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Chapter 10 - An Introduction to Chemistry: Chemical Calculations ...

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396 <strong>Chapter</strong> <strong>10</strong> <strong>Chemical</strong> <strong>Calculations</strong> and <strong>Chemical</strong> Equations<br />

19. When two solutions are mixed <strong>to</strong> start a reaction, it is more convenient <strong>to</strong> measure<br />

their _____________ than their masses.<br />

20. Molarity (abbreviated M) is defined as moles of _____________ per liter of<br />

_____________.<br />

21. Conversion fac<strong>to</strong>rs constructed from molarities can be used in s<strong>to</strong>ichiometric<br />

calculations in very much the same way conversion fac<strong>to</strong>rs from _____________<br />

are used. When a substance is pure, its molar mass can be used <strong>to</strong> convert back and<br />

forth between the measurable property of _____________ and moles. When a<br />

substance is in solution, its molarity can be used <strong>to</strong> convert between the measurable<br />

property of _____________ and moles of solute.<br />

<strong>Chapter</strong><br />

Problems<br />

Objective 2<br />

Objective 3<br />

Objective 2<br />

Objective 3<br />

Section <strong>10</strong>.1 Equation S<strong>to</strong>ichiometry<br />

Section <strong>10</strong>.2 Real-World Applications of Equation S<strong>to</strong>ichiometry<br />

22. Because the bond between fluorine a<strong>to</strong>ms in F 2 is relatively weak while the<br />

bonds between fluorine a<strong>to</strong>ms and a<strong>to</strong>ms of other elements are relatively strong,<br />

it is difficult <strong>to</strong> make dia<strong>to</strong>mic fluorine, F 2 . One way it can be made is <strong>to</strong> run<br />

an electric current through liquid hydrogen fluoride, HF. This reaction yields<br />

hydrogen gas, H 2 , and fluorine gas, F 2 .<br />

a. Write a complete balanced equation, including states, for this reaction.<br />

b. Draw a picture of the reaction, using rough sketches of space-filling models<br />

in place of the coefficients and formulas in the equation. Fluorine a<strong>to</strong>ms<br />

have a little more than twice the diameter of hydrogen a<strong>to</strong>ms.<br />

c. Write a conversion fac<strong>to</strong>r that could be used <strong>to</strong> convert between moles of<br />

HF and moles of F 2 .<br />

d. How many moles of F 2 form when one mole of HF reacts completely?<br />

e. How many moles of HF react <strong>to</strong> yield 3.452 moles of H 2 ?<br />

23. Hydrogen gas is used for many purposes, including the hydrogenation of<br />

vegetable oils <strong>to</strong> make margarine. The most common industrial process for<br />

producing hydrogen is “steam reforming,” in which methane gas, CH 4 , from<br />

natural gas reacts with water vapor <strong>to</strong> form carbon monoxide gas and hydrogen<br />

gas.<br />

a. Write a complete balanced equation, including states, for this reaction.<br />

b. Draw a picture of the reaction, using rough sketches of space-filling models<br />

in place of the coefficients and formulas in the equation. Draw the carbon<br />

a<strong>to</strong>ms a little larger than the oxygen a<strong>to</strong>ms. Both carbon and oxygen a<strong>to</strong>ms<br />

have over twice the diameter of hydrogen a<strong>to</strong>ms.<br />

c. Write a conversion fac<strong>to</strong>r that could be used <strong>to</strong> convert between moles of<br />

methane and moles of hydrogen.<br />

d. How many moles of hydrogen form when 4 moles of methane react<br />

completely?<br />

e. How many moles of water vapor react <strong>to</strong> yield 174.82 moles of hydrogen?

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