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<strong>Ecological</strong> <strong>Risk</strong> <strong>Assessment</strong><br />

ESM 223<br />

<strong>Ecological</strong> <strong>Risk</strong><br />

<strong>Assessment</strong><br />

Process to evaluate likelihood of adverse<br />

ecological effects as result of exposure to<br />

one or more stressors<br />

Function of ERA<br />

document whether actual or potential<br />

ecological risk exists at a site<br />

screen contaminants present at a site for<br />

those that pose an ecological risk<br />

generate information to evaluate options<br />

How is ERA regulated<br />

USEPA’s Responsibilities<br />

Part of RCRA and CERCLA<br />

set standards, take action<br />

Strengthened by SARA<br />

cleanup levels and remedial alternatives<br />

National Contingency Plan (NCP)<br />

implementation of CERCLA & SARA regulations<br />

remediation goals based on applicable or relevant and<br />

appropriate requirements (ARAR)<br />

Directed by regulatory and resource agencies<br />

USEPA<br />

Dept of Toxic Substances Control<br />

Regional Water Quality Board<br />

Section 404 of Clean Water Act<br />

Federal Water Quality Control Act<br />

Clean Air Act<br />

Toxic Substances Control Act<br />

Federal Insecticide, Fungicide and Rodenticide Act<br />

Endangered Species Act<br />

Section 662(a) and 2903 of Fish & Wildlife Conservation<br />

Act<br />

Coastal Zone Management Act<br />

Section 2171 of Wild and Scenic Rivers Act<br />

Migratory Bird Treaty Act<br />

Steps in ERA Process<br />

Screening Level <strong>Risk</strong> <strong>Assessment</strong><br />

Problem Formulation<br />

assessment endpoints<br />

conceptual model(s)<br />

analysis plan<br />

Analysis<br />

<strong>Ecological</strong> Exposure and Effects<br />

<strong>Risk</strong> Characterization<br />

Estimation and description<br />

<strong>Risk</strong> Management<br />

Decision making<br />

Simplified risk assessments<br />

Make rapid decisions early in the<br />

process<br />

Divide sites into<br />

Sites that present significant immediate<br />

ecological risk and require early remedial<br />

action<br />

Sites with no ecological risk, requiring no<br />

further action<br />

Sites that require further study


Screening ERA<br />

Tools in an ERA<br />

For the screening level<br />

<strong>Assessment</strong> endpoints must be explicit<br />

Measurable endpoints must be a measurable<br />

ecological characteristic - related to<br />

assessment endpoint<br />

Determine whether exposure is or may be<br />

above the levels where adverse ecological<br />

effects might be expected<br />

Establish exposure pathways of concern<br />

Environmental Chemistry<br />

Determine contaminant fate and transport<br />

Literature-based ecotoxicological data<br />

NOAEL<br />

LOAEL<br />

Ecotox information sources<br />

AQUIRE Database<br />

PHYTOTOX Database<br />

Integrated <strong>Risk</strong> Information System (IRIS)<br />

Hazardous Substances Databank<br />

US FWS Contaminant Hazard Review<br />

ATSDR Toxicological Profiles<br />

Registry of Toxic Effects of Chemical<br />

Substances (RTECS)<br />

Screening Criteria<br />

Water<br />

USEPA Ambient Water Quality Criteria<br />

Water Quality Objectives (CRWQCB, 1986)<br />

Sediments<br />

Sediments Effects Range Data from NOOA (Long & Morgan,<br />

1991)<br />

Sediment Quality Objectives (CRWQCB, 1986)<br />

Washington State Marine Sediments Criteria (WDOE, 1991)<br />

Soils<br />

Quebec Soil Clean-up Criteria (QME, 1988)<br />

Dutch Soil Clean-up Act (Beyer, 1990)<br />

Criteria for Contaminated Soil/Sediment Cleanup (Fitchko, 1989)<br />

ERA Example<br />

NAWS at Point Mugu<br />

Effects of sediment contamination on<br />

organisms near the base<br />

Copper and PCBs are the main concern in this<br />

region<br />

Copper can be acutely or chronically toxic to<br />

various organisms<br />

PCBs bioaccumulate and bioconcentrate,<br />

producing reproductive impairment


Fox River Case Study<br />

Fox River Human Health and <strong>Ecological</strong><br />

<strong>Risk</strong> <strong>Assessment</strong><br />

Executive Summary<br />

Table of Contents<br />

Geographical Setting<br />

Details of ERA<br />

Fox River Case Study<br />

Highlights of Executive Summary<br />

Populations considered<br />

Recreational anglers<br />

Subsistence anglers<br />

Hunters<br />

Drinking water users<br />

Local residents<br />

Recreational water users<br />

Construction workers


Fox River Case Study<br />

Fox River Case Study<br />

Highlights of Executive Summary<br />

Fish contain PCBs<br />

Anglers can have Cancer <strong>Risk</strong>s (CR) up to 1.5<br />

x 10 -3<br />

Hazard Index up to 56<br />

Based on Fish Tissue data from 1990 (study<br />

conducted in 1999)<br />

Highlights of Executive Summary<br />

Potential population exposed<br />

Up to 47,000 recreational anglers<br />

About 2-5,000 subsistence anglers<br />

Cancer risk about the same in the four<br />

reaches considered<br />

Highest risk from carp, followed by perch,<br />

walleye and white bass<br />

Fox River Case Study<br />

Highlights of Executive Summary<br />

<strong>Risk</strong> to hunters ~ 10 -4 (PCB contaminated<br />

waterfowl)<br />

<strong>Risk</strong> to people drinking contaminated water<br />

~10-6 in most contaminated stretch – mostly<br />

from arsenic in water<br />

May require further sampling to determine if<br />

arsenic continues to be a concern<br />

This water is not directly used a drinking source<br />

Fox River Case Study<br />

Sources<br />

Fox River Case Study


Fox River Case Study<br />

Fox River Case Study<br />

Pollutant loading has decreased by 85%<br />

since 1970s<br />

Although PCBs not discharged directly, still<br />

estimated loading of 3-5 kg/year from<br />

landfills and other sources (very low<br />

concentrations)<br />

Non-point sources: eroded particles and<br />

contaminated sediments from small creeks<br />

Fox River Case Study<br />

Transport Processes<br />

Atmospheric transport: contributes 2-16 kg<br />

PCB/yr to Green Bay in snow and rain plus<br />

some dry deposition<br />

Sediment transport: primary mechanism for<br />

moving PCBs through the watershed and river<br />

Fox River contributes > 90% of PCB loading to<br />

Green Bay<br />

Concentrations in water ~50-100 ng/L<br />

Fox River Case Study<br />

Sediment concentrations (from 532<br />

samples!) range from 2 to 222 x 10 3<br />

µg/kg<br />

In Sediment Deposits A, C and POG, total<br />

PCB loading exceeds 50 x 10 3 µg/kg<br />

Reflect specific point sources discharging<br />

PCBs in this region<br />

Fox River Case Study<br />

PCBs in fish tissue have been as high as<br />

26 x 10 3 µg/kg tissue in carp (in 1976)<br />

Have generally dropped about an order of<br />

magnitude in more recent samples<br />

Tissues also contain dioxins, furans,<br />

pesticides (DDT, DDE, Dieldrin), mercury,<br />

lead and arsenic …<br />

See Figures 2.1 to 2.20 in report<br />

Fox River Case Study<br />

Where does the data come to do the risk<br />

assessment


Fox River Case Study<br />

Human Health <strong>Risk</strong> Analysis<br />

Fox River Case Study


Fox River Case Study


Fox River Case Study<br />

<strong>Ecological</strong> <strong>Risk</strong> Analysis


Fox River Case Study<br />

Fox River Case Study<br />

Fox River Case Study<br />

Fox River Case Study


Fox River Case Study<br />

Fox River Case Study<br />

Fox River Case Study

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