Sales folder english - Adhesive Resins - Evonik Industries AG
Sales folder english - Adhesive Resins - Evonik Industries AG
Sales folder english - Adhesive Resins - Evonik Industries AG
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Flying the flag<br />
for customized solutions<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
<strong>Evonik</strong>. Power to create.
Designed Polymers<br />
for <strong>Adhesive</strong>s & Sealants<br />
<strong>Evonik</strong>. Power to create.
Flying the flag<br />
for customized solutions<br />
<strong>Evonik</strong> is one of the largest suppliers to the adhesives and sealants industry.<br />
With our Product Line <strong>Adhesive</strong> <strong>Resins</strong> we are clearly focussing this industry<br />
along with a dedicated vision:<br />
We want to be the first choice, whenever you are looking for polymer solutions<br />
for the industrial adhesives and sealants market! We want to be your preferred<br />
partner whenever particular competencies and market knowledge are needed<br />
and you are looking for individual solutions.<br />
On our path of becoming a solution provider, we continue to focus on the strengths<br />
that have served us well in the past:<br />
• customer orientation<br />
• reliability<br />
• know-how<br />
• future orientation.<br />
These are the four pillars on which we develop innovative solutions that are<br />
dedicated to one thing only: the success of our customers!<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
What does this mean for us<br />
And why is <strong>Evonik</strong> the right partner for your solutions<br />
Please find some more information on how we see ourselves and our<br />
competencies as well as our global customer approach on the next pages.<br />
The second chapter of this sales <strong>folder</strong> contains detailed technical<br />
information about our Designed-Polymer-Portfolio.<br />
4
Focus on Customer Orientation<br />
and Reliability<br />
An eye for innovation. Attention to customer needs.<br />
As the experts within <strong>Evonik</strong> for the <strong>Adhesive</strong>s & Sealants Industry, we are dedicated<br />
to customer service. We want to position ourselves as a provider of customized<br />
solutions and be the first choice of our customers when it comes to resolving<br />
challenges in the adhesives and sealants industry.<br />
Thanks to our global presence on all five continents and in more than 100 countries,<br />
we can respond flexibly and personally to the needs of our partners. This includes<br />
rapid innovation and the quick advancement of unique products and system solutions<br />
from the idea stage to market maturity – for the development of innovative polymers<br />
and formulations and for demanding optimizations alike. Our goal is to develop<br />
solutions that provide maximum benefit for our customers and our society.<br />
You give us your trust. We give you our word.<br />
We are convinced that closeness to customers and developing solutions in<br />
teamwork are the keys to success. That is why we work closely with our partners<br />
and involve them actively into our research and development work. This approach<br />
has helped us advance a number of highly successful solutions around the world.<br />
The relationship with our customers is characterized by reliability and trust.<br />
There is good reason why some of our customer relationships have existed<br />
for more than 25 years. We always treat our partners as equals and take them<br />
and their wishes very seriously. We consider it fundamental to keep<br />
our word and to guarantee a consistently high quality standard<br />
for our solutions.<br />
5
Know-How<br />
and Future Orientation<br />
Our milestones set the standard and secure success.<br />
Our success is based on our expertise in research and development. Our research<br />
teams around the world allow us to maintain and expand our technology leadership<br />
in the area of adhesives and sealants. In short, we set milestones.<br />
The close dialog with our partners produces innovations that stand out for their<br />
optimized performance, high efficiency and improved environmental compatibility,<br />
such as polymers with excellent bonding properties, better adhesion and optimized<br />
curing properties.<br />
Our milestones include tailor-made granulated amorphous poly(alpha)olefins,<br />
polyester polyols for moisture-curing one-component hot melt adhesives, reactive<br />
silane-modified amorphous poly(alpha)olefins, as well as acrylates and bio-based<br />
polyesters for reactive hot melts – in addition to highly reactive liquid<br />
polybutadienes for high performance adhesives and sealants and acrylic-based<br />
heat sealing lacquers for superior seal and peel performance.<br />
These are just some examples of the unique solutions we have developed to unlock<br />
specific applications and enhance the global productivity and success of<br />
our customers.<br />
Knowledge is the way. The future is the goal.<br />
Our goal is to conquer new markets and to consistently stay a step ahead, to<br />
recognize trends, and to use them profitably for our partners. Future viability and<br />
sustainability are particularly important factors in this regard. We not only keep an<br />
eye on the here and now, but also never forget about tomorrow and coming<br />
generations.<br />
This approach is reflected, for instance, in our nearly 100% solvent-free product<br />
range and the most recent example of our innovative strength: bio-based polyesterpolyols,<br />
a new product group developed on the basis of renewable raw materials.<br />
Our new investment in hydroxyl-terminated polybutadiene (HTPB) expands our<br />
portfolio and positions us to provide solutions related to megatrends like energy<br />
saving and resource efficiency.<br />
6
Our competencies<br />
for designed polymers<br />
Capabilities<br />
Designed<br />
Polymers for<br />
<strong>Adhesive</strong>s &<br />
Sealants<br />
Customer Needs<br />
Backbone Chemistry<br />
Capabilities<br />
Research & Development<br />
Applied Technology<br />
Analytical Department<br />
Engineering<br />
Scale-up and Production Facilities<br />
Marketing & <strong>Sales</strong><br />
Global Presence<br />
Logistics<br />
Customer Needs<br />
Excellent cohesion<br />
High adhesive strength<br />
towards individual substrates<br />
High tackiness<br />
Environmental performance<br />
High energy savings<br />
Fast cycle times<br />
Excellent initial strength<br />
Adjustable open times<br />
Backbone Chemistry<br />
Poly(alpha)olefines<br />
Polyesters<br />
Polyacrylates<br />
Polybutadienes<br />
FT-Waxes<br />
7
Crosslinkers<br />
<strong>Adhesive</strong> networks of<br />
Product Line <strong>Adhesive</strong> <strong>Resins</strong><br />
Product Line<br />
<strong>Adhesive</strong><br />
<strong>Resins</strong><br />
EAST<br />
<strong>Evonik</strong> for <strong>Adhesive</strong>s<br />
& Sealants<br />
Monomers<br />
Additives<br />
Scienceto-Business<br />
Center<br />
Bio-<br />
Technology<br />
Science-to-Business Center:<br />
<strong>Evonik</strong>’s cooperation framework<br />
for working together with external<br />
partners, universities and institutes<br />
•Bio-Technology<br />
•ECO 2 : Focus Energy Efficiency<br />
•Nanotronics<br />
Nanotronics<br />
Eco 2<br />
ASC: The <strong>Adhesive</strong> and Sealant Council (USA)<br />
IVLV: Industrievereinigung für Lebensmitteltechnologie<br />
und Verpackung e.V. (Germany)<br />
EWF: European Wax Federation (Europe)<br />
IVK: Industrieverband Klebstoffe e.V. (Germany)<br />
FEICA: Association of European <strong>Adhesive</strong> and<br />
Sealant Industry (Europe)<br />
BASA: British <strong>Adhesive</strong>s and Sealants Association<br />
FPA: Flexible Packaging Association<br />
8
Our dedicated sales force<br />
is committed to our<br />
global customer approach<br />
Germany (north)<br />
Scandinavia<br />
R. Kater<br />
rolf.kater@evonik.com<br />
phone +49 2156 109 174<br />
Germany (south)<br />
Austria<br />
Switzerland<br />
L. Malmedy<br />
ludger.malmedy@evonik.com<br />
phone +49 8251 870157<br />
France<br />
Benelux Countries<br />
United Kingdom<br />
R. Strobbe<br />
ronny.strobbe@evonik.com<br />
phone +32 475 283834<br />
Italy<br />
Spain<br />
Portugal<br />
A. Gogna<br />
alberto.gogna@evonik.com<br />
phone +39 02 333 008 49<br />
Turkey<br />
E. Onc<br />
emre.onc@evonik.com<br />
phone +90 216 395 9961<br />
Russia<br />
S. Kovalerov<br />
sergey.kovalerov@evonik.com<br />
phone +7 495 721 2862<br />
Romania<br />
Bulgaria<br />
A. Mehedintu<br />
alexandru.mehedintu@evonik.com<br />
phone +40 31 71 00786<br />
Other Eastern Europe<br />
T. Sabljic<br />
tomislav.sabljic@evonik.com<br />
phone +385 1 3862 674<br />
USA<br />
Canada<br />
C. Borgmann<br />
cornelia.borgmann@evonik.com<br />
phone +1 973 929-8466<br />
M. Leon<br />
mercedes.leon@evonik.com<br />
phone +1 973 541 8821<br />
S. Engert<br />
sabine.engert@evonik.com<br />
phone +1 973 541 8924<br />
Mexico<br />
G. Marquez<br />
gabriela.marquez@evonik.com<br />
phone +52 55 5483-1000<br />
Other South America<br />
J. Thomaz de Melo<br />
joaquim.melo@evonik.com<br />
phone +55 11 3146 2156<br />
Argentina<br />
G. Avella<br />
gabriel.avella@evonik.com<br />
phone +54 9 11 57562069<br />
UAE<br />
Saudi Arabia<br />
S. Arte<br />
sachin.arte@evonik.com<br />
phone +971 4 204 5586<br />
Egypt<br />
A. Nousser<br />
ahmed.nousser@evonik.com<br />
phone +20 2 7948 242<br />
Iran<br />
A. Nayeri<br />
ali.nayeri@evonik.com<br />
phone +9821 2222 3402109<br />
India<br />
S. Parab<br />
suresh.parab@evonik.com<br />
phone +91 22 6723 8800<br />
Japan<br />
A. Yamamoto<br />
atsushi.yamamoto@evonik.com<br />
phone +81 3 5323 7409<br />
K. Sugi<br />
kiyoaki.sugi@evonik.com<br />
phone +81 3 5323 7360<br />
Korea<br />
J. Kim<br />
jason.kim@evonik.com<br />
phone +82 2 2072 2398<br />
South/East Asia<br />
D. Han<br />
daryl.han@evonik.com<br />
phone +65 6 809 6843<br />
A. Chen<br />
aumpa.chen@evonik.com<br />
phone +6627847913<br />
China<br />
E. Frimel<br />
ernst.frimel@evonik.com<br />
phone +86 21 6119 1028<br />
J. Qian<br />
jerry.qian@evonik.com<br />
phone +86 21 6119 1343<br />
Taiwan<br />
R. Cheng<br />
roger.cheng@evonik.com<br />
phone +886 2 2717-1242<br />
Australia<br />
New Zealand<br />
A. Windsor<br />
andrew.windsor@evonik.com<br />
phone +61 3 85818404<br />
9
Customized solutions for<br />
diverse markets<br />
Automotive<br />
Bonding & Lamination Interior<br />
Car Carpets<br />
<strong>Adhesive</strong>s & Sealants for Different Application<br />
Sound Damping<br />
Windows<br />
Head Lamp <strong>Adhesive</strong>s<br />
Construction<br />
Flat Lamination, Sandwich Construction<br />
Profile Wrapping & Edge Bonding<br />
Sand Filled Mortar<br />
Sealants/ Insulated Glass Sealants<br />
Electronics<br />
Flexible Flat Cables<br />
Cable Filling / Jelly Compounds<br />
Electrical Insulations & Potting Compounds<br />
Lifestyle<br />
Carpets<br />
Hygiene<br />
Textile Industry<br />
Silicone Based Consumer Sealants<br />
Mattrasses<br />
Packaging<br />
Flexible Packaging<br />
Paper & Packaging<br />
Pharmaceutical Blister-Pack<br />
Food Packaging<br />
Other Markets<br />
Bitumen Modification<br />
Polymer Modification / Masterbatches<br />
Road Construction<br />
Plastic Processing<br />
Renewables / Solar Applications<br />
Flexible Printing Plates / Defoamers / PU Foams<br />
10
Our Product Portfolio<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
11
Our polyester-polyols, copolyesters<br />
and polyacrylates for your reactive<br />
and thermoplastic hot melts.<br />
Our amorphous poly-alpha-olefins<br />
(APAOs) are co- and terpolymers<br />
of ethene, propene and 1-butene.<br />
They are particularly useful for<br />
producing hot melt adhesives.<br />
Our synthetic waxes produced<br />
by the Fischer-Tropsch process<br />
act as your value additive for<br />
hot melt applications.<br />
Our liquid polybutadienes for<br />
your adhesives & sealants are<br />
stereospecific, low viscous and<br />
unsaponifiable.<br />
Our methacrylat binders<br />
for heat sealing applications<br />
in pharmaceutical blister-packs<br />
and food packaging.<br />
12
13<br />
Application Insights
Designed Polymers for<br />
<br />
<br />
<br />
Initial strength<br />
high<br />
low<br />
Spectrum of standard<br />
PES-RHM formulations<br />
DYNACOLL AC<br />
influence area<br />
short<br />
long<br />
Open time<br />
Mw 30.000 – 140.000 g/mol<br />
Tg 44 – 85 °C<br />
Viscosity 16 – 54 cm 3 /g<br />
FP (R&B) 120 – 190 °C<br />
MFR (190 °C) 7 – 1.000 g/10 mn<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
14
Designed Polymers for<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
15
Designed Polymers for<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
16
Designed Polymers for<br />
<br />
<br />
<br />
<br />
<br />
<br />
17
Designed Polymers for<br />
POLYVEST® MA 75, a maleic anhydride functionalized liquid polybutadiene with<br />
a viscosity of 6,000-9,000 mPa s (20°C), improves compounding of ethylenepropylene-diene-monomer-rubbers<br />
(EPDM). Compound formulations benefit<br />
from its improved dispersion of fillers, e.g. of chalk or carbon black.<br />
<br />
<br />
<br />
<br />
<br />
Guide formulation<br />
with mixture of<br />
EPDM and chalk and<br />
typical additives with<br />
increasing addition<br />
of small amounts of<br />
POLYVEST® MA 75<br />
(e.g. 0-4 parts by<br />
weight).<br />
18
Designed Polymers for<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
With POLYVEST® MA 75, a maleic anhydride functionalized liquid polybutadiene<br />
with a viscosity of 6,000-9,000 mPa s (@20°C), automotive tire formulations<br />
benefit from its improving silica dispersing character and show effects such as<br />
<br />
<br />
<br />
<br />
<br />
Reduced compound viscosity<br />
Reduced vulcanization time<br />
Increased tensile strength<br />
Increased elongation at break<br />
Increased break energy<br />
Guide formulation for automotive tires with mixture<br />
of Styrene Butadiene Rubber (SBR) and Butadiene<br />
Rubber (BR) and typical additives with increasing<br />
addition of small amounts of POLYVEST® MA 75<br />
(e.g. 0-2 parts by weight).<br />
19
Designed Polymers for<br />
Waterbased Heat Seal Formulations<br />
DEGALAN® VP 4240 D achieves direct adhesion to aluminum and<br />
gives very good sealability versus polystyrene (PS) cup materials.<br />
Features<br />
• Aqueous resin dispersion<br />
• Pure acrylic binder<br />
• Optimized core-shell structure<br />
• 50% solid content<br />
Advantages<br />
• Suitable for water based heat seal<br />
lacquer formulations<br />
• Environmental friendly dispersion<br />
• High efficiency<br />
Benefits<br />
• Direct adhesion on aluminum,<br />
no primer necessary<br />
• Broad sealing window<br />
• Lacquer formulation for<br />
sustainable packaging with<br />
eco-friendly heat sealing<br />
Label print<br />
Aluminium<br />
Direct adhesive heat seal<br />
lacquer based on<br />
DEGALAN® VP 4240 D<br />
Cover lid<br />
Sealing substrate: PS, PVC<br />
Cup<br />
DEGALAN® VP 4240 D provides good seal strength starting at 140°C and a very broad sealing window.<br />
10<br />
N/15mm<br />
8<br />
6<br />
4<br />
2<br />
0<br />
200°C 180°C 160°C 140°C 120°C 100°C<br />
Sealing Temperature<br />
◂ 7<br />
Aluminium vs. PS<br />
• Single step coating<br />
• Dry film coating weight 7 g / m²<br />
• Drying: 15 s / 180°C<br />
• Sealing: 1.0 s, 6 bar<br />
Initial after Sealing<br />
After 48 h immersion into water<br />
20
Designed Polymers for<br />
Pharmaceutical Blister Packaging<br />
DEGALAN® P 24 and DEGALAN® LP AL23 –<br />
State of the art in pharmaceutical blister packaging.<br />
Formulations of DEGALAN® P 24 and DEGALAN® LP AL23 with PVC copolymer show excellent performance in<br />
aluminum blister packaging. In combination with polyester primer like DYNAPOL®L 206 or 208 adhesion to PET is achieved.<br />
Features<br />
• Beads (100% solids)<br />
• LP AL23: Drug Master File<br />
• Compatible with PVC copolymers<br />
• State of the art binder for sealing<br />
versus PVC and PVdC<br />
Advantages<br />
• Free choice of solvent<br />
• Enables easy access to<br />
pharma applications<br />
• Wide range of application<br />
• Binders are suitable for pharma<br />
and food applications<br />
Benefits<br />
• Fast drying in combination with<br />
low boiler solvents<br />
• Shorter approval times with<br />
respect to pharma applications<br />
• Cost savings in lacquer formulation,<br />
due to less PVC needed<br />
• Less number of formulations needed<br />
Label print<br />
Aluminium<br />
Heat seal lacquer<br />
based on either<br />
DEGALAN ® P 24 or<br />
DEGALAN ® LP AL23<br />
formulated with a<br />
PVC-copolymer as an<br />
adhesion promoter<br />
Sealing substrate: PVC, (PVD) (PVdC)<br />
Blister foil<br />
Blister tray<br />
DEGALAN® P 24 and<br />
DEGALAN® LP AL23 –combined with<br />
PVC copolymer to give good adhesion to<br />
aluminum foil and secure sealing<br />
in pharma blister packaging.<br />
Heat Sealing Strength vs. DEGALAN® P 24 content: Example Pharmaceutical Blister Packaging<br />
10<br />
8<br />
DEGALAN® P 24 improves the heat seal strength<br />
for various PVC copolymers. Heat seal strength of<br />
more than 8 N/15mm can be achieved.<br />
6<br />
4<br />
N/15mm<br />
2<br />
0<br />
0 20 40 60 80<br />
DEGALAN® P 24 content / % (solid/solid)<br />
VMCH - Initial<br />
Vinnol H15/45 M - Initial<br />
Vinnol H 30/48 M - Initial<br />
Hard Aluminium vs. PVC<br />
• Combined with var. PVC copolymers<br />
• Drying: 15 seconds at 180 °C<br />
• Sealing: 1,0 seconds, 6 bar, 200°C<br />
• Heat Sealing Strength Test, α = 90°<br />
21
Designed Polymers for<br />
PVC Free Packaging<br />
DEGALAN® PM 666 and DEGALAN® 4151 E – Direct adhesion to<br />
aluminum and sealability versus Polystyrene, Polypropylene and PET.<br />
In combination with polyester primer like DYNAPOL® L 206 or 208, DEGALAN® PM 666 and DEGALAN® 4151 E<br />
also achieve good adhesion to PET.<br />
Features<br />
• Organic dispersion from<br />
copolymers of methacrylic esters<br />
grafted on EPDM olefins<br />
• Binder with functional groups which<br />
enables primerless application<br />
Advantages<br />
• Universal sealability versus all<br />
common cup materials<br />
• Direct adhesion to aluminum<br />
• No PVC copolymer is needed<br />
Benefits<br />
• Cost savings due to reduction of<br />
complexity<br />
• Eco-friendly - since PVC free - heat<br />
sealing lacquer<br />
• Superior alternative when PVC based<br />
heat seal lacquers need to be<br />
replaced in food packaging<br />
Label print<br />
Aluminium<br />
Direct adhesive heat seal<br />
lacquer based on<br />
DEGALAN® PM 666<br />
Cover lid<br />
Sealing substrate: PP, PS, PET<br />
Cup<br />
DEGALAN® PM 666 and DEGALAN® 4151 E –<br />
Direct adhesion to aluminum and sealability<br />
versus Polystyrene, Polypropylene and PET<br />
Heat Sealing Strength vs. Sealing Temperature<br />
N/15mm<br />
10<br />
7,8<br />
8<br />
6,7<br />
7,3<br />
6<br />
6,3<br />
4<br />
2,4<br />
2<br />
0,0<br />
0<br />
200°C 180°C 160°C 140°C<br />
Sealing Temperature<br />
Both, DEGALAN® PM 666 as well as<br />
DEGALAN® 4151 E show heat seal strength<br />
of more than 5 N/15mm at temperatures<br />
above 170°C.<br />
DEGALAN® 4151 E<br />
DEGALAN® PM 666<br />
Aluminium vs. PP<br />
• Not primered!<br />
• Drying: 15 sec. / 180 °C<br />
• Sealing: 1 sec., 6 bar,<br />
22
Designed Polymers for<br />
PET Lidding<br />
DEGALAN® VP 4174 E – “One to fit all” direct adhesion on Aluminum<br />
and PET is achieved.<br />
No primer is needed for DEGALAN® VP 4174 E to give good adhesion to aluminum and to PET.<br />
Features<br />
• Organic dispersion of copolymers of<br />
methacrylic esters grafted on EPDM<br />
olefins and polyesters<br />
• Designed for primerless PET lidding<br />
• Binder with functional groups and<br />
polymers which enables primerless<br />
application<br />
Advantages<br />
• Universal sealability versus all<br />
common cup materials<br />
• Direct adhesion to PET and<br />
aluminum<br />
• No primer is needed<br />
Benefits<br />
• Cost saving in PET lacquering due<br />
to one-pass application<br />
• “One to fit all” lacquer formulation<br />
is possible<br />
• Seals versus all common cup<br />
materials like PP, PS, PVC and PET<br />
Label print<br />
PET<br />
One-pass direct adhesive<br />
heat seal lacquer based on<br />
DEGALAN® VP 4174 E<br />
Cover lid<br />
High Efficiency of<br />
DEGALAN® VP 4174 E<br />
Cup<br />
Sealing substrate: PP, PS, PET<br />
Use for PVC free food packaging in<br />
your combi lacquer formulations to seal<br />
versus all common cup materials.<br />
DEGALAN® VP 4174 E – Heat Seal Strength at various<br />
material combinations<br />
DEGALAN® VP 4174 E<br />
gives a heat seal strength of more<br />
than 6 N/15mm even on<br />
PET WDW 50 substrates.<br />
Sealing vs. PP, PS and PET<br />
• No Primering!<br />
• Layer thickness PET 6 μm<br />
• Layer thickness Alu 8 μm<br />
• Drying: 15 sec. / 180 °C<br />
• Sealing: 1 sec., 6 bar, 200 °C<br />
N/15mm<br />
10<br />
8<br />
6<br />
4<br />
2<br />
0<br />
Aluminum<br />
8,4 8,7 6,0<br />
9,1 9,1<br />
6,7 6,0<br />
8,0<br />
vs. PP vs. PS vs. PET<br />
6,0<br />
Al25/PET12 PET WDW 50<br />
Recommended Application:<br />
23 - 55 μm PET substrate<br />
Recommended Heat Seal Lacquer<br />
coating weight:6 g/sqm (approx. 6 μm)<br />
Application Range: approx. 78 sqm/kg<br />
Efficiency + 35% vs. Aluminum<br />
Additional Application:<br />
38 μm aluminum substrate<br />
Recommended Heat Seal Lacquer<br />
coating weight dueto corrosion protection:<br />
8 g/sqm (approx. 8 μm)<br />
Application Range: approx. 58 sqm/kg<br />
The solid content of<br />
DEGALAN® VP 4174 E is about 46 % in<br />
comparison to DEGALAN® 4150 E with<br />
about 43 % (approx. 54 sqm/kg at 8 g/sqm,<br />
approx. 8 μm coating weight)<br />
23
DYNACOLL®<br />
Polyester-Polyols, Copolyesters<br />
and Polyacrylates<br />
<strong>Evonik</strong>. Power to create.<br />
24
DYNACOLL® 7000<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
Polyester-Polyols<br />
With its DYNACOLL® 7000 polyester-polyols <strong>Evonik</strong> offers tailor-made raw<br />
materials for one-component moisture-curable hotmelt (RHM) adhesives and<br />
sealants. DYNACOLL® 7000 products are linear copolyesters with primary<br />
hydroxyl functionality and medium molecular weight.<br />
Depending on their morphology the product range is divided into three<br />
basic groups:<br />
• DYNACOLL® 7100 series<br />
• DYNACOLL® 7200 series<br />
• DYNACOLL® 7300 series<br />
amorphous, solid<br />
liquid, pasty<br />
partially crystalline, solid<br />
The product group is designed as a building block system, most DYNACOLL® 7000<br />
polyester-polyols are compatible with each other. Partially incompatible but<br />
miscible systems are, however, necessary in many applications as well.<br />
DYNACOLL® 7000 copolyesters are usually supplied in 25 or 30 kg and<br />
190 or 200 kg steel drums. Liquid bulk deliveries are available on special request.<br />
Your benefits<br />
Our building block system allows a precise formulation of reactive PUR hot melts<br />
with low application temperatures and high heat resistance. Basic effects on the<br />
RHM properties are:<br />
• DYNACOLL® 7100 series<br />
• shortens open time<br />
• increases initial strength, melt viscosity and adhesion to polar substrates<br />
• DYNACOLL® 7200 series<br />
• increases flexibility, open time and adhesion to non-polar substrates<br />
• lowers melt viscosity<br />
• DYNACOLL® 7300 series<br />
• shortens open time (depending on crystallinity) and lowers melt viscosity<br />
• increases initial strength<br />
25
DYNACOLL® 7000<br />
Product Range<br />
Properties Melt Viscosity Grade<br />
Hydroxyl<br />
Number 2)<br />
Acid<br />
Number 2)<br />
Molecular<br />
Weight<br />
Glass<br />
Transition<br />
Temperature<br />
Melting<br />
Point<br />
Softening<br />
Point<br />
(R&B)<br />
Density<br />
at 23 °C<br />
Flash<br />
Point<br />
80 °C 130 °C<br />
Grade [mg KOH/g] [mg KOH/g] [g/mol] [°C] [°C] [°C] [kg/dm 3 ] [°C]<br />
[Parallel plate]<br />
[Pa s]<br />
[Parallel plate]<br />
[Pa s]<br />
Amorphous<br />
7110 1) 50 - 60 8 - 12 2,000 10 52 1.08 >300 1 7110 1)<br />
7111 27 - 34 max. 4 3,500 20 61 1.23 >300 3 7111<br />
7130 31 - 39 max. 2 3,000 30 76 1.17 >300 10 7130<br />
7131 31 - 39 max. 2 3,000 30 76 1.23 >300 10 7131<br />
7140 18 - 24 max. 2 5,500 30 87 1.21 >300 50 7140<br />
7150 38 - 46 max. 2 2,600 50 95 1.26 >300 50 7150<br />
Liquid<br />
7210 27 - 34 max. 2 3,500 -15 1.29 >200 11 7210<br />
7230 27 - 34 max. 2 3,500 -30 1.17 >200 10 7230<br />
7231 27 - 34 max. 2 3,500 -30 1.21 >200 8 7231<br />
7250 18 - 24 max. 2 5,500 -50 1.15 >200 5 7250<br />
7255 27 - 34 max. 2 3,500 -60 32 40 1.11 >200 2 7255<br />
Crystalline<br />
7362 47 - 54 max. 2 2,000 -60 53 60 1.15 >200 0.5 7362<br />
7360 27 - 34 max. 2 3,500 -60 55 63 1.16 >300 2 7360<br />
7363 18 - 24 max. 2 5,500 -60 56 63 1.16 >300 5 7363<br />
7365 14 - 20 max. 2 6,500 -60 57 63 1.16 >300 10 7365<br />
7361 10 - 16 max. 2 8,500 -60 57 65 1.16 >300 15 7361<br />
7381 27 - 34 max. 2 3,500 65 73 1.16 >300 2 7381<br />
7380 27 - 34 max. 2 3,500 70 77 1.10 >300 2 7380<br />
7330 27 - 34 max. 2 3,500 85 90 1.17 >300 0.3 7330<br />
7320 27 - 34 max. 3 3,500 -20 92 1.23 >300 4 7320<br />
7340 27 - 34 max. 2 3,500 -40 96 102 1.19 >300 1 7340<br />
7331 27 - 34 max. 2 3,500 -30 110 115 1.19 >300 2 7331<br />
7390 27 - 34 max. 3 3,500 -30 115 118 1.29 >300 0.7 7390<br />
7321 27 - 34 max. 2 3,500 -25 123 128 1.20 >300 3 7321<br />
1)<br />
available on special request<br />
2)<br />
Hydroxyl Number and Acid Number represent delivery specifications<br />
26
DYNACOLL® 7000<br />
Preparation of Reactive Hot Melts<br />
Molten DYNACOLL® grades are charged and heated up to approx. 130 °C. The melt<br />
is dried for 45 min. at less than 10 mbar. Water evaporation is important to avoid<br />
crosslinking reactions and to obtain good shelf life and viscosity stability of the<br />
RHM.<br />
The calculated amount of isocyanate is added under a weak stream of protective gas<br />
(dried nitrogen or carbon dioxide) and rapidly homogenized with the melt. Reaction<br />
time is normally 45 min. at 120 – 130 °C.<br />
The reaction is finished after the theoretical value of isocyanate content is reached.<br />
The isocyanate content is determined by reaction of the RHM with an excess of<br />
dibutylamine and titration with hydrochloric acid. The melt should be degassed until<br />
it is free of bubbles. Afterwards the reactive hot melt is filled into containers and<br />
stored in the absence of moisture and light. Depending on the application it is<br />
recommended to filter the melt.<br />
For quality control, the following data should be determined: isocyanate content,<br />
visosity at elevated temperature, melting point or softening point (R&B), open time.<br />
Calculation:<br />
Weight (diisocyanate) =<br />
(WPES1 . OH1 + WPESn . OHn) . EW . R<br />
56110<br />
WPES1 = weight of polyester 1<br />
OH1 = hydroxyl number polyester 1<br />
WPESn = weight of polyester n<br />
OHn = hydroxyl number polyester n<br />
EW = equivalent weight of diisocyanate used<br />
R = ratio of isocyanate to hydroxyl groups<br />
Reactive Hot Melt adhesives based on DYNACOLL® 7000<br />
• offer excellent bonding to a huge variety of substrates<br />
• provide solutions for versatile applications in diverse industries,<br />
e.g. wood working, automotive, packaging and textile industry,<br />
also for bookbinding applications and sandwich bonding<br />
• can be applied with standard hot melt equipment,<br />
e.g. roll coaters, bead, spray and melt print applicators etc.<br />
27
DYNACOLL® 7000<br />
Reactive Holt Melt Data<br />
Reaction products of DYNACOLL® with 4,4’- diphenylmethane diisocyanates (MDI) as a ratio of OH : NCO = 1 : 2.2<br />
Properties<br />
Melt Viscosity<br />
Grade<br />
Softening<br />
Point<br />
(R&B)<br />
[°C]<br />
Open Time<br />
[s]<br />
Setting Time<br />
[s]<br />
Tensile<br />
Strength<br />
[N/mm 2 ]<br />
Elongation<br />
at Break<br />
[%]<br />
130 °C<br />
[Parallel plate]<br />
[Pa s]<br />
Amorphous<br />
7110 1) 64 10 1 brittle 3<br />
7111 71 6 1 brittle 13<br />
7130 88 1 1 brittle 50<br />
7131 88 1 1 brittle 45<br />
7140 102 1 < 1 brittle 700<br />
7150 105 < 1 < 1 brittle 400<br />
Liquid<br />
7210 45 several hours several hours 15 800 5<br />
7230 several hours several hours 15 900 9<br />
7231 several hours several hours 15 900 8<br />
7250 several hours several hours 15 1,500 9<br />
7255 40 several hours several hours 30 1,100 5<br />
Crystalline<br />
7362 55 130 35 25 400 2<br />
7360 59 80 15 25 400 4<br />
7363 61 50 15 25 400 11<br />
7365 63 50 15 20 300 18<br />
7361 63 50 10 20 300 30<br />
7381 67 35 3 20 80 5<br />
7380 73 20 1 20 20 5<br />
7330 85 35 3 25 15 3<br />
7320 87 40 35 35 500 48<br />
7340 97 120 60 30 700 12<br />
7331 110 90 30 30 500 20<br />
7390 118 20 10 30 10 4<br />
7321 123 70 25 35 400 30<br />
1)<br />
available on special request<br />
28
DYNACOLL® 7000<br />
Compatibility<br />
Grade<br />
7110 1)<br />
7111<br />
7130<br />
7131<br />
7140<br />
7150<br />
7210<br />
7230<br />
7231<br />
7250<br />
7110 1) + + + + + + + + + + + + + + +<br />
7111 + + + + + + + + + + + + – – +<br />
7130 + + + + + + + + + + + + + + + +<br />
7131 + + + + + + + + + + + + + + + + + + + +<br />
7140 – – + + + + + – + + + +<br />
7150 + + + + + + + + + + + + + +<br />
7210 + + + + – + + + + +<br />
7230 + + + + + + + + + + + + + + + + + + +<br />
7231 + + + + + + + + + + + + + + + + + +<br />
7250 + + + + – + + + + + + + + + + + +<br />
7255 + + + + – + – + + + + + + + + + + + – + –<br />
7320 + + + + + + + + + + + + + + + + – – +<br />
7321 * – – + + + + + + + – – + + + + + + + + +<br />
7330 + – + + – + – + – + + + + + + + + + + +<br />
7331 – – + + + + – + + – + + + + + + – +<br />
7340 – – + + + + + + + – + + + + + + + + +<br />
7360 + + + + – + – + + + + + + + + + + + + +<br />
7361 + + + + – + – + + + + + + + + + + + + +<br />
7365 + + + + – + – + + + + + + + + + + + + +<br />
7380 – – – – – – – – – – – – + – – – + + +<br />
7381 – – – + – – – – – – + – + + + + + + + +<br />
7390 + + – + – – + + + – – – – – – – –<br />
7255<br />
7320<br />
7321 *<br />
7330<br />
7331<br />
7340<br />
7360<br />
7361<br />
7365<br />
7380<br />
7381<br />
7390<br />
1)<br />
available on special request<br />
Visual evaluation of the melt after storing 24 hours at 130 °C ( * at 140 °C):<br />
+ = transparent = opaque 1:1 Mixtures of copolyesters<br />
= cloudy – = phase separation 1:1 Mixtures of copolyesters reacted with MDI (OH : NCO = 1 : 2.2)<br />
29
DYNACOLL® 7000<br />
Analytical Methods<br />
Hydroxyl Number<br />
Determination according to DIN 53 240-02.<br />
Approx. 2-3 g of polyester are dissolved in dichloromethane or THF. The OH groups are<br />
esterified at RT with acetic anhydride, using 4-dimethyl-aminopyridine as catalyst. After<br />
hydrolysis of the unreacted anhydride, titration is carried out with 0.5 N methanolic KOH.<br />
Acid Number<br />
Determination according to DIN EN ISO 2114.<br />
Approx. 4 g of polyester are dissolved in 50 ml of tetrahydrofuran. Following addition of 50 ml<br />
of a mixture of equal parts by weight of tetrahydrofuran and ethanol, titration is carried out<br />
with methanolic or ethanolic KOH against phenolphthalein.<br />
Molecular Weight<br />
The molecular weight is calculated based on the sum of hydroxyl number and acid number.<br />
Glass Transition Temperature<br />
Determination according to DIN 53 765.<br />
The glass transisition temperature is determined as for the melting point.<br />
Melting Point<br />
Determination according to DIN 53 765.<br />
The melting point is determined using a DSC instrument. The sample and an empty reference<br />
crucible are heated at 20 °C/min. The melting point corresponds to the maximum of the<br />
melting peak. To ensure better reproducibility, it is customary to use the values from the<br />
second heating operation.<br />
Softening Point (Ring and Ball)<br />
Determination according to DIN ISO 4625.<br />
The sample is cast as a melt into a ring and the ring, following the solidifaction of the melt<br />
(or the recrystallization in the case of crystalline substances), is inserted into a test frame. The<br />
sample is stressed concentrically with a chrome-plated steel ball and the test frame is immersed<br />
in a bath of glycerol. The glycerol is heated at a rate of approximately 5 °C/min. The softening<br />
point (R&B) is the temperature of the glycerol bath at the time when the steel ball contacts the<br />
baseplate of the test frame.<br />
Density<br />
Determination according to DIN 51 757.<br />
Flash Point<br />
Determination according to ISO 2592.<br />
Open Time<br />
Determination according to <strong>Evonik</strong> internal method.<br />
The material is heated up to 130 °C and applied on paper as an approximately 0.5 mm thick<br />
film. Strips of open surface paper are pressed into the melt at certain intervals. After the<br />
adhesive film is tack-free the paper strips are removed. The open time is given by the time,<br />
when no fiber tear can be observed anymore.<br />
30
DYNACOLL® 7000<br />
Analytical Methods<br />
Setting Time<br />
Determination according to <strong>Evonik</strong> internal method.<br />
The setting time is given by the time it takes until two bonded wooden cubes can<br />
no longer be twisted against each other by hand.<br />
Melt Viscosity<br />
Determination according to DIN EN ISO 3219, parallel plate method.<br />
Tensile Strength / Elongation at Break<br />
Determination according to DIN 53 504.<br />
Dumbbell specimens are punched out from a 0.5 mm thick moisture cured RHM film.<br />
Curing conditions are 7 days, 20 °C and 65 % rel. humidity. Elongation at break denotes<br />
the percentage increase in length of an original section of 10 mm marked on the bar<br />
of the dumbbell specimen, at the moment of break.<br />
31
DYNACOLL® S<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
Copolyesters<br />
With its DYNACOLL® S product range <strong>Evonik</strong> offers thermoplastic copolyesters<br />
of high molecular weight to a wide variety of thermoplastic hot melt and solvent<br />
based applications.<br />
The individual grades differ in their melting point, degree of crystallinity and<br />
hardness and in their setting time. According to their crystallinity, the product<br />
range is arranged into four basic groups:<br />
• DYNACOLL® S - Highly crystalline grades<br />
• DYNACOLL® S - Moderately crystalline grades<br />
• DYNACOLL® S - Slightly crystalline grades<br />
• DYNACOLL® S - Amorphous grades<br />
DYNACOLL® S copolyesters are generally supplied as granules,<br />
usually in bags of 20 or 25 kg.<br />
They can be processed into following forms of applications:<br />
adhesive film, web or net, powder, paste, hot melt and solution.<br />
Your benefits<br />
• DYNACOLL® S - Highly crystalline grades<br />
• short open times and high heat resistance<br />
• good solvent and chemical resistance<br />
• DYNACOLL® S - Moderately crystalline grades<br />
• moderate open times<br />
• very good adhesive strength and heat resistance<br />
• DYNACOLL® S - Slightly crystalline grades<br />
• long open time with good heat resistance<br />
• excellent adhesion on a large number of substrates<br />
• DYNACOLL® S - Amorphous grades<br />
• good solubility in many solvents<br />
• very good adhesion on a large number of substrates<br />
32
DYNACOLL® S<br />
Product Range<br />
Properties Melt Flow Rate (MFR) [g/10 min] Melt Viscosity [Pa s] Solubility Grade<br />
Softening<br />
Point<br />
Melting<br />
Point<br />
Grade [°C] [°C] [°C]<br />
Glass<br />
Transition<br />
Temp.<br />
Hydroxyl<br />
Number<br />
[mg<br />
KOH/g]<br />
Acid<br />
Number<br />
Viscosity<br />
Number<br />
Shore D<br />
Hardness<br />
Open Time<br />
Tensile<br />
Strength<br />
Elongation<br />
at Break<br />
[mg<br />
KOH/g] [cm 3 /g] [s] [N/mm 2 ] [%] 160 °C 180 °C 200 °C 220 °C 160 °C 180 °C 200 °C 220 °C<br />
Methylene chloride<br />
Trichloroethylene<br />
Ethyl acetate<br />
MEK<br />
(methylethyl ketone)<br />
Toluene<br />
Highly crystalline<br />
S 243 195 195 35 68 79 5 40 7 130 240 50 – – – – – S 243<br />
Moderately crystalline<br />
S 1272 140 128 0 84 53 10 25 400 30 60 120 250 330 140 65 + – – – – S 1272<br />
S 1252 135 120 1) 20 94 64 5 20 450 20 45 900 360 180 + – – – – S 1252<br />
S 1218 130 115 15 80 63 20 20 300 30 60 110 210 300 150 80 + • – – – S 1218<br />
S 1227 115 100 10 80 63 5 15 350 40 90 150 240 240 120 60 + • – – – S 1227<br />
Slightly crystalline<br />
S 1402 100 90 1) -10 5 3 78 27 15 10 400 100 220 360 80 50 30 10 + + – – • S 1402<br />
S 1401 97 85 1) -25 6 2 80 19 15 5 500 110 190 290 80 40 25 15 + + • • + S 1401<br />
S EP 1408 90 80 1) -30 4 2 87 17 50 2 300 75 130 200 100 55 30 15 + + + + + S EP 1408<br />
Amorphous<br />
S 1606 155 65 4 2 62 80 15 60 5 30 60 150 90 + + + + – S 1606<br />
S 1611 130 50 4 2 61 79 10 20 3 100 190 70 15 + + + + + S 1611<br />
S 1426 140 35 4 2 90 78 20 50 5 15 30 60 270 + + + + + S 1426<br />
S EP 506.01 125 40 6 5 65 80 5 130 230 + + + + + S EP 506.01<br />
1)<br />
optical method<br />
All data given are typical values<br />
+ = > 10% (soluble)<br />
• = < 10 % (slightly insoluble)<br />
– = < 1% (virtually insoluble)<br />
33
DYNACOLL® S<br />
Applications<br />
Highly<br />
Cryst.<br />
Grade<br />
Moderatly<br />
Crystalline Grades<br />
Slightly<br />
Crystalline Grades<br />
Amorphous<br />
Grades<br />
S 243<br />
S 1272<br />
S 1252<br />
S 1218<br />
S 1227<br />
S 1402<br />
S 1401<br />
S EP 1408<br />
S 1606<br />
S 1611<br />
S 1426<br />
S EP 506.01<br />
Textile Industry<br />
Hot Melts ▯ ▯ ▯ ▯<br />
<strong>Adhesive</strong> film ▯ ▯ ▯<br />
<strong>Adhesive</strong> web and net ▯ ▯<br />
Profile Wrapping<br />
PVC Window frames ▯ ▯ ▯<br />
Metal / Plastics bonding ▯ ▯ ▯ ▯ ▯<br />
Metal primer ▯ ▯ ▯<br />
Electronic Industry<br />
Solvent based adhesives ▯ ▯ ▯ ▯<br />
Hot Melt adhesives<br />
▯<br />
Automotive Industry<br />
Air filter bondings<br />
Interior textile lamination ▯ ▯<br />
Decorative film lamination ▯ ▯ ▯<br />
Packaging Industry<br />
Biodegradeable adhesives<br />
Flexible packging ▯ ▯ ▯ ▯<br />
Polymer Modification<br />
Additive for Reactive Hot Melts ▯ ▯<br />
Masterbatches<br />
▯<br />
34
DYNACOLL® S<br />
Analytical Methods<br />
Softening Point (Ring and Ball)<br />
Determination according to DIN ISO 4625.<br />
The sample is cast as a melt into a ring and the ring, following the solidifaction of the melt<br />
(or the recrystallization in the case of crystalline substances), is inserted into a test frame.<br />
The sample is stressed concentrically with a chrome-plated steel ball and the test frame is<br />
immersed in a bath of glycerol. The glycerol is heated at a rate of approximately 5 °C/min.<br />
The softening point (R&B) is the temperature of the glycerol bath at the time when the steel<br />
ball contacts the baseplate of the test frame.<br />
Melting Point<br />
Determination according to DIN 53 765.<br />
The melting point is usually determined using a DSC instrument. The sample and an empty<br />
reference crucible are heated at 20 °C/min. The melting point corresponds to the maximum of<br />
the melting peak. To ensure better reproducibility, it is customary to use the values from the<br />
second heating operation. However, the melting point of certain grades is measured by an<br />
optical method (Mettler FP 82).<br />
Glass Transition Temperature<br />
Determination according to DIN 53 765.<br />
The glass transisition temperature is determined as for the melting point, but with a heating<br />
rate of 10 °C/min.<br />
Hydroxyl Number<br />
Determination according to DIN 53 240-02.<br />
Approx. 2-3 g of polyester are dissolved in dichloromethane or THF. The OH groups are<br />
esterified at RT with acetic anhydride, using 4-dimethyl-aminopyridine as catalyst. After<br />
hydrolysis of the unreacted anhydride, titration is carried out with 0.5 N methanolic KOH.<br />
Acid Number<br />
Determination according to DIN EN ISO 2114.<br />
Approx. 4 g of polyester are dissolved in 50 ml of tetrahydrofuran. Following addition<br />
of 50 ml of a mixture of equal parts by weight of tetrahydrofuran and ethanol, titration<br />
is carried out with methanolic or ethanolic KOH against phenolphthalein.<br />
Shore D Hardness<br />
Determination in accordance with DIN 53 505.<br />
All values refer to crystallized products.<br />
Viscosity Number<br />
Determination according to DIN 53 728.<br />
0.5 g of the test substance are dissolved in 100 ml of a mixture of 50 % by weight phenol and<br />
50 % by weight 1,2-dichlorobenzene. The viscosity of the solution and the solvent is<br />
determined by the Ubbelohde method. The viscosity number J is determined using the formula:<br />
J = [<br />
t 1<br />
- 1 ]<br />
1<br />
x<br />
t 2<br />
c<br />
t 1<br />
= flow time of solution [s]<br />
t 2<br />
= flow time of solvent [s]<br />
c = concentration of test substance [g/cm 3 ]<br />
35
DYNACOLL® S<br />
Analytical Methods<br />
Open Time<br />
Determination according to <strong>Evonik</strong> internal method.<br />
The open time is defined as the time between the application of the adhesive and the start<br />
of recrystallization – or in case of amorphous products until the surface becomes tack-free.<br />
Tensile Strength / Elongation at Break<br />
Determination in accordance with DIN EN ISO 527-1/3.<br />
It is determined on standard dumbbell-shaped specimens. The elongation at break denotes<br />
the percentage increase in length of an original section of 10 mm marked on the bar of the<br />
dumbbell specimen, at the moment of rupture.<br />
Melt Flow Rate (MFR)<br />
Determination according to DIN ISO 1133.<br />
Approx. 10 g of the test sample are placed in a temperature-conditioned metal cylinder.<br />
Via a cylindrical die, a force of 21.6 N acts on the melted sample. The weight of sample<br />
flowing through the standardized nozzle within a measured time is used to calculate the<br />
MFR. The MFR is expressed as the weight of sample extruded in 10 minutes. The densities<br />
for calculating the melt volume index (MVI) are listed in the specific technical data sheets.<br />
Melt Viscosity<br />
Determination according to DIN EN ISO 3219, parallel plate method.<br />
36
DYNACOLL® AC<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
Polyacrylates<br />
With its DYNACOLL® AC product range <strong>Evonik</strong> offers acrylics for one-component<br />
moisture curable hot melt adhesives.<br />
Acrylics for adhesives are bead polymers made of methyl methacrylate and n-butyl<br />
methacrylate which are mainly used to modify reactive hot melts for flat lamination<br />
applications.<br />
Various DYNACOLL® AC grades with tailored glass transition temperature and<br />
molecular weight are available. They also differ according to their acid and hydroxyl<br />
functionality.<br />
DYNACOLL® AC polyacrylates are supplied as beads in bags of 25 kg.<br />
Your benefits<br />
• DYNACOLL® AC provides outstanding quality and flow properties<br />
• DYNACOLL® AC modified reactive hot melts provide<br />
• low viscosity<br />
• very long open time<br />
• aggressive tack<br />
• high creep resistance directly after bonding<br />
37
DYNACOLL® AC<br />
Product Range<br />
Properties<br />
Glass<br />
Transition<br />
Temperature<br />
Tg<br />
Molecular<br />
Weight<br />
Mw<br />
Viscosity<br />
Number<br />
Acid<br />
Number<br />
Hydroxyl<br />
Number<br />
Softening<br />
Point<br />
(R&B)<br />
Melt Flow Rate<br />
190 °C<br />
[°C] [g/mol] [cm 3 /g] [mg KOH/g] [mg KOH/g] [°C] [g/10 min]<br />
Bead Polymers<br />
AC 1420 44 30,000 16 6 120 1,000<br />
AC 1520 48 35,000 19 8.5 135 500<br />
AC 1631 57 60,000 30 9 150 60<br />
AC 1620 56 35,000 19 8 140 300<br />
AC 1630 63 60,000 30 8 150 20<br />
AC 1750 65 140,000 54 4 190 9<br />
AC 1920 85 37,000 22 6 160 70<br />
AC 4830 82 60,000 30 175 8<br />
AC 2740 70 80,000 36 4 170 7<br />
38
DYNACOLL® AC<br />
Applications<br />
DYNACOLL® AC grades are mainly used to modify reactive hot melts for<br />
flat lamination purposes.<br />
Typical areas of application are:<br />
• Sandwich composites<br />
of aluminium, FRP panels, foam or wood-based substrates<br />
e. g. for recreational vehicals<br />
• Honeycomb structures<br />
e.g. for door manufacturing<br />
• Foil laminated particleboard<br />
e.g. for furniture<br />
• Medium density fiberboard panels<br />
e.g. for furniture<br />
Flat lamination applications require long open times to permit long handling times<br />
needed to bond huge panels or sandwich composites. On the other hand, initial<br />
strength has to be very high to hold the bonded parts in place without any further<br />
mechanical fixation.<br />
Preparation of Reactive Hot Melts<br />
These requirements can be fulfilled by reactive hot melts. Such moisture curing<br />
hot melt adhesives are typically prepared by reacting polymer mixture of<br />
DYNACOLL® AC acrylics, DYNACOLL® 7000 polyester-polyols and polypropylene<br />
glycols with excess diisocyanantes like MDI (Diphenylmethane diisoyanates) at<br />
elevated temperatures under exclusion of moisture.<br />
These reactive hot melts can be applied e.g. with roller coaters.<br />
39
DYNACOLL® AC<br />
Analytical Methods<br />
Glass Transition Temperature<br />
Determination according to ISO 11357-1.<br />
Molecular Weight<br />
Determination according to DIN 55627-1.<br />
Viscosity Number<br />
Determination according to ISO 1628-1.<br />
Acid Number<br />
Determination according to DIN EN ISO 2114.<br />
Hydroxyl Number<br />
Determination according to DIN 53 240-02.<br />
Softening Point (Ring and Ball)<br />
Determination according to DIN ISO 4625.<br />
Melt Flow Rate 190 °C<br />
Determination according to DIN ISO 1133 (21.6 N).<br />
40
DYNACOLL® Terra<br />
Bio-based Polyester-Polyols<br />
Terra<br />
<strong>Evonik</strong>. Power to create.<br />
41
DYNACOLL® Terra<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
Bio-based Polyester-Polyols<br />
With its DYNACOLL® Terra product range <strong>Evonik</strong> offers polyester-polyols made<br />
from renewable raw materials.<br />
These bio-based polyesters contain between > 30 and 100 ppw of renewable<br />
monomers.<br />
According to our DYNACOLL® 7000 product range a building block system of<br />
medium molecular weight copolyesters for moisture curing PUR hot melts was<br />
developed. It is divided in three basic groups:<br />
• Amorphous Grades<br />
• Liquid Grades<br />
• Crystalline Grades<br />
DYNACOLL® Terra bio-based polyesters are usually supplied in 25 or 30 kg and<br />
190 or 200 kg steel drums.<br />
Your benefits<br />
• support of resource efficiency by using green components<br />
• modular combination of polyesters in RHM formulation possible<br />
• available grades exhibiting broad range of properties in formulations<br />
• well-balanced and versatile adhesion properties<br />
• implementation of new properties possible<br />
42
DYNACOLL® Terra<br />
Product Range<br />
Properties<br />
Proportion of<br />
Renewables<br />
Hydroxyl<br />
Number<br />
Molecular<br />
Weight<br />
Glass<br />
Transition<br />
Temperature<br />
Melting<br />
Point<br />
Softening<br />
Point<br />
(R&B)<br />
Melt<br />
Viscosity<br />
Grade [%] [mg KOH/g] [g/mol] [°C] [°C] [°C] [Pa s]<br />
Amorphous<br />
EP 413.01 > 30 30 3,500 30 85 35 (130 °C)<br />
EP 413.02 > 30 30 3,500 30 85 32 (130 °C)<br />
EP 413.03 > 35 40 2,800 40 90 17 (130 °C)<br />
EP 413.04 > 30 50 2,200 50 95 15 (130 °C)<br />
Liquid<br />
EP 424.01 > 85 30 3,500 -40 4 (80 °C)<br />
EP 424.02 > 75 30 3,500 -45 4 (80 °C)<br />
Crystalline<br />
EP 481.01 100 30 3,500 -45 55 65 2 (80 °C)<br />
EP 480.01 100 30 3,500 -20 65 75 2 (80 °C)<br />
EP 480.02 > 60 30 3,500 70 80 2 (80 °C)<br />
Acid number < 2 mg KOH/g<br />
43
DYNACOLL® Terra<br />
Reactive Hot Melt Data<br />
Reaction products of DYNACOLL Terra with: 4,4‘ – MDI as a ratio of OH : NCO = 1 : 2.2<br />
Properties<br />
Softening<br />
Point (R&B)<br />
Open Time Setting Time Melt Viscosity<br />
at 130 °C<br />
Trensile<br />
Strength<br />
Elongation at<br />
Break<br />
Grade [°C] [s] [s] [Pa s] [N/mm 2 ] [%]<br />
Amorphous<br />
EP 413.01 102 1 1 200 brittle<br />
EP 413.02 103 1 1 400 brittle<br />
EP 413.03 100 1
DYNACOLL® Terra<br />
Analytical Methods<br />
Hydroxyl Number<br />
Determination according to DIN 53 240-02.<br />
Acid Number<br />
Determination according to DIN EN ISO 2114.<br />
Glass Transition Temperature<br />
Determination according to DIN 53 765.<br />
Melting Point<br />
Determination according to DIN 53 765.<br />
Softening Point (Ring and Ball)<br />
Determination according to DIN ISO 4625.<br />
Melt Viscosity<br />
Determination according to DIN EN ISO 3219.<br />
Open Time<br />
Determination according to <strong>Evonik</strong> internal method.<br />
The material is heated up to 130 °C and applied on paper as an approximately 0.5 mm thick<br />
film. Strips of open surface paper are pressed into the melt at certain intervals. After the<br />
adhesive film is tackfree the paper strips are removed. The open time is given by the time,<br />
when no fiber tear can be observed anymore.<br />
Setting Time<br />
Determination according to <strong>Evonik</strong> internal method.<br />
The setting time is given by the time it takes until two bonded wooden cubes can no longer<br />
be twisted against each other by hand.<br />
45
VESTOPLAST®<br />
Amorphous Poly-alpha-olefins<br />
<strong>Evonik</strong>. Power to create.<br />
46
VESTOPLAST®<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
Amorphous Poly-alpha-olefins<br />
With its VESTOPLAST® amorphous poly-alpha-olefins (APAO) <strong>Evonik</strong> offers<br />
a broad range of co- and terpolymers of ethene, propene and 1-butene as raw<br />
materials for various applications.<br />
Under variation of monomer composition, molecular weight and chemical<br />
modification optimum values are achieved for properties like hardness, melt<br />
viscosity, crystallinity and rate of crystallization.<br />
The production process allows us to offer both predominately amorphous, soft<br />
grades as well as harder, partially crystalline grades.<br />
In addition to our regular, pure thermoplastic grades we also offer unique reactive,<br />
silane-modified amorphous poly-alpha-olefins like VESTOPLAST® 206.<br />
VESTOPLAST® is usually supplied as granules in 20 kg polyethylene bags.<br />
A special wax powdering technique improves the flowability of the material.<br />
Your benefits<br />
• excellent adhesion and hot tack properties<br />
• bonding to various substrates<br />
• good cohesion and high thermal stability<br />
• good moisture and gas barrier behaviour<br />
• very good hydrolytic and UV stability<br />
47
VESTOPLAST®<br />
Product Range<br />
Properties<br />
Melt Viscosity<br />
at 190°<br />
Softening Point<br />
(Ring & Ball)<br />
Needle<br />
Penetration<br />
(100/25/5)<br />
Thermal Stability<br />
under Load<br />
S.A.F.T.<br />
Tensile Strength/<br />
Elongration at<br />
Break<br />
Shear Modulus<br />
at 23 °C<br />
Molecular Weight Open Time Glass Transition<br />
M n<br />
/ M w<br />
Temperature Tg<br />
DSC analysis<br />
Density<br />
at 23 °C<br />
Shore Hardness A<br />
[mPa s] [°C] [0.1 mm] [°C] [MPa / %] [MPa] [g/mol] [s] resp. [min] [°C] [g/cm 3 ]<br />
(1-) Butene-rich<br />
308 8,000 ± 2,000 136 ± 6 17 ± 3 65 – 70 1.5 / 500 14 11,300 / 49,000 4 min -29 0.87 n.d.<br />
408 8,000 ± 2,000 118 ± 4 5 ± 2 85 – 90 6.8 / 80 70 11,600 / 48,000 65 s -27 0.90 94<br />
508 8,000 ± 2,000 84 ± 4 14 ± 3 60 – 65 1.5 / 340 12 11,800 / 52,000 15 min -31 0.87 74<br />
520 22,000 ± 4,000 87 ± 4 14 ± 3 65 – 70 2.4 / 80 7 13,900 / 63,000 15 min -29 0.88 76<br />
608 9,000 ± 3,000 157 ± 4 18 ± 3 60 – 65 1.5 / 480 11 12,300 / 46,000 3 min -32 0.87 76<br />
Propene-rich<br />
703 2,700 ± 700 124 ± 6 12 ± 3 75 – 80 2.1 / 43 41 7,300 / 34,000 15 s -28 0.87 87<br />
704 3,500 ± 500 105 ± 5 23 ± 5 70 – 75 0.5 / 100 7.5 8,000 / 35,000 80 s -36 0.87 n.d.<br />
708 8,000 ± 2,000 106 ± 4 19 ± 3 85 – 90 1.0 / 330 4 11,500 / 75,000 55 s -33 0.87 67<br />
750 50,000 ± 10,000 107 ± 4 14 ± 3 85 – 90 5.0 / 1,000 14 18,100 / 92,000 50 s -33 0.87 75<br />
751 50,000 ± 10,000 99 ± 4 25 ± 3 60 – 65 1.5 / 1,000 2 18,800 / 88,000 30 min -33 0.87 43<br />
792 120,000 ± 30,000 108 ± 4 14 ± 3 90 – 95 5.8 / 1,200 7 23,800 / 118,000 2 min 30 s -27 0.87 n.d.<br />
828 25,000 ± 7,000 161 ± 4 22 ± 3 95 – 100 1.0 / 550 4 13,200 / 61,000 70 s -35 0.87 55<br />
888 120,000 ± 40,000 161 ± 5 16 ± 4 115 – 120 2.5 / 850 6.5 15,000 / 104,000 4 s -36 0.87 n.d.<br />
891 115,000 ± 35,000 162 ± 4 22 ± 4 105 – 110 2.0 / 1,000 3 18,800 / 85,000 40 s -33 0.86 n.d.<br />
EP NC 702 2,800 ± 500 105 ± 4 36 ± 5 60 – 65 0.4 / 200 n.d. n.d. > 30 min -22 n.d. n.d.<br />
EP 807 7,000 ± 2,000 161 ± 3 7 ± 3 125 – 130 4.0 / 40 n.d. n.d. < 2 s -28 n.d. n.d.<br />
Silane modified<br />
206 5,000 ± 1,000 98 ± 4 19 ± 3 > 160 * 1.9 / 720 n.d. 10,600 / 38,000 approx. 20 s -28 0.87 n.d.<br />
*<br />
after curing<br />
n.d. = not determined<br />
48
VESTOPLAST® Applications<br />
206<br />
308<br />
408<br />
508<br />
520<br />
608<br />
703<br />
704<br />
708<br />
750<br />
751<br />
792<br />
828<br />
888<br />
891<br />
EP NC 702<br />
EP 807<br />
S/SR<br />
Hygiene<br />
Diapers, Feminine & Adult Care ▯ ▯ ▯ ▯ ▯ ▯<br />
Woodworking<br />
Profile wrapping ▯ ▯ ▯<br />
Edge banding ▯ ▯ ▯ ▯<br />
Paper & Packaging<br />
Laminated paper ▯ ▯ ▯<br />
Labels ▯ ▯ ▯<br />
Bookbinding ▯ ▯ ▯ ▯<br />
Fruit juice container ▯ ▯ ▯<br />
Automotive<br />
Headliner ▯ ▯<br />
Door panels ▯ ▯ ▯ ▯<br />
Filters ▯ ▯ ▯ ▯ ▯ ▯<br />
Car lamps ▯ ▯ ▯ ▯ ▯<br />
Insulating Felts ▯ ▯ ▯ ▯<br />
Carpet/Textile Flooring<br />
Carpet tiles ▯ ▯<br />
Wall to wall carpets ▯ ▯<br />
Car carpets ▯ ▯ ▯ ▯<br />
Bitumen<br />
Membranes (Roofing & Bridges) ▯ ▯ ▯<br />
Road construction<br />
▯<br />
Various Applications<br />
Cable fillings ▯ ▯<br />
Masterbatches ▯ ▯ ▯<br />
Mattrasses ▯ ▯ ▯ ▯ ▯<br />
Shoes ▯ ▯ ▯ ▯<br />
White goods ▯ ▯ ▯ ▯ ▯<br />
Window & Solar cell sealants ▯ ▯ ▯ ▯<br />
49
VESTOPLAST®<br />
Analytical Methods<br />
Melt Viscosity<br />
Determination according to DIN 53 019, modified.<br />
The melt viscosity is determined by a rotational viscosimeter. It describes the melting flow<br />
behaviour at 190 °C, high viscous grades exhibit a slight dependence on shear rate, low viscous<br />
grades are almost newtonian at elevated tempertaures.<br />
Softening Point (Ring & Ball)<br />
Determination according to DIN EN 1427.<br />
The material is heated up at 180 °C and then the melt is casted into a ring. After 24 h (this time<br />
is needed for recrystallization of the amorphous products) the sample is stressed concentrically<br />
with a chrome-plated steel ball and the test frame is immersed in a bath of glycerin. This is<br />
heated up with approx. 5 °C/min and the softening point is the temperature when the ball<br />
contacts the baseplate of the test frame.<br />
Needle Penetration<br />
Determination according to DIN EN 1426, modified.<br />
The material is heated up at 180 °C in a thin can. After 24 h (this time is needed for<br />
recrystallization of the amorphous products) the hardness of the product is determined with<br />
a needle and weight of 100 g at 25 °C. The penetration time into the sample is 5 s.<br />
Thermal Stability under Load / S.A.F.T.<br />
Determination according to <strong>Evonik</strong> method, similar to WPS 68.<br />
The thermal stability under load describes the thermal stability behaviour of bonded substrates.<br />
In case of VESTOPLAST® we use grey board to compare each VESTOPLAST® grade with<br />
another. A drop of the melt (180 °C) is placed on a side of the board and that is pressed to<br />
another grey board (T-form). After 24 h the prepared specimen are placed in a heating cabinet<br />
with a weight of 450 g and heated up with 5 °C/h. The thermal stability is the temperature<br />
when the bonded specimen breaks down.<br />
Tensile Strength / Elongation at Break<br />
Determination according to DIN EN ISO 527-3, modified type 5.<br />
The tensile strength describes the tensile and elongation properties of a specimen type 3 with<br />
2 mm thickness.<br />
Shear Modulus at 23 °C<br />
Determination according to DIN EN ISO 6721-2.<br />
This part specifies the general principles of a method for determining the dynamic rheological<br />
properties of polymer melts, part 2 described the Torsion-pendulum method.<br />
Molecular Weight Mn/Mw<br />
Determination according to GPC, DIN 55 672, modified.<br />
The molecular weight is calculated according to GPC, DIN 55672-1, detailed in Mn and Mw.<br />
Open Time<br />
Determination according to <strong>Evonik</strong> internal method.<br />
The melt (180 °C) is applied as a film of 20 μm on a paper. Strips of paper are pressed into the<br />
film at certain intervalls (depending on the open time). 30 minutes after the last strip has been<br />
applied, a test is carried out to see which of the last strips applied can be lifted off without<br />
pulling out the paper fibers. The time at which this strip was applied is noted.<br />
50
VESTOPLAST®<br />
Analytical Methods<br />
Glass Transition Temperature<br />
Determination according to DIN 53 765.<br />
Density at 23 °C<br />
Determination according to DIN EN ISO 1183-1.<br />
Shore Hardness A<br />
Determination according to GPC, DIN 53 505.<br />
This determination specifies the hardness of a specimen. The resistance against penetration<br />
of a specific form and specific spring tension. The values are depending on the visco-elastic<br />
properties of the polymer.<br />
51
VESTOWAX®<br />
Fischer-Tropsch-Waxes<br />
<strong>Evonik</strong>. Power to create.<br />
52
VESTOWAX®<br />
The Value Additive<br />
Synthetic Waxes<br />
With its VESTOWAX® product range <strong>Evonik</strong> offers synthetic waxes produced<br />
by Fischer-Tropsch-Process.<br />
This process yields straight-chain products possessing low viscosity in the melt<br />
and having molecular weights of between 500 and 1,000 g/mol.<br />
The definition of the term ›wax‹ is based less on the chemical composition of<br />
a substance than on its physical properties:<br />
• kneadable at 20 °C, with a consistency ranging from solid to brittle-hard<br />
• coarsely to finely crystalline, translucent to opaque<br />
• melt above 40 °C without decomposition<br />
• already of relatively low viscosity at just above the melting point<br />
• highly temperature-dependent consistency and solubility<br />
• can be polished under gentle pressure<br />
In addition to crude FT-wax, the range of VESTOWAX® products includes<br />
modified hard paraffins, oxidates and partially saponified waxes.<br />
Depending on the supply form different bags sizes are offered:<br />
Prills usually in 25 kg bags or 700 kg big bags, pellets and coarse powder usually<br />
in 20 kg bags, microfine powder usually in 15 kg bags.<br />
Your benefits<br />
• solutions for a multitude of applications<br />
• extensive range of FT-modified grades<br />
• wide variety of supply forms - from pellets to microfine powder<br />
53
VESTOWAX®<br />
Product Range<br />
Properties<br />
Supply Form Drop Point Penetration<br />
Number<br />
Acid Number<br />
Saponification<br />
Number<br />
Molecular Mass<br />
Mw<br />
Density<br />
at 23 °C<br />
Viscosity<br />
Color<br />
[°C] [mm 10-1] [mg KOH/g] [mg KOH/g] [g/mol] [g/cm 3 ] [mPa s]<br />
Crude FT-Wax * )<br />
GTL Sarawax SX 105 Prills 114 – 120 1 ~ 900 ~ 0.94 < 20 (at 130 °C) white<br />
GTL Sarawax SX 100 Prills 108 – 112 1 ~ 700 ~ 0.94 < 20 (at 120 °C) white<br />
VESTOWAX Hard paraffins<br />
EH 100 Pellets 102 – 110 2 – 5 ~ 600 ~ 0.94 < 20 (at 120 °C) white<br />
SH 105 Pellets 108 – 114 1 ~ 750 ~ 0.94 < 20 (at 120 °C) white<br />
SH 105 Powder 112 – 116 1 ~ 750 ~ 0.94 < 20 (at 120 °C) white<br />
H 2050 MG Powder 114 – 120 1 ~ 900 ~ 0.94 < 20 (at 130 °C) white<br />
H 2050 SF Microfine Powder 114 – 120 1 ~ 900 ~ 0.94 < 20 (at 130 °C) white<br />
SH 112 Microfine Powder 114 – 120 1 ~ 900 ~ 0.94 < 20 (at 130 °C) white<br />
FM 1012 Microfine Powder 114 – 120 1 ~ 1.00 < 20 (at 130 °C) white<br />
VESTOWAX Oxidates<br />
C 20 Flakes 106 – 111 1 – 3 10 – 13 20 – 30 ~ 0.96 < 20 (at 120 °C) white<br />
C 40 Micro Prills 102 – 108 2 – 4 24 – 27 40 – 50 ~ 0.96 < 20 (at 130 °C) white<br />
C 60 Flakes & Powder 100 – 105 3 – 5 29 – 34 50 – 62 ~ 0.96 < 20 (at 120 °C) white<br />
*)<br />
Available from <strong>Evonik</strong> in Europe only.<br />
54
VESTOWAX®<br />
Applications<br />
Crude FT-WAX * )<br />
VESTOWAX Grades<br />
Sarawax<br />
SX 105<br />
Sarawax<br />
SX 100<br />
EH 100<br />
SH 105<br />
H 2050 MG<br />
H 2050 SF<br />
SH 112<br />
FM 1012<br />
C 20<br />
C 40<br />
C 60<br />
Hot Melts<br />
Crystallinity improver ▯ ▯ ▯<br />
Viscosity reducer ▯ ▯ ▯<br />
Melting point improver ▯ ▯ ▯<br />
Surface stickiness reducer ▯ ▯ ▯<br />
Plastics Processing<br />
Lubricants for PVC ▯ ▯ ▯<br />
Nucleating agent for expandable polystyrene ▯ ▯<br />
Dispersing aid for pigments and fillers ▯ ▯ ▯<br />
Processing aid for rubber ▯ ▯<br />
Internal mould release agent for thermosetting plastics ▯ ▯<br />
Mould release agent for waterborne systems ▯ ▯<br />
Mould release agent for solventborne systems ▯ ▯<br />
Printing Inks<br />
Rub resistance ▯ ▯ ▯<br />
Slip improver and anti-blocking agent ▯ ▯ ▯<br />
Paints<br />
Scratchproofing agent ▯ ▯ ▯<br />
Matting agent ▯ ▯<br />
Processing aid for powder coatings<br />
▯<br />
Technical Emulsions<br />
Sewing Yarn lubricant ▯ ▯<br />
Sizing agent<br />
▯<br />
Cosmetics<br />
Lipstick hardener ▯ ▯<br />
Oil binder for pastes ▯ ▯<br />
Dispersing aid for color-cosmetics<br />
▯<br />
Polishes<br />
Dry-bright emulsions ▯ ▯<br />
Solventborne systems ▯ ▯<br />
Wax Compounds & Candle Additives<br />
Dispersing aid for dyes ▯ ▯<br />
Hardening ▯ ▯ ▯<br />
*)<br />
Available from <strong>Evonik</strong> in Europe only.<br />
55
VESTOWAX®<br />
Analytical Methods<br />
Drop Point<br />
Determination according to DGF M-III 3.<br />
Also in accordance with DIN 51 801 or ASTM D 566.<br />
Penetration Number<br />
Determination according to DGF M-III 9b.<br />
Also in accordance with DIN 51 579 or ASTM D 1321.<br />
Acid Number<br />
Determination according to DGF M-IV 2.<br />
Also in accordance with DIN 53 402 or ASTM D 1386.<br />
Saponification Number<br />
Determination according to DGF M-IV 2.<br />
Also in accordance with DIN 53 401 or ASTM D 1387.<br />
Molecular Mass<br />
Determination by HT-GPC.<br />
Density at 23 °C<br />
Determination according to DIN 53 479.<br />
Viscosity<br />
Determination according to DIN 52 007/1.<br />
56
POLYVEST®<br />
Liquid Polybutadienes<br />
<strong>Evonik</strong>. Power to create.<br />
57
POLYVEST®<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
Liquid Polybutadienes<br />
With its POLYVEST® <strong>Evonik</strong> offers a range of stereospecific, low viscous and<br />
unsaponifiable liquid polybutadienes of different chemical composition:<br />
• POLYVEST® - non-functionalized liquid polybutadienes<br />
• POLYVEST® MA - maleic anhydride-functionalized liquid polybutadienes<br />
• POLYVEST® HT - hydroxyl-terminated liquid polybutadienes<br />
Our non-functionalized products differ in molar mass and viscosity.<br />
The MA-functionalized products are adducts of linear polybutadiene and maleic<br />
anhydride and differ in maleic anhydride content and viscosity. The anhydride<br />
groups are randomly distributed along the polymer chains and thus make the<br />
originally apolar polybutadiene more polar and accessible for various chemical<br />
reactions.<br />
The hydroxyl-terminated product is an alpha-omega-terminated diol of<br />
polybutadiene manufactured by radical polymerisation process. In addition to the<br />
double bonds in the polymer backbone, the hydroxyl functional groups provide<br />
opportunities for precise chemical modifications.<br />
The non-functionalized POLYVEST® grades are supplied in steel drums with<br />
190kgs net. The maleic anhydride-functionalized grades are supplied in steel drums<br />
with 180kgs net and 900kgs net IBC. POLYVEST HT® is available in steel drums<br />
and IBC. Road tanker delivery is possible for all grades.<br />
Your benefits<br />
The microstructure of our POLYVEST® grades makes them a highly reactive<br />
and cross-linking binder and provides them with properties including:<br />
• excellent chemical resistance<br />
• high water resistance<br />
• very good electrical insulation<br />
• very good cold-resistance<br />
• low moisture and oxygen permeability<br />
Our POLYVEST® grades can be used in a broad field of applications.<br />
58
POLYVEST®<br />
Product Range<br />
POLYVEST® 110 130 MA 75 EP * MA 120 EP * HT<br />
Specifications<br />
Viscosity at 20 °C [mPa s] 700 – 860 2,700 – 3,300 6,000 – 9,000 approx. 61,000 (23 °C) –<br />
Viscosity at 30 °C [mPa s] – – – approx. 30,000 4,000 - 5,500<br />
Acid Number [mg KOH/g] ≤ 0.3 ≤ 0.3 70 – 90 approx. 130 –<br />
Hydroxyl Number [mg KOH/g] – – – – 44 - 51<br />
Peroxide Number [mval/kg] ≤ 10 ≤ 10 – – –<br />
Typical Data<br />
Supply Form viscous liquid viscous liquid viscous liquid viscous liquid viscous liquid<br />
Microstructure:<br />
1,4 -cis double bonds approx. 75% approx. 77%<br />
approx. 20%<br />
1,4 -trans double bonds approx. 24% approx. 22% based on POLYVEST 110<br />
approx. 58%<br />
1,2 -vinyl double bonds approx. 1% approx. 1% approx. 22%<br />
Molecular Weight M n<br />
[g/ mol] approx. 2,600 approx. 4,600 approx. 3,000 approx. 3,200 approx. 4,000<br />
Iodine No. [g lod/100g] 420 – 480 420 – 480 380 – 420 380 – 420 420 - 440<br />
Density at 20 °C [g/cm 3 ] 0.90 – 0.92 0.90 – 0.92 approx. 0.95 approx. 0.97 0.90 - 0.92<br />
Gardner Color ≤ 1 ≤ 4 ≤ 2.5 ≤ 2.5 ≤ 1<br />
Flash Point [°C] approx. 180 approx. 200 approx. 300 > 300 (DIN ISO 2592) approx. 215<br />
Ignition Temperature [°C] approx. 360 approx. 350 approx. 360 approx. 355 approx. 375<br />
Pour Point [°C] approx. -55 approx. -50 approx. -25 approx. -1 approx. -18<br />
Tg [°C] approx. -100 approx. -99 approx. -95 approx. -92 approx. -80<br />
*<br />
EP = Experimental Product<br />
59
POLYVEST®<br />
Product Range<br />
POLYVEST® 110 130 MA 75 EP * MA 120 EP * HT<br />
Compatibility of POLYVEST® Grades with binders and resins<br />
Acrylate resins Methacrylates – – – – –<br />
OH-acrylates ◦ – ◦ ◦ –<br />
Alkyd resins short-oil – – – – –<br />
medium-oil ◦ – ◦ ◦ –<br />
long-oil ◦ – + + ◦<br />
Carbamic acid resins – – – – –<br />
Cellulose esters – – – – –<br />
Epoxy resins, low molecular weight – – ◦ ◦ –<br />
Glycerol resin esters – – ◦ ◦ –<br />
Hydrocarbon resins + + ◦ ◦ +<br />
Ketone resins ◦ ◦ ◦ ◦ ◦<br />
Melamine resins – – ◦ ◦ –<br />
Nitrocellulose – – – – –<br />
Phthalate resins – – – – –<br />
Resols, unplasticized – – – – –<br />
Rosin esters + + + + +<br />
Rosin-modified phenolic resins – – – – –<br />
Saturated polyesters – ◦ – – –<br />
Styrene-alkyd resins – – – – –<br />
Urea resins, unplasticized – – ◦ ◦ –<br />
Zinc resinates + + + + +<br />
Solubility of POLYVEST® Grades<br />
Alcohols – – ◦ ◦ –<br />
Aliphatic hydrocarbons + + + + +<br />
Aromatic hydrocarbons + + + + +<br />
Esters ◦ ◦ ◦ ◦ ◦<br />
Ethers + + + + +<br />
Glycol ethers – – – – –<br />
Ketones ◦ ◦ ◦ ◦ ◦<br />
+ compatible / soluble ◦ limited compatibility / solubility – incompatible / insoluble<br />
The compatibility results represent 40 wt.% of the binder/resin with POLYVEST.<br />
The solubility reflects adding 90 and 50 wt.% of solvent to 10 and 50 wt.% POLYVEST.<br />
This information is based on our best knowledge and experience. We recommend conducting your own tests and experiments prior to use.<br />
*<br />
EP = Experimental Product<br />
60
POLYVEST®<br />
Applications<br />
non-functionalized MA-functionalized hydroxyl-terminated<br />
Liquide polybutadienes POLYVEST® 110 130 MA 75 EP * MA 120 EP * HT<br />
Automotive<br />
<strong>Adhesive</strong>s and Sealants ▯ ▯ ▯ ▯ ▯<br />
Coatings<br />
Air Drying Improver of Vegetable Oils ▯ ▯<br />
Defoamers<br />
▯<br />
Impregnations ▯ ▯<br />
Modifier in Resin Systems ▯ ▯<br />
Construction<br />
<strong>Adhesive</strong>s and Sealants / Insulated Glass Sealants<br />
▯<br />
Binder for dusty and dry Quartz Sand ▯ ▯<br />
Binder for Soil Stabilization<br />
▯<br />
Modifier of Silicone Sealants<br />
▯<br />
Electronics<br />
Electrical Insulations and Potting Compounds ▯ ▯ ▯ ▯<br />
Plastics<br />
Cell Opener for PU-Foam<br />
▯<br />
Release Agents for PU-Foam ▯ ▯ ▯<br />
Polymer Modification<br />
Chlorinated Rubbers ▯ ▯<br />
Electrocoatings<br />
Waterborne, oxidative drying Binders<br />
▯<br />
▯<br />
Printing & Inks<br />
Offset Printing Inks ▯ ▯<br />
Flexible Printing Plates ▯ ▯<br />
Rubber<br />
Binder for recycled Rubber Compounds ▯ ▯ ▯<br />
Modifier in Carbon Black-filled EPDM Compounds ▯ ▯<br />
Modifier in Silica-filled Rubber Compounds ▯ ▯<br />
Plasticizer in Rubber Compounds ▯ ▯<br />
Polymeric Chalk Activator in EPDM Compounds ▯ ▯<br />
*<br />
EP = Experimental Product<br />
61
POLYVEST®<br />
Analytical Methods<br />
Viscosity<br />
Determination according to DIN EN ISO 3219.<br />
Acid Number<br />
Determination according to DIN EN ISO 2114.<br />
Hydroxyl Number<br />
Determination according to DIN 53 240-2.<br />
Peroxide Number<br />
Determination according to DGF-method: C-VI-6a (84).<br />
Molecular Weight M n<br />
Determination according to DIN 55 627-1.<br />
Iodine Number<br />
Determination according to DIN 53 241.<br />
Density at 20 °C<br />
Determination according to DIN ISO 2811-1.<br />
Gardner Color<br />
Determination according to DIN EN ISO 4630-2.<br />
Flash Point<br />
Determination according to DIN EN ISO 2719.<br />
Determination according to DIN ISO 2592 (POLYVEST® EP * MA 120).<br />
Ignition Temperature<br />
Determination according to DIN 51 794.<br />
Pour Point<br />
Determination according to DIN ISO 3016.<br />
Glass Transition Temperature Tg<br />
Determination according to DIN EN ISO 11 357-1.<br />
Further information<br />
Storage<br />
POLYVEST® products are stable for at least 1 year with exclusion of air,<br />
light and moisture and at storage temperatures below 25 °C.<br />
Safety and Handling<br />
POLYVEST® products react with atmospheric oxygen to form peroxides<br />
and undergo cross-linking in its presence. Thus POLYVEST® products are<br />
packed and delivered under a blanket of inert gas (nitrogen). When<br />
handling, prevent any exposure of the products to atmospheric oxygen.<br />
Opened containers should be blanketed with inert gas again and closed<br />
tightly. Please refer to our Material Safety Data Sheets.<br />
62
DEGALAN®<br />
Binders for Heat Seal Lacquers<br />
<strong>Evonik</strong>. Power to create.<br />
63
DEGALAN®<br />
Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />
Binders for Heat Sealing Applications<br />
With its DEGALAN® binders <strong>Evonik</strong> offers a unique product portfolio of functional<br />
methacrylic polymers. These binders represent an excellent solution for heat sealing<br />
applications in the packaging industry.<br />
Our functional binders can be divided into four groups based on their appearance:<br />
• DEGALAN® - Bead Polymers<br />
• DEGALAN® - Organic Solutions<br />
• DEGALAN® - Organic Dispersions<br />
• DEGALAN® - Aqueous Dispersions<br />
Our DEGALAN® binders for heat sealing applications are ideally suited for<br />
formulation of high-quality lacquers to provide an excellent and secure heat sealing<br />
in combination with smooth peeling.<br />
DEGALAN® organic dispersions provide direct adhesion to aluminium or PET lid<br />
material for economical and environmentally friendly packaging solutions.<br />
All common cup materials from polar polystyrene to non-polar polypropylene<br />
can be sealed.<br />
All products comply with international regulations for incident food contact.<br />
DEGALAN® methacrylate bead polymers are usually supplied in paper bags.<br />
DEGALAN® organic solutions, dispersions as well as aqueous dispersions can<br />
be supplied in drums, IBCs or tank trucks.<br />
Your benefits<br />
• excellent seal and peel properties on aluminium foil or film structures<br />
• outstanding smooth peel effect<br />
• wide property range: from easy opening to high sealing strength<br />
• multi-purpose sealing capabilities to various substrates<br />
• economical and environmental friendly packaging solutions<br />
64
DEGALAN®<br />
Product Range<br />
Properties<br />
Solvent<br />
Solid<br />
Content<br />
Viscosity<br />
Number<br />
Dynamic<br />
Viscosity<br />
1) 3)<br />
Dilutability<br />
2) 3)<br />
Solubility<br />
Sealability versus<br />
[%]<br />
[cm 3 /g]<br />
[mPa·s]<br />
[N/mm 2 ]<br />
DEGALAN® Bead Polymer<br />
P 24 – 100 approx. 55 approx. 450 4) E, K PS, PVC<br />
VP P 34 – 100 approx. 55 approx. 450 4) E, K PS, PVC<br />
DEGALAN® Organic Solution<br />
4792 L Methyl ethyl ketone 55 approx. 40 1,000 – 3,000 E, K PS, PVC<br />
4793 L Ethyl acetate 55 approx. 40 2,000 – 5,000 E, K PS, PVC<br />
DEGALAN® Organic Dispersion<br />
PM 555<br />
PM 666<br />
n-Butyl acetate/<br />
Methyl ethyl ketone<br />
70/30<br />
n-Butyl acetate/<br />
Methyl ethyl ketone<br />
70/30<br />
45 approx. 125 500 – 1,500 E, K PS, PVC, PP, PET<br />
45 approx. 125 1,000 – 3,500 E, K PS, PVC, PP, PET<br />
4150 E n-Propyl acetate/Ethyl<br />
acetate/Isooctane<br />
54/36.5/9.5<br />
4151 E n-Propyl acetate/Ethyl<br />
acetate/Isooctane<br />
47.8/43.8/8.4<br />
43 approx. 125 800 – 2,500 E, K PS, PVC, PP, PET<br />
40 approx. 125 500 – 2,000 E, K PS, PVC, PP, PET<br />
VP 4190 E<br />
VP 4311 E<br />
VP 4174 E<br />
n-Propyl acetate/Ethyl<br />
acetate/Cyclohexane<br />
60/37/3<br />
n-Propyl acetate/<br />
Cyclohexane 84/16<br />
n-Propyl acetate/Ethyl<br />
acetate/Isooctane<br />
49/42.5/8.5<br />
44 approx. 125 1,000 – 3,500 E, K PS, PVC, PP, PET<br />
40 approx. 65 500 – 2000 E, K PS, PVC, PET<br />
46 approx. 125 1,000 – 3,500 E, K PS, PVC, PP, PET<br />
DEGALAN® Aqueous Dispersion<br />
4140 D Water 50 not determined approx. 100 W PLA, Primer for<br />
aluminium<br />
4032 D Water 50 not determined approx. 100 W PS, PVC<br />
VP 4240 D Water 50 not determined approx. 300 - 400 W PS, PVC<br />
1)<br />
for dispersions and solutions<br />
2)<br />
for solids<br />
3)<br />
E = Esters, K = Ketones, W = Water<br />
4)<br />
40% in MEK<br />
65
DEGALAN®<br />
Applications<br />
Adhesion to Aluminum Adhesion to PET Sealable versus<br />
Direct<br />
Primered<br />
with<br />
PVC 1)<br />
In formulation<br />
with PVC<br />
Direct<br />
Primered<br />
with<br />
PES 2)<br />
In formulation<br />
with PVC<br />
PVC PS PP PET<br />
P 24 ▯ ▯ ▯ ▯ ▯ ▯<br />
VP P 34 ▯ ▯ ▯<br />
4792 L ▯ ▯ ▯ ▯ ▯ ▯<br />
4793 L ▯ ▯ ▯ ▯ ▯ ▯<br />
PM 555 ▯ ▯ ▯ ▯ ▯ ▯ ▯<br />
4150 E ▯ ▯ ▯ ▯ ▯ ▯ ▯<br />
VP 4190 E ▯ ▯ ▯ ▯ ▯ ▯ ▯<br />
PM 666 ▯ ▯ ▯ ▯ ▯ ▯<br />
4151 E ▯ ▯ ▯ ▯ ▯ ▯<br />
VP 4311 E ▯ ▯ ▯ ▯ ▯<br />
VP 4174 E ▯ ▯ ▯ ▯ ▯ ▯<br />
4140 D ▯ ▯ 3) ▯ 3)<br />
4032 D ▯ ▯ ▯<br />
VP 4240 D ▯ ▯ ▯<br />
1)<br />
PVC adhesion promoter like Vinnol® terpolymer grade from e.g. Wacker Chemie <strong>AG</strong>, Burghausen, Germany<br />
2)<br />
Polyester like Dynapol® L 206 oder L 208 from <strong>Evonik</strong> <strong>Industries</strong> <strong>AG</strong>, Marl, Germany<br />
3)<br />
PLA (Poly lactic acid)<br />
66
DEGALAN®<br />
Analytical Methods<br />
Solid Content<br />
Determination according to DIN EN ISO 3251.<br />
Dynamic Viscosity<br />
Determination according to DIN EN ISO 3219.<br />
Glass Transition Temperature Tg<br />
Determination according to DIN 53765 bzw. DIN EN ISO 11357-1.<br />
Viscosity Number<br />
Determination according to DIN 51562 bzw. DIN EN ISO 1628-1.<br />
Molecular Weight (Mw)<br />
Determination according to DIN 55672-1.<br />
67
If you need more information please contact us:<br />
adhesives@evonik.com<br />
www.evonik.com/designed-polymers<br />
This information and all further technical advice is based on our present knowledge<br />
and experience. However, it implies no liability or other legal responsibility on our part,<br />
including with regard to exisiting third party intellectual property rights, especially<br />
patent rights. In particular, no warranty, whether express or implied, or guarantee of<br />
product properties in the legal sense is intended or implied. We reserve the right to<br />
make any changes according to technological progress or further developments. The<br />
customer is not released from the obligation to conduct careful inspection and testing<br />
of incoming goods. Performance of the product described herein should be verified by<br />
testing, which should be carried out only by qualified experts in the sole responsibility<br />
of a customer. Reference to trade names used by other companies in neither a<br />
recommendation, nor does it imply that similar products could not be used.<br />
(September 2013)<br />
68