A reactive melt modification of polyethylene terephthalate
A reactive melt modification of polyethylene terephthalate
A reactive melt modification of polyethylene terephthalate
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CHAPTER 2<br />
PURPOSE AND SCOPE<br />
This thesis focuses on understanding the structural <strong>modification</strong> <strong>of</strong> PET and its effect on<br />
the polymer rheological properties through a <strong>reactive</strong> <strong>melt</strong> processing approach using low<br />
MW multifunctional epoxides, for improving processability, particularly in extrusion<br />
foaming. Reactive processing, in this case, involves undesirable degradation reactions<br />
and desirable chain extension and branching reactions resulting in changes in MW and<br />
MWD <strong>of</strong> PET.<br />
As sketched in Figure 2.1, extrusion foaming <strong>of</strong> PET to low densities is<br />
challenged by its low <strong>melt</strong> viscosity, <strong>melt</strong> strength, and <strong>melt</strong> elasticity. Researchers have<br />
correlated improvements in these and other rheological/processing properties with bubble<br />
stability and resistance to bubble coalescence during foaming. This thesis attempts to<br />
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