Juraj Varga - Prof. Per Jensen, Ph.D.
Juraj Varga - Prof. Per Jensen, Ph.D.
Juraj Varga - Prof. Per Jensen, Ph.D.
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FSO 3<br />
• radical<br />
The molecular parameters of the fluorosulfate radical in the vibronic ground state a,b,c .<br />
Parameter<br />
without hyperfine splitting<br />
with hyperfine splitting<br />
B<br />
5195.528365 (259)<br />
5195.528364 (291)<br />
D N<br />
×10 3 3.76291 (60)<br />
3.76287 (64)<br />
D NK<br />
×10 3 −1.28189 (131)<br />
−1.28162 (183)<br />
H N<br />
×10 9 −6.75 (44)<br />
−6.83 (46)<br />
H NK<br />
×10 6 0.18816 (127)<br />
0.18872 (156)<br />
H KN<br />
×10 6 −0.34627 (194)<br />
−0.34765 (307)<br />
h 3<br />
×10 9 6.640 (21) b<br />
6.640 (21) b<br />
ε aa<br />
−37.372 (59)<br />
−37.344 (67)<br />
ε bb<br />
−271.9178 (189)<br />
−271.8446 (265)<br />
D S N ×103 −0.9931 (73)<br />
−1.0123 (90)<br />
D S NK<br />
−0.0696 (188)<br />
−0.0616 (228)<br />
D S KN<br />
0.0725 (190)<br />
0.0646 (230)<br />
D S K ×103 −1.628 (275)<br />
−1.58 (37)<br />
a F<br />
…<br />
−24.1 (45)<br />
1.5 T aa<br />
…<br />
−2.628 (288)<br />
s c 0.014<br />
0.014<br />
a All the data are in MHz. The numbers in parentheses<br />
are standard deviations in the units of the last decimal<br />
digit. The frequencies of the K = 3 doublets are<br />
averaged.<br />
b Fitted separately.<br />
c The symbol s denotes a standard deviation of the fit.<br />
‣L.<br />
Kolesniková, , J. <strong>Varga</strong>, L. Nová Střítesk<br />
teská, , H. Beckers, , H.<br />
Wilner, , F. Aubke, and Š. . Urban: The Ground State Rotational<br />
Spectrum of the Fluorosulfate Radical, , J. Chem. <strong>Ph</strong>ys.,<br />
Accepted 2009.<br />
QUASAAR Winter School, February 20-25, 25, 2009 Demänovsk<br />
novská Dolina - Jasná, , Slovakia
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