Tabel 1. Physical, chemical and technical properties to be ... - fyto
Tabel 1. Physical, chemical and technical properties to be ... - fyto
Tabel 1. Physical, chemical and technical properties to be ... - fyto
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<strong>Ta<strong>be</strong>l</strong> <strong>1.</strong><br />
<strong>Physical</strong>, <strong>chemical</strong> <strong>and</strong> <strong>technical</strong> <strong>properties</strong> <strong>to</strong> <strong>be</strong> determined (certified lab = ISO CEI 17025, formerly EN45001)<br />
Parameter Formulation type To <strong>be</strong> determined Method FAO specification (or remark) Lab<br />
Active substance<br />
content<br />
All<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp. (GIFAP<br />
Monograph N° 17)<br />
Depending on the a.s.<br />
(GLC/HPLC,...)<br />
A.s. content not less than 95 %<br />
of the content determined<br />
<strong>be</strong>fore s<strong>to</strong>rage (or info<br />
concerning degradation<br />
products) + respect<br />
specification content a.s. (See<br />
ta<strong>be</strong>l 4)<br />
GLP/<br />
Liège<br />
Appearance<br />
(odour - colour -<br />
physical state)<br />
All<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
room temp. (GIFAP<br />
Monograph N° 17)<br />
Description / GLP/<br />
Liège/<br />
certified<br />
lab<br />
Explosive<br />
<strong>properties</strong><br />
All (except when<br />
thermodynamic<br />
information<br />
establishes<br />
incapability of<br />
exothermic reaction)<br />
Before s<strong>to</strong>rage EEC A14 / GLP<br />
Oxidizing<br />
<strong>properties</strong><br />
All (except when<br />
thermodynamic<br />
information<br />
establishes<br />
incapability of<br />
exothermic reaction<br />
with combustible<br />
materials)<br />
Before s<strong>to</strong>rage<br />
Solids : EEC A17<br />
Other preparations :<br />
justified method<br />
/ GLP
Parameter Formulation type To <strong>be</strong> determined Method FAO specification (or remark) Lab<br />
Flash point<br />
Liquids which<br />
contain flammable<br />
solvents<br />
Before s<strong>to</strong>rage<br />
EEC A9<br />
(or CIPAC MT 12,<br />
when flash point < 79<br />
°C)<br />
/ GLP<br />
Flammability Solids <strong>and</strong> gases Before s<strong>to</strong>rage solids : EEC A10 or<br />
A12<br />
gases : EEC A11<br />
Au<strong>to</strong>-flammability All Before s<strong>to</strong>rage liquids, gases: EEC<br />
A15<br />
solids: EEG A16<br />
(As appropriate : UN-<br />
Bowes-Cameron Cage<br />
Test)<br />
/ GLP<br />
/ GLP<br />
pH All aqueous liquids Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
CIPAC MT 75<br />
result < 4 : acidic preparation<br />
result > 10 : alkaline<br />
preparation<br />
GLP/<br />
Liège<br />
pH of a 1%<br />
dilution, emulsion<br />
or dispersion<br />
All applied as<br />
aqueous dilutions<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
CIPAC MT 75<br />
result < 4 : acidic preparation<br />
result > 10 : alkaline<br />
preparation<br />
GLP/<br />
Liège<br />
Acidity/<br />
alkalinity<br />
All acidic or alkaline<br />
preparations (see pH<br />
or pH at 1 %)<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
CIPAC MT 31 / GLP/<br />
Liège
Parameter Formulation type To <strong>be</strong> determined Method FAO specification (or remark) Lab<br />
Kinematic<br />
viscosity<br />
Liquids for ULV use<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
OECD 114<br />
(or CIPAC MT 22)<br />
/ GLP/<br />
Liège<br />
Viscosity<br />
Non new<strong>to</strong>nian<br />
liquids<br />
Before s<strong>to</strong>rage OECD 114 / GLP/<br />
Liège<br />
Surface tension Liquids Before s<strong>to</strong>rage EEC A5 / GLP/<br />
Liège<br />
Relative density Liquids Before s<strong>to</strong>rage EEC A3 (or CIPAC<br />
MT 3)<br />
Bulk (tap) density Powders, granules Before s<strong>to</strong>rage powders: CIPAC MT<br />
33<br />
granules: CIPAC MT<br />
159<br />
WG: CIPAC MT 169<br />
/ GLP/<br />
Liège<br />
/ GLP/<br />
Liège/<br />
certified<br />
lab
Parameter Formulation type To <strong>be</strong> determined Method FAO specification (or remark) Lab<br />
Effect of low<br />
temperatures on<br />
stability<br />
Liquids Before s<strong>to</strong>rage S petroleum oil<br />
products :<br />
CIPAC 48, 51 or<br />
54<br />
S SC, SE, aqueous<br />
SL : CIPAC MT<br />
S<br />
39.2 (7 days)<br />
CS : after<br />
frost/defrost<br />
cycle<br />
S other liquids :<br />
CIPAC MT 39.1<br />
(7 days)<br />
- SC: still comply with<br />
suspensibility <strong>and</strong> wet sieve<br />
test<br />
- FS : still comply with wet<br />
sieve test<br />
- SE : still comply with<br />
acidity/alcalinity, pH, pH at<br />
1%, wet sieve test,<br />
suspensibility, emulsifiability<br />
<strong>and</strong> spontaneity of dispersion<br />
- SL, LS, OL, UL, EC : max.<br />
0.3 ml of separated solid or<br />
liquid<br />
- EW, ES, ME : no separation<br />
of particulate or oily matter<br />
visible after gentle agitation<br />
- CS : still comply with content<br />
of free a.s., pH, pH at 1%,<br />
acidity/alcalinity,<br />
suspensibility, pourability,<br />
spontaneity of dispersion <strong>and</strong><br />
wet sieve test<br />
GLP/<br />
Liège/<br />
certified<br />
lab<br />
Wettability<br />
Solids which are<br />
diluted for use (SP,<br />
WP, WG, SG,...)<br />
- WS, SG, WP: <strong>be</strong>fore <strong>and</strong><br />
after s<strong>to</strong>rage at room temp<br />
(GIFAP Monograph N° 17)<br />
- other : <strong>be</strong>fore <strong>and</strong> after<br />
s<strong>to</strong>rage at high temp.<br />
(CIPAC MT 46) <strong>and</strong> at<br />
room temp.<br />
CIPAC MT 53.3 Wetted in max. 1 min. GLP/<br />
Liège/<br />
certified<br />
lab
Parameter Formulation type To <strong>be</strong> determined Method FAO specification (or remark) Lab<br />
Persistent foaming<br />
All preparations <strong>to</strong> <strong>be</strong><br />
diluted with water<br />
- at the highest used<br />
concentration<br />
- SL, LS, EC : <strong>be</strong>fore<br />
s<strong>to</strong>rage<br />
- SP, SG, WP, WG if<br />
formulated as WSB : <strong>be</strong>fore<br />
<strong>and</strong> after s<strong>to</strong>rage at high<br />
temp. (CIPAC MT 46) <strong>and</strong><br />
at room temp (GIFAP<br />
Monograph N° 17)<br />
- EW : <strong>be</strong>fore <strong>and</strong> after<br />
s<strong>to</strong>rage at high temp. <strong>and</strong> at<br />
room temp.<br />
- other : <strong>be</strong>fore <strong>and</strong> after<br />
s<strong>to</strong>rage at room temp.<br />
CIPAC MT 47.2<br />
(30 °C, CIPAC D<br />
water)<br />
max. 60 ml of foam after 1 min.<br />
GLP/<br />
Liège/<br />
certified<br />
lab<br />
Suspensibility<br />
Water dispersible<br />
products (WP, WG,<br />
SC, SE, ...)<br />
- At the highest <strong>and</strong> lowest<br />
used concentration<br />
- Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
WP : CIPAC MT 15<br />
(30 °C, CIPAC D<br />
water, 30 min)<br />
WG : CIPAC MT 168<br />
(30 °C, CIPAC D<br />
water, 30 min)<br />
liquids: CIPAC MT<br />
161 (30 °C, CIPAC D<br />
water, 30 min, except<br />
SE : 2h)<br />
WP, SC, CS, WG : min. 60 %<br />
GLP/<br />
Liège/<br />
certified<br />
lab
Parameter Formulation type To <strong>be</strong> determined Method FAO specification (or remark) Lab<br />
Spontaneity of<br />
dispersion<br />
Water dispersible<br />
products (WG, SC,<br />
CS, SE...)<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
solids : CIPAC MT<br />
174<br />
liquids : CIPAC MT<br />
160 (5 min, 30 °C,<br />
CIPAC D water)<br />
/ GLP/<br />
Liège/<br />
certified<br />
lab<br />
Dilution stability<br />
Water soluble<br />
products<br />
- at the highest used<br />
concentration<br />
- Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
LS, SL : CIPAC MT<br />
41 (18 u, 20 °C,<br />
CIPAC D water)<br />
SS, ST, SG, SP :<br />
CIPAC MT 179<br />
WSB : solubility of the<br />
bag, CIPAC MT 176<br />
LS, SL : clear <strong>and</strong> opalescent<br />
solution, free from more than a<br />
trace of sediment <strong>and</strong> visible<br />
solid particles, which all shall<br />
pass through a 45 µm test sieve.<br />
WSB: max. 30 s <strong>to</strong> pass the<br />
sieve<br />
GLP/<br />
Liège/<br />
certified<br />
lab<br />
Dry sieve test Dustable powders Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
CIPAC MT 59.1 Max. 5 % retained on a 75 µm<br />
test sieve; the residue on the<br />
sieve contains max. (0,005 x X)<br />
% of the sample as a.s., where<br />
X is the determined a.s. content<br />
in g/kg.<br />
GLP/<br />
Liège/<br />
certified<br />
lab<br />
Wet sieve test<br />
Water dispersible<br />
products<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
WG, WT: CIPAC MT<br />
167<br />
WP, WS, SC, CS, FS,<br />
SE, DC: CIPAC MT<br />
59.3<br />
Max. 2 % retained on a 75 µm<br />
test sieve<br />
GLP/<br />
Liège/<br />
certified<br />
lab
Particle size<br />
distribution<br />
Powders Before s<strong>to</strong>rage OECD 110<br />
(or laser diffraction)<br />
/ GLP/<br />
Liège<br />
Granules for direct<br />
application<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
CIPAC MT 58.3<br />
Min. 85 % of the formulation<br />
within the nominal declared<br />
size range.<br />
GR : ratio of the lower <strong>to</strong> the<br />
upper limit shall not exceed 1:4<br />
GLP/<br />
Liège<br />
Water dispersible<br />
granules<br />
Before s<strong>to</strong>rage CIPAC MT 170 / GLP/<br />
Liège<br />
Dust content Granules Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
CIPAC MT 171<br />
max. 30 mg (0,1 %) of dust<br />
(optical fac<strong>to</strong>r max. 25)<br />
GLP/<br />
Liège<br />
Particle size<br />
distribution of<br />
dust (if relevant<br />
for exposure risk)<br />
Granules<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
OECD 110<br />
(or laser diffraction)<br />
/ GLP/<br />
Liège<br />
Friability <strong>and</strong><br />
attrition<br />
Granules<br />
- GR, CG : <strong>be</strong>fore <strong>and</strong> after<br />
s<strong>to</strong>rage at high temp<br />
(CIPAC MT 46) <strong>and</strong> at<br />
room temp. (GIFAP<br />
Monograph N° 17)<br />
- other : <strong>be</strong>fore s<strong>to</strong>rage<br />
CIPAC MT 178 / GLP/<br />
Liège/<br />
certified<br />
lab
Emulsifiability,<br />
re-emulsifiability,<br />
emulsion stability<br />
Preparations which<br />
form emulsions<br />
- Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
- At the highest <strong>and</strong> the<br />
lowest used concentration<br />
- CIPAC MT 36 (30<br />
°C, CIPAC water<br />
A+D, 0 min, 30 min,<br />
2h, 24h <strong>and</strong> 24h+30<br />
min)<br />
- if used at<br />
concentrations of < 2%<br />
: CIPAC MT 173 or<br />
173' ( CIPAC A+D<br />
water, 30°C, 0 min, 30<br />
min, 4 u)<br />
- SE : CIPAC MT 173'<br />
(30 °C, CIPAC water<br />
A+D, 0 min, 30 min)<br />
CIPAC MT 36 : initial<br />
emulsification <strong>and</strong> reemulsification<br />
: complete<br />
(NB : CIPAC MT 173' = by<br />
dosage of a.s.)<br />
GLP/<br />
Liège/<br />
certified<br />
lab<br />
Flowability Granules Before s<strong>to</strong>rage CIPAC MT 172 / GLP/<br />
Liège/<br />
certified<br />
lab<br />
Pourability<br />
(rinsability)<br />
(including rinsed<br />
residue)<br />
Suspensions (SC, SE,<br />
FS)<br />
Before <strong>and</strong> after s<strong>to</strong>rage at<br />
high temp. (CIPAC MT 46)<br />
<strong>and</strong> at room temp (GIFAP<br />
Monograph N° 17)<br />
CIPAC MT 148.1 / GLP/<br />
Liège/<br />
certified<br />
lab<br />
Dustability Dustable powders Before s<strong>to</strong>rage CIPAC MT 34 / GLP/<br />
Liège/<br />
certified<br />
lab
<strong>Physical</strong><br />
compatibility of<br />
tank mixes<br />
All (according <strong>to</strong><br />
proposed use)<br />
Before s<strong>to</strong>rage<br />
in-house test methods<br />
or practical tests<br />
/ GLP/<br />
Liège/<br />
certified<br />
lab<br />
Chemical<br />
compatibility of<br />
tank mixes<br />
All (according <strong>to</strong><br />
proposed use) (except<br />
when no possibility of<br />
reaction)<br />
Before s<strong>to</strong>rage practical tests / GLP/<br />
Liège/<br />
certified<br />
lab<br />
Adherence <strong>and</strong><br />
distribution <strong>to</strong><br />
seeds<br />
Preparations for seed<br />
treatment<br />
- DS : Before <strong>and</strong> after<br />
s<strong>to</strong>rage at high temp.<br />
(CIPAC MT 46) <strong>and</strong> at<br />
room temp (GIFAP<br />
Monograph N° 17)<br />
- Before s<strong>to</strong>rage<br />
Distribution: CIPAC<br />
MT 175<br />
Adherence: CIPAC<br />
MT 83<br />
/ GLP/<br />
Liège/<br />
certified<br />
lab
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