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2007 Graduate Catalog and 2006 Annual R & D Report - Sirindhorn ...

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<strong>2007</strong> <strong>Graduate</strong> <strong>Catalog</strong> <strong>and</strong> <strong>2006</strong> <strong>Annual</strong> R & D <strong>Report</strong><br />

<strong>Sirindhorn</strong> International Institute of Technology (SIIT)<br />

Both linear <strong>and</strong> nonlinear optical properties of<br />

ferroelectrics can also be studied in the framework of<br />

this phenomenological theory by introducing L<strong>and</strong>au-<br />

Khalatnikov equations to model the dynamical<br />

interaction of a ferroelectric material with an incident<br />

electromagnetic beam. The resonance frequency of<br />

ferroelectrics is in the infrared; linear far infrared<br />

spectroscopy can be used as a probe of the thin-film<br />

properties of ferroelectrics. Many interesting nonlinear<br />

effects can also arise. Important applications in this<br />

area are terrahertz wave devices, tunable infrared<br />

sources, <strong>and</strong> parametric amplifiers.<br />

Nanotechnology <strong>and</strong> Nanoscience<br />

This is currently one of the most exciting areas of<br />

research, with great promise for future technologies.<br />

The programme of research of interest is to model<br />

nanoscale structures <strong>and</strong> from there start to model<br />

<strong>and</strong> propose devices that exploit the properties of<br />

these structures. The key point about the nanoscale<br />

is that quantum properties become much more<br />

apparent than at larger scales. This means that the<br />

technology <strong>and</strong> devices of the future will become<br />

increasingly linked to basic physics. Therefore it is<br />

essential to study the physics of these structures <strong>and</strong><br />

devices. A variety of theoretical <strong>and</strong> computational<br />

techniques, such as density function theory,<br />

molecular dynamics <strong>and</strong> Monte Carlo simulation, are<br />

available to study the quantum properties. Single<br />

processor computers can be used for some problems,<br />

whereas for more computationally intensive problems<br />

a cluster of computers can be employed for parallel<br />

processing.<br />

Dr. Pakorn Opaprakasit<br />

Assistant Professor<br />

B.Sc. (1 st Class Honors) in Chemistry, Chiang Mai University, Thail<strong>and</strong>.<br />

M.S. in Materials Science <strong>and</strong> Engineering (Polymer Option), the Pennsylvania State University,<br />

Pennsylvania, USA.<br />

Ph.D. in Materials Science <strong>and</strong> Engineering, the Pennsylvania State University, Pennsylvania, USA.<br />

Areas of Specialization: Infrared spectroscopy, Rapid prototyping, Natural rubber,<br />

Biocompatible/biodegradable polymers, Lactide-based polyesters, Coal/fossil fuels, Biodiesel.<br />

Research Interests:<br />

Properties Enhancement of Polylactide <strong>and</strong><br />

Natural Rubber for Multicolor Articles Rapid<br />

Prototyping<br />

The work is aiming to enhance properties of<br />

polylactide <strong>and</strong> natural rubber, <strong>and</strong> to setup a<br />

processing methodology to manufacture multicolor<br />

articles from the two economically significant raw<br />

materials of Thail<strong>and</strong>. Rapid prototyping (RP) is<br />

employed to reduce design <strong>and</strong> development time by<br />

fabricating parts layer-by-layer. Natural rubber is<br />

used in latex form, while polylactide is applied in<br />

powder form. Various properties of these materials<br />

are modified to be used in the RP process. Mixing<br />

behavior of colorants <strong>and</strong> base materials (polylactide<br />

<strong>and</strong> natural rubber) is also investigated to develop an<br />

in-process technique of producing colored parts.<br />

Thermal Properties <strong>and</strong> Degradation of<br />

Polylactide<br />

Polylactic acid or polylactides (PLA) are well known<br />

as a biodegradable <strong>and</strong> biocompatible thermoplastic<br />

<strong>and</strong> are of interest in various medical applications.<br />

Their enzymatic degradability <strong>and</strong> mechanical<br />

properties, which are comparable to those of PE <strong>and</strong><br />

PS, have also attracted interest in using these<br />

degradable polymers as packaging materials. Most<br />

importantly, the monomer constituents of these<br />

polymers can be derived from agricultural resources<br />

such as carbohydrates. A racemic crystal structure or<br />

stereocomplex can be achieved by mixing two<br />

polylactides with opposite configurations: poly L-<br />

lactide (L-PLA) <strong>and</strong> poly D-lactide (D-PLA). This<br />

stereocomplex, in turn, shows a higher melting<br />

temperature than that of its homopolymer counterpart.<br />

Accordingly, this stereocomplex has been used as a<br />

potential high performance biodegradable material.<br />

Current research is focused on the mechanism <strong>and</strong><br />

dynamics of crystallization <strong>and</strong> degradation<br />

processes of these polylactides <strong>and</strong> their<br />

stereocomplex.<br />

Conventional <strong>and</strong> Two-Dimensional FTIR<br />

Spectroscopy<br />

Infrared spectroscopy is a fundamental analytical<br />

technique that is widely used in material<br />

characterization. Recently, an advanced<br />

methodology, two-dimensional infrared spectroscopy<br />

(2D-FTIR) has been developed as a novel data<br />

analysis <strong>and</strong> presentation technique. This technique<br />

has provided notable advantages over conventional<br />

FTIR. For example, an improvement in b<strong>and</strong><br />

resolution, simplicity in b<strong>and</strong> assignment, <strong>and</strong><br />

determination of relative order of responses of<br />

specific functional groups to external perturbation,<br />

have been achieved. The 2D-FTIR has been applied<br />

to study effects of mechanical <strong>and</strong> electrical<br />

perturbations on the structural transition of<br />

PVDF/TrFE/CTFE piezoelectric polymer, <strong>and</strong><br />

investigate crystallization of biodegradable polymer or<br />

polylactide.<br />

39

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