Safety data sheet - Lex doo

www.lex.si
Safety data sheet
According to regulation (EC) N o . 1907/2006
KALII PERMANGANAS
Revision date (edition 13): 22.04.2013
Replace version: 21.10.2011
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Product code:
Product name:
1.2 Relevant identified uses of the substance or
mixture and uses advised against
1.3 Details of the supplier of the safety data sheet
Tel.:
Fax:
e-mail:
1.4 Emergency telephone number
0362
POTASSIUM PERMANGANATE
Pharmaceutical product
Lex, d.o.o., Vanganelska c. 26, 6000 Koper
05 625-18-10
05 625-18-12
info@lex.si
In case of poisoning consult your doctor or call Emergency, phone: 112.
2. Hazards identification
2.1 Classification of the substance or mixture
Classification GHS ((EC) No. 1272/2008): Ox. sol, 3
Acute tox.,4
Aquatic acute, 1
Aquatic chronic,1
Classification ES (67/548/EEC, 1999/45/EC):
2.2 Label elements
Labelling GHS ((EC) No. 1272/2008):
Hazard pictograms:
O Oxidative
Xn Harmful
N Harmful to the environment
H272 May intensify fire; oxidiser.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
R8 Contact with combustible material may cause fire.
R22 Harmful if swallowed.
R50/53 Very toxic to aquatic organisms, may cause longterm
adverse effects in the aquatic environment.
Signal word:
Hazard statements:
Precautionary statements:
Danger
H272
H302
H400
H410
P220
P221
P280
P301+P312
P306+P360
P370+P378
P501
2.3 Other hazards None known.
May intensify fire; oxidiser.
Harmful if swallowed.
Very toxic to aquatic life.
Very toxic to aquatic life with long lasting effects.
Keep/Store away from clothing/paper/combustible materials.
Take any precaution to avoid mixing with combustibles…
Wear protective gloves/protective clothing/eye
protection/face protection.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if
you feel unwell.
IF ON CLOTHING: rinse immediately contaminated clothing
and skin with plenty of water before removing clothes.
In case of fire: Use suitable media for extinction (see 5.1).
Dispose of contents/container according to regulations.
3. Composition/Information on ingredients
3.1 Substance
Formula:
KMnO4 POTASSIUM PERMANGANATE
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Lex d.o.o. • Vanganelska c. 26 • SI-6000
Koper
tel.: +386 5 625 18 10 • fax: +386 5 625 18
12
www.lex.si • www.lexarna.si

Safety data Sheet (according to Regulation (EC) no. 1907/2006)
KALII PERMANGANAS
product code: 0362
Molar mass:
158 g/mol
CAS: 7722-64-7
EINECS: 231-760-3
Index: 025-002-00-9
Concentration: 100 %
3.2 Mixtures No information available.
4. First aid measures
4.1 Description of first aid measures
Inhalation:
Skin contact:
Eye contact:
Ingestion:
4.2 Most important symptoms and effects, both
acute and delayed
4.3 Indication of immediate medical attention and
special treatment needed
Take affected persons out of danger in a well ventilated area. In case of difficulty breathing
immediately consult a doctor.
Wash with water and rinse thoroughly. Immediately remove any clothing soiled by the product.
Consult a doctor immediately. Wash separately contaminated clothing before reuse.
Wash immediately and thoroughly with running water for at least 15 minutes. Consult a doctor.
Immediately seek medical attention. Induce vomiting only if indicated by the doctor. Never give
anything by mouth if the patient is unconscious.
See chapter 11.
Follow doctor’s instructions.
5. Fire-fighting measures
5.1 Extinguishing media
Suitable extinguishing media:
Unsuitable extinguishing media:
5.2 Special hazards arising from the substance or
mixture
Specific hazards in case of fire:
5.3 Advice for fire-fighters
General:
Special protective equipment for fire-fighters:
CO2, dry chemicals. For leakage and spillage that have not been caught in fire, nebulised water
can be used to disperse vapours and protect people involved.
Do not use water jets. Water is not effective for extinguish fire, it can be used to cool container
exposed to flames to prevent explosions.
Avoid breathing products of combustion (carbon oxides, toxic products of pyrolysis, etc.).
In case of fire cool containers with water spray to avoid explosion or development of potentially
dangerous substances for health and safety. For information about risks to the environment,
health, protection, see this data sheet.
Protective helmet with visor, flame retardant clothing (jacket and trousers with bands around
the arms, legs and waist), gloves for intervention (fire, chainsaw and dielectric), a mask with
overpressure with a facial that covers the entire face of the operator or with the self contained
breathing in case of large quantities of smoke.
6. Accidental release measures
6.1 Personal precautions: Eliminate all sources of ignition (cigarettes, flames, sparks, etc...) or any heat source from the
area in which the loss occurred. Avoid formation of dust by sprinkling the product with water if
there are no contraindications. In the case of airborne dust adopt respiratory protection. Stop
the leak if there is no hazard. And do not handle damaged containers or spilled material without
appropriate protective equipment. Keep away unprotected persons. For information on risks for
the environmental and health protection, ventilation and personal protection equipment refer to
other sections of this sheet.
6.2 Environmental precautions Prevent product from entering into drains, surface water, and ground water and in confined
areas.
6.3 Methods and materials for containment and
cleaning up
Absorb liquid spill with inert absorbent material (sand, vermiculite, diatomaceous earth, etc.) in
suitable container (made from material not incompatible with the product). Collect the majority
of material and deposit it in containers for disposal. For solid product use spark proof
mechanical tools and deposit it in plastic container. Discard the residue with water spray if
there are no contraindications. Ensure adequate ventilation of the place. The disposal of
contaminated material must be in accordance with paragraph 13.
6.4 Reference to other sections Indications about personal protection and waste treatment see sections 8 and 13.
7. Handling and storage
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Lex d.o.o. • Vanganelska c. 26 • SI-6000
Koper
tel.: +386 5 625 18 10 • fax: +386 5 625 18
12
www.lex.si • www.lexarna.si

Safety data Sheet (according to Regulation (EC) no. 1907/2006)
KALII PERMANGANAS
product code: 0362
7.1 Precautions for safe handling Do not smoke during the work. Work in accordance with good working practice.
7.2 Conditions for safe storage, including any
incompatibilities
7.3 Specific end uses No information available.
8. Exposure controls/personal protection
8.1 Control parameters No information available.
8.2 Exposure controls
Hygiene measures:
Respiratory protection:
Hand protection:
Store in tightly closed container in cold and well ventilated place, away from heat, open
flames, sparks and other ignition sources.
Given that the use of appropriate technical measures should always take priority over personal
protective equipment (ensure good ventilation in the workplace through effective local
extraction or with the discharge of stale air). If these precautions do not maintain the
concentration of the product under exposure limit values in the workplace, wear appropriate
respiratory protection. Use the product in the reference to the label of danger for details. During
the choice of personal protective equipment if necessary, request advice from suppliers of
chemicals. The personal protective equipment must conform to the regulations below.
In case of exceeding the threshold value of one or more of the substances in the preparation or
the daily reported exposure at work or at a fraction established by the service of prevention and
corporate security, wear a filter semiofficially type FFP3 (ref. Standard EN 141). The use of
respiratory protection, such as masks with cartridge for organic vapour and dust / mist, it is
necessary in the absence of technical measures to limit worker exposure. Where the substance
in question is odourless or its olfactory threshold is higher than the relative exposure limit and
in case of emergency, or when exposure levels are unknown or the oxygen concentration in the
workplace is less than 17% volume, wear self-circuit compressed mask with open air (ref.
Standard EN 137) or breathing apparatus with air hose for use with full face mask, half mask or
mouthpiece (ref. Standard EN 138). Provide a system for emergency eyewash and shower. If
there is a risk of being exposed to splashes or sprays in relation to work, you should provide
adequate protection of mucous membranes (mouth, nose, eyes) in order to avoid accidental
absorptions.
Protect your hands with gloves category I (ref. Directive 89/686/EEC and EN 374) such as PVC,
latex or equivalent. In the final selection of glove material must be considered: degradation,
permeation and breakthrough times. In the case of preparations the resistance of gloves must
be tested before use because it is not predictable. The gloves have a time to wear that depends
on the duration of exposure.
Eye protection: Use suitable safety glasses – hermetic (reference standard EN 166).
Skin and body protection:
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Form:
Colour:
Odour:
Wear work clothes with long sleeves and safety footwear. Professional use of category I (ref.
Directive 89/686/EEC and EN 344). Wash with soap and water after removing clothing
protective.
crystals
dark violet
odourless
Melting point:

Safety data Sheet (according to Regulation (EC) no. 1907/2006)
KALII PERMANGANAS
product code: 0362
11. Toxicological information
11.1 Information on toxicological effects
Acute effect:
12. Ecological information
Harmful if swallowed. Even small amounts of ingested can cause several problems with
symptoms including nausea, abdominal pain, vomiting, and diarrhea. May cause irritation of
mucous membranes, upper respiratory tract and eyes. Symptoms of exposure may include
burning and irritation to the eyes, mouth, nose, throat, cough, difficulty breathing, dizziness,
headache, nausea and vomiting.
12.1 Toxicity Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Morone saxatilis LC50 (96h) 0,96 mg/l
Daphnia magna EC50 (48h) 0,084 mg/l
Aphanizomenon flos-aquae IC50 (72h) 0,18 mg/l
12.2 Persistence and degradability No information available.
12.3 Bioaccumulative potential No information available.
12.4 Mobility in soil No information available.
12.5 Results of PBT and vPvB assessment No information available.
12.6 Other adverse effects Use product with good working habits and do not allow it, to reach ground water, water course
or sewage system.
13. Disposal considerations
13.1 Waste treatment methods
Product:
Packaging:
14. Transport information
Reuse, if possible. The residues of the product are to be considered special hazardous waste.
Lex product packaging must be disposed of in compliance with the country specific regulations
or must be passed to a packaging return system. Under www.slopak.si you will find special
information on the respective national conditions.
Chemicals must be disposed of in compliance with the respective national regulations. Under
www.slopak.si you will find country and substance specific information for disposal.
ADR:
UN-Number:
Proper shipping name:
Class:
Packing group:
Hazard identification No:
Limited quantities:
1090 1490
acetone Potassium permanganate
35.1
II
33 50
LQ4 LQ11
15. Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Classification GHS ((EC) No. 1272/2008)
NIOSH -Registry of toxic effects of chemicals substances (1983)
I.N.R.S. -Fiche toxicologique
15.2 Chemical Safety Assessment No chemical safety assessment has been processed for the mixture and the substances it
contains.
16. Other information
Full text of H-Statements referred to under section 2.
H272 May intensify fire; oxidiser.
H314 Causes severe skin burns and eye damage.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
Full text of R-phrases referred to under section 2.
H272 May intensify fire; oxidiser.
H302 Harmful if swallowed.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
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Lex d.o.o. • Vanganelska c. 26 • SI-6000
Koper
tel.: +386 5 625 18 10 • fax: +386 5 625 18
12
www.lex.si • www.lexarna.si

Safety data Sheet (according to Regulation (EC) no. 1907/2006)
KALII PERMANGANAS
product code: 0362
Further information
Other information: This version replaces all previous versions.
Page 5/5
Lex d.o.o. • Vanganelska c. 26 • SI-6000
Koper
tel.: +386 5 625 18 10 • fax: +386 5 625 18
12
www.lex.si • www.lexarna.si