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An Introduction to Functional Groups in Organic Chemistry What are ...

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Thiols and Am<strong>in</strong>es<br />

CH 3<br />

H<br />

H 3C C<br />

OH<br />

CH 3<br />

H<br />

H 3C C CH 3<br />

SH<br />

H<br />

H 3C C<br />

NH 2<br />

OH<br />

alcohols<br />

SH<br />

thiols<br />

CH 3<br />

N<br />

am<strong>in</strong>es<br />

CH 3<br />

Ethers<br />

• The ether functional group is described as<br />

an sp 3 oxygen a<strong>to</strong>m bonded <strong>to</strong> two carbon<br />

a<strong>to</strong>ms, and may be symbolized as R-O-R'.<br />

• R and R' may be the same groups or<br />

different.<br />

CH 3 CH 2 O CH 2 CH CH O<br />

3 3<br />

CH 3<br />

C<br />

CH 3<br />

CH 3<br />

O<br />

Carbonyl-Conta<strong>in</strong><strong>in</strong>g <strong>Functional</strong><br />

<strong>Groups</strong><br />

• A carbonyl group is made up of a carbon a<strong>to</strong>m<br />

double bonded <strong>to</strong> an oxygen a<strong>to</strong>m. The carbon<br />

a<strong>to</strong>m is not bonded <strong>to</strong> any other heteroa<strong>to</strong>m.<br />

O<br />

C<br />

the carbonyl group<br />

• We will not consider the carbonyl group <strong>to</strong> be a<br />

functional group <strong>in</strong>-and-of itself; rather, it is the<br />

essential portion of two functional groups:<br />

aldehydes and ke<strong>to</strong>nes.<br />

Ke<strong>to</strong>nes<br />

• The ke<strong>to</strong>ne functional group conta<strong>in</strong>s a carbonyl<br />

group, with the carbon of that group bonded <strong>to</strong><br />

two other carbon a<strong>to</strong>ms.<br />

• R and R' may or may not be the same.<br />

R<br />

O<br />

C<br />

R'<br />

a ke<strong>to</strong>ne<br />

4

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