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8 3 2006 8 <br />

<br />

JOURNAL OF PALAEO GEO GRAPHY<br />

Vol18 No13<br />

Aug1 2006<br />

<br />

: 1671 - 1505 (2006) 03 - 0307 - 10 <br />

<br />

3<br />

<br />

1<br />

<br />

,2 <br />

3 4<br />

<br />

1 <br />

, 100034<br />

2 <br />

( ) , 102200<br />

3 <br />

, 100083<br />

4 <br />

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, <br />

,<br />

, <br />

, / , , <br />

, (<br />

) <br />

<br />

, <br />

, , , , <br />

<br />

, 2001 9 <br />

( ) , <br />

, <br />

<br />

: P588122 <br />

: A<br />

Geologic characteristics and their hydrocarbon implication of black shales<br />

of the Lower Cretaceous in Kuco2Gamba Basin , Tibet<br />

<br />

<br />

Yue Laiqun 1 ,2 Li Yongtie 3 Shi Xiaoying 4<br />

<br />

1 S t rategic Research Center of Oil and Gas Resources , ML R , Beijing 100034<br />

<br />

2 China U niversity of Pet roleum ( Beijing) , Beijing 102200<br />

3 Research Institute of Pet roleum Ex ploration & Development , Pet roChina , Beijing 100083<br />

<br />

4 China U niversity of Geosciences ( Beijing) , Beijing 100083<br />

Abstract The Kuco2Gamba Basin in the southern Tibet is located in the northern Himalayas<br />

structural zone , and is distributed in an east2west direction1 The sediments of the Early Cretaceous<br />

were dominated by clastics. Black shales were mainly developed in the member 4 and member 5 of<br />

Kuco Formation and Dongshan Formation of the Lower Cretaceous. Black shales are dominated by<br />

muddy and clay minerals. The ratio of sandstone to mudstone is tiny. Locally the cycles composed by<br />

3 <br />

(No149825102 )<br />

: 2006 - 04 - 10 <br />

: 2006 - 04 - 30


308 2006 8 <br />

fine2grained sandstones and siltites of the submarine fan were interbedded. Siderite and calcareous<br />

aerites were abundant , while organic fossils such as ammonite were poor. The sedimentary environ2<br />

ment was a marine reduction environment with slow facies change , low2energy waterbody and a spe2<br />

cial setting influenced by volcanic movement . The rare earth assemblage pattern reflected by the<br />

siltites in the black shales is quite similar to the basalt standard pattern. It is demonstrated that the<br />

deposit at that time was possibly accompanied by volcanic movement and intervention of mantle materi2<br />

als. Comprehensive geologic characters show that the black shales of the Lower Cretaceous in the<br />

study area are characterized by large2thickness , simple structure and better hydrocarbon formation<br />

conditions. Though the organic maturity is high , black shales are one of the important factors in fu2<br />

ture petroleum resource appraisal in the study area.<br />

Key words Tibet , Kuco2Gamba , northern Himalayas , Lower Cretaceous , black shales , hy2<br />

drocarbon formation condition , hydrocarbon potential<br />

About the f irst author Yue Laiqun , graduated from China University of Geosciences and ob2<br />

tained his doctoral degree in 2001. Now , he is a research professor and professoral engineer , and is<br />

engaged in geoscience and research on resources economy.<br />

1 <br />

1996) , <br />

, <br />

<br />

1<br />

<br />

, , <br />

(1) <br />

, <br />

<br />

1997 ; , 1991 ; , 1992 ; ,<br />

1 <br />

Fig11 Tectonic location of Kuco2Gamba<br />

2 <br />

Fig12 Location of Kuco and Gamba geological sections<br />

2 <br />

211 <br />

<br />

, <br />

, 3 000 m , , <br />

, , , <br />

<br />

, <br />

(2) , <br />

, ( , 1990) <br />

<br />

, <br />

(<br />

, 1993 , Jacobi Grandis ,


8 3 : <br />

309<br />

1 <br />

Table 1 Stratigraphic systems and their major characteristics of the Cretaceous in northern Himalayas<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

, <br />

<br />

<br />

, , , <br />

<br />

<br />

<br />

, <br />

, <br />

<br />

, <br />

<br />

<br />

, <br />

<br />

<br />

, <br />

<br />

<br />

<br />

( , 1987 ; ,<br />

<br />

, <br />

1985 ; Pathak and Jai Krishna , 1993) <br />

; <br />

; <br />

<br />

, , <br />

<br />

, (4) <br />

<br />

(3) , <br />

<br />

<br />

800 m , <br />

, <br />

, <br />

<br />

, Dimorphoplites ,<br />

Hypacanthoplites Protanisoceras , <br />

<br />

( , 1985 ; , 1990) <br />

<br />

, <br />

( , 1996) , <br />

,<br />

<br />

(5) <br />

3 <br />

, <br />

<br />

Fig13 Boundary between the Dongshan Formation and<br />

, <br />

the Chaqiela Formation in Gamba<br />

, <br />

, <br />

20 %<br />

, <br />

<br />

, <br />

(5) , <br />

<br />

, 212 <br />

(<br />

<br />

, 1996) , <br />

, , <br />

, 60 %90 % , <br />

, <br />

,


310 2006 8 <br />

4 <br />

Fig14 Photographs of the fine2grained rock fragments of sandstone intercalated layer in black shales<br />

A <br />

, , <br />

, <br />

, , 4 50 ;<br />

B <br />

, <br />

, <br />

, 011mm ,<br />

<br />

, , 4 20<br />

5 <br />

Fig15 Correlation of black shale2bearing strata of the Lower Cretaceous between Kuco and Gamba areas


8 3 : <br />

311<br />

<br />

, <br />

, <br />

, , <br />

, 0104 mm <br />

<br />

, <br />

; <br />

<br />

, <br />

<br />

; <br />

, 5 % , 6 <br />

<br />

Fig16 Rare earth distribution pattern of black shales<br />

, , <br />

<br />

, <br />

, 14 520 cm , 35 cm L/ H Eu/ REE( L La - Eu <br />

, <br />

, , H Gd - Lu <br />

, REE La - Lu <br />

) <br />

<br />

, <br />

(7) , <br />

<br />

, , <br />

Eu Ce , <br />

(<br />

Ce Eu <br />

, 2003) , L/ H 57 98 , Eu/ REE <br />

<br />

( Himachal 01450170 , <br />

Ce <br />

Pradesh) Spiti <br />

(Bhar2<br />

, <br />

Eu<br />

gava and Bassi , 1998) <br />

Ce<br />

213 <br />

3 + <br />

Ce 4 + ,<br />

<br />

, <br />

( )<br />

<br />

X (2) , <br />

14 <br />

, <br />

8 <br />

<br />

, <br />

(<br />

6) , <br />

2 <br />

( 10 - 6 )<br />

Table 2 Rare earth analysis results of black shales<br />

Ce , Eu<br />

<br />

<br />

<br />

<br />

g4 - 1 g4 - 2 g4 - 3 g4 - 4 g5 - 1 g5 - 2 d6 - 6 d9 - 6<br />

La 6017 4314 4718 4918 5910 7016 5813 5717<br />

Ce 125 8519 9611 107 123 153 112 104<br />

Nd 5012 4014 4415 4818 6210 7319 5714 5011<br />

Sm 1118 819 8193 9158 1116 1315 1015 9131<br />

Eu 2117 1155 1189 2134 2125 3154 2159 2133<br />

Tb 1178 0199 0194 1117 1139 1157 1126 1141<br />

Yb 3174 2142 2151 3116 2193 314 2167 2182<br />

Lu 0144 0130 0139 0137 0139 0143 0138 0137<br />

: <br />

5 7 L/ H Eu/ REE <br />

Fig17 Diagram showing relationship between L/ H<br />

and Eu/ REE of black shales


312 2006 8 <br />

(8) <br />

3 <br />

Table 3 Element ratio of different black shales of the<br />

Lower Cretaceous in northern Himalayas<br />

<br />

Sr/ Ba<br />

<br />

K/ Na Rb/ K Th/ U Co/ Ni Cr/ K<br />

g3 - 1<br />

g3 - 2<br />

g4 - 1<br />

g4 - 2<br />

g4 - 3<br />

g4 - 4<br />

g5 - 1<br />

g5 - 2<br />

01174 01494 01003 01325 01233 01005<br />

<br />

01389 11408 01003 01114 01031 01004<br />

01480 11174 01004 01211 01051 01004<br />

01629 11880 01004 0116 01013 01005<br />

<br />

11482 61708 01003 31364 01038 01005<br />

01327 21798 01003 71500 01019 01004<br />

01315 31213 01004 61875 01125 01005<br />

<br />

01320 41480 01004 101131 01032 01005<br />

8 <br />

La/ Yb REE <br />

Fig18 Diagram showing La/ Yb and REE<br />

content in different rocks<br />

Table 4 U , Th and K abundance of douke in black<br />

214 <br />

shales of the Lower Cretaceous in northern Himalayas<br />

Th U <br />

Th <br />

, <br />

( ) ( ) <br />

, <br />

U <br />

, ( UO 2 SO 4 ) <br />

( Na [ UO 2<br />

d6 - 6<br />

d9 - 6<br />

(CO 3 ) 3 ]) <br />

, U <br />

, , U <br />

01306 21472 01004 71547 01038 01009<br />

01310 31033 01003 61392 01009 01007<br />

4 <br />

UThK<br />

K/ 10 - 6 18 073 19 750 850<br />

Th/ 10 - 6 7138 1212 0104<br />

U/ 10 - 6 212 1177 01015<br />

Th/ U 2144 6197 2167<br />

Th <br />

, <br />

<br />

, (5) <br />

<br />

, , <br />

012 %<br />

, <br />

(3 0176 % , 13 C( PDB ) - 241380 - 211854 ; <br />

4) <br />

0146 % 1137 % , <br />

215 <br />

1102 % , <br />

13 C( PDB ) - 211148 - 241092 , <br />

<br />

- 22 <br />

CO 2 CO 2<br />

13 C - <br />

201805 - 241380 ,<br />

<br />

CO 2 - 23125 <br />

, <br />

, CO 2 <br />

( Hart and<br />

<br />

Kim , 1986 ; Ken Goldeira et al1 , 1991 ; Leary et<br />

<br />

al1 , 1989) , <br />

, <br />

( Yoshiyuki Tatsu2<br />

<br />

mi et al1 , 1998)


8 3 : <br />

313<br />

5 <br />

6 <br />

Table 5 Isotope data of organic carbon<br />

in the Lower Cretaceous black shales of study area<br />

<br />

g3 - 1<br />

g4 - 2<br />

g5 - 1<br />

g5 - 2<br />

d6 - 6<br />

d9 - 6<br />

<br />

13 C/ / <br />

- 221164 01009<br />

- 241101 01014<br />

<br />

- 211854 01004<br />

<br />

- 201805 01008<br />

- 211148 01007<br />

- 241092 01009<br />

5 <br />

<br />

for argillaceous in Qiangtang Basin<br />

<br />

<br />

7 <br />

<br />

/ % < 014 014016 016110 > 110<br />

<br />

9 <br />

A / 10 - 6 < 100 100500 5001 000 > 1 000<br />

<br />

<br />

< 100<br />

9 / 10 - 6 100200 200500 > 500<br />

<br />

9 <br />

<br />

9 <br />

<br />

3 <br />

311 <br />

<br />

( ) , <br />

<br />

, <br />

,<br />

(<br />

<br />

( ) )<br />

Table 6 Abundance appraisal standard of organic mass<br />

<br />

< 1 12 26 > 6<br />

/ mg g - 1<br />

7 <br />

Table 7 Organic mass abundance in different<br />

black shale2bearing formations<br />

<br />

/ % A/ 10 - 6 / 10 - 6 / mg g - 1<br />

011015 35 910 0112<br />

0120176 49 1710 0118<br />

01461137 48 1210 0140<br />

<br />

, <br />

1137 % , 1102 % , <br />

<br />

<br />

57 % , <br />

(6) <br />

16 % , <br />

0115018 mg/ g<br />

<br />

<br />

7 312 <br />

, <br />

<br />

, 7 <br />

, <br />

<br />

1 800 m<br />

<br />

, <br />

( ) (8) , ( ) ( 1 2 <br />

012 %0176 % , <br />

1 2) <br />

<br />

44 %<br />

0146 % <br />

9 <br />

8 <br />

Table 8 Classified criterion of organic mass in hydrocarbon resources rocks<br />

<br />

2 1 2 1<br />

H/ C < 017 017110 110113 113115 > 115<br />

<br />

13 C/ > - 2310 - 23102415 - 24152610 - 2610- 2810 < - 2810<br />

2920/ 1600 ( ) < 018 018117 117310 > 310 > 310<br />

1460/ 1600 ( ) < 0125 0125015 015018 > 018 > 018


314 2006 8 <br />

9 <br />

Table 9 Parameters of organic mass in the Fourth Kuco Formation , the Fifth Kuco Formation and the Dongshan Formation<br />

H/ C <br />

13 C/ HI/ mg g - 1 S 2 / S 3 <br />

<br />

<br />

<br />

<br />

G410 0103 - 24106 1 0106 C 10 - C 27 C 14 2 - 1<br />

G411 0106 - 24115 1 0108 C 11 - C 27 C 17 2 - 1<br />

G516 0105 - 21185 9 0107 C 17 - C 31 C 19 2<br />

G517 0114 - 24160 2 0109 C 13 - C 27 C 15 2 - <br />

G518 0113 - 20180 1 0103 C 08 - C 17 C 14 2<br />

G06 0112 - 2112 1 0107 C 13 - C 31 C 17 2 - 1<br />

<br />

G07 0104 - 2212 3 0109 C 13 - C 31 C 17 2 - 1<br />

G08 0108 - 2415 7 0109 C 13 - C 31 C 17 2 - 1<br />

<br />

60 % , C 25 - C 27 <br />

( HIOIS 2 / S 3 ) 2; , <br />

,<br />

2 - 1 ; <br />

<br />

, ; <br />

<br />

, <br />

, <br />

, <br />

, <br />

, <br />

( ) ( Ruediger Stienet al1 ,<br />

, <br />

, <br />

1986) <br />

, <br />

( S 2 ) , ( HI) <br />

( S 2 / S 3 ) , <br />

4 <br />

, <br />

<br />

, 411 <br />

, <br />

, <br />

, <br />

13 C , <br />

<br />

12 C , <br />

, <br />

, , <br />

13 C , <br />

<br />

- 21185 - 20180 , <br />

, <br />

<br />

(<br />

, 1993) , <br />

,<br />

<br />

<br />

313 <br />

<br />

<br />

R o 210 , <br />

, <br />

<br />

R o <br />

, <br />

, C 13 - C 33 , , <br />

<br />

C 21 , C - 21 / C + 22 1 55 %<br />

, <br />

C 17 - C 19 <br />

, <br />

,


8 3 : <br />

315<br />

, <br />

<br />

412 <br />

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English abstract) .<br />

()<br />

<br />

<br />

( ) Petroleum Science <br />

<br />

( ) Pet roleum Science 5 ,2003 <br />

<br />

, CN 11 - 4995/ TE , ,<br />

:80 - 379 <br />

Pet roleum Science <br />

,<br />

<br />

<br />

,<br />

, <br />

Pet roleum Science <br />

,<br />

<br />

, <br />

<br />

<br />

,<br />

: ; ; ( , , E2mail) ;<br />

<br />

(<br />

) ; ; ; ,<br />

<br />

<br />

<br />

<br />

:<br />

20 902 <br />

,100083<br />

:010 - 82370092 82375872<br />

E2mail :ps0092 @163. com

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