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Chapter-6 Entropy

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Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.<br />

The value of the integral depends on the end states on;y and not the<br />

path followed.<br />

This represents the change of a property.<br />

This is called entropy, S .<br />

dS<br />

Q<br />

( ) int rev<br />

T<br />

( kJ )<br />

K<br />

<strong>Entropy</strong> is an extensive property.<br />

2<br />

Q<br />

2 1 ( int rev<br />

T<br />

1<br />

The entropy change of a system: S<br />

S S )<br />

)<br />

Example: air temperature is raised from T1 to T2<br />

Q<br />

W<br />

Q<br />

<br />

S<br />

2<br />

1<br />

0<br />

dU<br />

<br />

<br />

Q<br />

(<br />

)<br />

T<br />

dU<br />

mC<br />

v<br />

intrev<br />

dT<br />

<br />

2<br />

<br />

1<br />

mCvdT<br />

T<br />

<br />

mC<br />

v<br />

T<br />

ln<br />

T<br />

2<br />

1<br />

Thermal<br />

insulation<br />

( kJ K<br />

Air<br />

Q

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