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Chemistry Manual 2012-2013 - Edison State College

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Blake Schmidt Page 1<br />

Modeling<br />

<strong>Chemistry</strong><br />

Honors<br />

Course <strong>Manual</strong>


Blake Schmidt - Introduction Page 2<br />

Welcome to Modeling <strong>Chemistry</strong> - Honors.<br />

You are about to embark on a<br />

learning experience unlike any<br />

other you have had in school.<br />

Modeling <strong>Chemistry</strong>-Honors is first and foremost a course in science. As such,<br />

your role in this class will be more often as a scientist than as a traditional student.<br />

Exactly what that means will soon become clear. For now, however, you need to<br />

know that this course will demand a lot from you. You will need to be active both<br />

inside and outside of the classroom: observing, experimenting, researching,<br />

reviewing, studying and practicing nearly every day.<br />

Our journey through chemistry is<br />

comparable to the construction of a<br />

building. Not only will you need to establish<br />

a strong foundation, but each subsequent<br />

level will need to be strong as well. If any<br />

level is incomplete, neglected, or just<br />

constructed poorly, the entire building is<br />

threatened. The same is true for this<br />

course. We will build continually on our<br />

knowledge of chemistry. If you fail to<br />

complete any one section in its entirety, you<br />

will impair your ability to build further. And<br />

yes, the final is cumulative.<br />

Acknowledgments<br />

The Modeling <strong>Chemistry</strong> Curriculum is a product of the Modeling Instruction Program. For information about<br />

Modeling Instruction, please visit http://modeling.asu.edu. This specific manual has been created by Blake<br />

Schmidt to supplement the Modeling <strong>Chemistry</strong> Curriculum. It follows the Modeling Instruction Curriculum<br />

very closely, but not exactly. The overwhelming majority of the labs and worksheets (i.e. Example Problems)<br />

are Modeling Instruction materials, but this exact manual is not a direct product of Modeling Instruction.<br />

Therefore, Blake Schmidt is fully responsible for any errors or deviations from the Modeling Curriculum.<br />

The author remains gratefully for the advice and assistance of Michael Mitchell, Frank Lock, and ACS -Hach<br />

Scientific for their aid in the formation of this manual. I also thank my past students for their helpful inputs.


Blake Schmidt - Introduction Page 3<br />

Course Syllabus<br />

This syllabus outlines the expectations<br />

students will need to meet in order to be<br />

successful in chemistry. This syllabus should be<br />

considered as a supplement to Charlotte<br />

County Public School's policies as described in<br />

the “Code of Student Conduct.” You are<br />

responsible for knowing and following these<br />

guidelines.<br />

Point Breakdown: Each quarter<br />

grade will be based on points<br />

earned in the following categories:<br />

Tests & Quizzes…………………….70%<br />

Participation……………...….…….20%<br />

Lab Reports…………………….……10%<br />

Semester grades will be based on<br />

35% for each quarter and 30% for<br />

the semester examination.<br />

Participation: Major concepts will be broken down into units (see Basic Plan of Attack). Each unit will consist<br />

mainly of laboratories and whiteboard classroom discussions. The fundamental concepts will be developed<br />

during these exercises. Each student is expected to participate in a positive manner toward the development<br />

of these concepts and to maintain a notebook. Students begin with a 75% (C) for participation. Each positive<br />

contribution adds to this score. Minimal participation will result in deduction, and negative participation (e.g.<br />

disruptive behavior) will result in major deduction (see Participation in Appendix).<br />

Tests and Quizzes: Students should expect to be quizzed for understanding as concepts are developed. Each<br />

unit may have one or two small quizzes and they may be unannounced. The overwhelming majority of points<br />

for this category, however, will be earned during tests. Each unit concludes with a test. Note that 70% of a<br />

quarter grade will be based on two or three tests. There will be an opportunity during office hours to earn<br />

back up to half of missed test points for most, but not all, tests. To repair a test, students will need to answer a<br />

new set of questions similar to those missed on the test. The total percentage of points earned back on the<br />

test will be determined by the percentage of questions answered correctly (100% correct = 50% back, 75%<br />

correct = 37.5% back, 50% correct = 25% back, 10% correct = 5% back, etc.). Students are encouraged to<br />

review their test with the instructor during office hours prior to attempting to answer the new questions. Test<br />

repair will be available during office hours for the entirety of the quarter in which the test was given.<br />

Lab Reports: Students are expected to write a complete PPOWR lab report for each lab. All lab reports are due<br />

the next school day following the completion of a lab. Each lab report will be assessed quickly for completion<br />

as a participation grade. Three lab reports will be formally assessed for content each quarter. Students will<br />

choose the three lab reports they submit for grading, but these must be submitted on the normal due date for<br />

that lab. Students can not submit lab reports for formal grading after that lab's due date.<br />

Academic Honesty: To make this class work its best, I encourage you to discuss and process information with<br />

friends, family, Google, and even Wikipedia (I especially recommend Wikipedia). At the same time, you cannot<br />

attempt to claim someone else’s work or thoughts as your own. You must give credit where credit is due:<br />

Always provide a reference. Make sure you are familiar with the difference between an acceptable<br />

paraphrase and plagiarism (see Appendix). I take cheating very seriously and will not tolerate plagiarism. Any<br />

plagiarized assignment will receive a failing grade and further action may be warranted depending on previous<br />

record (i.e. course failure). Consider yourself duly warned.


Blake Schmidt - Introduction Page 4<br />

Materials: Students are expected to bring these materials to class EVERYDAY:<br />

• Pens or pencils<br />

• Sturdy notebook - Whatever you like best.<br />

• Scientific Calculator with Log function (e.g. Texas Instruments TI-30Xa)<br />

Cell Phones Are NOT Calculators!<br />

• Dry Erase Markers (Expo markers are recommended)<br />

• Ability and eagerness to think<br />

Expectations: Students earning an A (>89.5%) will demonstrate a mastery<br />

of concepts and lab techniques that far exceeds expectations, as well as<br />

exceptional scientific writing and presentation skills. These students<br />

frequently lead and support their classmates and help others understand<br />

the material. B (89.4%-79.5%) students demonstrate great<br />

understanding of concepts and lab techniques, with work distinguished in<br />

most areas but not all. These students frequently demonstrate an ability<br />

to process information independently and share knowledge with others.<br />

C (79.4%-69.5%) students are defined as average, or meeting<br />

expectations. These students demonstrate a good understanding and<br />

ability to answer questions, but rarely expand or provide independent<br />

thought. D (69.4%-59.5%) students demonstrate a fair understanding and<br />

ability to answer questions, but are below the average level of their<br />

classmates. Students earning an F (


Blake Schmidt - Introduction Page 5<br />

Laboratory Safety Agreement<br />

If there is an emergency, inform the instructor immediately.<br />

Safety in the laboratory is very important. You must obey the following rules and behave in an<br />

appropriate manner at all times. Before you begin any experiment, you must be familiar with the<br />

procedure. Be sure you know where to put the waste. All damaged glass must be disposed in the<br />

sharps waste container. Make sure you know where the fire extinguisher, fire blanket, and eye-wash<br />

station are located.<br />

Appropriate attire is required for lab safety.<br />

• Eye protection must be worn over the eyes at all times.<br />

• We recommend that you do not wear contact lenses.<br />

• You must wear closed toe shoes.<br />

• Keep long hair pulled back.<br />

• Clothes that cover the body and legs are highly recommended.<br />

Responsible behavior is required for lab safety.<br />

• Eating and drinking are not allowed in the lab.<br />

• Wash hands frequently while in the lab and at the end of each lab period.<br />

• Gloves should be used when handling toxic or corrosive chemicals.<br />

• Never use an open flame in the vicinity of flammable substances.<br />

• Keep your face away from the opening of the vessel when mixing reagents, when applying heat,<br />

or when testing for an odor.<br />

Etiquette is necessary for lab safety.<br />

• At the end of each lab, make sure you clean your lab bench and put your chair away.<br />

• All materials should be cleaned and left to dry or put back in the appropriate place.<br />

Hazard Warning: CAUTION---the solids, liquids and gaseous substances, and combinations thereof,<br />

used in experiments are potentially hazardous in one or more of the following ways:<br />

• they may be irritants to, or have caustic action on, the skin, mucous membranes, lungs, and eyes.<br />

• they may be systemic poisons.<br />

• they may be flammable or explosive.


Blake Schmidt - Introduction Page 6<br />

○<br />

○<br />

○<br />

○<br />

Semester One<br />

Welcome to Modeling <strong>Chemistry</strong>-Honors<br />

• Introduction/Expectations PPT<br />

• Syllabus (Signatures)<br />

• <strong>Chemistry</strong> Concepts Inventory<br />

• Expectations Quiz<br />

Unit 1: What is Science?<br />

• Student Presentations (Science is…)<br />

• The Scientific Method PPT<br />

• McPherson Paper<br />

• Acting Scientifically PPT<br />

• Dimensional Analysis PPT<br />

• Test<br />

Unit 2: Identifying Matter<br />

• Lab/Whiteboard Expectations Lab<br />

• Mass and Change Labs<br />

• Conservation of Matter PPT<br />

• Volume Lab<br />

• Mass and Volume Lab<br />

• Density of a Gas Lab<br />

• Thickness of Al Foil Lab<br />

• Test<br />

Unit 3: Physical Properties of Matter<br />

• Release the Gas Lab<br />

• Hot vs. Cold Lab<br />

• Thermal Expansion Lab<br />

• Sea Level and Global Warming PPT<br />

• Crush Can Lab<br />

• Straw Presentations<br />

• Weather and Atmosphere PPT<br />

• Pressure, Number of Particles, Temperature, and<br />

Volume Labs<br />

• Test<br />

○<br />

○<br />

○<br />

○<br />

Basic Plan of Attack<br />

Semester Two<br />

Unit 6: Naming Compounds<br />

• Naming Molecular Compounds PPT<br />

• Naming Ionic Compounds PPT<br />

• Test<br />

Unit 7: Counting Particles<br />

• 5 Balloons Lab<br />

• 5 Balloons Hypothesis PPT<br />

• Relative Mass Lab<br />

• The Mole PPT<br />

• Empirical Formula Lab<br />

• MgxOy Lab<br />

• Magnesium sulfate ∙ ?-hydrate Lab<br />

• Test<br />

Unit 8: Chemical Reactions<br />

• Nail Lab<br />

• Galvanized Nail Lab<br />

• Electrochemistry PPT<br />

• Chemical Reactions Lab<br />

• Chemical Change Lab<br />

• Energy in Reactions PPT<br />

• Test<br />

Unit 9: Solution Stoichiometry<br />

• Molarity Lab<br />

• Lead iodide/Cobalt hydroxide Lab<br />

• BCA Tables PPT<br />

• Acids/Bases/pH PPT<br />

• Sodium Hydroxide/Hydrochloric Acid Lab<br />

• Test<br />

○<br />

○<br />

Unit 4: Thermodynamics<br />

• Heat vs. Temperature Lab<br />

• Icy Hot Lab<br />

• Energy and Change PPT<br />

• Lauric Acid/Candle Wax Labs<br />

• Heat is On PPT<br />

• Temperature of Bunsen Burner Flame Lab<br />

• Heat Capacity of Steel/Anti-Freeze Labs<br />

• Absolute Zero<br />

• Test<br />

Unit 5: Classifying Matter<br />

• Solubility of Sugar Lab<br />

• Solubility and Solutions PPT<br />

• Sand and Salt Lab<br />

• Electrolysis of Water Lab<br />

• Classifying Matter/Periodic Table PPT<br />

• Sticky Tape Lab<br />

• Atomic Theory PPT<br />

• Conductivity Lab<br />

• Melting Point Lab<br />

• Molecular Compounds PPT<br />

• Ionic Compounds PPT<br />

• Metallic/Covalent Networks PPT<br />

• Unknowns Lab<br />

• Test<br />

• Midterm Examination<br />

○<br />

○<br />

Unit 10: Gas and Energy Stoichiometry<br />

• 3 Containers Lab<br />

• Molar Volume of Gas Lab<br />

• Molar Gas Law PPT<br />

• Energy of Combustion Lab<br />

• Calorimetry PPT<br />

• Test<br />

Unit 11: Quantum Theory<br />

• Wave Interference Simulation<br />

• Properties of Waves<br />

•<br />

• Do the Wave PPT<br />

• Describing Light Lab<br />

• Emission Spectra/Flame Test Lab<br />

• Atom<br />

• The Quantum Atom Model PPT<br />

• Test<br />

• <strong>Chemistry</strong> Concepts Inventory<br />

• Final Examination (Cumulative)<br />

Blackbody Radiation/Photoelectric Effect<br />

Lab/Whiteboard<br />

PowerPoint Presentation<br />

Video


Blake Schmidt - Unit 1 Page 7<br />

Unit 1: What is Science?<br />

Student Presentations (Science is…)<br />

Prepare a 2-4 minute oral presentation that answers the question, "what is science?"<br />

Keep your opinion/thoughts as the focus. Do not provide a textbook definition.<br />

As you define science, please try to also answer the following questions:<br />

Is science good or bad?<br />

Of what use is science?<br />

Who does science?<br />

What, if anything, does science produce?<br />

After hearing the presentations, reflect on your answer. Has your opinion changed at all?<br />

It is highly recommended that you formalize your thoughts by putting them into your<br />

notebook. By writing such a reflection, you challenge your mind to think more deeply<br />

about the topic and you provide yourself with an invaluable resource for reviewing.<br />

The Scientific Method<br />

In order to view PowerPoint presentations from the course website, you may need to<br />

download Microsoft's PowerPoint Viewer, which is available from Microsoft's website:<br />

http://www.microsoft.com/downloads/details.aspx?FamilyID=<br />

048dc840-14e1-467d-8dca-19d2a8fd7485&DisplayLang=en<br />

McPherson G. 2001. Teaching & Learning the Scientific Method.<br />

The American Biology Teacher 63 (4): 242-245.<br />

Hypothesis Formation may be the most important part of the scientific method. Let's<br />

figure out how to form a good hypothesis.<br />

U1 EP1<br />

Acting Scientifically<br />

U1 EP2<br />

Dimensional Analysis (Conversions)<br />

U1 EP3


Blake Schmidt - Unit 1 Page 8<br />

U1 EP1<br />

Unit 1: Example Problems 1<br />

The Scientific Method<br />

1.<br />

True or False. All scientists use the same scientific method for all scientific endeavors. Why or why not?<br />

2.<br />

List the 7 steps of the basic scientific method presented in class.<br />

3.<br />

Hypothetically go through all the steps of the scientific method yourself. For example, you may have<br />

noticed that grass grows poorly next to sidewalks on campus. Why? Form a hypothesis, a prediction, a<br />

hypothetical experiment, etc. Do not use this example: come up with your own original example.<br />

4.<br />

How is a hypothesis different from a prediction?<br />

5.<br />

Why is it important to distinguish a hypothesis from a prediction?<br />

6.<br />

In January 2005, Bobby Henderson proposed the existence of an intelligent designer known as Flying<br />

Spaghetti Monster (FSM). By August 2005, BoingBoing.net offered $1 million to anyone that could prove<br />

that Jesus was NOT the son the of FSM. Why was BoingBoing.net confident enough to stake a million<br />

dollars against anyone finding such evidence?<br />

7.<br />

How does Pastafarianism (belief in FSM) demonstrate a difference between science and religion and the<br />

danger of teaching non-science in a science classroom?


Blake Schmidt - Unit 1 Page 9<br />

U1 EP2 Unit 1: Example Problems 2<br />

Accuracy/Precision/Significant Figures<br />

1.<br />

Explain how a series of measurements can be precise without being accurate.<br />

2.<br />

Why are significant figures important when reporting measurements?<br />

3.<br />

Suppose a graduated cylinder was not calibrated correctly. How would this effect the results of<br />

a measurement? How would it effect the results of a calculation using this measurement?<br />

4.<br />

5.<br />

6.<br />

How many significant figures are there in each of the following numbers?<br />

a. 0.4004 m<br />

b. 6000 g<br />

c. 1.00030 km<br />

d. 400 mL<br />

Write the following numbers in scientific notation.<br />

a. 0.0006730 g<br />

b. 7500 km<br />

c. 602.2 mm<br />

d. .0094 mg<br />

Calculate the sum of 6.078 g and 0.3329 g.<br />

7.<br />

Subtract 7.11 cm from 8.2 cm.<br />

8.<br />

What is the product of 0.8102 m and 3.44 m?<br />

9.<br />

Divide 94.20 g by 3.16722 mL.<br />

10.<br />

A large building is 1.02 x 10 2 m long, 31 m wide, and 4.25E2 m high. Calculate the volume.


Blake Schmidt - Unit 1 Page 10<br />

U1 EP3<br />

Unit 1: Example Problems 3<br />

Dimensional Analysis<br />

1.<br />

A quarterback throws for 350. yards in a game. How many feet? How many inches?<br />

2.<br />

A car traveling at 75 miles per hour will travel what distance in 90. minutes?<br />

3.<br />

A bullet is fired at 1500. feet per second. How many miles per hour?<br />

4.<br />

A car travels at 100. miles per hour. How many feet per second?<br />

5.<br />

A patient takes 2000. mg of Tylenol. How many grams? How many kg?<br />

6.<br />

What is the mass in kilograms of a 2.2E5 g container of fertilizer?<br />

7.<br />

A horse travels 244 furlongs in a fortnight. How many miles per hour was the horse traveling?<br />

A furlong is 1/8 mile and a fortnight is 2 weeks.<br />

8.<br />

The drug Surital can be used as a pre-anesthetic at a dosage of 1.0 mL per 5.0 lbs. How much<br />

Surital should be given to a dog that is 19 kg? 1 kg = 2.2 lbs.<br />

9.<br />

To reduce salivation when using Surital, atropine can be used at a dosage of 1.0 cc per 20. lbs.<br />

How much atropine should be used for a 4.5 kg cat? 1 cc = 1 mL.<br />

10.<br />

Ketomine can be used as an intramuscular anesthetic for cats. The dosage is 15.0 mg per lb.<br />

The ketomine is available in bottled form with a concentration of 100. mg per cc. How many cc<br />

are needed for a 7.21 kg cat?<br />

11.<br />

A man suffers a heart attack. The responding paramedic estimates the man to be 175 lbs.<br />

Epinephrine is injected into the trachea at 1.0 cc per 10. kg. How much epinephrine should be<br />

administered to this man?


Blake Schmidt - Unit 2 Page 11<br />

Unit 2: Identifying Matter<br />

Lab/Whiteboard Expectations Lab<br />

The purpose of this lab is to familiarize you with experimenting and whiteboarding in chemistry.<br />

The majority of labs will be very similar to this lab in terms of format. You will not be given a detailed<br />

list of steps to follow. You will, however, be given a basic overview of the lab and made aware of any<br />

special items. Because you will be tested on the concepts and techniques developed during labs, it is<br />

critical to keep thorough and organized notes. An example of notes for this lab has been included.<br />

You should follow a similar format for all other labs.<br />

Mass and Change Labs<br />

The following six labs will help us identify and understand matter:<br />

1. Clumped/Separate Steel Wool<br />

4. Solid/Dissolved Alka-Seltzer<br />

2. Ice/Liquid Water<br />

5. Burnt Steel Wool<br />

3. Solid/Dissolved Sugar<br />

6. Solid from Liquids<br />

After completing all the labs, form a hypothesis to explain all of your observations about mass.<br />

U2 EP1<br />

Conservation of Mass Presentation<br />

Volume Lab<br />

Now that you have a grasp of mass, you can learn about volume. In this lab, you will investigate the<br />

relationship between volume measured with a ruler and volume measured with a graduated cylinder.<br />

Mass and Volume Lab<br />

With mass and volume under your belt, investigate how these two quantities of matter are related.<br />

U2 EP2<br />

Density of a Gas Lab<br />

How does the density of a gas compare with a liquid or solid? What must be true about the particles<br />

that make up a gas? What about the particles in a liquid or solid?<br />

Thickness of Aluminum Foil Lab<br />

Combine your understanding of mass and volume with your mastery of math and determine the<br />

thickness of aluminum foil. If you have time, compare how heavy-duty foil measures up with regular?<br />

U2 EP3


Blake Schmidt - Unit 2 Page 12<br />

Example Notes<br />

Unit 2 Expectations Lab<br />

Purpose: become familiar with labs and whiteboards (W/B)<br />

Procedure: Fill 1000 ml beaker with water.<br />

3 test tubes with water (1 = 10% full; 2 = 50%; 3 = 100%).<br />

Seal with thumb and then flip test tube into water.<br />

Place a piece of calcium carbide into 1000 ml beaker.<br />

Trap gas coming off calcium carbide in test tube.<br />

Flame test for each.<br />

Observations: Water stays in upside-down test tube in beaker.<br />

Calcium carbide bubbles when placed in water, releasing gas.<br />

(10% filled with water) Exploded-flame shot out of test tube and made a<br />

loud whistle.Test tube was cool afterwards and did not have any residue.<br />

(50%) Ignited gas made a relatively small flame that traveled down the<br />

test tube rather quickly and then went out. The test tube turned black<br />

and warmed a little. Black ash came out of the tube and floated<br />

around the room.<br />

(100%) Ignited gas made a small flame that burned for about 15<br />

seconds just a little down into the tube (close to the top of tube). Flame<br />

then went out and top of test tube was hot. No ash or black residue.<br />

Whiteboard Particle Diagrams<br />

100 % 50% 10%<br />

AIR<br />

ASH<br />

FLAME<br />

GAS<br />

Reflection: I need to make sure I keep the room neat and clean, and wear<br />

goggles. I also need to really think about what I put on my whiteboard.<br />

For example, if there are two types of gases in my test tube, I should draw<br />

both. I also need to be specific with my drawings so that others know what<br />

I’ve drawn: like using different symbols or colors to represent different types<br />

of particles. I also need to pay attention to other presentations and make<br />

sure others thought of the same stuff I, or my group, did. One question that<br />

I should ask myself often is “how do I know?” This question will help me put<br />

my thoughts onto paper and into my presentations, and we need to<br />

demonstrate our thoughts. As far as the experiment goes, I think the way<br />

the gas burns depends mostly on how much air is mixed into it.


Blake Schmidt - Unit 2 Page 13<br />

U2 EP1<br />

Unit 2: Example Problems 1<br />

Mass and Change<br />

1.<br />

When you pulled the steel wool apart, you found that the mass was unchanged. When you heated the<br />

steel wool, you found that the mass changed. Explain.<br />

Draw diagrams (at the particle level) of the steel wool before and after the change.<br />

Clumped/Separated<br />

Before Heating/After Heating<br />

2.<br />

When ice melts, the volume of water is smaller than that of the ice. How does the mass of the water<br />

compare to the mass of the ice?<br />

Draw diagrams of the ice and water. Use small circles to represent the water particles.<br />

3.<br />

When the sugar dissolved in the water, you found that the mass remained unchanged. When the Alka-<br />

Seltzer dissolved in the water, the mass of the system changed. Explain.<br />

Draw diagrams of each of the materials before and after it was dissolved.<br />

Solid Sugar/Dissolved Sugar<br />

Solid Alka-Seltzer/Dissolved Alka-Seltzer<br />

4.<br />

Form a hypothesis to explain the observations from the Mass and Change labs.


Blake Schmidt - Unit 2 Page 14<br />

U2 EP2<br />

Unit 2: Example Problems 2<br />

Mass, Volume and Density<br />

1.<br />

Study the matter shown to the right. Assume the<br />

particles are uniformly distributed throughout each<br />

object and particles of the same size have the same<br />

mass. In the table below, show how the masses,<br />

volumes and densities of A and B compare by adding<br />

the symbol or = to the statement in the second<br />

column. Explain your reasoning for each answer.<br />

A<br />

B<br />

Property<br />

Mass<br />

Volume<br />

Density<br />

Relationship Reasoning<br />

A ____ B<br />

A ____ B<br />

A ____ B<br />

2.<br />

Study the matter shown to the right. Assume the<br />

particles are uniformly distributed throughout each<br />

object and particles of the same size have the same<br />

mass. In the table below show how the masses,<br />

volumes and densities compare by adding the symbol<br />

or = to the statement in the second column.<br />

Explain your reasoning for each answer.<br />

C<br />

E<br />

D<br />

Property<br />

Mass<br />

Volume<br />

Density<br />

Relationship Reasoning<br />

C ____ D<br />

C ____ E<br />

D ____ E<br />

C ____ D<br />

C ____ E<br />

D ____ E<br />

C ____ D<br />

C ____ E<br />

D ____ E<br />

3.<br />

Is object F or object G more dense? Assume the<br />

particles are uniformly distributed throughout each<br />

object, and particles with a larger size have a larger<br />

mass. Explain your reasoning.<br />

F<br />

G


Blake Schmidt - Unit 2 Page 15<br />

U2 EP2<br />

Unit 2: Example Problems 2<br />

Mass, Volume and Density<br />

Mass (g)<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

Substance A<br />

Substance B<br />

0 10 20 30 40 50 60 70 80<br />

Volume (mL)<br />

4.<br />

The graph above shows the relationship between mass and volume for two substances.<br />

Use the graph above to answer the following questions.<br />

a.<br />

You have built a simple two-pan balance to<br />

compare the masses of substances A and B. What<br />

would happen to the balance if you put equal<br />

masses of A and B in the two pans? What would<br />

happen if you put equal volumes of A and B in the<br />

two pans? Explain your reasoning.<br />

b.<br />

Write equations for both substances. What does the slope physically represent? What<br />

does it tell you about these substances?<br />

c.<br />

What mass of Substance B would be needed to balance the pans if 10 mL of Substance A<br />

is in one pan? Explain your reasoning.<br />

d.<br />

What volume of Substance A would be needed to balance the pans if 35 mL of Substance<br />

B is in one pan? Explain your reasoning.<br />

e.<br />

f.<br />

Water has a density of 1.00 g/mL. Sketch a line to represent water on the graph above.<br />

Determine whether substance A and B will sink or float when placed in a bucket of water.<br />

A: sink / float B: sink / float (circle correct response)<br />

Defend your answer using the graph, and your outstanding understanding of density.


Blake Schmidt - Unit 2 Page 16<br />

U2 EP2<br />

Unit 2: Example Problems 2<br />

Mass, Volume and Density<br />

Substance Density (g/mL)<br />

Aluminum……....2.70<br />

Titanium…...…...4.54<br />

Zinc…………...…..7.13<br />

Tin…………...…….7.31<br />

Iron………...……..7.87<br />

Nickel……...…….8.90<br />

Copper……...…..8.96<br />

Silver………...….10.50<br />

Lead………...…..11.35<br />

Mercury…...…..13.35<br />

Gold………...…..19.30<br />

5.<br />

6.<br />

Sketch a graph of mass vs. volume for titanium, copper and mercury.<br />

Suppose you made some cubes out of each metal in the table. Each measures 2.00 cm on every side.<br />

(all except mercury – why can you not make a cube of mercury?)<br />

a. What is the volume of each cube in cm 3 ? in mL? (Show your work)<br />

V = ______ cm 3<br />

V = ______ mL<br />

b.<br />

Find the mass of the following metal cubes:<br />

lead cube _____________<br />

nickel cube _____________<br />

zinc cube _____________<br />

(Show your work)<br />

7.<br />

Alicia's cheapskate boyfriend gave her a ring he claims is 24-carat gold. Alicia is skeptical. She<br />

measures the mass of the ring (15.28 g) and finds the volume of the ring by water displacement<br />

(initial volume 42.2 mL, final volume 43.7 mL). Should she treasure the ring as his first truly generous<br />

gift to her, or throw it at him the next time he walks by? Defend your answer.<br />

8.<br />

A student filled a graduated cylinder with water and read the meniscus at 25.8 mL. The student then<br />

dropped a solid material into the graduated cylinder and the water level rose to 35.9 mL. If the solid<br />

material had a density of 2.99 g/mL, determine the mass of the solid object.


Blake Schmidt - Unit 2 Page 17<br />

U2 EP3<br />

Unit 2: Example Problems 3<br />

Mass, Volume, and Density<br />

1.<br />

2.<br />

3.<br />

4.<br />

5.<br />

6.<br />

7.<br />

8.<br />

9.<br />

10.<br />

11.<br />

12.<br />

13.<br />

Ethanol has a density of 0.789 g/cm 3 .<br />

a. What is the mass of 225 cm 3 of ethanol?<br />

b. What is the volume of 75.0 g of ethanol?<br />

The cup is a volume widely used by cooks in America. One cup is equivalent to 225 cm 3 . If 1.00 cup<br />

of olive oil has a mass of 205 g, what is the density of olive oil in g/cm 3 ?<br />

What would you expect to happen if the cup of olive oil is poured into a container of ethanol?<br />

Gold has a density of 19.3 g/ cm 3 . A cube of gold measures 4.23 cm on each edge.<br />

a. What is the volume of the cube?<br />

b. What is its mass?<br />

Your standard backpack is 30. cm x 30. cm x 40. cm. Suppose you find a hoard of pure gold while<br />

treasure hunting in the wilderness. How much mass would your standard backpack hold if you filled<br />

it with the gold? An average student has a mass of 70. kg. How do these values compare?<br />

A kilogram is about 2.2 pounds. A 70. kg person is how many pounds? How many pounds of gold are<br />

in the backpack?<br />

An object measures 3.0 cm tall, 4.0 cm wide, and 5.0 cm long. How many mL?<br />

Use the density table from U2 EP2 to help you answer the following questions.<br />

What is the mass of 10. mL of aluminum?<br />

What is the volume of 15 g piece of lead?<br />

A piece of metal is 14 g and has a volume of 5.19 mL. What kind of metal is it?<br />

You are given 10. mL of aluminum and 10. mL of lead.<br />

a. Which piece is larger?<br />

b. Which has more mass?<br />

c. Which is denser?<br />

d. How many grams of lead?<br />

You are given 50. g of zinc and 50. g of tin.<br />

a. Which piece is larger?<br />

b. Which has more mass?<br />

c. Which is denser?<br />

d. How many mL of zinc?<br />

e. How many mL of tin?<br />

You are given 100. g of zinc and 75 g of nickel.<br />

a. Which piece is more massive?<br />

b. How many mL of zinc?<br />

c. How many mL of nickel?<br />

d. Which piece is larger?


Blake Schmidt - Unit 3 Page 18<br />

Unit 3: Physical Properties of Matter<br />

Release the Gas Lab<br />

You have a craving for an Outback Special. As soon as you arrive in the parking lot and open your<br />

door, you can smell all those wonderful proteins grilling on the barbie. How do those smelly<br />

particles make their way from the grill to your nose ?<br />

Hot vs. Cold Lab<br />

Some like it hot, some do not! What is hot anyway? What is cold? What is temperature?<br />

Thermal Expansion Lab<br />

Grandma just cannot get that lid off the grape jelly. But after running it in hot water for a while,<br />

it pops right off. What gives?<br />

U3 EP1<br />

Sea Level and Global Warming Presentation<br />

Crush Can Lab<br />

Just when you thought you understood this stuff, this lab happens. It will take a lot of brain power<br />

to figure this one out. Once you get it, however, it explains a whole lot about our everyday world.<br />

Straw Presentations<br />

How does a straw work? Besides well! Just another one of those everyday occurrences that can be<br />

explained from the Crush Can Lab. Demonstrate your understanding with a presentation.<br />

Weather and the Atmosphere Presentation<br />

U3 EP2<br />

Pressure, Number of Particles, Temperature, and Volume Labs<br />

If you think you are under pressure now, just wait. These labs will allow us to explain the<br />

relationships between pressure and number of particles, pressure and temperature, and pressure<br />

and volume. Graphs never looked so good!<br />

U3 EP3


Blake Schmidt - Unit 3 Page 19<br />

U3 EP1<br />

Unit 3: Example Problems 1<br />

Physical Properties of Matter<br />

1.<br />

You decide to boil water for pasta. You place the pan of water on the stove and turn on the burner.<br />

a. How does the behavior of the water molecules change as the pan of water is heated?<br />

b.<br />

What about your answer to (a) would change if more water was in the pan?<br />

2.<br />

What property of matter best describes the way a typical alcohol thermometer works?<br />

Explain (in terms of energy transfer) why the alcohol level in the thermometer rises (or falls) when you<br />

place the thermometer in contact with both warmer (or colder) objects.<br />

3.<br />

Does the concept of temperature apply to a single particle? Explain.<br />

4.<br />

If you feel feverish, why can you not take your own temperature with your hand?<br />

5.<br />

Your older brother announces that the lid to a jar of pickles from the refrigerator is “impossible” to<br />

loosen. You take the jar, hold the lid under the hot water from your sink’s faucet for a few seconds,<br />

and calmly open the jar. Your brother, when faced with this blow to his pride, claims that he loosened<br />

it for you. What knowledge of materials have you applied in this situation that really explains how you<br />

were able to open the lid?<br />

6.<br />

Which is warmer to the touch, a bucket of water at 50.˚C or a bathtub filled with water at 25˚C?<br />

Which of these contains more energy?


Blake Schmidt - Unit 3 Page 20<br />

U3 EP2<br />

Unit 3: Example Problems 2<br />

Measuring Pressure<br />

For Problems 1 & 2, calculate<br />

the pressure of the gas inside<br />

the flask that is connected to<br />

the manometer. The pressure<br />

in the room (Proom) is given.<br />

3.<br />

What do we mean by atmospheric pressure? What causes this pressure?<br />

4.<br />

How do we measure atmospheric pressure? Is atmospheric pressure the same everywhere on the<br />

surface of the earth?<br />

5.<br />

Why is the fluid in a barometer mercury, rather than water or another liquid?<br />

6.<br />

Explain why you cannot use a hand pump like the one below right to lift water up to the 3 rd floor of an<br />

apartment complex.<br />

7.<br />

One standard atmosphere of pressure (SP) is equivalent to ____________mmHg.<br />

8.<br />

Convert pressure measurements from one system of units to another in the following problems.<br />

1 atmosphere = 760 mmHg = 14.7 psi (pounds per square inch)<br />

a. 320. mmHg to atm<br />

b. 30.0 psi to mmHg<br />

c. Barometric pressure in Breckenridge, Colorado (9600. feet) is 580. mm Hg. How many atm?


Blake Schmidt - Unit 3 Page 21<br />

1.<br />

U3 EP3<br />

Use an IFE table to answer the following questions.<br />

Unit 3: Example Problems 3<br />

IFE Tables<br />

A sample of gas occupies 150. mL at 25˚C. What is its volume when the temperature is increased<br />

to 50.˚C? Assume P and n are constant.<br />

Initial<br />

Final<br />

Effect<br />

Pressure Temperature(K) Volume number of particles<br />

2.<br />

The pressure in a bicycle tire is 105 psi at 25˚C in Boulder. You take the bicycle up to Frasier,<br />

where the temperature is – 5˚C. What is the pressure in the tire? What must be constant?<br />

P T(K) V n<br />

I<br />

F<br />

E<br />

3.<br />

4.<br />

5.<br />

6.<br />

7.<br />

8.<br />

9.<br />

What would be the new pressure if 250. cm 3 of gas at<br />

standard pressure is compressed to 150. cm 3 ?<br />

What would be the new volume if 250. cm 3 of gas at 25˚C and<br />

730. mm pressure were changed to standard conditions of<br />

temperature and pressure (STP)?<br />

Sam’s bike tire contains 15 units of air particles and has a<br />

volume of 160. mL. Under these conditions, the pressure is<br />

13 psi. The tire develops a leak and now contains 10. units of<br />

air and has contracted to a volume of 150. mL. What would<br />

the tire pressure be now?<br />

A closed flask of air (0.250 L) contains 5.0 “bobs” of particles.<br />

The pressure probe on the flask reads 93 kPa. A student uses<br />

a syringe to add an additional 3.0 “bobs” of air through the<br />

stopper. Find the new pressure.<br />

A 350. mL sample of gas has a temperature of 30.˚C and a<br />

pressure of 1.20 atm. What temperature is needed for the<br />

same amount of gas to fit into a 250. mL flask at 1.0 atm?<br />

A 475 cm 3 sample of gas at STP is allowed to expand until it<br />

occupies a volume of 600. cm 3 . What temperature would be<br />

needed to return the gas to standard pressure?<br />

The box on the left contains gas molecules at 25˚C and 1.0<br />

atm. The top of the box is free to move down and is held up<br />

by pressure. Using the box to the right, adjust the top of the<br />

box and gas particles to match what it will look like at STP.


Blake Schmidt - Unit 4 Page 22<br />

Unit 4: Thermodynamics<br />

Heat vs. Temperature Lab<br />

We often think of heat and temperature as one and the same. It is important, however, to distinguish<br />

one from the other. This lab will make the difference clear.<br />

Icy Hot Lab<br />

It is often the simple things that reveal the most to us. Just wait to see how much the simple graph<br />

produced from this lab can tell us.<br />

Energy and Change Presentation<br />

U4 EP1<br />

Lauric Acid/Candle Wax Labs<br />

These labs will help drive home the concepts learned from Icy Hot and U4 EP1.<br />

U4 EP2<br />

The Heat is On Presentation<br />

U4 EP3<br />

U4 EP4<br />

Temperature of Bunsen Burner Flame Lab<br />

You know it's hot, but just how hot is it? Use your mastery of thermodynamics to figure it out.<br />

Heat Capacity of Steel/Anti-Freeze Labs<br />

Now that you know the temperature of the Bunsen Burner Flame, you can calculate these constants.<br />

Absolute Zero<br />

This 109 minute video documents humanity's quest to understand and master cold. It highlights and<br />

expands on the concepts developed in Units 3 & 4. Be sure you can answer questions pertaining to the<br />

topics listed below as discussed in the video. If you miss any of the video, or just want to watch it again,<br />

you should be able to view the video at www.pbs.org/wgbh/nova/zero/program.html.<br />

○<br />

○<br />

○<br />

○<br />

○<br />

○<br />

○<br />

○<br />

○<br />

○<br />

○<br />

○<br />

Contributions of Robert Boyle to cold.<br />

The temperature scales developed by Daniel Fahrenheit and Anders Celsius.<br />

How a thermometer works.<br />

The first evidence that cold has a lower limit (provided by Guillaume Amontons).<br />

Antoine Lavoisier's caloric theory and why it was so well accepted.<br />

Benjamin Thompson's (Count Rumford) evidence against caloric theory.<br />

Contributions of Michael Faraday, Sadi Carnot, James Joule and William Thompson (Lord Kelvin).<br />

The industrialization of cold by Frederic Tudor, Clarence Birdseye and Willis Carrier.<br />

The quests of James Dewar and Heike Kamerlingh Onnes.<br />

Superconductivity and its potential uses.<br />

Contributions of Eric Cornell, Carl Wieman, Wolfgang Ketterle, and Daniel Kleppner<br />

Bose-Einstein Condensates and their potential uses.


Blake Schmidt - Unit 4 Page 23<br />

U4 EP1<br />

Unit 4: Example Problems 1<br />

LOL Charts<br />

For questions 1-4 below, use energy bar charts to represent the ways that energy is stored in the<br />

system and flows into or out of the system. Be able to describe the arrangement and motion of<br />

the particles and how they change from the initial to the final state.<br />

1.<br />

A cup of hot coffee sits on the table and cools.<br />

2.<br />

A can of cold soda warms as it is left on the counter.<br />

3.<br />

A tray of water (20.˚C) is placed in the freezer and turns into ice cubes (- 8.0˚C).<br />

4.<br />

One of the ice cubes described in #3 is placed in a glass of room temperature (25˚C) soft drink.<br />

Do separate bar charts for the ice cube and the soft drink.<br />

5.<br />

Where does the energy that leaves the system in #3 go? How does this energy transfer affect the room<br />

temperature in the kitchen? Do you have any experience that supports your answer?<br />

6.<br />

The graph below shows a cooling curve for a substance as it freezes. Sketch a cooling curve for a larger<br />

sample of that same substance. Divide the graph into appropriate sections and identify what phases<br />

(states) of matter are present in each. Draw particle diagrams to represent the particles in each section.<br />

T<br />

E


Blake Schmidt - Unit 4 Page 24<br />

1.<br />

U4 EP2<br />

Water vapor in the room condenses on a cold plastic bottle of water.<br />

Unit 4: Example Problems 2<br />

More LOL Charts<br />

2.<br />

A pan of water (25˚C) is heated to boiling and some of the water is boiled away. Do separate energy bar<br />

charts for each stage of the process.<br />

3.<br />

You spill some warm water on your shirt. As it evaporates, you feel cool. Do separate charts again.<br />

4.<br />

During boiling, bubbles appear in the liquid water. In the boxes below represent the arrangement of<br />

molecules inside the liquid water and inside a bubble.<br />

Liquid<br />

Bubble<br />

5.<br />

What is inside the bubble? Explain your reasoning.<br />

6.<br />

Suppose the burner under a pan of boiling water is turned to a higher setting. How will this effect the<br />

temperature of the water in the pan? Explain.<br />

7.<br />

The graph below shows a heating curve for a liquid heated beyond its boiling point. Sketch a heating<br />

curve for a larger sample of that same liquid. Divide the graph into appropriate sections and<br />

identify what phases of matter are present in each. Draw particle diagrams to represent the<br />

particles in each section.<br />

T<br />

E


Blake Schmidt - Unit 4 Page 25<br />

U4 EP3<br />

Unit 4: Example Problems 3<br />

Q = mC<br />

OR Q = mC∆T<br />

The following properties of water are useful for solving quantitative energy problems. These<br />

constants will be given on tests; therefore, you do not have to memorize them, but you will need to<br />

know how to use them. You should, however, remember that 1 calorie = 4.18 Joules.<br />

Specific Heat Capacity of Liquid Water: 4.18 J/g∙˚C<br />

Specific Heat Capacity of Ice: 2.1 J/g∙˚C<br />

Heat of Vaporization: 2260 J/g<br />

Heat of Fusion: 334 J/g<br />

Begin each problem by sketching an appropriate heating or cooling curve and then use that curve to<br />

determine which equations and constants to use.<br />

1.<br />

A cup of coffee (140 g) cools from 75˚C down to comfortable room temperature 20.˚C. How much<br />

energy does it release to the surroundings?<br />

2.<br />

Suppose you lose 2.0 lbs of water due to sweating during gym class. If all of this water evaporated,<br />

how much energy (in kJ) did the water absorb from your body? 2.2 lbs = 1.0 kg<br />

3.<br />

Suppose during the Icy Hot lab that 65 kJ of energy were transferred to 450. g of water at 20.˚C.<br />

What would have been the final temperature of the water?<br />

4.<br />

The heat capacity of solid iron is 0.447 J/g∙˚C. If the same quantity of energy as in #3 was transferred<br />

to a 450. g chunk of iron at 20.˚C, what would be the final temperature?<br />

5.<br />

Suppose a bag full of ice (450. g) at 0.0˚C sits on the counter and begins to melt to liquid water.<br />

How much energy must be absorbed by the ice if 2/3 of it melted?<br />

6.<br />

A serving of Cheez-Its releases 130. kcal when digested by your body. If this same amount of energy<br />

was transferred to 2.5 kg of water at 27˚C, what would be the final temperature?<br />

7.<br />

If this same quantity of energy (130. kcal) was transferred to 2.5 kg of water at its boiling point, what<br />

fraction of the water would be vaporized?


Blake Schmidt - Unit 4 Page 26<br />

U4 EP4<br />

Unit 4: Example Problems 4<br />

Q = mC AND Q = mC∆T<br />

The following properties of water are useful for solving quantitative energy problems. These<br />

constants will be given on tests; therefore, you do not have to memorize them, but you will need to<br />

know how to use them. You should, however, remember that 1 calorie = 4.18 Joules.<br />

Specific Heat Capacity of Liquid Water: 4.18 J/g∙˚C<br />

Specific Heat Capacity of Ice: 2.1 J/g∙˚C<br />

Heat of Vaporization: 2260 J/g<br />

Heat of Fusion: 334 J/g<br />

Begin each problem by sketching an appropriate heating or cooling curve and then use that curve to<br />

determine which equations and constants to use.<br />

1.<br />

How much energy must be absorbed by a 150. g sample of ice at 0.0 ˚C that melts and warms to 25.0˚C?<br />

2.<br />

Suppose in the Icy Hot lab that the burner transfers 325 kJ of energy to 450. g of liquid water at 20. ˚C.<br />

What mass of the water will boil away?<br />

3.<br />

A 12 oz can of soft drink (340. g) at 25˚C is placed in a freezer at – 12˚C. How much energy must be<br />

removed from the soft drink for it to reach this temperature?<br />

4.<br />

65.0 kJ of energy are added to 150. g of ice at 0.0˚C. What is the final temperature of the water?<br />

5.<br />

250. kJ of energy are removed from a 4.00E 2 g sample of water at 60.˚C. Will the sample of water freeze<br />

completely? Explain.<br />

6.<br />

An ice cube tray full of ice (235g) at –7.0˚C is allowed to warm up to 22˚C. How much energy must be<br />

absorbed by the contents of the tray for this to happen?<br />

7.<br />

If this same quantity of energy was removed from 40.0 g of water vapor at 100. ˚C, what would be the<br />

final temperature of the water?


Blake Schmidt - Unit 5 Page 27<br />

Unit 5: Classifying Matter<br />

Solubility of Sugar Lab<br />

Our model of matter will need to undergo some modifications to explain these results.<br />

Solubility and Solutions Presentation<br />

U5 EP1<br />

Sand and Salt Lab<br />

You may not like this lab at first, but with some thinking and good lab technique, it should be easy.<br />

Electrolysis of Water Lab<br />

Why is water H2O? This lab may be the first time you have actual evidence to support that formula.<br />

Classifying Matter/Periodic Table Presentation<br />

U5 EP2<br />

Sticky Tape Lab<br />

The lab may be simple, but explaining the results is not. Try your best to make a model that works.<br />

Atomic Theory Presentation<br />

Conductivity Lab<br />

What is electricity? How is it conducted? And how can our model of matter explain all that?<br />

Melting Points Lab<br />

At room temperature, water is liquid but sugar is solid. How can our model explain these observations?<br />

Molecular Compounds Presentation<br />

Sodium Metal Demonstration<br />

Too bad that the sodium in table salt does not react with water like this. More importantly, why not?<br />

Ionic Compounds Presentation<br />

Metallic Bonds / Covalent Networks Presentation<br />

U5 EP3<br />

Unknowns Lab<br />

Use the information you have gathered to determine the type of bond present in an unknown chemical.


Blake Schmidt - Unit 5 Page 28<br />

U5 EP1<br />

Unit 5: Example Problems 1<br />

Solutions/Solubility<br />

1.<br />

2.<br />

3.<br />

4.<br />

5.<br />

6.<br />

7.<br />

8.<br />

9.<br />

10.<br />

11.<br />

12.<br />

13.<br />

Carbon dioxide dissolved in water is an example of which solute-solvent combination?<br />

a. liquid-gas b. gas-liquid c. liquid-liquid d. gas-gas<br />

Sugar dissolved in water is an example of which solute-solvent combination?<br />

a. liquid-liquid b. solid-solid c. liquid-solid d. solid-liquid<br />

Which mixture is made up of the smallest particles?<br />

a. milk b. shaving cream c. saltwater d. muddy water<br />

Which mixture contains visible particles that settle out unless the mixture is stirred?<br />

a. colloid b. solution c. emulsion d. suspension<br />

A metal solution is a(n)<br />

a. colloid b. suspension c. alloy d. emulsion<br />

The Tyndall effect is used to distinguish between<br />

a. liquids and gases. c. emulsions and colloids.<br />

b. solutions and colloids.d. solvents and solutes.<br />

Increasing the surface area of the solute<br />

a. increases the rate of dissolution.<br />

b. decreases the rate of dissolution.<br />

c. has no effect on the rate of dissolution.<br />

d. can increase, decrease, or have no effect on the rate of dissolution.<br />

Stirring increases the rate of dissolution because it<br />

a. raises the temperature.<br />

b. lowers the temperature.<br />

c. brings fresh solvent into contact with the solute.<br />

d. decreases the surface area of the solute.<br />

Which of the following will dissolve most rapidly?<br />

a. sugar cubes in cold water c. powdered sugar in cold water<br />

b. sugar cubes in hot water d. powdered sugar in hot water<br />

Which of the following will dissolve most slowly?<br />

a. large salt crystals in unstirred water c. small salt crystals in unstirred water<br />

b. large salt crystals in stirred water d. small salt crystals in stirred water<br />

If the amount of solute present in a solution at a given temperature is less than the maximum<br />

amount that can dissolve at that temperature, the solution is said to be<br />

a. saturated. c. supersaturated.<br />

b. unsaturated. d. concentrated.<br />

A solute crystal is dropped into a solution containing dissolved solute. It falls to the bottom of<br />

the beaker and does not dissolve after vigorous stirring. What does this indicate about the<br />

solution?<br />

a. It is probably unsaturated. c. It is probably saturated.<br />

b. It is probably supersaturated. d. It is not at equilibrium.<br />

In a solution at equilibrium,<br />

a. no dissolution occurs.<br />

b. the rate of dissolution is less than the rate of crystallization.<br />

c. the rate of dissolution is greater than the rate of crystallization.<br />

d. the rate of dissolution and the rate of crystallization are equal.


Blake Schmidt - Unit 5 Page 29<br />

U5 EP2<br />

Unit 5: Example Problems 2<br />

Matter & Periodic Table<br />

1.<br />

2.<br />

3.<br />

4.<br />

5.<br />

6.<br />

7.<br />

8.<br />

9.<br />

10.<br />

11.<br />

12.<br />

13.<br />

14.<br />

The idea of arranging the elements in the periodic table according to their chemical and<br />

physical properties is attributed to _______________________.<br />

Mendeleev left spaces in his periodic table and predicted the existence of three elements and<br />

their______________________.<br />

The discovery of what elements added a new column to Mendeleev's periodic table?<br />

a. noble gases b. transition metals c. halogens d. alkaline -earth metals<br />

What are the elements with atomic numbers from 58 to 71 called?<br />

Argon, krypton, and xenon are __________________________.<br />

The periodic law allows some properties of an element to be predicted based on its<br />

a. position in periodic table b. symbol c. mass d. color<br />

Potassium and bromine belong to ____________________.<br />

In which group does hydrogen belong? Explain.<br />

The most reactive group of nonmetals is _______________________.<br />

Elements in group 1, aka ____________________, are (more/less) reactive than elements in<br />

group 2, aka ______________________.<br />

What type of mixture has components in a uniform distribution?<br />

Which of the following is a homogeneous mixture?<br />

a. water b. sugar water c. whole wheat bread d. sugar<br />

All of the following are heterogeneous mixtures except<br />

a. whole wheat bread b. granite c. tap water d. oil -water mixture<br />

Identify the separation techniques pictured below. Which technique would be useful to<br />

separate a mixture of sand, salt and water? Of salt and water? Elements of water?


Blake Schmidt - Unit 5 Page 30<br />

U5 EP3<br />

Unit 5: Example Problems 3<br />

Types of Compounds<br />

1.<br />

Below left is a 2-D array that represents an ionic lattice. At right is a 2-D array that represents a<br />

molecular solid. In what ways are they similar? In what ways are they different?<br />

2.<br />

Below are groups of the inner cores of the atoms of the tapes. Sketch in the mobile negative<br />

charges to show how the top tape becomes (+) and the bottom becomes (-). Label each tape.<br />

3.<br />

Describe the contents of each cell.<br />

1<br />

4<br />

2<br />

3


Blake Schmidt - Unit 6 Page 31<br />

Unit 6: Naming Compounds<br />

Naming Molecular Compounds Presentation<br />

U6 EP1<br />

Naming Ionic Compounds Presentation<br />

U6 EP2


Blake Schmidt - Unit 6 Page 32<br />

U6 EP1<br />

Unit 6: Example Problems 1<br />

Molecular Compounds<br />

Name and/or write the formula for the following molecules. Be prepared to draw each.<br />

1.<br />

a. CBr4<br />

b. N2P3<br />

5.<br />

O<br />

H<br />

c. PCl3<br />

H<br />

d. ICl<br />

e. N2O<br />

6.<br />

2.<br />

f. SiF4<br />

a. GeH4<br />

O<br />

C<br />

O<br />

b. N2Br4<br />

c. P2S5<br />

d. SeO2<br />

7.<br />

H<br />

e. NH3<br />

H<br />

C<br />

H<br />

3.<br />

f. SiO2<br />

a. phosphorus triiodide<br />

H<br />

b. silicon tetrachloride<br />

c. dinitrogen pentoxide<br />

e. dinitrogen tetroxide<br />

8.<br />

O<br />

4.<br />

f. carbon monoxide<br />

a. carbon dioxide<br />

b. sulfur hexafluoride<br />

O<br />

S<br />

O<br />

c. dinitrogen tetrachloride<br />

d. carbon tetraiodide<br />

9.<br />

e. phosphorus pentafluoride<br />

f. diphosphorus pentoxide<br />

O<br />

H<br />

O<br />

H


Blake Schmidt - Unit 6 Page 33<br />

1.<br />

U6 EP2<br />

Unit 6: Example Problems 2<br />

Ionic Compounds<br />

Name and/or write the formula for the following ionic compounds. Be prepared to draw each<br />

as both an electrically neutral empirical compound and dissociated ions.<br />

a. Na2O<br />

5.<br />

a. lithium bromide<br />

9.<br />

a. sodium nitrate<br />

b. K2S<br />

b. sodium iodide<br />

b. aluminum phosphate<br />

c. MgCl2<br />

c. silver sulfide<br />

c. calcium carbonate<br />

d. CaBr2<br />

d. cesium oxide<br />

d. sodium carbonate<br />

e. BaI2<br />

e. beryllium iodide<br />

e. calcium nitrate<br />

f. Al2S3<br />

f. barium hydride<br />

f. aluminum carbonate<br />

2.<br />

a. CsBr<br />

6.<br />

a. silver oxide<br />

10.<br />

a. K2SO4<br />

b. AgF<br />

b. aluminum sulfide<br />

b. Mg(NO2)2<br />

c. Na3N<br />

c. sodium nitride<br />

c. AgNO3<br />

d. K2O<br />

d. barium chloride<br />

d. Cu3PO4<br />

e. AgBr<br />

e. strontium hydride<br />

e. Be(OH)2<br />

f. MgI2<br />

f. aluminum fluoride<br />

f. Al3HCO3<br />

3.<br />

a. SnBr2<br />

7.<br />

a. chromium(III) chloride<br />

11.<br />

a. potassium hydroxide<br />

b. SnBr4<br />

b. tin(IV) oxide<br />

b. ammonium hydroxide<br />

c. CrO<br />

c. lead(II) oxide<br />

c. potassium bicarbonate<br />

d. Cr2O3<br />

d. copper(II) iodide<br />

d. zinc carbonate<br />

e. Hg2I2<br />

e. cobalt(II) oxide<br />

e. cobalt(II) hydroxide<br />

4.<br />

f. HgI2<br />

a. PbCl2<br />

8.<br />

f. cobalt(III) oxide<br />

a. chromium(III) sulfide<br />

12.<br />

f. iron(III) phosphate<br />

+<br />

a.<br />

Na<br />

b. Fe2O3<br />

b. manganese(IV) oxide<br />

c. SnI2<br />

c. gold(III) chloride<br />

b. K Cl<br />

d. Hg2O<br />

d. titanium(IV) chloride<br />

e. HgS<br />

f. CuI<br />

e. iron(II) bromide<br />

f. iron(II) oxide<br />

c.<br />

+<br />

Na<br />

O<br />

O<br />

S<br />

O<br />

2-<br />

O


Blake Schmidt - Unit 7 Page 34<br />

Unit 7: Counting Particles<br />

5 Balloons Lab<br />

Can you form one of the most popular hypotheses in all of chemistry?<br />

5 Balloons Hypothesis Presentation<br />

Relative Mass Lab<br />

Even though we cannot see individual particles of matter, our new hypothesis allows us to make some<br />

very useful statements about them.<br />

U7 EP1<br />

The Mole Presentation<br />

U7 EP2<br />

Empirical Formula Lab<br />

In Unit 5, we just accepted oxidation numbers as fact. What evidence do we have to support them?<br />

This lab will reveal how we know the formula for zinc chloride with real evidence.<br />

MgxOy Lab<br />

More evidence to support oxidation numbers. Just promise not to stare!<br />

U7 EP3<br />

Magnesium sulfate ∙ ?-hydrate Lab<br />

We have already come across some ionic compounds that incorporate water into their crystal lattice<br />

structure (hygroscopic compounds like calcium chloride). How much water does your sample of<br />

magnesium sulfate contain? What is the formula for this hydrate?


Blake Schmidt - Unit 7 Page 35<br />

U7 EP1<br />

Unit 7: Example Problems 1<br />

Relative Mass<br />

The following items are sold regularly by the dozen instead of individually:<br />

eggs, bagels, munchkins (donut holes), and chicken wings.<br />

1.<br />

Why are these items sold in this manner?<br />

A student determined the mass of a dozen of each of these items.<br />

Eggs = 1.5 pounds<br />

Bagels = 3.0 pounds<br />

Munchkins = 0.75 pounds<br />

Wings = 2.25 pounds<br />

2.<br />

3.<br />

Calculate the average mass of ONE of each item.<br />

Place the correct number of munchkins in the empty balance pan.<br />

1.0# 0.75#<br />

4.<br />

Compare how you "counted" particles in the pressure vs. number of particles lab in Unit 3 with<br />

how you "counted" particles in the relative mass lab. What assumptions did you make in each lab?<br />

What reasoning did you use to reach these assumptions?


Blake Schmidt - Unit 7 Page 36<br />

U7 EP2<br />

Unit 7: Example Problems 2<br />

The Mole<br />

1.<br />

2.<br />

3.<br />

4.<br />

5.<br />

6.<br />

7.<br />

8.<br />

9.<br />

10.<br />

11.<br />

12.<br />

13.<br />

14.<br />

Assuming that each human being has 60. trillion body cells (6.0 x 10 13 ) and that Earth's population is 6.7<br />

billion (6.7E 9 ), calculate the total number of living human body cells on this planet. What percentage of<br />

a mole is this number?<br />

Roadrunner, the fastest supercomputer in the world as of June 2008, can perform a petaflop. A "flop" is<br />

an acronym meaning floating-point operations per second. One petaflop is 1,000 .trillion operations per<br />

second. How long (in both seconds and years) will it take Roadrunner to perform a mole of operations?<br />

(1 year = 365.25 days)<br />

If you started counting when you first learned how to count and then counted by ones, eight hours a<br />

day, 5 days a week for 50 weeks a year, you would be judged a 'good counter' if you could reach 4 billion<br />

by the time you retired at age 65. If every human on Earth (6.7E 9 ) were to count this way until<br />

retirement, what percentage of a mole would they count?<br />

An old (pre-1987) penny is nearly pure copper. If such a penny has a mass of 3.3 g, how many moles of<br />

copper atoms would be in one penny?<br />

Four nails have a total mass of 4.42 grams. How many moles of iron atoms do they contain?<br />

A raindrop has a mass of 0.050 g. How many moles of water does a raindrop contain?<br />

What mass of water would you need to have 15.0 moles of H2O?<br />

One box of Morton’s Salt contains 737 grams. How many moles of sodium chloride is this?<br />

A chocolate chip cookie recipe calls for 0.050 moles of baking soda (sodium bicarbonate). How many<br />

grams should the chef mass out?<br />

Rust is iron(III) oxide. The owner of a l959 Cadillac convertible wants to restore it by removing the rust<br />

with oxalic acid, but he needs to know how many moles of rust will be involved in the reaction. How<br />

many moles of iron(III) oxide are contained in 2.50 kg of rust?<br />

First-century Roman doctors believed that urine whitened teeth and also kept them firmly in place. As<br />

gross as that sounds, it must have worked because it was used as an active ingredient in toothpaste and<br />

mouthwash well into the 18th century. Would you believe it’s still used today? Thankfully, not in its<br />

original form! Modern dentists recognized that it was the ammonia that cleaned the teeth, and they<br />

still use that. The formula for ammonia is NH3. How many moles are in 0.75 g of ammonia? How many<br />

molecules? How many nitrogen atoms? How many hydrogen atoms?<br />

Lead(II) chromate was used as a pigment in paints. How many moles of lead(II) chromate are in 75.0 g of<br />

lead(II) chromate? How many atoms of oxygen are present?<br />

The diameter of the tungsten wire in a light bulb filament is very small, less than two thousandths of an<br />

inch, or about 1/20 mm. The mass of the filament is so very small – 0.0176 grams – that it would take<br />

1,600 filaments to weigh an ounce! How many tungsten atoms are in a typical light bulb filament?<br />

Two popular antacids tablets are Tums and Maalox. The active ingredient in both of these antacids is<br />

calcium carbonate. Tums Regular Strength tablets contain 0.747 g and Maalox tablets contain 0.600 g of<br />

calcium carbonate. How many more molecules of calcium carbonate does a Tums provide than a<br />

Maalox?


Blake Schmidt - Unit 7 Page 37<br />

U7 EP3<br />

Unit 7: Example Problems 3<br />

Empirical Formulas<br />

1.<br />

Find the empirical formula of a compound containing 32.0 g of bromine and 4.9 g of magnesium.<br />

2.<br />

What is the empirical formula of a carbon-oxygen compound if a 95.2 g sample of the compound<br />

contains 40.8 g of carbon and the rest is oxygen?<br />

3.<br />

A compound was analyzed and found to contain 9.8 g of nitrogen, 0.70 g of hydrogen, and 33.6 g of<br />

oxygen. What is the empirical formula of the compound?<br />

4.<br />

A compound composed of hydrogen and oxygen is found to contain 0.59 g of hydrogen and 9.40 g<br />

of oxygen. The molar mass of this compound is 34.0 g/mol. Find the empirical and molecular<br />

formulas.<br />

5.<br />

A sample of iron oxide was found to contain 1.116 g of iron and 0.480 g of oxygen. Its molar mass is<br />

roughly 5x as great as that of oxygen gas. Find the empirical and molecular formulas.<br />

6.<br />

Find the percentage composition of a compound that contains 17.6 g of iron and 10.3 g of sulfur.<br />

7.<br />

Find the percentage composition of a compound that contains 1.94 g of carbon, 0.48 g of<br />

hydrogen, and 2.58 g of sulfur. What is the empirical formula?<br />

8.<br />

What is the % by mass of oxygen in magnesium nitrate?<br />

9.<br />

What is the percentage composition of water?<br />

10.<br />

What is the empirical formula for a compound that is 39.3% sodium and the rest chlorine?


Blake Schmidt - Unit 8 Page 38<br />

Unit 8: Chemical Reactions<br />

Nail Lab<br />

You have never seen nails do this before.<br />

U8 EP1<br />

U8 EP2<br />

U8 EP3<br />

Galvanized Nail Lab<br />

You may have heard of a galvanized nail before, but now you will see how it is made.<br />

Hopefully, you can develop a model to explain how the process works.<br />

Electrochemistry Presentation<br />

U8 EP4<br />

Chemical Reactions Lab<br />

These chemical reactions are great examples of the types of reactions that you<br />

will need to be familiar with.<br />

U8 EP5<br />

Chemical Change Lab<br />

It begins with copper metal and nitric acid. Let us see what we end up with.<br />

Energy in Chemical Reactions Presentation<br />

U8 EP6


Blake Schmidt - Unit 8 Page 39<br />

U8 EP1<br />

Unit 8: Example Problems 1<br />

Rearranging Atoms<br />

1.<br />

2.<br />

Define the following terms and provide examples of each.<br />

a. Conservation of Mass<br />

b. Chemical Formula<br />

c. Subscript<br />

d. Coefficient<br />

Draw particle diagrams for each reactant and each product. Adjust the number of each particle<br />

accordingly so that the chemical equation follows the conservation of mass.<br />

a. H2 + O2 H2O<br />

b. H2 + Cl2 HCl<br />

c. Na + O 2 Na2O<br />

d. N2 + H2 NH3<br />

e. CH4 + O2 CO2 + H2O<br />

f. NO + O 2 NO2<br />

g. Fe + Cl 2 FeCl3<br />

h. CH3OH + O 2 CO2 + H2O


Blake Schmidt - Unit 8 Page 40<br />

U8 EP2<br />

Unit 8: Example Problems 2<br />

Balancing Equations<br />

Adjust coefficients to balance the following equations (1-35). Be prepared to draw particle diagrams.<br />

1.<br />

____C + ____H2O → ____CO + ____H2<br />

2.<br />

____MgO →____Mg + ____O2<br />

3.<br />

____Al + ____O2 → ____Al2O3<br />

4.<br />

____Zn + ____H2SO4 → ____ZnSO4 + ____H2<br />

5.<br />

____Cl2 + ____KI → ____KCl + ____I2<br />

6.<br />

____CuCl → ____Cu + ____Cl2<br />

7.<br />

____Na + ____Cl2 → ____NaCl<br />

8.<br />

____Al + ____HCl→ ____AlCl3 + ____H2<br />

9.<br />

____Fe2O3 → ____Fe + ____O2<br />

10.<br />

____P + ____O2→____P2O5<br />

11.<br />

____Mg + ____HCl → ____MgCl2 + ____H2<br />

12.<br />

____H2 + ____N2 → ____NH3<br />

13.<br />

____BaCl2 + ____H2SO4 → ____BaSO4 + ____HCl<br />

14.<br />

____CH4 + ____O2 →____CO2 + ____H2O<br />

15.<br />

____ZnCl2 + ____(NH4)2S → ____ZnS + ____ NH4Cl


Blake Schmidt - Unit 8 Page 41<br />

U8 EP2<br />

Unit 8: Example Problems 2<br />

Balancing Equations<br />

16.<br />

17.<br />

18.<br />

19.<br />

20.<br />

21.<br />

____SO2 + ____O2<br />

____CH4 + ____O2<br />

____P + ____Cl2<br />

____CO + ____O2<br />

____CH4 + ____ O2<br />

____Li + ____Br2<br />

____SO3<br />

____CO + ____H2O<br />

____PCl3<br />

____CO2<br />

____CH3OH<br />

____LiBr<br />

22.<br />

____Al2O3<br />

____Al + ____O2<br />

23.<br />

24.<br />

____Na + ____H2O<br />

____CO2 + ____H2O<br />

____NaOH + ____H2<br />

____C6H12O6 + ____O2<br />

25.<br />

____H2SO4 + ____NaCl<br />

____HCl + ____Na2SO4<br />

Two reactions are used to get rid of sulfur dioxide, a pollutant from burning coal:<br />

26.<br />

____H2 + ____SO2<br />

____H2S + ____H2O<br />

27.<br />

____CaCO3 + ____SO2 + ____ O2<br />

____CaSO4 + ____CO2<br />

28.<br />

29.<br />

30.<br />

31.<br />

____AgNO3 + ____CaCl2<br />

____HCl + ____Ba(OH)2<br />

____H3PO4 + ____NaOH<br />

____Pb(NO3)2 + ____KI<br />

____AgCl + ____Ca(NO3)2<br />

____BaCl2 + ____H2O<br />

____Na3PO4 + ____H2O<br />

____ PbI2 + ____KNO3<br />

32.<br />

33.<br />

34.<br />

35.<br />

____CuO + ____NH3<br />

____C2H5OH + ____O2<br />

____C2H6 + ____O2<br />

____NO2 + ____H2O<br />

____N2 + ____Cu + ____H2O<br />

____CO2 + ____H2O<br />

____CH3COOH + ____H2O<br />

____HNO3 + ____NO


Blake Schmidt - Unit 8 Page 42<br />

U8 EP3<br />

Unit 8: Example Problems 3<br />

Writing Balanced Equations<br />

1.<br />

Nitric oxide (NO) reacts with ozone (O3) to produce nitrogen dioxide and oxygen.<br />

2.<br />

Iron burns in air to form a black solid, Fe3O4.<br />

3.<br />

Sodium metal reacts with chlorine gas to form sodium chloride.<br />

4.<br />

Acetylene, C2H2, burns in air to form carbon dioxide and water.<br />

5.<br />

Hydrogen peroxide (H2O2) easily decomposes into water and oxygen.<br />

6.<br />

Hydrazine (N2H4) and hydrogen peroxide are used together as rocket fuel. The products are<br />

nitrogen and water.<br />

7.<br />

If potassium chlorate is strongly heated, it decomposes to yield oxygen gas and potassium<br />

chloride.<br />

8.<br />

When sodium hydroxide is added to sulfuric acid (H2SO4), the products are water and sodium<br />

sulfate.<br />

9.<br />

In the Haber process, hydrogen and nitrogen react to form ammonia.<br />

10.<br />

Ammonia (NH3) reacts with hydrogen chloride to form ammonium chloride.<br />

11.<br />

Calcium carbonate decomposes upon heating to form calcium oxide and carbon dioxide.<br />

12.<br />

Barium oxide reacts with water to form barium hydroxide.<br />

13.<br />

Acetaldehyde (CH3CHO) decomposes to form methane (CH4) and carbon monoxide.<br />

14.<br />

Zinc is combined with copper(II) nitrate.<br />

15.<br />

Calcium sulfite decomposes when heated to form calcium oxide and sulfur dioxide.


Blake Schmidt - Unit 8 Page 43<br />

U8 EP3<br />

Unit 8: Example Problems 3<br />

Writing Balanced Equations<br />

16.<br />

Aluminum is combined with sulfuric acid (H2SO4).<br />

17.<br />

A nitrogen containing carbon compound, C 2H6N2, decomposes to form ethane, C2H6, and<br />

nitrogen.<br />

18.<br />

Phosgene, COCl2, is formed when carbon monoxide reacts with chlorine gas.<br />

19.<br />

Manganese(II) iodide decomposes when exposed to light to form manganese and iodine.<br />

20.<br />

Dinitrogen pentoxide reacts with water to produce nitric acid (HNO 3).<br />

21.<br />

Magnesium is combined with titanium (IV) chloride.<br />

22.<br />

Carbon reacts with zinc oxide to produce zinc and carbon dioxide.<br />

23.<br />

Bromine reacts with sodium iodide to form sodium bromide and iodine.<br />

24.<br />

Phosphorus (P4) reacts with bromine to produce phosphorus tribromide.<br />

25.<br />

Ethanol, C2H5OH, reacts with oxygen to produce carbon dioxide and water.<br />

26.<br />

Calcium hydride reacts with water to produce calcium hydroxide and hydrogen.<br />

27.<br />

Sulfuric acid, H2SO4, reacts with potassium hydroxide.<br />

28.<br />

Propane, C3H8, burns in air.<br />

29.<br />

Lead is combined with aluminum chloride.<br />

30.<br />

Zinc is combined with hydrochloric acid.


Blake Schmidt - Unit 8 Page 44<br />

U8 EP4<br />

Unit 8: Example Problems 4<br />

Electrochemistry<br />

1.<br />

2.<br />

3.<br />

4.<br />

5.<br />

6.<br />

In an electrochemical cell, electrons are generated at the<br />

a. anode.<br />

b. cathode.<br />

c. circuit.<br />

d. electrolyte.<br />

What is used to keep two half-cells apart but allow charges to flow?<br />

a. an electrolyte<br />

b. a cathode<br />

c. a porous barrier<br />

d. an anode<br />

Where does oxidation take place in an electrochemical cell?<br />

a. the anode<br />

b. the cathode<br />

c. the anode or the cathode<br />

d. the half-cell<br />

The oxidation number of the substance taking part in the reaction that occurs at the cathode<br />

a. decreases.<br />

b. increases.<br />

c. does not change.<br />

d. None of the above<br />

In an electrochemical cell, the cathode is the<br />

a. neutral electrode.<br />

b. electrode at which matter can gain or lose electrons.<br />

c. electrode at which matter gains electrons.<br />

d. electrode at which matter loses electrons.<br />

Draw a complete (labels, etc.) electrochemical cell using copper and zinc.<br />

Use sulfate as the anion for aqueous solutions of each metal.<br />

7.<br />

Draw (with labels) and describe how a typical AA battery works.


Blake Schmidt - Unit 8 Page 45<br />

U8 EP5<br />

Unit 8: Example Problems 5<br />

Types of Rxns<br />

Indicate whether the following are examples of synthesis (combination), decomposition,<br />

combustion, single replacement or double replacement. The number in boldface is the<br />

SUM of the coefficients of the correctly balanced equation.<br />

1.<br />

Na3PO4 + KOH NaOH + K3PO4 8<br />

2.<br />

MgCl2 + Li2CO3 MgCO3 + LiCl 5<br />

3.<br />

C 6H 12 + O 2 CO 2 + H 2O 22<br />

4.<br />

Pb + FeSO 4 PbSO 4 + Fe 4<br />

5.<br />

CaCO3 CaO + CO2 3<br />

6.<br />

P 4 + O 2 P 2O 3 6<br />

7.<br />

RbNO 3 + BeF 2 Be(NO 3) 2 + RbF 6<br />

8.<br />

AgNO3 + Cu Cu(NO3)2 + Ag 6<br />

9.<br />

C 3H 6O + O 2 CO 2 + H 2O 11<br />

10.<br />

C5H5 + Fe Fe(C5H5) 2 4<br />

11.<br />

SeCl6 + O2 SeO2 + Cl2 6<br />

12.<br />

MgCl2 + Mn(SO3)2 MgSO3 + MnCl4 6<br />

13.<br />

Zr 2O 3 + Sn Zr + SnO 2 12<br />

14.<br />

(NH 4) 2Cr 2O 7 Cr 2O 3 + N 2 + H 2O 7


Blake Schmidt - Unit 8 Page 46<br />

U8 EP6<br />

Unit 8: Example Problems 6<br />

LOLOL Charts<br />

For questions 1-5 below, use energy bar charts to represent the ways that energy is stored in<br />

the system and flows into or out of the system. Be able to describe the arrangement and<br />

motion of the particles and how they change from the initial to the final state.<br />

1.<br />

Heating calcium carbonate decomposes it into calcium oxide and carbon dioxide.<br />

2.<br />

Solid zinc is combined with hydrochloric acid in a test tube. The test tube feels warmer.<br />

3.<br />

Isopropyl alcohol, C3H8O is burned in air.<br />

4.<br />

In some chemical cold packs, solid ammonium chloride dissolves in water forming aqueous<br />

ammonium and chloride ions.<br />

5.<br />

In some chemical hot packs, a supersaturated solution of sodium acetate forms crystals of solid<br />

sodium acetate.


Blake Schmidt - Unit 9 Page 47<br />

Unit 9: Solution Stoichiometry<br />

Molarity Lab<br />

What does that "M" on the bottle of 3.0 M HCl stand for?<br />

U9 EP1<br />

Cobalt hydroxide/Lead iodide Lab<br />

Remember how to decant? I hope so. You will need to recall a lot of information<br />

and lab techniques to perform this lab.<br />

BCA Tables Presentation<br />

U9 EP2<br />

U9 EP3<br />

U9 EP4<br />

Acids / Bases / pH Presentation<br />

Sodium hydroxide / Hydrochloric acid Lab<br />

U9 EP5


Blake Schmidt - Unit 9 Page 48<br />

Moles KCl<br />

Mass NaCl (g)<br />

U9 EP1<br />

1.<br />

Use the graph at right to determine the<br />

molarity of the potassium chloride solution.<br />

0.030<br />

0.025<br />

0.020<br />

Unit 9: Example Problems 1<br />

Molarity<br />

Slope = 0.00175<br />

0.015<br />

0.010<br />

0.005<br />

0.000<br />

0 2 4 6 8 10 12 14 16<br />

Volume (mL)<br />

140<br />

2.<br />

Use the graph at right to determine the<br />

molarity of the sodium chloride solution.<br />

120<br />

100<br />

80<br />

Slope = 0.1169<br />

60<br />

40<br />

20<br />

3.<br />

4.<br />

5.<br />

6.<br />

7.<br />

8.<br />

9.<br />

10.<br />

11.<br />

Sodium chloride was dissolved in water to produce a 1.5M solution.<br />

a. Explain what this concentration tells us about the NaCl solution.<br />

b. How might a chemist use this ratio?<br />

0<br />

0 200 400 600 800 1000 1200<br />

Volume (mL)<br />

A 45.3 g sample of potassium nitrate is dissolved in enough water to make 225 mL of solution.<br />

Determine the molar concentration of the potassium nitrate.<br />

Find the molarity of a solution made from 275 g of CuSO4 dissolved in enough water to make 4.25 L.<br />

An alcoholic iodine solution (“tincture” of iodine) is prepared by dissolving 5.15 g of iodine crystals in<br />

enough alcohol to make a volume of 225 mL. Calculate the molarity of iodine in the solution.<br />

What final volume would be needed in order to prepare a 0.25 M NaCl solution from 5.2 g of NaCl (s)?<br />

Draw a particle diagram of each of these ionic substances in solution. Then calculate the molarity of<br />

each ion present in each of the following solutions.<br />

a. 0.25 M AlCl3<br />

b. 0.375 M Na2CrO4<br />

c. 0.0020 Ca(OH)2<br />

d. 0.103 M Na3PO4<br />

How many grams of silver nitrate are needed to prepare 250. mL of standard 0.100 M silver nitrate<br />

solution?<br />

If 10.0 g of AgNO3is available, find the volume needed to prepare a 0.25 M AgNO3solution.<br />

Concentrated hydrochloric acid is made by pumping hydrogen chloride gas into distilled water. If<br />

concentrated HCl contains 439 g of HCl per liter, what is the molarity?


Blake Schmidt - Unit 9 Page 49<br />

U9 EP2<br />

Unit 9: Example Problems 2<br />

BCA Stoichiometry<br />

Begin each problem with a balanced chemical equation. Complete the BCA table using the<br />

coefficients from the balanced equation to determine the appropriate mole ratios.<br />

1.<br />

Hydrogen sulfide gas, which smells like rotten eggs, burns in air to produce sulfur dioxide and water.<br />

How many moles of oxygen gas would be needed to completely burn 8 moles of hydrogen sulfide?<br />

H2S(g) + O2(g) SO2(g) + H2O(g)<br />

M Before ___ ___ ___ ___<br />

O<br />

L Change ___ + ___ ___ + ___<br />

E<br />

S After ___ ___ ___ ___<br />

2.<br />

Propane, C3H8, burns in air to form carbon dioxide and water. If 12 moles of carbon dioxide are<br />

formed, how many moles of propane were burned?<br />

3.<br />

Ammonia for fertilizer is made by causing hydrogen and nitrogen to react at high temperature and<br />

pressure. How many moles of ammonia can be made from 0.15 moles of nitrogen gas?<br />

4.<br />

The poison gas phosgene, COCl2, reacts with water in the lungs to form hydrochloric acid and carbon<br />

dioxide. How many moles of hydrochloric acid would be formed by 0.835 moles of phosgene?<br />

5.<br />

Iron metal and oxygen combine to form the magnetite, Fe3O4. How many moles of iron can be<br />

converted to magnetite by 8.80 moles of pure oxygen? How many moles of magnetite are produced?<br />

6.<br />

The recipe for Coca-Cola Classic is a closely guarded secret, so a complete balanced equation is out.<br />

Researchers outside the company believe the flavoring mixture, known as “7X”, contains oils of orange, lemon,<br />

nutmeg, cinnamon, and coriander. The original mixture also contained caffeine, vanilla, caramel, lime juice,<br />

sugar or artificial sweetener, and citric acid. Over the years, the recipe has changed. For example, the original<br />

recipe contained citric acid but this was combined with phosphoric acid to cut production costs. Corn syrup<br />

replaced sugar for the same reason. Here is the part of the recipe that we know.<br />

C8H10N4O2 + 4 H3PO4 + 6 CO2 + other ingredients C6H5CO2K + other products<br />

caffeine phosphoric acid potassium benzoate<br />

To produce 1000 cans of Coca-Cola Classic, 40g (0.21 moles) of caffeine are reacted with phosphoric acid and<br />

other ingredients. How many moles of phosphoric acid are required? How many moles of CO2 are required?


Blake Schmidt - Unit 9 Page 50<br />

1.<br />

U9 EP3<br />

Unit 9: Example Problems 3<br />

Percent Yield<br />

Use BCA tables to complete the following problems.<br />

Using the Hoffman apparatus for electrolysis, a chemist decomposes 36 g of water into its gaseous<br />

elements. How many grams of hydrogen gas should she recover (theoretical yield)?<br />

2.<br />

Liquid sodium reacts with chlorine gas to produce sodium chloride. You want to produce 584.5 g of sodium<br />

chloride. How many grams of sodium are needed?<br />

3.<br />

You eat 180.0 g of glucose (90 M&Ms). If glucose, C6H12O6, reacts with oxygen gas to produce carbon dioxide<br />

and water, how many grams of oxygen will you have to breathe in to burn the glucose? How many grams of<br />

carbon dioxide should be produced?<br />

4.<br />

Suppose 4.61 g of zinc was allowed to react with hydrochloric acid to produce zinc chloride and hydrogen<br />

gas. How much zinc chloride should you get? Suppose that you actually recovered 8.56 g of zinc chloride.<br />

What is your percent yield?<br />

5.<br />

Determine the mass of carbon dioxide that should be produced in the reaction between 3.74 g of carbon<br />

and excess O2. What is the % yield if 11.34 g of CO2is recovered?<br />

6.<br />

In the reaction between excess K(s) and 4.28 g of O2(g), potassium oxide is formed . What mass would you<br />

expect to form (theoretical yield)? If 17.36 g of K2O is actually produced, what is the percent yield?<br />

7.<br />

Determine the mass of carbon dioxide one could expect to form (and the percent yield) for the reaction<br />

between excess CH4and 11.6 g of O2if 5.38 g of carbon dioxide gas is produced along with some water vapor.<br />

8.<br />

Determine the mass of water vapor you would expect to form (and the percent yield) in the reaction<br />

between 15.8 g of NH3and excess oxygen to produce water and nitric oxide (NO). The mass of water actually<br />

formed is 21.8 g.


Blake Schmidt - Unit 9 Page 51<br />

U9 EP4<br />

Unit 9: Example Problems 4<br />

Limiting Reactant<br />

1.<br />

Write the balanced equation for the reaction between hydrogen and oxygen.<br />

Suppose that 4 molecules of hydrogen gas and 4 molecules of oxygen gas react to form water.<br />

Make a drawing that represents the reaction container before and after the reaction.<br />

a.<br />

b.<br />

c.<br />

How many molecules of water can be produced?<br />

Which reactant is in excess? Why?<br />

How many molecules of excess reactant are there?<br />

Construct a BCA table for this reactant mixture using molecules instead of moles.<br />

Answer questions a-c using the BCA table. How, if at all, do your answers differ?<br />

Based on your two methods of analysis above, what determines how much product can be made<br />

from a particular reactant mix?<br />

2.<br />

Make a drawing that represents the reaction container before and after the reaction of 6 molecules<br />

of nitrogen and 12 molecules of hydrogen. How many molecules of ammonia can be produced?<br />

Which reactant is in excess? Why? How many molecules of excess reactant are there?<br />

Answer the same questions using a BCA table instead of the particle diagrams.<br />

Describe how you know which reactant determines how much product can be made.<br />

3.<br />

4.<br />

5.<br />

6.<br />

Use only BCA tables to answer the remaining questions.<br />

When 0.50 mole of aluminum reacts with 0.72 mole of iodine to form aluminum iodide, how many<br />

moles of the excess reactant will remain? How many moles of aluminum iodide will be formed?<br />

When sodium hydroxide reacts with sulfuric acid (H2SO4), water and sodium sulfate are the<br />

products. Calculate the mass of sodium sulfate produced when 15.5 g of sodium hydroxide are<br />

reacted with 46.7 g of sulfuric acid.<br />

A 14.6 g sample of oxygen gas is placed in a sealed container with 2.5 g of hydrogen gas. The<br />

mixture is sparked, producing water vapor. Calculate the mass of water formed. Calculate the<br />

number of moles of the excess reactant remaining.<br />

Neuroscientists believe that the only chemical in chocolate that may have a feel -good effect on the<br />

human brain is phenylethylamine (PEA). Although the PEA in chocolate occurs naturally, PEA can be<br />

made in the laboratory by the following reaction: CH 5NO2 + C8H8O C8H11N + CO2 + H2O<br />

How much PEA can be made from 75.0 g of CH5NO2 and 125g of C8H8O? What mass of the excess<br />

reactant remains?


Blake Schmidt - Unit 9 Page 52<br />

U9 EP5<br />

Unit 9: Example Problems 5<br />

Solution Stoichiometry<br />

1.<br />

How many moles of lead(II) hydroxide (solid) can be formed when 0.0225L of<br />

0.135 M Pb(NO3)2 solution reacts with excess sodium hydroxide?<br />

2.<br />

Aqueous barium nitrate reacts with aqueous sodium sulfate. Abigail places 20.00 mL of 0.500 M<br />

barium nitrate in a flask. She has a 0.225M sodium sulfate solution available. What volume of<br />

this solution must she add to her flask of barium nitrate so she has no excess reactant left over?<br />

3.<br />

Calcium chloride (aq) reacts with sodium carbonate (aq). Determine what volume of a 2.00 M<br />

calcium chloride solution would be needed to exactly react with 0.0650 L of 1.50 M Na2CO3.<br />

How many grams of sodium chloride should be produced from the reaction. How much sodium<br />

chloride will actually be produced if the percent yield for the reaction is 85%?<br />

4.<br />

The remaining problems represent all types of stoichiometry problems<br />

Calculate the number of moles of potassium chlorate (s) that must decompose to produce<br />

potassium chloride (s) and 1.8 moles of oxygen.<br />

5.<br />

Magnesium metal reacts with hydrochloric acid. What volume of 1.0 M hydrochloric acid is<br />

needed to completely react with 2.43 g of magnesium?<br />

6.<br />

Ethane, C2H6, combusts in air. What mass of oxygen is needed to react with 2.20 mol of ethane?<br />

7.<br />

Determine the mass of sodium nitrate produced when 0.73 g of nickel(II) nitrate reacts with<br />

sodium hydroxide.<br />

8.<br />

2.93 g of copper metal is placed in a 0.75 M silver nitrate solution, producing silver metal and<br />

aqueous copper(II) nitrate. The silver nitrate solution contained 1.41 g of silver nitrate. What is<br />

the volume of the silver nitrate solution? If 0.87 g of silver metal is recovered, what is % yield?<br />

9.<br />

Hydrochloric acid is added to sodium bicarbonate, producing sodium chloride, water and carbon<br />

dioxide. What is the percent yield if 4.68 g of CO2 are collected when 10.0 g of sodium hydrogen<br />

carbonate reacts with excess 3.0 M HCl?<br />

10.<br />

If 5.0 g of phosphorus and 35 g of bromine react, how many grams of phosphorus tribromide<br />

should be produced?<br />

11.<br />

Zinc sulfide and oxygen gas react to form zinc oxide and sulfur dioxide. Determine the amount<br />

of ZnO that should be produced in a reaction between 46.5 g of ZnS and 13.3 g of oxygen. What<br />

is the mass of the xs reactant?


Blake Schmidt - Unit 10 Page 53<br />

Unit 10: Gas and Energy Stoichiometry<br />

3 Containers Lab<br />

We know the volume and the number of particles, so what else must be true? Do not be afraid<br />

to make some assumptions.<br />

U10 EP1<br />

Molar Volume of a Gas Lab<br />

Using magnesium metal and hydrochloric acid, determine the volume (in L) of 1 mole of<br />

hydrogen gas at standard temperature and pressure. This volume will allow us to do a lot.<br />

Molar Gas Law Presentation<br />

U10 EP2<br />

U10 EP3<br />

Energy of Combustion Lab<br />

We have revisited gases and now we will revisit energy and thermodynamics. How much<br />

energy is released by during the combustion of candle wax?<br />

Calorimetry Presentation<br />

U10 EP4


Blake Schmidt - Unit 10 Page 54<br />

U10 EP1<br />

Unit 10: Example Problems 1<br />

Gases Again<br />

1.<br />

A can of spray paint contains nitrogen gas as the propellant. The pressure of the gas is 3.5 atm<br />

when the temperature is 20.˚C. The can is left in the sun, and the temperature of the gas increases<br />

to 50.˚C. What is the pressure in the can?<br />

2.<br />

A 90.0 mL volume of helium was collected under a pressure of 740. mmHg. At what volume would<br />

the pressure of this gas be 700 mmHg? Assume temperature is constant.<br />

3.<br />

A small bubble rises from the bottom of a lake, where the temperature is 8˚C and the pressure is<br />

6.4 atm, to the water’s surface, where the temperature is 25˚C and pressure is 1.0 atm. Calculate<br />

the final volume (in mL) of the bubble if its initial volume was 2.1 mL.<br />

4.<br />

Three gases are mixed in a 1.00 L container. The partial pressure of CO 2 is 250. mmHg,<br />

N2 is 375 mmHg and He is 125 mmHg. What is the pressure of the mixture of gases?<br />

5.<br />

What are the percentages of the gases in the above mixture?<br />

6.<br />

Our atmosphere is a mixture of gases (roughly 79% N2, 20% O2 and 1% Ar). What is the partial<br />

pressure (in mmHg) of each gas at standard pressure?<br />

7.<br />

A mixture of He and O2 gases is used by deep-sea divers. If the pressure of the gas a diver inhales is<br />

8.0 atm, what percent of the mixture should be O 2 if the partial pressure of O2 is to be the same as<br />

what the diver would ordinarily breathe at sea level?<br />

8.<br />

When you found the density of carbon dioxide gas in Unit 2, you collected the gas by displacing<br />

water. At the time, we assumed the gas was only carbon dioxide. The gas you collected actually<br />

was a mixture of CO2 and water vapor. How did water vapor get mixed in. Hint: What happens to<br />

a drop of water left on a table?<br />

9.<br />

If, on the day of the Density of a Gas Lab, the room pressure was 730. mmHg and the partial<br />

pressure of water vapor was 21 mmHg, what would be the partial pressure of the CO 2 gas?<br />

10.<br />

Suppose that when you reacted zinc with hydrochloric acid, you collected the hydrogen gas by<br />

water displacement. If the pressure in the room is 735 mmHg, and the partial pressure of the<br />

water is 22 mmHg, what would be the partial pressure of the hydrogen gas? If the volume of the<br />

hydrogen is 25.0 mL, what is the volume of the hydrogen gas alone at standard pressure?


Blake Schmidt - Unit 10 Page 55<br />

U10 EP2<br />

Unit 10: Example Problems 2<br />

Molar Gas Law<br />

1.<br />

What volume does 16.0 g of O2 occupy at STP?<br />

2.<br />

A mixture contains 5.00 g each of oxygen, nitrogen, carbon dioxide and neon gas.<br />

Calculate the volume of this mixture at STP.<br />

3.<br />

A 250 mL flask of hydrogen is collected at 763 mmHg and 35˚C by displacement of water. The<br />

vapor pressure of water at 35˚C is 42.2 mmHg. How many mol of hydrogen are in the flask?<br />

4.<br />

A weather balloon contains 65 L of helium at 20.0˚C and 0.932 atm. How many atoms of<br />

helium are in the balloon?<br />

5.<br />

What will the volume of the weather balloon from question 4 be when it rises into the<br />

stratosphere where the temperature is -61˚C and the pressure is 1.0856E-2 atm?<br />

6.<br />

A 4.44 L container holds 15.4 g of oxygen at 25.25˚C. What is the pressure in mmHg?<br />

7.<br />

How many moles of air are in a 2.65 L balloon at 22.1˚C and 1.09 atm?<br />

8.<br />

How many moles of neon are in a 0.50 L tube at STP?<br />

9.<br />

How many moles of air are in a 1.00 L tube at STP?


Blake Schmidt - Unit 10 Page 56<br />

U10 EP3<br />

Unit 10: Example Problems 3<br />

Gas Stoichiometry<br />

1.<br />

When calcium carbonate is heated strongly, carbon dioxide gas is evolved.<br />

CaCO3(s) → CaO(s) + CO2(g)<br />

If 4.74 g of calcium carbonate is heated, what volume of CO 2(g) would be produced when<br />

collected at STP?<br />

2.<br />

Zinc metal reacts vigorously with chlorine gas to form zinc chloride. What volume of chlorine gas<br />

at 25˚C and 1.00 atm is required to react completely with 1.13 g of zinc?<br />

3.<br />

Consider the following reaction:<br />

P4(s) + 6 H2(g) ––> 4 PH3(g)<br />

What mass of P4 will completely react with 2.50 L of hydrogen gas at 0˚C and 1.50 atm pressure?<br />

4.<br />

If water is added to magnesium nitride and heated, ammonia gas is produced.<br />

Mg3N2(s) + 3H2O(l) ––> 3 MgO + 2NH3(g)<br />

If 10.3 g of magnesium nitride is treated with water, what volume of ammonia gas would be<br />

collected at 20˚C and 0.989 atm?<br />

5.<br />

Nitrogen gas and hydrogen gas combine to produce ammonia gas. What volume of hydrogen gas<br />

at 25˚C and 735 mmHg is required for the complete reaction of 10.0 g of nitrogen?


Blake Schmidt - Unit 10 Page 57<br />

U10 EP4<br />

Unit 10: Example Problems 4<br />

Energy Stoichiometry<br />

1.<br />

How many kJ of heat will be released when 4.72 g of carbon reacts with excess oxygen gas to<br />

produce carbon dioxide? C + O2 CO2 ∆H° = –393.5 kJ<br />

2.<br />

How much heat should be transferred when 38.2 g of liquid bromine reacts with excess<br />

hydrogen gas to form hydrogen bromide? Is the heat being transferred from the system to the<br />

surroundings or from the surroundings to the system? H2 + Br2 2 HBr ∆H° = 72.80 kJ<br />

3.<br />

How many kJ of heat would you expect to be transferred when 6.44 g of sulfur react with<br />

excess oxygen to produce sulfur trioxide? Is this reaction endothermic or exothermic?<br />

2 S + 3 O2 2 SO3 ∆H° = –791.4 kJ<br />

4.<br />

Nitrogen gas and oxygen gas can combine to produce nitric oxide, NO. If such a reaction<br />

absorbs 88.0 kJ of heat from the surroundings, how many grams of nitrogen gas do you predict<br />

were consumed in the reaction? N2 + O2 2 NO ∆H° = 180 kJ<br />

5.<br />

Ammonia gas combines with excess oxygen gas to produce nitric oxide and water. If 256 kJ of<br />

energy were released in such a reaction, how many grams of ammonia gas were reacted?<br />

4 NH3 + 5 O2 4 NO + 6 H2O ∆H° = – 1170 kJ<br />

6.<br />

Carbon in the form of graphite combines with excess hydrogen gas to form benzene, C6H6. In<br />

the following reaction 3.95 kJ of heat were transferred. Calculate the grams of graphite reacted.<br />

Is the reaction endothermic or exothermic? 6 C + 3 H2 C6H6 ∆H° = 49.03 kJ<br />

7.<br />

How much heat will be released if 30.0 g of octane (C8H18) is burned in excess oxygen?<br />

C8H18+ 12 1/2 O2 8 CO2+ 9 H2O ∆H° = –5483.4 kJ<br />

How much heat would be released by burning one gallon of octane? The density of octane is<br />

0.703g/mL. 1 gallon = 3.79 liters.


Blake Schmidt - Unit 11 Page 58<br />

Unit 11: Quantum Theory<br />

Wave Interference Simulation<br />

Let's get familiar with waves. Just not at the beach!<br />

Properties of Waves<br />

By now, we are very familiar with the behavior of particles. But to develop our understanding<br />

of the atom further, we will need to investigate the properties of waves, including the basic<br />

mathematical relationships that describe them.<br />

Blackbody Radiation and the Photoelectric Effect Simulations<br />

These two experiments were instrumental in developing quantum theory.<br />

Do the Wave Presentation<br />

Describing Light Lab<br />

Use spectrascopes to describe the light emitted by three different sources.<br />

Emission spectra/Flame Test Lab<br />

Each element emits a unique spectra of light, like a fingerprint. We'll use a burner flame to<br />

coax several elements into emitting their unique brand of light.<br />

Atom<br />

This 3-hour BBC series will guide us through the brilliant people and thoughts that shaped<br />

quantum theory and the implications of quantum theory on society. For anyone interested in<br />

exploring quantum theory further, I highly recommend reading the book "Atom" by Piers<br />

Bizony that accompanies this video. Students should be familiar with the following scientists<br />

and concepts for the test.<br />

Albert Einstein, Brownian Motion, Louis de Broglie, Erwin Schrödinger, Wave Function,<br />

Neils Bohr, Wolfgang Pauli, Exclusion Principle, Werner Heisenberg, Copenhagen<br />

Interpretation, Quantum Jumps, Madame Curie, Ernest Rutherford, JJ Thomson, Solar<br />

System Model, Otto Hahn, Lise Meitner, Max Planck, Hans Geiger, Francis Aston, Mass<br />

Spectrometer, James Chadwick, Wilson and Penzias, Fred Hoyle, George Gamow, Paul<br />

Dirac, Richard Feynman, Murray Gell-Mann, QED, Anti-matter, Positron, Quark.<br />

U11 EP1<br />

The Quantum Atom Model Presentation<br />

U11 EP2


Blake Schmidt - Unit 11 Page 59<br />

1.<br />

2.<br />

3.<br />

4.<br />

5.<br />

6.<br />

7.<br />

U11 EP1 Unit 11: Example Problems 1<br />

Electromagnetic Spectrum<br />

Because excited hydrogen atoms always produce the same line-emission spectrum, scientists<br />

concluded that hydrogen<br />

a. had no electrons. c. released photons of only certain energies.<br />

b. did not release photons. d. could only exist in the ground state.<br />

When the pink-colored light of glowing hydrogen gas passes through a prism, it is possible to<br />

see<br />

a. all the colors of the rainbow. c. four lines of different colors.<br />

b. only lavender-colored lines. d. black light.<br />

The product of the frequency and the wavelength of a wave equals the<br />

a. number of waves passing a point in a second.<br />

b. speed of the wave.<br />

c. distance between wave crests.<br />

d. time for one full wave to pass.<br />

Visible light, X rays, infrared radiation, and radio waves all have the same<br />

a. energy. c. speed.<br />

b. wavelength. d. frequency.<br />

For electromagnetic radiation, c (the speed of light) equals<br />

a. frequency minus wavelength. c. frequency divided by wavelength.<br />

b. frequency plus wavelength. d. frequency times wavelength.<br />

If electromagnetic radiation A has a lower frequency than electromagnetic radiation B, then<br />

compared to B, the wavelength of A is<br />

a. longer. c. equal.<br />

b. shorter. d. exactly half the length of B's wavelength.<br />

According to Bohr, electrons cannot reside at ____ in the figure below.<br />

8.<br />

9.<br />

10.<br />

11.<br />

12.<br />

13.<br />

A line spectrum is produced when an electron moves from one energy level<br />

a. to a higher energy level. c. into the nucleus.<br />

b. to a lower energy level. d. to another position in the same sublevel.<br />

The Bohr model of the atom was an attempt to explain hydrogen's<br />

a. density. c. mass.<br />

b. flammability. d. line-emission spectrum.<br />

If electrons in an atom have the lowest possible energies, the atom is in the<br />

a. ground state. c. excited state.<br />

b. inert state. d. radiation-emitting state.<br />

The distance between two successive peaks on adjacent waves is its<br />

a. frequency. c. quantum number.<br />

b. wavelength. d. velocity.<br />

The wave model of light does not explain<br />

a. the frequency of light. c. interference.<br />

b. the continuous spectrum. d. the photoelectric effect.<br />

The energy of a photon is related to its<br />

a. mass. c. frequency.<br />

b. speed. d. size.


Blake Schmidt - Unit 11 Page 60<br />

1.<br />

2.<br />

3.<br />

4.<br />

5.<br />

6.<br />

7.<br />

8.<br />

9.<br />

10.<br />

11.<br />

12.<br />

U11 EP2<br />

Unit 11: Example Problems 2<br />

Quantum Atom<br />

All of the following describe the Heisenberg uncertainly principle except<br />

a. it states that it is impossible to determine simultaneously both the position and velocity<br />

of an electron or any other particle.<br />

b. it is one of the fundamental principles of our present understanding of light and matter.<br />

c. it helped lay the foundation for the modern quantum theory.<br />

d. it helps to locate an electron in an atom.<br />

All of the following describe the Schrödinger wave equation except<br />

a. it is an equation that treats electrons in atoms as waves.<br />

b. only waves of specific energies and frequencies provide solutions to the equation.<br />

c. it helped lay the foundation for the modern quantum theory.<br />

d. it is similar to Bohr's theory.<br />

The French scientist Louis de Broglie theorized that<br />

a. electrons could have a dual wave-particle nature.<br />

b. light waves did not have a dual wave-particle nature.<br />

c. the natures of light and quantized electron orbits were not similar.<br />

d. Bohr's model of the hydrogen atom was completely correct.<br />

How many quantum numbers are needed to describe the energy state of an electron in an<br />

atom?<br />

a. 1 b. 2 c. 3 d. 4<br />

The letter designations for the first four sublevels with the maximum number of electrons that<br />

can be accommodated in each sublevel are<br />

a. s:2, p:4, d:6, and f:8.<br />

b. s:1, p:3, d:5, and f:7.<br />

c. s:2, p:6, d:10, and f:14.<br />

d. s:1, p:2, d:3, and f:4.<br />

The statement that no two electrons in the same atom can have the same four quantum<br />

numbers is<br />

a. the Pauli exclusion principle. c. Bohr's law.<br />

b. Hund's rule. d. the Aufbau principle.<br />

Which of the following rules requires that each of the p orbitals at a particular energy level<br />

receive one electron before any of them can have two electrons?<br />

a. Hund's rule c. the Aufbau principle<br />

b. the Pauli exclusion principle d. the quantum rule<br />

The sequence in which energy sublevels are filled is specified by<br />

a. the Pauli exclusion principle. c. Lyman's series.<br />

b. the orbital rule. d. the Aufbau principle.<br />

Which of the following lists atomic orbitals in the correct order they are filled according to the<br />

Aufbau principle?<br />

a. 1s 2s 2p 3s 4s 3p 3d 4p 5s<br />

b. 1s 2s 2p 3s 3p 4s 3d 4p 5s<br />

c. 1s 2s 2p 3s 3p 4s 4p 3d 4d<br />

d. 1s 2s 2p 3s 3p 3d 4s 4p 5s<br />

The electron notation for aluminum is _______________________.<br />

An element with 8 electrons in its highest main energy level is a(n)<br />

a. octet element. c. Aufbau element.<br />

b. third period element. d. noble gas.<br />

Which model of the atom explains the orbitals of electrons as waves?<br />

a. the Bohr model c. Rutherford's model<br />

b. the quantum model d. Planck's theory


Blake Schmidt - Appendix Page 61<br />

Appendix<br />

Plagiarism will not be tolerated. When paraphrasing another author, students should<br />

maintain the main idea or point of the phrase using their own words, sentence structure and<br />

proper citation. The following examples of paraphrasing have been included as a guide. Avoid<br />

plagiarism because of unacceptable paraphrase. And remember, scientists generally do not use<br />

direct quotes: they paraphrase.<br />

Paraphrasing<br />

Original Text<br />

"At the moment, the evidence seems to favor an African Eve, because other genetic<br />

studies (of nuclear DNA) also point to an origin there and because that's where the<br />

earliest fossils of modern humans have been found. But wherever Eve's home was, the<br />

rival geneticists agree that she lived relatively recently, and this is what provokes<br />

anthropologists to start arguing--often with Biblical metaphors of their own."<br />

From: Tierney, J. 1988 January 11. The Search for Adam and Eve. Newsweek, 23-25.<br />

Unacceptable Paraphrase (Plagiarism)<br />

Currently, evidence points to an African Eve, since nuclear DNA studies favor the same<br />

starting point and early modern fossils of humans have been discovered there. However,<br />

no matter where Eve was from, competitive geneticists believe that she existed more<br />

recently. This makes anthropologists argue—many times with religious comparisons of<br />

their own (Tierney 1988).<br />

Acceptable Paraphrase<br />

Tierney (1988) contends that both the fossil and genetic evidence suggest an "African<br />

Eve." However, a major controversy between the geneticists and the anthropologists<br />

centers around not where Eve originated, but when, with geneticists believing in a more<br />

recent date.<br />

The following two pages provide examples of how to cite using APA format, the chosen format<br />

for most scientists. The examples show how to cite at the end of your paper (i.e. End-Text),<br />

such as in a bibliography or reference section. They also show how to cite within the body of<br />

your paper (i.e. In-Text), such as at the end of the sentence you are referencing. Please see me<br />

if you have any trouble formatting your references. I would also recommend using a citation<br />

machine: many are available on the web.


Blake Schmidt - Appendix Page 62<br />

Examples of proper citation of sources, both End-text and In-text.<br />

Journals<br />

[unknown author] (year) [title of article] [title of journal] [vol] [pages]<br />

Anonymous. 1997. Epidemiology for primary health care. International Journal of Epidemiology. 5:224-225.<br />

In-text: (Anon. 1997)<br />

[two authors] (year) [title of article] (title of journal) (vol) (pages)<br />

Bryant Pl. and Simpson P. 1984. Intrinsic and extrinsic control of growth in developing organs.<br />

Quart. Rev. BioI. 59:387-415.<br />

In-text: (Bryant and Simpson 1984)<br />

[author. 1st publ. in same year] (title of article) [title of journal] [vol (issue)] (pages)<br />

Billings S. 1992a. Mathematical notations. Journal of Chem. Engineering. 46(5):20-25.<br />

In-text: (Smith 1990, cited in Billings 1992a)<br />

[author-2nd publ. in same year] (title article) (title of journal) [vol (issue)](pages)<br />

Billings S. 1992b. Modules and Notations. Mathematical Review. 54(2):5-7.<br />

In-text: (Billings 1992b)<br />

(multiple authors) (year) (title of article) (title of journal) [vol] (number) (pages)<br />

Steiner U, Klein J, Eiser E, Budkowski A, Fetters LJ. 1992. Complete wetting from polymer mixtures.<br />

Science. 258(5085): 1122-9.<br />

In-text: (Steiner et al. 1992)<br />

Magazines and Newspapers<br />

[author) [year] [month] (title of article) [title of magazine] [pages]<br />

Richardson S. 1994 January. The Return of the Plague. Discover, 69-70.<br />

In-text: (Richardson 1994)<br />

[two authors] [year] (mo/day) [title of article] [title of newspaper] [sec:pg] [col]<br />

Rensberger B. and Specter B. 1989. Aug. 7 CFCs may be destroyed by natural<br />

process. Washington Post. A:2(col 5).<br />

In-text: (Rensberger and Specter 1989)<br />

(unknown author) (year) (mo/day) (title of article) (title of newspaper) (sec page)<br />

Anonymous. 1990 Aug 24. Gene data may help fight colon cancer. Los Angeles Times. A:4.<br />

In-text: (Anon. 1990)<br />

Books and Book Chapters<br />

(author) (year) (title of book ) (publisher) (place of publ.)<br />

Ling GN. 1984. In Search of the Physical Basis of Life. Plenum Press; New York.<br />

In-text: (Ling 1984)<br />

[organization/publisher as author] (year) [title of book] [place of publ.]<br />

IOS-International Organization for Standardization. 1979. Statistical methods. Geneva.<br />

In-text: (IOS 1979)<br />

[author of chapter] [year] [title of book chapter] [page numbers] [in] [editor of book] [title of book]<br />

[publisher of book ] [place of publication]<br />

Southwood TRE. 1981. Bionomic strategies and population parameters. Pages 50-52. In RM. May, ed.<br />

Theoretical Ecology. Sinauer Associates, Sunderland, MA.<br />

In-text: (Southwood 1981)


Blake Schmidt - Appendix Page 63<br />

Examples of proper citation of sources, both End-text and In-text.<br />

Pamphlets<br />

[organization as author] [no year given] [title of pamphlet] [place of publication]<br />

Humane Society. n.d. Care of critically ill pets. Washington, D.C.<br />

In-text: (Humane Society n.d.)<br />

Government Documents/Reports/Publications<br />

(government organization as author) [mo/year] (title of report) (place of publication)<br />

(government documentation number]<br />

NIH-National Institutes of Health (US). Dec. 1988. Report of the Human Fetal Tissue Transplantation Panel,<br />

consultants to the Advisory Committee to the Director. NIH. Bethdsda (MD): PB90-155268,<br />

PB90-155276.<br />

In-text: (NIH 1988)<br />

(two authors) (year) (title of government report) (report number) (publisher of report) [place of publ.]<br />

Lassiter RR. and Cooley JL. 1983. Prediction of ecological effects of toxic chemicals, overall strategy and<br />

theoretical basis for the ecosystem model EP A-600/3-83-084. National Technical Information Service<br />

PB 3-261-685, Springfield, V A.<br />

In-text: (Lassiter and Cooler 1983)<br />

Conference Papers<br />

[author] [year] (title of conference paper) [organization for whom paper was presented]<br />

[place of conference] [date of conference]<br />

O'Leary DS. 1983. Risks and benefits of cooperating with the media. Paper presented at the annual meeting<br />

of the American Association of the Advancement of Science, Washington, D.C., 8 January 1982.<br />

In-text: (O'Leary 1983)<br />

Web Sites<br />

[unknown author] [year] [title of article] [complete web address] [date you accessed the web page]<br />

Anonymous. 1996. Use of wildland fire. http://www.fs.fed.uslIandlwdfire7a.htJDl Accessed 15 August 1997.<br />

In-text: (Anon. 1996)<br />

(corporation as author) (no date given) [title of article] [complete web address) [date accessed]<br />

Aquatic Conservation Network. n.d. Aquatic Conservation. http://www.tnews.com/textlwetlands.html<br />

Accessed 17 August 1997.<br />

In-text: (Aquatic Cons n.d.)<br />

[author] [year] [title of article] [complete web address] [date accessed]<br />

Tardent P. 1995. Cell Biology, annual report. http://www.unizh.ch/-zoo/depts/celllreport94.htmI<br />

Accessed 25 July 1997.<br />

In-text: (Tardent 1995)<br />

Video/TV Programs<br />

[editor of program] [year] [title of program] [production company] [place of prod] [sponsored by]<br />

Wood RM. editor. 1989. New horizons in esthetic dentistry [videocassette]. Visualeyes Productions,<br />

producer. Chicago: Chicago Dental Society.<br />

In-text: (Wood 1989)


Blake Schmidt - Appendix Page 64<br />

Participation<br />

<strong>Chemistry</strong> is a science, and science is a verb; therefore, participation is a vital<br />

component to your success in chemistry. In order for this class to work its best,<br />

we need you to contribute positively. Simply showing up and going through the<br />

motions will not increase your participation score. Below is a list of some of the<br />

ways that your actions will effect your participation grade.<br />

Positive Contributions Increase Your Participation Score:<br />

You maintain a notebook complete with lab write-ups and reflections<br />

You think critically before speaking/presenting<br />

You make detailed observations<br />

You attempt to complete all example problems<br />

You clean-up after yourself AND others<br />

You work well with your lab partner(s)<br />

You help others understand<br />

You share when appropriate<br />

Others value your ideas/observations<br />

You add unique perspectives<br />

Negative Contributions Decrease Your Participation Score:<br />

You neglect to take notes, write lab reflections, or do example problems<br />

You're not prepared (e.g. no calculator, markers or notebook)<br />

You do other stuff (e.g. homework, read a book, iPod)<br />

You neglect to clean-up or put stuff away<br />

You do not follow directions<br />

You play with or break lab equipment<br />

You pose a danger to yourself and others during lab<br />

You do not respect your classmates<br />

Remember, we need you. Your opinions/ideas/observations are important and<br />

need to be shared to help you and others understand. A team never succeeds<br />

when its players just show up and go through the motions.

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