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SYSTEMATIC APPROACH TO WATER TREATMENT PLANT PROCESS<br />

OPTIMIZATION AND WHY SHOULD SURFACE WATER TREATMENT<br />

PLANTS MONITOR UV254 IN SOURCE WATER<br />

Alex Yavich, Ph.D., P.E.<br />

Optimization Solutions Environmental, LLC


What Will Be Discussed<br />

‣ Chemical feed rate optimization<br />

‣ Coagulant choice<br />

‣ Rapid and flocculation mixing<br />

‣ UV254 moni<strong>to</strong>ring


Chemical Feed Rate Optimization<br />

‣ Ensuring adequate chemical feed rates under all plant<br />

conditions is the first step in water plant process optimization<br />

‣ Optimization of chemical feed rates not only improves<br />

effluent quality and reduce chemical usage, but also helps<br />

identify other potential areas for improvement


Coagulation Feed Optimization<br />

Optimization<br />

goal<br />

Computer models can be developed <strong>to</strong> provide real time advisement <strong>to</strong> the<br />

opera<strong>to</strong>rs of the optimal chemical feed rates under various plant conditions


Case 1<br />

Three Rivers Filtration <strong>Plant</strong>, Fort Wayne, IN<br />

• Total capacity: 72 MGD<br />

• Source water: St. Joseph River


Case 1: Raw <strong>Water</strong> Quality


Case 1: <strong>Treatment</strong> train<br />

Fe 2 (SO 4 ) 3<br />

Lime<br />

PAC<br />

Fe 2 (SO 4 ) 3<br />

CO 2<br />

Influent<br />

Primary Coagulation /<br />

Lime Softening Stage<br />

Second Coagulation<br />

Stage<br />

Filtration<br />

Effluent


Chemical Feed Control at Fort Wayne <strong>Plant</strong>


Case 1: Chemical feed optimization<br />

1<br />

All costs in 2011 chemical prices


Optimal Coagulant<br />

‣ Optimal coagulant is the coagulant that best meets<br />

plant’s operational goals<br />

‣ By choosing the right coagulant, a water treatment<br />

plant can significantly improve its process<br />

performance and the quality of finished water


What are the Choices<br />

‣ Metal salts<br />

Turbidity removal through charge neutralization and sweep coagulation<br />

of colloidal particles<br />

Commonly used coagulants: alum, ferric sulfate, ferric chloride,<br />

polyaluminum chloride<br />

‣ Cationic polymers<br />

Charge neutralization is major coagulation mechanism<br />

Wide range of products available


Optimal Coagulant: Major Considerations<br />

‣ Raw water quality: turbidity, pH, alkalinity, NOM etc.<br />

‣ Operational objectives: effluent quality, chemical cost,<br />

sludge production, filter run etc.<br />

‣ <strong>Plant</strong> size<br />

‣ <strong>Treatment</strong> train: lime softening, UV disinfection etc.<br />

‣ Hardware: floccula<strong>to</strong>rs (variable/constant speed), clarifiers<br />

(conventional basins, upflow clarifiers, plate settlers etc.), filter<br />

configuration (media type, size, support etc.)


Case 2<br />

Holland <strong>Water</strong> <strong>Treatment</strong> <strong>Plant</strong><br />

Holland, MI<br />

Capacity:<br />

Source water:<br />

38.5 MGD<br />

Lake Michigan


Case 2: Raw <strong>Water</strong> Quality<br />

Raw <strong>Water</strong> Parameters<br />

Typical Range<br />

Temperature, o F<br />

32 – 77<br />

Alkalinity, mg/L as CaCO 3<br />

100 – 145<br />

Turbidity, NTU<br />

0.3 – 40<br />

Total <strong>org</strong>anic carbon, mg/L<br />

1.6 – 2.5<br />

UV254, cm -1 0.01 – 0.2


Case 2: Holland WTP Schematic<br />

Cl<br />

Coagulant<br />

Raw<br />

water<br />

Low lift pump<br />

MIxing<br />

Chamber<br />

Flocculation<br />

Basins<br />

Settling basins<br />

Filters<br />

Cl<br />

Treated<br />

water<br />

Clearwell<br />

High lift<br />

pumps


Operational Goal<br />

• Alum was his<strong>to</strong>rically employed for coagulation<br />

• Sludge production was problematic<br />

• Goal – reduce sludge production


Alternative Coagulants Tested<br />

• PACl<br />

• Alumer (a premanufactured blend of alum and cationic<br />

polymer)<br />

• “Seasonal” coagulation practice<br />

– Alum: December thru April<br />

– Alumer: May thru November


Coagulation Computer Models at HWTP


Results of Full-Scale Testing and<br />

Computer Simulation Analysis<br />

• PACl<br />

– Sludge could be reduced by up <strong>to</strong> 45 percent<br />

– Cost would increase by appr. 20%<br />

– Potential turbidity problems on four Integral Media Support (IMS)<br />

cap filters<br />

• Alumer<br />

– Sludge could be reduced by up <strong>to</strong> 35 percent<br />

– Cost would increase by 5-15%<br />

– Not cost effective at increased UV254<br />

• “Seasonal” coagulation practice<br />

– Sludge could be reduced by up <strong>to</strong> 25 percent<br />

– No cost increase (compared <strong>to</strong> alum)<br />

– More complex operation


<strong>Plant</strong>’s Best Choice (current practice)<br />

Alum and Cationic Polymer (fed separately)<br />

• Sludge reduced by up <strong>to</strong> 35 percent<br />

• Expected cost reduction by 25 - 30 percent (compared <strong>to</strong> alumer)<br />

• Consistent filtered turbidity<br />

• Improved operational control<br />

• Can be optimized <strong>to</strong> meet plant’s future goals


What Affected the Choice of Coagulant at HWTP<br />

• Raw water quality: turbidity and NOM<br />

• Operational goals: sludge production, effluent quality, chemical costs<br />

• <strong>Treatment</strong> train: sedimentation basins, filter configuration, feeding<br />

equipment


Rapid and Flocculation Mixing<br />

Raw<br />

water<br />

Low lift<br />

pump<br />

Coagulant<br />

Mixing<br />

Chamber<br />

Flocculation<br />

Basin<br />

Settling basin<br />

Mixing Intensity (G-value)<br />

G = (P/μV) 1/2<br />

G – velocity gradient, s -1<br />

P – power input, ft·lb/s<br />

µ – dynamic viscosity, ft·s/ft 2<br />

V – volume, ft 3


Rapid and Flocculation Mixing<br />

Raw<br />

water<br />

Low lift<br />

pump<br />

Coagulant<br />

Mixing<br />

Chamber<br />

Flocculation<br />

Basin<br />

Settling basin<br />

Operation Mixing Time G value, s -1<br />

Rapid mixing 1 – 60 sec 600 - 1500<br />

Flocculation 20 – 30 min 40 - 70


Case 3<br />

St. Joseph <strong>Water</strong> Filtration <strong>Plant</strong><br />

St. Joseph, MI<br />

Capacity:<br />

Source water:<br />

Raw turbidity:<br />

<strong>Treatment</strong>:<br />

12 MGD<br />

Lake Michigan<br />

1 – 60 NTU<br />

Alum coagulation<br />

No rapid mixer


Case 3: <strong>Plant</strong> Schematic<br />

Cl<br />

NaOH<br />

Alum<br />

Raw<br />

water<br />

Low lift pump<br />

Sludge<br />

Drain<br />

Accela<strong>to</strong>r Clarifiers (3)<br />

Filters<br />

Cl<br />

Treated<br />

water<br />

Clearwell<br />

High lift<br />

pumps


Case 3: Rapid Mixing Analysis<br />

Type MIxing time, s G value, s -1<br />

St. Joseph plant<br />

(hydraulic mixing in the pipe)<br />

10 - 60 100 - 400<br />

Mechanical mixers<br />

(for comparison) 10 - 60 600 - 1000<br />

In-line blenders<br />

(for comparison) 0.5 - 1 1000 - 1500


Case 3: Computer simulation analysis


Case 3: Effect of coagulant mixing


Case 4<br />

Holland <strong>Water</strong> <strong>Treatment</strong> <strong>Plant</strong><br />

Holland, MI<br />

Capacity:<br />

Source water:<br />

38.5 MGD<br />

Lake Michigan


Case 4: Effect of Flocculation Mixing on Filtered<br />

Turbidity


<strong>Water</strong> Quality Moni<strong>to</strong>ring: UV254<br />

‣ UV254 is a measure of ultraviolet absorption at a wavelength<br />

of 254 nm<br />

‣ UV254 is a surrogate measure of natural <strong>org</strong>anic matter<br />

(NOM) in water


Why Should Surface <strong>Water</strong> <strong>Treatment</strong> <strong>Plant</strong>s<br />

Moni<strong>to</strong>r UV254 in Raw <strong>Water</strong><br />

Coagulation<br />

Filtration<br />

Clarification<br />

UV254<br />

DBP control<br />

Taste and Odor<br />

Control<br />

Disinfection


Case 5: Effect of UV254 on coagulant demand<br />

Lake Michigan Filtration <strong>Plant</strong>, Grand Rapids, MI<br />

Capacity – 130 MGD<br />

Source – Lake Michigan


Case 6: Effect of UV254 on effluent turbidity<br />

South Haven <strong>Water</strong> <strong>Treatment</strong> <strong>Plant</strong>, South Haven, MI<br />

Capacity – 4 MGD<br />

Source – Lake Michigan


UV254 Analysis is Fast and Simple


Benefits of UV254 Moni<strong>to</strong>ring<br />

‣ Improved chemical feed control<br />

‣ Consistent effluent turbidity<br />

‣ Reduced chemical costs<br />

‣ Important fac<strong>to</strong>r in identifying the “optimal”<br />

coagulant<br />

‣ Improved DBP control<br />

‣ Helps optimize UV disinfection


Summary<br />

Ensure that chemical feed rates are satisfac<strong>to</strong>ry under all<br />

plant conditions<br />

Does the plant use the right coagulant<br />

Verify that rapid mixing operation is adequate<br />

Adjust, if possible, flocculation speed at least seasonally<br />

Implement raw water UV254 moni<strong>to</strong>ring (surface WTPs)


Q&A<br />

Alex Yavich<br />

Ph. (616) 975-0847<br />

E-mail: yavichal@osenv.com<br />

Web: www.osenv.com

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