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100 e ' 36 Drawin& II 5816 ~1cure 7 T~ D1.tr1butlOD ot ~JP Between Hexone and 1M Al( K03}3 - O.o,M ~e(KB~)2(S04}2- O.~7M 2 ~e%7l p,Jr141ae •• PI o - O.1M lD1tlal urea cODcentration in aqueoua .olutionaj2 alnute equilibration ... e a. ab~e but with 4 .our equili_ratlon o u • - DO urea In aqueous .olut1~ • - equl11brat10D ot hexone pha.e with tre.h aqueous 8olution • - equ111l»ratlQJl ot aqueous pha.e vi th tre •• hexcme l': r ? ... 01 11 III l:J ~ ~ Z IO "'~ "., N 4 > .. I] W aLl o ~ ') 0' . - IJ • '1111 .J o '" .J 0; U : lli1·n~m1 · t : ~ .. ...- Of ..... IS . f, ·~ •• I - T 4 H-+-tf-+++ 31'-nltH-H t · ee 0" t - I : 1 .. 1 1 I.! I' ! " I . L ~ I ! . - ! I ' ! , .... ,.
e 37 In J'igure 8 ia plCJtted the lIlp distribution as a tunct1cm of pH using tri-n-but:vl8m1ne as the complexing ~t. The graph show the distribution obtained from the original extraction and also o.n approach to equillbrium conditions follomD8 a tour-hour equilibration. e D1agnun.a ot the extractions at the tour pll'a are sbovn in Figures 9-12. All linea l"mD1ng f'rcIn left to right are aqueous phaaea, tboae running fl"om right to lett are he1008 phases. The Dt.IDIbar directly under the intersections a.ro the observed distribution ratios, thone to t.ht;) rignt ot the intersections are the time ot equilIbration. F1gures 10, 12 at IiI • 1 .. 58 and -0.02 shoy definite ev1clence ot fxoact1onationa. J'1gure 11 i8 not self-consistent and DO explana: .... 1.on for it can be ottered a "1 this time. J'igure 9 1D4:icates eitber tbttt 1 t atta1ned equilibr1um 111 2 minutes ot less or t.hat 1 t is in a ~tt\ e~le state and equU1brium vas not approacb;)d after 4 hours. At pH - 0.02 (P1gure 12) the ayatem appt."8r8 to be approach1Dg equiUbrlum with .:1 time greater tbaD tour hours. At pH 1.58 (J'lgure 10) equil1brhn 1s a.pparent.ly reached between two minutes and tour hou:re 6 This sytltem can bf) explained as8Ulll1Dg two torms ot Bp as tollova: kaq = [BPI] [iPlIl = RPl aq E' Dx· 11. t ~ kors • D]:I ;: .10, »X "f IPllaq ~ DII = 0.05 JlPIorg 1 korg • ) l1Pllorg k,wPl ] [.PII] • 23 Dist.ribution ratios cal.culated on these aaaumpt10us are show in parentheeco on Figure 10 aDd are in agreement witb the obaerv8d valuos. ~e Determinat10n ot B1tT~o Add In Hexane in the Presence ot 01'San.!C Cmr,p1ez1ns Agents e Ii tric acid may be detemind by direct t1 trat.lon in 50Ir methanol solut1on containing a small amount ot bexcme and in the presence or e1 thflJr 2 hexylpyrld1no, tri-n-butyl amine mono-nitrate, or tetra-n-butyl sxrmo.u1um nitrate. The potent1Cl111etric 'break using a calomel-glus c~ll i9 ah:lrp with all three but 1s shorter '
Page 1 and 2: .. '7" ! A ~S1fj[ OJ :,J.Ll'i,j ~8r
Page 3 and 4: • _ ~ I I • : I e i • O(U , -
Page 5 and 6: .e ABSTRk(;'r OF r.U;ui.T.'!:IiLY R
Page 7 and 8: 6 ~ Abstract ot ~uarterly Re~ort (C
Page 9 and 10: e 8 1. REACTOR :rtJEIS Inorganic, P
Page 11 and 12: 10 e The pH meueuremento were carri
Page 13 and 14: 2 - I!Illd where R is a constant at
Page 15 and 16: we 14 suggests that a particular ag
Page 17 and 18: e 7 changes aan be tolmd. extends a
Page 19 and 20: - 19 The sucoess ot such studies ap
Page 21 and 22: e 21 were Ao aDd Fo M'e the initial
Page 23 and 24: e 23 Por constant b and h e~at10n 1
Page 25 and 26: e .. ~ 25 / Process Chemistry s A o
Page 27 and 28: e 27 Pre-equilibration of pbaaes be
Page 29 and 30: e 100 e -- P- - . - -- 29 DrawlOi #
Page 31 and 32: 0 C\J
Page 33 and 34: e 33' It vaa found that the data fo
Page 35: , e e e " e - • 180 J'1pre 6 TI
Page 39 and 40: e aqueous phase pH IE 2.70 39 hexon
Page 41 and 42: e 41 present as the base itself' bu
Page 43 and 44: e 43 TABLR I The Dete1'lB1Daticm of
Page 45 and 46: e e 45 'i. stock fJolution of tet:t
Page 47 and 48: e 47 TABLE III (CCilt. ) Vol: Bunl
Page 49 and 50: e 49 .I'our coutant. rele.t1ftg SuA
Page 51 and 52: - Hexane Phase e Time between equil
Page 53 and 54: e 53 F1gul'e 16 Proposed E:z;plazaa
Page 55 and 56: 55 -. . Xenon Cross Sections as a F
Page 57 and 58: 5'-' A number of extractionrs of Xe
Page 59 and 60: .. 59 Calibr~t.ion ~f Assal Equipme
Page 61 and 62: 61 e Since the amount of cont;minat
Page 63 and 64: e In the experimontH.l work d. seri
Page 65 and 66: -. 65 Tah1e III H~lf tire of Jodine
Page 67 and 68: . >- 12 I- > I U « « 10 I w c
Page 69 and 70: e e e 5.0. Ore. w.i'J II 5801 FiG.
Page 71 and 72: .. 71 Program t E-xpor1J'lental inv
Page 73 and 74: • RecQverY or Ru 106 (rom Met!!l
Page 75 and 76: - 75 }'rum the first portion of Tab
Page 77 and 78: 77 - No explanation is offered for
Page 79 and 80: e 79 Table I Inacti ve Carbon in 0w
Page 81 and 82: - 81 An additional :.200 ml. of 18
Page 83 and 84: e 83 Experimental Use of C14 (C" J.
Page 85 and 86: e e 85 t',llquots of the aqueous so
Page 87 and 88:
e e e 87 with stirring.' Two mL of
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e J .. StJPPQRTING CHH1ICAL RFEFAJl
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e be accurst ae follows }~uby ar.al
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e r,. ~88 V(Jlt~3 wse obl~1n(td f'o
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e 95 ' In these separi'ltiofls yttr
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e 97 At best the separation is poor
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99 - Lanthanum Studies The value qu
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· 101 - Hard Gamma R8)ys from ySS
Page 103 and 104:
• e e Solid Chemistry ot' Rutheni
Page 105 and 106:
• 105 Separation of the Long-Live
Page 107 and 108:
300. .. ~ FIRST CYCLE SHOWING CONCE
Page 109 and 110:
• 110 151 B- ~ e- (""""50 Kev) Pr
Page 111 and 112:
FIG. IV RADIATIONS OF LONG-LIVED FI
Page 113 and 114:
I - . ! ~ rf " ~ , 1 I ~ I , ~ I ..
Page 115 and 116:
116 - D .. Xc> 1. Study of Baok Rea
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.- F1(0) Table 1 • (Continued) 11
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I • c::: w f-- -.J .......... ~ 2
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FIG. 3 . INITIAL RATE OF PEROXIDE R
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~ -~ I 124 -- Table 3 0 DecQnPo~it1
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~ - e • 100 i 126 ______ _ _ _ _
Page 127 and 128:
128 -- Tab~e 5. Amount of n.p reaot
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130 • preBsur~ drop here cannot b
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flit 132 A S1g>lltled. Feuation of
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• 134 The System Uranyl Sulfate -
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-. e • Tc - - - -- - - - --------
Page 137 and 138:
138 '" Cloud Chamber Studiea (Ro Li
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IIIIIIIIIIIIIII e 140 The disintegr
Page 141 and 142:
142 e experiments BO that a SUII ot
Page 143 and 144:
144 PolarogrE!Ph1c Ana.l;Ysis of Ra
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e 146 7 Te. 10 I \: .&oj""" 'r' .Jr
Page 147 and 148:
148 e The effect of temperature, ti
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150 e in the pipette have been only
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152· - e The llama preparatiOD use
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e e • Figure 2. Kurie plot of Cb
Page 155 and 156:
e e e Figure 4. Compton electrons a
Page 157 and 158:
e e e Counts per minute per unit mo
Page 159 and 160:
e 160 where the..B and L nter to th
Page 161 and 162:
e Electron and 0 TL:--~Newman, 162
Page 163 and 164:
e e ~. 164 In a continuation of the
Page 165 and 166:
to •
Page 167 and 168:
-166" e Zircon1um - neY U. S. Burea
Page 169 and 170:
SEPARATION OF LONG-LIVED Sm AND EuA
Page 171 and 172:
e e -- , • Film D-43 . Black prod
Page 173 and 174:
• X-R!l Diffraction ()t. A. Bredi
Page 175 and 176:
e. e 175 Another observation may tu
Page 177 and 178:
~ 177 The results obtained thus tar
Page 179 and 180:
e e 179 o . RU0 2 (Strukturber1oht)
Page 181 and 182:
e 181 Instruments and PAlste&! Meas
Page 183 and 184:
- f 183 Allot these circuits operat
Page 185 and 186:
185 e 4- ANALYTICAL SERVICE Lab. an
Page 187:
, , ...J o x ~ C) %- Z ~ ~
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