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production of wax esters in crambe

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• Tack<strong>in</strong>ess agents – For applications where the oil needs to adhere to the<br />

surface extremely well. Examples are polymers <strong>of</strong> e.g. alum<strong>in</strong>ium soaps<br />

<strong>of</strong> long-cha<strong>in</strong> fatty acids.<br />

• Antiwear agents (AW) – AW agents are polar molecules that b<strong>in</strong>d or<br />

attach themselves to metal surfaces. In this way they form a layer that<br />

protects the metal surface from wear that can occur dur<strong>in</strong>g boundary<br />

lubrication conditions e.g. direct contact between asperities. This reduces<br />

friction and wear up to 250°C. Anti-wear improvements can be achieved<br />

from add<strong>in</strong>g sulphurised fatty acids to the base oil (Cao et al., 2000).<br />

• Detergents and dispersant – Are added to a lubricant to keep compounds<br />

and substances dissolved <strong>in</strong> the liquid and avoid<strong>in</strong>g a deposition onto<br />

metal surfaces.<br />

• Compounded oil – A m<strong>in</strong>eral oil that is blended with animal or vegetable<br />

oil <strong>in</strong> order to improve its performance as a lubricant.<br />

2.5.2 Performance-Enhanc<strong>in</strong>g additives<br />

• Pour-po<strong>in</strong>t depressants – The temperature where an oil does not pour or<br />

flow any more is referred to as the pour po<strong>in</strong>t. Molecules such as paraff<strong>in</strong><br />

<strong>wax</strong>es tend to solidify and stiffen at low temperatures. Pour po<strong>in</strong>t<br />

depressants reduce the size and cohesiveness <strong>of</strong> these crystal<br />

structures, which reduces the pour po<strong>in</strong>t <strong>of</strong> the base oil and <strong>in</strong>creases<br />

flow at lower temperatures.<br />

• Viscosity <strong>in</strong>dex (VI) improvers – VI improvers are used to limit the rate <strong>of</strong><br />

change <strong>of</strong> viscosity with temperature. Their effects are generally<br />

observed at higher temperatures where they allow the viscosity <strong>of</strong> the oil<br />

to <strong>in</strong>crease with<strong>in</strong> a limited range permitted by the oils and the<br />

concentration <strong>of</strong> the additive.<br />

• Emulsifiers – Soluble oil requires that water can be emulsified rapidly and<br />

form stable emulsions. Emulsifiers are used <strong>in</strong> lubricants used for cutt<strong>in</strong>g,<br />

gr<strong>in</strong>d<strong>in</strong>g, and drill<strong>in</strong>g applications <strong>in</strong> mach<strong>in</strong>e shops.<br />

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