughout each<br />
object, and particles with a larger size have a larger<br />
mass. Explain your reasoning.<br />
F<br />
G
Blake Schmidt - Unit 2 Page 15<br />
U2 EP2<br />
Unit 2: Example Problems 2<br />
Mass, Volume and Density<br />
Mass (g)<br />
80<br />
70<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
Substance A<br />
Substance B<br />
0 10 20 30 40 50 60 70 80<br />
Volume (mL)<br />
4.<br />
The graph above shows the relationship between mass and volume for two substances.<br />
Use the graph above to answer the following questions.<br />
a.<br />
You have built a simple two-pan balance to<br />
compare the masses of substances A and B. What<br />
would happen to the balance if you put equal<br />
masses of A and B in the two pans? What would<br />
happen if you put equal volumes of A and B in the<br />
two pans? Explain your reasoning.<br />
b.<br />
Write equations for both substances. What does the slope physically represent? What<br />
does it tell you about these substances?<br />
c.<br />
What mass of Substance B would be needed to balance the pans if 10 mL of Substance A<br />
is in one pan? Explain your reasoning.<br />
d.<br />
What volume of Substance A would be needed to balance the pans if 35 mL of Substance<br />
B is in one pan? Explain your reasoning.<br />
e.<br />
f.<br />
Water has a density of 1.00 g/mL. Sketch a line to represent water on the graph above.<br />
Determine whether substance A and B will sink or float when placed in a bucket of water.<br />
A: sink / float B: sink / float (circle correct response)<br />
Defend your answer using the graph, and your outstanding understanding of density.
Blake Schmidt - Unit 2 Page 16<br />
U2 EP2<br />
Unit 2: Example Problems 2<br />
Mass, Volume and Density<br />
Substance Density (g/mL)<br />
Aluminum……....2.70<br />
Titanium…...…...4.54<br />
Zinc…………...…..7.13<br />
Tin…………...…….7.31<br />
Iron………...……..7.87<br />
Nickel……...…….8.90<br />
Copper……...…..8.96<br />
Silver………...….10.50<br />
Lead………...…..11.35<br />
Mercury…...…..13.35<br />
Gold………...…..19.30<br />
5.<br />
6.<br />
Sketch a graph of mass vs. volume for titanium, copper and mercury.<br />
Suppose you made some cubes out of each metal in the table. Each measures 2.00 cm on every side.<br />
(all except mercury – why can you not make a cube of mercury?)<br />
a. What is the volume of each cube in cm 3 ? in mL? (Show your work)<br />
V = ______ cm 3<br />
V = ______ mL<br />
b.<br />
Find the mass of the following metal cubes:<br />
lead cube _____________<br />
nickel cube _____________<br />
zinc cube _____________<br />
(Show your work)<br />
7.<br />
Alicia's cheapskate boyfriend gave her a ring he claims is 24-carat gold. Alicia is skeptical. She<br />
measures the mass of the ring (15.28 g) and finds the volume of the ring by water displacement<br />
(initial volume 42.2 mL, final volume 43.7 mL). Should she treasure the ring as his first truly generous<br />
gift to her, or throw it at him the next time he walks by? Defend your answer.<br />
8.<br />
A student filled a graduated cylinder with water and read the meniscus at 25.8 mL. The student then<br />
dropped a solid material into the graduated cylinder and the water level rose to 35.9 mL. If the solid<br />
material had a density of 2.99 g/mL, determine the mass of the solid object.
Blake Schmidt - Unit 2 Page 17<br />
U2 EP3<br />
Unit 2: Example Problems 3<br />
Mass, Volume, and Density<br />
1.<br />
2.<br />
3.<br />
4.<br />
5.<br />
6.<br />
7.<br />
8.<br />
9.<br />
10.<br />
11.<br />
12.<br />
13.<br />
Ethanol has a density of 0.789 g/cm 3 .<br />
a. What is the mass of 225 cm 3 of ethanol?<br />
b. What is the volume of 75.0 g of ethanol?<br />
The cup is a volume widely used by cooks in America. One cup is equivalent to 225 cm 3 . If 1.00 cup<br />
of olive oil has a mass of 205 g, what is the density of olive oil in g/cm 3 ?<br />
What would you expect to happen if the cup of olive oil is poured into a container of ethanol?<br />
Gold has a density of 19.3 g/ cm 3 . A cube of gold measures 4.23 cm on each edge.<br />
a. What is the volume of the cube?<br />
b. What is its mass?<br />
Your standard backpack is 30. cm x 30. cm x 40. cm. Suppose you find a hoard of pure gold while<br />
treasure hunting in the wilderness. How much mass would your standard backpack hold if you filled<br />
it with the gold? An average student has a mass of 70. kg. How do these values compare?<br />
A kilogram is about 2.2 pounds. A 70. kg person is how many pounds? How many pounds of gold are<br />
in the backpack?<br />
An object measures 3.0 cm tall, 4.0 cm wide, and 5.0 cm long. How many mL?<br />
Use the density table from U2 EP2 to help you answer the following questions.<br />
What is the mass of 10. mL of aluminum?<br />
What is the volume of 15 g piece of lead?<br />
A piece of metal is 14 g and has a volume of 5.19 mL. What kind of metal is it?<br />
You are given 10. mL of aluminum and 10. mL of lead.<br />
a. Which piece is larger?<br />
b. Which has more mass?<br />
c. Which is denser?<br />
d. How many grams of lead?<br />
You are given 50. g of zinc and 50. g of tin.<br />
a. Which piece is larger?<br />
b. Which has more mass?<br />
c. Which is denser?<br />
d. How many mL of zinc?<br />
e. How many mL of tin?<br />
You are given 100. g of zinc and 75 g of nickel.<br />
a. Which piece is more massive?<br />
b. How many mL of zinc?<br />
c. How many mL of nickel?<br />
d. Which piece is larger?
Blake Schmidt - Unit 3 Page 18<br />
Unit 3: Physical Properties of Matter<br />
Release the Gas Lab<br />
You have a craving for an Outback Special. As soon as you arrive in the parking lot and open your<br />
door, you can smell all those wonderful proteins grilling on the barbie. How do those smelly<br />
particles make their way from the grill to your nose ?<br />
Hot vs. Cold Lab<br />
Some like it hot, some do not! What is hot anyway? What is cold? What is temperature?<br />
Thermal Expansion Lab<br />
Grandma just cannot get that lid off the grape jelly. But after running it in hot water for a while,<br />
it pops right off. What gives?<br />
U3 EP1<br />
Sea Level and Global Warming Presentation<br />
Crush Can Lab<br />
Just when you thought you understood this stuff, this lab happens. It will take a lot of brain power<br />
to figure this one out. Once you get it, however, it explains a whole lot about our everyday world.<br />
Straw Presentations<br />
How does a straw work? Besides well! Just another one of those everyday occurrences that can be<br />
explained from the Crush Can Lab. Demonstrate your understanding with a presentation.<br />
Weather and the Atmosphere Presentation<br />
U3 EP2<br />
Pressure, Number of Particles, Temperature, and Volume Labs<br />
If you think you are under pressure now, just wait. These labs will allow us to explain the<br />
relationships between pressure and number of particles, pressure and temperature, and pressure<br />
and volume. Graphs never looked so good!<br />
U3 EP3
Blake Schmidt - Unit 3 Page 19<br />
U3 EP1<br />
Unit 3: Example Problems 1<br />
Physical Properties of Matter<br />
1.<br />
You decide to boil water for pasta. You place the pan of water on the stove and turn on the burner.<br />
a. How does the behavior of the water molecules change as the pan of water is heated?<br />
b.<br />
What about your answer to (a) would change if more water was in the pan?<br />
2.<br />
What property of matter best describes the way a typical alcohol thermometer works?<br />
Explain (in terms of energy transfer) why the alcohol level in the thermometer rises (or falls) when you<br />
place the thermometer in contact with both warmer (or colder) objects.<br />
3.<br />
Does the concept of temperature apply to a single particle? Explain.<br />
4.<br />
If you feel feverish, why can you not take your own temperature with your hand?<br />
5.<br />
Your older brother announces that the lid to a jar of pickles from the refrigerator is “impossible” to<br />
loosen. You take the jar, hold the lid under the hot water from your sink’s faucet for a few seconds,<br />
and calmly open the jar. Your brother, when faced with this blow to his pride, claims that he loosened<br />
it for you. What knowledge of materials have you applied in this situation that really explains how you<br />
were able to open the lid?<br />
6.<br />
Which is warmer to the touch, a bucket of water at 50.˚C or a bathtub filled with water at 25˚C?<br />
Which of these contains more energy?
Blake Schmidt - Unit 3 Page 20<br />
U3 EP2<br />
Unit 3: Example Problems 2<br />
Measuring Pressure<br />
For Problems 1 & 2, calculate<br />
the pressure of the gas inside<br />
the flask that is connected to<br />
the manometer. The pressure<br />
in the room (Proom) is given.<br />
3.<br />
What do we mean by atmospheric pressure? What causes this pressure?<br />
4.<br />
How do we measure atmospheric pressure? Is atmospheric pressure the same everywhere on the<br />
surface of the earth?<br />
5.<br />
Why is the fluid in a barometer mercury, rather than water or another liquid?<br />
6.<br />
Explain why you cannot use a hand pump like the one below right to lift water up to the 3 rd floor of an<br />
apartment complex.<br />
7.<br />
One standard atmosphere of pressure (SP) is equivalent to ____________mmHg.<br />
8.<br />
Convert pressure measurements from one system of units to another in the following problems.<br />
1 atmosphere = 760 mmHg = 14.7 psi (pounds per square inch)<br />
a. 320. mmHg to atm<br />
b. 30.0 psi to mmHg<br />
c. Barometric pressure in Breckenridge, Colorado (9600. feet) is 580. mm Hg. How many atm?
Blake Schmidt - Unit 3 Page 21<br />
1.<br />
U3 EP3<br />
Use an IFE table to answer the following questions.<br />
Unit 3: Example Problems 3<br />
IFE Tables<br />
A sample of gas occupies 150. mL at 25˚C. What is its volume when the temperature is increased<br />
to 50.˚C? Assume P and n are constant.<br />
Initial<br />
Final<br />
Effect<br />
Pressure Temperature(K) Volume number of particles<br />
2.<br />
The pressure in a bicycle tire is 105 psi at 25˚C in Boulder. You take the bicycle up to Frasier,<br />
where the temperature is – 5˚C. What is the pressure in the tire? What must be constant?<br />
P T(K) V n<br />
I<br />
F<br />
E<br />
3.<br />
4.<br />
5.<br />
6.<br />
7.<br />
8.<br />
9.<br />
What would be the new pressure if 250. cm 3 of gas at<br />
standard pressure is compressed to 150. cm 3 ?<br />
What would be the new volume if 250. cm 3 of gas at 25˚C and<br />
730. mm pressure were changed to standard conditions of<br />
temperature and pressure (STP)?<br />
Sam’s bike tire contains 15 units of air particles and has a<br />
volume of 160. mL. Under these conditions, the pressure is<br />
13 psi. The tire develops a leak and now contains 10. units of<br />
air and has contracted to a volume of 150. mL. What would<br />
the tire pressure be now?<br />
A closed flask of air (0.250 L) contains 5.0 “bobs” of particles.<br />
The pressure probe on the flask reads 93 kPa. A student uses<br />
a syringe to add an additional 3.0 “bobs” of air through the<br />
stopper. Find the new pressure.<br />
A 350. mL sample of gas has a temperature of 30.˚C and a<br />
pressure of 1.20 atm. What temperature is needed for the<br />
same amount of gas to fit into a 250. mL flask at 1.0 atm?<br />
A 475 cm 3 sample of gas at STP is allowed to expand until it<br />
occupies a volume of 600. cm 3 . What temperature would be<br />
needed to return the gas to standard pressure?<br />
The box on the left contains gas molecules at 25˚C and 1.0<br />
atm. The top of the box is free to move down and is held up<br />
by pressure. Using the box to the right, adjust the top of the<br />
box and gas particles to match what it will look like at STP.
Blake Schmidt - Unit 4 Page 22<br />
Unit 4: Thermodynamics<br />
Heat vs. Temperature Lab<br />
We often think of heat and temperature as one and the same. It is important, however, to distinguish<br />
one from the other. This lab will make the difference clear.<br />
Icy Hot Lab<br />
It is often the simple things that reveal the most to us. Just wait to see how much the simple graph<br />
produced from this lab can tell us.<br />
Energy and Change Presentation<br />
U4 EP1<br />
Lauric Acid/Candle Wax Labs<br />
These labs will help drive home the concepts learned from Icy Hot and U4 EP1.<br />
U4 EP2<br />
The Heat is On Presentation<br />
U4 EP3<br />
U4 EP4<br />
Temperature of Bunsen Burner Flame Lab<br />
You know it's hot, but just how hot is it? Use your mastery of thermodynamics to figure it out.<br />
Heat Capacity of Steel/Anti-Freeze Labs<br />
Now that you know the temperature of the Bunsen Burner Flame, you can calculate these constants.<br />
Absolute Zero<br />
This 109 minute video documents humanity's quest to understand and master cold. It highlights and<br />
expands on the concepts developed in Units 3 & 4. Be sure you can answer questions pertaining to the<br />
topics listed below as discussed in the video. If you miss any of the video, or just want to watch it again,<br />
you should be able to view the video at www.pbs.org/wgbh/nova/zero/program.html.<br />
○<br />
○<br />
○<br />
○<br />
○<br />
○<br />
○<br />
○<br />
○<br />
○<br />
○<br />
○<br />
Contributions of Robert Boyle to cold.<br />
The temperature scales developed by Daniel Fahrenheit and Anders Celsius.<br />
How a thermometer works.<br />
The first evidence that cold has a lower limit (provided by Guillaume Amontons).<br />
Antoine Lavoisier's caloric theory and why it was so well accepted.<br />
Benjamin Thompson's (Count Rumford) evidence against caloric theory.<br />
Contributions of Michael Faraday, Sadi Carnot, James Joule and William Thompson (Lord Kelvin).<br />
The industrialization of cold by Frederic Tudor, Clarence Birdseye and Willis Carrier.<br />
The quests of James Dewar and Heike Kamerlingh Onnes.<br />
Superconductivity and its potential uses.<br />
Contributions of Eric Cornell, Carl Wieman, Wolfgang Ketterle, and Daniel Kleppner<br />
Bose-Einstein Condensates and their potential uses.
Blake Schmidt - Unit 4 Page 23<br />
U4 EP1<br />
Unit 4: Example Problems 1<br />
LOL Charts<br />
For questions 1-4 below, use energy bar charts to represent the ways that energy is stored in the<br />
system and flows into or out of the system. Be able to describe the arrangement and motion of<br />
the particles and how they change from the initial to the final state.<br />
1.<br />
A cup of hot coffee sits on the table and cools.<br />
2.<br />
A can of cold soda warms as it is left on the counter.<br />
3.<br />
A tray of water (20.˚C) is placed in the freezer and turns into ice cubes (- 8.0˚C).<br />
4.<br />
One of the ice cubes described in #3 is placed in a glass of room temperature (25˚C) soft drink.<br />
Do separate bar charts for the ice cube and the soft drink.<br />
5.<br />
Where does the energy that leaves the system in #3 go? How does this energy transfer affect the room<br />
temperature in the kitchen? Do you have any experience that supports your answer?<br />
6.<br />
The graph below shows a cooling curve for a substance as it freezes. Sketch a cooling curve for a larger<br />
sample of that same substance. Divide the graph into appropriate sections and identify what phases<br />
(states) of matter are present in each. Draw particle diagrams to represent the particles in each section.<br />
T<br />
E
Blake Schmidt - Unit 4 Page 24<br />
1.<br />
U4 EP2<br />
Water vapor in the room condenses on a cold plastic bottle of water.<br />
Unit 4: Example Problems 2<br />
More LOL Charts<br />
2.<br />
A pan of water (25˚C) is heated to boiling and some of the water is boiled away. Do separate energy bar<br />
charts for each stage of the process.<br />
3.<br />
You spill some warm water on your shirt. As it evaporates, you feel cool. Do separate charts again.<br />
4.<br />
During boiling, bubbles appear in the liquid water. In the boxes below represent the arrangement of<br />
molecules inside the liquid water and inside a bubble.<br />
Liquid<br />
Bubble<br />
5.<br />
What is inside the bubble? Explain your reasoning.<br />
6.<br />
Suppose the burner under a pan of boiling water is turned to a higher setting. How will this effect the<br />
temperature of the water in the pan? Explain.<br />
7.<br />
The graph below shows a heating curve for a liquid heated beyond its boiling point. Sketch a heating<br />
curve for a larger sample of that same liquid. Divide the graph into appropriate sections and<br />
identify what phases of matter are present in each. Draw particle diagrams to represent the<br />
particles in each section.<br />
T<br />
E
Blake Schmidt - Unit 4 Page 25<br />
U4 EP3<br />
Unit 4: Example Problems 3<br />
Q = mC<br />
OR Q = mC∆T<br />
The following properties of water are useful for solving quantitative energy problems. These<br />
constants will be given on tests; therefore, you do not have to memorize them, but you will need to<br />
know how to use them. You should, however, remember that 1 calorie = 4.18 Joules.<br />
Specific Heat Capacity of Liquid Water: 4.18 J/g∙˚C<br />
Specific Heat Capacity of Ice: 2.1 J/g∙˚C<br />
Heat of Vaporization: 2260 J/g<br />
Heat of Fusion: 334 J/g<br />
Begin each problem by sketching an appropriate heating or cooling curve and then use that curve to<br />
determine which equations and constants to use.<br />
1.<br />
A cup of coffee (140 g) cools from 75˚C down to comfortable room temperature 20.˚C. How much<br />
energy does it release to the surroundings?<br />
2.<br />
Suppose you lose 2.0 lbs of water due to sweating during gym class. If all of this water evaporated,<br />
how much energy (in kJ) did the water absorb from your body? 2.2 lbs = 1.0 kg<br />
3.<br />
Suppose during the Icy Hot lab that 65 kJ of energy were transferred to 450. g of water at 20.˚C.<br />
What would have been the final temperature of the water?<br />
4.<br />
The heat capacity of solid iron is 0.447 J/g∙˚C. If the same quantity of energy as in #3 was transferred<br />
to a 450. g chunk of iron at 20.˚C, what would be the final temperature?<br />
5.<br />
Suppose a bag full of ice (450. g) at 0.0˚C sits on the counter and begins to melt to liquid water.<br />
How much energy must be absorbed by the ice if 2/3 of it melted?<br />
6.<br />
A serving of Cheez-Its releases 130. kcal when digested by your body. If this same amount of energy<br />
was transferred to 2.5 kg of water at 27˚C, what would be the final temperature?<br />
7.<br />
If this same quantity of energy (130. kcal) was transferred to 2.5 kg of water at its boiling point, what<br />
fraction of the water would be vaporized?
Blake Schmidt - Unit 4 Page 26<br />
U4 EP4<br />
Unit 4: Example Problems 4<br />
Q = mC AND Q = mC∆T<br />
The following properties of water are useful for solving quantitative energy problems. These<br />
constants will be given on tests; therefore, you do not have to memorize them, but you will need to<br />
know how to use them. You should, however, remember that 1 calorie = 4.18 Joules.<br />
Specific Heat Capacity of Liquid Water: 4.18 J/g∙˚C<br />
Specific Heat Capacity of Ice: 2.1 J/g∙˚C<br />
Heat of Vaporization: 2260 J/g<br />
Heat of Fusion: 334 J/g<br />
Begin each problem by sketching an appropriate heating or cooling curve and then use that curve to<br />
determine which equations and constants to use.<br />
1.<br />
How much energy must be absorbed by a 150. g sample of ice at 0.0 ˚C that melts and warms to 25.0˚C?<br />
2.<br />
Suppose in the Icy Hot lab that the burner transfers 325 kJ of energy to 450. g of liquid water at 20. ˚C.<br />
What mass of the water will boil away?<br />
3.<br />
A 12 oz can of soft drink (340. g) at 25˚C is placed in a freezer at – 12˚C. How much energy must be<br />
removed from the soft drink for it to reach this temperature?<br />
4.<br />
65.0 kJ of energy are added to 150. g of ice at 0.0˚C. What is the final temperature of the water?<br />
5.<br />
250. kJ of energy are removed from a 4.00E 2 g sample of water at 60.˚C. Will the sample of water freeze<br />
completely? Explain.<br />
6.<br />
An ice cube tray full of ice (235g) at –7.0˚C is allowed to warm up to 22˚C. How much energy must be<br />
absorbed by the contents of the tray for this to happen?<br />
7.<br />
If this same quantity of energy was removed from 40.0 g of water vapor at 100. ˚C, what would be the<br />
final temperature of the water?
Blake Schmidt - Unit 5 Page 27<br />
Unit 5: Classifying Matter<br />
Solubility of Sugar Lab<br />
Our model of matter will need to undergo some modifications to explain these results.<br />
Solubility and Solutions Presentation<br />
U5 EP1<br />
Sand and Salt Lab<br />
You may not like this lab at first, but with some thinking and good lab technique, it should be easy.<br />
Electrolysis of Water Lab<br />
Why is water H2O? This lab may be the first time you have actual evidence to support that formula.<br />
Classifying Matter/Periodic Table Presentation<br />
U5 EP2<br />
Sticky Tape Lab<br />
The lab may be simple, but explaining the results is not. Try your best to make a model that works.<br />
Atomic Theory Presentation<br />
Conductivity Lab<br />
What is electricity? How is it conducted? And how can our model of matter explain all that?<br />
Melting Points Lab<br />
At room temperature, water is liquid but sugar is solid. How can our model explain these observations?<br />
Molecular Compounds Presentation<br />
Sodium Metal Demonstration<br />
Too bad that the sodium in table salt does not react with water like this. More importantly, why not?<br />
Ionic Compounds Presentation<br />
Metallic Bonds / Covalent Networks Presentation<br />
U5 EP3<br />
Unknowns Lab<br />
Use the information you have gathered to determine the type of bond present in an unknown chemical.
Blake Schmidt - Unit 5 Page 28<br />
U5 EP1<br />
Unit 5: Example Problems 1<br />
Solutions/Solubility<br />
1.<br />
2.<br />
3.<br />
4.<br />
5.<br />
6.<br />
7.<br />
8.<br />
9.<br />
10.<br />
11.<br />
12.<br />
13.<br />
Carbon dioxide dissolved in water is an example of which solute-solvent combination?<br />
a. liquid-gas b. gas-liquid c. liquid-liquid d. gas-gas<br />
Sugar dissolved in water is an example of which solute-solvent combination?<br />
a. liquid-liquid b. solid-solid c. liquid-solid d. solid-liquid<br />
Which mixture is made up of the smallest particles?<br />
a. milk b. shaving cream c. saltwater d. muddy water<br />
Which mixture contains visible particles that settle out unless the mixture is stirred?<br />
a. colloid b. solution c. emulsion d. suspension<br />
A metal solution is a(n)<br />
a. colloid b. suspension c. alloy d. emulsion<br />
The Tyndall effect is used to distinguish between<br />
a. liquids and gases. c. emulsions and colloids.<br />
b. solutions and colloids.d. solvents and solutes.<br />
Increasing the surface area of the solute<br />
a. increases the rate of dissolution.<br />
b. decreases the rate of dissolution.<br />
c. has no effect on the rate of dissolution.<br />
d. can increase, decrease, or have no effect on the rate of dissolution.<br />
Stirring increases the rate of dissolution because it<br />
a. raises the temperature.<br />
b. lowers the temperature.<br />
c. brings fresh solvent into contact with the solute.<br />
d. decreases the surface area of the solute.<br />
Which of the following will dissolve most rapidly?<br />
a. sugar cubes in cold water c. powdered sugar in cold water<br />
b. sugar cubes in hot water d. powdered sugar in hot water<br />
Which of the following will dissolve most slowly?<br />
a. large salt crystals in unstirred water c. small salt crystals in unstirred water<br />
b. large salt crystals in stirred water d. small salt crystals in stirred water<br />
If the amount of solute present in a solution at a given temperature is less than the maximum<br />
amount that can dissolve at that temperature, the solution is said to be<br />
a. saturated. c. supersaturated.<br />
b. unsaturated. d. concentrated.<br />
A solute crystal is dropped into a solution containing dissolved solute. It falls to the bottom of<br />
the beaker and does not dissolve after vigorous stirring. What does this indicate about the<br />
solution?<br />
a. It is probably unsaturated. c. It is probably saturated.<br />
b. It is probably supersaturated. d. It is not at equilibrium.<br />
In a solution at equilibrium,<br />
a. no dissolution occurs.<br />
b. the rate of dissolution is less than the rate of crystallization.<br />
c. the rate of dissolution is greater than the rate of crystallization.<br />
d. the rate of dissolution and the rate of crystallization are equal.
Blake Schmidt - Unit 5 Page 29<br />
U5 EP2<br />
Unit 5: Example Problems 2<br />
Matter & Periodic Table<br />
1.<br />
2.<br />
3.<br />
4.<br />
5.<br />
6.<br />
7.<br />
8.<br />
9.<br />
10.<br />
11.<br />
12.<br />
13.<br />
14.<br />
The idea of arranging the elements in the periodic table according to their chemical and<br />
physical properties is attributed to _______________________.<br />
Mendeleev left spaces in his periodic table and predicted the existence of three elements and<br />
their______________________.<br />
The discovery of what elements added a new column to Mendeleev's periodic table?<br />
a. noble gases b. transition metals c. halogens d. alkaline -earth metals<br />
What are the elements with atomic numbers from 58 to 71 called?<br />
Argon, krypton, and xenon are __________________________.<br />
The periodic law allows some properties of an element to be predicted based on its<br />
a. position in periodic table b. symbol c. mass d. color<br />
Potassium and bromine belong to ____________________.<br />
In which group does hydrogen belong? Explain.<br />
The most reactive group of nonmetals is _______________________.<br />
Elements in group 1, aka ____________________, are (more/less) reactive than elements in<br />
group 2, aka ______________________.<br />
What type of mixture has components in a uniform distribution?<br />
Which of the following is a homogeneous mixture?<br />
a. water b. sugar water c. whole wheat bread d. sugar<br />
All of the following are heterogeneous mixtures except<br />
a. whole wheat bread b. granite c. tap water d. oil -water mixture<br />
Identify the separation techniques pictured below. Which technique would be useful to<br />
separate a mixture of sand, salt and water? Of salt and water? Elements of water?
Blake Schmidt - Unit 5 Page 30<br />
U5 EP3<br />
Unit 5: Example Problems 3<br />
Types of Compounds<br />
1.<br />
Below left is a 2-D array that represents an ionic lattice. At right is a 2-D array that represents a<br />
molecular solid. In what ways are they similar? In what ways are they different?<br />
2.<br />
Below are groups of the inner cores of the atoms of the tapes. Sketch in the mobile negative<br />
charges to show how the top tape becomes (+) and the bottom becomes (-). Label each tape.<br />
3.<br />
Describe the contents of each cell.<br />
1<br />
4<br />
2<br />
3
Blake Schmidt - Unit 6 Page 31<br />
Unit 6: Naming Compounds<br />
Naming Molecular Compounds Presentation<br />
U6 EP1<br />
Naming Ionic Compounds Presentation<br />
U6 EP2
Blake Schmidt - Unit 6 Page 32<br />
U6 EP1<br />
Unit 6: Example Problems 1<br />
Molecular Compounds<br />
Name and/or write the formula for the following molecules. Be prepared to draw each.<br />
1.<br />
a. CBr4<br />
b. N2P3<br />
5.<br />
O<br />
H<br />
c. PCl3<br />
H<br />
d. ICl<br />
e. N2O<br />
6.<br />
2.<br />
f. SiF4<br />
a. GeH4<br />
O<br />
C<br />
O<br />
b. N2Br4<br />
c. P2S5<br />
d. SeO2<br />
7.<br />
H<br />
e. NH3<br />
H<br />
C<br />
H<br />
3.<br />
f. SiO2<br />
a. phosphorus triiodide<br />
H<br />
b. silicon tetrachloride<br />
c. dinitrogen pentoxide<br />
e. dinitrogen tetroxide<br />
8.<br />
O<br />
4.<br />
f. carbon monoxide<br />
a. carbon dioxide<br />
b. sulfur hexafluoride<br />
O<br />
S<br />
O<br />
c. dinitrogen tetrachloride<br />
d. carbon tetraiodide<br />
9.<br />
e. phosphorus pentafluoride<br />
f. diphosphorus pentoxide<br />
O<br />
H<br />
O<br />
H
Blake Schmidt - Unit 6 Page 33<br />
1.<br />
U6 EP2<br />
Unit 6: Example Problems 2<br />
Ionic Compounds<br />
Name and/or write the formula for the following ionic compounds. Be prepared to draw each<br />
as both an electrically neutral empirical compound and dissociated ions.<br />
a. Na2O<br />
5.<br />
a. lithium bromide<br />
9.<br />
a. sodium nitrate<br />
b. K2S<br />
b. sodium iodide<br />
b. aluminum phosphate<br />
c. MgCl2<br />
c. silver sulfide<br />
c. calcium carbonate<br />
d. CaBr2<br />
d. cesium oxide<br />
d. sodium carbonate<br />
e. BaI2<br />
e. beryllium iodide<br />
e. calcium nitrate<br />
f. Al2S3<br />
f. barium hydride<br />
f. aluminum carbonate<br />
2.<br />
a. CsBr<br />
6.<br />
a. silver oxide<br />
10.<br />
a. K2SO4<br />
b. AgF<br />
b. aluminum sulfide<br />
b. Mg(NO2)2<br />
c. Na3N<br />
c. sodium nitride<br />
c. AgNO3<br />
d. K2O<br />
d. barium chloride<br />
d. Cu3PO4<br />
e. AgBr<br />
e. strontium hydride<br />
e. Be(OH)2<br />
f. MgI2<br />
f. aluminum fluoride<br />
f. Al3HCO3<br />
3.<br />
a. SnBr2<br />
7.<br />
a. chromium(III) chloride<br />
11.<br />
a. potassium hydroxide<br />
b. SnBr4<br />
b. tin(IV) oxide<br />
b. ammonium hydroxide<br />
c. CrO<br />
c. lead(II) oxide<br />
c. potassium bicarbonate<br />
d. Cr2O3<br />
d. copper(II) iodide<br />
d. zinc carbonate<br />
e. Hg2I2<br />
e. cobalt(II) oxide<br />
e. cobalt(II) hydroxide<br />
4.<br />
f. HgI2<br />
a. PbCl2<br />
8.<br />
f. cobalt(III) oxide<br />
a. chromium(III) sulfide<br />
12.<br />
f. iron(III) phosphate<br />
+<br />
a.<br />
Na<br />
b. Fe2O3<br />
b. manganese(IV) oxide<br />
c. SnI2<br />
c. gold(III) chloride<br />
b. K Cl<br />
d. Hg2O<br />
d. titanium(IV) chloride<br />
e. HgS<br />
f. CuI<br />
e. iron(II) bromide<br />
f. iron(II) oxide<br />
c.<br />
+<br />
Na<br />
O<br />
O<br />
S<br />
O<br />
2-<br />
O
Blake Schmidt - Unit 7 Page 34<br />
Unit 7: Counting Particles<br />
5 Balloons Lab<br />
Can you form one of the most popular hypotheses in all of chemistry?<br />
5 Balloons Hypothesis Presentation<br />
Relative Mass Lab<br />
Even though we cannot see individual particles of matter, our new hypothesis allows us to make some<br />
very useful statements about them.<br />
U7 EP1<br />
The Mole Presentation<br />
U7 EP2<br />
Empirical Formula Lab<br />
In Unit 5, we just accepted oxidation numbers as fact. What evidence do we have to support them?<br />
This lab will reveal how we know the formula for zinc chloride with real evidence.<br />
MgxOy Lab<br />
More evidence to support oxidation numbers. Just promise not to stare!<br />
U7 EP3<br />
Magnesium sulfate ∙ ?-hydrate Lab<br />
We have already come across some ionic compounds that incorporate water into their crystal lattice<br />
structure (hygroscopic compounds like calcium chloride). How much water does your sample of<br />
magnesium sulfate contain? What is the formula for this hydrate?
Blake Schmidt - Unit 7 Page 35<br />
U7 EP1<br />
Unit 7: Example Problems 1<br />
Relative Mass<br />
The following items are sold regularly by the dozen instead of individually:<br />
eggs, bagels, munchkins (donut holes), and chicken wings.<br />
1.<br />
Why are these items sold in this manner?<br />
A student determined the mass of a dozen of each of these items.<br />
Eggs = 1.5 pounds<br />
Bagels = 3.0 pounds<br />
Munchkins = 0.75 pounds<br />
Wings = 2.25 pounds<br />
2.<br />
3.<br />
Calculate the average mass of ONE of each item.<br />
Place the correct number of munchkins in the empty balance pan.<br />
1.0# 0.75#<br />
4.<br />
Compare how you "counted" particles in the pressure vs. number of particles lab in Unit 3 with<br />
how you "counted" particles in the relative mass lab. What assumptions did you make in each lab?<br />
What reasoning did you use to reach these assumptions?
Blake Schmidt - Unit 7 Page 36<br />
U7 EP2<br />
Unit 7: Example Problems 2<br />
The Mole<br />
1.<br />
2.<br />
3.<br />
4.<br />
5.<br />
6.<br />
7.<br />
8.<br />
9.<br />
10.<br />
11.<br />
12.<br />
13.<br />
14.<br />
Assuming that each human being has 60. trillion body cells (6.0 x 10 13 ) and that Earth's population is 6.7<br />
billion (6.7E 9 ), calculate the total number of living human body cells on this planet. What percentage of<br />
a mole is this number?<br />
Roadrunner, the fastest supercomputer in the world as of June 2008, can perform a petaflop. A "flop" is<br />
an acronym meaning floating-point operations per second. One petaflop is 1,000 .trillion operations per<br />
second. How long (in both seconds and years) will it take Roadrunner to perform a mole of operations?<br />
(1 year = 365.25 days)<br />
If you started counting when you first learned how to count and then counted by ones, eight hours a<br />
day, 5 days a week for 50 weeks a year, you would be judged a 'good counter' if you could reach 4 billion<br />
by the time you retired at age 65. If every human on Earth (6.7E 9 ) were to count this way until<br />
retirement, what percentage of a mole would they count?<br />
An old (pre-1987) penny is nearly pure copper. If such a penny has a mass of 3.3 g, how many moles of<br />
copper atoms would be in one penny?<br />
Four nails have a total mass of 4.42 grams. How many moles of iron atoms do they contain?<br />
A raindrop has a mass of 0.050 g. How many moles of water does a raindrop contain?<br />
What mass of water would you need to have 15.0 moles of H2O?<br />
One box of Morton’s Salt contains 737 grams. How many moles of sodium chloride is this?<br />
A chocolate chip cookie recipe calls for 0.050 moles of baking soda (sodium bicarbonate). How many<br />
grams should the chef mass out?<br />
Rust is iron(III) oxide. The owner of a l959 Cadillac convertible wants to restore it by removing the rust<br />
with oxalic acid, but he needs to know how many moles of rust will be involved in the reaction. How<br />
many moles of iron(III) oxide are contained in 2.50 kg of rust?<br />
First-century Roman doctors believed that urine whitened teeth and also kept them firmly in place. As<br />
gross as that sounds, it must have worked because it was used as an active ingredient in toothpaste and<br />
mouthwash well into the 18th century. Would you believe it’s still used today? Thankfully, not in its<br />
original form! Modern dentists recognized that it was the ammonia that cleaned the teeth, and they<br />
still use that. The formula for ammonia is NH3. How many moles are in 0.75 g of ammonia? How many<br />
molecules? How many nitrogen atoms? How many hydrogen atoms?<br />
Lead(II) chromate was used as a pigment in paints. How many moles of lead(II) chromate are in 75.0 g of<br />
lead(II) chromate? How many atoms of oxygen are present?<br />
The diameter of the tungsten wire in a light bulb filament is very small, less than two thousandths of an<br />
inch, or about 1/20 mm. The mass of the filament is so very small – 0.0176 grams – that it would take<br />
1,600 filaments to weigh an ounce! How many tungsten atoms are in a typical light bulb filament?<br />
Two popular antacids tablets are Tums and Maalox. The active ingredient in both of these antacids is<br />
calcium carbonate. Tums Regular Strength tablets contain 0.747 g and Maalox tablets contain 0.600 g of<br />
calcium carbonate. How many more molecules of calcium carbonate does a Tums provide than a<br />
Maalox?
Blake Schmidt - Unit 7 Page 37<br />
U7 EP3<br />
Unit 7: Example Problems 3<br />
Empirical Formulas<br />
1.<br />
Find the empirical formula of a compound containing 32.0 g of bromine and 4.9 g of magnesium.<br />
2.<br />
What is the empirical formula of a carbon-oxygen compound if a 95.2 g sample of the compound<br />
contains 40.8 g of carbon and the rest is oxygen?<br />
3.<br />
A compound was analyzed and found to contain 9.8 g of nitrogen, 0.70 g of hydrogen, and 33.6 g of<br />
oxygen. What is the empirical formula of the compound?<br />
4.<br />
A compound composed of hydrogen and oxygen is found to contain 0.59 g of hydrogen and 9.40 g<br />
of oxygen. The molar mass of this compound is 34.0 g/mol. Find the empirical and molecular<br />
formulas.<br />
5.<br />
A sample of iron oxide was found to contain 1.116 g of iron and 0.480 g of oxygen. Its molar mass is<br />
roughly 5x as great as that of oxygen gas. Find the empirical and molecular formulas.<br />
6.<br />
Find the percentage composition of a compound that contains 17.6 g of iron and 10.3 g of sulfur.<br />
7.<br />
Find the percentage composition of a compound that contains 1.94 g of carbon, 0.48 g of<br />
hydrogen, and 2.58 g of sulfur. What is the empirical formula?<br />
8.<br />
What is the % by mass of oxygen in magnesium nitrate?<br />
9.<br />
What is the percentage composition of water?<br />
10.<br />
What is the empirical formula for a compound that is 39.3% sodium and the rest chlorine?
Blake Schmidt - Unit 8 Page 38<br />
Unit 8: Chemical Reactions<br />
Nail Lab<br />
You have never seen nails do this before.<br />
U8 EP1<br />
U8 EP2<br />
U8 EP3<br />
Galvanized Nail Lab<br />
You may have heard of a galvanized nail before, but now you will see how it is made.<br />
Hopefully, you can develop a model to explain how the process works.<br />
Electrochemistry Presentation<br />
U8 EP4<br />
Chemical Reactions Lab<br />
These chemical reactions are great examples of the types of reactions that you<br />
will need to be familiar with.<br />
U8 EP5<br />
Chemical Change Lab<br />
It begins with copper metal and nitric acid. Let us see what we end up with.<br />
Energy in Chemical Reactions Presentation<br />
U8 EP6
Blake Schmidt - Unit 8 Page 39<br />
U8 EP1<br />
Unit 8: Example Problems 1<br />
Rearranging Atoms<br />
1.<br />
2.<br />
Define the following terms and provide examples of each.<br />
a. Conservation of Mass<br />
b. Chemical Formula<br />
c. Subscript<br />
d. Coefficient<br />
Draw particle diagrams for each reactant and each product. Adjust the number of each particle<br />
accordingly so that the chemical equation follows the conservation of mass.<br />
a. H2 + O2 H2O<br />
b. H2 + Cl2 HCl<br />
c. Na + O 2 Na2O<br />
d. N2 + H2 NH3<br />
e. CH4 + O2 CO2 + H2O<br />
f. NO + O 2 NO2<br />
g. Fe + Cl 2 FeCl3<br />
h. CH3OH + O 2 CO2 + H2O
Blake Schmidt - Unit 8 Page 40<br />
U8 EP2<br />
Unit 8: Example Problems 2<br />
Balancing Equations<br />
Adjust coefficients to balance the following equations (1-35). Be prepared to draw particle diagrams.<br />
1.<br />
____C + ____H2O → ____CO + ____H2<br />
2.<br />
____MgO →____Mg + ____O2<br />
3.<br />
____Al + ____O2 → ____Al2O3<br />
4.<br />
____Zn + ____H2SO4 → ____ZnSO4 + ____H2<br />
5.<br />
____Cl2 + ____KI → ____KCl + ____I2<br />
6.<br />
____CuCl → ____Cu + ____Cl2<br />
7.<br />
____Na + ____Cl2 → ____NaCl<br />
8.<br />
____Al + ____HCl→ ____AlCl3 + ____H2<br />
9.<br />
____Fe2O3 → ____Fe + ____O2<br />
10.<br />
____P + ____O2→____P2O5<br />
11.<br />
____Mg + ____HCl → ____MgCl2 + ____H2<br />
12.<br />
____H2 + ____N2 → ____NH3<br />
13.<br />
____BaCl2 + ____H2SO4 → ____BaSO4 + ____HCl<br />
14.<br />
____CH4 + ____O2 →____CO2 + ____H2O<br />
15.<br />
____ZnCl2 + ____(NH4)2S → ____ZnS + ____ NH4Cl
Blake Schmidt - Unit 8 Page 41<br />
U8 EP2<br />
Unit 8: Example Problems 2<br />
Balancing Equations<br />
16.<br />
17.<br />
18.<br />
19.<br />
20.<br />
21.<br />
____SO2 + ____O2<br />
____CH4 + ____O2<br />
____P + ____Cl2<br />
____CO + ____O2<br />
____CH4 + ____ O2<br />
____Li + ____Br2<br />
____SO3<br />
____CO + ____H2O<br />
____PCl3<br />
____CO2<br />
____CH3OH<br />
____LiBr<br />
22.<br />
____Al2O3<br />
____Al + ____O2<br />
23.<br />
24.<br />
____Na + ____H2O<br />
____CO2 + ____H2O<br />
____NaOH + ____H2<br />
____C6H12O6 + ____O2<br />
25.<br />
____H2SO4 + ____NaCl<br />
____HCl + ____Na2SO4<br />
Two reactions are used to get rid of sulfur dioxide, a pollutant from burning coal:<br />
26.<br />
____H2 + ____SO2<br />
____H2S + ____H2O<br />
27.<br />
____CaCO3 + ____SO2 + ____ O2<br />
____CaSO4 + ____CO2<br />
28.<br />
29.<br />
30.<br />
31.<br />
____AgNO3 + ____CaCl2<br />
____HCl + ____Ba(OH)2<br />
____H3PO4 + ____NaOH<br />
____Pb(NO3)2 + ____KI<br />
____AgCl + ____Ca(NO3)2<br />
____BaCl2 + ____H2O<br />
____Na3PO4 + ____H2O<br />
____ PbI2 + ____KNO3<br />
32.<br />
33.<br />
34.<br />
35.<br />
____CuO + ____NH3<br />
____C2H5OH + ____O2<br />
____C2H6 + ____O2<br />
____NO2 + ____H2O<br />
____N2 + ____Cu + ____H2O<br />
____CO2 + ____H2O<br />
____CH3COOH + ____H2O<br />
____HNO3 + ____NO
Blake Schmidt - Unit 8 Page 42<br />
U8 EP3<br />
Unit 8: Example Problems 3<br />
Writing Balanced Equations<br />
1.<br />
Nitric oxide (NO) reacts with ozone (O3) to produce nitrogen dioxide and oxygen.<br />
2.<br />
Iron burns in air to form a black solid, Fe3O4.<br />
3.<br />
Sodium metal reacts with chlorine gas to form sodium chloride.<br />
4.<br />
Acetylene, C2H2, burns in air to form carbon dioxide and water.<br />
5.<br />
Hydrogen peroxide (H2O2) easily decomposes into water and oxygen.<br />
6.<br />
Hydrazine (N2H4) and hydrogen peroxide are used together as rocket fuel. The products are<br />
nitrogen and water.<br />
7.<br />
If potassium chlorate is strongly heated, it decomposes to yield oxygen gas and potassium<br />
chloride.<br />
8.<br />
When sodium hydroxide is added to sulfuric acid (H2SO4), the products are water and sodium<br />
sulfate.<br />
9.<br />
In the Haber process, hydrogen and nitrogen react to form ammonia.<br />
10.<br />
Ammonia (NH3) reacts with hydrogen chloride to form ammonium chloride.<br />
11.<br />
Calcium carbonate decomposes upon heating to form calcium oxide and carbon dioxide.<br />
12.<br />
Barium oxide reacts with water to form barium hydroxide.<br />
13.<br />
Acetaldehyde (CH3CHO) decomposes to form methane (CH4) and carbon monoxide.<br />
14.<br />
Zinc is combined with copper(II) nitrate.<br />
15.<br />
Calcium sulfite decomposes when heated to form calcium oxide and sulfur dioxide.
Blake Schmidt - Unit 8 Page 43<br />
U8 EP3<br />
Unit 8: Example Problems 3<br />
Writing Balanced Equations<br />
16.<br />
Aluminum is combined with sulfuric acid (H2SO4).<br />
17.<br />
A nitrogen containing carbon compound, C 2H6N2, decomposes to form ethane, C2H6, and<br />
nitrogen.<br />
18.<br />
Phosgene, COCl2, is formed when carbon monoxide reacts with chlorine gas.<br />
19.<br />
Manganese(II) iodide decomposes when exposed to light to form manganese and iodine.<br />
20.<br />
Dinitrogen pentoxide reacts with water to produce nitric acid (HNO 3).<br />
21.<br />
Magnesium is combined with titanium (IV) chloride.<br />
22.<br />
Carbon reacts with zinc oxide to produce zinc and carbon dioxide.<br />
23.<br />
Bromine reacts with sodium iodide to form sodium bromide and iodine.<br />
24.<br />
Phosphorus (P4) reacts with bromine to produce phosphorus tribromide.<br />
25.<br />
Ethanol, C2H5OH, reacts with oxygen to produce carbon dioxide and water.<br />
26.<br />
Calcium hydride reacts with water to produce calcium hydroxide and hydrogen.<br />
27.<br />
Sulfuric acid, H2SO4, reacts with potassium hydroxide.<br />
28.<br />
Propane, C3H8, burns in air.<br />
29.<br />
Lead is combined with aluminum chloride.<br />
30.<br />
Zinc is combined with hydrochloric acid.
Blake Schmidt - Unit 8 Page 44<br />
U8 EP4<br />
Unit 8: Example Problems 4<br />
Electrochemistry<br />
1.<br />
2.<br />
3.<br />
4.<br />
5.<br />
6.<br />
In an electrochemical cell, electrons are generated at the<br />
a. anode.<br />
b. cathode.<br />
c. circuit.<br />
d. electrolyte.<br />
What is used to keep two half-cells apart but allow charges to flow?<br />
a. an electrolyte<br />
b. a cathode<br />
c. a porous barrier<br />
d. an anode<br />
Where does oxidation take place in an electrochemical cell?<br />
a. the anode<br />
b. the cathode<br />
c. the anode or the cathode<br />
d. the half-cell<br />
The oxidation number of the substance taking part in the reaction that occurs at the cathode<br />
a. decreases.<br />
b. increases.<br />
c. does not change.<br />
d. None of the above<br />
In an electrochemical cell, the cathode is the<br />
a. neutral electrode.<br />
b. electrode at which matter can gain or lose electrons.<br />
c. electrode at which matter gains electrons.<br />
d. electrode at which matter loses electrons.<br />
Draw a complete (labels, etc.) electrochemical cell using copper and zinc.<br />
Use sulfate as the anion for aqueous solutions of each metal.<br />
7.<br />
Draw (with labels) and describe how a typical AA battery works.
Blake Schmidt - Unit 8 Page 45<br />
U8 EP5<br />
Unit 8: Example Problems 5<br />
Types of Rxns<br />
Indicate whether the following are examples of synthesis (combination), decomposition,<br />
combustion, single replacement or double replacement. The number in boldface is the<br />
SUM of the coefficients of the correctly balanced equation.<br />
1.<br />
Na3PO4 + KOH NaOH + K3PO4 8<br />
2.<br />
MgCl2 + Li2CO3 MgCO3 + LiCl 5<br />
3.<br />
C 6H 12 + O 2 CO 2 + H 2O 22<br />
4.<br />
Pb + FeSO 4 PbSO 4 + Fe 4<br />
5.<br />
CaCO3 CaO + CO2 3<br />
6.<br />
P 4 + O 2 P 2O 3 6<br />
7.<br />
RbNO 3 + BeF 2 Be(NO 3) 2 + RbF 6<br />
8.<br />
AgNO3 + Cu Cu(NO3)2 + Ag 6<br />
9.<br />
C 3H 6O + O 2 CO 2 + H 2O 11<br />
10.<br />
C5H5 + Fe Fe(C5H5) 2 4<br />
11.<br />
SeCl6 + O2 SeO2 + Cl2 6<br />
12.<br />
MgCl2 + Mn(SO3)2 MgSO3 + MnCl4 6<br />
13.<br />
Zr 2O 3 + Sn Zr + SnO 2 12<br />
14.<br />
(NH 4) 2Cr 2O 7 Cr 2O 3 + N 2 + H 2O 7
Blake Schmidt - Unit 8 Page 46<br />
U8 EP6<br />
Unit 8: Example Problems 6<br />
LOLOL Charts<br />
For questions 1-5 below, use energy bar charts to represent the ways that energy is stored in<br />
the system and flows into or out of the system. Be able to describe the arrangement and<br />
motion of the particles and how they change from the initial to the final state.<br />
1.<br />
Heating calcium carbonate decomposes it into calcium oxide and carbon dioxide.<br />
2.<br />
Solid zinc is combined with hydrochloric acid in a test tube. The test tube feels warmer.<br />
3.<br />
Isopropyl alcohol, C3H8O is burned in air.<br />
4.<br />
In some chemical cold packs, solid ammonium chloride dissolves in water forming aqueous<br />
ammonium and chloride ions.<br />
5.<br />
In some chemical hot packs, a supersaturated solution of sodium acetate forms crystals of solid<br />
sodium acetate.
Blake Schmidt - Unit 9 Page 47<br />
Unit 9: Solution Stoichiometry<br />
Molarity Lab<br />
What does that "M" on the bottle of 3.0 M HCl stand for?<br />
U9 EP1<br />
Cobalt hydroxide/Lead iodide Lab<br />
Remember how to decant? I hope so. You will need to recall a lot of information<br />
and lab techniques to perform this lab.<br />
BCA Tables Presentation<br />
U9 EP2<br />
U9 EP3<br />
U9 EP4<br />
Acids / Bases / pH Presentation<br />
Sodium hydroxide / Hydrochloric acid Lab<br />
U9 EP5
Blake Schmidt - Unit 9 Page 48<br />
Moles KCl<br />
Mass NaCl (g)<br />
U9 EP1<br />
1.<br />
Use the graph at right to determine the<br />
molarity of the potassium chloride solution.<br />
0.030<br />
0.025<br />
0.020<br />
Unit 9: Example Problems 1<br />
Molarity<br />
Slope = 0.00175<br />
0.015<br />
0.010<br />
0.005<br />
0.000<br />
0 2 4 6 8 10 12 14 16<br />
Volume (mL)<br />
140<br />
2.<br />
Use the graph at right to determine the<br />
molarity of the sodium chloride solution.<br />
120<br />
100<br />
80<br />
Slope = 0.1169<br />
60<br />
40<br />
20<br />
3.<br />
4.<br />
5.<br />
6.<br />
7.<br />
8.<br />
9.<br />
10.<br />
11.<br />
Sodium chloride was dissolved in water to produce a 1.5M solution.<br />
a. Explain what this concentration tells us about the NaCl solution.<br />
b. How might a chemist use this ratio?<br />
0<br />
0 200 400 600 800 1000 1200<br />
Volume (mL)<br />
A 45.3 g sample of potassium nitrate is dissolved in enough water to make 225 mL of solution.<br />
Determine the molar concentration of the potassium nitrate.<br />
Find the molarity of a solution made from 275 g of CuSO4 dissolved in enough water to make 4.25 L.<br />
An alcoholic iodine solution (“tincture” of iodine) is prepared by dissolving 5.15 g of iodine crystals in<br />
enough alcohol to make a volume of 225 mL. Calculate the molarity of iodine in the solution.<br />
What final volume would be needed in order to prepare a 0.25 M NaCl solution from 5.2 g of NaCl (s)?<br />
Draw a particle diagram of each of these ionic substances in solution. Then calculate the molarity of<br />
each ion present in each of the following solutions.<br />
a. 0.25 M AlCl3<br />
b. 0.375 M Na2CrO4<br />
c. 0.0020 Ca(OH)2<br />
d. 0.103 M Na3PO4<br />
How many grams of silver nitrate are needed to prepare 250. mL of standard 0.100 M silver nitrate<br />
solution?<br />
If 10.0 g of AgNO3is available, find the volume needed to prepare a 0.25 M AgNO3solution.<br />
Concentrated hydrochloric acid is made by pumping hydrogen chloride gas into distilled water. If<br />
concentrated HCl contains 439 g of HCl per liter, what is the molarity?
Blake Schmidt - Unit 9 Page 49<br />
U9 EP2<br />
Unit 9: Example Problems 2<br />
BCA Stoichiometry<br />
Begin each problem with a balanced chemical equation. Complete the BCA table using the<br />
coefficients from the balanced equation to determine the appropriate mole ratios.<br />
1.<br />
Hydrogen sulfide gas, which smells like rotten eggs, burns in air to produce sulfur dioxide and water.<br />
How many moles of oxygen gas would be needed to completely burn 8 moles of hydrogen sulfide?<br />
H2S(g) + O2(g) SO2(g) + H2O(g)<br />
M Before ___ ___ ___ ___<br />
O<br />
L Change ___ + ___ ___ + ___<br />
E<br />
S After ___ ___ ___ ___<br />
2.<br />
Propane, C3H8, burns in air to form carbon dioxide and water. If 12 moles of carbon dioxide are<br />
formed, how many moles of propane were burned?<br />
3.<br />
Ammonia for fertilizer is made by causing hydrogen and nitrogen to react at high temperature and<br />
pressure. How many moles of ammonia can be made from 0.15 moles of nitrogen gas?<br />
4.<br />
The poison gas phosgene, COCl2, reacts with water in the lungs to form hydrochloric acid and carbon<br />
dioxide. How many moles of hydrochloric acid would be formed by 0.835 moles of phosgene?<br />
5.<br />
Iron metal and oxygen combine to form the magnetite, Fe3O4. How many moles of iron can be<br />
converted to magnetite by 8.80 moles of pure oxygen? How many moles of magnetite are produced?<br />
6.<br />
The recipe for Coca-Cola Classic is a closely guarded secret, so a complete balanced equation is out.<br />
Researchers outside the company believe the flavoring mixture, known as “7X”, contains oils of orange, lemon,<br />
nutmeg, cinnamon, and coriander. The original mixture also contained caffeine, vanilla, caramel, lime juice,<br />
sugar or artificial sweetener, and citric acid. Over the years, the recipe has changed. For example, the original<br />
recipe contained citric acid but this was combined with phosphoric acid to cut production costs. Corn syrup<br />
replaced sugar for the same reason. Here is the part of the recipe that we know.<br />
C8H10N4O2 + 4 H3PO4 + 6 CO2 + other ingredients C6H5CO2K + other products<br />
caffeine phosphoric acid potassium benzoate<br />
To produce 1000 cans of Coca-Cola Classic, 40g (0.21 moles) of caffeine are reacted with phosphoric acid and<br />
other ingredients. How many moles of phosphoric acid are required? How many moles of CO2 are required?
Blake Schmidt - Unit 9 Page 50<br />
1.<br />
U9 EP3<br />
Unit 9: Example Problems 3<br />
Percent Yield<br />
Use BCA tables to complete the following problems.<br />
Using the Hoffman apparatus for electrolysis, a chemist decomposes 36 g of water into its gaseous<br />
elements. How many grams of hydrogen gas should she recover (theoretical yield)?<br />
2.<br />
Liquid sodium reacts with chlorine gas to produce sodium chloride. You want to produce 584.5 g of sodium<br />
chloride. How many grams of sodium are needed?<br />
3.<br />
You eat 180.0 g of glucose (90 M&Ms). If glucose, C6H12O6, reacts with oxygen gas to produce carbon dioxide<br />
and water, how many grams of oxygen will you have to breathe in to burn the glucose? How many grams of<br />
carbon dioxide should be produced?<br />
4.<br />
Suppose 4.61 g of zinc was allowed to react with hydrochloric acid to produce zinc chloride and hydrogen<br />
gas. How much zinc chloride should you get? Suppose that you actually recovered 8.56 g of zinc chloride.<br />
What is your percent yield?<br />
5.<br />
Determine the mass of carbon dioxide that should be produced in the reaction between 3.74 g of carbon<br />
and excess O2. What is the % yield if 11.34 g of CO2is recovered?<br />
6.<br />
In the reaction between excess K(s) and 4.28 g of O2(g), potassium oxide is formed . What mass would you<br />
expect to form (theoretical yield)? If 17.36 g of K2O is actually produced, what is the percent yield?<br />
7.<br />
Determine the mass of carbon dioxide one could expect to form (and the percent yield) for the reaction<br />
between excess CH4and 11.6 g of O2if 5.38 g of carbon dioxide gas is produced along with some water vapor.<br />
8.<br />
Determine the mass of water vapor you would expect to form (and the percent yield) in the reaction<br />
between 15.8 g of NH3and excess oxygen to produce water and nitric oxide (NO). The mass of water actually<br />
formed is 21.8 g.
Blake Schmidt - Unit 9 Page 51<br />
U9 EP4<br />
Unit 9: Example Problems 4<br />
Limiting Reactant<br />
1.<br />
Write the balanced equation for the reaction between hydrogen and oxygen.<br />
Suppose that 4 molecules of hydrogen gas and 4 molecules of oxygen gas react to form water.<br />
Make a drawing that represents the reaction container before and after the reaction.<br />
a.<br />
b.<br />
c.<br />
How many molecules of water can be produced?<br />
Which reactant is in excess? Why?<br />
How many molecules of excess reactant are there?<br />
Construct a BCA table for this reactant mixture using molecules instead of moles.<br />
Answer questions a-c using the BCA table. How, if at all, do your answers differ?<br />
Based on your two methods of analysis above, what determines how much product can be made<br />
from a particular reactant mix?<br />
2.<br />
Make a drawing that represents the reaction container before and after the reaction of 6 molecules<br />
of nitrogen and 12 molecules of hydrogen. How many molecules of ammonia can be produced?<br />
Which reactant is in excess? Why? How many molecules of excess reactant are there?<br />
Answer the same questions using a BCA table instead of the particle diagrams.<br />
Describe how you know which reactant determines how much product can be made.<br />
3.<br />
4.<br />
5.<br />
6.<br />
Use only BCA tables to answer the remaining questions.<br />
When 0.50 mole of aluminum reacts with 0.72 mole of iodine to form aluminum iodide, how many<br />
moles of the excess reactant will remain? How many moles of aluminum iodide will be formed?<br />
When sodium hydroxide reacts with sulfuric acid (H2SO4), water and sodium sulfate are the<br />
products. Calculate the mass of sodium sulfate produced when 15.5 g of sodium hydroxide are<br />
reacted with 46.7 g of sulfuric acid.<br />
A 14.6 g sample of oxygen gas is placed in a sealed container with 2.5 g of hydrogen gas. The<br />
mixture is sparked, producing water vapor. Calculate the mass of water formed. Calculate the<br />
number of moles of the excess reactant remaining.<br />
Neuroscientists believe that the only chemical in chocolate that may have a feel -good effect on the<br />
human brain is phenylethylamine (PEA). Although the PEA in chocolate occurs naturally, PEA can be<br />
made in the laboratory by the following reaction: CH 5NO2 + C8H8O C8H11N + CO2 + H2O<br />
How much PEA can be made from 75.0 g of CH5NO2 and 125g of C8H8O? What mass of the excess<br />
reactant remains?
Blake Schmidt - Unit 9 Page 52<br />
U9 EP5<br />
Unit 9: Example Problems 5<br />
Solution Stoichiometry<br />
1.<br />
How many moles of lead(II) hydroxide (solid) can be formed when 0.0225L of<br />
0.135 M Pb(NO3)2 solution reacts with excess sodium hydroxide?<br />
2.<br />
Aqueous barium nitrate reacts with aqueous sodium sulfate. Abigail places 20.00 mL of 0.500 M<br />
barium nitrate in a flask. She has a 0.225M sodium sulfate solution available. What volume of<br />
this solution must she add to her flask of barium nitrate so she has no excess reactant left over?<br />
3.<br />
Calcium chloride (aq) reacts with sodium carbonate (aq). Determine what volume of a 2.00 M<br />
calcium chloride solution would be needed to exactly react with 0.0650 L of 1.50 M Na2CO3.<br />
How many grams of sodium chloride should be produced from the reaction. How much sodium<br />
chloride will actually be produced if the percent yield for the reaction is 85%?<br />
4.<br />
The remaining problems represent all types of stoichiometry problems<br />
Calculate the number of moles of potassium chlorate (s) that must decompose to produce<br />
potassium chloride (s) and 1.8 moles of oxygen.<br />
5.<br />
Magnesium metal reacts with hydrochloric acid. What volume of 1.0 M hydrochloric acid is<br />
needed to completely react with 2.43 g of magnesium?<br />
6.<br />
Ethane, C2H6, combusts in air. What mass of oxygen is needed to react with 2.20 mol of ethane?<br />
7.<br />
Determine the mass of sodium nitrate produced when 0.73 g of nickel(II) nitrate reacts with<br />
sodium hydroxide.<br />
8.<br />
2.93 g of copper metal is placed in a 0.75 M silver nitrate solution, producing silver metal and<br />
aqueous copper(II) nitrate. The silver nitrate solution contained 1.41 g of silver nitrate. What is<br />
the volume of the silver nitrate solution? If 0.87 g of silver metal is recovered, what is % yield?<br />
9.<br />
Hydrochloric acid is added to sodium bicarbonate, producing sodium chloride, water and carbon<br />
dioxide. What is the percent yield if 4.68 g of CO2 are collected when 10.0 g of sodium hydrogen<br />
carbonate reacts with excess 3.0 M HCl?<br />
10.<br />
If 5.0 g of phosphorus and 35 g of bromine react, how many grams of phosphorus tribromide<br />
should be produced?<br />
11.<br />
Zinc sulfide and oxygen gas react to form zinc oxide and sulfur dioxide. Determine the amount<br />
of ZnO that should be produced in a reaction between 46.5 g of ZnS and 13.3 g of oxygen. What<br />
is the mass of the xs reactant?
Blake Schmidt - Unit 10 Page 53<br />
Unit 10: Gas and Energy Stoichiometry<br />
3 Containers Lab<br />
We know the volume and the number of particles, so what else must be true? Do not be afraid<br />
to make some assumptions.<br />
U10 EP1<br />
Molar Volume of a Gas Lab<br />
Using magnesium metal and hydrochloric acid, determine the volume (in L) of 1 mole of<br />
hydrogen gas at standard temperature and pressure. This volume will allow us to do a lot.<br />
Molar Gas Law Presentation<br />
U10 EP2<br />
U10 EP3<br />
Energy of Combustion Lab<br />
We have revisited gases and now we will revisit energy and thermodynamics. How much<br />
energy is released by during the combustion of candle wax?<br />
Calorimetry Presentation<br />
U10 EP4
Blake Schmidt - Unit 10 Page 54<br />
U10 EP1<br />
Unit 10: Example Problems 1<br />
Gases Again<br />
1.<br />
A can of spray paint contains nitrogen gas as the propellant. The pressure of the gas is 3.5 atm<br />
when the temperature is 20.˚C. The can is left in the sun, and the temperature of the gas increases<br />
to 50.˚C. What is the pressure in the can?<br />
2.<br />
A 90.0 mL volume of helium was collected under a pressure of 740. mmHg. At what volume would<br />
the pressure of this gas be 700 mmHg? Assume temperature is constant.<br />
3.<br />
A small bubble rises from the bottom of a lake, where the temperature is 8˚C and the pressure is<br />
6.4 atm, to the water’s surface, where the temperature is 25˚C and pressure is 1.0 atm. Calculate<br />
the final volume (in mL) of the bubble if its initial volume was 2.1 mL.<br />
4.<br />
Three gases are mixed in a 1.00 L container. The partial pressure of CO 2 is 250. mmHg,<br />
N2 is 375 mmHg and He is 125 mmHg. What is the pressure of the mixture of gases?<br />
5.<br />
What are the percentages of the gases in the above mixture?<br />
6.<br />
Our atmosphere is a mixture of gases (roughly 79% N2, 20% O2 and 1% Ar). What is the partial<br />
pressure (in mmHg) of each gas at standard pressure?<br />
7.<br />
A mixture of He and O2 gases is used by deep-sea divers. If the pressure of the gas a diver inhales is<br />
8.0 atm, what percent of the mixture should be O 2 if the partial pressure of O2 is to be the same as<br />
what the diver would ordinarily breathe at sea level?<br />
8.<br />
When you found the density of carbon dioxide gas in Unit 2, you collected the gas by displacing<br />
water. At the time, we assumed the gas was only carbon dioxide. The gas you collected actually<br />
was a mixture of CO2 and water vapor. How did water vapor get mixed in. Hint: What happens to<br />
a drop of water left on a table?<br />
9.<br />
If, on the day of the Density of a Gas Lab, the room pressure was 730. mmHg and the partial<br />
pressure of water vapor was 21 mmHg, what would be the partial pressure of the CO 2 gas?<br />
10.<br />
Suppose that when you reacted zinc with hydrochloric acid, you collected the hydrogen gas by<br />
water displacement. If the pressure in the room is 735 mmHg, and the partial pressure of the<br />
water is 22 mmHg, what would be the partial pressure of the hydrogen gas? If the volume of the<br />
hydrogen is 25.0 mL, what is the volume of the hydrogen gas alone at standard pressure?
Blake Schmidt - Unit 10 Page 55<br />
U10 EP2<br />
Unit 10: Example Problems 2<br />
Molar Gas Law<br />
1.<br />
What volume does 16.0 g of O2 occupy at STP?<br />
2.<br />
A mixture contains 5.00 g each of oxygen, nitrogen, carbon dioxide and neon gas.<br />
Calculate the volume of this mixture at STP.<br />
3.<br />
A 250 mL flask of hydrogen is collected at 763 mmHg and 35˚C by displacement of water. The<br />
vapor pressure of water at 35˚C is 42.2 mmHg. How many mol of hydrogen are in the flask?<br />
4.<br />
A weather balloon contains 65 L of helium at 20.0˚C and 0.932 atm. How many atoms of<br />
helium are in the balloon?<br />
5.<br />
What will the volume of the weather balloon from question 4 be when it rises into the<br />
stratosphere where the temperature is -61˚C and the pressure is 1.0856E-2 atm?<br />
6.<br />
A 4.44 L container holds 15.4 g of oxygen at 25.25˚C. What is the pressure in mmHg?<br />
7.<br />
How many moles of air are in a 2.65 L balloon at 22.1˚C and 1.09 atm?<br />
8.<br />
How many moles of neon are in a 0.50 L tube at STP?<br />
9.<br />
How many moles of air are in a 1.00 L tube at STP?
Blake Schmidt - Unit 10 Page 56<br />
U10 EP3<br />
Unit 10: Example Problems 3<br />
Gas Stoichiometry<br />
1.<br />
When calcium carbonate is heated strongly, carbon dioxide gas is evolved.<br />
CaCO3(s) → CaO(s) + CO2(g)<br />
If 4.74 g of calcium carbonate is heated, what volume of CO 2(g) would be produced when<br />
collected at STP?<br />
2.<br />
Zinc metal reacts vigorously with chlorine gas to form zinc chloride. What volume of chlorine gas<br />
at 25˚C and 1.00 atm is required to react completely with 1.13 g of zinc?<br />
3.<br />
Consider the following reaction:<br />
P4(s) + 6 H2(g) ––> 4 PH3(g)<br />
What mass of P4 will completely react with 2.50 L of hydrogen gas at 0˚C and 1.50 atm pressure?<br />
4.<br />
If water is added to magnesium nitride and heated, ammonia gas is produced.<br />
Mg3N2(s) + 3H2O(l) ––> 3 MgO + 2NH3(g)<br />
If 10.3 g of magnesium nitride is treated with water, what volume of ammonia gas would be<br />
collected at 20˚C and 0.989 atm?<br />
5.<br />
Nitrogen gas and hydrogen gas combine to produce ammonia gas. What volume of hydrogen gas<br />
at 25˚C and 735 mmHg is required for the complete reaction of 10.0 g of nitrogen?
Blake Schmidt - Unit 10 Page 57<br />
U10 EP4<br />
Unit 10: Example Problems 4<br />
Energy Stoichiometry<br />
1.<br />
How many kJ of heat will be released when 4.72 g of carbon reacts with excess oxygen gas to<br />
produce carbon dioxide? C + O2 CO2 ∆H° = –393.5 kJ<br />
2.<br />
How much heat should be transferred when 38.2 g of liquid bromine reacts with excess<br />
hydrogen gas to form hydrogen bromide? Is the heat being transferred from the system to the<br />
surroundings or from the surroundings to the system? H2 + Br2 2 HBr ∆H° = 72.80 kJ<br />
3.<br />
How many kJ of heat would you expect to be transferred when 6.44 g of sulfur react with<br />
excess oxygen to produce sulfur trioxide? Is this reaction endothermic or exothermic?<br />
2 S + 3 O2 2 SO3 ∆H° = –791.4 kJ<br />
4.<br />
Nitrogen gas and oxygen gas can combine to produce nitric oxide, NO. If such a reaction<br />
absorbs 88.0 kJ of heat from the surroundings, how many grams of nitrogen gas do you predict<br />
were consumed in the reaction? N2 + O2 2 NO ∆H° = 180 kJ<br />
5.<br />
Ammonia gas combines with excess oxygen gas to produce nitric oxide and water. If 256 kJ of<br />
energy were released in such a reaction, how many grams of ammonia gas were reacted?<br />
4 NH3 + 5 O2 4 NO + 6 H2O ∆H° = – 1170 kJ<br />
6.<br />
Carbon in the form of graphite combines with excess hydrogen gas to form benzene, C6H6. In<br />
the following reaction 3.95 kJ of heat were transferred. Calculate the grams of graphite reacted.<br />
Is the reaction endothermic or exothermic? 6 C + 3 H2 C6H6 ∆H° = 49.03 kJ<br />
7.<br />
How much heat will be released if 30.0 g of octane (C8H18) is burned in excess oxygen?<br />
C8H18+ 12 1/2 O2 8 CO2+ 9 H2O ∆H° = –5483.4 kJ<br />
How much heat would be released by burning one gallon of octane? The density of octane is<br />
0.703g/mL. 1 gallon = 3.79 liters.
Blake Schmidt - Unit 11 Page 58<br />
Unit 11: Quantum Theory<br />
Wave Interference Simulation<br />
Let's get familiar with waves. Just not at the beach!<br />
Properties of Waves<br />
By now, we are very familiar with the behavior of particles. But to develop our understanding<br />
of the atom further, we will need to investigate the properties of waves, including the basic<br />
mathematical relationships that describe them.<br />
Blackbody Radiation and the Photoelectric Effect Simulations<br />
These two experiments were instrumental in developing quantum theory.<br />
Do the Wave Presentation<br />
Describing Light Lab<br />
Use spectrascopes to describe the light emitted by three different sources.<br />
Emission spectra/Flame Test Lab<br />
Each element emits a unique spectra of light, like a fingerprint. We'll use a burner flame to<br />
coax several elements into emitting their unique brand of light.<br />
Atom<br />
This 3-hour BBC series will guide us through the brilliant people and thoughts that shaped<br />
quantum theory and the implications of quantum theory on society. For anyone interested in<br />
exploring quantum theory further, I highly recommend reading the book "Atom" by Piers<br />
Bizony that accompanies this video. Students should be familiar with the following scientists<br />
and concepts for the test.<br />
Albert Einstein, Brownian Motion, Louis de Broglie, Erwin Schrödinger, Wave Function,<br />
Neils Bohr, Wolfgang Pauli, Exclusion Principle, Werner Heisenberg, Copenhagen<br />
Interpretation, Quantum Jumps, Madame Curie, Ernest Rutherford, JJ Thomson, Solar<br />
System Model, Otto Hahn, Lise Meitner, Max Planck, Hans Geiger, Francis Aston, Mass<br />
Spectrometer, James Chadwick, Wilson and Penzias, Fred Hoyle, George Gamow, Paul<br />
Dirac, Richard Feynman, Murray Gell-Mann, QED, Anti-matter, Positron, Quark.<br />
U11 EP1<br />
The Quantum Atom Model Presentation<br />
U11 EP2
Blake Schmidt - Unit 11 Page 59<br />
1.<br />
2.<br />
3.<br />
4.<br />
5.<br />
6.<br />
7.<br />
U11 EP1 Unit 11: Example Problems 1<br />
Electromagnetic Spectrum<br />
Because excited hydrogen atoms always produce the same line-emission spectrum, scientists<br />
concluded that hydrogen<br />
a. had no electrons. c. released photons of only certain energies.<br />
b. did not release photons. d. could only exist in the ground state.<br />
When the pink-colored light of glowing hydrogen gas passes through a prism, it is possible to<br />
see<br />
a. all the colors of the rainbow. c. four lines of different colors.<br />
b. only lavender-colored lines. d. black light.<br />
The product of the frequency and the wavelength of a wave equals the<br />
a. number of waves passing a point in a second.<br />
b. speed of the wave.<br />
c. distance between wave crests.<br />
d. time for one full wave to pass.<br />
Visible light, X rays, infrared radiation, and radio waves all have the same<br />
a. energy. c. speed.<br />
b. wavelength. d. frequency.<br />
For electromagnetic radiation, c (the speed of light) equals<br />
a. frequency minus wavelength. c. frequency divided by wavelength.<br />
b. frequency plus wavelength. d. frequency times wavelength.<br />
If electromagnetic radiation A has a lower frequency than electromagnetic radiation B, then<br />
compared to B, the wavelength of A is<br />
a. longer. c. equal.<br />
b. shorter. d. exactly half the length of B's wavelength.<br />
According to Bohr, electrons cannot reside at ____ in the figure below.<br />
8.<br />
9.<br />
10.<br />
11.<br />
12.<br />
13.<br />
A line spectrum is produced when an electron moves from one energy level<br />
a. to a higher energy level. c. into the nucleus.<br />
b. to a lower energy level. d. to another position in the same sublevel.<br />
The Bohr model of the atom was an attempt to explain hydrogen's<br />
a. density. c. mass.<br />
b. flammability. d. line-emission spectrum.<br />
If electrons in an atom have the lowest possible energies, the atom is in the<br />
a. ground state. c. excited state.<br />
b. inert state. d. radiation-emitting state.<br />
The distance between two successive peaks on adjacent waves is its<br />
a. frequency. c. quantum number.<br />
b. wavelength. d. velocity.<br />
The wave model of light does not explain<br />
a. the frequency of light. c. interference.<br />
b. the continuous spectrum. d. the photoelectric effect.<br />
The energy of a photon is related to its<br />
a. mass. c. frequency.<br />
b. speed. d. size.
Blake Schmidt - Unit 11 Page 60<br />
1.<br />
2.<br />
3.<br />
4.<br />
5.<br />
6.<br />
7.<br />
8.<br />
9.<br />
10.<br />
11.<br />
12.<br />
U11 EP2<br />
Unit 11: Example Problems 2<br />
Quantum Atom<br />
All of the following describe the Heisenberg uncertainly principle except<br />
a. it states that it is impossible to determine simultaneously both the position and velocity<br />
of an electron or any other particle.<br />
b. it is one of the fundamental principles of our present understanding of light and matter.<br />
c. it helped lay the foundation for the modern quantum theory.<br />
d. it helps to locate an electron in an atom.<br />
All of the following describe the Schrödinger wave equation except<br />
a. it is an equation that treats electrons in atoms as waves.<br />
b. only waves of specific energies and frequencies provide solutions to the equation.<br />
c. it helped lay the foundation for the modern quantum theory.<br />
d. it is similar to Bohr's theory.<br />
The French scientist Louis de Broglie theorized that<br />
a. electrons could have a dual wave-particle nature.<br />
b. light waves did not have a dual wave-particle nature.<br />
c. the natures of light and quantized electron orbits were not similar.<br />
d. Bohr's model of the hydrogen atom was completely correct.<br />
How many quantum numbers are needed to describe the energy state of an electron in an<br />
atom?<br />
a. 1 b. 2 c. 3 d. 4<br />
The letter designations for the first four sublevels with the maximum number of electrons that<br />
can be accommodated in each sublevel are<br />
a. s:2, p:4, d:6, and f:8.<br />
b. s:1, p:3, d:5, and f:7.<br />
c. s:2, p:6, d:10, and f:14.<br />
d. s:1, p:2, d:3, and f:4.<br />
The statement that no two electrons in the same atom can have the same four quantum<br />
numbers is<br />
a. the Pauli exclusion principle. c. Bohr's law.<br />
b. Hund's rule. d. the Aufbau principle.<br />
Which of the following rules requires that each of the p orbitals at a particular energy level<br />
receive one electron before any of them can have two electrons?<br />
a. Hund's rule c. the Aufbau principle<br />
b. the Pauli exclusion principle d. the quantum rule<br />
The sequence in which energy sublevels are filled is specified by<br />
a. the Pauli exclusion principle. c. Lyman's series.<br />
b. the orbital rule. d. the Aufbau principle.<br />
Which of the following lists atomic orbitals in the correct order they are filled according to the<br />
Aufbau principle?<br />
a. 1s 2s 2p 3s 4s 3p 3d 4p 5s<br />
b. 1s 2s 2p 3s 3p 4s 3d 4p 5s<br />
c. 1s 2s 2p 3s 3p 4s 4p 3d 4d<br />
d. 1s 2s 2p 3s 3p 3d 4s 4p 5s<br />
The electron notation for aluminum is _______________________.<br />
An element with 8 electrons in its highest main energy level is a(n)<br />
a. octet element. c. Aufbau element.<br />
b. third period element. d. noble gas.<br />
Which model of the atom explains the orbitals of electrons as waves?<br />
a. the Bohr model c. Rutherford's model<br />
b. the quantum model d. Planck's theory
Blake Schmidt - Appendix Page 61<br />
Appendix<br />
Plagiarism will not be tolerated. When paraphrasing another author, students should<br />
maintain the main idea or point of the phrase using their own words, sentence structure and<br />
proper citation. The following examples of paraphrasing have been included as a guide. Avoid<br />
plagiarism because of unacceptable paraphrase. And remember, scientists generally do not use<br />
direct quotes: they paraphrase.<br />
Paraphrasing<br />
Original Text<br />
"At the moment, the evidence seems to favor an African Eve, because other genetic<br />
studies (of nuclear DNA) also point to an origin there and because that's where the<br />
earliest fossils of modern humans have been found. But wherever Eve's home was, the<br />
rival geneticists agree that she lived relatively recently, and this is what provokes<br />
anthropologists to start arguing--often with Biblical metaphors of their own."<br />
From: Tierney, J. 1988 January 11. The Search for Adam and Eve. Newsweek, 23-25.<br />
Unacceptable Paraphrase (Plagiarism)<br />
Currently, evidence points to an African Eve, since nuclear DNA studies favor the same<br />
starting point and early modern fossils of humans have been discovered there. However,<br />
no matter where Eve was from, competitive geneticists believe that she existed more<br />
recently. This makes anthropologists argue—many times with religious comparisons of<br />
their own (Tierney 1988).<br />
Acceptable Paraphrase<br />
Tierney (1988) contends that both the fossil and genetic evidence suggest an "African<br />
Eve." However, a major controversy between the geneticists and the anthropologists<br />
centers around not where Eve originated, but when, with geneticists believing in a more<br />
recent date.<br />
The following two pages provide examples of how to cite using APA format, the chosen format<br />
for most scientists. The examples show how to cite at the end of your paper (i.e. End-Text),<br />
such as in a bibliography or reference section. They also show how to cite within the body of<br />
your paper (i.e. In-Text), such as at the end of the sentence you are referencing. Please see me<br />
if you have any trouble formatting your references. I would also recommend using a citation<br />
machine: many are available on the web.
Blake Schmidt - Appendix Page 62<br />
Examples of proper citation of sources, both End-text and In-text.<br />
Journals<br />
[unknown author] (year) [title of article] [title of journal] [vol] [pages]<br />
Anonymous. 1997. Epidemiology for primary health care. International Journal of Epidemiology. 5:224-225.<br />
In-text: (Anon. 1997)<br />
[two authors] (year) [title of article] (title of journal) (vol) (pages)<br />
Bryant Pl. and Simpson P. 1984. Intrinsic and extrinsic control of growth in developing organs.<br />
Quart. Rev. BioI. 59:387-415.<br />
In-text: (Bryant and Simpson 1984)<br />
[author. 1st publ. in same year] (title of article) [title of journal] [vol (issue)] (pages)<br />
Billings S. 1992a. Mathematical notations. Journal of Chem. Engineering. 46(5):20-25.<br />
In-text: (Smith 1990, cited in Billings 1992a)<br />
[author-2nd publ. in same year] (title article) (title of journal) [vol (issue)](pages)<br />
Billings S. 1992b. Modules and Notations. Mathematical Review. 54(2):5-7.<br />
In-text: (Billings 1992b)<br />
(multiple authors) (year) (title of article) (title of journal) [vol] (number) (pages)<br />
Steiner U, Klein J, Eiser E, Budkowski A, Fetters LJ. 1992. Complete wetting from polymer mixtures.<br />
Science. 258(5085): 1122-9.<br />
In-text: (Steiner et al. 1992)<br />
Magazines and Newspapers<br />
[author) [year] [month] (title of article) [title of magazine] [pages]<br />
Richardson S. 1994 January. The Return of the Plague. Discover, 69-70.<br />
In-text: (Richardson 1994)<br />
[two authors] [year] (mo/day) [title of article] [title of newspaper] [sec:pg] [col]<br />
Rensberger B. and Specter B. 1989. Aug. 7 CFCs may be destroyed by natural<br />
process. Washington Post. A:2(col 5).<br />
In-text: (Rensberger and Specter 1989)<br />
(unknown author) (year) (mo/day) (title of article) (title of newspaper) (sec page)<br />
Anonymous. 1990 Aug 24. Gene data may help fight colon cancer. Los Angeles Times. A:4.<br />
In-text: (Anon. 1990)<br />
Books and Book Chapters<br />
(author) (year) (title of book ) (publisher) (place of publ.)<br />
Ling GN. 1984. In Search of the Physical Basis of Life. Plenum Press; New York.<br />
In-text: (Ling 1984)<br />
[organization/publisher as author] (year) [title of book] [place of publ.]<br />
IOS-International Organization for Standardization. 1979. Statistical methods. Geneva.<br />
In-text: (IOS 1979)<br />
[author of chapter] [year] [title of book chapter] [page numbers] [in] [editor of book] [title of book]<br />
[publisher of book ] [place of publication]<br />
Southwood TRE. 1981. Bionomic strategies and population parameters. Pages 50-52. In RM. May, ed.<br />
Theoretical Ecology. Sinauer Associates, Sunderland, MA.<br />
In-text: (Southwood 1981)
Blake Schmidt - Appendix Page 63<br />
Examples of proper citation of sources, both End-text and In-text.<br />
Pamphlets<br />
[organization as author] [no year given] [title of pamphlet] [place of publication]<br />
Humane Society. n.d. Care of critically ill pets. Washington, D.C.<br />
In-text: (Humane Society n.d.)<br />
Government Documents/Reports/Publications<br />
(government organization as author) [mo/year] (title of report) (place of publication)<br />
(government documentation number]<br />
NIH-National Institutes of Health (US). Dec. 1988. Report of the Human Fetal Tissue Transplantation Panel,<br />
consultants to the Advisory Committee to the Director. NIH. Bethdsda (MD): PB90-155268,<br />
PB90-155276.<br />
In-text: (NIH 1988)<br />
(two authors) (year) (title of government report) (report number) (publisher of report) [place of publ.]<br />
Lassiter RR. and Cooley JL. 1983. Prediction of ecological effects of toxic chemicals, overall strategy and<br />
theoretical basis for the ecosystem model EP A-600/3-83-084. National Technical Information Service<br />
PB 3-261-685, Springfield, V A.<br />
In-text: (Lassiter and Cooler 1983)<br />
Conference Papers<br />
[author] [year] (title of conference paper) [organization for whom paper was presented]<br />
[place of conference] [date of conference]<br />
O'Leary DS. 1983. Risks and benefits of cooperating with the media. Paper presented at the annual meeting<br />
of the American Association of the Advancement of Science, Washington, D.C., 8 January 1982.<br />
In-text: (O'Leary 1983)<br />
Web Sites<br />
[unknown author] [year] [title of article] [complete web address] [date you accessed the web page]<br />
Anonymous. 1996. Use of wildland fire. http://www.fs.fed.uslIandlwdfire7a.htJDl Accessed 15 August 1997.<br />
In-text: (Anon. 1996)<br />
(corporation as author) (no date given) [title of article] [complete web address) [date accessed]<br />
Aquatic Conservation Network. n.d. Aquatic Conservation. http://www.tnews.com/textlwetlands.html<br />
Accessed 17 August 1997.<br />
In-text: (Aquatic Cons n.d.)<br />
[author] [year] [title of article] [complete web address] [date accessed]<br />
Tardent P. 1995. Cell Biology, annual report. http://www.unizh.ch/-zoo/depts/celllreport94.htmI<br />
Accessed 25 July 1997.<br />
In-text: (Tardent 1995)<br />
Video/TV Programs<br />
[editor of program] [year] [title of program] [production company] [place of prod] [sponsored by]<br />
Wood RM. editor. 1989. New horizons in esthetic dentistry [videocassette]. Visualeyes Productions,<br />
producer. Chicago: Chicago Dental Society.<br />
In-text: (Wood 1989)
Blake Schmidt - Appendix Page 64<br />
Participation<br />
<strong>Chemistry</strong> is a science, and science is a verb; therefore, participation is a vital<br />
component to your success in chemistry. In order for this class to work its best,<br />
we need you to contribute positively. Simply showing up and going through the<br />
motions will not increase your participation score. Below is a list of some of the<br />
ways that your actions will effect your participation grade.<br />
Positive Contributions Increase Your Participation Score:<br />
You maintain a notebook complete with lab write-ups and reflections<br />
You think critically before speaking/presenting<br />
You make detailed observations<br />
You attempt to complete all example problems<br />
You clean-up after yourself AND others<br />
You work well with your lab partner(s)<br />
You help others understand<br />
You share when appropriate<br />
Others value your ideas/observations<br />
You add unique perspectives<br />
Negative Contributions Decrease Your Participation Score:<br />
You neglect to take notes, write lab reflections, or do example problems<br />
You're not prepared (e.g. no calculator, markers or notebook)<br />
You do other stuff (e.g. homework, read a book, iPod)<br />
You neglect to clean-up or put stuff away<br />
You do not follow directions<br />
You play with or break lab equipment<br />
You pose a danger to yourself and others during lab<br />
You do not respect your classmates<br />
Remember, we need you. Your opinions/ideas/observations are important and<br />
need to be shared to help you and others understand. A team never succeeds<br />
when its players just show up and go through the motions.