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Chemistry 338 2 Semester Final Exam Review Sheet

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Unit 9 - Acids and Bases _Chapters 14-15 & 18<br />

22. Calculate the pH of the following and classify acid/base/neutral:<br />

a. 1.0x10 -2 M = [H + ] b 3.7 x 10 -5 M = [OH - ]<br />

pH = 2 - Acid<br />

pH = 9.57 – base<br />

23. A 0.11 M weak acid has a [H + ] = 0.0004 M at equilibrium. What is the Ka of the acid?<br />

1 HA (aq) ↔ 1 H + (aq) + 1 A - (aq)<br />

I 0.11 0 0<br />

C -0.0004 +0.0004 +0.0004<br />

E 0.1096 0.0004 0.0004<br />

Ka = [H+][A-] Ka = [0.0004][0.0004] Ka = 1.46x10 -6<br />

[HA] [0.1096]<br />

24. How many mL of a10 M HCl are needed to neutralize 380 mL of a 7 M NaOH?<br />

1 HCl + 1 NaOH 1 NaCl + 1 H 2 O<br />

380 mL _ NaOH 1 L _ NaOH 7 mol _ NaOH 1 mol _ HCl 1 L _ HCl 1000 mL _ HCl<br />

x x x x x<br />

1 1000 mL _ NaOH 1 L _ NaOH 1 mol _ NaOH 10 mol _ HCl 1 L _ HCl<br />

= 266 mL HCl<br />

<br />

25. In the following reaction, identify the acid and base and its conjugate pairs (Bronsted-<br />

Lowry): H 2 O + NH 3 → NH 4 + + OH -<br />

A B CA CB<br />

26. Name the following acids:<br />

a) H 2 S – hydrosulfuric acid<br />

b) HNO 2 – nitrous acid<br />

c) HClO 3 – chloric acid<br />

27. What is the salt that forms when Sr(OH) 2 reacts with HNO 3 ?<br />

Sr(OH) 2 + 2 HNO 3 Sr(NO 3 ) 2 + 2 H 2 O<br />

Sr(NO 3 ) 2<br />

Unit 10 - Electrons – Chapter 4, 6<br />

28. Draw the lewis dot structure, state the shape, and hybridization<br />

a. CH 4 - tetrahedral, sp 3

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