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Sales folder english - Adhesive Resins - Evonik Industries AG

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Flying the flag<br />

for customized solutions<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

<strong>Evonik</strong>. Power to create.


Designed Polymers<br />

for <strong>Adhesive</strong>s & Sealants<br />

<strong>Evonik</strong>. Power to create.


Flying the flag<br />

for customized solutions<br />

<strong>Evonik</strong> is one of the largest suppliers to the adhesives and sealants industry.<br />

With our Product Line <strong>Adhesive</strong> <strong>Resins</strong> we are clearly focussing this industry<br />

along with a dedicated vision:<br />

We want to be the first choice, whenever you are looking for polymer solutions<br />

for the industrial adhesives and sealants market! We want to be your preferred<br />

partner whenever particular competencies and market knowledge are needed<br />

and you are looking for individual solutions.<br />

On our path of becoming a solution provider, we continue to focus on the strengths<br />

that have served us well in the past:<br />

• customer orientation<br />

• reliability<br />

• know-how<br />

• future orientation.<br />

These are the four pillars on which we develop innovative solutions that are<br />

dedicated to one thing only: the success of our customers!<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

What does this mean for us<br />

And why is <strong>Evonik</strong> the right partner for your solutions<br />

Please find some more information on how we see ourselves and our<br />

competencies as well as our global customer approach on the next pages.<br />

The second chapter of this sales <strong>folder</strong> contains detailed technical<br />

information about our Designed-Polymer-Portfolio.<br />

4


Focus on Customer Orientation<br />

and Reliability<br />

An eye for innovation. Attention to customer needs.<br />

As the experts within <strong>Evonik</strong> for the <strong>Adhesive</strong>s & Sealants Industry, we are dedicated<br />

to customer service. We want to position ourselves as a provider of customized<br />

solutions and be the first choice of our customers when it comes to resolving<br />

challenges in the adhesives and sealants industry.<br />

Thanks to our global presence on all five continents and in more than 100 countries,<br />

we can respond flexibly and personally to the needs of our partners. This includes<br />

rapid innovation and the quick advancement of unique products and system solutions<br />

from the idea stage to market maturity – for the development of innovative polymers<br />

and formulations and for demanding optimizations alike. Our goal is to develop<br />

solutions that provide maximum benefit for our customers and our society.<br />

You give us your trust. We give you our word.<br />

We are convinced that closeness to customers and developing solutions in<br />

teamwork are the keys to success. That is why we work closely with our partners<br />

and involve them actively into our research and development work. This approach<br />

has helped us advance a number of highly successful solutions around the world.<br />

The relationship with our customers is characterized by reliability and trust.<br />

There is good reason why some of our customer relationships have existed<br />

for more than 25 years. We always treat our partners as equals and take them<br />

and their wishes very seriously. We consider it fundamental to keep<br />

our word and to guarantee a consistently high quality standard<br />

for our solutions.<br />

5


Know-How<br />

and Future Orientation<br />

Our milestones set the standard and secure success.<br />

Our success is based on our expertise in research and development. Our research<br />

teams around the world allow us to maintain and expand our technology leadership<br />

in the area of adhesives and sealants. In short, we set milestones.<br />

The close dialog with our partners produces innovations that stand out for their<br />

optimized performance, high efficiency and improved environmental compatibility,<br />

such as polymers with excellent bonding properties, better adhesion and optimized<br />

curing properties.<br />

Our milestones include tailor-made granulated amorphous poly(alpha)olefins,<br />

polyester polyols for moisture-curing one-component hot melt adhesives, reactive<br />

silane-modified amorphous poly(alpha)olefins, as well as acrylates and bio-based<br />

polyesters for reactive hot melts – in addition to highly reactive liquid<br />

polybutadienes for high performance adhesives and sealants and acrylic-based<br />

heat sealing lacquers for superior seal and peel performance.<br />

These are just some examples of the unique solutions we have developed to unlock<br />

specific applications and enhance the global productivity and success of<br />

our customers.<br />

Knowledge is the way. The future is the goal.<br />

Our goal is to conquer new markets and to consistently stay a step ahead, to<br />

recognize trends, and to use them profitably for our partners. Future viability and<br />

sustainability are particularly important factors in this regard. We not only keep an<br />

eye on the here and now, but also never forget about tomorrow and coming<br />

generations.<br />

This approach is reflected, for instance, in our nearly 100% solvent-free product<br />

range and the most recent example of our innovative strength: bio-based polyesterpolyols,<br />

a new product group developed on the basis of renewable raw materials.<br />

Our new investment in hydroxyl-terminated polybutadiene (HTPB) expands our<br />

portfolio and positions us to provide solutions related to megatrends like energy<br />

saving and resource efficiency.<br />

6


Our competencies<br />

for designed polymers<br />

Capabilities<br />

Designed<br />

Polymers for<br />

<strong>Adhesive</strong>s &<br />

Sealants<br />

Customer Needs<br />

Backbone Chemistry<br />

Capabilities<br />

Research & Development<br />

Applied Technology<br />

Analytical Department<br />

Engineering<br />

Scale-up and Production Facilities<br />

Marketing & <strong>Sales</strong><br />

Global Presence<br />

Logistics<br />

Customer Needs<br />

Excellent cohesion<br />

High adhesive strength<br />

towards individual substrates<br />

High tackiness<br />

Environmental performance<br />

High energy savings<br />

Fast cycle times<br />

Excellent initial strength<br />

Adjustable open times<br />

Backbone Chemistry<br />

Poly(alpha)olefines<br />

Polyesters<br />

Polyacrylates<br />

Polybutadienes<br />

FT-Waxes<br />

7


Crosslinkers<br />

<strong>Adhesive</strong> networks of<br />

Product Line <strong>Adhesive</strong> <strong>Resins</strong><br />

Product Line<br />

<strong>Adhesive</strong><br />

<strong>Resins</strong><br />

EAST<br />

<strong>Evonik</strong> for <strong>Adhesive</strong>s<br />

& Sealants<br />

Monomers<br />

Additives<br />

Scienceto-Business<br />

Center<br />

Bio-<br />

Technology<br />

Science-to-Business Center:<br />

<strong>Evonik</strong>’s cooperation framework<br />

for working together with external<br />

partners, universities and institutes<br />

•Bio-Technology<br />

•ECO 2 : Focus Energy Efficiency<br />

•Nanotronics<br />

Nanotronics<br />

Eco 2<br />

ASC: The <strong>Adhesive</strong> and Sealant Council (USA)<br />

IVLV: Industrievereinigung für Lebensmitteltechnologie<br />

und Verpackung e.V. (Germany)<br />

EWF: European Wax Federation (Europe)<br />

IVK: Industrieverband Klebstoffe e.V. (Germany)<br />

FEICA: Association of European <strong>Adhesive</strong> and<br />

Sealant Industry (Europe)<br />

BASA: British <strong>Adhesive</strong>s and Sealants Association<br />

FPA: Flexible Packaging Association<br />

8


Our dedicated sales force<br />

is committed to our<br />

global customer approach<br />

Germany (north)<br />

Scandinavia<br />

R. Kater<br />

rolf.kater@evonik.com<br />

phone +49 2156 109 174<br />

Germany (south)<br />

Austria<br />

Switzerland<br />

L. Malmedy<br />

ludger.malmedy@evonik.com<br />

phone +49 8251 870157<br />

France<br />

Benelux Countries<br />

United Kingdom<br />

R. Strobbe<br />

ronny.strobbe@evonik.com<br />

phone +32 475 283834<br />

Italy<br />

Spain<br />

Portugal<br />

A. Gogna<br />

alberto.gogna@evonik.com<br />

phone +39 02 333 008 49<br />

Turkey<br />

E. Onc<br />

emre.onc@evonik.com<br />

phone +90 216 395 9961<br />

Russia<br />

S. Kovalerov<br />

sergey.kovalerov@evonik.com<br />

phone +7 495 721 2862<br />

Romania<br />

Bulgaria<br />

A. Mehedintu<br />

alexandru.mehedintu@evonik.com<br />

phone +40 31 71 00786<br />

Other Eastern Europe<br />

T. Sabljic<br />

tomislav.sabljic@evonik.com<br />

phone +385 1 3862 674<br />

USA<br />

Canada<br />

C. Borgmann<br />

cornelia.borgmann@evonik.com<br />

phone +1 973 929-8466<br />

M. Leon<br />

mercedes.leon@evonik.com<br />

phone +1 973 541 8821<br />

S. Engert<br />

sabine.engert@evonik.com<br />

phone +1 973 541 8924<br />

Mexico<br />

G. Marquez<br />

gabriela.marquez@evonik.com<br />

phone +52 55 5483-1000<br />

Other South America<br />

J. Thomaz de Melo<br />

joaquim.melo@evonik.com<br />

phone +55 11 3146 2156<br />

Argentina<br />

G. Avella<br />

gabriel.avella@evonik.com<br />

phone +54 9 11 57562069<br />

UAE<br />

Saudi Arabia<br />

S. Arte<br />

sachin.arte@evonik.com<br />

phone +971 4 204 5586<br />

Egypt<br />

A. Nousser<br />

ahmed.nousser@evonik.com<br />

phone +20 2 7948 242<br />

Iran<br />

A. Nayeri<br />

ali.nayeri@evonik.com<br />

phone +9821 2222 3402109<br />

India<br />

S. Parab<br />

suresh.parab@evonik.com<br />

phone +91 22 6723 8800<br />

Japan<br />

A. Yamamoto<br />

atsushi.yamamoto@evonik.com<br />

phone +81 3 5323 7409<br />

K. Sugi<br />

kiyoaki.sugi@evonik.com<br />

phone +81 3 5323 7360<br />

Korea<br />

J. Kim<br />

jason.kim@evonik.com<br />

phone +82 2 2072 2398<br />

South/East Asia<br />

D. Han<br />

daryl.han@evonik.com<br />

phone +65 6 809 6843<br />

A. Chen<br />

aumpa.chen@evonik.com<br />

phone +6627847913<br />

China<br />

E. Frimel<br />

ernst.frimel@evonik.com<br />

phone +86 21 6119 1028<br />

J. Qian<br />

jerry.qian@evonik.com<br />

phone +86 21 6119 1343<br />

Taiwan<br />

R. Cheng<br />

roger.cheng@evonik.com<br />

phone +886 2 2717-1242<br />

Australia<br />

New Zealand<br />

A. Windsor<br />

andrew.windsor@evonik.com<br />

phone +61 3 85818404<br />

9


Customized solutions for<br />

diverse markets<br />

Automotive<br />

Bonding & Lamination Interior<br />

Car Carpets<br />

<strong>Adhesive</strong>s & Sealants for Different Application<br />

Sound Damping<br />

Windows<br />

Head Lamp <strong>Adhesive</strong>s<br />

Construction<br />

Flat Lamination, Sandwich Construction<br />

Profile Wrapping & Edge Bonding<br />

Sand Filled Mortar<br />

Sealants/ Insulated Glass Sealants<br />

Electronics<br />

Flexible Flat Cables<br />

Cable Filling / Jelly Compounds<br />

Electrical Insulations & Potting Compounds<br />

Lifestyle<br />

Carpets<br />

Hygiene<br />

Textile Industry<br />

Silicone Based Consumer Sealants<br />

Mattrasses<br />

Packaging<br />

Flexible Packaging<br />

Paper & Packaging<br />

Pharmaceutical Blister-Pack<br />

Food Packaging<br />

Other Markets<br />

Bitumen Modification<br />

Polymer Modification / Masterbatches<br />

Road Construction<br />

Plastic Processing<br />

Renewables / Solar Applications<br />

Flexible Printing Plates / Defoamers / PU Foams<br />

10


Our Product Portfolio<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

11


Our polyester-polyols, copolyesters<br />

and polyacrylates for your reactive<br />

and thermoplastic hot melts.<br />

Our amorphous poly-alpha-olefins<br />

(APAOs) are co- and terpolymers<br />

of ethene, propene and 1-butene.<br />

They are particularly useful for<br />

producing hot melt adhesives.<br />

Our synthetic waxes produced<br />

by the Fischer-Tropsch process<br />

act as your value additive for<br />

hot melt applications.<br />

Our liquid polybutadienes for<br />

your adhesives & sealants are<br />

stereospecific, low viscous and<br />

unsaponifiable.<br />

Our methacrylat binders<br />

for heat sealing applications<br />

in pharmaceutical blister-packs<br />

and food packaging.<br />

12


13<br />

Application Insights


Designed Polymers for<br />

<br />

<br />

<br />

Initial strength<br />

high<br />

low<br />

Spectrum of standard<br />

PES-RHM formulations<br />

DYNACOLL AC<br />

influence area<br />

short<br />

long<br />

Open time<br />

Mw 30.000 – 140.000 g/mol<br />

Tg 44 – 85 °C<br />

Viscosity 16 – 54 cm 3 /g<br />

FP (R&B) 120 – 190 °C<br />

MFR (190 °C) 7 – 1.000 g/10 mn<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

14


Designed Polymers for<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

15


Designed Polymers for<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

16


Designed Polymers for<br />

<br />

<br />

<br />

<br />

<br />

<br />

17


Designed Polymers for<br />

POLYVEST® MA 75, a maleic anhydride functionalized liquid polybutadiene with<br />

a viscosity of 6,000-9,000 mPa s (20°C), improves compounding of ethylenepropylene-diene-monomer-rubbers<br />

(EPDM). Compound formulations benefit<br />

from its improved dispersion of fillers, e.g. of chalk or carbon black.<br />

<br />

<br />

<br />

<br />

<br />

Guide formulation<br />

with mixture of<br />

EPDM and chalk and<br />

typical additives with<br />

increasing addition<br />

of small amounts of<br />

POLYVEST® MA 75<br />

(e.g. 0-4 parts by<br />

weight).<br />

18


Designed Polymers for<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

<br />

With POLYVEST® MA 75, a maleic anhydride functionalized liquid polybutadiene<br />

with a viscosity of 6,000-9,000 mPa s (@20°C), automotive tire formulations<br />

benefit from its improving silica dispersing character and show effects such as<br />

<br />

<br />

<br />

<br />

<br />

Reduced compound viscosity<br />

Reduced vulcanization time<br />

Increased tensile strength<br />

Increased elongation at break<br />

Increased break energy<br />

Guide formulation for automotive tires with mixture<br />

of Styrene Butadiene Rubber (SBR) and Butadiene<br />

Rubber (BR) and typical additives with increasing<br />

addition of small amounts of POLYVEST® MA 75<br />

(e.g. 0-2 parts by weight).<br />

19


Designed Polymers for<br />

Waterbased Heat Seal Formulations<br />

DEGALAN® VP 4240 D achieves direct adhesion to aluminum and<br />

gives very good sealability versus polystyrene (PS) cup materials.<br />

Features<br />

• Aqueous resin dispersion<br />

• Pure acrylic binder<br />

• Optimized core-shell structure<br />

• 50% solid content<br />

Advantages<br />

• Suitable for water based heat seal<br />

lacquer formulations<br />

• Environmental friendly dispersion<br />

• High efficiency<br />

Benefits<br />

• Direct adhesion on aluminum,<br />

no primer necessary<br />

• Broad sealing window<br />

• Lacquer formulation for<br />

sustainable packaging with<br />

eco-friendly heat sealing<br />

Label print<br />

Aluminium<br />

Direct adhesive heat seal<br />

lacquer based on<br />

DEGALAN® VP 4240 D<br />

Cover lid<br />

Sealing substrate: PS, PVC<br />

Cup<br />

DEGALAN® VP 4240 D provides good seal strength starting at 140°C and a very broad sealing window.<br />

10<br />

N/15mm<br />

8<br />

6<br />

4<br />

2<br />

0<br />

200°C 180°C 160°C 140°C 120°C 100°C<br />

Sealing Temperature<br />

◂ 7<br />

Aluminium vs. PS<br />

• Single step coating<br />

• Dry film coating weight 7 g / m²<br />

• Drying: 15 s / 180°C<br />

• Sealing: 1.0 s, 6 bar<br />

Initial after Sealing<br />

After 48 h immersion into water<br />

20


Designed Polymers for<br />

Pharmaceutical Blister Packaging<br />

DEGALAN® P 24 and DEGALAN® LP AL23 –<br />

State of the art in pharmaceutical blister packaging.<br />

Formulations of DEGALAN® P 24 and DEGALAN® LP AL23 with PVC copolymer show excellent performance in<br />

aluminum blister packaging. In combination with polyester primer like DYNAPOL®L 206 or 208 adhesion to PET is achieved.<br />

Features<br />

• Beads (100% solids)<br />

• LP AL23: Drug Master File<br />

• Compatible with PVC copolymers<br />

• State of the art binder for sealing<br />

versus PVC and PVdC<br />

Advantages<br />

• Free choice of solvent<br />

• Enables easy access to<br />

pharma applications<br />

• Wide range of application<br />

• Binders are suitable for pharma<br />

and food applications<br />

Benefits<br />

• Fast drying in combination with<br />

low boiler solvents<br />

• Shorter approval times with<br />

respect to pharma applications<br />

• Cost savings in lacquer formulation,<br />

due to less PVC needed<br />

• Less number of formulations needed<br />

Label print<br />

Aluminium<br />

Heat seal lacquer<br />

based on either<br />

DEGALAN ® P 24 or<br />

DEGALAN ® LP AL23<br />

formulated with a<br />

PVC-copolymer as an<br />

adhesion promoter<br />

Sealing substrate: PVC, (PVD) (PVdC)<br />

Blister foil<br />

Blister tray<br />

DEGALAN® P 24 and<br />

DEGALAN® LP AL23 –combined with<br />

PVC copolymer to give good adhesion to<br />

aluminum foil and secure sealing<br />

in pharma blister packaging.<br />

Heat Sealing Strength vs. DEGALAN® P 24 content: Example Pharmaceutical Blister Packaging<br />

10<br />

8<br />

DEGALAN® P 24 improves the heat seal strength<br />

for various PVC copolymers. Heat seal strength of<br />

more than 8 N/15mm can be achieved.<br />

6<br />

4<br />

N/15mm<br />

2<br />

0<br />

0 20 40 60 80<br />

DEGALAN® P 24 content / % (solid/solid)<br />

VMCH - Initial<br />

Vinnol H15/45 M - Initial<br />

Vinnol H 30/48 M - Initial<br />

Hard Aluminium vs. PVC<br />

• Combined with var. PVC copolymers<br />

• Drying: 15 seconds at 180 °C<br />

• Sealing: 1,0 seconds, 6 bar, 200°C<br />

• Heat Sealing Strength Test, α = 90°<br />

21


Designed Polymers for<br />

PVC Free Packaging<br />

DEGALAN® PM 666 and DEGALAN® 4151 E – Direct adhesion to<br />

aluminum and sealability versus Polystyrene, Polypropylene and PET.<br />

In combination with polyester primer like DYNAPOL® L 206 or 208, DEGALAN® PM 666 and DEGALAN® 4151 E<br />

also achieve good adhesion to PET.<br />

Features<br />

• Organic dispersion from<br />

copolymers of methacrylic esters<br />

grafted on EPDM olefins<br />

• Binder with functional groups which<br />

enables primerless application<br />

Advantages<br />

• Universal sealability versus all<br />

common cup materials<br />

• Direct adhesion to aluminum<br />

• No PVC copolymer is needed<br />

Benefits<br />

• Cost savings due to reduction of<br />

complexity<br />

• Eco-friendly - since PVC free - heat<br />

sealing lacquer<br />

• Superior alternative when PVC based<br />

heat seal lacquers need to be<br />

replaced in food packaging<br />

Label print<br />

Aluminium<br />

Direct adhesive heat seal<br />

lacquer based on<br />

DEGALAN® PM 666<br />

Cover lid<br />

Sealing substrate: PP, PS, PET<br />

Cup<br />

DEGALAN® PM 666 and DEGALAN® 4151 E –<br />

Direct adhesion to aluminum and sealability<br />

versus Polystyrene, Polypropylene and PET<br />

Heat Sealing Strength vs. Sealing Temperature<br />

N/15mm<br />

10<br />

7,8<br />

8<br />

6,7<br />

7,3<br />

6<br />

6,3<br />

4<br />

2,4<br />

2<br />

0,0<br />

0<br />

200°C 180°C 160°C 140°C<br />

Sealing Temperature<br />

Both, DEGALAN® PM 666 as well as<br />

DEGALAN® 4151 E show heat seal strength<br />

of more than 5 N/15mm at temperatures<br />

above 170°C.<br />

DEGALAN® 4151 E<br />

DEGALAN® PM 666<br />

Aluminium vs. PP<br />

• Not primered!<br />

• Drying: 15 sec. / 180 °C<br />

• Sealing: 1 sec., 6 bar,<br />

22


Designed Polymers for<br />

PET Lidding<br />

DEGALAN® VP 4174 E – “One to fit all” direct adhesion on Aluminum<br />

and PET is achieved.<br />

No primer is needed for DEGALAN® VP 4174 E to give good adhesion to aluminum and to PET.<br />

Features<br />

• Organic dispersion of copolymers of<br />

methacrylic esters grafted on EPDM<br />

olefins and polyesters<br />

• Designed for primerless PET lidding<br />

• Binder with functional groups and<br />

polymers which enables primerless<br />

application<br />

Advantages<br />

• Universal sealability versus all<br />

common cup materials<br />

• Direct adhesion to PET and<br />

aluminum<br />

• No primer is needed<br />

Benefits<br />

• Cost saving in PET lacquering due<br />

to one-pass application<br />

• “One to fit all” lacquer formulation<br />

is possible<br />

• Seals versus all common cup<br />

materials like PP, PS, PVC and PET<br />

Label print<br />

PET<br />

One-pass direct adhesive<br />

heat seal lacquer based on<br />

DEGALAN® VP 4174 E<br />

Cover lid<br />

High Efficiency of<br />

DEGALAN® VP 4174 E<br />

Cup<br />

Sealing substrate: PP, PS, PET<br />

Use for PVC free food packaging in<br />

your combi lacquer formulations to seal<br />

versus all common cup materials.<br />

DEGALAN® VP 4174 E – Heat Seal Strength at various<br />

material combinations<br />

DEGALAN® VP 4174 E<br />

gives a heat seal strength of more<br />

than 6 N/15mm even on<br />

PET WDW 50 substrates.<br />

Sealing vs. PP, PS and PET<br />

• No Primering!<br />

• Layer thickness PET 6 μm<br />

• Layer thickness Alu 8 μm<br />

• Drying: 15 sec. / 180 °C<br />

• Sealing: 1 sec., 6 bar, 200 °C<br />

N/15mm<br />

10<br />

8<br />

6<br />

4<br />

2<br />

0<br />

Aluminum<br />

8,4 8,7 6,0<br />

9,1 9,1<br />

6,7 6,0<br />

8,0<br />

vs. PP vs. PS vs. PET<br />

6,0<br />

Al25/PET12 PET WDW 50<br />

Recommended Application:<br />

23 - 55 μm PET substrate<br />

Recommended Heat Seal Lacquer<br />

coating weight:6 g/sqm (approx. 6 μm)<br />

Application Range: approx. 78 sqm/kg<br />

Efficiency + 35% vs. Aluminum<br />

Additional Application:<br />

38 μm aluminum substrate<br />

Recommended Heat Seal Lacquer<br />

coating weight dueto corrosion protection:<br />

8 g/sqm (approx. 8 μm)<br />

Application Range: approx. 58 sqm/kg<br />

The solid content of<br />

DEGALAN® VP 4174 E is about 46 % in<br />

comparison to DEGALAN® 4150 E with<br />

about 43 % (approx. 54 sqm/kg at 8 g/sqm,<br />

approx. 8 μm coating weight)<br />

23


DYNACOLL®<br />

Polyester-Polyols, Copolyesters<br />

and Polyacrylates<br />

<strong>Evonik</strong>. Power to create.<br />

24


DYNACOLL® 7000<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

Polyester-Polyols<br />

With its DYNACOLL® 7000 polyester-polyols <strong>Evonik</strong> offers tailor-made raw<br />

materials for one-component moisture-curable hotmelt (RHM) adhesives and<br />

sealants. DYNACOLL® 7000 products are linear copolyesters with primary<br />

hydroxyl functionality and medium molecular weight.<br />

Depending on their morphology the product range is divided into three<br />

basic groups:<br />

• DYNACOLL® 7100 series<br />

• DYNACOLL® 7200 series<br />

• DYNACOLL® 7300 series<br />

amorphous, solid<br />

liquid, pasty<br />

partially crystalline, solid<br />

The product group is designed as a building block system, most DYNACOLL® 7000<br />

polyester-polyols are compatible with each other. Partially incompatible but<br />

miscible systems are, however, necessary in many applications as well.<br />

DYNACOLL® 7000 copolyesters are usually supplied in 25 or 30 kg and<br />

190 or 200 kg steel drums. Liquid bulk deliveries are available on special request.<br />

Your benefits<br />

Our building block system allows a precise formulation of reactive PUR hot melts<br />

with low application temperatures and high heat resistance. Basic effects on the<br />

RHM properties are:<br />

• DYNACOLL® 7100 series<br />

• shortens open time<br />

• increases initial strength, melt viscosity and adhesion to polar substrates<br />

• DYNACOLL® 7200 series<br />

• increases flexibility, open time and adhesion to non-polar substrates<br />

• lowers melt viscosity<br />

• DYNACOLL® 7300 series<br />

• shortens open time (depending on crystallinity) and lowers melt viscosity<br />

• increases initial strength<br />

25


DYNACOLL® 7000<br />

Product Range<br />

Properties Melt Viscosity Grade<br />

Hydroxyl<br />

Number 2)<br />

Acid<br />

Number 2)<br />

Molecular<br />

Weight<br />

Glass<br />

Transition<br />

Temperature<br />

Melting<br />

Point<br />

Softening<br />

Point<br />

(R&B)<br />

Density<br />

at 23 °C<br />

Flash<br />

Point<br />

80 °C 130 °C<br />

Grade [mg KOH/g] [mg KOH/g] [g/mol] [°C] [°C] [°C] [kg/dm 3 ] [°C]<br />

[Parallel plate]<br />

[Pa s]<br />

[Parallel plate]<br />

[Pa s]<br />

Amorphous<br />

7110 1) 50 - 60 8 - 12 2,000 10 52 1.08 >300 1 7110 1)<br />

7111 27 - 34 max. 4 3,500 20 61 1.23 >300 3 7111<br />

7130 31 - 39 max. 2 3,000 30 76 1.17 >300 10 7130<br />

7131 31 - 39 max. 2 3,000 30 76 1.23 >300 10 7131<br />

7140 18 - 24 max. 2 5,500 30 87 1.21 >300 50 7140<br />

7150 38 - 46 max. 2 2,600 50 95 1.26 >300 50 7150<br />

Liquid<br />

7210 27 - 34 max. 2 3,500 -15 1.29 >200 11 7210<br />

7230 27 - 34 max. 2 3,500 -30 1.17 >200 10 7230<br />

7231 27 - 34 max. 2 3,500 -30 1.21 >200 8 7231<br />

7250 18 - 24 max. 2 5,500 -50 1.15 >200 5 7250<br />

7255 27 - 34 max. 2 3,500 -60 32 40 1.11 >200 2 7255<br />

Crystalline<br />

7362 47 - 54 max. 2 2,000 -60 53 60 1.15 >200 0.5 7362<br />

7360 27 - 34 max. 2 3,500 -60 55 63 1.16 >300 2 7360<br />

7363 18 - 24 max. 2 5,500 -60 56 63 1.16 >300 5 7363<br />

7365 14 - 20 max. 2 6,500 -60 57 63 1.16 >300 10 7365<br />

7361 10 - 16 max. 2 8,500 -60 57 65 1.16 >300 15 7361<br />

7381 27 - 34 max. 2 3,500 65 73 1.16 >300 2 7381<br />

7380 27 - 34 max. 2 3,500 70 77 1.10 >300 2 7380<br />

7330 27 - 34 max. 2 3,500 85 90 1.17 >300 0.3 7330<br />

7320 27 - 34 max. 3 3,500 -20 92 1.23 >300 4 7320<br />

7340 27 - 34 max. 2 3,500 -40 96 102 1.19 >300 1 7340<br />

7331 27 - 34 max. 2 3,500 -30 110 115 1.19 >300 2 7331<br />

7390 27 - 34 max. 3 3,500 -30 115 118 1.29 >300 0.7 7390<br />

7321 27 - 34 max. 2 3,500 -25 123 128 1.20 >300 3 7321<br />

1)<br />

available on special request<br />

2)<br />

Hydroxyl Number and Acid Number represent delivery specifications<br />

26


DYNACOLL® 7000<br />

Preparation of Reactive Hot Melts<br />

Molten DYNACOLL® grades are charged and heated up to approx. 130 °C. The melt<br />

is dried for 45 min. at less than 10 mbar. Water evaporation is important to avoid<br />

crosslinking reactions and to obtain good shelf life and viscosity stability of the<br />

RHM.<br />

The calculated amount of isocyanate is added under a weak stream of protective gas<br />

(dried nitrogen or carbon dioxide) and rapidly homogenized with the melt. Reaction<br />

time is normally 45 min. at 120 – 130 °C.<br />

The reaction is finished after the theoretical value of isocyanate content is reached.<br />

The isocyanate content is determined by reaction of the RHM with an excess of<br />

dibutylamine and titration with hydrochloric acid. The melt should be degassed until<br />

it is free of bubbles. Afterwards the reactive hot melt is filled into containers and<br />

stored in the absence of moisture and light. Depending on the application it is<br />

recommended to filter the melt.<br />

For quality control, the following data should be determined: isocyanate content,<br />

visosity at elevated temperature, melting point or softening point (R&B), open time.<br />

Calculation:<br />

Weight (diisocyanate) =<br />

(WPES1 . OH1 + WPESn . OHn) . EW . R<br />

56110<br />

WPES1 = weight of polyester 1<br />

OH1 = hydroxyl number polyester 1<br />

WPESn = weight of polyester n<br />

OHn = hydroxyl number polyester n<br />

EW = equivalent weight of diisocyanate used<br />

R = ratio of isocyanate to hydroxyl groups<br />

Reactive Hot Melt adhesives based on DYNACOLL® 7000<br />

• offer excellent bonding to a huge variety of substrates<br />

• provide solutions for versatile applications in diverse industries,<br />

e.g. wood working, automotive, packaging and textile industry,<br />

also for bookbinding applications and sandwich bonding<br />

• can be applied with standard hot melt equipment,<br />

e.g. roll coaters, bead, spray and melt print applicators etc.<br />

27


DYNACOLL® 7000<br />

Reactive Holt Melt Data<br />

Reaction products of DYNACOLL® with 4,4’- diphenylmethane diisocyanates (MDI) as a ratio of OH : NCO = 1 : 2.2<br />

Properties<br />

Melt Viscosity<br />

Grade<br />

Softening<br />

Point<br />

(R&B)<br />

[°C]<br />

Open Time<br />

[s]<br />

Setting Time<br />

[s]<br />

Tensile<br />

Strength<br />

[N/mm 2 ]<br />

Elongation<br />

at Break<br />

[%]<br />

130 °C<br />

[Parallel plate]<br />

[Pa s]<br />

Amorphous<br />

7110 1) 64 10 1 brittle 3<br />

7111 71 6 1 brittle 13<br />

7130 88 1 1 brittle 50<br />

7131 88 1 1 brittle 45<br />

7140 102 1 < 1 brittle 700<br />

7150 105 < 1 < 1 brittle 400<br />

Liquid<br />

7210 45 several hours several hours 15 800 5<br />

7230 several hours several hours 15 900 9<br />

7231 several hours several hours 15 900 8<br />

7250 several hours several hours 15 1,500 9<br />

7255 40 several hours several hours 30 1,100 5<br />

Crystalline<br />

7362 55 130 35 25 400 2<br />

7360 59 80 15 25 400 4<br />

7363 61 50 15 25 400 11<br />

7365 63 50 15 20 300 18<br />

7361 63 50 10 20 300 30<br />

7381 67 35 3 20 80 5<br />

7380 73 20 1 20 20 5<br />

7330 85 35 3 25 15 3<br />

7320 87 40 35 35 500 48<br />

7340 97 120 60 30 700 12<br />

7331 110 90 30 30 500 20<br />

7390 118 20 10 30 10 4<br />

7321 123 70 25 35 400 30<br />

1)<br />

available on special request<br />

28


DYNACOLL® 7000<br />

Compatibility<br />

Grade<br />

7110 1)<br />

7111<br />

7130<br />

7131<br />

7140<br />

7150<br />

7210<br />

7230<br />

7231<br />

7250<br />

7110 1) + + + + + + + + + + + + + + +<br />

7111 + + + + + + + + + + + + – – +<br />

7130 + + + + + + + + + + + + + + + +<br />

7131 + + + + + + + + + + + + + + + + + + + +<br />

7140 – – + + + + + – + + + +<br />

7150 + + + + + + + + + + + + + +<br />

7210 + + + + – + + + + +<br />

7230 + + + + + + + + + + + + + + + + + + +<br />

7231 + + + + + + + + + + + + + + + + + +<br />

7250 + + + + – + + + + + + + + + + + +<br />

7255 + + + + – + – + + + + + + + + + + + – + –<br />

7320 + + + + + + + + + + + + + + + + – – +<br />

7321 * – – + + + + + + + – – + + + + + + + + +<br />

7330 + – + + – + – + – + + + + + + + + + + +<br />

7331 – – + + + + – + + – + + + + + + – +<br />

7340 – – + + + + + + + – + + + + + + + + +<br />

7360 + + + + – + – + + + + + + + + + + + + +<br />

7361 + + + + – + – + + + + + + + + + + + + +<br />

7365 + + + + – + – + + + + + + + + + + + + +<br />

7380 – – – – – – – – – – – – + – – – + + +<br />

7381 – – – + – – – – – – + – + + + + + + + +<br />

7390 + + – + – – + + + – – – – – – – –<br />

7255<br />

7320<br />

7321 *<br />

7330<br />

7331<br />

7340<br />

7360<br />

7361<br />

7365<br />

7380<br />

7381<br />

7390<br />

1)<br />

available on special request<br />

Visual evaluation of the melt after storing 24 hours at 130 °C ( * at 140 °C):<br />

+ = transparent = opaque 1:1 Mixtures of copolyesters<br />

= cloudy – = phase separation 1:1 Mixtures of copolyesters reacted with MDI (OH : NCO = 1 : 2.2)<br />

29


DYNACOLL® 7000<br />

Analytical Methods<br />

Hydroxyl Number<br />

Determination according to DIN 53 240-02.<br />

Approx. 2-3 g of polyester are dissolved in dichloromethane or THF. The OH groups are<br />

esterified at RT with acetic anhydride, using 4-dimethyl-aminopyridine as catalyst. After<br />

hydrolysis of the unreacted anhydride, titration is carried out with 0.5 N methanolic KOH.<br />

Acid Number<br />

Determination according to DIN EN ISO 2114.<br />

Approx. 4 g of polyester are dissolved in 50 ml of tetrahydrofuran. Following addition of 50 ml<br />

of a mixture of equal parts by weight of tetrahydrofuran and ethanol, titration is carried out<br />

with methanolic or ethanolic KOH against phenolphthalein.<br />

Molecular Weight<br />

The molecular weight is calculated based on the sum of hydroxyl number and acid number.<br />

Glass Transition Temperature<br />

Determination according to DIN 53 765.<br />

The glass transisition temperature is determined as for the melting point.<br />

Melting Point<br />

Determination according to DIN 53 765.<br />

The melting point is determined using a DSC instrument. The sample and an empty reference<br />

crucible are heated at 20 °C/min. The melting point corresponds to the maximum of the<br />

melting peak. To ensure better reproducibility, it is customary to use the values from the<br />

second heating operation.<br />

Softening Point (Ring and Ball)<br />

Determination according to DIN ISO 4625.<br />

The sample is cast as a melt into a ring and the ring, following the solidifaction of the melt<br />

(or the recrystallization in the case of crystalline substances), is inserted into a test frame. The<br />

sample is stressed concentrically with a chrome-plated steel ball and the test frame is immersed<br />

in a bath of glycerol. The glycerol is heated at a rate of approximately 5 °C/min. The softening<br />

point (R&B) is the temperature of the glycerol bath at the time when the steel ball contacts the<br />

baseplate of the test frame.<br />

Density<br />

Determination according to DIN 51 757.<br />

Flash Point<br />

Determination according to ISO 2592.<br />

Open Time<br />

Determination according to <strong>Evonik</strong> internal method.<br />

The material is heated up to 130 °C and applied on paper as an approximately 0.5 mm thick<br />

film. Strips of open surface paper are pressed into the melt at certain intervals. After the<br />

adhesive film is tack-free the paper strips are removed. The open time is given by the time,<br />

when no fiber tear can be observed anymore.<br />

30


DYNACOLL® 7000<br />

Analytical Methods<br />

Setting Time<br />

Determination according to <strong>Evonik</strong> internal method.<br />

The setting time is given by the time it takes until two bonded wooden cubes can<br />

no longer be twisted against each other by hand.<br />

Melt Viscosity<br />

Determination according to DIN EN ISO 3219, parallel plate method.<br />

Tensile Strength / Elongation at Break<br />

Determination according to DIN 53 504.<br />

Dumbbell specimens are punched out from a 0.5 mm thick moisture cured RHM film.<br />

Curing conditions are 7 days, 20 °C and 65 % rel. humidity. Elongation at break denotes<br />

the percentage increase in length of an original section of 10 mm marked on the bar<br />

of the dumbbell specimen, at the moment of break.<br />

31


DYNACOLL® S<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

Copolyesters<br />

With its DYNACOLL® S product range <strong>Evonik</strong> offers thermoplastic copolyesters<br />

of high molecular weight to a wide variety of thermoplastic hot melt and solvent<br />

based applications.<br />

The individual grades differ in their melting point, degree of crystallinity and<br />

hardness and in their setting time. According to their crystallinity, the product<br />

range is arranged into four basic groups:<br />

• DYNACOLL® S - Highly crystalline grades<br />

• DYNACOLL® S - Moderately crystalline grades<br />

• DYNACOLL® S - Slightly crystalline grades<br />

• DYNACOLL® S - Amorphous grades<br />

DYNACOLL® S copolyesters are generally supplied as granules,<br />

usually in bags of 20 or 25 kg.<br />

They can be processed into following forms of applications:<br />

adhesive film, web or net, powder, paste, hot melt and solution.<br />

Your benefits<br />

• DYNACOLL® S - Highly crystalline grades<br />

• short open times and high heat resistance<br />

• good solvent and chemical resistance<br />

• DYNACOLL® S - Moderately crystalline grades<br />

• moderate open times<br />

• very good adhesive strength and heat resistance<br />

• DYNACOLL® S - Slightly crystalline grades<br />

• long open time with good heat resistance<br />

• excellent adhesion on a large number of substrates<br />

• DYNACOLL® S - Amorphous grades<br />

• good solubility in many solvents<br />

• very good adhesion on a large number of substrates<br />

32


DYNACOLL® S<br />

Product Range<br />

Properties Melt Flow Rate (MFR) [g/10 min] Melt Viscosity [Pa s] Solubility Grade<br />

Softening<br />

Point<br />

Melting<br />

Point<br />

Grade [°C] [°C] [°C]<br />

Glass<br />

Transition<br />

Temp.<br />

Hydroxyl<br />

Number<br />

[mg<br />

KOH/g]<br />

Acid<br />

Number<br />

Viscosity<br />

Number<br />

Shore D<br />

Hardness<br />

Open Time<br />

Tensile<br />

Strength<br />

Elongation<br />

at Break<br />

[mg<br />

KOH/g] [cm 3 /g] [s] [N/mm 2 ] [%] 160 °C 180 °C 200 °C 220 °C 160 °C 180 °C 200 °C 220 °C<br />

Methylene chloride<br />

Trichloroethylene<br />

Ethyl acetate<br />

MEK<br />

(methylethyl ketone)<br />

Toluene<br />

Highly crystalline<br />

S 243 195 195 35 68 79 5 40 7 130 240 50 – – – – – S 243<br />

Moderately crystalline<br />

S 1272 140 128 0 84 53 10 25 400 30 60 120 250 330 140 65 + – – – – S 1272<br />

S 1252 135 120 1) 20 94 64 5 20 450 20 45 900 360 180 + – – – – S 1252<br />

S 1218 130 115 15 80 63 20 20 300 30 60 110 210 300 150 80 + • – – – S 1218<br />

S 1227 115 100 10 80 63 5 15 350 40 90 150 240 240 120 60 + • – – – S 1227<br />

Slightly crystalline<br />

S 1402 100 90 1) -10 5 3 78 27 15 10 400 100 220 360 80 50 30 10 + + – – • S 1402<br />

S 1401 97 85 1) -25 6 2 80 19 15 5 500 110 190 290 80 40 25 15 + + • • + S 1401<br />

S EP 1408 90 80 1) -30 4 2 87 17 50 2 300 75 130 200 100 55 30 15 + + + + + S EP 1408<br />

Amorphous<br />

S 1606 155 65 4 2 62 80 15 60 5 30 60 150 90 + + + + – S 1606<br />

S 1611 130 50 4 2 61 79 10 20 3 100 190 70 15 + + + + + S 1611<br />

S 1426 140 35 4 2 90 78 20 50 5 15 30 60 270 + + + + + S 1426<br />

S EP 506.01 125 40 6 5 65 80 5 130 230 + + + + + S EP 506.01<br />

1)<br />

optical method<br />

All data given are typical values<br />

+ = > 10% (soluble)<br />

• = < 10 % (slightly insoluble)<br />

– = < 1% (virtually insoluble)<br />

33


DYNACOLL® S<br />

Applications<br />

Highly<br />

Cryst.<br />

Grade<br />

Moderatly<br />

Crystalline Grades<br />

Slightly<br />

Crystalline Grades<br />

Amorphous<br />

Grades<br />

S 243<br />

S 1272<br />

S 1252<br />

S 1218<br />

S 1227<br />

S 1402<br />

S 1401<br />

S EP 1408<br />

S 1606<br />

S 1611<br />

S 1426<br />

S EP 506.01<br />

Textile Industry<br />

Hot Melts ▯ ▯ ▯ ▯<br />

<strong>Adhesive</strong> film ▯ ▯ ▯<br />

<strong>Adhesive</strong> web and net ▯ ▯<br />

Profile Wrapping<br />

PVC Window frames ▯ ▯ ▯<br />

Metal / Plastics bonding ▯ ▯ ▯ ▯ ▯<br />

Metal primer ▯ ▯ ▯<br />

Electronic Industry<br />

Solvent based adhesives ▯ ▯ ▯ ▯<br />

Hot Melt adhesives<br />

▯<br />

Automotive Industry<br />

Air filter bondings<br />

Interior textile lamination ▯ ▯<br />

Decorative film lamination ▯ ▯ ▯<br />

Packaging Industry<br />

Biodegradeable adhesives<br />

Flexible packging ▯ ▯ ▯ ▯<br />

Polymer Modification<br />

Additive for Reactive Hot Melts ▯ ▯<br />

Masterbatches<br />

▯<br />

34


DYNACOLL® S<br />

Analytical Methods<br />

Softening Point (Ring and Ball)<br />

Determination according to DIN ISO 4625.<br />

The sample is cast as a melt into a ring and the ring, following the solidifaction of the melt<br />

(or the recrystallization in the case of crystalline substances), is inserted into a test frame.<br />

The sample is stressed concentrically with a chrome-plated steel ball and the test frame is<br />

immersed in a bath of glycerol. The glycerol is heated at a rate of approximately 5 °C/min.<br />

The softening point (R&B) is the temperature of the glycerol bath at the time when the steel<br />

ball contacts the baseplate of the test frame.<br />

Melting Point<br />

Determination according to DIN 53 765.<br />

The melting point is usually determined using a DSC instrument. The sample and an empty<br />

reference crucible are heated at 20 °C/min. The melting point corresponds to the maximum of<br />

the melting peak. To ensure better reproducibility, it is customary to use the values from the<br />

second heating operation. However, the melting point of certain grades is measured by an<br />

optical method (Mettler FP 82).<br />

Glass Transition Temperature<br />

Determination according to DIN 53 765.<br />

The glass transisition temperature is determined as for the melting point, but with a heating<br />

rate of 10 °C/min.<br />

Hydroxyl Number<br />

Determination according to DIN 53 240-02.<br />

Approx. 2-3 g of polyester are dissolved in dichloromethane or THF. The OH groups are<br />

esterified at RT with acetic anhydride, using 4-dimethyl-aminopyridine as catalyst. After<br />

hydrolysis of the unreacted anhydride, titration is carried out with 0.5 N methanolic KOH.<br />

Acid Number<br />

Determination according to DIN EN ISO 2114.<br />

Approx. 4 g of polyester are dissolved in 50 ml of tetrahydrofuran. Following addition<br />

of 50 ml of a mixture of equal parts by weight of tetrahydrofuran and ethanol, titration<br />

is carried out with methanolic or ethanolic KOH against phenolphthalein.<br />

Shore D Hardness<br />

Determination in accordance with DIN 53 505.<br />

All values refer to crystallized products.<br />

Viscosity Number<br />

Determination according to DIN 53 728.<br />

0.5 g of the test substance are dissolved in 100 ml of a mixture of 50 % by weight phenol and<br />

50 % by weight 1,2-dichlorobenzene. The viscosity of the solution and the solvent is<br />

determined by the Ubbelohde method. The viscosity number J is determined using the formula:<br />

J = [<br />

t 1<br />

- 1 ]<br />

1<br />

x<br />

t 2<br />

c<br />

t 1<br />

= flow time of solution [s]<br />

t 2<br />

= flow time of solvent [s]<br />

c = concentration of test substance [g/cm 3 ]<br />

35


DYNACOLL® S<br />

Analytical Methods<br />

Open Time<br />

Determination according to <strong>Evonik</strong> internal method.<br />

The open time is defined as the time between the application of the adhesive and the start<br />

of recrystallization – or in case of amorphous products until the surface becomes tack-free.<br />

Tensile Strength / Elongation at Break<br />

Determination in accordance with DIN EN ISO 527-1/3.<br />

It is determined on standard dumbbell-shaped specimens. The elongation at break denotes<br />

the percentage increase in length of an original section of 10 mm marked on the bar of the<br />

dumbbell specimen, at the moment of rupture.<br />

Melt Flow Rate (MFR)<br />

Determination according to DIN ISO 1133.<br />

Approx. 10 g of the test sample are placed in a temperature-conditioned metal cylinder.<br />

Via a cylindrical die, a force of 21.6 N acts on the melted sample. The weight of sample<br />

flowing through the standardized nozzle within a measured time is used to calculate the<br />

MFR. The MFR is expressed as the weight of sample extruded in 10 minutes. The densities<br />

for calculating the melt volume index (MVI) are listed in the specific technical data sheets.<br />

Melt Viscosity<br />

Determination according to DIN EN ISO 3219, parallel plate method.<br />

36


DYNACOLL® AC<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

Polyacrylates<br />

With its DYNACOLL® AC product range <strong>Evonik</strong> offers acrylics for one-component<br />

moisture curable hot melt adhesives.<br />

Acrylics for adhesives are bead polymers made of methyl methacrylate and n-butyl<br />

methacrylate which are mainly used to modify reactive hot melts for flat lamination<br />

applications.<br />

Various DYNACOLL® AC grades with tailored glass transition temperature and<br />

molecular weight are available. They also differ according to their acid and hydroxyl<br />

functionality.<br />

DYNACOLL® AC polyacrylates are supplied as beads in bags of 25 kg.<br />

Your benefits<br />

• DYNACOLL® AC provides outstanding quality and flow properties<br />

• DYNACOLL® AC modified reactive hot melts provide<br />

• low viscosity<br />

• very long open time<br />

• aggressive tack<br />

• high creep resistance directly after bonding<br />

37


DYNACOLL® AC<br />

Product Range<br />

Properties<br />

Glass<br />

Transition<br />

Temperature<br />

Tg<br />

Molecular<br />

Weight<br />

Mw<br />

Viscosity<br />

Number<br />

Acid<br />

Number<br />

Hydroxyl<br />

Number<br />

Softening<br />

Point<br />

(R&B)<br />

Melt Flow Rate<br />

190 °C<br />

[°C] [g/mol] [cm 3 /g] [mg KOH/g] [mg KOH/g] [°C] [g/10 min]<br />

Bead Polymers<br />

AC 1420 44 30,000 16 6 120 1,000<br />

AC 1520 48 35,000 19 8.5 135 500<br />

AC 1631 57 60,000 30 9 150 60<br />

AC 1620 56 35,000 19 8 140 300<br />

AC 1630 63 60,000 30 8 150 20<br />

AC 1750 65 140,000 54 4 190 9<br />

AC 1920 85 37,000 22 6 160 70<br />

AC 4830 82 60,000 30 175 8<br />

AC 2740 70 80,000 36 4 170 7<br />

38


DYNACOLL® AC<br />

Applications<br />

DYNACOLL® AC grades are mainly used to modify reactive hot melts for<br />

flat lamination purposes.<br />

Typical areas of application are:<br />

• Sandwich composites<br />

of aluminium, FRP panels, foam or wood-based substrates<br />

e. g. for recreational vehicals<br />

• Honeycomb structures<br />

e.g. for door manufacturing<br />

• Foil laminated particleboard<br />

e.g. for furniture<br />

• Medium density fiberboard panels<br />

e.g. for furniture<br />

Flat lamination applications require long open times to permit long handling times<br />

needed to bond huge panels or sandwich composites. On the other hand, initial<br />

strength has to be very high to hold the bonded parts in place without any further<br />

mechanical fixation.<br />

Preparation of Reactive Hot Melts<br />

These requirements can be fulfilled by reactive hot melts. Such moisture curing<br />

hot melt adhesives are typically prepared by reacting polymer mixture of<br />

DYNACOLL® AC acrylics, DYNACOLL® 7000 polyester-polyols and polypropylene<br />

glycols with excess diisocyanantes like MDI (Diphenylmethane diisoyanates) at<br />

elevated temperatures under exclusion of moisture.<br />

These reactive hot melts can be applied e.g. with roller coaters.<br />

39


DYNACOLL® AC<br />

Analytical Methods<br />

Glass Transition Temperature<br />

Determination according to ISO 11357-1.<br />

Molecular Weight<br />

Determination according to DIN 55627-1.<br />

Viscosity Number<br />

Determination according to ISO 1628-1.<br />

Acid Number<br />

Determination according to DIN EN ISO 2114.<br />

Hydroxyl Number<br />

Determination according to DIN 53 240-02.<br />

Softening Point (Ring and Ball)<br />

Determination according to DIN ISO 4625.<br />

Melt Flow Rate 190 °C<br />

Determination according to DIN ISO 1133 (21.6 N).<br />

40


DYNACOLL® Terra<br />

Bio-based Polyester-Polyols<br />

Terra<br />

<strong>Evonik</strong>. Power to create.<br />

41


DYNACOLL® Terra<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

Bio-based Polyester-Polyols<br />

With its DYNACOLL® Terra product range <strong>Evonik</strong> offers polyester-polyols made<br />

from renewable raw materials.<br />

These bio-based polyesters contain between > 30 and 100 ppw of renewable<br />

monomers.<br />

According to our DYNACOLL® 7000 product range a building block system of<br />

medium molecular weight copolyesters for moisture curing PUR hot melts was<br />

developed. It is divided in three basic groups:<br />

• Amorphous Grades<br />

• Liquid Grades<br />

• Crystalline Grades<br />

DYNACOLL® Terra bio-based polyesters are usually supplied in 25 or 30 kg and<br />

190 or 200 kg steel drums.<br />

Your benefits<br />

• support of resource efficiency by using green components<br />

• modular combination of polyesters in RHM formulation possible<br />

• available grades exhibiting broad range of properties in formulations<br />

• well-balanced and versatile adhesion properties<br />

• implementation of new properties possible<br />

42


DYNACOLL® Terra<br />

Product Range<br />

Properties<br />

Proportion of<br />

Renewables<br />

Hydroxyl<br />

Number<br />

Molecular<br />

Weight<br />

Glass<br />

Transition<br />

Temperature<br />

Melting<br />

Point<br />

Softening<br />

Point<br />

(R&B)<br />

Melt<br />

Viscosity<br />

Grade [%] [mg KOH/g] [g/mol] [°C] [°C] [°C] [Pa s]<br />

Amorphous<br />

EP 413.01 > 30 30 3,500 30 85 35 (130 °C)<br />

EP 413.02 > 30 30 3,500 30 85 32 (130 °C)<br />

EP 413.03 > 35 40 2,800 40 90 17 (130 °C)<br />

EP 413.04 > 30 50 2,200 50 95 15 (130 °C)<br />

Liquid<br />

EP 424.01 > 85 30 3,500 -40 4 (80 °C)<br />

EP 424.02 > 75 30 3,500 -45 4 (80 °C)<br />

Crystalline<br />

EP 481.01 100 30 3,500 -45 55 65 2 (80 °C)<br />

EP 480.01 100 30 3,500 -20 65 75 2 (80 °C)<br />

EP 480.02 > 60 30 3,500 70 80 2 (80 °C)<br />

Acid number < 2 mg KOH/g<br />

43


DYNACOLL® Terra<br />

Reactive Hot Melt Data<br />

Reaction products of DYNACOLL Terra with: 4,4‘ – MDI as a ratio of OH : NCO = 1 : 2.2<br />

Properties<br />

Softening<br />

Point (R&B)<br />

Open Time Setting Time Melt Viscosity<br />

at 130 °C<br />

Trensile<br />

Strength<br />

Elongation at<br />

Break<br />

Grade [°C] [s] [s] [Pa s] [N/mm 2 ] [%]<br />

Amorphous<br />

EP 413.01 102 1 1 200 brittle<br />

EP 413.02 103 1 1 400 brittle<br />

EP 413.03 100 1


DYNACOLL® Terra<br />

Analytical Methods<br />

Hydroxyl Number<br />

Determination according to DIN 53 240-02.<br />

Acid Number<br />

Determination according to DIN EN ISO 2114.<br />

Glass Transition Temperature<br />

Determination according to DIN 53 765.<br />

Melting Point<br />

Determination according to DIN 53 765.<br />

Softening Point (Ring and Ball)<br />

Determination according to DIN ISO 4625.<br />

Melt Viscosity<br />

Determination according to DIN EN ISO 3219.<br />

Open Time<br />

Determination according to <strong>Evonik</strong> internal method.<br />

The material is heated up to 130 °C and applied on paper as an approximately 0.5 mm thick<br />

film. Strips of open surface paper are pressed into the melt at certain intervals. After the<br />

adhesive film is tackfree the paper strips are removed. The open time is given by the time,<br />

when no fiber tear can be observed anymore.<br />

Setting Time<br />

Determination according to <strong>Evonik</strong> internal method.<br />

The setting time is given by the time it takes until two bonded wooden cubes can no longer<br />

be twisted against each other by hand.<br />

45


VESTOPLAST®<br />

Amorphous Poly-alpha-olefins<br />

<strong>Evonik</strong>. Power to create.<br />

46


VESTOPLAST®<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

Amorphous Poly-alpha-olefins<br />

With its VESTOPLAST® amorphous poly-alpha-olefins (APAO) <strong>Evonik</strong> offers<br />

a broad range of co- and terpolymers of ethene, propene and 1-butene as raw<br />

materials for various applications.<br />

Under variation of monomer composition, molecular weight and chemical<br />

modification optimum values are achieved for properties like hardness, melt<br />

viscosity, crystallinity and rate of crystallization.<br />

The production process allows us to offer both predominately amorphous, soft<br />

grades as well as harder, partially crystalline grades.<br />

In addition to our regular, pure thermoplastic grades we also offer unique reactive,<br />

silane-modified amorphous poly-alpha-olefins like VESTOPLAST® 206.<br />

VESTOPLAST® is usually supplied as granules in 20 kg polyethylene bags.<br />

A special wax powdering technique improves the flowability of the material.<br />

Your benefits<br />

• excellent adhesion and hot tack properties<br />

• bonding to various substrates<br />

• good cohesion and high thermal stability<br />

• good moisture and gas barrier behaviour<br />

• very good hydrolytic and UV stability<br />

47


VESTOPLAST®<br />

Product Range<br />

Properties<br />

Melt Viscosity<br />

at 190°<br />

Softening Point<br />

(Ring & Ball)<br />

Needle<br />

Penetration<br />

(100/25/5)<br />

Thermal Stability<br />

under Load<br />

S.A.F.T.<br />

Tensile Strength/<br />

Elongration at<br />

Break<br />

Shear Modulus<br />

at 23 °C<br />

Molecular Weight Open Time Glass Transition<br />

M n<br />

/ M w<br />

Temperature Tg<br />

DSC analysis<br />

Density<br />

at 23 °C<br />

Shore Hardness A<br />

[mPa s] [°C] [0.1 mm] [°C] [MPa / %] [MPa] [g/mol] [s] resp. [min] [°C] [g/cm 3 ]<br />

(1-) Butene-rich<br />

308 8,000 ± 2,000 136 ± 6 17 ± 3 65 – 70 1.5 / 500 14 11,300 / 49,000 4 min -29 0.87 n.d.<br />

408 8,000 ± 2,000 118 ± 4 5 ± 2 85 – 90 6.8 / 80 70 11,600 / 48,000 65 s -27 0.90 94<br />

508 8,000 ± 2,000 84 ± 4 14 ± 3 60 – 65 1.5 / 340 12 11,800 / 52,000 15 min -31 0.87 74<br />

520 22,000 ± 4,000 87 ± 4 14 ± 3 65 – 70 2.4 / 80 7 13,900 / 63,000 15 min -29 0.88 76<br />

608 9,000 ± 3,000 157 ± 4 18 ± 3 60 – 65 1.5 / 480 11 12,300 / 46,000 3 min -32 0.87 76<br />

Propene-rich<br />

703 2,700 ± 700 124 ± 6 12 ± 3 75 – 80 2.1 / 43 41 7,300 / 34,000 15 s -28 0.87 87<br />

704 3,500 ± 500 105 ± 5 23 ± 5 70 – 75 0.5 / 100 7.5 8,000 / 35,000 80 s -36 0.87 n.d.<br />

708 8,000 ± 2,000 106 ± 4 19 ± 3 85 – 90 1.0 / 330 4 11,500 / 75,000 55 s -33 0.87 67<br />

750 50,000 ± 10,000 107 ± 4 14 ± 3 85 – 90 5.0 / 1,000 14 18,100 / 92,000 50 s -33 0.87 75<br />

751 50,000 ± 10,000 99 ± 4 25 ± 3 60 – 65 1.5 / 1,000 2 18,800 / 88,000 30 min -33 0.87 43<br />

792 120,000 ± 30,000 108 ± 4 14 ± 3 90 – 95 5.8 / 1,200 7 23,800 / 118,000 2 min 30 s -27 0.87 n.d.<br />

828 25,000 ± 7,000 161 ± 4 22 ± 3 95 – 100 1.0 / 550 4 13,200 / 61,000 70 s -35 0.87 55<br />

888 120,000 ± 40,000 161 ± 5 16 ± 4 115 – 120 2.5 / 850 6.5 15,000 / 104,000 4 s -36 0.87 n.d.<br />

891 115,000 ± 35,000 162 ± 4 22 ± 4 105 – 110 2.0 / 1,000 3 18,800 / 85,000 40 s -33 0.86 n.d.<br />

EP NC 702 2,800 ± 500 105 ± 4 36 ± 5 60 – 65 0.4 / 200 n.d. n.d. > 30 min -22 n.d. n.d.<br />

EP 807 7,000 ± 2,000 161 ± 3 7 ± 3 125 – 130 4.0 / 40 n.d. n.d. < 2 s -28 n.d. n.d.<br />

Silane modified<br />

206 5,000 ± 1,000 98 ± 4 19 ± 3 > 160 * 1.9 / 720 n.d. 10,600 / 38,000 approx. 20 s -28 0.87 n.d.<br />

*<br />

after curing<br />

n.d. = not determined<br />

48


VESTOPLAST® Applications<br />

206<br />

308<br />

408<br />

508<br />

520<br />

608<br />

703<br />

704<br />

708<br />

750<br />

751<br />

792<br />

828<br />

888<br />

891<br />

EP NC 702<br />

EP 807<br />

S/SR<br />

Hygiene<br />

Diapers, Feminine & Adult Care ▯ ▯ ▯ ▯ ▯ ▯<br />

Woodworking<br />

Profile wrapping ▯ ▯ ▯<br />

Edge banding ▯ ▯ ▯ ▯<br />

Paper & Packaging<br />

Laminated paper ▯ ▯ ▯<br />

Labels ▯ ▯ ▯<br />

Bookbinding ▯ ▯ ▯ ▯<br />

Fruit juice container ▯ ▯ ▯<br />

Automotive<br />

Headliner ▯ ▯<br />

Door panels ▯ ▯ ▯ ▯<br />

Filters ▯ ▯ ▯ ▯ ▯ ▯<br />

Car lamps ▯ ▯ ▯ ▯ ▯<br />

Insulating Felts ▯ ▯ ▯ ▯<br />

Carpet/Textile Flooring<br />

Carpet tiles ▯ ▯<br />

Wall to wall carpets ▯ ▯<br />

Car carpets ▯ ▯ ▯ ▯<br />

Bitumen<br />

Membranes (Roofing & Bridges) ▯ ▯ ▯<br />

Road construction<br />

▯<br />

Various Applications<br />

Cable fillings ▯ ▯<br />

Masterbatches ▯ ▯ ▯<br />

Mattrasses ▯ ▯ ▯ ▯ ▯<br />

Shoes ▯ ▯ ▯ ▯<br />

White goods ▯ ▯ ▯ ▯ ▯<br />

Window & Solar cell sealants ▯ ▯ ▯ ▯<br />

49


VESTOPLAST®<br />

Analytical Methods<br />

Melt Viscosity<br />

Determination according to DIN 53 019, modified.<br />

The melt viscosity is determined by a rotational viscosimeter. It describes the melting flow<br />

behaviour at 190 °C, high viscous grades exhibit a slight dependence on shear rate, low viscous<br />

grades are almost newtonian at elevated tempertaures.<br />

Softening Point (Ring & Ball)<br />

Determination according to DIN EN 1427.<br />

The material is heated up at 180 °C and then the melt is casted into a ring. After 24 h (this time<br />

is needed for recrystallization of the amorphous products) the sample is stressed concentrically<br />

with a chrome-plated steel ball and the test frame is immersed in a bath of glycerin. This is<br />

heated up with approx. 5 °C/min and the softening point is the temperature when the ball<br />

contacts the baseplate of the test frame.<br />

Needle Penetration<br />

Determination according to DIN EN 1426, modified.<br />

The material is heated up at 180 °C in a thin can. After 24 h (this time is needed for<br />

recrystallization of the amorphous products) the hardness of the product is determined with<br />

a needle and weight of 100 g at 25 °C. The penetration time into the sample is 5 s.<br />

Thermal Stability under Load / S.A.F.T.<br />

Determination according to <strong>Evonik</strong> method, similar to WPS 68.<br />

The thermal stability under load describes the thermal stability behaviour of bonded substrates.<br />

In case of VESTOPLAST® we use grey board to compare each VESTOPLAST® grade with<br />

another. A drop of the melt (180 °C) is placed on a side of the board and that is pressed to<br />

another grey board (T-form). After 24 h the prepared specimen are placed in a heating cabinet<br />

with a weight of 450 g and heated up with 5 °C/h. The thermal stability is the temperature<br />

when the bonded specimen breaks down.<br />

Tensile Strength / Elongation at Break<br />

Determination according to DIN EN ISO 527-3, modified type 5.<br />

The tensile strength describes the tensile and elongation properties of a specimen type 3 with<br />

2 mm thickness.<br />

Shear Modulus at 23 °C<br />

Determination according to DIN EN ISO 6721-2.<br />

This part specifies the general principles of a method for determining the dynamic rheological<br />

properties of polymer melts, part 2 described the Torsion-pendulum method.<br />

Molecular Weight Mn/Mw<br />

Determination according to GPC, DIN 55 672, modified.<br />

The molecular weight is calculated according to GPC, DIN 55672-1, detailed in Mn and Mw.<br />

Open Time<br />

Determination according to <strong>Evonik</strong> internal method.<br />

The melt (180 °C) is applied as a film of 20 μm on a paper. Strips of paper are pressed into the<br />

film at certain intervalls (depending on the open time). 30 minutes after the last strip has been<br />

applied, a test is carried out to see which of the last strips applied can be lifted off without<br />

pulling out the paper fibers. The time at which this strip was applied is noted.<br />

50


VESTOPLAST®<br />

Analytical Methods<br />

Glass Transition Temperature<br />

Determination according to DIN 53 765.<br />

Density at 23 °C<br />

Determination according to DIN EN ISO 1183-1.<br />

Shore Hardness A<br />

Determination according to GPC, DIN 53 505.<br />

This determination specifies the hardness of a specimen. The resistance against penetration<br />

of a specific form and specific spring tension. The values are depending on the visco-elastic<br />

properties of the polymer.<br />

51


VESTOWAX®<br />

Fischer-Tropsch-Waxes<br />

<strong>Evonik</strong>. Power to create.<br />

52


VESTOWAX®<br />

The Value Additive<br />

Synthetic Waxes<br />

With its VESTOWAX® product range <strong>Evonik</strong> offers synthetic waxes produced<br />

by Fischer-Tropsch-Process.<br />

This process yields straight-chain products possessing low viscosity in the melt<br />

and having molecular weights of between 500 and 1,000 g/mol.<br />

The definition of the term ›wax‹ is based less on the chemical composition of<br />

a substance than on its physical properties:<br />

• kneadable at 20 °C, with a consistency ranging from solid to brittle-hard<br />

• coarsely to finely crystalline, translucent to opaque<br />

• melt above 40 °C without decomposition<br />

• already of relatively low viscosity at just above the melting point<br />

• highly temperature-dependent consistency and solubility<br />

• can be polished under gentle pressure<br />

In addition to crude FT-wax, the range of VESTOWAX® products includes<br />

modified hard paraffins, oxidates and partially saponified waxes.<br />

Depending on the supply form different bags sizes are offered:<br />

Prills usually in 25 kg bags or 700 kg big bags, pellets and coarse powder usually<br />

in 20 kg bags, microfine powder usually in 15 kg bags.<br />

Your benefits<br />

• solutions for a multitude of applications<br />

• extensive range of FT-modified grades<br />

• wide variety of supply forms - from pellets to microfine powder<br />

53


VESTOWAX®<br />

Product Range<br />

Properties<br />

Supply Form Drop Point Penetration<br />

Number<br />

Acid Number<br />

Saponification<br />

Number<br />

Molecular Mass<br />

Mw<br />

Density<br />

at 23 °C<br />

Viscosity<br />

Color<br />

[°C] [mm 10-1] [mg KOH/g] [mg KOH/g] [g/mol] [g/cm 3 ] [mPa s]<br />

Crude FT-Wax * )<br />

GTL Sarawax SX 105 Prills 114 – 120 1 ~ 900 ~ 0.94 < 20 (at 130 °C) white<br />

GTL Sarawax SX 100 Prills 108 – 112 1 ~ 700 ~ 0.94 < 20 (at 120 °C) white<br />

VESTOWAX Hard paraffins<br />

EH 100 Pellets 102 – 110 2 – 5 ~ 600 ~ 0.94 < 20 (at 120 °C) white<br />

SH 105 Pellets 108 – 114 1 ~ 750 ~ 0.94 < 20 (at 120 °C) white<br />

SH 105 Powder 112 – 116 1 ~ 750 ~ 0.94 < 20 (at 120 °C) white<br />

H 2050 MG Powder 114 – 120 1 ~ 900 ~ 0.94 < 20 (at 130 °C) white<br />

H 2050 SF Microfine Powder 114 – 120 1 ~ 900 ~ 0.94 < 20 (at 130 °C) white<br />

SH 112 Microfine Powder 114 – 120 1 ~ 900 ~ 0.94 < 20 (at 130 °C) white<br />

FM 1012 Microfine Powder 114 – 120 1 ~ 1.00 < 20 (at 130 °C) white<br />

VESTOWAX Oxidates<br />

C 20 Flakes 106 – 111 1 – 3 10 – 13 20 – 30 ~ 0.96 < 20 (at 120 °C) white<br />

C 40 Micro Prills 102 – 108 2 – 4 24 – 27 40 – 50 ~ 0.96 < 20 (at 130 °C) white<br />

C 60 Flakes & Powder 100 – 105 3 – 5 29 – 34 50 – 62 ~ 0.96 < 20 (at 120 °C) white<br />

*)<br />

Available from <strong>Evonik</strong> in Europe only.<br />

54


VESTOWAX®<br />

Applications<br />

Crude FT-WAX * )<br />

VESTOWAX Grades<br />

Sarawax<br />

SX 105<br />

Sarawax<br />

SX 100<br />

EH 100<br />

SH 105<br />

H 2050 MG<br />

H 2050 SF<br />

SH 112<br />

FM 1012<br />

C 20<br />

C 40<br />

C 60<br />

Hot Melts<br />

Crystallinity improver ▯ ▯ ▯<br />

Viscosity reducer ▯ ▯ ▯<br />

Melting point improver ▯ ▯ ▯<br />

Surface stickiness reducer ▯ ▯ ▯<br />

Plastics Processing<br />

Lubricants for PVC ▯ ▯ ▯<br />

Nucleating agent for expandable polystyrene ▯ ▯<br />

Dispersing aid for pigments and fillers ▯ ▯ ▯<br />

Processing aid for rubber ▯ ▯<br />

Internal mould release agent for thermosetting plastics ▯ ▯<br />

Mould release agent for waterborne systems ▯ ▯<br />

Mould release agent for solventborne systems ▯ ▯<br />

Printing Inks<br />

Rub resistance ▯ ▯ ▯<br />

Slip improver and anti-blocking agent ▯ ▯ ▯<br />

Paints<br />

Scratchproofing agent ▯ ▯ ▯<br />

Matting agent ▯ ▯<br />

Processing aid for powder coatings<br />

▯<br />

Technical Emulsions<br />

Sewing Yarn lubricant ▯ ▯<br />

Sizing agent<br />

▯<br />

Cosmetics<br />

Lipstick hardener ▯ ▯<br />

Oil binder for pastes ▯ ▯<br />

Dispersing aid for color-cosmetics<br />

▯<br />

Polishes<br />

Dry-bright emulsions ▯ ▯<br />

Solventborne systems ▯ ▯<br />

Wax Compounds & Candle Additives<br />

Dispersing aid for dyes ▯ ▯<br />

Hardening ▯ ▯ ▯<br />

*)<br />

Available from <strong>Evonik</strong> in Europe only.<br />

55


VESTOWAX®<br />

Analytical Methods<br />

Drop Point<br />

Determination according to DGF M-III 3.<br />

Also in accordance with DIN 51 801 or ASTM D 566.<br />

Penetration Number<br />

Determination according to DGF M-III 9b.<br />

Also in accordance with DIN 51 579 or ASTM D 1321.<br />

Acid Number<br />

Determination according to DGF M-IV 2.<br />

Also in accordance with DIN 53 402 or ASTM D 1386.<br />

Saponification Number<br />

Determination according to DGF M-IV 2.<br />

Also in accordance with DIN 53 401 or ASTM D 1387.<br />

Molecular Mass<br />

Determination by HT-GPC.<br />

Density at 23 °C<br />

Determination according to DIN 53 479.<br />

Viscosity<br />

Determination according to DIN 52 007/1.<br />

56


POLYVEST®<br />

Liquid Polybutadienes<br />

<strong>Evonik</strong>. Power to create.<br />

57


POLYVEST®<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

Liquid Polybutadienes<br />

With its POLYVEST® <strong>Evonik</strong> offers a range of stereospecific, low viscous and<br />

unsaponifiable liquid polybutadienes of different chemical composition:<br />

• POLYVEST® - non-functionalized liquid polybutadienes<br />

• POLYVEST® MA - maleic anhydride-functionalized liquid polybutadienes<br />

• POLYVEST® HT - hydroxyl-terminated liquid polybutadienes<br />

Our non-functionalized products differ in molar mass and viscosity.<br />

The MA-functionalized products are adducts of linear polybutadiene and maleic<br />

anhydride and differ in maleic anhydride content and viscosity. The anhydride<br />

groups are randomly distributed along the polymer chains and thus make the<br />

originally apolar polybutadiene more polar and accessible for various chemical<br />

reactions.<br />

The hydroxyl-terminated product is an alpha-omega-terminated diol of<br />

polybutadiene manufactured by radical polymerisation process. In addition to the<br />

double bonds in the polymer backbone, the hydroxyl functional groups provide<br />

opportunities for precise chemical modifications.<br />

The non-functionalized POLYVEST® grades are supplied in steel drums with<br />

190kgs net. The maleic anhydride-functionalized grades are supplied in steel drums<br />

with 180kgs net and 900kgs net IBC. POLYVEST HT® is available in steel drums<br />

and IBC. Road tanker delivery is possible for all grades.<br />

Your benefits<br />

The microstructure of our POLYVEST® grades makes them a highly reactive<br />

and cross-linking binder and provides them with properties including:<br />

• excellent chemical resistance<br />

• high water resistance<br />

• very good electrical insulation<br />

• very good cold-resistance<br />

• low moisture and oxygen permeability<br />

Our POLYVEST® grades can be used in a broad field of applications.<br />

58


POLYVEST®<br />

Product Range<br />

POLYVEST® 110 130 MA 75 EP * MA 120 EP * HT<br />

Specifications<br />

Viscosity at 20 °C [mPa s] 700 – 860 2,700 – 3,300 6,000 – 9,000 approx. 61,000 (23 °C) –<br />

Viscosity at 30 °C [mPa s] – – – approx. 30,000 4,000 - 5,500<br />

Acid Number [mg KOH/g] ≤ 0.3 ≤ 0.3 70 – 90 approx. 130 –<br />

Hydroxyl Number [mg KOH/g] – – – – 44 - 51<br />

Peroxide Number [mval/kg] ≤ 10 ≤ 10 – – –<br />

Typical Data<br />

Supply Form viscous liquid viscous liquid viscous liquid viscous liquid viscous liquid<br />

Microstructure:<br />

1,4 -cis double bonds approx. 75% approx. 77%<br />

approx. 20%<br />

1,4 -trans double bonds approx. 24% approx. 22% based on POLYVEST 110<br />

approx. 58%<br />

1,2 -vinyl double bonds approx. 1% approx. 1% approx. 22%<br />

Molecular Weight M n<br />

[g/ mol] approx. 2,600 approx. 4,600 approx. 3,000 approx. 3,200 approx. 4,000<br />

Iodine No. [g lod/100g] 420 – 480 420 – 480 380 – 420 380 – 420 420 - 440<br />

Density at 20 °C [g/cm 3 ] 0.90 – 0.92 0.90 – 0.92 approx. 0.95 approx. 0.97 0.90 - 0.92<br />

Gardner Color ≤ 1 ≤ 4 ≤ 2.5 ≤ 2.5 ≤ 1<br />

Flash Point [°C] approx. 180 approx. 200 approx. 300 > 300 (DIN ISO 2592) approx. 215<br />

Ignition Temperature [°C] approx. 360 approx. 350 approx. 360 approx. 355 approx. 375<br />

Pour Point [°C] approx. -55 approx. -50 approx. -25 approx. -1 approx. -18<br />

Tg [°C] approx. -100 approx. -99 approx. -95 approx. -92 approx. -80<br />

*<br />

EP = Experimental Product<br />

59


POLYVEST®<br />

Product Range<br />

POLYVEST® 110 130 MA 75 EP * MA 120 EP * HT<br />

Compatibility of POLYVEST® Grades with binders and resins<br />

Acrylate resins Methacrylates – – – – –<br />

OH-acrylates ◦ – ◦ ◦ –<br />

Alkyd resins short-oil – – – – –<br />

medium-oil ◦ – ◦ ◦ –<br />

long-oil ◦ – + + ◦<br />

Carbamic acid resins – – – – –<br />

Cellulose esters – – – – –<br />

Epoxy resins, low molecular weight – – ◦ ◦ –<br />

Glycerol resin esters – – ◦ ◦ –<br />

Hydrocarbon resins + + ◦ ◦ +<br />

Ketone resins ◦ ◦ ◦ ◦ ◦<br />

Melamine resins – – ◦ ◦ –<br />

Nitrocellulose – – – – –<br />

Phthalate resins – – – – –<br />

Resols, unplasticized – – – – –<br />

Rosin esters + + + + +<br />

Rosin-modified phenolic resins – – – – –<br />

Saturated polyesters – ◦ – – –<br />

Styrene-alkyd resins – – – – –<br />

Urea resins, unplasticized – – ◦ ◦ –<br />

Zinc resinates + + + + +<br />

Solubility of POLYVEST® Grades<br />

Alcohols – – ◦ ◦ –<br />

Aliphatic hydrocarbons + + + + +<br />

Aromatic hydrocarbons + + + + +<br />

Esters ◦ ◦ ◦ ◦ ◦<br />

Ethers + + + + +<br />

Glycol ethers – – – – –<br />

Ketones ◦ ◦ ◦ ◦ ◦<br />

+ compatible / soluble ◦ limited compatibility / solubility – incompatible / insoluble<br />

The compatibility results represent 40 wt.% of the binder/resin with POLYVEST.<br />

The solubility reflects adding 90 and 50 wt.% of solvent to 10 and 50 wt.% POLYVEST.<br />

This information is based on our best knowledge and experience. We recommend conducting your own tests and experiments prior to use.<br />

*<br />

EP = Experimental Product<br />

60


POLYVEST®<br />

Applications<br />

non-functionalized MA-functionalized hydroxyl-terminated<br />

Liquide polybutadienes POLYVEST® 110 130 MA 75 EP * MA 120 EP * HT<br />

Automotive<br />

<strong>Adhesive</strong>s and Sealants ▯ ▯ ▯ ▯ ▯<br />

Coatings<br />

Air Drying Improver of Vegetable Oils ▯ ▯<br />

Defoamers<br />

▯<br />

Impregnations ▯ ▯<br />

Modifier in Resin Systems ▯ ▯<br />

Construction<br />

<strong>Adhesive</strong>s and Sealants / Insulated Glass Sealants<br />

▯<br />

Binder for dusty and dry Quartz Sand ▯ ▯<br />

Binder for Soil Stabilization<br />

▯<br />

Modifier of Silicone Sealants<br />

▯<br />

Electronics<br />

Electrical Insulations and Potting Compounds ▯ ▯ ▯ ▯<br />

Plastics<br />

Cell Opener for PU-Foam<br />

▯<br />

Release Agents for PU-Foam ▯ ▯ ▯<br />

Polymer Modification<br />

Chlorinated Rubbers ▯ ▯<br />

Electrocoatings<br />

Waterborne, oxidative drying Binders<br />

▯<br />

▯<br />

Printing & Inks<br />

Offset Printing Inks ▯ ▯<br />

Flexible Printing Plates ▯ ▯<br />

Rubber<br />

Binder for recycled Rubber Compounds ▯ ▯ ▯<br />

Modifier in Carbon Black-filled EPDM Compounds ▯ ▯<br />

Modifier in Silica-filled Rubber Compounds ▯ ▯<br />

Plasticizer in Rubber Compounds ▯ ▯<br />

Polymeric Chalk Activator in EPDM Compounds ▯ ▯<br />

*<br />

EP = Experimental Product<br />

61


POLYVEST®<br />

Analytical Methods<br />

Viscosity<br />

Determination according to DIN EN ISO 3219.<br />

Acid Number<br />

Determination according to DIN EN ISO 2114.<br />

Hydroxyl Number<br />

Determination according to DIN 53 240-2.<br />

Peroxide Number<br />

Determination according to DGF-method: C-VI-6a (84).<br />

Molecular Weight M n<br />

Determination according to DIN 55 627-1.<br />

Iodine Number<br />

Determination according to DIN 53 241.<br />

Density at 20 °C<br />

Determination according to DIN ISO 2811-1.<br />

Gardner Color<br />

Determination according to DIN EN ISO 4630-2.<br />

Flash Point<br />

Determination according to DIN EN ISO 2719.<br />

Determination according to DIN ISO 2592 (POLYVEST® EP * MA 120).<br />

Ignition Temperature<br />

Determination according to DIN 51 794.<br />

Pour Point<br />

Determination according to DIN ISO 3016.<br />

Glass Transition Temperature Tg<br />

Determination according to DIN EN ISO 11 357-1.<br />

Further information<br />

Storage<br />

POLYVEST® products are stable for at least 1 year with exclusion of air,<br />

light and moisture and at storage temperatures below 25 °C.<br />

Safety and Handling<br />

POLYVEST® products react with atmospheric oxygen to form peroxides<br />

and undergo cross-linking in its presence. Thus POLYVEST® products are<br />

packed and delivered under a blanket of inert gas (nitrogen). When<br />

handling, prevent any exposure of the products to atmospheric oxygen.<br />

Opened containers should be blanketed with inert gas again and closed<br />

tightly. Please refer to our Material Safety Data Sheets.<br />

62


DEGALAN®<br />

Binders for Heat Seal Lacquers<br />

<strong>Evonik</strong>. Power to create.<br />

63


DEGALAN®<br />

Designed Polymers for <strong>Adhesive</strong>s & Sealants<br />

Binders for Heat Sealing Applications<br />

With its DEGALAN® binders <strong>Evonik</strong> offers a unique product portfolio of functional<br />

methacrylic polymers. These binders represent an excellent solution for heat sealing<br />

applications in the packaging industry.<br />

Our functional binders can be divided into four groups based on their appearance:<br />

• DEGALAN® - Bead Polymers<br />

• DEGALAN® - Organic Solutions<br />

• DEGALAN® - Organic Dispersions<br />

• DEGALAN® - Aqueous Dispersions<br />

Our DEGALAN® binders for heat sealing applications are ideally suited for<br />

formulation of high-quality lacquers to provide an excellent and secure heat sealing<br />

in combination with smooth peeling.<br />

DEGALAN® organic dispersions provide direct adhesion to aluminium or PET lid<br />

material for economical and environmentally friendly packaging solutions.<br />

All common cup materials from polar polystyrene to non-polar polypropylene<br />

can be sealed.<br />

All products comply with international regulations for incident food contact.<br />

DEGALAN® methacrylate bead polymers are usually supplied in paper bags.<br />

DEGALAN® organic solutions, dispersions as well as aqueous dispersions can<br />

be supplied in drums, IBCs or tank trucks.<br />

Your benefits<br />

• excellent seal and peel properties on aluminium foil or film structures<br />

• outstanding smooth peel effect<br />

• wide property range: from easy opening to high sealing strength<br />

• multi-purpose sealing capabilities to various substrates<br />

• economical and environmental friendly packaging solutions<br />

64


DEGALAN®<br />

Product Range<br />

Properties<br />

Solvent<br />

Solid<br />

Content<br />

Viscosity<br />

Number<br />

Dynamic<br />

Viscosity<br />

1) 3)<br />

Dilutability<br />

2) 3)<br />

Solubility<br />

Sealability versus<br />

[%]<br />

[cm 3 /g]<br />

[mPa·s]<br />

[N/mm 2 ]<br />

DEGALAN® Bead Polymer<br />

P 24 – 100 approx. 55 approx. 450 4) E, K PS, PVC<br />

VP P 34 – 100 approx. 55 approx. 450 4) E, K PS, PVC<br />

DEGALAN® Organic Solution<br />

4792 L Methyl ethyl ketone 55 approx. 40 1,000 – 3,000 E, K PS, PVC<br />

4793 L Ethyl acetate 55 approx. 40 2,000 – 5,000 E, K PS, PVC<br />

DEGALAN® Organic Dispersion<br />

PM 555<br />

PM 666<br />

n-Butyl acetate/<br />

Methyl ethyl ketone<br />

70/30<br />

n-Butyl acetate/<br />

Methyl ethyl ketone<br />

70/30<br />

45 approx. 125 500 – 1,500 E, K PS, PVC, PP, PET<br />

45 approx. 125 1,000 – 3,500 E, K PS, PVC, PP, PET<br />

4150 E n-Propyl acetate/Ethyl<br />

acetate/Isooctane<br />

54/36.5/9.5<br />

4151 E n-Propyl acetate/Ethyl<br />

acetate/Isooctane<br />

47.8/43.8/8.4<br />

43 approx. 125 800 – 2,500 E, K PS, PVC, PP, PET<br />

40 approx. 125 500 – 2,000 E, K PS, PVC, PP, PET<br />

VP 4190 E<br />

VP 4311 E<br />

VP 4174 E<br />

n-Propyl acetate/Ethyl<br />

acetate/Cyclohexane<br />

60/37/3<br />

n-Propyl acetate/<br />

Cyclohexane 84/16<br />

n-Propyl acetate/Ethyl<br />

acetate/Isooctane<br />

49/42.5/8.5<br />

44 approx. 125 1,000 – 3,500 E, K PS, PVC, PP, PET<br />

40 approx. 65 500 – 2000 E, K PS, PVC, PET<br />

46 approx. 125 1,000 – 3,500 E, K PS, PVC, PP, PET<br />

DEGALAN® Aqueous Dispersion<br />

4140 D Water 50 not determined approx. 100 W PLA, Primer for<br />

aluminium<br />

4032 D Water 50 not determined approx. 100 W PS, PVC<br />

VP 4240 D Water 50 not determined approx. 300 - 400 W PS, PVC<br />

1)<br />

for dispersions and solutions<br />

2)<br />

for solids<br />

3)<br />

E = Esters, K = Ketones, W = Water<br />

4)<br />

40% in MEK<br />

65


DEGALAN®<br />

Applications<br />

Adhesion to Aluminum Adhesion to PET Sealable versus<br />

Direct<br />

Primered<br />

with<br />

PVC 1)<br />

In formulation<br />

with PVC<br />

Direct<br />

Primered<br />

with<br />

PES 2)<br />

In formulation<br />

with PVC<br />

PVC PS PP PET<br />

P 24 ▯ ▯ ▯ ▯ ▯ ▯<br />

VP P 34 ▯ ▯ ▯<br />

4792 L ▯ ▯ ▯ ▯ ▯ ▯<br />

4793 L ▯ ▯ ▯ ▯ ▯ ▯<br />

PM 555 ▯ ▯ ▯ ▯ ▯ ▯ ▯<br />

4150 E ▯ ▯ ▯ ▯ ▯ ▯ ▯<br />

VP 4190 E ▯ ▯ ▯ ▯ ▯ ▯ ▯<br />

PM 666 ▯ ▯ ▯ ▯ ▯ ▯<br />

4151 E ▯ ▯ ▯ ▯ ▯ ▯<br />

VP 4311 E ▯ ▯ ▯ ▯ ▯<br />

VP 4174 E ▯ ▯ ▯ ▯ ▯ ▯<br />

4140 D ▯ ▯ 3) ▯ 3)<br />

4032 D ▯ ▯ ▯<br />

VP 4240 D ▯ ▯ ▯<br />

1)<br />

PVC adhesion promoter like Vinnol® terpolymer grade from e.g. Wacker Chemie <strong>AG</strong>, Burghausen, Germany<br />

2)<br />

Polyester like Dynapol® L 206 oder L 208 from <strong>Evonik</strong> <strong>Industries</strong> <strong>AG</strong>, Marl, Germany<br />

3)<br />

PLA (Poly lactic acid)<br />

66


DEGALAN®<br />

Analytical Methods<br />

Solid Content<br />

Determination according to DIN EN ISO 3251.<br />

Dynamic Viscosity<br />

Determination according to DIN EN ISO 3219.<br />

Glass Transition Temperature Tg<br />

Determination according to DIN 53765 bzw. DIN EN ISO 11357-1.<br />

Viscosity Number<br />

Determination according to DIN 51562 bzw. DIN EN ISO 1628-1.<br />

Molecular Weight (Mw)<br />

Determination according to DIN 55672-1.<br />

67


If you need more information please contact us:<br />

adhesives@evonik.com<br />

www.evonik.com/designed-polymers<br />

This information and all further technical advice is based on our present knowledge<br />

and experience. However, it implies no liability or other legal responsibility on our part,<br />

including with regard to exisiting third party intellectual property rights, especially<br />

patent rights. In particular, no warranty, whether express or implied, or guarantee of<br />

product properties in the legal sense is intended or implied. We reserve the right to<br />

make any changes according to technological progress or further developments. The<br />

customer is not released from the obligation to conduct careful inspection and testing<br />

of incoming goods. Performance of the product described herein should be verified by<br />

testing, which should be carried out only by qualified experts in the sole responsibility<br />

of a customer. Reference to trade names used by other companies in neither a<br />

recommendation, nor does it imply that similar products could not be used.<br />

(September 2013)<br />

68

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