15.01.2015 Views

Aste T., Weaire D. Pursuit of perfect packing (IOP 2000)(147s).pdf

Aste T., Weaire D. Pursuit of perfect packing (IOP 2000)(147s).pdf

Aste T., Weaire D. Pursuit of perfect packing (IOP 2000)(147s).pdf

SHOW MORE
SHOW LESS

Create successful ePaper yourself

Turn your PDF publications into a flip-book with our unique Google optimized e-Paper software.

22 Hard problems with hard spheres<br />

(a)<br />

(b)<br />

Figure 3.2. Bernal <strong>packing</strong> <strong>of</strong> spheres.<br />

variety. He also recognized the difficulty <strong>of</strong> doing so, other than by direct observation<br />

<strong>of</strong> a model system. Why not ball bearings He called this unsophisticated<br />

approach ‘a new way <strong>of</strong> looking’ at liquids.<br />

Hence the shaking and kneading <strong>of</strong> ball bearings in a bag, the pouring in <strong>of</strong><br />

wax, the meticulous measurement <strong>of</strong> the positions <strong>of</strong> balls as the random cluster<br />

was disassembled. The <strong>packing</strong> fraction <strong>of</strong> the Bernal <strong>packing</strong> was found to be<br />

roughly 0.64; or slightly less if the balls are not kneaded to encourage them to<br />

come together closely. Although particular local arrangements recur within it,<br />

they are variable in shape and random in distribution 2 .<br />

Subsequently, the chief scientific interest <strong>of</strong> the Bernal structure has been<br />

in its application to describe the structures <strong>of</strong> amorphous (i.e. non-crystalline)<br />

metals.<br />

Si l’ordre satisfait la raison,<br />

le désordre fait les délices de l’imagination.<br />

Paul Claudel (1868–1955)<br />

3.3 A new way <strong>of</strong> looking<br />

Desmond Bernal, born in 1901 on an Irish farm, was one <strong>of</strong> the prime movers <strong>of</strong><br />

modern crystallography and biophysics. He is thought to have narrowly missed<br />

a Nobel Prize for his work on sex hormones. This would have been singularly<br />

appropriate for a man whose sexual appetite was rumoured to be prodigious. This<br />

¾ Bernal J D and Mason J 1960 Co-ordination <strong>of</strong> randomly packed spheres Nature 385 910–11.

Hooray! Your file is uploaded and ready to be published.

Saved successfully!

Ooh no, something went wrong!