SAFETY DATA SHEET - Granville Oil & Chemicals Ltd
SAFETY DATA SHEET - Granville Oil & Chemicals Ltd
SAFETY DATA SHEET - Granville Oil & Chemicals Ltd
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<strong>SAFETY</strong> <strong>DATA</strong> <strong>SHEET</strong><br />
according to 1907/2006/EC, Article 31<br />
Smooth Paint - Blue<br />
SECTION 1: Identification of the substance/mixture and of the company/undertaking<br />
1.1. Product identifier<br />
Product name<br />
Smooth Paint - Blue<br />
1.3. Details of the supplier of the safety data sheet<br />
Company<br />
Address<br />
<strong>Granville</strong> <strong>Oil</strong> & <strong>Chemicals</strong> <strong>Ltd</strong><br />
29 Goldthorpe Industrial Estate<br />
Goldthorpe, Rotherham,<br />
S63 9BL ENGLAND<br />
Telephone +44 (0) 1709 890099<br />
Fax +44 (0) 1709 891121<br />
1.4. Emergency telephone number<br />
Emergency telephone<br />
number<br />
+44 (0)1709 890099<br />
830am - 5.00pm Monday - Friday<br />
Revision<br />
Revision date<br />
Page 1/5<br />
2<br />
2013-10-08<br />
SECTION 2: Hazards identification<br />
2.1. Classification of the substance or mixture<br />
2.1.1. Classification -<br />
1999/45/ЕC<br />
Main hazards<br />
2.2. Label elements<br />
Symbols<br />
N; R51/53 R10-66<br />
Symbols: N: Dangerous for the environment.<br />
Flammable. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic<br />
environment. Repeated exposure may cause skin dryness or cracking.<br />
N: Dangerous for the environment.<br />
Risk phrases<br />
Safety phrases<br />
R10 - Flammable.<br />
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic<br />
environment.<br />
R66 - Repeated exposure may cause skin dryness or cracking.<br />
S2 - Keep out of the reach of children.<br />
S3 - Keep in a cool place.<br />
S16 - Keep away from sources of ignition - No smoking.<br />
S24/25 - Avoid contact with skin and eyes.<br />
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical<br />
advice.<br />
S29 - Do not empty into drains.<br />
SECTION 3: Composition/information on ingredients<br />
3.2. Mixtures<br />
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3.2. Mixtures<br />
67/548/EEC / 1999/45/EC<br />
Smooth Paint - Blue<br />
Revision<br />
Revision date<br />
Page<br />
2/5<br />
2<br />
2013-10-08<br />
Chemical Name Index No. CAS No. EC No. REACH Registration Conc. Classification<br />
Number<br />
(%w/w)<br />
Heavy Hydrodelsufurized naptha<br />
64742-82-1 265-185-4 30 - 40% Xn; R65 N; R51/53 R10-66<br />
(petrol<br />
Xylene (Xylene, o-,m-,-p-or mixed 601-022-00-9 1330-20-7 215-535-7 0 - 0.5% R10 Xn; R20/21 Xi; R38<br />
isomers)<br />
Cyclohexanone 606-010-00-7 108-94-1 203-631-1 0 - 0.5% R10 Xn; R20<br />
White Spirit 64742-88-7 265-191-7 1 - 10% Xn; R65 N; R51/53 R10-66<br />
Ethylbenzene 601-023-00-4 100-41-4 202-849-4 0 - 0.5% F; R11 Xn; R20<br />
Iso-butanol (2-Methylpropan-1-ol) 603-108-00-1 78-83-1 201-148-0 0 - 0.5% R10 Xi; R37/38-41 R67<br />
titanium dioxide (Titanium dioxide<br />
total inhalable)<br />
13463-67-7 236-675-5 1 - 10%<br />
SECTION 4: First aid measures<br />
4.1. Description of first aid measures<br />
Inhalation<br />
Eye contact<br />
Skin contact<br />
Ingestion<br />
SECTION 5: Firefighting measures<br />
5.1. Extinguishing media<br />
Irritating to respiratory system. Inhalation may cause coughing, tightness of the chest and irritation<br />
of the respiratory system. Move the exposed person to fresh air. Seek medical attention.<br />
Irritating to eyes. Rinse immediately with plenty of water for 15 minutes holding the eyelids open.<br />
Seek medical attention if irritation or symptoms persist.<br />
Irritating to skin. Wash off immediately with plenty of soap and water. Remove contaminated<br />
clothing. Seek medical attention if irritation or symptoms persist.<br />
Ingestion may cause nausea and vomiting. Seek medical attention if irritation or symptoms<br />
persist. DO NOT INDUCE VOMITING.<br />
Carbon oxides.<br />
5.2. Special hazards arising from the substance or mixture<br />
5.3. Advice for firefighters<br />
SECTION 6: Accidental release measures<br />
Burning produces irritating, toxic and obnoxious fumes.<br />
Self-contained breathing apparatus. Wear protective clothing.<br />
6.1. Personal precautions, protective equipment and emergency procedures<br />
6.2. Environmental precautions<br />
6.3. Methods and material for containment and cleaning up<br />
SECTION 7: Handling and storage<br />
7.1. Precautions for safe handling<br />
7.2. Conditions for safe storage, including any incompatibilities<br />
Ensure adequate ventilation of the working area. Wear suitable protective equipment. Eliminate all<br />
sources of ignition. Evacuate personnel to a safe area.<br />
Do not allow product to enter drains. Prevent further spillage if safe.<br />
Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labelled containers for<br />
disposal. Clean spillage area thoroughly with plenty of water.<br />
Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Use explosion<br />
proof equipment. Keep away from sources of ignition - No smoking.<br />
Keep in a cool, dry, well ventilated area. Keep containers tightly closed. Store in correctly labelled<br />
containers.<br />
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SECTION 8: Exposure controls/personal protection<br />
8.1. Control parameters<br />
Smooth Paint - Blue<br />
Revision<br />
Revision date<br />
Page 3/5<br />
2<br />
2013-10-08<br />
8.1.1. Exposure Limit Values<br />
Cyclohexanone WEL 8-hr limit ppm: 10 WEL 8-hr limit mg/m3: -<br />
WEL 15 min limit ppm: 20 WEL 15 min limit mg/m3: -<br />
Ethylbenzene WEL 8-hr limit ppm: 100 WEL 8-hr limit mg/m3: 441<br />
Iso-butanol<br />
(2-Methylpropan-1-ol)<br />
titanium dioxide (Titanium<br />
dioxide respirable)<br />
titanium dioxide (Titanium<br />
dioxide total inhalable)<br />
Xylene (Xylene, o-,m-,-p-or<br />
mixed isomers)<br />
SECTION 9: Physical and chemical properties<br />
9.1. Information on basic physical and chemical properties<br />
9.2. Other information<br />
State<br />
Liquid<br />
Colour Blue<br />
Odour Characteristic<br />
Flash point 37 °C<br />
Relative density<br />
WEL 15 min limit ppm: 125 WEL 15 min limit mg/m3: 552<br />
WEL 8-hr limit ppm: 50 WEL 8-hr limit mg/m3: 154<br />
WEL 15 min limit ppm: 75 WEL 15 min limit mg/m3: 231<br />
WEL 8-hr limit ppm: - WEL 8-hr limit mg/m3: 4<br />
WEL 15 min limit ppm: - WEL 15 min limit mg/m3: -<br />
WEL 8-hr limit ppm: - WEL 8-hr limit mg/m3: 10<br />
WEL 15 min limit ppm: - WEL 15 min limit mg/m3: -<br />
WEL 8-hr limit ppm: 50 WEL 8-hr limit mg/m3: 220<br />
WEL 15 min limit ppm: 100 WEL 15 min limit mg/m3: 441<br />
0.994 (Water = 1 @ 20 °C)<br />
Viscosity 280 sec. 3 mm (ISO 2431)<br />
Solubility<br />
VOC (Volatile organic<br />
compounds)<br />
Insoluble in water<br />
417 g/l<br />
SECTION 10: Stability and reactivity<br />
10.2. Chemical stability<br />
10.3. Possibility of hazardous reactions<br />
10.4. Conditions to avoid<br />
Stable under normal conditions.<br />
Oxidising agents.<br />
SECTION 11: Toxicological information<br />
11.1. Information on toxicological effects<br />
Acute toxicity<br />
11.1.13. Other information<br />
SECTION 12: Ecological information<br />
Further information<br />
Heat, sparks and open flames.<br />
R66 - Repeated exposure may cause skin dryness or cracking.<br />
Vapours may cause drowsiness and dizziness.<br />
Do not allow product to enter drains. Dispose of in compliance with all local and national<br />
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Further information<br />
regulations.<br />
SECTION 13: Disposal considerations<br />
General information<br />
Dispose of in accordance with local and national regulations.<br />
SECTION 14: Transport information<br />
Hazard pictograms<br />
14.1. UN number<br />
14.2. UN proper shipping name<br />
14.3. Transport hazard class(es)<br />
ADR/RID 3<br />
Subsidiary risk -<br />
IMDG 3<br />
Subsidiary risk -<br />
IATA 3<br />
Subsidiary risk -<br />
14.4. Packing group<br />
Packing group<br />
14.5. Environmental hazards<br />
Environmental hazards<br />
Marine pollutant<br />
ADR/RID<br />
UN1263<br />
PAINT<br />
III<br />
No<br />
No<br />
Hazard ID 30<br />
Tunnel Category<br />
IMDG<br />
EmS Code<br />
IATA<br />
(D/E)<br />
Packing Instruction (Cargo) 366<br />
Maximum quantity<br />
Packing Instruction<br />
(Passenger)<br />
Maximum quantity<br />
F-E S-E<br />
220 L<br />
355<br />
60 L<br />
SECTION 15: Regulatory information<br />
SECTION 16: Other information<br />
Other information<br />
Revision<br />
This document differs from the previous version in the following areas:.<br />
15 - Safety phrases.<br />
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Other information<br />
Text of risk phrases in<br />
Section 3<br />
Maximum content of VOC<br />
Smooth Paint - Blue<br />
Revision<br />
Revision date<br />
R10 - Flammable<br />
R11 - Highly flammable.<br />
R20/21 - Harmful by inhalation and in contact with skin.<br />
R20 - Harmful by inhalation.<br />
R37/38 - Irritating to respiratory system and skin.<br />
R38 - Irritating to skin.<br />
R41 - Risk of serious damage to eyes.<br />
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic<br />
environment.<br />
R65 - Harmful: may cause lung damage if swallowed.<br />
R66 - Repeated exposure may cause skin dryness or cracking.<br />
R67 - Vapours may cause drowsiness and dizziness.<br />
417 g/l.<br />
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