Chemwatch Australian MSDS 42095 - Westernex

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DY-MARK SAFE MARK NON FLAMMABLE AEROSOL LEAD FREE COLOURS Chemwatch Independent Material Safety Data Sheet Issue Date: 7-Sep-2009 CHEMWATCH 42095 C9317EC Version No:5 CD 2009/2 Page 2 of 7 Section 4 - FIRST AID MEASURES SWALLOWED ■ - Not considered a normal route of entry. ■ - For advice, contact a Poisons Information Centre or a doctor. ■ - Avoid giving milk or oils. ■ - Avoid giving alcohol. EYE ■ If aerosols come in contact with the eyes: - Immediately hold the eyelids apart and flush the eye continuously for at least 15 minutes with fresh running water. - Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. SKIN ■ If solids or aerosol mists are deposited upon the skin: - Flush skin and hair with running water (and soap if available). - Remove any adhering solids with industrial skin cleansing cream. INHALED ■ If aerosols, fumes or combustion products are inhaled: - Remove to fresh air. - Lay patient down. Keep warm and rested. NOTES TO PHYSICIAN ■ for intoxication due to Freons/ Halons; A: Emergency and Supportive Measures - Maintain an open airway and assist ventilation if necessary - Treat coma and arrhythmias if they occur. Avoid (adrenaline) epinephrine or other sympathomimetic amines that may precipitate ventricular arrhythmias. Tachyarrhythmias caused by increased myocardial sensitisation may be treated with propranolol, 1-2 mg IV or esmolol 25-100 microgm/kg/min IV. Followed acute or short term repeated exposures to ethylene glycol monoalkyl ethers and their acetates: - Hepatic metabolism produces ethylene glycol as a metabolite. - Clinical presentation, following severe intoxication, resembles that of ethylene glycol exposures. Treat symptomatically. For acute or short term repeated exposures to ethylene glycol: - Early treatment of ingestion is important. Ensure emesis is satisfactory. - Test and correct for metabolic acidosis and hypocalcaemia. Section 5 - FIRE FIGHTING MEASURES EXTINGUISHING MEDIA ■ SMALL FIRE: Use extinguishing agent suitable for type of surrounding fire. LARGE FIRE: Cool cylinder. SMALL FIRE: - Water spray, dry chemical or CO2 LARGE FIRE: - Water spray or fog. FIRE FIGHTING ■ - Alert Fire Brigade and tell them location and nature of hazard. - May be violently or explosively reactive. When any large container (including road and rail tankers) is involved in a fire, consider evacuation by 100 metres in all directions. FIRE/EXPLOSION HAZARD ■ - Non combustible. - Not considered to be a significant fire risk. Decomposition may produce toxic fumes of: carbon monoxide (CO), carbon dioxide (CO2), hydrogen chloride, phosgene, hydrogen fluoride, other pyrolysis products typical of burning organic material. Contains low boiling substance: Closed containers may rupture due to pressure buildup under fire conditions. FIRE INCOMPATIBILITY ■ - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result. HAZCHEM: 2YE Personal Protective Equipment Gas tight chemical resistant suit. continued...
DY-MARK SAFE MARK NON FLAMMABLE AEROSOL LEAD FREE COLOURS Chemwatch Independent Material Safety Data Sheet Issue Date: 7-Sep-2009 CHEMWATCH 42095 C9317EC Version No:5 CD 2009/2 Page 3 of 7 Section 6 - ACCIDENTAL RELEASE MEASURES MINOR SPILLS ■ - Clean up all spills immediately. - Avoid breathing vapours and contact with skin and eyes. MAJOR SPILLS ■ - Remove leaking cylinders to a safe place. - Fit vent pipes. Release pressure under safe, controlled conditions. - DO NOT exert excessive pressure on valve; DO NOT attempt to operate damaged valve. - Clear area of personnel and move upwind. - Alert Fire Brigade and tell them location and nature of hazard. Personal Protective Equipment advice is contained in Section 8 of the MSDS. Section 7 - HANDLING AND STORAGE PROCEDURE FOR HANDLING ■ - Avoid all personal contact, including inhalation. - Wear protective clothing when risk of exposure occurs. SUITABLE CONTAINER ■ - DO NOT use aluminium or galvanised containers. - Aerosol dispenser. - Check that containers are clearly labelled. STORAGE INCOMPATIBILITY ■ Ethylene glycol monobutyl ether (2-butoxyethanol) and its acetate: - May form unstable peroxides in storage - is incompatible with oxidisers, permanganates, peroxides, ammonium persulfate, bromine dioxide, nitrates, strong acids, sulfuric acid, nitric acid, perchloric acid. Methylene chloride - is a combustible liquid under certain circumstances even though there is no measurable flash point and it is difficult to ignite - its is flammable in ambient air in the range 12-23%; increased oxygen content can greatly enhance fire and explosion potential. Haloalkanes: - are highly reactive:some of the more lightly substituted lower members are highly flammable; the more highly substituted may be used as fire suppressants, not always with the anticipated results. - may react with the lighter divalent metals to produce more reactive compounds analogous to Grignard reagents. - Segregate from alcohol, water. - Compressed gases may contain a large amount of kinetic energy over and above that potentially available from the energy of reaction produced by the gas in chemical reaction with other substances. STORAGE REQUIREMENTS ■ - Keep dry to avoid corrosion of cans. Corrosion may result in container perforation and internal pressure may eject contents of can. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE CONTROLS Source Material TWA ppm TWA mg/m³ STEL ppm STEL mg/m³ Notes ___________ ___________ _______ _______ _______ _______ _______ Australia Exposure methylene chloride 50 174 Sk Standards (Methylene chloride) Australia Exposure ethylene glycol 20 96.9 50 242 Sk Standards monobutyl ether (2- Butoxyethanol) Australia Exposure tetrafluoroethane (1, 1000 4240 Standards 1, 1, 2- Tetrafluoroethane) PERSONAL PROTECTION RESPIRATOR Type AXNO Filter of sufficient capacity EYE ■ No special equipment for minor exposure i.e. when handling small quantities. HANDS/FEET ■ - No special equipment needed when handling small quantities. - OTHERWISE: continued...
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Chemwatch Australian MSDS 42095 - Westernex

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