K = K0 K1 K2 K0 K1 K2
K = K0 K1 K2 K0 K1 K2
K = K0 K1 K2 K0 K1 K2
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ΔH o 298 = 2*135100 - 227480 = 42720.00 J mol -1<br />
ΔG o 298 = 2*124700 - 209970 = 39430.00 J mol -1<br />
ΔG o /RT =<br />
K 0 = exp(-ΔG o 0 /RT 0 )<br />
= exp(-39430/(8.314*298.15))<br />
= 1.2353E-07<br />
K 1 = exp((ΔH o 0 /RT 0 )(1-T 0 /T))<br />
= exp((42720/(8.314*298.15))*(1-298.15/923.15))<br />
= 1.1677E+05<br />
τ = 923.15/298.15 = 3.0963<br />
K 2 = exp{ΔA[lnτ-(τ-1)/τ] + (1/2)ΔBT 0 (τ-1) 2 /τ + (1/6)ΔCT 2 0 (τ-1) 2 (τ+2)/τ + (1/2)ΔD(τ-1) 2 /(T 2 0 τ 2 )}<br />
= exp(0.06*(ln(3.0963)-(3.0963-1)/3.0963)+(1/2)*0.000173*298.15*(3.0963-1)*(3.0963-1)/3.0963<br />
+(1/2)*(-19100)*(3.0963-1)*(3.0963-1)/(298.15*298.15*3.0963*3.0963))<br />
= 1.0147<br />
K = K 0 K 1 K 2<br />
= 1.2353*1.1677*1.0147E-2<br />
= 1.4637E-02