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Prélèvement
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Filtration dans certains cas
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Rapatriement au laboratoire
Ajout de Fe, 150 Nd, 172 Yb
Attente > 24 h pour homogénéisation
Remontée du pH à 7 (NH 4 OH)
Attente de 48 à 72 h pour floculation
Siphonnage de l’eau surnageante
Transfert dans cône à centrifuger
Centrifugation, dilution du sel
Transfert bêcher, évaporation, reprise en HCl 6N
Séparation du Fe sur colonne
Évaporation, reprise HNO 3 0.3N
Ajout In-Re
Mesure ICP-MS
Traitement des données

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Élution des cartouches
Évaporation, reprise HCl 2N
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Évaporation, reprise HCl 0.3N
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Évaporation, reprise 1µL HCl 1N
Dépôt filament
Mesure TIMS
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Option Explicit
Sub REE()
'
Dim listingicp, nomechantillon, nompesee, traitement, jour As String
Dim premiereligne, i, j, k, nbrligneparech, nbricp, icpasuivant, choix, position As Integer
Dim concIn, concRe, Ceojour, concNd, ConcYb As Double
' MODULE GENERAL
' ouvre model.xls et le sauve sous traitement.xls
traitement = InputBox("entrez le nom du fichier resultat")
Workbooks.Open FileName:="C:\Francois\ICP-MS\Traitement\model.xls"
Workbooks("model.xls").SaveAs FileName:= _
"C:\Francois\ICP-MS\Traitement\" & traitement
concIn = InputBox("entrez la concentration d'In dans In-Re en ppm")
concRe = InputBox("entrez la concentration de Re dans In-Re en ppm")
Ceojour = InputBox("entrez Ceojour (valeur de l'ordre de 1)")
concNd = InputBox("entrez la concentration de Nd dans le spike en ppb")
ConcYb = InputBox("entrez la concentration d'Yb dans le spike en ppb")
Sheets("model").Activate
ActiveSheet.Cells(13, 3) = concIn
ActiveSheet.Cells(14, 3) = concRe
ActiveSheet.Cells(15, 3) = concNd
ActiveSheet.Cells(16, 3) = ConcYb
ActiveSheet.Cells(17, 3) = Ceojour
nompesee = InputBox("entrez le nom du fichier de pesee situé dans le repertoire traitement")
Workbooks.Open FileName:="C:\Francois\ICP-MS\Traitement\" & nompesee
' ouvre le listing
listingicp = InputBox _
("entrez le nom du fichier de donnees ICP se trouvant dans le repertoire listingICP")
Workbooks.Open FileName:="C:\Francois\ICP-MS\listingICP\" & listingicp
' demande la premiere ligne du listing et compte le nombre de ligne par echantillon
premiereligne = InputBox("entrez le numero de la 1ere ligne du listing ICP")
jour = Workbooks(listingicp).Sheets(1).Cells(1, 1)
i = 2
Do While Workbooks(listingicp).Sheets(1).Cells(i, 1) jour
i = i + 1
Loop
nbrligneparech = i - 1
'Remplissage des icp
Workbooks(listingicp).Activate
j = 0
i = premiereligne
Do While Cells(i, 1) ("")
If Cells(i, 1) Like ("ICPA*") Then
Range(Cells(i + 2, 3), Cells(i + 32, 4)).Copy
Workbooks(traitement).Sheets("ICP").Activate
ActiveSheet.Range(Cells(4, 5 + 2 * j), Cells(34, 6 + 2 * j)) _
.PasteSpecial Paste:=xlPasteValues
Cells(2, 6 + 2 * j) = Workbooks(listingicp).Sheets(1).Cells(i - 1, 5)
Cells(1, 5 + 2 * j) = ("ICPA")
Cells(2, 5 + 2 * j) = Workbooks(listingicp).Sheets(1).Cells(i - 1, 1).Row
Workbooks(listingicp).Activate
j = j + 1

‹
End If
i = i + 1
Loop
nbricp = j
' copie des conc icp de icp vers model
Workbooks(traitement).Sheets("ICP").Activate
ActiveSheet.Range(Cells(4, 2), Cells(34, 2)).Copy
Sheets("model").Activate
ActiveSheet.Range(Cells(43, 6), Cells(73, 6)).PasteSpecial Paste:=xlPasteValues
' MODULE A REPETER A CHAQUE ECHANTILLON
'
i = premiereligne
j = 0
Do While Workbooks(listingicp).Sheets(1).Cells(i, 1) ("")
If Workbooks(listingicp).Sheets(1).Cells(i + 1, 1) Like ("#*") Then
Workbooks(traitement).Sheets("model").Copy _
before:=Workbooks(traitement).Sheets("model") 'nouvelle feuille
nomechantillon = Workbooks(listingicp).Sheets(1).Cells(i + 1, 1) 'on la renomme
Workbooks(traitement).ActiveSheet.Name = nomechantillon
Cells(1, 2) = nomechantillon
Cells(2, 2) = Workbooks(listingicp).Sheets(1).Cells(i, 5) 'heure
copie les coups echantillon
Workbooks(listingicp).Activate
ActiveWorkbook.Sheets(1).Range(Cells(i + 3, 3), Cells(i + 33, 4)).Copy
Workbooks(traitement).Activate
ActiveWorkbook.Sheets(nomechantillon).Range("C43:D73").PasteSpecial Paste:=xlPasteValues
'copie les pesees
With Workbooks(traitement).Sheets(nomechantillon)
.Cells(6, 3) = Workbooks(nompesee).Sheets(1).Cells(3 + j, 1)
.Cells(7, 3) = Workbooks(nompesee).Sheets(1).Cells(3 + j, 2)
.Cells(8, 3) = Workbooks(nompesee).Sheets(1).Cells(3 + j, 3)
.Cells(9, 3) = Workbooks(nompesee).Sheets(1).Cells(3 + j, 4)
.Cells(10, 3) = Workbooks(nompesee).Sheets(1).Cells(3 + j, 5)
.Cells(11, 3) = Workbooks(nompesee).Sheets(1).Cells(3 + j, 6)
End With
'recherche de ICPA suivant
icpasuivant = 0
For k = 0 To nbricp - 1 Step 1
If Workbooks(traitement).Sheets("ICP").Cells(2, 5 + 2 * k) > i Then
icpasuivant = (5 + 2 * k)
k = nbricp
End If
Next
If icpasuivant = 0 Then
MsgBox ("probleme icpa suivant")
Stop
End If
'collage des icpa
collageicp traitement, nomechantillon, icpasuivant, 1
MsgBox ("1) resultats avec ICPA precedent:")
collageicp traitement, nomechantillon, icpasuivant, 2
MsgBox ("2) resultats avec moyenne ICPA :")
collageicp traitement, nomechantillon, icpasuivant, 3
MsgBox ("3) resultats avec ICPA suivant:")

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choix = InputBox("votre choix: 1, 2 ou 3")
Select Case choix
Case 1
collageicp traitement, nomechantillon, icpasuivant, 1
MsgBox ("1) resultats avec ICPA precedent:")
Case 2
collageicp traitement, nomechantillon, icpasuivant, 2
MsgBox ("2) resultats avec moyenne ICPA :")
Case 3
MsgBox ("3) resultats avec ICPA suivant:")
End Select
'incremente les indices pour avancer dans les fichiers pesee et listing et sauve la nouvelle feuille
j = j + 1
i = i + nbrligneparech
Else
i = i + nbrligneparech
End If
ActiveWorkbook.Save
Loop
MsgBox ("merci d'avoir joué avec nous")
End Sub
Private Sub collageicp(traitement, nomechantillon, icpasuivant, position)
Dim lignedebut, colonnedebut, lignefin, colonnefin As Integer
Select Case position
Case 1
lignedebut = 4
colonnedebut = icpasuivant - 2
lignefin = 34
colonnefin = icpasuivant - 1
Case 2
lignedebut = 129
colonnedebut = icpasuivant - 3
lignefin = 159
colonnefin = icpasuivant - 3
Case 3
lignedebut = 4
colonnedebut = icpasuivant
lignefin = 34
colonnefin = icpasuivant + 1
End Select
Workbooks(traitement).Sheets("ICP").Activate
ActiveSheet.Range(Cells(lignedebut, colonnedebut), Cells(lignefin, colonnefin)).Copy
Sheets(nomechantillon).Range("g43").PasteSpecial Paste:=xlPasteValues
Sheets(nomechantillon).Activate
End Sub

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IDENTIFICATION DONNEES HYDROLOGIQUES COMPOSITION ISOTOPIQUE DE Nd CONCENTRATION DE Nd
Filtration
ε Nd (x si filtré) Méthode [Nd]
(10 -12 g/g)
Nombre de
scans (si <
à 100)
143 Nd/
144 Nd
2σ
(x10 -6 )
Filtration
(x si filtré)
O2
θ (°C) S (PSU) σ θ (mg/L)
Profondeur
(m)
Station (nom,
position, date,
profondeur)
1
55.03°N, -52.14°E 21 4.81 34.43 27.25 10.62 0.511845 11 -15.5 Cart. 2.48
05/07/1999 198 3.80 34.79 27.64 9.42 x 0.511889 10 -14.6
2716 m
2
58.92°N, -47.12°E 30 5.12 34.49 27.25 10.00 0.511942 10 -13.6 Cart. 2.59
06/07/1999 101 4.19 34.78 27.59 9.72 0.511919 10 -14.0 Cart. 2.75
2901 m 230 4.27 34.90 27.67 9.38 0.511907 12.5 80 -14.3
600 3.52 34.84 27.71 9.43 0.511927 11 -13.9 Cart. 2.73
1000 3.27 34.86 27.75 9.14 0.511939 10 -13.6 Cart. 2.66
1600 2.87 34.85 27.77 9.47 0.511946 11 -13.5 Cart. 2.50
2270 2.57 34.89 27.84 9.16 0.511993 12 -12.6 2.49
2550 2.10 34.89 27.87 9.26 0.512018 10 -12.1 2.62
2796 1.29 34.84 27.90 9.82 0.512100 11 -10.5 Cart. 2.28
3
62.65°N, -53.90°E 16 3.85 33.61 26.70 10.87 0.511863 12 -15.1 Cart. 3.42
09/07/1999 41 2.83 33.96 27.07 10.50 0.511907 12 -14.3
2476 m 178 4.70 34.87 27.61 9.14 x 0.511863 10 -15.1
400 4.36 34.90 27.67 9.14 0.511875 10 -14.9 4.01
998 3.42 34.86 27.74 9.06 0.511862 9 -15.1 x 3.12
1700 2.87 34.86 27.78 9.33 0.511895 10 -14.5 3.66
2251 2.50 34.88 27.84 9.20 0.511796 12 -16.4
2431 1.83 34.87 27.88 9.45 0.511873 12 -14.9
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57.96°N, -57.39°E ~ 7 ~ 6 ~ 34 - - x 0.511829 9 -15.8 x 3.93
11/08/1999 ~ 7 ~ 6 ~ 34 - - 0.511830 15 60 -15.8 3.85
Prof. inconnue
5
55,01°N, -56.40°E ~ 7 ~ 1.5 ~ 30.6 - - x 0.511361 10 -24.9 x 6.32
11/07/1999
Prof. inconnue
6
50.20°N, -45.68°E 26 8.65 33.92 26.33 9.75 0.511602 11 -20.2 4.91
14/07/1999 1650 2.99 34.86 27.77 9.29 0.511923 10 -13.9 2.50
3540 m 2499 2.70 34.90 27.84 9.06 0.511961 10 -13.2 2.64
3501 1.79 34.88 27.89 9.45 0.511897 9 -14.5 Cart. 4.76
7
55.55°N, -43.97°E 40 6.60 34.63 27.19 9.89 0.511837 9 -15.6 Cart. 3.08
16/07/1999 325 3.43 34.82 27.70 9.28 0.511886 10 -14.7 Cart. 2.74
3225 m 476 3.42 34.84 27.72 9.14 0.511890 11 -14.6 Cart. 2.94
926 3.21 34.86 27.75 9.07 0.511917 9 -14.1 2.57
2101 2.91 34.89 27.80 9.15 0.511955 9 -13.3 Cart. 2.95
2750 2.62 34.92 27.86 8.96 0.511981 10 -12.8 2.71
3270 2.12 34.90 27.88 9.18 0.511977 10 -12.9 Cart. 3.25
8
62.07°N, -40.19°E 201 5.90 35.02 27.59 8.84 0.511909 12 -14.2 3.00
16/07/1999
3225 m
9
62.70°N, -37.59°E 25 9.33 35.01 27.07 9.68 0.511889 10 -14.6 2.68
18/07/1999 101 6.48 35.05 27.53 8.79 0.511925 8 -13.9 Cart. 2.71
2125 m 205 5.60 35.00 27.60 8.88 0.511917 10 -14.1 2.76
601 4.10 34.90 27.70 9.04 0.511956 10 -13.3 2.66
1026 3.41 34.89 27.76 8.99 0.511933 11 -13.8 2.79
1519 2.88 34.85 27.78 9.47 0.511960 12 -13.2 Cart. 2.83
1801 2.70 34.87 27.81 9.39 0.512006 11 -12.3 Cart. 2.89
2100 1.22 34.85 27.91 9.99 0.512153 9 -9.5 3.35

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IDENTIFICATION DONNEES HYDROLOGIQUES COMPOSITION ISOTOPIQUE DE Nd CONCENTRATION DE Nd
Station (nom,
position, date,
profondeur)
Profondeur
(m)
θ (°C) S (PSU) σ θ
O2
(mg/L)
Filtration 143
(x si filtré)
Nd/ 144 Nd
2σ
(x10 -6 )
Nombre de
scans (si <
à 100)
ε Nd
Filtration
(x si filtré) Méthode [Nd]
(10 -12 g/g)
12
56.37°N, -27.82°E 20 11.39 35.00 26.70 8.52 0.511878 10 -14.8 Cart. 2.51
22/07/1999 74 9.97 35.07 27.01 8.53 0.511873 9 -14.9 Cart. 2.81
2840 m 250 6.90 34.89 27.35 7.68 0.511866 9 -15.1 2.80
351 6.37 34.91 27.43 7.86 0.511867 11 -15.0 Cart. 2.89
500 5.47 34.94 27.57 7.41 0.511878 10 -14.8 Cart. 2.85
651 4.91 34.97 27.66 7.69 0.511884 10 -14.7 Cart. 2.80
1101 3.65 34.90 27.74 8.68 0.511907 10 -14.3 2.65
1750 3.07 34.88 27.78 9.21 0.511917 11 -14.1 Cart. 2.66
2500 2.66 34.95 27.88 8.85 0.511993 11 -12.6 Cart. 2.88
2828 2.48 34.96 27.90 8.99 0.512119 11 -10.1 Cart. 2.72
14
65.02°N, -30.23°E 31 9.55 35.06 27.08 9.14 0.511921 9 -14.0 2.15
27/07/1999 401 6.46 35.09 27.56 8.68 0.511959 11 -13.2 2.59
1875 m 549 5.63 35.02 27.61 8.53 0.511940 12 -13.6 2.62
1229 3.70 34.93 27.77 8.85 0.511981 10 -12.8 2.70
1860 2.35 34.89 27.85 9.47 0.512066 11 -11.2 2.71
15
65.32°N, -30.88°E 20 8.87 35.09 27.21 9.28 0.511935 11 -13.7 2.40
27/07/1999 750 4.49 34.94 27.68 8.77 0.511937 10 -13.7 2.52
993 m 800 4.44 34.96 27.71 8.48 0.511964 10 -13.1 2.57
984 1.36 34.82 27.88 10.08 0.512096 12 60 -10.6 2.66
16
65.17°N, -30.52°E 200 7.05 35.14 27.52 9.13 0.511912 11 -14.2 2.88
27/07/1999 1002 3.82 34.94 27.76 8.76 0.512034 11 -11.8 Cart. 2.28
1500 m 1299 0.92 34.77 27.86 10.40 0.512091 11 -10.7 3.01
1399 0.49 34.81 27.93 10.50 0.512105 9 -10.4 2.85
17
67.98°N, -21.78°E 405 -0.05 34.85 27.99 10.37 0.512107 10 -10.4 2.46
29/07/1999
861 m

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18
69.07°N, -7.91°E 640 -0.35 34.88 28.03 9.91 0.512118 14 80 -10.1 2.59
01/08/1999 989 -0.71 34.89 28.05 9.74 0.512146 11 -9.6 3.10
1020 m
19
69.12°N, -7.50°E 20 6.52 34.76 27.29 10.10 0.512101 11 -10.5 1.74
01/08/1999 1500 -0.87 34.90 28.07 9.69 0.512116 10 -10.2 2.53
2065 m
20
69.21°N, -6.85°E 331 0.22 34.86 27.98 10.44 0.512207 11 -8.4 2.87
02/08/1999 2491 -1.02 34.90 28.07 9.63 0.512136 10 -9.8 2.69
2502 m
21
66.55°N, -10.11°E 20 7.94 34.65 27.00 10.15 0.512230 11 -8.0 2.13
03/08/1999 101 -0.26 34.75 27.92 11.74 0.512164 12 -9.2 2.25
1450 m 1000 -0.68 34.89 28.05 9.68 0.512134 11 -9.8 Cart. 2.20
1431 -0.87 34.90 28.07 9.43 0.512231 10 -7.9 2.96
22
62.75°N, -9.01°E 20 10.96 35.24 26.97 9.22 0.511963 12 -13.2 1.83
04/08/1999 50 9.19 35.29 27.32 9.04 0.511960 10 -13.2 2.52
490 m 200 8.18 35.26 27.45 9.03 0.511929 12 -13.8 Cart. 2.55
411 7.41 35.21 27.53 8.40 0.512029 11 -11.9 Cart. 2.01
483 5.71 35.13 27.70 8.82 0.512436 9 -3.9 4.04
23
60.50°N, -5.00°E 51 10.13 35.34 27.20 8.92 0.511970 12 -13.0 2.44
06/08/1999 99 9.20 35.33 27.35 8.93 0.511982 11 80 -12.8 2.64
1000 m 280 7.72 35.24 27.50 9.16 0.511984 10 -12.8 2.38
500 2.41 34.92 27.88 10.50 0.512172 11 -9.1 2.76
599 0.33 34.88 27.99 10.37 0.512221 10 -8.1 Cart. 2.89
800 -0.60 34.89 28.05 10.09 0.512170 11 -9.1 2.87
988 -0.77 34.90 28.06 9.97 0.512266 10 -7.3 3.54
24
62.74°N, -4.00°E 20 9.76 35.01 27.00 9.83 0.511976 10 -12.9 2.21
07/08/1999 100 8.14 35.26 27.45 9.14 0.511946 10 -13.5 2.67
1010 m 375 1.77 34.87 27.89 10.68 0.512183 12 -8.9 Cart. 2.57
450 1.02 34.87 27.94 10.50 0.512200 10 -8.5 Cart. 2.44
950 -0.53 34.89 28.04 10.02 0.512381 10 -5.0 Cart. 2.89
1003 -0.54 34.89 28.04 10.00 0.512346 11 -5.7 3.69

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IDENTIFICATION
Station (nom,
position, date,
profondeur)
Profondeur
(m)
DONNEES HYDROLOGIQUES COMPOSITION ISOTOPIQUE DE Nd CONCENTRATION DE Nd
θ (°C) S (PSU) σ θ
O2
(mg/L)
Filtration 143
(x si filtré)
Nd/ 144 Nd
2σ
(x10 -6 )
Nombre de
scans (si <
à 100)
ε Nd
Filtration
(x si filtré) Méthode [Nd]
(10 -12 g/g)
25
64.65°N, 4.18°E 21 12.23 35.04 26.57 9.36 0.511961 10 -13.2 2.24
11/08/1999 101 8.11 35.27 27.47 8.86 0.511968 11 -13.1 3.44
1400 m 401 2.88 34.92 27.83 10.13 0.512160 11 -9.3 Cart. 2.76
600 -0.24 34.89 28.03 10.12 0.512121 10 -10.1 Cart. 2.52
800 -0.67 34.89 28.05 9.99 0.512128 10 -9.9 Cart. 2.54
1385 -0.96 34.90 28.07 9.74 0.512172 11 -9.1 3.29
26
69.03°N, 7.95°E 43 8.29 35.19 27.38 9.64 0.512011 12 80 -12.2 Cart. 1.30
14/08/1999 74 7.27 35.22 27.55 9.28 0.512016 10 -12.1 2.94
3060 m 351 4.84 35.10 27.77 9.80 0.512017 12 -12.1 Cart. 2.25
801 0.93 34.89 27.96 10.19 0.512115 10 -10.2 3.16
1001 -0.21 34.88 28.02 10.07 0.512130 11 -9.9 Cart. 2.32
1700 -0.82 34.90 28.07 9.75 0.512108 12 -10.3 Cart. 2.49
2972 -1.01 34.90 28.08 9.79 0.512135 9 -9.8 3.93
29
77.67°N, 7.69°E 2 4.86 26.61 21.05 7.36 0.512042 9 -11.6 2.08
22/08/1999 50 4.88 35.08 27.76 10.01 0.512038 10 -11.7 2.42
3320 m 248 3.40 35.03 27.87 9.98 0.512065 10 -11.2 2.50
604 0.37 34.88 27.99 10.63 0.512072 10 -11.0 2.44
1513 -0.85 34.90 28.07 9.75 0.512120 15 80 -10.1 2.41
2423 -1.00 34.90 28.08 9.80 0.512115 10 -10.2 Cart. 2.69
3360* -0.99 34.91 28.08 9.88 0.512098 11 -10.5 2.73
30
76.74°N, -2.33°E 5 4.60 34.68 27.47 8.90 0.512051 16 60 -11.5 2.52
22/08/1999 21 4.56 34.72 27.50 7.51 x 0.512011 11 -12.2 x 2.28
2560 m 103 2.21 34.97 27.93 10.30 0.512058 12 80 -11.3 2.56
405 0.20 34.90 28.01 10.53 0.512065 10 -11.2
505 0.00 34.89 28.02 10.64 0.512062 11 -11.2 2.44
1314 -0.67 34.91 28.07 9.73 0.512092 11 40 -10.7 2.49
2016 -1.00 34.90 28.07 9.85 0.512099 11 -10.5
2512 -1.06 34.90 28.08 9.94 x 0.512117 10 -10.2 x 2.58
2512 -1.06 34.90 28.08 9.94 0.512083 12 -10.8 2.83

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32
77.03°N, -3.75°E 21 -1.25 33.24 26.74 12.23 x 0.512150 12 80 -9.5
23/08/1999 21 -1.25 33.24 26.74 12.23 0.512135 12 -9.8 3.39
1895 m 123 3.12 34.89 27.79 9.48 0.512051 10 -11.5 2.82
208 2.60 34.96 27.89 9.95 0.512043 12 -11.6 2.64
208 2.60 34.96 27.89 9.95 0.512002 10 -12.4 3.03
482 1.33 34.92 27.96 10.02 0.512033 11 -11.8 2.49
608 0.61 34.88 27.98 9.78 0.512088 10 -10.7 2.46
805 0.14 34.89 28.01 10.03 0.512066 11 -11.2
1423 -0.57 34.91 28.06 9.80 0.512052 16 53 -11.4 2.64
1840 -0.74 34.92 28.07 9.73 x 0.512121 11 -10.1
1840 -0.74 34.92 28.07 9.73 0.512087 10 -10.7
33
77.18°N, -4.39°E 20 -0.69 33.16 26.65 13.37 0.512167 10 -9.2 3.57
23/08/1999 50 -0.69 33.16 26.65 13.37 0.512108 11 -10.3 3.36
1575 m 351 2.14 34.97 27.94 10.08 0.512046 22 40 -11.5 2.71
42
72.91°N, -12.97°E 707 -0.53 34.88 28.04 10.40 0.512079 11 -10.9 2.36
25/08/1999 2635 -1.12 34.90 28.08 10.00 x 0.512113 13 80 -10.2 x 3.15
2690 m
45
72.91°N, -15.85°E 1521 -0.84 34.91 28.08 9.68 0.512102 11 -10.5 3.11
25/08/1999
2000 m
46
72.87°N, -16.18°E 50 -1.00 34.33 27.61 11.64 0.512077 11 -10.9 3.22
26/08/1999 900 -0.46 34.89 28.04 10.05 0.512095 11 -10.6 2.41
1520 m
48
70.00°N, -17.01°E 431 -0.04 34.88 28.01 10.41 0.512068 12 -11.1 2.38
26/08/1999 698 -0.42 34.89 28.04 10.09 0.512083 11 -10.8 2.39
1280 m 1001 -0.65 34.90 28.06 9.88 0.512086 11 -10.8 2.37
50
70.00°N, -18.00°E 404 0.15 34.90 28.01 10.39 0.512106 19.5 40 -10.4 2.43
27/08/1999 573 -0.35 34.89 28.04 10.21 0.512096 17 60 -10.6 2.41
1655 m 1007 -0.67 34.90 28.06 9.89 0.512091 9 -10.7 2.49
1596 -0.91 34.91 28.08 9.76 0.512052 7 -11.4 3.75

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IDENTIFICATION DONNEES HYDROLOGIQUES COMPOSITION ISOTOPIQUE DE Nd CONCENTRATION DE Nd
Station (nom,
position, date,
profondeur)
Profondeur
(m)
θ (°C) S (PSU) σ θ
O2
(mg/L)
Filtration 143
(x si filtré)
Nd/ 144 Nd
2σ
(x10 -6 )
Nombre de
scans (si <
à 100)
ε Nd
Filtration
(x si filtré) Méthode [Nd]
(10 -12 g/g)
52
68.21°N, -29.63°E 6 2.32 30.53 24.37 11.31 0.512427 11 -4.1 13.52
28/08/1999 80 -1.35 33.13 26.65 11.97 0.512478 9 -3.1 14.64
375 m 251 1.02 34.56 27.69 10.46 0.512416 10 -4.3 6.78
303 0.20 34.57 27.74 10.54 0.512524 10 -2.2 11.91
53
68.20°N, -29.63°E 183 3.31 34.52 27.47 10.15 0.512117 10 -10.2 3.62
28/08/1999 200 4.31 34.77 27.57 9.68 0.512078 14 80 -10.9 3.04
450 m
54
66.16°N, -27.52°E 5 3.81 31.40 24.94 11.02 0.512100 12 -10.5 5.98
29/08/1999 59 -1.47 33.65 27.07 11.59 0.512065 11 -11.2 14.70
500 m 120 -1.39 34.19 27.51 11.08 0.512060 12 -11.3
352 0.16 34.83 27.96 10.55 0.512091 11 -10.7 3.52
442 -0.03 34.87 28.01 10.29 0.512268 10 -7.2 2.82
479 -0.04 34.87 28.01 10.18 0.512168 16 60 -9.2 3.33
55
66.08°N, -27.25°E 11 5.71 33.45 26.36 10.47 0.512073 12 -11.0 4.04
29/08/1999 51 2.62 34.39 27.43 10.76 0.512047 19 80 -11.5 5.91
625 m 97 6.80 35.13 27.55 8.86 0.511961 12 -13.2 2.71
372 0.15 34.84 27.97 10.85 0.512188 11 -8.8
610 -0.12 34.88 28.02 10.20 0.512125 12 -10.0 2.47
610 -0.12 34.88 28.02 10.20 x 0.512211 14 60 -8.3 x 2.65
56
66.01°N, -26.98°E 10 5.16 32.52 25.70 10.79 0.512104 9 -10.4
4.33
29/08/1999 54 -0.46 33.30 26.75 12.40 0.512161 11 -9.3 4.56
560 m 120 3.58 34.40 27.35 10.40 0.512048 11 -11.5 3.02
182 6.29 35.06 27.56 9.20 0.512019 12 -12.1 2.80
302 4.45 34.91 27.66 9.27 0.512069 12 -11.1
345 -0.25 34.53 27.74 10.77 0.512242 11 -7.7 2.99
544+502 -0.51 34.90 28.05 9.99 0.512264 11 -7.3 4.12

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Fjord Bergen
60.87°N, 4.67°E ~ 7 - ~ 31.9 - - 0.511870 11 -15.0 Cart. 8.64
11/08/1999 ~ 7 - ~ 31.9 - - x 0.511886 10 -14.7 x Cart. 8.94
Fjord Trodheim
63.62°N, 9.32°E ~ 7 ~ 12.4 ~ 31.9 - - 0.511993 8 -12.6 Cart. 12.51
13/08/1999 ~ 7 ~ 12.4 ~ 31.9 - - x 0.511998 11 -12.5 x Cart. 12.37
Fjord Spitzberg
67.82°N, 15.27°E ~ 7 ~ 3.7 ~ 31.9 - - 0.512058 10 -11.3 Cart. 21.95
21/08/1999 ~ 7 ~ 3.7 ~ 31.9 - - x 0.512065 10 -11.2 x 12.75
Fjord Nansen
68.21°N, -29.66°E ~ 7 ~ 2.1 ~ 30.6 - - 0.512567 11 -1.4 14.54
28/08/1999 ~ 7 ~ 2.1 ~ 30.6 - - x 0.512205 11 -8.4 x 5.74
Sédiment de
surface, station
43, carotte MD99-
2308Hy
Sédiment de
surface, station
38, carotte MD99-
2307Hy
Sable de plage
Spitzberg
ECHANTILLONS SOLIDES
2520 - - - - 0.511935 11 -13.7 26991531
2321 - - - - 0.512052 8 -11.4 24372887
0 - - - - 0.511912 9 -14.2 4335579

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IDENTIFICATION DONNEES HYDROLOGIQUES PARAMETRES DE MESURE
CONCENTRATIONS (10 -12 g/g)
Station (nom,
position, date,
profondeur)
Profondeur
(m)
θ (°C) S (PSU) σ θ O2 (mg/L)
Filtration (x
si filtré)
Méthode Rendement La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Ce* La/Yb
1
55.03°N, -52.14°E 21 4.81 34.43 27.25 10.62 Cart. 94% 2.13 1.55 0.59 2.48 0.53 0.12 0.67 0.10 0.77 0.20 0.69 0.10 0.58 0.09 0.32 0.27
05/07/1999
2716 m
2
58.92°N, -47.12°E 30 5.12 34.49 27.25 10.00 Cart. 98% 1.77 1.19 0.59 2.59 0.52 0.13 0.75 0.12 0.89 0.24 0.80 0.11 0.69 0.11 0.26 0.19
06/07/1999 30 5.12 34.49 27.25 10.00 x 85% 3.44 1.26 0.59 2.72 0.56 0.14 0.77 0.13 0.97 0.25 0.93 0.12 0.78 0.14 0.20 0.33
2901 m 101 4.19 34.78 27.59 9.72 Cart. 97% 1.67 1.20 0.63 2.75 0.56 0.15 0.81 0.13 0.99 0.25 0.89 0.13 0.81 0.13 0.26 0.15
600 3.52 34.84 27.71 9.43 Cart. 100% 2.12 1.09 0.63 2.73 0.54 0.14 0.77 0.13 0.93 0.25 0.84 0.11 0.70 0.10 0.22 0.22
1000 3.27 34.86 27.75 9.14 Cart. 98% 2.38 1.04 0.63 2.66 0.54 0.15 0.80 0.13 0.96 0.25 0.88 0.12 0.73 0.11 0.20 0.23
1600 2.87 34.85 27.77 9.47 Cart. 101% 1.98 1.06 0.58 2.50 0.50 0.12 0.72 0.12 0.85 0.22 0.76 0.11 0.66 0.10 0.23 0.22
1850 2.85 34.87 27.79 9.27 89% 3.45 1.22 0.58 2.61 0.53 0.13 0.73 0.13 0.94 0.25 0.90 0.12 0.80 0.14 0.20 0.32
2270 2.57 34.89 27.84 9.16 91% 3.22 0.95 0.55 2.49 0.54 0.14 0.74 0.12 0.93 0.25 0.88 0.12 0.80 0.14 0.16 0.30
2270 2.57 34.89 27.84 9.16 Cart. 98% 2.02 0.96 0.54 2.43 0.53 0.12 0.72 0.12 0.85 0.22 0.77 0.10 0.65 0.09 0.21 0.23
2550 2.10 34.89 27.87 9.26 90% 3.52 1.15 0.57 2.62 0.54 0.14 0.72 0.13 0.93 0.24 0.86 0.12 0.80 0.14 0.18 0.32
2550 2.10 34.89 27.87 9.26 Cart. 97% 2.24 1.05 0.61 2.56 0.55 0.14 0.76 0.12 0.92 0.24 0.82 0.11 0.69 0.10 0.21 0.24
2796 1.29 34.84 27.90 9.82 Cart. 93% 1.42 0.70 0.52 2.28 0.49 0.13 0.67 0.11 0.79 0.21 0.68 0.09 0.51 0.07 0.18 0.21
2876 1.21 34.84 27.90 9.86 x 91% 3.75 2.44 0.72 3.20 0.68 0.18 0.88 0.15 1.09 0.27 0.92 0.13 0.83 0.14 0.34 0.33
2876 1.21 34.84 27.90 9.86 71% 3.25 1.90 0.62 3.01 0.60 0.17 0.89 0.14 1.03 0.26 0.95 0.12 0.90 0.14 0.31 0.28
3
62.65°N, -53.90°E 16 3.85 33.61 26.70 10.87 Cart. 100% 3.16 2.98 0.82 3.42 0.60 0.15 0.84 0.14 0.97 0.25 0.85 0.12 0.71 0.10 0.43 0.33
09/07/1999 16 3.85 33.61 26.70 10.87 x 87% 8.84 11.38 1.64 6.13 0.68 0.17 1.09 0.15 1.12 0.29 1.04 0.14 0.92 0.15 0.69 0.74
2476 m 400 4.36 34.90 27.67 9.14 92% 5.67 5.19 1.01 4.01 0.53 0.13 0.76 0.13 0.97 0.25 0.91 0.12 0.79 0.13 0.50 0.54
998 3.42 34.86 27.74 9.06 x 93% 4.13 2.45 0.72 3.12 0.53 0.14 0.73 0.13 0.94 0.25 0.86 0.12 0.81 0.14 0.32 0.38
1700 2.87 34.86 27.78 9.33 92% 5.45 4.23 0.92 3.66 0.55 0.14 0.73 0.13 0.94 0.25 0.86 0.12 0.79 0.14 0.43 0.51
4
57.96°N, -57.39°E ~ 7 ~ 6 ~ 34 - - 88% 5.22 3.39 0.89 3.85 0.74 0.18 0.96 0.16 1.15 0.29 1.03 0.14 0.90 0.15 0.36 0.43
11/08/1999 ~ 7 ~ 6 ~ 34 - - x 89% 5.75 5.64 1.12 3.93 0.73 0.17 0.94 0.16 1.16 0.28 1.00 0.13 0.90 0.15 0.51 0.47
Prof. inconnue
5
55,01°N, -56.40°E ~ 7 ~ 1.5 ~ 30.6 - - x 94% 8.78 5.44 1.53 6.32 1.06 0.22 1.25 0.19 1.41 0.36 1.22 0.17 1.12 0.19 0.34 0.58
11/07/1999
Prof. inconnue
6
50.20°N, -45.68°E 26 8.65 33.92 26.33 9.75 30% 2.32 2.95 1.01 4.91 0.97 0.20 0.91 0.13 0.95 0.26 0.93 0.13 0.96 0.16 0.42 0.18
14/07/1999 1650 2.99 34.86 27.77 9.29 84% 2.65 0.96 0.54 2.50 0.51 0.13 0.69 0.12 0.90 0.23 0.83 0.11 0.78 0.14 0.19 0.25
3540 m 1650 2.99 34.86 27.77 9.29 Cart. 102% 2.67 1.17 0.66 2.84 0.58 0.14 0.81 0.13 0.95 0.26 0.86 0.12 0.74 0.11 0.20 0.27
2151 2.87 34.88 27.80 9.19 91% 3.41 1.18 0.57 2.60 0.49 0.13 0.71 0.12 0.92 0.24 0.87 0.12 0.80 0.14 0.19 0.32
2499 2.70 34.90 27.84 9.06 91% 3.56 1.43 0.61 2.64 0.50 0.13 0.72 0.13 0.94 0.26 0.90 0.12 0.82 0.15 0.22 0.32
3501 1.79 34.88 27.89 9.45 Cart. 98% 5.88 8.51 1.45 4.76 0.56 0.14 0.83 0.13 0.94 0.24 0.82 0.11 0.67 0.11 0.67 0.62
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7
55.55°N, -43.97°E 2 7.80 34.60 26.99 9.64 x 64% 1.80 1.01 0.54 2.60 0.53 0.13 0.65 0.11 0.82 0.20 0.75 0.11 0.70 0.11 0.24 0.19
16/07/1999 40 6.60 34.63 27.19 9.89 Cart. 100% 2.90 2.19 0.75 3.08 0.52 0.13 0.74 0.12 0.87 0.23 0.78 0.10 0.60 0.09 0.34 0.35
3225 m 60 4.82 34.70 27.46 9.87 92% 3.69 1.61 0.63 2.80 0.51 0.13 0.70 0.11 0.93 0.23 0.86 0.11 0.78 0.13 0.24 0.36
325 3.43 34.82 27.70 9.28 Cart. 95% 1.61 1.22 0.61 2.74 0.57 0.15 0.82 0.14 0.95 0.26 0.88 0.13 0.77 0.11 0.28 0.15
476 3.42 34.84 27.72 9.14 Cart. 98% 3.09 1.20 0.69 2.94 0.58 0.15 0.85 0.14 1.00 0.26 0.91 0.12 0.73 0.11 0.19 0.30
926 3.21 34.86 27.75 9.07 94% 3.34 0.91 0.54 2.57 0.50 0.13 0.72 0.12 0.93 0.25 0.88 0.12 0.79 0.14 0.15 0.32
926 3.21 34.86 27.75 9.07 Cart. 88% 2.68 0.93 0.62 2.78 0.56 0.14 0.82 0.14 1.01 0.27 0.91 0.13 0.79 0.12 0.17 0.25
2101 2.91 34.89 27.80 9.15 Cart. 100% 2.57 1.59 0.67 2.95 0.54 0.14 0.78 0.13 0.94 0.24 0.84 0.11 0.72 0.11 0.28 0.26
2750 2.62 34.92 27.86 8.96 73% 1.66 1.48 0.58 2.71 0.54 0.14 0.66 0.11 0.77 0.20 0.76 0.11 0.76 0.14 0.34 0.16
3270 2.12 34.90 27.88 9.18 Cart. 99% 3.61 2.17 0.77 3.25 0.59 0.15 0.84 0.13 0.99 0.26 0.90 0.12 0.79 0.12 0.30 0.34
8
62.07°N, -40.19°E 31 7.71 35.03 27.34 9.56 x 68% 2.03 0.79 0.53 2.50 0.50 0.13 0.69 0.11 0.86 0.22 0.78 0.11 0.74 0.13 0.18 0.20
16/07/1999 31 7.71 35.03 27.34 9.56 87% 3.23 1.10 0.56 2.61 0.54 0.14 0.74 0.12 0.92 0.25 0.86 0.12 0.78 0.13 0.19 0.31
3225 m 201 5.90 35.02 27.59 8.84 90% 3.74 1.92 0.70 3.00 0.57 0.14 0.77 0.13 0.98 0.27 0.90 0.12 0.78 0.14 0.27 0.35
651 4.02 34.91 27.71 8.89 74% 2.44 1.68 0.65 2.94 0.58 0.15 0.71 0.12 0.91 0.23 0.82 0.11 0.83 0.14 0.31 0.22
901 3.50 34.89 27.75 8.96 91% 4.44 3.07 0.81 3.33 0.54 0.14 0.73 0.13 0.95 0.25 0.86 0.13 0.79 0.14 0.37 0.42
1258 2.68 34.86 27.80 9.34 x 87% 3.99 2.38 0.71 2.91 0.53 0.14 0.79 0.13 0.97 0.25 0.92 0.13 0.83 0.14 0.32 0.36
1258 2.68 34.86 27.80 9.34 38% 1.41 1.43 0.60 3.00 0.65 0.16 0.70 0.11 0.83 0.21 0.75 0.11 0.84 0.14 0.34 0.13
9
62.70°N, -37.59°E 25 9.33 35.01 27.07 9.68 87% 3.32 1.17 0.57 2.68 0.55 0.13 0.72 0.11 0.92 0.24 0.81 0.12 0.75 0.13 0.19 0.33
18/07/1999 25 9.33 35.01 27.07 9.68 Cart. 101% 3.00 1.21 0.64 2.75 0.53 0.14 0.78 0.13 0.92 0.24 0.83 0.12 0.71 0.10 0.20 0.31
2125 m 26 9.32 35.01 27.07 9.70 x 89% 3.25 1.30 0.56 2.57 0.51 0.13 0.68 0.12 0.89 0.24 0.79 0.11 0.76 0.13 0.22 0.32
101 6.48 35.05 27.53 8.79 Cart. 95% 2.32 0.81 0.60 2.71 0.53 0.14 0.79 0.13 0.92 0.24 0.80 0.11 0.65 0.09 0.16 0.26
205 5.60 35.00 27.60 8.88 72% 3.40 1.00 0.57 2.76 0.52 0.14 0.75 0.13 0.91 0.23 0.91 0.12 0.74 0.13 0.16 0.35
205 5.60 35.00 27.60 8.88 Cart. 101% 2.74 1.11 0.63 2.71 0.54 0.14 0.77 0.12 0.90 0.23 0.82 0.11 0.66 0.10 0.20 0.31
601 4.10 34.90 27.70 9.04 89% 3.40 1.12 0.57 2.66 0.52 0.13 0.74 0.13 0.96 0.26 0.85 0.13 0.78 0.14 0.18 0.32
601 4.10 34.90 27.70 9.04 Cart. 95% 2.75 0.97 0.69 2.80 0.57 0.15 0.83 0.13 0.97 0.25 0.88 0.11 0.69 0.10 0.16 0.28
1026 3.41 34.89 27.76 8.99 91% 3.58 1.19 0.59 2.79 0.50 0.14 0.74 0.13 0.96 0.25 0.93 0.13 0.78 0.14 0.19 0.35
1026 3.41 34.89 27.76 8.99 Cart. 91% 2.76 1.18 0.64 2.81 0.54 0.14 0.77 0.13 0.97 0.25 0.86 0.12 0.71 0.11 0.21 0.28
1519 2.88 34.85 27.78 9.47 Cart. 99% 2.99 1.38 0.69 2.83 0.56 0.14 0.83 0.13 0.96 0.26 0.85 0.12 0.67 0.10 0.22 0.32
1801 2.70 34.87 27.81 9.39 Cart. 99% 2.44 1.63 0.70 2.89 0.57 0.15 0.83 0.13 0.97 0.26 0.87 0.12 0.72 0.11 0.28 0.24
2100 1.22 34.85 27.91 9.99 84% 3.48 2.17 0.67 3.35 0.57 0.15 0.78 0.13 0.98 0.25 0.90 0.12 0.79 0.14 0.33 0.33
2100 1.22 34.85 27.91 9.99 Cart. 55% 2.24 2.53 0.69 3.03 0.59 0.16 0.81 0.13 0.92 0.23 0.77 0.10 0.59 0.08 0.46 0.28
10
61.92°N, -36.35°E 5 9.21 34.94 27.04 9.33 x 87% 3.67 1.59 0.63 2.86 0.61 0.00 0.80 0.14 1.08 0.28 0.92 0.13 0.78 0.14 0.24 0.35
19/07/1999 45 6.40 34.98 27.49 9.47 x 84% 3.34 1.47 0.63 2.70 0.52 0.13 0.74 0.13 0.96 0.25 0.86 0.12 0.76 0.13 0.23 0.32
2750 m
12
56.37°N, -27.82°E 20 11.39 35.00 26.70 8.52 Cart. 100% 2.00 1.19 0.57 2.51 0.50 0.13 0.69 0.12 0.82 0.21 0.73 0.09 0.54 0.08 0.26 0.27
22/07/1999 74 9.97 35.07 27.01 8.53 Cart. 97% 2.41 1.18 0.65 2.81 0.56 0.14 0.79 0.13 0.92 0.23 0.82 0.11 0.63 0.09 0.22 0.28
2840 m 250 6.90 34.89 27.35 7.68 88% 3.61 1.09 0.65 2.80 0.56 0.15 0.76 0.13 0.99 0.26 0.86 0.13 0.80 0.14 0.16 0.33
250 6.90 34.89 27.35 7.68 Cart. 97% 2.56 1.23 0.68 2.97 0.57 0.15 0.84 0.14 0.98 0.26 0.87 0.12 0.73 0.11 0.21 0.26
351 6.37 34.91 27.43 7.86 Cart. 100% 2.43 1.20 0.67 2.89 0.57 0.15 0.81 0.13 0.97 0.25 0.84 0.12 0.74 0.11 0.22 0.24
500 5.47 34.94 27.57 7.41 Cart. 95% 2.65 1.02 0.65 2.85 0.58 0.15 0.83 0.14 1.02 0.26 0.90 0.13 0.79 0.12 0.18 0.25
651 4.91 34.97 27.66 7.69 Cart. 99% 2.33 1.00 0.65 2.80 0.53 0.14 0.78 0.12 0.90 0.24 0.81 0.11 0.69 0.10 0.19 0.25
1101 3.65 34.90 27.74 8.68 92% 3.55 1.07 0.59 2.65 0.51 0.14 0.75 0.12 0.96 0.25 0.84 0.12 0.80 0.13 0.17 0.33
1101 3.65 34.90 27.74 8.68 Cart. 99% 2.49 0.96 0.60 2.58 0.51 0.13 0.74 0.12 0.86 0.23 0.79 0.10 0.61 0.09 0.18 0.30
1750 3.07 34.88 27.78 9.21 Cart. 98% 2.39 1.09 0.62 2.66 0.53 0.13 0.75 0.13 0.89 0.24 0.81 0.11 0.66 0.10 0.21 0.27
2020 2.98 34.94 27.84 8.91 91% 3.14 0.99 0.52 2.33 0.47 0.13 0.69 0.12 0.92 0.24 0.82 0.12 0.80 0.14 0.18 0.29
2500 2.66 34.95 27.88 8.85 Cart. 100% 2.72 2.12 0.69 2.88 0.47 0.13 0.71 0.11 0.85 0.22 0.78 0.11 0.66 0.10 0.36 0.31
2828 2.48 34.96 27.90 8.99 Cart. 99% 2.54 1.62 0.63 2.72 0.53 0.15 0.75 0.13 0.92 0.24 0.83 0.11 0.69 0.11 0.30 0.27

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IDENTIFICATION DONNEES HYDROLOGIQUES PARAMETRES DE MESURE CONCENTRATIONS (10 -12 g/g)
Station (nom,
position, date,
profondeur)
Profondeur
(m)
θ (°C) S (PSU) σ θ O2 (mg/L)
Filtration (x
si filtré)
Méthode Rendement La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Ce* La/Yb
13
56.80°N, -30.67°E 25 10.47 35.02 26.88 8.65 90% 3.26 1.19 0.57 2.58 0.49 0.13 0.71 0.12 0.93 0.24 0.81 0.11 0.73 0.12 0.20 0.34
22/07/1999 25 10.47 35.02 26.88 8.65 x 89% 3.33 1.30 0.56 2.45 0.46 0.12 0.67 0.11 0.85 0.22 0.76 0.10 0.64 0.11 0.22 0.38
2430 m 25 10.47 35.02 26.88 8.65 x 87% 4.15 2.91 0.72 3.09 0.54 0.15 0.79 0.13 0.97 0.26 0.96 0.13 0.85 0.15 0.38 0.37
25 10.47 35.02 26.88 8.65 95% 3.20 1.63 0.57 2.69 0.52 0.15 0.72 0.12 0.95 0.24 0.84 0.12 0.80 0.14 0.28 0.30
14
65.02°N, -30.23°E 31 9.55 35.06 27.08 9.14 87% 2.74 0.83 0.46 2.15 0.43 0.11 0.62 0.10 0.80 0.22 0.74 0.10 0.67 0.11 0.17 0.31
27/07/1999 401 6.46 35.09 27.56 8.68 83% 3.21 1.05 0.57 2.59 0.52 0.14 0.74 0.13 0.94 0.25 0.92 0.12 0.80 0.14 0.18 0.31
1875 m 549 5.63 35.02 27.61 8.53 93% 3.26 0.99 0.57 2.62 0.51 0.13 0.70 0.12 0.94 0.25 0.83 0.12 0.78 0.14 0.17 0.31
1229 3.70 34.93 27.77 8.85 90% 3.59 1.37 0.61 2.70 0.54 0.14 0.74 0.12 0.94 0.25 0.87 0.13 0.84 0.14 0.21 0.32
1802 2.91 34.88 27.80 9.35 82% 4.35 2.68 0.74 3.00 0.50 0.14 0.75 0.12 0.96 0.25 0.93 0.13 0.81 0.15 0.34 0.40
1860 2.35 34.89 27.85 9.47 93% 3.52 1.62 0.61 2.71 0.52 0.14 0.72 0.12 0.96 0.24 0.85 0.12 0.79 0.13 0.25 0.33
1860 2.35 34.89 27.85 9.47 x 90% 3.75 1.87 0.67 2.96 0.56 0.15 0.79 0.14 1.01 0.26 0.87 0.12 0.82 0.14 0.27 0.34
15
65.32°N, -30.88°E 20 8.87 35.09 27.21 9.28 74% 3.23 0.97 0.52 2.40 0.44 0.12 0.68 0.11 0.85 0.23 0.78 0.11 0.65 0.12 0.17 0.37
27/07/1999 151 7.21 35.13 27.49 8.73 88% 3.20 0.98 0.54 2.48 0.49 0.13 0.69 0.11 0.90 0.24 0.80 0.12 0.75 0.12 0.17 0.32
993 m 650 5.19 34.99 27.64 8.60 90% 4.17 2.71 0.75 3.40 0.66 0.17 0.91 0.15 1.10 0.28 0.94 0.13 0.88 0.15 0.35 0.35
750 4.49 34.94 27.68 8.77 91% 3.36 0.83 0.58 2.52 0.54 0.13 0.73 0.12 0.93 0.24 0.86 0.12 0.80 0.14 0.14 0.31
800 4.44 34.96 27.71 8.48 91% 3.32 0.98 0.57 2.57 0.52 0.14 0.75 0.13 0.99 0.27 0.89 0.12 0.82 0.15 0.16 0.30
930 2.05 34.89 27.88 9.41 87% 4.07 2.44 0.71 3.10 0.55 0.15 0.77 0.13 0.98 0.25 0.87 0.12 0.79 0.14 0.33 0.38
984 1.36 34.82 27.88 10.08 88% 3.27 1.74 0.58 2.66 0.54 0.15 0.77 0.13 0.99 0.25 0.86 0.12 0.82 0.15 0.29 0.29
984 1.36 34.82 27.88 10.08 x 90% 3.36 1.59 0.59 2.75 0.56 0.15 0.78 0.13 0.98 0.26 0.86 0.13 0.80 0.14 0.26 0.31
16
65.17°N, -30.52°E 50 9.38 35.08 27.12 9.53 84% 3.31 0.97 0.55 2.36 0.47 0.13 0.68 0.12 0.88 0.25 0.84 0.11 0.65 0.12 0.16 0.37
27/07/1999 200 7.05 35.14 27.52 9.13 82% 3.96 1.63 0.68 2.88 0.54 0.14 0.78 0.12 0.97 0.25 0.87 0.12 0.75 0.13 0.23 0.39
1500 m 1002 3.82 34.94 27.76 8.76 Cart. 92% 1.86 0.71 0.54 2.28 0.51 0.13 0.74 0.13 0.89 0.24 0.81 0.10 0.56 0.08 0.16 0.23
1299 0.92 34.77 27.86 10.40 80% 3.73 1.66 0.66 3.01 0.59 0.16 0.82 0.14 1.06 0.27 0.89 0.12 0.80 0.15 0.24 0.35
1399 0.49 34.81 27.93 10.50 82% 3.75 1.55 0.65 2.85 0.56 0.16 0.84 0.13 1.03 0.26 0.92 0.13 0.78 0.15 0.23 0.35
17
67.98°N, -21.78°E 28 4.28 34.18 27.11 10.77 x 83% 3.33 1.39 0.59 2.63 0.51 0.14 0.73 0.13 0.92 0.24 0.83 0.12 0.71 0.12 0.23 0.36
29/07/1999 199 0.01 34.82 27.96 10.87 84% 3.27 1.18 0.57 2.56 0.54 0.14 0.74 0.13 0.95 0.25 0.86 0.12 0.76 0.13 0.20 0.31
861 m 300 0.06 34.85 27.98 10.46 85% 3.17 1.11 0.54 2.47 0.50 0.14 0.73 0.13 0.94 0.25 0.85 0.12 0.75 0.13 0.19 0.31
405 -0.05 34.85 27.99 10.37 Cart. 99% 1.71 0.95 0.47 2.11 0.44 0.12 0.65 0.11 0.79 0.21 0.70 0.09 0.54 0.08 0.24 0.23
405 -0.05 34.85 27.99 10.37 82% 3.15 1.06 0.56 2.46 0.49 0.14 0.75 0.12 0.94 0.25 0.85 0.12 0.77 0.13 0.18 0.30
18
69.07°N, -7.91°E 36 3.75 34.92 27.75 10.63 85% 2.85 0.95 0.43 2.02 0.38 0.11 0.61 0.10 0.81 0.21 0.76 0.11 0.65 0.12 0.19 0.32
01/08/1999 60 2.90 34.95 27.85 10.38 83% 3.33 1.73 0.56 2.39 0.46 0.13 0.69 0.11 0.86 0.23 0.81 0.11 0.72 0.12 0.29 0.34
1020 m 100 2.23 34.92 27.89 10.51 85% 3.18 1.17 0.54 2.42 0.46 0.13 0.72 0.12 0.89 0.23 0.79 0.11 0.71 0.12 0.20 0.33
141 2.33 34.94 27.90 10.64 81% 2.77 1.16 0.51 2.30 0.48 0.13 0.72 0.13 0.95 0.24 0.89 0.12 0.80 0.13 0.22 0.26
640 -0.35 34.88 28.03 9.91 86% 3.21 1.35 0.56 2.59 0.52 0.14 0.71 0.12 0.93 0.25 0.82 0.12 0.78 0.13 0.23 0.32
989 -0.71 34.89 28.05 9.74 83% 4.08 2.41 0.70 3.10 0.60 0.17 0.82 0.15 1.02 0.27 0.91 0.13 0.81 0.14 0.33 0.37
19
69.12°N, -7.50°E 20 6.52 34.76 27.29 10.10 x 81% 3.83 2.63 0.59 2.43 0.46 0.12 0.64 0.10 0.82 0.22 0.79 0.11 0.65 0.12 0.40 0.43
01/08/1999 20 6.52 34.76 27.29 10.10 80% 2.27 0.76 0.36 1.74 0.32 0.10 0.51 0.09 0.73 0.21 0.72 0.10 0.66 0.11 0.19 0.26
2065 m 201 1.58 34.91 27.93 10.55 83% 3.11 1.37 0.52 2.43 0.51 0.14 0.73 0.12 0.97 0.24 0.90 0.12 0.78 0.14 0.25 0.29
275 0.83 34.88 27.96 10.10 83% 3.09 1.16 0.54 2.52 0.52 0.14 0.74 0.12 0.93 0.24 0.88 0.12 0.78 0.13 0.21 0.30
1500 -0.87 34.90 28.07 9.69 85% 3.19 1.19 0.55 2.53 0.50 0.14 0.73 0.12 0.91 0.24 0.84 0.12 0.80 0.14 0.20 0.30
2030 -0.97 34.90 28.07 9.68 88% 3.59 1.89 0.64 2.71 0.52 0.14 0.73 0.13 0.93 0.24 0.86 0.12 0.76 0.14 0.29 0.34

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20
69.21°N, -6.85°E 21 6.84 34.84 27.32 10.16 61% 2.46 0.87 0.38 1.79 0.34 0.10 0.52 0.09 0.73 0.20 0.71 0.10 0.63 0.10 0.20 0.29
02/08/1999 331 0.22 34.86 27.98 10.44 84% 3.62 2.26 0.67 2.87 0.57 0.16 0.82 0.14 0.99 0.26 0.89 0.13 0.80 0.14 0.33 0.34
2502 m 1055 -0.74 34.89 28.06 9.80 83% 3.30 1.17 0.58 2.72 0.53 0.14 0.75 0.12 0.92 0.24 0.83 0.11 0.76 0.13 0.19 0.32
1932 -0.95 34.90 28.07 9.69 84% 3.33 1.31 0.60 2.61 0.56 0.15 0.75 0.13 0.95 0.25 0.87 0.12 0.78 0.14 0.21 0.31
2491 -1.02 34.90 28.07 9.63 77% 2.54 1.17 0.55 2.69 0.52 0.14 0.72 0.13 0.92 0.24 0.83 0.12 0.78 0.14 0.23 0.25
2491 -1.02 34.90 28.07 9.63 x 84% 3.84 2.47 0.68 2.83 0.51 0.13 0.68 0.11 0.87 0.22 0.81 0.12 0.76 0.13 0.35 0.39
21
66.55°N, -10.11°E 20 7.94 34.65 27.00 10.15 63% 2.85 1.18 0.46 2.13 0.45 0.13 0.63 0.11 0.81 0.22 0.75 0.10 0.65 0.11 0.24 0.32
03/08/1999 38 2.51 34.78 27.75 11.35 x 65% 4.24 2.24 0.63 2.73 0.50 0.14 0.77 0.13 0.95 0.25 0.86 0.12 0.73 0.13 0.31 0.43
1450 m 80 -0.02 34.75 27.91 11.79 55% 2.92 1.22 0.49 2.23 0.43 0.12 0.65 0.11 0.87 0.23 0.76 0.11 0.68 0.12 0.23 0.32
101 -0.26 34.75 27.92 11.74 73% 2.68 1.10 0.48 2.25 0.46 0.12 0.68 0.12 0.90 0.24 0.85 0.11 0.75 0.13 0.22 0.27
176 -0.33 34.79 27.95 11.63 64% 3.05 1.22 0.54 2.54 0.49 0.14 0.73 0.12 0.93 0.24 0.84 0.12 0.75 0.13 0.22 0.30
250 0.16 34.87 27.99 10.20 66% 3.09 1.04 0.52 2.45 0.49 0.14 0.72 0.13 0.93 0.25 0.84 0.12 0.73 0.13 0.19 0.31
1000 -0.68 34.89 28.05 9.68 Cart. 98% 2.34 1.01 0.52 2.20 0.48 0.13 0.69 0.12 0.85 0.22 0.75 0.10 0.63 0.10 0.21 0.27
1431 -0.87 34.90 28.07 9.43 66% 3.59 2.06 0.66 2.96 0.62 0.16 0.82 0.13 0.99 0.24 0.84 0.13 0.80 0.14 0.31 0.34
22
62.75°N, -9.01°E 20 10.96 35.24 26.97 9.22 69% 2.44 0.86 0.42 1.83 0.36 0.10 0.56 0.10 0.73 0.21 0.70 0.10 0.60 0.10 0.20 0.30
04/08/1999 50 9.19 35.29 27.32 9.04 66% 3.32 1.10 0.59 2.52 0.51 0.13 0.72 0.12 0.91 0.24 0.80 0.12 0.72 0.12 0.18 0.34
490 m 100 8.51 35.27 27.41 9.09 67% 3.31 1.16 0.58 2.49 0.53 0.14 0.74 0.13 0.93 0.25 0.85 0.13 0.78 0.13 0.19 0.32
200 8.18 35.26 27.45 9.03 Cart. 98% 2.68 1.02 0.58 2.55 0.50 0.13 0.75 0.12 0.88 0.23 0.78 0.10 0.64 0.09 0.19 0.31
350 7.83 35.23 27.48 8.64 65% 3.14 0.89 0.53 2.46 0.50 0.14 0.73 0.12 0.92 0.24 0.83 0.12 0.75 0.13 0.16 0.32
411 7.41 35.21 27.53 8.40 100% 1.95 0.84 0.46 2.01 0.48 0.13 0.75 0.13 0.99 0.25 0.88 0.12 0.75 0.11 0.20 0.19
483 5.71 35.13 27.70 8.82 65% 4.34 3.58 0.90 4.04 0.90 0.25 1.16 0.20 1.37 0.32 1.09 0.15 0.91 0.16 0.42 0.34
23
60.50°N, -5.00°E 51 10.13 35.34 27.20 8.92 70% 3.16 1.22 0.58 2.44 0.50 0.13 0.74 0.12 0.92 0.24 0.81 0.11 0.69 0.12 0.21 0.34
06/08/1999 99 9.20 35.33 27.35 8.93 70% 3.12 1.27 0.57 2.64 0.51 0.14 0.76 0.13 0.95 0.25 0.85 0.12 0.77 0.13 0.22 0.31
1000 m 99 9.20 35.33 27.35 8.93 Cart. 98% 1.75 0.64 0.47 2.06 0.44 0.11 0.60 0.10 0.72 0.19 0.66 0.09 0.50 0.07 0.16 0.26
280 7.72 35.24 27.50 9.16 68% 2.70 1.14 0.50 2.38 0.47 0.13 0.68 0.12 0.89 0.23 0.85 0.11 0.75 0.13 0.23 0.27
446 4.84 35.06 27.74 9.91 70% 3.41 1.94 0.64 2.94 0.60 0.17 0.87 0.14 1.06 0.28 0.96 0.14 0.85 0.15 0.30 0.30
500 2.41 34.92 27.88 10.50 85% 3.12 1.78 0.58 2.76 0.55 0.15 0.77 0.13 0.95 0.24 0.90 0.12 0.82 0.14 0.31 0.30
599 0.33 34.88 27.99 10.37 Cart. 100% 2.68 1.65 0.67 2.89 0.59 0.16 0.85 0.14 0.99 0.26 0.89 0.12 0.72 0.10 0.29 0.27
800 -0.60 34.89 28.05 10.09 70% 3.34 1.60 0.62 2.87 0.56 0.16 0.81 0.14 1.01 0.26 0.90 0.12 0.84 0.15 0.26 0.30
988 -0.77 34.90 28.06 9.97 75% 4.04 2.77 0.82 3.54 0.72 0.21 0.97 0.17 1.16 0.29 0.98 0.13 0.88 0.15 0.35 0.34
24
62.74°N, -4.00°E 20 9.76 35.01 27.00 9.83 66% 2.95 1.03 0.49 2.21 0.45 0.13 0.67 0.11 0.86 0.24 0.83 0.11 0.70 0.12 0.20 0.31
07/08/1999 100 8.14 35.26 27.45 9.14 73% 3.34 1.19 0.57 2.67 0.53 0.14 0.77 0.13 0.96 0.25 0.84 0.12 0.77 0.13 0.20 0.33
1010 m 375 1.77 34.87 27.89 10.68 Cart. 95% 1.39 1.37 0.56 2.57 0.53 0.15 0.81 0.13 0.98 0.25 0.84 0.11 0.64 0.09 0.35 0.16
450 1.02 34.87 27.94 10.50 Cart. 98% 2.58 1.38 0.57 2.44 0.52 0.14 0.78 0.13 0.94 0.24 0.81 0.11 0.63 0.10 0.26 0.29
551 0.18 34.87 27.99 10.30 73% 5.26 4.60 0.94 3.64 0.64 0.17 0.87 0.14 1.06 0.29 0.94 0.13 0.89 0.16 0.47 0.44
950 -0.53 34.89 28.04 10.02 Cart. 96% 2.46 2.23 0.67 2.89 0.63 0.17 0.87 0.14 0.93 0.22 0.74 0.10 0.56 0.08 0.40 0.31
1003 -0.54 34.89 28.04 10.00 72% 4.32 3.27 0.84 3.69 0.79 0.22 1.04 0.17 1.26 0.31 1.05 0.15 0.92 0.16 0.39 0.34
25
64.65°N, 4.18°E 21 12.23 35.04 26.57 9.36 80% 3.22 1.67 0.52 2.24 0.42 0.12 0.64 0.11 0.85 0.24 0.78 0.11 0.67 0.12 0.29 0.35
11/08/1999 101 8.11 35.27 27.47 8.86 55% 5.25 3.55 0.83 3.44 0.61 0.15 0.83 0.14 1.03 0.26 0.88 0.13 0.78 0.14 0.39 0.50
1400 m 360 3.97 34.97 27.77 9.95 70% 6.22 4.62 0.97 3.90 0.67 0.19 0.88 0.15 1.11 0.29 0.97 0.14 0.86 0.15 0.43 0.54
401 2.88 34.92 27.83 10.13 Cart. 100% 2.65 1.63 0.63 2.76 0.57 0.16 0.80 0.13 0.95 0.24 0.82 0.11 0.68 0.10 0.29 0.29
600 -0.24 34.89 28.03 10.12 Cart. 99% 1.84 1.19 0.60 2.52 0.56 0.14 0.79 0.13 0.95 0.25 0.83 0.12 0.65 0.10 0.26 0.20
800 -0.67 34.89 28.05 9.99 Cart. 98% 1.95 1.11 0.57 2.54 0.55 0.14 0.77 0.13 0.92 0.24 0.80 0.11 0.70 0.10 0.24 0.21
1385 -0.96 34.90 28.07 9.74 74% 4.04 2.78 0.78 3.29 0.66 0.19 0.89 0.15 1.07 0.28 0.93 0.14 0.83 0.15 0.36 0.36

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IDENTIFICATION DONNEES HYDROLOGIQUES PARAMETRES DE MESURE CONCENTRATIONS (10 -12 g/g)
Station (nom,
position, date,
profondeur)
Profondeur
(m)
θ (°C) S (PSU) σ θ O2 (mg/L)
Filtration (x
si filtré)
Méthode Rendement La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Ce* La/Yb
26
69.03°N, 7.95°E 20 10.60 35.12 26.94 9.33 Cart. 94% 1.62 0.95 0.39 1.70 0.33 0.09 0.51 0.09 0.64 0.17 0.59 0.08 0.44 0.06 0.28 0.27
14/08/1999 43 8.29 35.19 27.38 9.64 Cart. 95% 1.30 0.72 0.30 1.30 0.26 0.06 0.39 0.07 0.53 0.15 0.58 0.09 0.57 0.09 0.26 0.17
3060 m 74 7.27 35.22 27.55 9.28 80% 4.02 2.77 0.70 2.94 0.59 0.16 0.80 0.12 0.99 0.24 0.86 0.12 0.77 0.14 0.38 0.38
351 4.84 35.10 27.77 9.80 Cart. 94% 2.08 1.50 0.54 2.25 0.44 0.12 0.67 0.11 0.80 0.21 0.72 0.09 0.51 0.08 0.33 0.29
801 0.93 34.89 27.96 10.19 85% 4.39 2.29 0.75 3.16 0.64 0.18 0.92 0.15 1.12 0.28 1.00 0.14 0.88 0.15 0.29 0.36
1001 -0.21 34.88 28.02 10.07 Cart. 97% 1.16 0.97 0.50 2.32 0.49 0.13 0.74 0.12 0.89 0.23 0.76 0.09 0.58 0.08 0.28 0.15
1700 -0.82 34.90 28.07 9.75 Cart. 99% 2.06 1.04 0.60 2.49 0.55 0.15 0.79 0.13 0.96 0.25 0.88 0.12 0.70 0.11 0.21 0.21
2972 -1.01 34.90 28.08 9.79 85% 6.28 4.76 0.96 3.93 0.68 0.17 0.88 0.15 1.03 0.28 0.91 0.14 0.88 0.15 0.44 0.54
28
77.55°N, 10.60°E 6 6.89 35.07 27.49 9.72 88% 2.89 1.30 0.49 2.33 0.46 0.12 0.68 0.12 0.88 0.23 0.79 0.11 0.71 0.12 0.25 0.31
21/08/1999 25 6.87 35.07 27.49 9.83 x 87% 4.51 2.63 0.99 4.03 0.98 0.24 1.17 0.21 1.55 0.40 1.33 0.19 1.09 0.18 0.29 0.31
1075 m 504 2.09 34.98 27.95 10.12 90% 3.59 2.00 0.65 2.91 0.63 0.17 0.84 0.14 1.02 0.27 0.93 0.13 0.79 0.14 0.30 0.33
29
77.67°N, 7.69°E 2 4.86 26.61 21.05 7.36 89% 2.72 1.03 0.46 2.08 0.42 0.11 0.63 0.11 0.83 0.22 0.79 0.11 0.65 0.12 0.21 0.31
22/08/1999 2 4.86 26.61 21.05 7.36 x 89% 2.81 1.29 0.50 2.19 0.42 0.11 0.64 0.11 0.83 0.22 0.76 0.11 0.64 0.11 0.25 0.32
3320 m 2 4.86 26.61 21.05 7.36 x 90% 3.05 1.81 0.54 2.53 0.53 0.15 0.75 0.13 0.89 0.23 0.82 0.11 0.67 0.12 0.32 0.33
50 4.88 35.08 27.76 10.01 88% 3.12 1.49 0.54 2.42 0.50 0.13 0.72 0.12 0.95 0.24 0.86 0.12 0.76 0.14 0.26 0.30
50 4.88 35.08 27.76 10.01 x 74% 2.92 1.37 0.52 2.31 0.49 0.13 0.72 0.12 0.92 0.25 0.91 0.12 0.79 0.14 0.25 0.27
92 4.16 35.06 27.82 10.04 77% 2.88 1.07 0.49 2.32 0.46 0.13 0.70 0.13 0.92 0.25 0.91 0.12 0.74 0.13 0.20 0.29
248 3.40 35.03 27.87 9.98 89% 3.28 1.32 0.56 2.50 0.53 0.14 0.77 0.13 0.98 0.26 0.88 0.12 0.79 0.14 0.22 0.30
604 0.37 34.88 27.99 10.63 91% 3.16 1.33 0.57 2.44 0.54 0.15 0.78 0.13 0.98 0.26 0.90 0.12 0.76 0.14 0.23 0.30
1513 -0.85 34.90 28.07 9.75 92% 3.03 0.89 0.53 2.41 0.51 0.14 0.74 0.13 0.94 0.25 0.83 0.12 0.78 0.14 0.16 0.29
2423 -1.00 34.90 28.08 9.80 Cart. 103% 1.60 1.18 0.57 2.69 0.57 0.15 0.78 0.13 0.93 0.25 0.85 0.12 0.73 0.11 0.28 0.16
3360* -0.99 34.91 28.08 9.88 x 92% 3.33 1.52 0.61 2.62 0.47 0.13 0.70 0.11 0.88 0.24 0.81 0.12 0.77 0.14 0.24 0.32
3360* -0.99 34.91 28.08 9.88 90% 3.27 1.47 0.60 2.73 0.57 0.15 0.79 0.13 0.96 0.26 0.87 0.13 0.80 0.14 0.24 0.30
30
76.74°N, -2.33°E 5 4.60 34.68 27.47 8.90 x 85% 2.61 1.11 0.48 2.20 0.47 0.12 0.65 0.11 0.83 0.23 0.77 0.11 0.67 0.11 0.23 0.29
22/08/1999 5 4.60 34.68 27.47 8.90 85% 3.30 1.30 0.57 2.52 0.51 0.14 0.76 0.13 0.97 0.25 0.86 0.13 0.78 0.13 0.22 0.31
2560 m 21 4.56 34.72 27.50 7.51 x 75% 2.43 0.89 0.48 2.28 0.47 0.13 0.66 0.12 0.89 0.23 0.83 0.11 0.69 0.11 0.19 0.26
103 2.21 34.97 27.93 10.30 88% 3.24 1.35 0.55 2.56 0.55 0.15 0.78 0.13 0.98 0.25 0.87 0.13 0.79 0.14 0.23 0.30
505 0.00 34.89 28.02 10.64 92% 3.03 1.04 0.52 2.44 0.48 0.14 0.76 0.13 0.94 0.26 0.86 0.12 0.77 0.14 0.19 0.29
1314 -0.67 34.91 28.07 9.73 88% 3.20 0.92 0.55 2.49 0.55 0.15 0.76 0.12 0.97 0.26 0.87 0.12 0.78 0.14 0.16 0.30
2512 -1.06 34.90 28.08 9.94 x 83% 3.06 1.89 0.58 2.58 0.57 0.14 0.69 0.11 0.88 0.22 0.81 0.11 0.72 0.13 0.33 0.32
2512 -1.06 34.90 28.08 9.94 92% 3.56 1.52 0.63 2.83 0.57 0.16 0.80 0.14 1.00 0.26 0.90 0.13 0.80 0.14 0.23 0.33
32
77.03°N, -3.75°E 5 0.52 31.35 25.14 12.28 58% 4.25 2.27 0.79 3.71 0.80 0.21 1.15 0.18 1.41 0.36 1.21 0.17 1.19 0.21 0.28 0.27
23/08/1999 21 -1.25 33.24 26.74 12.23 79% 3.98 1.45 0.70 3.39 0.75 0.21 1.07 0.18 1.42 0.36 1.23 0.17 1.18 0.20 0.20 0.25
1895 m 123 3.12 34.89 27.79 9.48 55% 3.54 1.74 0.63 2.82 0.58 0.15 0.85 0.14 1.06 0.28 0.93 0.13 0.81 0.14 0.27 0.32
208 2.60 34.96 27.89 9.95 56% 3.19 1.53 0.58 2.64 0.56 0.15 0.79 0.13 1.00 0.26 0.88 0.12 0.79 0.14 0.26 0.30
208 2.60 34.96 27.89 9.95 84% 3.47 2.57 0.66 3.03 0.62 0.16 0.82 0.14 1.03 0.25 0.92 0.12 0.82 0.14 0.39 0.32
482 1.33 34.92 27.96 10.02 57% 3.02 1.24 0.55 2.49 0.51 0.16 0.80 0.13 1.01 0.26 0.90 0.14 0.82 0.14 0.22 0.27
608 0.61 34.88 27.98 9.78 53% 3.05 1.17 0.55 2.46 0.55 0.15 0.77 0.13 1.01 0.26 0.89 0.12 0.82 0.14 0.21 0.28
1423 -0.57 34.91 28.06 9.80 89% 3.20 1.61 0.57 2.64 0.54 0.15 0.77 0.13 0.94 0.25 0.85 0.12 0.81 0.14 0.27 0.30

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33
77.18°N, -4.39°E 20 -0.69 33.16 26.65 13.37 57% 4.29 1.46 0.81 3.57 0.76 0.22 1.16 0.20 1.52 0.39 1.31 0.19 1.20 0.22 0.18 0.26
23/08/1999 50 -0.69 33.16 26.65 13.37 62% 4.06 1.77 0.72 3.36 0.71 0.19 1.04 0.18 1.28 0.33 1.11 0.16 1.04 0.19 0.24 0.29
1575 m 149 2.60 34.86 27.81 9.61 52% 2.62 1.67 0.58 2.71 0.56 0.15 0.77 0.13 1.02 0.26 0.86 0.13 0.82 0.13 0.31 0.24
351 2.14 34.97 27.94 10.08 59% 3.28 1.58 0.61 2.71 0.57 0.15 0.81 0.14 1.02 0.26 0.90 0.12 0.77 0.14 0.26 0.31
38
73.96°N, -13.86°E 115 2.78 35.00 27.90 10.28 57% 4.44 3.83 0.83 3.28 0.60 0.16 0.84 0.14 1.05 0.27 0.92 0.13 0.82 0.14 0.46 0.39
24/08/1999
2321 m
39
74.01°N, -14.18°E 280 2.00 34.97 27.95 10.10 x 63% 7.35 9.31 1.37 4.85 0.54 0.15 0.84 0.14 0.94 0.25 0.85 0.12 0.76 0.14 0.67 0.72
24/08/1999
1995 m
40
74.06°N, -14.48°E 290 2.02 34.97 27.95 10.04 54% 2.36 2.00 0.61 2.77 0.55 0.15 0.76 0.13 0.96 0.25 0.87 0.12 0.79 0.14 0.38 0.22
24/08/1999
1500 m
41
74.11°N, -14.70°E 293 2.08 34.97 27.94 10.19 x 59% 5.26 5.98 1.00 3.68 0.52 0.13 0.73 0.12 0.89 0.23 0.84 0.12 0.71 0.14 0.60 0.54
24/08/1999
985 m
42
72.91°N, -12.97°E 4 5.29 34.28 27.07 10.11 x 61% 6.45 6.58 1.21 4.63 0.63 0.17 0.94 0.14 1.10 0.28 0.95 0.13 0.80 0.14 0.54 0.60
25/08/1999 35 0.88 34.66 27.78 12.15 x 62% 2.94 0.99 0.55 2.38 0.51 0.13 0.68 0.10 0.83 0.22 0.79 0.11 0.62 0.10 0.18 0.36
2690 m 81 1.36 34.92 27.96 10.25 61% 3.14 1.65 0.57 2.65 0.57 0.15 0.82 0.14 1.04 0.27 0.90 0.13 0.82 0.14 0.28 0.28
707 -0.53 34.88 28.04 10.40 65% 2.95 1.00 0.53 2.36 0.51 0.13 0.76 0.13 0.96 0.25 0.91 0.13 0.78 0.13 0.18 0.28
1517 -0.80 34.91 28.07 9.71 66% 3.47 1.60 0.63 2.78 0.61 0.14 0.78 0.14 0.99 0.26 0.89 0.13 0.78 0.14 0.25 0.32
2023 -0.97 34.91 28.08 9.78 87% 2.85 0.99 0.51 2.40 0.51 0.14 0.71 0.13 0.90 0.24 0.89 0.12 0.80 0.14 0.19 0.26
2635 -1.12 34.90 28.08 10.00 x 69% 3.99 1.74 0.76 3.15 0.67 0.17 0.90 0.14 1.04 0.25 0.91 0.12 0.76 0.14 0.23 0.38
45
72.91°N, -15.85°E 5 3.70 33.33 26.48 10.58 x 79% 3.94 2.93 0.73 3.03 0.51 0.14 0.76 0.13 1.00 0.26 0.95 0.13 0.82 0.13 0.40 0.36
25/08/1999 21 5.11 34.34 27.14 10.31 83% 2.98 1.17 0.53 2.52 0.49 0.13 0.72 0.12 0.92 0.24 0.86 0.11 0.75 0.12 0.21 0.30
2000 m 36 2.45 34.68 27.68 11.32 78% 2.88 1.09 0.50 2.34 0.50 0.13 0.73 0.12 0.94 0.25 0.84 0.12 0.76 0.13 0.21 0.28
102 1.52 34.93 27.95 10.03 78% 2.87 1.23 0.50 2.44 0.51 0.14 0.76 0.13 0.94 0.25 0.87 0.12 0.78 0.13 0.23 0.28
353 0.29 34.91 28.02 10.32 77% 3.15 1.18 0.58 2.60 0.55 0.14 0.79 0.13 1.01 0.26 0.91 0.13 0.80 0.14 0.20 0.29
754 -0.46 34.89 28.04 9.98 78% 3.16 1.72 0.59 2.63 0.49 0.14 0.73 0.12 0.95 0.25 0.87 0.13 0.79 0.14 0.29 0.30
1521 -0.84 34.91 28.08 9.68 74% 3.05 2.20 0.71 3.11 0.60 0.15 0.79 0.13 0.99 0.26 0.86 0.13 0.81 0.14 0.35 0.28
1944 -1.03 34.91 28.08 9.78 x 64% 4.01 3.76 0.70 2.82 0.48 0.12 0.67 0.11 0.89 0.23 0.83 0.11 0.81 0.14 0.51 0.37
46
72.87°N, -16.18°E 25 2.39 33.81 26.99 11.97 79% 3.93 1.78 0.69 3.08 0.62 0.17 0.96 0.16 1.23 0.32 1.11 0.15 0.99 0.18 0.25 0.29
26/08/1999 50 -1.00 34.33 27.61 11.64 83% 3.63 3.58 0.71 3.22 0.66 0.17 0.96 0.16 1.19 0.30 1.04 0.15 0.93 0.16 0.51 0.29
1520 m 134 2.58 34.96 27.89 10.23 81% 3.53 2.12 0.64 2.79 0.79 0.15 0.81 0.14 1.02 0.27 0.92 0.13 0.83 0.14 0.32 0.31
221 1.92 34.96 27.94 10.27 78% 3.29 1.65 0.59 2.70 0.56 0.15 0.78 0.13 1.00 0.26 0.90 0.12 0.81 0.14 0.27 0.30
400 0.92 34.91 27.98 9.98 83% 2.89 1.01 0.53 2.42 0.51 0.14 0.76 0.13 0.98 0.25 0.90 0.13 0.81 0.14 0.19 0.26
701 0.07 34.90 28.02 10.54 78% 6.00 5.82 1.07 3.95 0.60 0.16 0.87 0.14 1.02 0.27 0.92 0.14 0.81 0.14 0.53 0.55
900 -0.46 34.89 28.04 10.05 82% 2.87 1.44 0.52 2.41 0.49 0.13 0.72 0.13 0.94 0.25 0.86 0.12 0.79 0.14 0.27 0.27

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IDENTIFICATION DONNEES HYDROLOGIQUES PARAMETRES DE MESURE CONCENTRATIONS (10 -12 g/g)
Station (nom,
position, date,
profondeur)
Profondeur
(m)
θ (°C) S (PSU) σ θ O2 (mg/L)
Filtration (x
si filtré)
Méthode Rendement La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Ce* La/Yb
48
70.00°N, -17.01°E 10 5.90 34.50 27.17 10.10 x 77% 2.52 0.88 0.45 2.03 0.44 0.11 0.61 0.79 0.81 0.22 0.78 0.10 0.61 0.11 0.19 0.30
26/08/1999 98 -0.09 34.83 27.97 11.52 77% 3.02 1.17 0.52 2.40 0.51 0.14 0.75 0.13 0.95 0.25 0.88 0.12 0.78 0.14 0.21 0.28
1280 m 200 -0.34 34.83 27.99 11.40 72% 3.32 1.54 0.58 2.62 0.49 0.14 0.75 0.12 0.95 0.25 0.91 0.11 0.74 0.13 0.25 0.33
431 -0.04 34.88 28.01 10.41 80% 2.97 1.10 0.53 2.38 0.49 0.14 0.74 0.12 0.94 0.25 0.88 0.12 0.78 0.14 0.20 0.28
698 -0.42 34.89 28.04 10.09 84% 2.94 1.13 0.53 2.39 0.50 0.14 0.76 0.13 0.93 0.25 0.85 0.12 0.77 0.13 0.21 0.28
1001 -0.65 34.90 28.06 9.88 69% 2.65 0.98 0.49 2.37 0.53 0.14 0.71 0.14 0.92 0.23 0.89 0.12 0.83 0.14 0.20 0.24
1232 -0.70 34.90 28.06 9.84 x 80% 3.58 2.45 0.66 2.69 0.52 0.13 0.72 0.12 0.90 0.24 0.84 0.12 0.76 0.14 0.37 0.35
50
70.00°N, -18.00°E 10 5.76 33.26 26.21 10.17 77% 3.39 1.27 0.60 2.69 0.56 0.15 0.81 0.14 1.04 0.26 0.89 0.13 0.81 0.14 0.20 0.31
27/08/1999 101 0.62 34.71 27.84 10.71 79% 2.98 1.22 0.52 2.55 0.51 0.15 0.76 0.13 0.97 0.25 0.88 0.12 0.80 0.14 0.22 0.28
1655 m 174 0.76 34.83 27.93 10.52 72% 2.89 1.09 0.51 2.46 0.54 0.13 0.72 0.87 0.89 0.24 0.88 0.13 0.74 0.13 0.21 0.29
404 0.15 34.90 28.01 10.39 82% 3.04 1.27 0.54 2.43 0.50 0.14 0.75 0.13 0.96 0.26 0.88 0.12 0.81 0.15 0.23 0.28
573 -0.35 34.89 28.04 10.21 68% 2.98 0.92 0.50 2.41 0.52 0.13 0.74 0.96 0.98 0.25 0.93 0.11 0.79 0.14 0.17 0.27
1007 -0.67 34.90 28.06 9.89 83% 3.08 1.28 0.54 2.49 0.52 0.15 0.74 0.12 1.00 0.26 0.89 0.13 0.83 0.15 0.23 0.28
1596 -0.91 34.91 28.08 9.76 82% 4.65 4.34 0.93 3.75 0.88 0.20 0.99 0.15 1.11 0.28 0.94 0.13 0.86 0.16 0.48 0.40
52
68.21°N, -29.63°E 6 2.32 30.53 24.37 11.31 81% 13.28 17.76 3.14 13.52 2.87 0.81 3.40 0.53 3.48 0.78 2.42 0.32 2.11 0.34 0.63 0.46
28/08/1999 80 -1.35 33.13 26.65 11.97 84% 13.96 21.29 3.37 14.64 3.03 0.87 3.42 0.54 3.48 0.75 2.36 0.32 2.01 0.34 0.72 0.52
375 m 251 1.02 34.56 27.69 10.46 58% 6.00 7.81 1.43 6.78 1.58 0.41 1.79 1.80 1.84 0.43 1.39 0.18 1.14 0.18 0.61 0.39
303 0.20 34.57 27.74 10.54 83% 10.03 17.30 2.69 11.91 2.71 0.78 3.01 0.46 2.97 0.63 1.88 0.26 1.60 0.26 0.77 0.46
53
68.20°N, -29.63°E 183 3.31 34.52 27.47 10.15 76% 4.26 2.56 0.80 3.62 0.79 0.19 1.00 1.18 1.20 0.31 1.07 0.15 0.91 0.16 0.32 0.35
28/08/1999 200 4.31 34.77 27.57 9.68 79% 3.72 1.67 0.69 3.04 0.66 0.17 0.91 0.15 1.14 0.30 0.99 0.14 0.87 0.17 0.24 0.31
450 m
54
66.16°N, -27.52°E 5 3.81 31.40 24.94 11.02 67% 4.94 4.12 1.26 5.98 1.24 0.34 1.59 0.26 1.87 0.45 1.57 0.22 1.53 0.26 0.38 0.24
29/08/1999 59 -1.47 33.65 27.07 11.59 73% 25.72 34.78 4.71 14.70 0.81 0.22 1.61 1.40 1.43 0.35 1.24 0.17 1.08 0.19 0.72 1.76
500 m 352 0.16 34.83 27.96 10.55 82% 4.27 4.44 0.84 3.52 0.73 0.19 0.96 0.15 1.15 0.29 0.97 0.14 0.86 0.16 0.54 0.37
442 -0.03 34.87 28.01 10.29 73% 3.23 1.84 0.61 2.82 0.59 0.16 0.80 0.15 1.00 0.25 0.91 0.12 0.79 0.14 0.30 0.30
479 -0.04 34.87 28.01 10.18 80% 4.08 3.16 0.77 3.33 0.63 0.17 0.87 0.15 1.09 0.27 0.94 0.13 0.84 0.15 0.41 0.36
55
66.08°N, -27.25°E 11 5.71 33.45 26.36 10.47 74% 4.14 2.41 0.88 4.04 0.84 0.22 1.14 0.19 1.36 0.35 1.17 0.17 1.09 0.18 0.29 0.28
29/08/1999 51 2.62 34.39 27.43 10.76 70% 10.38 8.78 1.74 5.91 0.66 0.18 1.00 1.13 1.16 0.30 1.04 0.14 0.90 0.15 0.47 0.83
625 m 97 6.80 35.13 27.55 8.86 70% 3.50 1.31 0.61 2.71 0.62 0.15 0.79 0.97 0.99 0.25 0.91 0.12 0.78 0.13 0.20 0.33
550 -0.12 34.88 28.02 10.24 60% 2.96 1.07 0.53 2.38 0.54 0.15 0.71 0.94 0.96 0.25 0.89 0.11 0.79 0.13 0.20 0.28
610 -0.12 34.88 28.02 10.20 67% 2.96 1.15 0.53 2.47 0.51 0.14 0.72 0.13 0.93 0.24 0.85 0.11 0.75 0.13 0.21 0.29
56
66.01°N, -26.98°E 10 5.16 32.52 25.70 10.79 70% 4.00 2.74 0.95 4.33 0.90 0.25 1.25 0.20 1.50 0.38 1.26 0.17 1.21 0.20 0.32 0.24
29/08/1999 54 -0.46 33.30 26.75 12.40 67% 5.34 3.00 1.01 4.56 0.95 0.24 1.32 1.63 1.66 0.42 1.42 0.20 1.22 0.22 0.30 0.32
560 m 120 3.58 34.40 27.35 10.40 43% 1.37 1.02 0.59 3.02 0.70 0.17 0.82 0.13 1.02 0.25 0.89 0.13 0.92 0.15 0.25 0.11
182 6.29 35.06 27.56 9.20 72% 3.47 1.38 0.60 2.80 0.56 0.14 0.80 0.97 0.99 0.26 0.89 0.12 0.78 0.13 0.22 0.33
302 4.45 34.91 27.66 9.27 73% 3.53 1.61 0.62 2.88 0.63 0.16 0.85 1.03 1.05 0.27 0.98 0.13 0.88 0.14 0.25 0.30
345 -0.25 34.53 27.74 10.77 34% 1.31 1.02 0.57 2.99 0.76 0.18 0.83 0.14 1.00 0.25 0.90 0.14 0.93 0.17 0.26 0.10
544+502 (523) -0.51 34.90 28.05 9.99 67% 4.55 4.13 0.93 4.12 0.91 0.22 1.06 1.18 1.21 0.30 1.00 0.14 0.89 0.15 0.46 0.38

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57
61.99°N, -23.97°E 21 11.48 35.12 26.78 8.52 70% 3.08 3.13 0.74 3.32 0.67 0.16 0.82 0.14 0.96 0.23 0.81 0.12 0.65 0.12 0.48 0.36
29/08/1999 403 8.00 35.23 27.46 8.61 67% 3.25 1.03 0.59 2.63 0.51 0.14 0.75 0.90 0.97 0.24 0.91 0.12 0.78 0.13 0.17 0.30
1500 m 1475 3.39 34.99 27.84 9.25 x 57% 3.38 1.72 0.58 2.57 0.46 0.12 0.72 0.14 0.92 0.24 0.88 0.12 0.77 0.13 0.28 0.33
Fjord Trodheim
63.62°N, 9.32°E ~ 7 ~ 12.4 ~ 31.9 - - 104% 6.81 11.99 3.01 12.51 2.41 0.51 2.74 0.43 2.79 0.65 2.07 0.29 1.79 0.27 0.58 0.28
13/8/99 ~ 7 ~ 12.4 ~ 31.9 - - x 99% 7.39 11.94 2.98 12.37 2.40 0.49 2.74 0.43 2.70 0.63 2.05 0.28 1.76 0.26 0.57 0.31
Fjord Bergen
60.87°N, 4.67°E ~ 7 - ~ 31.9 - - 98% 12.25 11.96 2.59 8.64 1.42 0.28 1.66 0.25 1.60 0.39 1.29 0.18 1.12 0.17 0.49 0.81
11/8/99 ~ 7 - ~ 31.9 - - x 98% 11.37 12.40 2.53 8.94 1.45 0.28 1.70 0.25 1.61 0.39 1.27 0.18 1.12 0.17 0.53 0.75
Fjord Spitzberg
67.82°N, 15.27°E ~ 7 ~ 3.7 ~ 31.9 - - 96% 13.51 25.26 4.58 21.95 5.68 1.49 6.92 1.00 5.59 1.08 2.88 0.32 1.69 0.23 0.73 0.58
21/8/99 ~ 7 ~ 3.7 ~ 31.9 - - x 99% 6.02 9.31 2.17 10.64 2.65 0.74 3.64 0.55 3.26 0.68 1.83 0.21 1.08 0.15 0.58 0.40
~ 7 ~ 3.7 ~ 31.9 - - x 83% 9.74 11.46 2.50 12.75 3.07 0.84 4.06 0.61 3.88 0.82 2.37 0.29 1.58 0.26 0.53 0.46
Fjord Nansen
68.21°N, -29.66°E ~ 7 ~ 2.1 ~ 30.6 - - 97% 12.31 19.11 3.21 14.54 3.35 0.90 3.99 0.61 3.76 0.82 2.41 0.33 2.16 0.34 0.70 0.43
28/8/99 ~ 7 ~ 2.1 ~ 30.6 - - 92% 13.01 20.37 3.42 15.61 3.51 0.95 4.14 0.63 3.90 0.84 2.52 0.35 2.26 0.35 0.70 0.43
~ 7 ~ 2.1 ~ 30.6 - - x 79% 6.98 5.82 1.29 5.74 1.17 0.33 1.60 0.26 1.93 0.47 1.59 0.24 1.50 0.26 0.44 0.35
Sédiment de
surface, station 43,
carotte MD99-
2308Hy
Sédiment de
surface, station 38,
carotte MD99-
2307Hy
Sable de plage
Spitzberg
ECHANTILLONS SOLIDES (concentrations en 10 -6 g/g)
2520 - - - - 98% 30.59 64.79 7.29 26.99 5.03 1.11 4.50 0.64 3.52 0.70 2.07 0.30 1.97 0.29 1.00 1.14
2321 - - - - 98% 25.04 54.26 6.30 24.37 4.54 1.04 3.93 0.58 3.22 0.63 1.90 0.27 1.85 0.26 1.00 1.02
0 - - - - 99% 3.14 8.16 1.11 4.34 1.00 0.25 0.97 0.18 1.15 0.25 0.86 0.13 0.87 0.13 0.99 0.26

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DENMARK STRAIT WATER HETEROGENEITY: CIRCULATION
TRACED BY NEODYMIUM ISOTOPES AND RARE EARTH
ELEMENTS
Francois Lacan ∗ and Catherine Jeandel
LEGOS, Observatoire Midi-Pyrénées, 18 av Edouard Belin, 31401 Toulouse Cedex 4, France
ABSTRACT
Seawater Neodymium isotopic composition and Rare Earth Elements concentrations
were measured along four hydrologic sections within the East Greenland Current, between the
Fram and the Denmark Straits, during summer 1999. East Greenland Current intermediate
waters, between 77°N and 70°N, displaying similar hydrological characteristics as Denmark
Strait Overflow Water, have very constant REE characteristics and ε Nd value of –11.2. This
constancy reveals the absence of lithogenic input, from the East Greenland margin, into
intermediate waters in this area, corroborating previous dissolved aluminum data (Measures
and Edmond, 1992). The Denmark Strait Overflow Water was characterized by ε Nd = -8.7 ±
1.4. This value (which is in very good agreement with one previous data; Piepgras and
Wasserburg, 1987) can be explained by the imprint of basaltic formations bordering the
Denmark Strait on the intermediate waters described above. The heterogeneity of the DSOW
Nd signature revealed the resuspension of Precambrian particles in the Strait. The presence of
Atlantic Water is observed at a station located at the mouth of Nansen Fjord, on the western
side of Denmark Strait. We suggest that this water reaches the fjord from the Irminger current
within eddy structures. These results provide a better understanding of the DSOW Nd
signature, which will allow a better use of this tracer in the study of modern and paleo North
Atlantic Deep Water dynamic.
Keywords: Denmark Strait, circulation, neodymium, water masses, weathering, isotopic
tracer.
1. Introduction
Neodymium (Nd) is a Rare Earth Element (REE). It mainly occurs at the earth surface
in the solid phase. Its Isotopic Composition (Nd IC) is the 143 Nd/ 144 Nd ratio, expressed as ε Nd ,
which is the deviation of this ratio in the sample from a reference value (CHUR, Chondritic
Uniform Reservoir, 143 Nd/ 144 Nd = 0.512638, which represents the present day average earth
value):
143
⎛ ⎛ Nd ⎞ ⎞
⎜ ⎜ ⎟ ⎟
144
⎜ ⎝ Nd⎠
measured ⎟ 4
ε Nd
= ⎜
− 1
⎛ Nd ⎞
⎟ × 10
143
⎜ ⎜ ⎟
144
⎝ ⎝ Nd⎠
⎟
⎠
CHUR
∗
Corresponding author. Fax: +33 5.61.25.32.05. Phone: +33 5.61.33.30.03. Email address:
francois.Lacan@cnes.fr
1

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The Nd IC of a rock depends both on its age and samarium to neodymium ratio. ε Nd
ranges from –40 in old continental formations (e.g.: Greenland; Taylor et al., 1992) to +10 in
new volcanic formations (e.g.: Iceland; O'nions and Grönvold, 1973). The Nd found in the
ocean is of terrigeneous origin. It is brought to the ocean in dissolved or particulate phases, by
rivers, the atmosphere or remobilization from margin sediments. Within the ocean, most of
the Nd is found in the dissolved phase, the particulate phase represents only 5 to 10% of the
total content (Jeandel et al., 1995). Although input processes are still not completely
understood, it seems that dissolved/particulate exchanges at the margins play a preponderant
role (Jeandel et al., 1998; Lacan and Jeandel, 2001; Tachikawa et al., 2002). In the vicinity of
lithogenic sources, ε Nd is thus used as a tracer of particle transport and dissolved particulate
exchanges (Grousset et al., 1988; Jeandel et al., 1995; Tachikawa et al., 1999b). Away from
them, it is conservative and used as a tracer of water masses (Piepgras and Wasserburg, 1987;
Piepgras and Jacobsen, 1988; Jeandel, 1993; Jeandel et al., 1998; Lacan and Jeandel, 2001).
Nd residence time in the ocean is around 500 to 1000 years (Tachikawa et al., 1999a). That
makes ε Nd suitable to trace intra and inter ocean currents.
ε Nd is widely used in paleo-oceanography. Signal variations stored in sediments (mostly
metalliferous), are classically interpreted as reflecting past variations in circulation. Recently,
several studies have suggested that fluctuations in the Nd sources, via variations in erosion
rates, could also affect ε Nd records (Vance and Burton, 1999; Frank et al., 2001; Tachikawa et
al., 2002).
The past Nd IC of the North Atlantic Deep Water (NADW) has been particularly well
studied (Burton et al., 1997; Abouchami et al., 1999; Vance and Burton, 1999; Rutberg et al.,
2000). The production of this water mass initiates the conveyor belt circulation, and thus is a
key factor controlling our climate (Broecker, 1991). NADW is formed out of four sources:
Denmark Strait Overflow Water (DSOW), Island Scotland Overflow Water (ISOW),
Labrador Sea Water (LSW) and Lower Deep Water (LDW, derived from Antarctic Bottom
Water, AABW). Those are formed by convection in high latitudes: the DSOW and the ISOW
in the Nordic Seas (Greenland, Island and Norwegian Seas), the LSW in the Labrador Sea and
the AABW around the Antarctic continent (Dickson and Brown, 1994). The few data
available before this work show that the Nd ICs of these sources are very distinct: ε Nd ≈ -8 in
the Nordic Seas overflow waters, ε Nd ≈ -14.7 in the LSW and ε Nd ≈ -11.7 in the AABW
(Piepgras and Wasserburg, 1987). ε Nd variations in the past or present NADW could thus be
used to evaluate the relative contribution of each of its source waters and to draw conclusions
about fluctuations in the conveyor belt activity, if it can be ascertained that the end-member
values are constant.
To further develop this potential application of ε Nd , we need to better understand how
these waters acquire their signature. So far, only three Nd IC measurements were available for
the Nordic Seas, which is insufficient to constrain the signature of the DSOW and ISOW. One
of the goals of the Signature/GINS cruise (IFRTP) was to further address these questions. The
cruise has been carried out on board the R/V Marion Dufresne, in July and August 1999, in
the North Atlantic and more particularly in the Greenland and Iceland Seas. Hydrological
parameters (θ, S, O 2 and Acoustic Doppler Currents) and chemical tracers: CFC, SF6, 129 I,
REE and Nd IC have been measured. In this paper, we present Nd ICs and REE
concentrations of seawater samples from the East Greenland Current (EGC), along the east
Greenland slope, between the Fram and Denmark straits. We use these results to explain the
ε Nd signature of the DSOW and to better constrain the circulation in the Denmark Strait.
2

)¡ *
2. Hydrological context, sampling, analytical procedures
The Nordic Seas refer to the seas lying between Greenland and Norway: the Norwegian,
the Greenland and the Iceland Seas (Fig. 1). Their deep openings with the oceans are the Fram
Strait in the north, the Denmark Strait in the southwest and the Faroe Shetland Channel in the
southeast. Their main hydrological structures are: 1) an eastern boundary current, the
Norwegian Atlantic Current followed by the West Spitsbergen Current, bringing warm and
saline Atlantic Water to the north, 2) a western boundary current, the East Greenland Current
(EGC), carrying waters from the Fram Strait, through the Greenland and Iceland Seas,
towards the Denmark Strait, 3) three cyclonic gyres in the Greenland, Iceland and Norwegian
Seas (Fig. 1; Poulain and Warn-Varnas, 1996; Hansen and Østerhus, 2000).
Figure 1.
Studied area. The large black arrows represent the main hydrodynamic structures: the
East Greenland Current, the Greenland Sea and Iceland Sea gyres. Hydrological sections are
indicated by black white-edged segments. The dashed lines bordering the coasts indicate their
geological type. The white black-striped lines indicate Precambrian formations (ε Nd around –
35), whereas the black white-striped ones indicate basaltic ones (ε Nd around +8). Note the
basaltic nature of the formations bordering the Denmark Strait.
The East Greenland Current flows parallel to the isobaths. It extends from the
continental shelf beyond the bottom of the slope, around 3000 m depth. Its annual mean
transport is 21 ± 3 Sv (1 Sv = 10 6 m 3 .s -1 ; Woodgate et al., 1999). It carries waters of different
origins, some come from the Arctic Ocean, some from the Atlantic Ocean by way of the
Norwegian Atlantic Current and the West Spitsbergen Current, and some from the Greenland
and Iceland gyres (Rudels et al., 1999b).
Seawater samples were collected along four sections within the EGC, above the slope,
between the Fram and Denmark Straits (Fig. 1). A station was also carried out at the mouth of
the Nansen Fjord, in the northwest of Denmark Strait.
3

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We analyzed the Nd ICs and REE concentrations of unfiltered samples in most cases.
Some surface and bottom samples were filtered using 0.45 µm filter. The analytical
procedures are described in Lacan and Jeandel, 2001. The reproducibility of the Nd IC
measurement was 0.5 εNd unit, blank values were 700 pg (3.5% of the most depleted sample
and 2% on average). Reproducibility of the REE concentration measurements was better than
10% for the whole REE and better than 5% for Nd, blanks values were better than 8% for the
whole REE and better than 3% for Nd. Results are reported in Table 1.
3. Denmark Strait Overflow Waters (DSOW)
3.1 East Greenland Current
The DSOW are the densest waters overflowing the Denmark Strait. Their origins are the
topic of numerous studies and still unclear. Among the remaining hypotheses, most of the
recent publications suggest that the precursors of the DSOW are carried within the EGC from
the north of the Nordic Seas (Strass et al., 1993; Mauritzen, 1996; Rudels et al., 1999a).
During the Signature/GINS campaign, the DSOW had the following hydrological
characteristics: -0.5

)¡
Table 1.
Physical (θ, S, σ θ ), chemical (O 2 ) and geochemical (Ce * =Ce×2/(La+Pr), La/Lu, [Nd],
ε Nd ) data used in this work. All data come from the Signature/GINS cruise (summer 1999).
All geochemical measurements were performed on unfiltered samples. Water masses were
identified by their θ-S characteristics defined by Swift, 1986 (LAIW : Lower Arctic
Intermediate Water, UAIW : Upper Arctic Intermediate Water, PW : Polar Water, AW :
Atlantic Water, ASW : Arctic Surface Water, PIW : Polar Intermediate Water). DSOW stands
for Denmark Strait Overflow Water.
5

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3.2. Denmark Strait
The section located at the Denmark Strait sill comprises three stations (West, Center and
East). Nd IC profiles are shown in Fig. 2, data are reported in Table 1. Four unfiltered samples
were collected in the DSOW flowing just above the sill: Two samples at station West (479
and 442 m), one sample at station Center (610 m) and one sample at station East (523 m). In
contrast to the homogeneity of its precursors in the EGC, DSOW display heterogeneous Nd
ICs, ranging between –10.3 and –7.5, with an average value of -8.7 ± 1.4. Nd concentrations
are also heterogeneous, ranging between 2.5 and 4.1 ppt, with an average value of 3.2 ± 0.7
ppt. The scatter in these data is mostly due to resuspensions (see sections 3.3 and 3.4). The
mean values are identical to those reported for one sample taken in 1981 downstream of the
Denmark Strait (ε Nd = -8.6 ± 0.5, [Nd] = 3 ppt; Piepgras and Wasserburg, 1987).
Figure 2.
ε Nd profiles in the Denmark Strait and the Nansen Fjord. Note the subsurface minimum,
associated with the Atlantic Water (AW), found at all stations except station West. The dotted
ellipse shows the DSOW samples. Note the scattering of the DSOW data and their rather
radiogenic values. The unbroken ellipse shows the "pure DSOW" (not subject to unradiogenic
particle resuspension). The filled circle represents the filtered bottom sample from station
Center.
Nd ICs and concentrations differ greatly from those found in the EGC. Two hypotheses
can explain this difference. Either the waters sampled in the EGC underwent Nd inputs
between 70°N and the Denmark Strait, or they mixed with waters coming from the Iceland
6

)¡
Sea (as suggested by Swift et al., 1980). Although most recent publications suggest that the
precursors of the DSOW are carried within the EGC from the north of the Nordic Seas (Strass
et al., 1993; Mauritzen, 1996; Rudels et al., 1999a), the hypothesis of an Iceland Sea
contribution can not be dismissed. But, because we do not have the Iceland Sea end-member,
we are unable to address this question in the present work. We will therefore assume in the
following that the DSOW originates in the EGC upstream of 70°N and see if this is consistent
with our data. We will therefore look if Nd inputs can cause the shift from ε Nd = -11.2 within
the EGC to ε Nd = -8.7 in the Denmark Strait and try to understand the shift from a strong
homogeneity to a pronounced heterogeneity.
In order to study Nd inputs between 70°N and DS, we need to know the geological
nature of the surrounding formations. Whereas the Greenland coast is mostly composed of
Precambrian materials between the Fram Strait and 70°N, the EGC becomes bordered by
basaltic structures between 70°N and Denmark Strait. On its eastern side, these borders are
first the Kolbeinsey ridge (see Fig. 1, ε Nd ≈ +10; Mertz et al., 1991) and then the Icelandic
slope (ε Nd ≈ +8; O'nions and Grönvold, 1973). On its western side, it is bordered by the
Blosseville coast (εNd ≈ +6; Bernstein et al., 1998) down to Kangerlussuaq fjord (68°10’ N,
just a few kilometer downstream of Denmark Strait), then again by Precambrian formations
(ε Nd ≈ -38; Taylor et al., 1992).
3.3. Particle resuspension at the Denmark Strait
In addition to the measurement of the unfiltered sample at 610 m depth of the station
Center (ε Nd = -10.3), we measured the corresponding filtered sample: ε Nd = –8.6. This
comparison implies the presence of particles of which ε Nd is lower than –10.3. Unfortunately,
we do not have the concentration of the filtered sample: this prevents us to calculate the Nd IC
of the particles.
At station West, the two deepest samples (480 and 440 m) display strictly identical
hydrological characteristics (θ, S, σ θ and O 2 , see Table 1), which indicates that they are from
the same water mass. However, their Nd ICs differ from two ε Nd units and their Nd
concentrations from 0.5 ppt (ε Nd = -9.5 and -7.5; [Nd] = 3.3 and 2.8 ppt, at 480 et 440 m
respectively). This suggests that, compared to the 440 m sample, the 480 m sample received
an input of unradiogenic Nd. This conclusion is consistent with the relative position of the
two samples: the 480 m one is at the bottom and therefore is likely to contain more
resuspended sediment. From the Nd IC and concentration variations, we estimated that the
"contaminating suspensions" must have an Nd IC of –21. This value is very close to the
measurement of a surface sediment sampled south of cape Farewell: ε Nd =-23 (Sinko, 1994). It
is also in agreement with our deduction that the Nd IC of the station Center bottom sample
particles must be lower than ε Nd < -10.3.
In view of the geological context, such a enrichment can only be explained by the
presence of Precambrian formations in the west of the Denmark strait south of 68°N.
Considering the flow in that area (mainly south-westward orientated), these inputs must have
occurred near the sill of the strait, because the sediments could not have been transported
further north. These inputs would then be recent (at the time of the sampling) and restricted to
the waters flowing at the bottom and the west of the strait. That would explain why they do
not affect the 440 m station West sample (60 m above the bottom) nor the bottom sample of
station East. The fate of these particles downstream of the Denmark Strait could not be
investigated, but the agreement between Piepgras and Wasserburg's value and our mean value
suggests that they are carried with the DSOW at 64°N.
7

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3.4. Enrichment of basaltic origin
We will now look at the DSOW samples which did not undergo unradiogenic particle
resuspensions and which we define as "pure DSOW". Their Nd ICs are: -7.5 (West 440m), -
8.6 (Center 610 m filtered) and –7.6 (East 520 m, see Fig. 2). These waters reach the entrance
of the strait with a mean Nd IC of –7.9 ± 0.6 and a mean concentration of 3.5 ppt while their
characteristics at 70°N were: ε Nd = -11.2 and [Nd] = 2.4 ppt. These variations imply an Nd
input characterized by an ε Nd of –0.9. This value could reflect the input of dissolved Nd from
basaltic formation on either side of the EGC, downstream of 70°N. The following calculations
allow to assess the validity of this hypothesis.
Figure 3.
Denmark Strait area. The black arrow shows the East Greenland Current. The black
white-edged segments and circle show the 70°N and Denmark Strait sections and the Nansen
Fjord station, respectively. The white-shaded area schematizes the contact area between the
DSOW and the margins. The white-striped areas indicate basaltic formations, the others being
Precambrian ones.
Recent estimations of the DSOW flux based on in situ high resolution current
measurements suggest that the flux of DSOW with σ θ < 28.01 has a mean value of
approximately 0.7 Sv (Girton et al., 2001). The increase in concentration described above
then requires an Nd flux of 24 t.yr -1 . DSOW precursors, within the EGC upstream of 70°N,
flow between 400 and 1000 m. As they approach the Denmark Strait, they get in contact with
the sea floor and the sides of the strait. We estimated this contact area to be around 20 000
8

)¡
km 2 (Fig. 3). Taking a value of 8 ppm for the Nd concentration in surrounding basaltic
formations (Mertz et al., 1991; Bernstein et al., 1998) and a value of 1.5 g.cm -3 for the
sediment density (Carter and Raymo, 1999), the Nd flux calculated above corresponds to the
dissolution of a 0.1 mm thick sediment layer per year. Though this value is large, it represents
only a small fraction (5 – 9 %) of sediment accumulation rates recorded in sheltered
neighboring area (1.2 to 1.8 mm.yr -1 , for instance at Nansen Fjord mouth; Jennings and
Weiner, 1996). The fact that DSOW precursors within the EGC are not subject to any input
upstream of 70°N whereas they suddenly undergo important input between 70°N and the
Denmark Strait can be explained by two reasons. First, the contact area between the water
mass and the margin upstream of 70°N is restricted to the western edge of the water mass,
which flows along the Greenland slope between 400 and 1000m. As it approaches the
Denmark Strait, this contact area increases suddenly, since the sea floor and the Iceland slope
get in contact with the lower and eastern boundaries of the water mass. Second, the geological
nature of the margins shifts from a Precambrian type to a basaltic one, the former (made of
crystallized minerals) being much less soluble than the latter. This confirms that the
dissolution of a small fraction of basaltic material bordering the strait, could explain the shift
in the Nd isotopic signature between 70°N and the Denmark Strait.
4. Atlantic Water crossing the strait towards Greenland
Nd IC profiles in the Denmark Strait display minima between 100 and 200 m depth at
stations Center and East (ε Nd = -13.5 and –12.4 respectively, see Fig. 2). These minima are
associated with temperature and salinity maxima (θ = 6.8°C, S = 35.13), and with dissolved
oxygen minima (O2 = 8.86 mg.l -1 ). These characteristics clearly identify Atlantic Water
(AW), carried by the Irminger Current towards the Iceland Sea.
The Nansen Fjord station is located in the West of Denmark strait, along the Greenland
coast, within a basaltic area. Temperature and salinity profiles show the presence of very fresh
water within the first 20 m (S < 31, θ > 2°C), then Polar Water (PW; θ=-1.35, S=33.13) down
to 150 m depth, then AW (θ=4.31, S=34.77) down to 250 m depth, and finally a water having
the characteristics of Arctic Surface Water (ASW; S=34.57, θ=0.2°C) bellow 250m depth.
The ε Nd profile is shown in Fig. 2.
Polar Water of the Nansen fjord has an Nd IC of –3.4 and a very high Nd concentration
of 14.6 ppt. Comparing with a PW sample upstream in the EGC (73°N section, 50 m depth,
ε Nd = -11.2, [Nd] = 3.2 ppt), we notice a large increase in ε Nd and Nd concentration. We
estimated that this enrichment is characterized by an ε Nd of –1.2, which is consistent with the
basaltic nature of the fjord area (between 70 and 68°N). This value is also in excellent
agreement with the one calculated, in the preceding section, for the radiogenic enrichment of
the DSOW (ε Nd = -0.9). Since the basaltic rocks are found only north of the fjord, the PW
likely undergoes lithogenic inputs along this coast. The bottom water of the fjord has also a
radiogenic signature and a high Nd concentration (ε Nd = –2.5, [Nd] = 11.9 ppt). In the same
way, this suggests that it underwent a similar radiogenic enrichment as the PW.
On the other hand, intermediate waters in the fjord are characterized by ε Nd and [Nd]
minima (ε Nd = -11.2 and [Nd] = 3 ppt). These characteristics as well as their θ an S maxima,
are clearly identifying AW. The presence of AW in this place is surprising since the only
known current carrying AW in the Denmark strait is the Irminger Current, which is restricted
to the eastern part of the strait. The fact that its Nd IC and concentration are not very different
from the AW measured in the strait (station Center, 97 m, ε Nd = -13.5, [Nd]=2.7 ppt], Fig. 2
and Tab. 1) shows that, either it comes from the Irminger Current and crosses the strait, or it
9

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flows north-eastward along the east Greenland Coast following a coastal counter current.
Coastal counter currents are particularly subject to terrigeneous matter inputs, but the absence
of any concentration increase or Precambrian influence on the ε Nd value precludes this
possibility. Therefore, AW likely comes from the Irminger Current and crosses the strait. The
flow in the Denmark Strait being in a very large majority southwestward orientated, a limb of
the Irminger Current crossing the whole strait uninterruptedly is hardly imaginable. Moreover
the absence of AW at station West suggests that its transportation is due to discontinuous
structures. One has therefore to invoke a small dimension structure (at the strait scale), which
is able to cross the strait without being entrained by the EGC. It is therefore probable that the
AW found at the mouth of the Nansen Fjord crossed the strait within eddies. Eddy formations
in the Denmark Strait have been described in several papers (Krauss and Käse, 1998; Spall
and Price, 1998).
5. Conclusions
During the Signature/GINS cruise (IFRTP, July-August 1999), DSOW had the
following characteristics: -0.5

)¡ ¢
and crew of the R/V Marion Dufresne for having carried out the cruise. A. Gouzy is
acknowledged for his intensive contribution to the sampling and preconcentration of Nd on
board. We are grateful to M. Souhaut, M. Roy-Barman and P. Brunet for their help with the
analytical work. R. Francois, G. Reverdin, N. Ayoub, J.D. Milliman, J.T. Andrews and C.
Hillaire-Marcel are deeply thanked for their help in interpreting the data. We also
acknowledge R. Schlitzer for providing the free Ocean Data View software.
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