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8 3 2006 8 <br />
<br />
JOURNAL OF PALAEO GEO GRAPHY<br />
Vol18 No13<br />
Aug1 2006<br />
<br />
: 1671 - 1505 (2006) 03 - 0307 - 10 <br />
<br />
3<br />
<br />
1<br />
<br />
,2 <br />
3 4<br />
<br />
1 <br />
, 100034<br />
2 <br />
( ) , 102200<br />
3 <br />
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4 <br />
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, <br />
, / , , <br />
, (<br />
) <br />
<br />
, <br />
, , , , <br />
<br />
, 2001 9 <br />
( ) , <br />
, <br />
<br />
: P588122 <br />
: A<br />
Geologic characteristics and their hydrocarbon implication of black shales<br />
of the Lower Cretaceous in Kuco2Gamba Basin , Tibet<br />
<br />
<br />
Yue Laiqun 1 ,2 Li Yongtie 3 Shi Xiaoying 4<br />
<br />
1 S t rategic Research Center of Oil and Gas Resources , ML R , Beijing 100034<br />
<br />
2 China U niversity of Pet roleum ( Beijing) , Beijing 102200<br />
3 Research Institute of Pet roleum Ex ploration & Development , Pet roChina , Beijing 100083<br />
<br />
4 China U niversity of Geosciences ( Beijing) , Beijing 100083<br />
Abstract The Kuco2Gamba Basin in the southern Tibet is located in the northern Himalayas<br />
structural zone , and is distributed in an east2west direction1 The sediments of the Early Cretaceous<br />
were dominated by clastics. Black shales were mainly developed in the member 4 and member 5 of<br />
Kuco Formation and Dongshan Formation of the Lower Cretaceous. Black shales are dominated by<br />
muddy and clay minerals. The ratio of sandstone to mudstone is tiny. Locally the cycles composed by<br />
3 <br />
(No149825102 )<br />
: 2006 - 04 - 10 <br />
: 2006 - 04 - 30
308 2006 8 <br />
fine2grained sandstones and siltites of the submarine fan were interbedded. Siderite and calcareous<br />
aerites were abundant , while organic fossils such as ammonite were poor. The sedimentary environ2<br />
ment was a marine reduction environment with slow facies change , low2energy waterbody and a spe2<br />
cial setting influenced by volcanic movement . The rare earth assemblage pattern reflected by the<br />
siltites in the black shales is quite similar to the basalt standard pattern. It is demonstrated that the<br />
deposit at that time was possibly accompanied by volcanic movement and intervention of mantle materi2<br />
als. Comprehensive geologic characters show that the black shales of the Lower Cretaceous in the<br />
study area are characterized by large2thickness , simple structure and better hydrocarbon formation<br />
conditions. Though the organic maturity is high , black shales are one of the important factors in fu2<br />
ture petroleum resource appraisal in the study area.<br />
Key words Tibet , Kuco2Gamba , northern Himalayas , Lower Cretaceous , black shales , hy2<br />
drocarbon formation condition , hydrocarbon potential<br />
About the f irst author Yue Laiqun , graduated from China University of Geosciences and ob2<br />
tained his doctoral degree in 2001. Now , he is a research professor and professoral engineer , and is<br />
engaged in geoscience and research on resources economy.<br />
1 <br />
1996) , <br />
, <br />
<br />
1<br />
<br />
, , <br />
(1) <br />
, <br />
<br />
1997 ; , 1991 ; , 1992 ; ,<br />
1 <br />
Fig11 Tectonic location of Kuco2Gamba<br />
2 <br />
Fig12 Location of Kuco and Gamba geological sections<br />
2 <br />
211 <br />
<br />
, <br />
, 3 000 m , , <br />
, , , <br />
<br />
, <br />
(2) , <br />
, ( , 1990) <br />
<br />
, <br />
(<br />
, 1993 , Jacobi Grandis ,
8 3 : <br />
309<br />
1 <br />
Table 1 Stratigraphic systems and their major characteristics of the Cretaceous in northern Himalayas<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
, <br />
<br />
<br />
, , , <br />
<br />
<br />
<br />
, <br />
, <br />
<br />
, <br />
<br />
<br />
, <br />
<br />
<br />
, <br />
<br />
<br />
<br />
( , 1987 ; ,<br />
<br />
, <br />
1985 ; Pathak and Jai Krishna , 1993) <br />
; <br />
; <br />
<br />
, , <br />
<br />
, (4) <br />
<br />
(3) , <br />
<br />
<br />
800 m , <br />
, <br />
, <br />
<br />
, Dimorphoplites ,<br />
Hypacanthoplites Protanisoceras , <br />
<br />
( , 1985 ; , 1990) <br />
<br />
, <br />
( , 1996) , <br />
,<br />
<br />
(5) <br />
3 <br />
, <br />
<br />
Fig13 Boundary between the Dongshan Formation and<br />
, <br />
the Chaqiela Formation in Gamba<br />
, <br />
, <br />
20 %<br />
, <br />
<br />
, <br />
(5) , <br />
<br />
, 212 <br />
(<br />
<br />
, 1996) , <br />
, , <br />
, 60 %90 % , <br />
, <br />
,
310 2006 8 <br />
4 <br />
Fig14 Photographs of the fine2grained rock fragments of sandstone intercalated layer in black shales<br />
A <br />
, , <br />
, <br />
, , 4 50 ;<br />
B <br />
, <br />
, <br />
, 011mm ,<br />
<br />
, , 4 20<br />
5 <br />
Fig15 Correlation of black shale2bearing strata of the Lower Cretaceous between Kuco and Gamba areas
8 3 : <br />
311<br />
<br />
, <br />
, <br />
, , <br />
, 0104 mm <br />
<br />
, <br />
; <br />
<br />
, <br />
<br />
; <br />
, 5 % , 6 <br />
<br />
Fig16 Rare earth distribution pattern of black shales<br />
, , <br />
<br />
, <br />
, 14 520 cm , 35 cm L/ H Eu/ REE( L La - Eu <br />
, <br />
, , H Gd - Lu <br />
, REE La - Lu <br />
) <br />
<br />
, <br />
(7) , <br />
<br />
, , <br />
Eu Ce , <br />
(<br />
Ce Eu <br />
, 2003) , L/ H 57 98 , Eu/ REE <br />
<br />
( Himachal 01450170 , <br />
Ce <br />
Pradesh) Spiti <br />
(Bhar2<br />
, <br />
Eu<br />
gava and Bassi , 1998) <br />
Ce<br />
213 <br />
3 + <br />
Ce 4 + ,<br />
<br />
, <br />
( )<br />
<br />
X (2) , <br />
14 <br />
, <br />
8 <br />
<br />
, <br />
(<br />
6) , <br />
2 <br />
( 10 - 6 )<br />
Table 2 Rare earth analysis results of black shales<br />
Ce , Eu<br />
<br />
<br />
<br />
<br />
g4 - 1 g4 - 2 g4 - 3 g4 - 4 g5 - 1 g5 - 2 d6 - 6 d9 - 6<br />
La 6017 4314 4718 4918 5910 7016 5813 5717<br />
Ce 125 8519 9611 107 123 153 112 104<br />
Nd 5012 4014 4415 4818 6210 7319 5714 5011<br />
Sm 1118 819 8193 9158 1116 1315 1015 9131<br />
Eu 2117 1155 1189 2134 2125 3154 2159 2133<br />
Tb 1178 0199 0194 1117 1139 1157 1126 1141<br />
Yb 3174 2142 2151 3116 2193 314 2167 2182<br />
Lu 0144 0130 0139 0137 0139 0143 0138 0137<br />
: <br />
5 7 L/ H Eu/ REE <br />
Fig17 Diagram showing relationship between L/ H<br />
and Eu/ REE of black shales
312 2006 8 <br />
(8) <br />
3 <br />
Table 3 Element ratio of different black shales of the<br />
Lower Cretaceous in northern Himalayas<br />
<br />
Sr/ Ba<br />
<br />
K/ Na Rb/ K Th/ U Co/ Ni Cr/ K<br />
g3 - 1<br />
g3 - 2<br />
g4 - 1<br />
g4 - 2<br />
g4 - 3<br />
g4 - 4<br />
g5 - 1<br />
g5 - 2<br />
01174 01494 01003 01325 01233 01005<br />
<br />
01389 11408 01003 01114 01031 01004<br />
01480 11174 01004 01211 01051 01004<br />
01629 11880 01004 0116 01013 01005<br />
<br />
11482 61708 01003 31364 01038 01005<br />
01327 21798 01003 71500 01019 01004<br />
01315 31213 01004 61875 01125 01005<br />
<br />
01320 41480 01004 101131 01032 01005<br />
8 <br />
La/ Yb REE <br />
Fig18 Diagram showing La/ Yb and REE<br />
content in different rocks<br />
Table 4 U , Th and K abundance of douke in black<br />
214 <br />
shales of the Lower Cretaceous in northern Himalayas<br />
Th U <br />
Th <br />
, <br />
( ) ( ) <br />
, <br />
U <br />
, ( UO 2 SO 4 ) <br />
( Na [ UO 2<br />
d6 - 6<br />
d9 - 6<br />
(CO 3 ) 3 ]) <br />
, U <br />
, , U <br />
01306 21472 01004 71547 01038 01009<br />
01310 31033 01003 61392 01009 01007<br />
4 <br />
UThK<br />
K/ 10 - 6 18 073 19 750 850<br />
Th/ 10 - 6 7138 1212 0104<br />
U/ 10 - 6 212 1177 01015<br />
Th/ U 2144 6197 2167<br />
Th <br />
, <br />
<br />
, (5) <br />
<br />
, , <br />
012 %<br />
, <br />
(3 0176 % , 13 C( PDB ) - 241380 - 211854 ; <br />
4) <br />
0146 % 1137 % , <br />
215 <br />
1102 % , <br />
13 C( PDB ) - 211148 - 241092 , <br />
<br />
- 22 <br />
CO 2 CO 2<br />
13 C - <br />
201805 - 241380 ,<br />
<br />
CO 2 - 23125 <br />
, <br />
, CO 2 <br />
( Hart and<br />
<br />
Kim , 1986 ; Ken Goldeira et al1 , 1991 ; Leary et<br />
<br />
al1 , 1989) , <br />
, <br />
( Yoshiyuki Tatsu2<br />
<br />
mi et al1 , 1998)
8 3 : <br />
313<br />
5 <br />
6 <br />
Table 5 Isotope data of organic carbon<br />
in the Lower Cretaceous black shales of study area<br />
<br />
g3 - 1<br />
g4 - 2<br />
g5 - 1<br />
g5 - 2<br />
d6 - 6<br />
d9 - 6<br />
<br />
13 C/ / <br />
- 221164 01009<br />
- 241101 01014<br />
<br />
- 211854 01004<br />
<br />
- 201805 01008<br />
- 211148 01007<br />
- 241092 01009<br />
5 <br />
<br />
for argillaceous in Qiangtang Basin<br />
<br />
<br />
7 <br />
<br />
/ % < 014 014016 016110 > 110<br />
<br />
9 <br />
A / 10 - 6 < 100 100500 5001 000 > 1 000<br />
<br />
<br />
< 100<br />
9 / 10 - 6 100200 200500 > 500<br />
<br />
9 <br />
<br />
9 <br />
<br />
3 <br />
311 <br />
<br />
( ) , <br />
<br />
, <br />
,<br />
(<br />
<br />
( ) )<br />
Table 6 Abundance appraisal standard of organic mass<br />
<br />
< 1 12 26 > 6<br />
/ mg g - 1<br />
7 <br />
Table 7 Organic mass abundance in different<br />
black shale2bearing formations<br />
<br />
/ % A/ 10 - 6 / 10 - 6 / mg g - 1<br />
011015 35 910 0112<br />
0120176 49 1710 0118<br />
01461137 48 1210 0140<br />
<br />
, <br />
1137 % , 1102 % , <br />
<br />
<br />
57 % , <br />
(6) <br />
16 % , <br />
0115018 mg/ g<br />
<br />
<br />
7 312 <br />
, <br />
<br />
, 7 <br />
, <br />
<br />
1 800 m<br />
<br />
, <br />
( ) (8) , ( ) ( 1 2 <br />
012 %0176 % , <br />
1 2) <br />
<br />
44 %<br />
0146 % <br />
9 <br />
8 <br />
Table 8 Classified criterion of organic mass in hydrocarbon resources rocks<br />
<br />
2 1 2 1<br />
H/ C < 017 017110 110113 113115 > 115<br />
<br />
13 C/ > - 2310 - 23102415 - 24152610 - 2610- 2810 < - 2810<br />
2920/ 1600 ( ) < 018 018117 117310 > 310 > 310<br />
1460/ 1600 ( ) < 0125 0125015 015018 > 018 > 018
314 2006 8 <br />
9 <br />
Table 9 Parameters of organic mass in the Fourth Kuco Formation , the Fifth Kuco Formation and the Dongshan Formation<br />
H/ C <br />
13 C/ HI/ mg g - 1 S 2 / S 3 <br />
<br />
<br />
<br />
<br />
G410 0103 - 24106 1 0106 C 10 - C 27 C 14 2 - 1<br />
G411 0106 - 24115 1 0108 C 11 - C 27 C 17 2 - 1<br />
G516 0105 - 21185 9 0107 C 17 - C 31 C 19 2<br />
G517 0114 - 24160 2 0109 C 13 - C 27 C 15 2 - <br />
G518 0113 - 20180 1 0103 C 08 - C 17 C 14 2<br />
G06 0112 - 2112 1 0107 C 13 - C 31 C 17 2 - 1<br />
<br />
G07 0104 - 2212 3 0109 C 13 - C 31 C 17 2 - 1<br />
G08 0108 - 2415 7 0109 C 13 - C 31 C 17 2 - 1<br />
<br />
60 % , C 25 - C 27 <br />
( HIOIS 2 / S 3 ) 2; , <br />
,<br />
2 - 1 ; <br />
<br />
, ; <br />
<br />
, <br />
, <br />
, <br />
, <br />
, <br />
( ) ( Ruediger Stienet al1 ,<br />
, <br />
, <br />
1986) <br />
, <br />
( S 2 ) , ( HI) <br />
( S 2 / S 3 ) , <br />
4 <br />
, <br />
<br />
, 411 <br />
, <br />
, <br />
, <br />
13 C , <br />
<br />
12 C , <br />
, <br />
, , <br />
13 C , <br />
<br />
- 21185 - 20180 , <br />
, <br />
<br />
(<br />
, 1993) , <br />
,<br />
<br />
<br />
313 <br />
<br />
<br />
R o 210 , <br />
, <br />
<br />
R o <br />
, <br />
, C 13 - C 33 , , <br />
<br />
C 21 , C - 21 / C + 22 1 55 %<br />
, <br />
C 17 - C 19 <br />
, <br />
,
8 3 : <br />
315<br />
, <br />
<br />
412 <br />
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()<br />
<br />
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( ) Petroleum Science <br />
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Pet roleum Science <br />
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